The present disclosure generally relates to the micro-assembly and electrical connection of micro-integrated circuits using micro-transfer printing.
Components can be transferred from a source wafer to a target substrate using micro-transfer printing. Methods for transferring small, active components (e.g., micro-devices) from one substrate to another are described in U.S. Pat. Nos. 7,943,491, 8,039,847, and 7,622,367. In these approaches, small integrated circuits are formed on a native semiconductor source wafer. The small, unpackaged bare-die integrated circuits, or chiplets, are released from the native source wafer by pattern-wise etching sacrificial portions of a sacrificial layer located beneath the chiplets, leaving each chiplet suspended over an etched sacrificial portion by a tether physically connecting the chiplet to an anchor separating the etched sacrificial layer portions. A viscoelastic stamp is pressed against the process side of the chiplets on the native source wafer, adhering each chiplet to an individual stamp post. The stamp with the adhered chiplets is then removed from the native source wafer. The chiplets on the stamp posts are pressed against a non-native target substrate or backplane with the stamp and adhered to the target substrate. In another example, U.S. Pat. No. 8,722,458 entitled Optical Systems Fabricated by Printing-Based Assembly teaches transferring light-emitting, light-sensing, or light-collecting semiconductor elements from a wafer substrate to a target substrate or backplane.
Electrically connecting integrated circuit structures on a wafer or other substrate can be difficult if the integrated circuit structures extend a significant height above the substrate. This height is commonly called a step height and can be, for example, no less than two microns, no less than five microns, no less than ten microns, or no less than twenty microns. Electrical connections to integrated circuit structures are commonly made on the top (e.g., the process surface) of an integrated circuit structure. When conductive materials, for example metals used to make electrodes or electrical wires, are deposited on a substrate, for example by evaporation or sputtering, the materials tend to deposit more thickly on horizontal surfaces (e.g., the substrate surface or micro-device top surface) than on vertical surfaces (e.g., the side of an integrated circuit or micro-device structure) causing relatively poor, or no, electrical conductivity on the vertical surface. This problem becomes more significant as the step height increases. Conventionally, this problem is addressed by making a more gradual transition from a substrate surface to the top of the integrated circuit structure so that conductive material deposits thicker on the gradual and less steep transition. For example, dielectric materials can be deposited and patterned with sloped walls. However, this approach makes the connected structure larger, inhibiting desirable miniaturization. Another method relies on planarizing the substrate surface so that the substrate surface is approximately in the same plane, or even slightly above, a top surface of the integrated circuit structure. This approach is described in, for example, U.S. Pat. No. 5,674,773 entitled Method for planarizing high step-height integrated circuit structures. However, a thick planarization layer can inhibit forming electrical connections to a metal layer, contact pad, or conductor (wire) on the substrate surface, since vias will be necessary to open the electrical connections and the side walls of the vias can suffer from the same step height problem. There is a need, therefore, for integrated-circuit structures and methods that facilitate electrical connections between the integrated-circuit structures.
The present disclosure provides, inter alia, structures and methods for a micro-device structure that includes a substrate having a substrate surface, a cavity disposed in and extending into the substrate from the substrate surface, a micro-device disposed in the cavity, the micro-device comprising a micro-device contact, a planarization layer disposed over at least a portion of the substrate, and an electrode disposed at least partially over or on the planarization layer and electrically connected to the micro-device contact. The planarization layer can be a cavity-filling layer and need not planarize the entire substrate surface.
According to some embodiments, the micro-device structure comprises a substrate contact disposed on or in the substrate surface and the electrode is electrically connected to the substrate contact. The substrate contact can be an electrode, wire, contact pad or other electrically conductive structure disposed on the substrate. The micro-device can comprise a separated or broken (e.g., fractured) tether as a consequence of micro-transfer printing the micro-device from a micro-device source wafer into the cavity in the substrate. The planarization layer can be disposed at least partly in the cavity and the micro-device can be disposed at least partly on at least a portion of the planarization layer in the cavity.
According to some embodiments, (i) the micro-device has a thickness no greater than two microns, no greater than five microns, no greater than ten microns, no greater than fifteen microns, or no greater than twenty microns, (ii) the cavity has a depth of no greater than 500 nm, no greater than one micron, no greater than two microns, no greater than five microns, no greater than ten microns, no greater than fifteen microns, or no greater than twenty microns, (iii) the planarization layer has a thickness over the substrate surface of no greater than ten nm, no greater than twenty nm, no greater than thirty nm, no greater than fifty nm, no greater than sixty nm, no greater than seventy-five nm, no greater than one hundred nm, no greater than two hundred fifty nm, no v than five hundred nm, or no greater than one micron, or (iv) any compatible combination of (i), (ii), and (iii).
The substrate surface and a top surface of the micro-device can be separated by a distance no greater than five microns, no greater than three microns, no greater than two microns, no greater than one micron, or no greater than five hundred nm in a direction orthogonal to the substrate surface.
According to some embodiments of the present disclosure, the micro-device is a first micro-device, the micro-device contact is a first micro-device contact and the micro-device structure comprises a second micro-device disposed in the cavity, the second micro-device comprising a second micro-device contact, and the electrode electrically connects the first micro-device contact to the second micro-device contact.
