Radiation shielding for a substrate holder

Information

  • Patent Grant
  • 9167625
  • Patent Number
    9,167,625
  • Date Filed
    Wednesday, November 14, 2012
    12 years ago
  • Date Issued
    Tuesday, October 20, 2015
    9 years ago
Abstract
A reaction chamber including a substrate supporting member positioned within the reaction chamber, the reaction chamber having a first region and a second region, a shield positioned within the second chamber and movable with the substrate supporting member, and wherein the shield is adjacent at least a bottom surface of the substrate supporting member.
Description
BACKGROUND

It can be difficult to heat a substrate being processed in a substrate processing tool. Variation in substrate heating may lead to within-substrate temperature variations. Such within-substrate temperature variations may lead to within-substrate processing non-uniformities. In some settings, substrates exhibiting such non-uniformities may produce defective devices. Further, deposition product may be deposited in the lower processing chamber, leading to reduced temperatures in the reaction chamber and therefore increased power consumption to overcome the inadequate heating. Additionally, the build-up of deposition product in the chamber can lead to premature chamber cleaning requirements and increased cost.


SUMMARY

Aspects of this document relate to reaction chambers for processing substrates. In one aspect, a reaction chamber includes a substrate supporting member positioned within the reaction chamber, the reaction chamber having a first region and a second region, a shield positioned within the second region and movable with the substrate supporting member, and wherein the shield is adjacent at least a bottom surface of the substrate supporting member.


In an implementation, the shield may be adjacent a sidewall of the substrate supporting member. The first region may be a substrate processing region and the second region may be a substrate loading region. The first region may be positioned above the second region in the reaction chamber. The reaction chamber may further include an isolation device at least partially separating the first and second regions. The reaction chamber may further include a gap formed between the shield and the isolation device. The gap may be between 5 and 10 mm. The shield may be spaced from the substrate supporting member between 5 and 20 mm.


The shield may further include a bottom member and a sidewall member. The bottom member and the sidewall member may connect to one another at an angle of approximately 90 degrees. The bottom member and the sidewall member may connect to one another at an angle between approximately 25 and 65 degrees. The shield may be secured to a shaft of the substrate supporting member. The shield may retain heat generated by the substrate support assembly. The substrate support assembly may further include a heater.


In another aspect, a shield for processing a substrate may include a bottom member having an aperture to surround a substrate support member shaft, a sidewall member extending upward at an angle from the bottom member, wherein the bottom member is positioned below the substrate support member and the sidewall member is positioned around the substrate support member, and wherein the shield moves vertically with the substrate support member.


In an implementation, the shield may be spaced from the substrate supporting member between 5 and 20 mm. The shield sidewall member may avoid contact with a reaction chamber wall. The sidewall may further include a top surface spaced from a reaction chamber surface between approximately 5 and 10 mm.


In another aspect, a reaction chamber may include a first region, a second region, and a third region, the first region positioned above the second and third regions, and adapted for processing a substrate, the second region positioned below the first region and adapted for loading the substrate in the reaction chamber, the third region positioned between the first region and the second region, and wherein the third region is movable within the second region.


In an implementation, the reaction chamber may further include a shield defining a barrier between the second region and the third region. The shield may be movable within the second region. A third region volume varies based on a position of the substrate support member.


In still another aspect, a method of heating a substrate in a processing region includes providing a shield within the processing chamber below a substrate support member, loading a substrate in a processing region of the processing chamber, activating a heater, and radiating heat from the shield to the substrate support member.


In an implementation, the method may further include the step of moving the substrate support member from a loading position to a processing position. The method may further include the step of monitoring the temperature of a cavity between the substrate support member and the shield.


Aspects and implementations of the disclosure presented here are described below in the drawings and detailed description. Unless specifically noted, it is intended that the words and phrases in the specification and the claims be given their plain, ordinary, and accustomed meaning to those of ordinary skill in the applicable arts. The inventors are fully aware that they can be their own lexicographers if desired. The inventors expressly elect, as their own lexicographers, to use only the plain and ordinary meaning of terms in the specification and claims unless they clearly state otherwise and then further, expressly set forth the “special” definition of that term and explain how it differs from the plain and ordinary meaning. Absent such clear statements of intent to apply a “special” definition, it is the inventors' intent and desire that the simple, plain and ordinary meaning of the terms be applied to the interpretation of the specification and claims.


