Process of forming a microphone using support member

Information

  • Patent Grant
  • 8309386
  • Patent Number
    8,309,386
  • Date Filed
    Friday, October 3, 2008
    16 years ago
  • Date Issued
    Tuesday, November 13, 2012
    12 years ago
Abstract
A method of forming a microphone forms a backplate, and a flexible diaphragm on at least a portion of a wet etch removable sacrificial layer. The method adds a wet etch resistant material, where a portion of the wet etch resistant material is positioned between the diaphragm and the backplate to support the diaphragm. Some of the wet etch resistant material is not positioned between the diaphragm and backplate. The method then removes the sacrificial material before removing any of the wet etch resistant material added during the prior noted act of adding. The wet etch resistant material then is removed substantially in its entirety after removing at least part of the sacrificial material.
Description
FIELD OF THE INVENTION

The invention generally relates to microphones and, more particularly, the invention relates to methods for forming microphones.


BACKGROUND OF THE INVENTION

Some processes form microphones, such as MEMS microphones, by depositing a diaphragm material onto a sacrificial material that ultimately is removed by wet etching processes. Problems arise, however, when the surface tension of the liquid etchant causes the diaphragm to stick to its corresponding backplate. See U.S. Pat. No. 5,314,572 for an example of one method discussed for use with inertial sensors.


SUMMARY OF THE INVENTION

In accordance with one aspect of the invention, a method of forming a microphone forms a backplate, and a flexible diaphragm on at least a portion of a wet etch removable sacrificial layer. The method adds a wet etch resistant material, where a portion of the wet etch resistant material is positioned between the diaphragm and the backplate to support the diaphragm. Some of the wet etch resistant material is not positioned between the diaphragm and backplate. The method then removes the sacrificial material before removing any of the wet etch resistant material added during the prior noted act of adding. The wet etch resistant material then is removed substantially in its entirety after removing at least part of the sacrificial material.


Some embodiments release the diaphragm, which involves removing the sacrificial material and removing the wet etch resistant material. In some embodiments, the wet etch resistant material comprises a photoresist material. Moreover, the wet etch resistant material may be removed by application of a dry etch. It should be noted that the act of forming a flexible diaphragm may include a number of different things. For example, it may involved depositing a material on a sacrificial layer, or simply providing a silicon wafer on an insulator, such as the top layer of a silicon-on-insulator (“SOI”) wafer.


In illustrative embodiments, the wet etch resistant material is a single, substantially contiguous apparatus, which is substantially completely removed by the process in a single act. Moreover, the wet etch resistant material may be unpatterned after the portion of wet etch resistant material is positioned between the diaphragm and the backplate.


The backplate may be formed from a number of different types of wafers, such as a part of a SOI wafer. As a further example, the sacrificial material may be formed from polysilicon or oxide.


Various processes may be executed to complete the microphone. For example, the method may form a first hole through the diaphragm, and a second hole through the sacrificial material. The second hole effectively produces a channel between a bottom surface of the diaphragm and a top surface of the backplate. To support the diaphragm, the portion of wet etch resistant material substantially fills the channel. In some embodiments, the wet etch resistant material substantially completely fills the first hole even when the sacrificial material is removed.


In accordance with another embodiment of the invention, a method of forming a MEMS microphone provides an SOI wafer having a top layer, forms a sacrificial material on the top layer of the SOI wafer, and forms a diaphragm on the sacrificial material. The method also forms a hole through the diaphragm, and a channel through the sacrificial material. The hole and channel are in fluid communication, and the channel exposes a bottom surface of the diaphragm and a top surface of the top layer of the SOI wafer. The method then adds a wet etch resistant material having a first portion within the channel and a second contiguous portion that is external to channel and substantially completely fills the hole through the diaphragm. At least a portion of the sacrificial material is removed before removing any of the wet etch resistant material.