According to some embodiments, the substrate surface and a top surface of the micro-device are separated by a distance less than a thickness of the micro-device (e.g., no more than half of the thickness, no more than a quarter of the thickness, no more than an eighth of the thickness, or no more than a tenth of the thickness).
According to some embodiments of the present disclosure, the micro-device is a first micro-device, the micro-device contact is a first micro-device contact, the cavity is a first cavity, and the micro-device structure comprises a second micro-device disposed in a second cavity extending into the substrate from the substrate surface, the second micro-device comprising a second micro-device contact, and the electrode electrically connects the first micro-device contact to the second micro-device contact.
According to some embodiments of the present disclosure, a micro-device structure comprises a substrate having a substrate surface, one or more cavities extending into the substrate from the substrate surface, two or more micro-devices, at least one of the micro-devices disposed in each of the one or more cavities, each of the micro-devices comprising a micro-device contact, and an electrode electrically connecting at least a first micro-device contact of a first one of the micro-devices and a second micro-device contact of a second one of the micro-devices. The one or more cavities can comprise at least two cavities, two or more of the micro-devices are disposed in one of the one or more cavities, or both. According to some embodiments, a planarization layer is disposed over at least a portion of the substrate. According to some embodiments, a first cavity of the one or more cavities extends a first distance into the substrate, a second cavity of the one or more cavities extends a second distance into the substrate, and the first distance is different from the second distance. According to some embodiments, a first micro-device of the two or more micro-devices has a first thickness, a second micro-device of the two or more micro-devices has a second thickness, and the first thickness is different from the second thickness. Some embodiments of the present disclosure comprise a substrate contact disposed on or in the substrate surface and the electrode is electrically connected to the substrate contact.
According to some embodiments, a top surface of the micro-device is separated from the substrate surface by a distance no greater than five microns, no greater than three microns, no greater than two microns, no greater than one micron, or no greater than five hundred nm in a direction orthogonal to the substrate surface. According to some embodiments, the micro-device comprises a separated or broken (e.g., fractured) tether as a consequence of micro-transfer printing the micro-device.
According to embodiments of the present invention, ones of the micro-devices (i) have different functionalities, (ii) comprise different materials (e.g., different semiconductors) (e.g., have been printed from different source wafers), or (iii) both (i) and (ii). Some embodiments further comprise a second electrode electrically connecting at least a third micro-device contact of a third one of the micro-devices and a fourth micro-device contact of a fourth one of the micro-devices. The electrode can further electrically connect at least a third micro-device contact of a third one of the micro-devices.
According to some embodiments of the present disclosure, a method of making a micro-device structure comprises providing a substrate having a substrate surface and one or more cavities extending into the substrate from the substrate surface, providing a micro-device source wafer comprising one or more micro-devices disposed on or in the micro-device source wafer, each comprising a micro-device contact, micro-transfer printing the one or more micro-devices from the micro-device source wafer into the one or more cavities, planarizing the substrate, and forming an electrode disposed at least partially over or on the planarization layer that electrically connects to the micro-device contact of at least one of the micro-devices. Some embodiments comprise forming one or more vias in the planarizing layer prior to forming the electrode and forming the electrode comprises forming a portion of the electrode in the via. The one or more vias can have sloped sides. Forming the electrode can comprise forming one or electrodes on the substrate surface or in electrical contact with a substrate contact disposed on the substrate surface. The at least one of the micro-devices can be at least two of the micro-devices. The substrate can comprise a substrate contact disposed on or in the substrate surface and forming the electrode can comprise electrically connecting the electrode to the substrate contact.
According to some embodiments of the present disclosure, a micro-device structure comprises a substrate having a substrate surface, a cavity extending into the substrate from the substrate surface, a micro-device disposed in the cavity, and a planarization layer disposed over at least a portion of the substrate and in contact with the micro-device and the cavity. At least a portion of the micro-device can be exposed and the planarization layer can extend over only a portion of the micro-device.
In some embodiments, the planarization layer has a pit adjacent to the micro-device or a protrusion adjacent to or over the micro-device. The pit can be disposed between a side of the micro-device non-parallel to the substrate surface and a side of the cavity non-parallel to the substrate surface, e.g., between a side of the micro-device and a side of the cavity.
According to some embodiments, the micro-device structure comprises a via formed through the planarization layer that exposes a portion of the substrate surface or exposes a layer or structure disposed on the substrate surface. The planarization layer can have a planarization layer surface on a side of the planarization layer opposite the substrate and the micro-device has a micro-device surface on a side of the micro-device opposite the substrate. The via can have a via side width that extends from the planarization layer surface to the substrate surface or to the layer or structure formed on the substrate surface. The planarization layer can have a device via side width that extends from the planarization layer surface to the micro-device surface. The device via side width can be greater than the via side width.
According to some embodiments, the planarization layer has a planarization layer surface on a side of the planarization layer opposite the substrate and the micro-device has a micro-device surface on a side of the micro-device opposite the substrate. The via can have a via edge that extends from the planarization layer surface to the substrate surface or to the layer or structure formed on the substrate surface, so that the via edge has an average via slope with respect to the substrate surface. The planarization layer can have a planarization edge that extends from the planarization layer surface to the micro-device surface, so that the planarization edge has an average micro-device planarization slope with respect to the substrate surface. The via slope can be greater than the micro-device planarization slope.