The inventors are also aware of the normal precepts of English grammar Thus, if a noun, term, or phrase is intended to be further characterized, specified, or narrowed in some way, then such noun, term, or phrase will expressly include additional adjectives, descriptive terms, or other modifiers in accordance with the normal precepts of English grammar Absent the use of such adjectives, descriptive terms, or modifiers, it is the intent that such nouns, terms, or phrases be given their plain, and ordinary English meaning to those skilled in the applicable arts as set forth above.


The foregoing and other aspects, features, and advantages will be apparent to those artisans of ordinary skill in the art from the DESCRIPTION and DRAWINGS, and from the CLAIMS.





BRIEF DESCRIPTION OF THE DRAWINGS

Embodiments of the present invention will hereinafter be described in conjunction with the appended drawings, where like designations denote like elements, and:



FIG. 1 schematically shows a substrate processing chamber including a radiation shield according to an embodiment of the present disclosure in the substrate loading position.



FIG. 2 schematically shows a substrate processing chamber including a radiation shield according to an embodiment of the present disclosure in the substrate processing position.



FIG. 3 schematically shows a bottom perspective view of a portion of the radiation shield illustrated in FIG. 1.



FIG. 4 schematically shows a perspective exploded view of the radiation shield illustrated in FIG. 1.



FIG. 5 schematically shows a sectional view of the area labeled FIG. 5 in FIG. 2.



FIG. 6 schematically shows a sectional view of the area labeled FIG. 6 in FIG. 5.



FIG. 7 schematically shows a sectional view of the area labeled FIG. 5 in FIG. 2 and the removal of the radiation shield.



FIG. 8 shows example temperature data for a susceptor heater assembly without a radiation shield.



FIG. 9 shows example temperature data for a susceptor heater assembly with a radiation shield of the present disclosure.



FIG. 10 shows example temperature data for a wafer substrate without a radiation shield.



FIG. 11 shows example temperature data for a wafer substrate with a radiation shield.



FIG. 12 schematically shows a sectional view of a second embodiment radiation shield of the present disclosure.



FIG. 13 shows a flow chart for a method of processing a substrate according to an embodiment of the present disclosure.





DETAILED DESCRIPTION

Some substrate processing tools may include environments that vary in the amount of incident radiation reflected therein. For example, various materials, surface finishes, surface coatings, and/or environmental geometries may affect an amount of thermal radiation reflected within a substrate processing tool, potentially causing a non-uniform temperature field to develop within a substrate being processed in the substrate processing tool.


For example, a substrate being supported by a susceptor heater assembly that is heated by one or more resistive heaters may lose heat via thermal radiation to a low pressure environment within a substrate processing tool. Such radiative losses may increase as the temperature of the susceptor heater assembly increases. Further, because the area between a susceptor heater assembly and the surrounding low pressure environment may be non-uniform in some settings, the radiation capture properties of the substrate processing tool environment may affect the radiation loss from the susceptor heater assembly. In turn, a substrate subjected to an uneven radiation capture environment may develop a non-uniform temperature profile within the substrate. As used herein, radiation capture refers to an object's or an environment's ability to capture thermal radiation. Because some substrate processing operations may depend on temperature, such non-uniform temperature profiles may lead to non-uniformities in the processed substrate. For example, a semiconductor substrate subjected to a film deposition process may exhibit a convex, concave, or skewed film thickness profile as a result of the non-uniform temperature that may produce defects and may lead to defective semiconductor devices.


Some previous approaches to reduce the effect of the surrounding radiation capture environment on within-substrate temperature fields have employed fixed radiation shields positioned within portions of processing tools. However, such fixed shields frequently have gaps to allow substrate transfer robots to move substrates within the tool, or that otherwise provide an incomplete and/or inconsistent radiation capture environment. In some other cases, such fixed shields may be irregularly formed so that there may be non-uniform view factors between the susceptor heater assembly and the fixed shield.