The method eventually may release the diaphragm. To that end, the wet etch resistant material illustratively is removed after removing at least part of the sacrificial material. In some embodiments, the method removes a portion of the bottom and middle SOI layers to form a backside cavity. The method also may form a backplate hole through the top layer of the SOI wafer. Illustrative embodiments ensure that the wet etch resistant material is unpatterned after the wet etch resistant material is added to the channel.


In accordance with another embodiment of the invention, a MEMS microphone apparatus has a backplate, a diaphragm having a through-hole and top and bottom sides, and a substantially contiguous, unpatterned, wet etch resistant material, between the backplate and diaphragm. The material supports the diaphragm by being in contact with both the top and bottom sides of the diaphragm. In addition, the apparatus has an air space between portions of the diaphragm and the backplate.


In accordance with other embodiments of the invention, a method of forming a MEMS microphone provides a diaphragm layer on a sacrificial layer, where the sacrificial layer is between the diaphragm layer and a substrate. Next, the method forms a wet etch resistant material between the substrate and the diaphragm, and forms a backside cavity. The method then applies a wet etch material to the sacrificial material through the backside cavity to remove at least a portion of the sacrificial layer. At least a portion of the wet etch resistant material supports the diaphragm layer after applying the wet etch material.


In some embodiments, the diaphragm layer, sacrificial layer and substrate are respective layers of a single SOI wafer. Moreover, the act of providing may include depositing a material on the sacrificial layer to form the diaphragm.





BRIEF DESCRIPTION OF THE DRAWINGS

The foregoing advantages of the invention will be appreciated more fully from the following further description thereof with reference to the accompanying drawings wherein:



FIG. 1A schematically shows a perspective view of an unpackaged microphone that may be fabricated in accordance with illustrative embodiments of the invention.



FIG. 1B schematically shows a cross-sectional view of the microphone shown in FIG. 1A.



FIGS. 2A and 2B show a process of forming the microphone shown in FIGS. 1A and 1B in accordance with illustrative embodiments of the invention.



FIG. 3A schematically shows a view of the microphone during a stage of the method shown in FIG. 2A (steps 200-208).



FIG. 3B schematically shows a view of the microphone during a stage of the method shown in FIG. 2A (step 214).



FIG. 3C schematically shows a view of the microphone during a stage of the method shown in FIG. 2A (step 216).



FIG. 3D schematically shows a view of the microphone during a stage of the method shown in FIG. 2A (step 218).



FIG. 3E schematically shows a view of the microphone during a stage of the method shown in FIG. 2A (step 220).





DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS

In illustrative embodiments, a method of forming a microphone uses a liquid etch resistant material to prevent its diaphragm from adhering or otherwise sticking to its backplate during a liquid/wet etch step. To that end, the illustrative method forms a wet etch resistant material between the diaphragm and backplate, thus supporting the diaphragm during a wet etch step. Various embodiments eliminate patterning steps by ensuring that the liquid etch material is added and removed in relatively few steps (e.g., one or two steps for adding, and a single step for removing—no specialized patterning processes for the wet etch resistant material are necessary). Details of illustrative embodiments are discussed below.



FIG. 1A schematically shows a top, perspective view of a microphone 10 (also referred to as a “microphone chip 10”) that may be fabricated in accordance with illustrative embodiments of the invention. FIG. 1B schematically shows a cross-section of the same microphone 10 across line B-B of FIG. 1A.


Among other things, the microphone 10 includes a static backplate 12 that supports and forms a capacitor with a flexible diaphragm 14. In illustrative embodiments, the backplate 12 is formed from single crystal silicon (e.g., the top layer of a silicon-on-insulator wafer), while the diaphragm 14 is formed from deposited polysilicon. Other embodiments, however, use other types of materials to form the backplate 12 and the diaphragm 14. For example, a single crystal silicon bulk wafer, or some deposited material may form the backplate 12. In a similar manner, a single crystal silicon bulk wafer, part of an silicon-on-insulator wafer, or some other deposited material may form the diaphragm 14. To facilitate operation, the backplate 12 has a plurality of through-holes 16 that lead to a backside cavity 18.