In some embodiments, the substrate of the micro-device structure comprises a substrate contact disposed on the substrate in the via, the micro-device comprises a micro-device contact disposed on a surface of the micro-device opposite the substrate, and the micro-device structure comprises an electrode disposed on a portion of the planarization layer opposite the substrate that electrically connects the substrate contact to the micro-device contact. The micro-device contact can be a first micro-device contact and in some embodiments the micro-device can comprise a second micro-device contact disposed on the surface of the micro-device opposite the substrate so that a first portion of the first micro-device contact is exposed through the planarization layer, a second portion of the second micro-device contact is exposed through the planarization layer, and the first portion is larger than the second portion.
In some embodiments, a side of the micro-device non-parallel to the substrate surface can be closer to a side of the cavity non-parallel to the substrate surface than any other side of the micro-device non-parallel to the substrate surface is to any side of the cavity. The side of the micro-device can be in contact with the side of the cavity or can be within one micron of the side of the cavity. Two sides of the micro-device non-parallel to the substrate surface can each be closer to a respective one of two sides of the cavity non-parallel to the substrate surface than any other sides of the micro-device non-parallel to the substrate surface are to any side of the cavity, e.g., so that the micro-device is disposed in a corner of the cavity. In some embodiments a center of the micro-device is not coincident with a center of the cavity.
According to some embodiments of the present disclosure, a surface of the micro-device opposite the substrate extends farther from the substrate surface than a surface of the planarization layer opposite the substrate. A surface of the planarization layer opposite the substrate can extend farther from the substrate surface than a surface of the micro-device opposite the substrate. A surface of the micro-device opposite the substrate can be below a surface of the planarization layer with respect to the substrate. The micro-device can be entirely within the cavity. The micro-device can be only partly within the cavity and can extend above the cavity with respect to the substrate. The planarization layer can extend over only a portion of a surface of the micro-device opposite the substrate.
In some embodiments, the micro-device comprises a broken (e.g., fractured) or separated micro-device tether, is a bare, unpackaged die, or both.
According to embodiments of the present disclosure, a substrate structure comprises a substrate having a substrate surface and a patterned cured layer disposed on and in contact with the substrate surface. The patterned cured layer can have a layer surface on a side of the patterned cured layer opposite the substrate surface. A first portion of the patterned cured layer can cover a first portion of the substrate surface and a second portion of the patterned cured layer can cover a second portion of the substrate surface, a first via can extend from the layer surface to the substrate surface in the first portion, and a second via can extend from the layer surface to the substrate surface or a structure disposed on or in the substrate in the second portion. The first via can have a first via edge width and the second via can have a second via edge width greater than the first via edge width so that a slope of the first via is greater than a slope of the second via. In some embodiments, the patterned cured layer comprises a photoresist, for example a positive photoresist or a negative photoresist.
In some embodiments, a patterned metal layer can be disposed on the second portion. The patterned metal layer can extend into the first portion. The patterned cured layer can be cross linked and can comprise, for example, epoxy, resin, benzocyclobutene, or Intervia photodielectric (e.g., a photo-patternable dielectric material).
In some embodiments, a micro-device can be disposed on the substrate surface and the second portion can be in contact with the micro-device. The micro-device can extend no less than 5 microns (e.g., no less than 10 microns, no less than 15 microns, or no less than 20 microns) from the substrate surface.
According to embodiments of the present disclosure, a method of making a substrate structure comprises providing a substrate having a substrate surface, disposing a curable layer on the substrate surface, providing a dithered mask over the substrate surface and over the curable layer, the dithered mask comprising light portions that are substantially transparent, dark portions that are substantially opaque, and dithered portions that are more transparent than the dark portions and less transparent than the light portions, exposing the curable layer to electromagnetic radiation through the dithered mask to pattern and partially cure the curable layer forming completely cured portions of the curable layer, completely uncured portions of the curable layer, and portions of the curable layer that are partially cured, and developing the curable layer to cure the curable layer and form a patterned cured layer having a variable thickness. The patterned cured layer can have a first via with a first side edge width and a second via can have a second via side width greater than the first via side width. Some embodiments comprise reflowing the patterned cured layer.
The curable layer can be a photoresist, for example a positive photoresist or a negative photoresist. Some embodiments of the present disclosure can comprise hard curing the patterned cured layer, for example so that the patterned cured layer has a slope with an angle no greater than 45 degrees, no greater than 30 degrees, no greater than 20 degrees, or no greater than 10 degrees with respect to the substrate surface.
Some embodiments of the present disclosure comprise micro-transfer printing a micro-device onto the substrate surface or printing a micro-device into a cavity in the substrate. Some embodiments comprise micro-transfer printing the micro-device with offset shear.