Accordingly, the disclosed embodiments relate to a radiation shield positioned to reflect thermal radiation (including one or more wavelengths of infrared radiation) and/or heat emitted from a susceptor heater assembly used for supporting and heating a substrate within a substrate processing chamber. For example, the disclosed embodiments provide a radiation shield supported by a structure used to move the susceptor heater assembly within a substrate processing chamber so that the radiation shield moves with the susceptor heater assembly as the susceptor heater assembly is moved from a first position to a second position within the substrate processing chamber. As another example, the disclosed embodiments provide a radiation shield coupled to a susceptor heater assembly where the radiation shield is configured to reflect thermal radiation and/or heat emitted by the susceptor heater assembly to at least two different sides of the susceptor heater assembly. By maintaining a predetermined radiation capture environment (in some embodiments, a uniform radiation capture environment), such radiation shields may enhance within-substrate temperature uniformity. In turn, within-substrate processing uniformity (e.g., deposition rate, etch rate, and so on) may be enhanced, potentially enhancing substrate deposited film quality provided by the substrate processing chamber and/or at downstream processing operations. Further, in some examples, increasing an amount of thermal radiation and/or heat reflected to the susceptor heater assembly may reduce power consumed by a heater included in the susceptor heater assembly. Consequently, in some embodiments, enhanced heater control and/or lifetime may be realized. In addition, a reduction in chamber cleaning frequency may also be obtained.



FIG. 1 schematically shows a cross-section of an embodiment of a substrate processing chamber 100 for processing semiconductor substrates in a substrate loading/unloading position. In some embodiments, substrate processing chamber 100 may be included in a suitable substrate processing tool. Substrate processing chamber 100 may be used for processing semiconductor substrates via any suitable process, e.g., film deposition, film etch, and the like. While the embodiment of substrate processing chamber 100 depicted in FIG. 1 shows a single chamber, it will be appreciated that any suitable number of process chambers may be included in a processing tool so that substrates may be transferred between process chambers without being exposed to ambient conditions. For example, some processing tools may include just one chamber while other processing tools may include two or more chambers. In these examples, each reaction chamber may include only a single region or a plurality of regions. While not shown in FIG. 1, various load locks, load ports, and substrate transfer handling robots may be used to transfer substrates between ambient conditions and substrate processing chamber 100 before, during, and after substrate processing.


As shown in FIGS. 1 and 2, substrate processing chamber 100 includes an upper reactor 102 within which a reaction zone or processing region 103 is formed where substrate processing occurs. Substrate processing chamber 100 also includes a lower reactor 104 with a substrate loading region 105 where substrate transfer operations are performed. FIG. 1 also shows a movable pedestal 106 used to support a substrate within substrate processing chamber 100. The embodiment shown in FIG. 1 depicts pedestal 106 in a lowered position within lower reactor 104. In some settings, pedestal 106 may be placed in a lowered position as a part of transferring a substrate 107 in or out of substrate processing chamber 100.


In the embodiment shown in FIG. 1, lower reactor 104 includes a substrate transfer opening 108 through which substrates are transferred in and out of substrate processing chamber 100. In some embodiments, a gate valve (not shown) may be coupled to substrate transfer opening 108 so that substrate processing chamber 100 may be isolated from other portions of a semiconductor processing tool and/or so that substrate processing chamber 100 may be pumped down to a pressure below an ambient pressure (e.g., to a low pressure state).