Springs 19 movably connect the diaphragm 14 to the static portion of the microphone 10, which includes the substrate. Audio signals cause the diaphragm 14 to vibrate, thus producing a changing capacitance. On-chip or off-chip circuitry (not shown) receive (via contacts 15) and convert this changing capacitance into electrical signals that can be further processed. It should be noted that discussion of the specific microphone 10 shown in FIGS. 1A and 1B is for illustrative purposes only. Other microphone configurations thus may be used with illustrative embodiments of the invention.



FIGS. 2A and 2B show a process of forming the microphone 10 shown in FIGS. 1A and 1B in accordance with illustrative embodiments of the invention. The remaining figures illustrate various steps of this process. It should be noted that this process does not describe all steps required for forming the microphone 10. Instead, it shows various relevant steps for forming the microphone 10. Accordingly, some steps are not discussed.


The process begins at step 200, which etches trenches 20 in the top layer of a silicon-on-insulator wafer (“SOI wafer”). FIG. 3A schematically shows an intermediate apparatus 22 illustrating this step, as well as steps 202-208. Next, the process adds sacrificial oxide 24 to the walls of the trenches 20 and along at least a portion of the top surface of the top layer of the SOI wafer (step 202). Among other ways, this oxide 24 may be grown or deposited. Step 202 continues by adding sacrificial polysilicon 26 to the oxide lined trenches 20 and top-side oxide 24.


After adding the sacrificial polysilicon 26, the process etches a hole 28 into the sacrificial polysilicon 26 (step 204). The process then continues to step 206, which adds more oxide 24 to substantially encapsulate the sacrificial polysilicon 26. In a manner similar to other steps that add oxide 24, this oxide 24 essentially integrates with other oxides in which it comes into contact. Step 206 continues by adding an additional polysilicon layer that ultimately forms the diaphragm 14.


Nitride 30 for passivation and metal 32 for electrical connectivity also are added. For example, deposited metal may be patterned to form a first electrode for placing electrical charge on the diaphragm 14, another electrode for placing electrical charge on the backplate 12, and bond pads 15 for providing additional electrical connections. There may be electrical connections (not shown) between bond pads and the electrodes.


The process then both exposes the diaphragm 14, and etches holes 34 through the diaphragm 14 (step 208). As discussed below in greater detail, one of these holes (“diaphragm hole 34A”) ultimately assists in forming a pedestal 42 that, for a limited time during this process, supports the diaphragm 14. A photoresist layer 36 then is added, completely covering the diaphragm 14 (step 210). This photoresist layer 36 serves the function of an etch mask.


After adding the photoresist 36, the process exposes the diaphragm hole 34A (step 212, FIG. 3B). To that end, the process forms a hole (“resist hole 38”) through the photoresist 36 by exposing that selected portion to light. This resist hole 38 illustratively has a larger inner diameter than that of the diaphragm hole 34A.


After forming the resist hole 38, the process forms a hole 40 through the oxide 24 (step 214, FIG. 3B). In illustrative embodiments, this oxide hole 40 effectively forms an internal channel that extends to the top surface of the upper SOI wafer.


It is expected that the oxide hole 40 first will have an inner diameter that is substantially equal to the inner diameter of the diaphragm hole 34A. A second step, such as an aqueous HF etch, may be used to enlarge the inner diameter of the oxide hole 40 to be greater than the inner diameter of the diaphragm hole 34A. This enlarged oxide hole diameter essentially exposes a portion of the bottom side of the diaphragm 14. In other words, at this point in the process, the channel forms an air space between the bottom side of the diaphragm 14 and the top surface of the backplate 12.


Also at this point in the process, the entire photoresist layer 36 may be removed to permit further processing. For example, the process may pattern the diaphragm 14, thus necessitating removal of the existing photoresist layer 36 (i.e., the mask formed by the photoresist layer 36). Other embodiments, however, do not remove this photoresist layer 36 until step 222 (discussed below).