According to some embodiments of the present disclosure, a variable-resolution photolithographic mask comprises one or more dark areas that are relatively opaque to electromagnetic radiation and one or more light areas that are relatively transparent to electromagnetic radiation, the mask substrate having one or more spatial areas of transparency transition from one of the one or more dark areas to one of the one or more light areas. At least one of the one or more spatial areas of transparency transition comprises a high-resolution transition area that changes from relatively opaque to relatively transparent in a first spatial distance and a low-resolution transition area that changes from relatively opaque to relatively transparent in a second spatial distance greater than the first spatial distance.
The low-resolution transition area can comprise a variable density of electromagnetic-radiation-absorbing material or electromagnetic-radiation-reflecting material in or on a mask substrate. The electromagnetic-radiation-absorbing material or electromagnetic-radiation-reflecting material in or on the mask substrate can comprise chromium or carbon black.
The low-resolution transition area can comprise a pattern of one or more structures that have a variable spatial density of a constant amount of electromagnetic radiation material absorbing material in the mask substrate. The pattern of one or more structures can comprise triangles, lines with varying widths, areas having curved edges, dots, or rectangles.
Embodiments of the present disclosure provide improved electrical connections between the micro-device contacts on a top surface of a micro-device disposed on a substrate and substrate contacts or electrical connections on the substrate or a layer disposed on the substrate.
The foregoing and other objects, aspects, features, and advantages of the present disclosure will become more apparent and better understood by referring to the following description taken in conjunction with the accompanying drawings, in which:
Features and advantages of the present disclosure will become more apparent from the detailed description set forth below when taken in conjunction with the drawings, in which like reference characters identify corresponding elements throughout. In the drawings, like reference numbers generally indicate identical, functionally similar, and/or structurally similar elements. The figures are not drawn to scale since the variation in size of various elements in the Figures is too great to permit depiction to scale.
The present disclosure provides, inter alia, micro-device structures comprising one or more micro-devices disposed on a substrate that are electrically connected, for example with a photolithographically defined wire or other electrical connection, to electrical connections, contacts, or wires on the substrate or a layer disposed on the substrate or to other micro-devices. Embodiments of the present disclosure provide structures with a reduced step height (e.g., a distance) between the top surface of a micro-device and the substrate or layer disposed on the substrate, where the top or top surface of a micro-device is a side of the micro-device opposite the substrate so that the micro-device is between the top surface and at least some portion of the substrate. Structures with such reduced step heights enable improved electrical connections between the top surface of the micro-device and electrical conductors on the substrate surface or a layer disposed on the substrate surface, for example by reducing vertical or steep edges in the structure and the need to deposit material on the vertical or steep edges. Such steep edges can be found on the side of a micro-device or the side or edge of a via. According to some embodiments, micro-devices provided as a bare die (e.g., without an integrated circuit package) can have a micro-device substrate thickness no less than five, ten, fifteen, or twenty microns with steep (e.g., substantially or effectively orthogonal to a top surface of the micro-device) edge or side of the micro-device. Where a surface of the substrate or top surface of the micro-device are effectively horizontal, such steep edges can be effectively vertical, or nearly so. Disposing material (e.g., electrically conductive material such as metal) on such steep or vertical edges can be difficult, especially where the thickness of the deposited metal (e.g., less than five microns) is less than the step height of the micro-device on the substrate (e.g., no less than five, ten, fifteen, or twenty microns, or even more). Because deposited material coverage on the steep or vertical edges can be poor, electrical connections between the top surface of the micro-device and the substrate can be likewise poor or non-existent and can therefore have a high resistance or form an electrical open (e.g., no electrical continuity between electrical contacts on the top surface of the micro-device and electrical conductors on the substrate).
According to embodiments of the present invention and as illustrated in
As shown in the plan view of
Embodiments of the present disclosure are well adapted to electrically connecting small integrated circuits (e.g., micro-devices 20) disposed on substrate 10, for example integrated circuits that are bare die and are not packaged. Such small integrated circuits can provide improved utilization of source wafers and improved circuit density and performance for heterogeneous systems comprising circuits made in different materials and native to different source wafers or source substrates. In embodiments of the present disclosure, micro-device 20 has a thickness no less than two microns, no less than five microns, no less than ten microns, no less than fifteen microns, or no less than twenty microns. Micro-device 20 can have a length or width, or both, of no greater than two hundred microns (e.g., no greater than one hundred microns, no greater than fifty microns, no greater than twenty microns, no greater than ten microns, or no greater than five microns).
According to embodiments of the present disclosure, a reduced step height between micro-device top surface 21 and substrate surface 11 can be provided by disposing micro-device 20 in cavity 12 so that micro-device top surface 21 is closer to substrate surface 11 than would be the case if micro-device 20 were placed on substrate surface 11 without cavity 12. Thus, in embodiments cavity 12 can have a depth substantially equal or relatively close to a thickness of micro-device 20, e.g., within five percent, ten percent, twenty percent, or fifty percent. In some embodiments, cavity 12 has a depth of no less than 500 nm, no less than one micron, no less than two microns, no less than five microns, no less than ten microns, no less than fifteen microns, or no less than twenty microns. Thus, according to embodiments, substrate surface 11 and micro-device top surface 21 are separated by a distance no greater than five microns (e.g., no greater than three microns, no greater than two microns, no greater than one micron, or no greater than five hundred nm) in a direction orthogonal to substrate surface 11.