In the example shown in FIG. 1, pedestal 106 comprises a susceptor heater assembly 110 for supporting a substrate within substrate processing chamber 100. Susceptor heater assembly 110 includes a heater assembly 112 used to adjust a temperature of the substrate before, during, and/or after substrate processing. In some embodiments, heater assembly 112 may include a resistive platen heater. In the embodiment shown in FIG. 1, heater assembly 112 includes a base 114 and a substrate supporting portion. In some embodiments, base 114 may include one or more channels configured to retain one or more resistive heating elements 116 may be positioned within base 114. In some other embodiments, heater assembly 112 may be a one-piece heater, multiple pieces fused/welded together, or a heater separable from a substrate support. Susceptor heater assembly 110 is mounted on an elevator 118 so that the substrate may be raised and lowered. In some embodiments, heater assembly 112 may be welded to elevator 118. Nevertheless, any suitable heating arrangements may be utilized within the reaction chamber.


Susceptor heater assembly 110 is depicted in FIG. 1 as including an optional substrate support surface 111 configured to support substrate 107. In some embodiments, substrate support surface 111 may be omitted, so that substrate 107 may be supported by a substrate pocket 117 formed into heater assembly 112. As shown in FIG. 1, substrate pocket 117 may be formed into an upper surface of substrate supporting surface of heater assembly 112 or alternatively in an upper surface of a substrate support or susceptor. In some other embodiments where heater assembly 112 includes a one-piece heater, a substrate pocket may be formed into an upper surface of the one-piece heater, so that substrate 107 rests directly on the one-piece heater.



FIG. 1 also shows a radiation shield 120 coupled to susceptor heater assembly 110 via elevator 118. Radiation shield 120 is configured to reflect at least a portion of thermal radiation emitted from susceptor heater assembly 110 back toward susceptor heater assembly 110. In some embodiments, radiation shield 120 may be configured to reflect thermal radiation and/or heat emitted by susceptor heater assembly 110 to at least two different sides of susceptor heater assembly 110. For example, FIG. 1 shows radiation shield 120 adapted to reflect some of the thermal radiation and/or heat emitted from bottom surface 122 and side surface 124 of susceptor heater assembly 110 back to susceptor heater assembly 110. This potentially may reduce power consumption by heater assembly 112 and/or reduce within-substrate temperature non-uniformities that may result from an uneven radiation capture and/or reflection environment near susceptor heater assembly 110. Further, in some embodiments, radiation shield 120 may be configured so that surfaces of radiation shield 120 reflect thermal radiation and/or heat to at least two different sides of heater assembly 112. For example, in the embodiment shown in FIG. 1, radiation shield 120 is depicted as extending beyond heater assembly 112 so that thermal radiation and/or heat is reflected to side and/or bottom surfaces of heater assembly 112. While creating non-uniformity may be a goal, this same arrangement may be used to exaggerate a non-uniformity as may be desired during processing of a substrate.


In the embodiment shown in FIG. 1, radiation shield 120 is shaped and sized so that radiation shield 120 is separated from susceptor heater assembly 110 by a gap. Spacing radiation shield 120 and susceptor heater assembly 110 may help maintain an even radiation capture environment around susceptor heater assembly 110. It will be appreciated that a distance separating radiation shield 120 from susceptor heater assembly 110 may vary according to processing conditions (e.g., susceptor heater assembly temperatures, process pressures, etc.). For example, as pressure increases, thermal convection and/or conduction heat transfer processes may affect temperature fields within the substrate. A closer view of example spacing between radiation shield 120 and susceptor heater assembly 110 may be seen in FIG. 2, which schematically shows an embodiment of radiation shield 120 in a raised position within substrate processing chamber 100.


For example, a vertical gap 126a that defines a space between bottom surface 122 and radiation shield 120 and a horizontal gap 126b that defines a space between side surface 124 and radiation shield 120. In one implementation, vertical gap 126a is between 5 and 20 mm, preferably between 10 and 20 mm, while horizontal gap 126b is between 5 and 15 mm, preferably 7 and 12 mm. In one implementation, vertical gap 126a is approximately 17.25 mm, while horizontal gap 126b is approximately 9 mm. Nevertheless, shield 120 may be positioned any suitable distance from the bottom surface 122 and the side surface 124 without departing from the spirit and scope of the disclosure.