The process then continues to step 216, which adds more photoresist 36, to substantially fill the oxide and diaphragm holes 40 and 34 (FIG. 3C). The photoresist 36 filling the oxide hole 40 contacts the silicon of the top SOI layer, as well as the underside of the diaphragm 14 around the diaphragm hole 34A.


The embodiment that does not remove the original mask thus applies a sufficient amount of photoresist 36 in two steps (i.e., first the mask, then the additional resist to substantially fill the oxide hole 40), while the embodiment that removes the original mask applies a sufficient amount of photoresist 36 in a single step. In both embodiments, as shown in FIG. 3C, the photoresist 36 essentially acts as the single, substantially contiguous apparatus above and below the diaphragm 14. Neither embodiment patterns the photoresist 36 before the sacrificial layer is etched (i.e., removal of the sacrificial oxide 24 and polysilicon 26, discussed below).


In addition, the process may form the backside cavity 18 at this time. To that end, as shown in FIG. 3C, conventional processes may apply another photoresist mask on the bottom side of the SOI wafer to etch away a portion of the bottom SOI silicon layer. This should expose a portion of the oxide layer within the SOI wafer. A portion of the exposed oxide layer then is removed to expose the remainder of the sacrificial materials, including the sacrificial polysilicon 26.


At this point, the sacrificial materials may be removed. To that end, the process removes the sacrificial polysilicon 26 (step 218, FIG. 3D) and then the sacrificial oxide 24 (step 220, FIG. 3E). Among other ways, illustrative embodiments remove the polysilicon 26 with a dry etch process (e.g., using xenon difluoride) through the backside cavity 18. In addition, illustrative embodiments remove the oxide 24 with a wet etch process (e.g., by placing the apparatus in an acid bath for a predetermined amount of time). Some embodiments, however, do not remove all of the sacrificial material. For example, such embodiments may not remove portions of the oxide 24. In that case, the oxide 24 may impact capacitance.


As shown in FIG. 3E, the photoresist 36 between the diaphragm 14 and top SOI layer supports the diaphragm 14. In other words, the photoresist 36 at that location forms a pedestal 42 that supports the diaphragm 14. As known by those skilled in the art, the photoresist 36 is substantially resistant to wet etch processes (e.g., aqueous HF process, such as those discussed above). It nevertheless should be noted that other wet etch resistant materials may be used. Discussion of photoresist 36 thus is illustrative and not intended to limit the scope of all embodiments.


Stated another way, a portion of the photoresist 36 is within an air space between the diaphragm 14 and the backplate 12; namely, it interrupts or otherwise forms a part of the boundary of the air space. In addition, as shown in the figures, this photoresist 36 extends as a substantially contiguous apparatus through the hole 34 in the diaphragm 14 and on the top surface of the diaphragm 14. It is not patterned before removing at least a portion of the sacrificial layers. No patterning steps are required to effectively fabricate the microphone 10.


To release the diaphragm 14, the process continues to step 222, which removes the photoresist 36/pedestal 42 in a single step. Among other ways, dry etch processes through the backside cavity 18 may be used to accomplish this step. This step illustratively removes substantially all of the photoresist 36—not simply selected portions of the photoresist 36.


It should be noted that a plurality of pedestals 42 may be used to minimize the risk of stiction between the backplate 12 and the diaphragm 14. The number of pedestals used is a function of a number of factors, including the type of wet etch resistant material used, the size and shape of the pedestals 42, and the size, shape, and composition of the diaphragm 14. Discussion of a single pedestal 42 therefore is for illustrative purposes.


It also should be noted that various embodiments of the present invention is not limited to any particular shape, material, or configuration of the microphone 10 or diaphragm 14. The microphone 10 may be, for example, round or square, solid or perforated by one or more holes, and/or flat or corrugated. Different diaphragm configurations might require different or additional processes from those described. For example, additional processes may be required to form holes or corrugations in the diaphragm 14.