In embodiments of the present disclosure, a reduced step height between micro-device top surface 21 and substrate surface 11 can be provided by providing planarization layer 30 with a thickness substantially equal to or relatively close to a height (e.g., distance D in
According to embodiments of the present disclosure and as illustrated in the flow diagram of
In step 130 and as shown in
If planarization layer 30 extends over micro-device contact 24, a via 60 can be formed over micro-device contact 24 and if planarization layer 30 extends over substrate contact 44, a via 60 can be formed over substrate contact 44 in step 150 and as shown in
According to embodiments of the present disclosure, cavity 12 can have a depth substantially equal to or within five percent, ten percent, twenty percent, or fifty percent of the thickness of micro-device 20.
According to embodiments of the present disclosure and as illustrated in
Planarization layer 30 can be disposed at least partially on a sidewall of cavity 12, for example as shown in
According to some embodiments of the present disclosure and as illustrated in
According to some embodiments of the present disclosure and as illustrated in
Thus, according to embodiments of the present disclosure, a micro-device structure 90 comprises a substrate 10 having a substrate surface 11, one or more cavities 12 disposed in substrate 10, each of the cavities 12 extending to substrate surface 11, two or more micro-devices 20, at least one micro-device 20 disposed in each of the one or more cavities 12, each micro-device 20 comprising a micro-device contact 24, and an electrode 50 electrically connecting at least a first micro-device contact 24A of a first micro-device 20A and a second micro-device contact 24B of a second micro-device 20B. As shown in
Micro-device structures according to embodiments of the present disclosure can comprise a substrate 10 having a substrate surface 11, a cavity 12 extending into substrate 10 from substrate surface 11, a micro-device 20 disposed in cavity 12, and a planarization layer 30 disposed over at least a portion of substrate 10 in contact with micro-device 20. Planarization layer 30 can be a cavity-filling layer and need not planarize the entire substrate surface 11. At least a portion of micro-device 20, e.g., a portion or only a portion of micro-device top surface 21 can be exposed and planarization layer 30 can extend into cavity 12, can contact a cavity side 13 of cavity 12, can extend over only a portion of micro-device 20, e.g., only a portion of micro-device top surface 21, can contact a micro-device side 23 of micro-device 20, or any combination of these. As shown in
Planarization layers 30 disposed over substrates 10 and micro-devices 20 disposed in cavities 12 can be coated using, for example, spin coating or spray coating. However, it is possible that the coated planarization layer is not in fact locally planar in the region of cavity 12, especially when planarization layer 20 is relatively thin, for example no greater than five microns, no greater than two microns, no greater than one micron, no greater than 0.5 microns, or no greater than 0.2 microns. As shown in
Reduced (e.g., poor) electrode coverage 70 can be mitigated or prevented, according to embodiments of the present disclosure and as shown in
Thus, according to embodiments of the present disclosure and as shown in
Via 60 has a via edge that extends from planarization layer surface 31 to substrate surface 11 or to any layer or structure formed on substrate surface 11 and the via edge has an average via slope with respect to substrate surface 11. Low-spatial resolution via 61 has a planarization edge of planarization layer 30 with an average micro-device planarization slope with respect to substrate surface 11. The via slope is greater than the micro-device planarization slope, e.g., the via slope is steeper than the micro-device planarization slope so that via 60 has a higher spatial resolution than low-spatial resolution via 61.
Embodiments of the present disclosure include a wide variety of high-resolution vias 60, low-resolution vias 61, substrate contacts 44, and micro-device contacts 24. In some embodiments, micro-devices 20 can comprise multiple micro-device contacts 24 that are exposed by a common low-resolution via 61, for example as shown in
In some embodiments, a side of micro-device 20 non-parallel to substrate surface 11 (e.g., a vertical micro-device side 23 or edge) is closer to a side of cavity 12 non-parallel to substrate surface 11 (e.g., a vertical cavity side 13 or edge) than any other side of micro-device 20 non-parallel to the substrate surface. Thus, micro-device 20 can be printed closely adjacent to or pushed toward a side of cavity 12. In some embodiments, a side of micro-device 20 is in contact with a side of cavity 12 or is within one micron of the side of cavity 12. In some embodiments, two sides of micro-device 20 non-parallel to the substrate surface are closer to two sides of cavity 12 non-parallel to substrate surface 11 than any other sides of micro-device 20 non-parallel to substrate surface 11, for example where micro-device 20 is disposed closely adjacent to or in contact with a corner of cavity 12. In some such embodiments, a center of micro-device 20 is not necessarily congruent with a center of cavity 12 so that micro-device 20 is offset within and with respect to cavity 12 rather than centered within cavity 12.