In some embodiments, such gaps may define a constant separation between radiation shield 120 and susceptor heater assembly 110 within an acceptable tolerance. Such constant separation may provide a uniform radiation capture and/or reflection environment for susceptor heater assembly 110, potentially resulting in uniform temperature profile within susceptor heater assembly 110 and/or substrate 107 supported thereon. For example, in a scenario where a circularly symmetric substrate is supported on a circularly symmetric substrate heater assembly, positioning a radiation shield to create a circularly symmetric radiation capture and/or reflection environment around the susceptor heater assembly may result in a circularly symmetric temperature profile within the substrate. In turn, a temperature of the substrate, measured at a fixed radial distance from a center of the substrate, may be independent of polar angle.


It will be appreciated that, in some embodiments, such separation between radiation shield 120 and susceptor heater assembly 120 may vary. For example, separation between susceptor heater assembly 110 and radiation shield 120 may vary locally to offset emissivity variations of susceptor heater assembly 110 and/or radiation shield 120 and/or to accommodate various fittings, sensors, and/or other hardware features. For example, FIG. 2 depicts a chamfered surface 128 formed into radiation shield 120, which may assist with clearance of various hardware fittings within lower reactor 104 as susceptor heater assembly 110 is raised and lowered. In some embodiments, a distance between chamfered surface 128 and susceptor heater assembly 110 may be less than a distance defining vertical gap 126a and/or horizontal gap 126b.



FIG. 2 also shows a space 202 formed between radiation shield 120 and upper reactor 102. In some embodiments, space 202 may be sized to provide a preselected thermal radiation reflectance from radiation shield 120 while also providing a predetermined gas flow conductance between upper reactor 102 and lower reactor 104 via space 202 when the pedestal is in a raised position, such as during substrate processing shown in FIG. 2. Thus, space 202 may be sized to provide a desired radiation capture and/or reflection environment for susceptor heater assembly 110 without sealing radiation shield 120 to upper reactor 102. This may provide differential pumping via space 202 among other portions of substrate processing chamber 100. In some embodiments, however, radiation shield 120 may be configured to fit snugly against upper reactor 102. In one non-limiting example, space 202 may be approximately 5 mm to 10 mm, and preferably 8.25 mm in one implementation. Specifically, an isolation device 206 may be positioned co-planar with an outer surface of shield 120. The outer surface of shield 120 may include a sidewall 208 and a bottom wall 210 which may be connected by a chamfered surface 128. The chamfered surface 128 may be positioned at an angle between approximately 25 and approximately 65 degrees, or as will described below, at an angle of approximately 90 degrees without a chambered surface.


Referring to FIG. 1, susceptor heater assembly 110 is shown in a first position with the susceptor heater assembly 110 in a lower position and lift pins extending above a top surface of the susceptor support surface 111. The lift pins are arranged to receive a substrate 107 on the lift pins. Moving to FIG. 2, the susceptor heater assembly 110 is moved upwards in the direction associated with arrows 204 until the susceptor support surface 111 is within the upper chamber 102 and forms at least a portion of a first region. A second region is formed by the inner surface of shield 120, while the third region is formed by the lower chamber 104. In this arrangement, the second region may be wholly contained within the third region, or only partially contained within the third region.


In some embodiments, radiation shield 120 may be supported by elevator 118 and retained by one or more retaining structures. In some embodiments, such retaining structures may include suitable clips. FIG. 3 schematically shows an embodiment of pedestal 106 in a raised position.



FIGS. 3 and 4 illustrate examples of the shield 120 and an attachment apparatus for securing the shield to the susceptor heater assembly 110. Specifically, shield 120 may include a central aperture 212 with a flat surface 214 arranged to assist with securing the shield to the elevator 118. Shield 120 may also include a plurality of holes 216 to permit the lift pins to pass there through. Susceptor heater assembly 110 may also include a raised portion 218 having a flat receiving portion facing shield 120. An alignment tab 220 may be located on elevator 118 above a grooved or teeth portion 222, which is in turn above a concave portion 224.