Accordingly, stiction issues relating to surface tension of liquids should be mitigated because sacrificial layer removal processes using liquids are completed before the pedestal 42 is removed. Moreover, removing the sacrificial material through the backside cavity 18 favorably impacts microphone 10 performance by not requiring etch holes though the diaphragm 14 (to permit communication of the etching material). Specifically, as known by those in the art, it is preferable to have a diaphragm 14 with a large area to provide a stronger, more robust capacitive signal. Etching holes in the diaphragm 14 undesirably reduces the effective diaphragm area, thus reducing the effective signal. In addition, use of the backside cavity 18 eliminates the need to pattern the photoresist 36 used to support the diaphragm 14, consequently simplifying the fabrication process.


Although the above discussion discloses various exemplary embodiments of the invention, it should be apparent that those skilled in the art can make various modifications that will achieve some of the advantages of the invention without departing from the true scope of the invention.

Claims
  • 1. A method of forming a microphone, the method comprising: forming a backplate by etching at least one trench into a substrate, and filling at least one trench with at first sacrificial material and a second sacrificial material;depositing a wet etch removable sacrificial material on the first sacrificial material and the second sacrificial material;forming a flexible diaphragm on at least a portion of a wet etch removable sacrificial material;adding a wet etch resistant material, a portion of the wet etch resistant material being positioned between the diaphragm and the backplate to support the diaphragm;removing the first and second sacrificial material and the wet etch removable sacrificial material before removing any of the wet etch resistant material added by the act of adding; andremoving the added wet etch resistant material after removing at least part of the sacrificial material.
  • 2. The method as defined by claim 1 further comprising releasing the diaphragm, releasing comprising removing the first and second sacrificial material and the wet etch removable sacrificial material and removing the wet etch resistant material.
  • 3. The method as defined by claim 1 wherein the wet etch resistant material comprises a photoresist material.
  • 4. The method as defined by claim 1 further comprising: forming a hole through the diaphragm;forming a channel through the first and second sacrificial material and the wet etch removable sacrificial material, the channel being in fluid communication with the hole through the diaphragm; andthe wet etch resistant material substantially filling the channel while the sacrificial material is removed.
  • 5. The method as defined by claim 1 wherein adding includes adding a contiguous apparatus of wet etch resistant material, substantially all of the contiguous apparatus being removed by the act of removing the added wet etch resistant material.
  • 6. The method as defined by claim 1 wherein the wet etch resistant material is unpatterned after the portion of wet etch resistant material is positioned between the diaphragm and the backplate.
  • 7. The method as defined by claim 1 wherein the backplate is part of a silicon-on-insulator wafer.
  • 8. The method as defined by claim 1 wherein the wet etch removable sacrificial material comprises oxide.
  • 9. The method as defined by claim 1 further comprising: forming a first hole through the diaphragm;forming a second hole through the first and second sacrificial material and the wet etch removable sacrificial material, the second hole producing a channel between a bottom surface of the diaphragm and a top surface of the backplate, the portion of wet etch resistant material substantially filling the channel.
  • 10. The method according to claim 1 wherein forming a backplate comprises: filling at least one trench with a sacrificial material comprising sacrificial oxide.
  • 11. The method according to claim 1 wherein forming a backplate comprises: filling at least one trench with a sacrificial material comprising sacrificial polysilicon.
  • 12. A method of forming a MEMS microphone, the method comprising: providing a diaphragm layer on a sacrificial layer, the sacrificial layer being between the diaphragm layer and a substrate;forming a pedestal of wet etch resistant material between the substrate and the diaphragm;forming a backside cavity;applying a wet etch material to the sacrificial material through the backside cavity to remove at least a portion of the sacrificial layer, at least a portion of the wet etch resistant material supporting the diaphragm layer after applying the wet etch material; andremoving substantially all of the wet etch resistant material after removing at least a portion of the sacrificial material to release the diaphragm layer.
  • 13. The method as defined by claim 12 wherein the diaphragm layer, sacrificial layer and substrate are respective layers of a single SOI wafer.
  • 14. The method as defined by claim 12 wherein providing comprises depositing a material on the sacrificial layer to form the diaphragm.
  • 15. The method as defined by claim 12 wherein the wet etch resistant material is substantially unpatterned before applying the wet etch material to the sacrificial material.
  • 16. The method according to claim 1 wherein the first sacrificial material comprises sacrificial oxide and the second sacrificial material comprises sacrificial polysilicon.
PRIORITY