In some embodiments, micro-device 20 extends beyond (e.g., sticks up or protrudes through planarization layer 30, e.g., as shown in
In some embodiments, micro-device 20 does not extend over the top of cavity 12 (e.g., does not extend above substrate surface 11 or planarization layer surface 31) as shown in
In general, and according to some embodiments of the present disclosure, a substrate structure comprises a substrate 10 having a substrate surface 11 and a patterned cured layer (e.g., planarization layer 30) disposed on and in contact with substrate surface 11, the patterned cured layer having a layer surface (e.g., planarization layer surface 31) on a side of the patterned cured layer opposite substrate surface 11. A first portion of the patterned cured layer covers a first portion of substrate surface 11 (e.g., covers substrate circuit 40) and a second portion of the patterned cured layer covers a second portion of substrate surface 11 (e.g., covers cavity 12 or at least a portion of micro-device 20 or another portion of substrate 10). A first via 60 extends from the layer surface to the substrate surface in the first portion and a second low-resolution via 61 extends from the layer surface to substrate surface 11 or a structure (e.g., cavity 12 or micro-device 20) disposed on or in substrate 10 in the second portion. The first via has a first substrate via side width WV (e.g. substrate via side width WV) and the second via has a second via side width WP (e.g., device via side width WP) greater than the first via side width WV so that a slope of the first via 60 is greater than a slope of the second via 61.
In some embodiments of the present disclosure, micro-devices 20 can be micro-transfer printed from a micro-device 20 source wafer into cavities 12. In some embodiments, a single micro-device 20 is disposed in each cavity 12. In some embodiments, multiple micro-devices 20 are disposed in each cavity 12. As a consequence of micro-transfer printing, micro-devices 20 can comprise a broken (e.g., fractured) or separated micro-device tether 22 or is a bare, unpackaged die, or both. Micro-transfer printing enables very small micro-devices, e.g., having a length or width, or both, no greater than 100, 50, 20, 10, 5, or 3 microns and, alternatively or additionally, a thickness no greater than 50, 20, 10, 5, or 2 microns, into a cavity of similar, but slightly larger, size. Prior methods, such as pick-and-place for surface mount components cannot dispose such small devices into such small cavities. Thus, some embodiments of the present disclosure enable a significant reduction in size (e.g., at least a factor of 10 in each dimension) for electronic or opto-electronic components with a consequent reduction in parasitic resistance, capacitance, and inductance, and an increase in heat removal.
According to some embodiments of the present disclosure, forming a low-resolution via 61 over micro-device 20, micro-device sides (edges) 23, cavity 12, or cavity sides (edges) 13 can mitigate or eliminate difficulties in forming electrodes 50 over micro-device 20, micro-device sides 23, cavity 12, or cavity sides 13 with effective deposition thickness and conductivity. Such low-resolution vias can be constructed using dithered masks 73. According to some embodiments and as shown in
In some embodiments and as shown in
In some embodiments and as shown in
Thus, according to some embodiments of the present disclosure, a variable-resolution photolithographic mask (e.g., dithered mask 73) comprises a mask substrate 76 having one or more dark areas 78 that are relatively opaque to electromagnetic radiation and one or more light areas 79 that are relatively transparent to electromagnetic radiation, the mask substrate 76 having one or more spatial areas of transparency transition from one of the dark areas 78 to one of the light areas 79. At least one of the spatial areas of transparency transition comprises a high-resolution transition area that changes from relatively opaque to relatively transparent in a first spatial distance and a low-resolution transition area that changes from relatively opaque to relatively transparent in a second spatial distance greater than the first spatial distance in either one or two dimensions.
The variation in light absorption can be continuous, for example as shown in
When disposed over an undeveloped planarization layer 30 and exposed to electromagnetic radiation, dithered mask 73 allows variable amounts of radiation to expose planarization layer 30. If planarization layer 30 is a positive photoresist, the exposure will variably degrade the photoresist material in the area exposed to the variable amount of radiation. If planarization layer 30 is a negative photoresist, the exposure will variably strengthen the photoresist material in the area exposed to the variable amount of radiation, e.g., by polymerization or cross linking. When planarization layer 30 is subsequently exposed to a developer, the weak areas of planarization layer 30 wash away. According to some embodiments of the present disclosure, planarization layer 30 can be either a positive or a negative photoresist can be used with a correspondingly patterned dithered mask 73. Because the amount of photoresist material degradation or strengthening varies relatively gradually compared to the conventional binary pattern (either as opaque as possible or as transparent as possible), when planarization layer 30 is developed, the planarization layer 30 thickness gradually changes. For clarity, the Figures show structures and methods using a positive photoresist, but embodiments of the present disclosure are not limited to such and embodiments using negative photoresists are analogously contemplated.
According to some embodiments, a dithered mask 73 is a binary mask 30 that provides a dithered exposure to planarization layer 30 by moving dithered mask 30 over planarization layer 30 and performing multiple exposures where the multiple exposures expose at least one portion of planarization layer 30 every time. Thus, different portions of planarization layer 30 will be exposed by different amounts that, when developed form a variable-thickness planarization layer 30.