A spacer 226 is used to assist with alignment of the shield 120 and susceptor heater assembly 110. The spacer 226 may include a top surface 228 with concave surfaces 230 therein. The spacer 226 may include an opening 232 and an alignment protrusion 234 having a flat surface 236, both extending from a bottom surface 238 of the spacer. A groove 235 may be positioned radially inward of alignment protrusion 234 and arranged to receive release pins as will be discussed below. Finally, the spacer may also include an alignment aperture 240 for cooperation with alignment tab 220 of the elevator 118. Accordingly, the spacer 226 is aligned with elevator 118 at alignment aperture 240 and alignment tab 220, which is in turn aligned with alignment protrusion 234. Shield central aperture 212 and flat surface 214 are aligned with alignment protrusion 234 and flat 236 of spacer 226 to thereby orient the susceptor heater assembly 110, spacer 226, and shield 120 for proper operation.



FIGS. 3 and 4 illustrate a locking clip 242 having a plurality of engagement protrusions 244 extending generally inward and each having an engagement surface 246 together defining an interior perimeter which is slightly smaller than an outer surface of elevator 118 and specifically grooved portion 222. The locking clip 242 may also include a plurality of release tabs 248 extending outward from the outer perimeter of the locking clip. Each of the engagement protrusions 244 may include a mounting hole 245 for receiving release pins as will be discussed below in greater detail.


Radiation shield 120 may have any suitable shape. For example, in some embodiments where susceptor heater assembly 110 has a circular profile for supporting a circularly-shaped substrate, radiation shield 120 may be circularly-shaped so as to provide a uniform thermal radiation reflection and/or absorption environment. However, it will be appreciated that in some embodiments, radiation shield 120 may have other suitable shapes, such as polygonal shapes, as the shape of radiation shield 120 may be influenced by heat transfer considerations as well as geometric influences.


Radiation shield 120 may be formed from any suitable material. Non-limiting examples include aluminum, stainless steel, and titanium. Further, it will be appreciated that radiation shield 120 may be formed in any suitable manner. In some embodiments, radiation shield 120 may be formed by metal spinning Other suitable fabrication techniques include casting, stamping, and turning. In some embodiments, radiation shield 120 may include suitable surface treatments and/or surface finishes configured to alter one or more radiation reflectivity characteristics of the material from which it is formed. Such treatments and finishes may be configured to reflect thermal radiation locally (e.g., toward susceptor heater assembly 110, in some examples) or globally. For example, radiation shield 120 may include a highly polished surface adapted to reflect thermal radiation in some embodiments. Additionally or alternatively, in some embodiments, radiation shield 120 may include surface treatments configured to reflect one or more wavelengths of infrared radiation. Further, in some embodiments, radiation shield 120 may be assembled by any suitable technique. For example, in some embodiments, radiation shield sub-assemblies may be welded together or removably connected together.



FIGS. 5 through 7 illustrate various operational views of the installation and removal of the shield 120 and specifically the locking clip 242. As shown in FIG. 5, spacer 226 is moved in the direction associated with arrow 204 until the alignment tab 220 and alignment aperture 240 are engaged, such that spacer 226 is arranged to receive shield 120 moved upwards in the direction associated with arrow 204 until the shield central aperture 212 and flat surface 214 are aligned with and in contact with spacer bottom surface 238. Next, locking clip 242 is also moved upwards along elevator 118, with engagement protrusions 244 bent downwards as the locking clip is moved upwards. Specifically, since the engagement surfaces 246 of the engagement protrusions 244 define an interior perimeter that is smaller in diameter than elevator 118 outer perimeter, there is a frictional engagement between elevator 118 and engagement protrusions 244, which requires that the engagement protrusions 244 are essentially pulled upwards by the vertical movement of the locking clip 242. When the locking clip engagement protrusions 244 and engagement surfaces 246 contact grooved portion 222, the engagement protrusions 244 fit within grooved portion 222 and only permit movement upwards in the direction associated with arrow 204, thereby preventing unlocking or separation of the locking clip, shield, and spacer from the susceptor heater assembly 110.