This patent application claims priority from provisional U.S. patent application No. 60/754,984, filed Dec. 29, 2005, entitled, “PROCESS OF FORMING A MICROPHONE USING SUPPORT MEMBER,” and naming Jason Weigold as inventor, the disclosure of which is incorporated herein, in its entirety, by reference, and is a continuation of U.S. patent application Ser. No. 11/613,003, filed Dec. 19, 2006, entitled, “PROCESS OF FORMING A MICROPHONE USING SUPPORT MEMBER,” and naming Jason Weigold as inventor, the disclosure of which is incorporated herein, in its entirety, by reference. This patent application also is a continuation-in-part and claims priority from U.S. patent application Ser. No. 11/113,925, filed Apr. 25, 2005, entitled, “MICROMACHINED MICROPHONE AND MULTISENSOR AND METHOD FOR PRODUCING SAME,” and naming John R. Martin, Timothy J. Brosnihan, Craig Core, Thomas Kieran Nunan, Jason Weigold, and Zin Zhang as inventors, the disclosure of which is incorporated herein, in its entirety, by reference.

US Referenced Citations (100)
Number Name Date Kind
4492825 Brzezinski et al. Jan 1985 A
4524247 Lindenberger et al. Jun 1985 A
4533795 Baumhauer, Jr. et al. Aug 1985 A
4558184 Busch-Vishniac et al. Dec 1985 A
4744863 Guckel et al. May 1988 A
4776019 Miyatake Oct 1988 A
4825335 Wilner Apr 1989 A
4853669 Guckel et al. Aug 1989 A
4996082 Guckel et al. Feb 1991 A
5090254 Guckel et al. Feb 1992 A
5113466 Acarlar et al. May 1992 A
5134572 Takasaki et al. Jul 1992 A
5146435 Bernstein Sep 1992 A
5178015 Loeppert et al. Jan 1993 A
5188983 Guckel et al. Feb 1993 A
5258097 Mastrangelo Nov 1993 A
5303210 Bernstein Apr 1994 A
5314572 Core et al. May 1994 A
5317107 Osorio May 1994 A
5452268 Bernstein Sep 1995 A
5490220 Loeppert Feb 1996 A
5573679 Mitchell et al. Nov 1996 A
5593926 Fujihira Jan 1997 A
5596222 Bernstein Jan 1997 A
5632854 Mirza et al. May 1997 A
5633552 Lee et al. May 1997 A
5658710 Neukermans Aug 1997 A
5684324 Bernstein Nov 1997 A
5692060 Wickstrom Nov 1997 A
5740261 Loeppert et al. Apr 1998 A
5817539 Werner Oct 1998 A
5870482 Loeppert et al. Feb 1999 A
5888845 Bashir et al. Mar 1999 A
5923995 Kao et al. Jul 1999 A
5939633 Judy Aug 1999 A
5956292 Bernstein Sep 1999 A
5960093 Miller Sep 1999 A
6012335 Bashir et al. Jan 2000 A
6128961 Haronian Oct 2000 A
6140689 Scheiter et al. Oct 2000 A
6243474 Tai et al. Jun 2001 B1
6249075 Bishop et al. Jun 2001 B1
6324907 Halteren et al. Dec 2001 B1
6426239 Gogoi et al. Jul 2002 B1
6505511 Geen et al. Jan 2003 B1
6522762 Mullenborn et al. Feb 2003 B1
6535460 Loeppert et al. Mar 2003 B2
6535663 Chertkow Mar 2003 B1
6552469 Pederson et al. Apr 2003 B1
6667189 Wang et al. Dec 2003 B1