As illustrated in
The variable thickness can have a slope with an angle no greater than 45 degrees, no greater than 30 degrees, no greater than 20 degrees, or no greater than 10 degrees. Micro-device 20 can be or can include, for example, any one or more of an electronic component, a piezoelectric device, an integrated circuit, an electromechanical filter, an acoustic resonator, an antenna, a micro-heater, a micro-fluidic structure for containing and constraining fluids, a micro-mechanical device, and a power source, for example a piezo-electric power source. Micro-device(s) 20 can be electronic, optical, or optoelectronic devices that can be electrically, optically, or both electrically and optically interconnected to other micro-devices 20 or substrate circuit 40. Although many figures presented herein often illustrate a single micro-device 20, one of ordinary skill in the art will appreciate that there will generally be many such micro-devices 20 or cavities 12 (e.g., in a two-dimensional array). According to some embodiments, micro-device 20 has a thickness less than 1 mm (e.g., no greater than 500, 200, 100, 50, 20, 10, 5, 1, or 0.5 microns). According to some embodiments, micro-device 20 has a length or width less than 1 mm (e.g., no greater than 500, 200, 100, 50, 20, or 10 microns).
A micro-device 20 can be any device that has at least one dimension that is in the micron range, for example having a planar extent from 2 microns by 5 microns to 200 microns by 500 microns (e.g., an extent of 2 microns by 5 microns, 20 microns by 50 microns, or 200 microns by 500 microns) and, optionally, a thickness of from 200 nm to 200 microns (e.g., at least or no greater than 2 microns, 20 microns, or 200 microns). In some embodiments, micro-device 20 has a dimension as large as, or larger than 5 mm. Micro-device 20 can have any suitable aspect ratio or size in any dimension and any useful shape, for example a rectangular area or cross section. Micro-device 20 can be non-native to substrate 10. According to embodiments of the present disclosure, cavity 12 has a length and width over substrate 10 that is only slightly larger than a length and width of micro-device 20, for example 500 nm, one micron, two microns, three microns, five microns, ten microns, or twenty microns larger in length or width, or both length and width. Similarly, cavity 12 can have a thickness that is only slightly larger or smaller than a thickness of micro-device 20, for example no greater than twenty microns, no greater than ten microns, no greater than five microns, no greater than two microns, no greater than one micron, or no greater than 50 nm. Providing a cavity 12 with a depth approximately equal to a thickness of micro-device 20 reduces a step height S from micro-device top surface 21 and a substrate surface 11 of substrate 10. Providing a cavity 12 with an area over substrate surface 11 that is only slightly larger than an area of micro-device 20 likewise reduces the topology (changes in substrate surface 11 height with respect to a plane), improving the coating of an electrical conductor over substrate surface 11 and micro-device 20. According to embodiments of the present disclosure, micro-devices 20 can be micro-transfer printed into cavities 12 that have an area that is only a few, or less than one, microns larger in length and width than an area of the micro-devices 20. Other conventional methods such as pick-and-place used to dispose surface mount devices on a target substrate can be too inaccurate or too imprecise to effectively place micro-devices 20 into such cavities 12 and cannot readily dispose micro-devices with a length and width less than 200 microns.
According to some embodiments, micro-device 20 can be disposed over and native to a source wafer (e.g., a source substrate). A source wafer can comprise a sacrificial layer comprising anchor portions laterally separated by sacrificial portions in a direction parallel to a surface of the source wafer. Anchor portions can be a part of source wafer or a structure disposed on the source wafer. Micro-devices 20 can each be disposed over a sacrificial portion and physically connected by a tether 22 to an anchor portion. Sacrificial portions can be etched to form a gap between a micro-device 20 and the source wafer so that micro-devices 20 can be transfer printed from the source wafer to target substrate 10, thereby fracturing or separating tethers 22.
In some embodiments of the present disclosure, micro-devices 20 are small integrated circuits, which may be referred to as chiplets, having a thin micro-device substrate with at least one of (i) a thickness of only a few microns, for example less than or equal to 25 microns, less than or equal to 15 microns, or less than or equal to 10 microns, (ii) a width of 5-1000 microns (e.g., 5-10 microns, 10-50 microns, 50-100 microns, or 100-1000 microns), and (iii) a length of 5-1000 microns (e.g., 5-10 microns, 10-50 microns, 50-100 microns, or 100-1000 microns). Such chiplets can be made in a native source semiconductor wafer (e.g., a silicon wafer) having a process side and a back side used to handle and transport the source wafer using lithographic processes. Micro-devices 20 can be formed using lithographic processes in an active layer on or in the process side of a micro-device source wafer. Methods of forming such structures are described, for example, in U.S. Pat. No. 8,889,485. According to some embodiments of the present disclosure, source wafers can be provided with micro-devices 20, sacrificial layer (a release layer), sacrificial portions, and tethers 22 already formed, or they can be constructed as part of a process in accordance with certain embodiments of the present disclosure.
In certain embodiments, micro-devices 20 can be constructed using foundry fabrication processes used in the art. Layers of materials can be used, including materials such as metals, oxides, nitrides and other materials used in the integrated-circuit art. Micro-devices 20 can have different sizes, for example, less than 1000 square microns or less than 10,000 square microns, less than 100,000 square microns, or less than 1 square mm, or larger. Micro-devices 20 can have, for example, at least one of a length, a width, and a thickness of no greater than 500 microns (e.g., no greater than 250 microns, no greater than 100 microns, no greater than 50 microns, no greater than 25 microns, or no greater than 10 microns). Micro-devices 20 can have variable aspect ratios, for example at least 1:1, at least 2:1, at least 5:1, or at least 10:1. Micro-devices 20 can be rectangular or can have other shapes.