Referring now to FIG. 6, which is an enlarged sectional view of the section labeled FIG-6 in FIG. 5. As can be seen in greater detail, release tabs 248 are spaced apart by a gap 250 formed between the release tabs and the shield 120. A mounting surface 252 is located on a top side of locking clip 242 and contacts bottom wall 210 of shield 120 to secure the shield to the spacer and ultimately the susceptor heater assembly 110. The locking clip 242 may also include a spacing wall 254 which provides the gap 250 between release tabs 248 and the bottom wall 210 of shield 120. Advantageously, the gap 250 permits removal of the locking clip 242, the shield 120, and the spacer 226 by allowing a user to locate his/her fingers or a tool in gap 250 as will be discussed in greater detail below.



FIG. 7 illustrates the removal of locking clip 242, the shield 120, and the spacer 226 being removed with a removal tool 260 generally includes release pins 262 having a first end 262a and a second end 262b, with second end 262b removably positionable within mounting holes 245 to bias engagement protrusions 244 in the direction associated with arrows 306. Specifically, Second end 262b includes a recessed area 264 which is arranged to fit within mounting holes 245 and may extending into groove 235 as may be necessary. The removal tool also includes a clamping member 270 having a flange 272 with threaded holes 274 therein, a plurality of spacing members 276 with gripping arms 278 connected to spacing member 276 and opposite flange 272. Gripping arms 278 are preferably sized and shaped to fit within gap 250 between shield 120 and release tabs 248. In one implementation, clamping member 270 is arranged to be moved upwards in the direction associated with arrows 302 around the release tabs 248 and then rotated to be in contact with the release tabs and positioned in gap 250. The removal tool 260 also includes a washer 280 having a plurality of threaded apertures 282 for receiving bolts 290 and an aperture 284 so that the washer can travel around elevator shaft 118.


Having described all of the removal tool 260 components, the operation will now be described. Release pins 262 are positioned within mounting holes 245 with recessed area 264 positioned within groove 235 if necessary. Next, clamping mechanism is positioned so that gripping arms 278 are within gaps 250 between release tabs 248 and shield 120. The washer 280 is then placed in contact with pins 260 and particularly first end 262a of the release pins. Bolts 290 are then secured through threaded apertures 272 and 282 steadily around the perimeter of the washer so that washer 280 is pulled upwards in the direction associated with arrows 302 by rotational movement of bolts 290 to displace the bolts in the direction associated with arrows 300. The upward movement of washer 280 creates a rotational movement of release pins 262 and imparts rotational movement in the direction associated with arrows 304. The rotational movement in the direction associated with arrows 304 imparts a bending force on engagement protrusions 244 in the direction associated with arrows 306. Accordingly, the bending force 306 imparted on the engagement protrusions increases the interior perimeter 246 to a point that locking clip 242 can be moved in the direction associated with arrow 308 and removed from elevator 118. In the same manner, shield 120 may also then be removed with or without spacer 226. While the above description uses certain orders of operation and directions (upward or downward), any suitable order of operations may be utilized and the directions may be reversed if the removal operation is performed with susceptor assembly 110 on a bench and upside down with elevator 118 pointing upwards. Further, the installation process may require a similar operation and merely be performed in reverse order. It should also be noted and appreciated that a number of other shield attachment means may be utilized without departing from the spirit and scope of the disclosure so long as the shield is connected to the elevator or other suitable reactor components.


In some settings, embodiments of radiation shields like those disclosed herein potentially may reduce power consumed by a heater included in a susceptor or even with the susceptor separated from the heater. For example, FIGS. 8 and 9 show example temperature data for an unshielded susceptor heater assembly (shown as data 702) compared to temperature data for a susceptor heater assembly employing a radiation shield according to an embodiment of the present disclosure (shown as data 704). In the examples shown in FIGS. 8 and 9, the heater power is adjusted to control the temperature of the susceptor (shown as susceptor temperature setting 706 in FIG. 8) to a preselected value of 420° C. for example. Accordingly, heat lost from the susceptor heater assembly may cause the power consumed by the heater, and thus the heater temperature, to necessarily increase. The example temperature data shown in FIGS. 8 and 9 was collected in a reactor controlled to various pressure setpoints (shown as reactor pressure setting 708 in FIG. 8) between 1.5 and 5 Torr. As shown in FIG. 9, heater temperature 710 corresponding to the unshielded susceptor heater assembly was approximately 15° C. higher at 2 Torr and approximately 22° C. higher at 5 Torr relative to the heater temperature exhibited by the shielded susceptor heater assembly, as shown in heater temperature 712. Accordingly, it will be appreciated that radiation shielding according to the disclosed embodiments may reduce heater power consumption, which may increase heater service life, or to increase the ultimate substrate temperature for the same heater temperature since more heat from the heater is directed into the susceptor heater assembly and substrate.