6677176 Wong et al. Jan 2004 B2
6704427 Kearey Mar 2004 B2
6732588 Mullenborn et al. May 2004 B1
6741709 Kay et al. May 2004 B2
6743654 Coffa et al. Jun 2004 B2
6753583 Stoffel et al. Jun 2004 B2
6781231 Minervini Aug 2004 B2
6812620 Scheeper et al. Nov 2004 B2
6816301 Schiller Nov 2004 B1
6829131 Loeb et al. Dec 2004 B1
6847090 Loeppert Jan 2005 B2
6857312 Choe et al. Feb 2005 B2
6859542 Johannsen et al. Feb 2005 B2
6870937 Hirosaki et al. Mar 2005 B1
6883903 Truninger et al. Apr 2005 B2
6912759 Izadnegahdar et al. Jul 2005 B2
6914992 van Halteren et al. Jul 2005 B1
7023066 Lee et al. Apr 2006 B2
7138694 Nunan et al. Nov 2006 B2
7142682 Müllenborn et al. Nov 2006 B2
7148077 Fuertsch et al. Dec 2006 B2
7166910 Minervini Jan 2007 B2
7280436 Pedersen Oct 2007 B2
20020079550 Daneman et al. Jun 2002 A1
20020102004 Minervini Aug 2002 A1
20020181725 Johannsen et al. Dec 2002 A1
20030016839 Loeppert et al. Jan 2003 A1
20030133588 Pedersen Jul 2003 A1
20040046245 Minervini Mar 2004 A1
20040155942 Anagnostopoulos et al. Aug 2004 A1
20040179705 Wang et al. Sep 2004 A1
20040184632 Minervini Sep 2004 A1
20040184633 Kay et al. Sep 2004 A1
20050005421 Wang et al. Jan 2005 A1
20050018864 Minervini Jan 2005 A1
20050089188 Feng Apr 2005 A1
20050098840 Fuertsch et al. May 2005 A1
20050102721 Barth May 2005 A1
20050185812 Minervini Aug 2005 A1
20050204557 Anagnostopoulos et al. Sep 2005 A1
20060093170 Zhe et al. May 2006 A1
20060093171 Zhe et al. May 2006 A1
20060116180 Minervini Jun 2006 A1
20060157841 Minervini Jul 2006 A1
20060223291 Chen et al. Oct 2006 A1
20060233400 Ohbayashi et al. Oct 2006 A1
20060280319 Wang et al. Dec 2006 A1
20070047744 Harney et al. Mar 2007 A1
20070057602 Song Mar 2007 A1
20070058826 Sawamoto et al. Mar 2007 A1
Foreign Referenced Citations (21)
Number Date Country
196 48 424 Jun 1998 DE
10 2004 011 148 Nov 2005 DE
0596456 May 1994 EP
0 783 107 Jul 1997 EP
08240609 Sep 1996 JP
2002-223499 Aug 2002 JP
2005-331281 Dec 2005 JP
WO 8301362 Apr 1983 WO
WO 0120948 Mar 2001 WO
WO 0141497 Jun 2001 WO
WO 0215636 Feb 2002 WO
WO 0245463 Jun 2002 WO
WO 02052893 Jul 2002 WO
WO 03045110 May 2003 WO
WO 2005036698 Apr 2005 WO
WO 2005086532 Sep 2005 WO
WO 2005111555 Nov 2005 WO
WO 2005111555 Dec 2005 WO
WO 2006116017 Nov 2006 WO
WO 2007010361 Jan 2007 WO
WO 2007029878 Mar 2007 WO
Related Publications (1)
Number Date Country
20090029501 A1 Jan 2009 US
Provisional Applications (1)
Number Date Country
60754984 Dec 2005 US
Continuations (1)
Number Date Country
Parent 11613003 Dec 2006 US
Child 12244840 US
Continuation in Parts (1)
Number Date Country
Parent 11113925 Apr 2005 US
Child 11613003 US