Tethers 22 can comprise any suitable tether material and can incorporate one or more layers, for example one or more layers similar to or the same as those layer(s) of micro-device 20, for example comprising electrode material, dielectric(s), or encapsulation layer(s), including resins, silicon oxides, silicon nitrides, or semiconductors. Tethers 22 can be constructed be depositing (e.g., by evaporation or sputtering) material such as oxide, nitride, metal, polymer, or semiconductor material, and patterning the material, for example using photolithographic methods and materials, such as pattern-wise exposed and etched photoresist.
Micro-device source wafers (e.g., source substrates) can be any useful substrate with a surface suitable for forming or having patterned sacrificial layers, sacrificial portions, anchor portions, and forming or disposing micro-devices 20. Source wafers can comprise glass, ceramic, polymer, metal, quartz, or semiconductors, for example as found in the integrated circuit or display industries. A sacrificial portion can be a designated portion of a sacrificial layer, for example an anisotropically etchable portion, for example designated by virtue of etchant applied to the source wafer is exposed to it relative to other portions of the source wafer, or a differentially etchable material from sacrificial layer, for example a buried oxide or nitride layer, such as silicon dioxide. A surface of the source wafer can be substantially planar and suitable for photolithographic processing, for example as found in the integrated circuit or MEMS art. Source wafers can be chosen, for example, based on desirable growth characteristics (e.g., lattice constant, crystal structure, or crystallographic orientation) for growing one or more materials thereon. In some embodiments of the present disclosure, the source wafer is anisotropically etchable.
For example, a source wafer can be a monocrystalline silicon substrate with a {100} orientation. An anisotropically etchable material etches at different rates in different crystallographic directions, due to reactivities of different crystallographic planes to a given etchant. For example, potassium hydroxide (KOH) displays an etch rate selectivity 400 times higher in silicon [100] crystal directions than in silicon [111] directions. In particular, silicon {100} is a readily available, relatively lower cost monocrystalline silicon material. Moreover, in some embodiments, micro-devices 20 made on or in a silicon {100} crystal structure can have less stress and therefore less device bowing after release.
As is understood by those skilled in the art, the terms “over” and “under” are relative terms and can be interchanged in reference to different orientations of the layers, elements, and substrates included in the present disclosure. For example, a first layer on a second layer, in some implementations means a first layer directly on and in contact with a second layer. In other implementations, a first layer on a second layer includes a first layer and a second layer with another layer therebetween.
Having described certain implementations of embodiments, it will now become apparent to one of skill in the art that other implementations incorporating the concepts of the disclosure may be used. Therefore, the disclosure should not be limited to certain implementations, but rather should be limited only by the spirit and scope of the following claims.
Throughout the description, where apparatus and systems are described as having, including, or comprising specific components, or where processes and methods are described as having, including, or comprising specific steps, it is contemplated that, additionally, there are apparatus, and systems of the disclosed technology that consist essentially of, or consist of, the recited components, and that there are processes and methods according to the disclosed technology that consist essentially of, or consist of, the recited processing steps.
It should be understood that the order of steps or order for performing certain action is immaterial so long as operability is maintained. Moreover, two or more steps or actions in some circumstances can be conducted simultaneously. The disclosure has been described in detail with particular reference to certain embodiments thereof, but it will be understood that variations and modifications can be effected within the spirit and scope of the claimed invention.
A cross section
D distance
S step height
WP device via side width
WV via side width
10 substrate/target substrate
11 substrate surface
12 cavity
12A first cavity
12B second cavity
13 cavity side
14 adhesive layer
20 micro-device
20A first micro-device
20B second micro-device
21 micro-device top surface
22 tether
23 micro-device side
24 micro-device contact
24A micro-device contact
24B micro-device contact
26 dielectric structure
30 planarization layer
31 planarization layer surface
40 substrate circuit
44 substrate contact
50 electrode
60 via
61 low-resolution via
62 pit/trench
64 protrusion/bump
70 poor electrode coverage
72 mask
73 dithered mask
74 incident electromagnetic radiation
75 transmitted electromagnetic radiation
76 mask substrate
77 dithered film
78 dark areas
79 light areas
80 stamp
82 stamp post
90 micro-device structure
100 provide target substrate step
110 provide micro-device source wafer step
120 etch cavity in target substrate step
130 print micro-device into cavity step
140 planarize structure step
150 pattern vias step
160 form electrodes step
200 provide substrate step
205 print micro-device step
210 dispose planarization layer step
220 provide dithered mask step
230 expose planarization layer through dithered mask step
240 develop planarization layer step
250 optional reflow planarization layer step
260 hard cure planarization layer step
270 pattern electrodes step
This application is a continuation-in-part of U.S. patent application Ser. No. 17/404,300, filed on Aug. 17, 2021, and also claims the benefit of U.S. Provisional Patent Application No. 63/272,652, filed on Oct. 27, 2021, the disclosure of each of which is hereby incorporated by reference herein in its entirety.
Number | Date | Country | |
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63272652 | Oct 2021 | US |
Number | Date | Country | |
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Parent | 17404300 | Aug 2021 | US |
Child | 17972484 | US |