Further, in some settings, embodiments of radiation shields like those disclosed herein potentially may enhance within-substrate temperature uniformity. For example, FIGS. 10 and 11 show example substrate temperature uniformity data for an unshielded susceptor heater assembly (shown as data 802) compared to substrate temperature uniformity data for a susceptor heater assembly employing a radiation shield according to an embodiment of the present disclosure (shown as data 804). In the examples shown in FIG. 10, the heater power is adjusted to control the temperature of the susceptor to a preselected value of 420° C. while the reactor was controlled to various pressure setpoints between 1.5 and 5 Torr. As shown in FIG. 10, a mean substrate temperature 806 corresponding to the unshielded susceptor heater assembly was approximately 1° C. higher than a mean temperature 808 corresponding to the shielded susceptor heater assembly. Further, a substrate temperature range 810 corresponding to the unshielded susceptor heater assembly was approximately 1° C. higher than a substrate temperature range 812 corresponding to the shielded susceptor heater assembly. Accordingly, shielding the susceptor heater assembly may, in some examples, decrease within-substrate temperature non-uniformities. This potentially may enhance substrate processing quality, and may enhance downstream substrate processing quality as well. Appendix A also shows embodiments of radiation shields according to the present disclosure and temperature data related thereto.



FIG. 12 illustrates another embodiment of a substrate support assembly 400 with a pedestal heater 402 and a separable susceptor 404 with a wafer 406 positioned on the susceptor. A shield 408 functions similar to shield 120 and includes a sidewall 410 and a bottom wall 412 positioned at approximately 90 degrees to one another. Shield 408 may be secured to a pedestal heater shaft 414 with a clip 416 selectively positioned in a recess 418 of the heater shaft. Accordingly, the arrangement, operation, and installation/removal of shields 120 and 408 are similar to one another and provide similar benefits of increased heater control, wafer heat distribution control, reduced power consumption, and less frequent chamber cleaning requirements.


It will be understood that the hardware described herein may be used when processing substrates in a substrate processing chamber. FIG. 13 shows a flow chart for an embodiment of a method 1300 for processing a substrate in a substrate processing chamber. Method 1300 may be performed by any suitable hardware and software. It will be appreciated that portions of the processes described in method 1300 may be omitted, reordered, and/or supplemented without departing from the scope of the present disclosure.


At 1302, method 1300 includes supporting a substrate on a susceptor heater assembly. In some embodiments, method 1300 may include, at 1304, supporting a substrate on a susceptor heater assembly coupled to a radiation shield configured to reflect thermal radiation to at least two sides of the susceptor heater assembly. At 1306, method 1300 includes moving the susceptor heater assembly from a first position to a second position. In some embodiments, method 1300 may include, at 1308, moving the susceptor heater assembly so that a radiation shield moves with the susceptor heater assembly. At 1310, method 1300 includes processing the substrate. At 1312, method 1300 includes moving the susceptor heater assembly from the second position to the first position.


Embodiments of method 1300 may be performed by a system process controller comprising a data-holding subsystem comprising instructions executable by a logic subsystem to perform the processes described herein. Any suitable system process controller may be employed without departing from the scope of the present disclosure.


For example, a system process controller (not specifically shown) may be provided for controlling the example substrate processing chamber 100. The system process controller may operate process module control subsystems, such as gas control subsystems, pressure control subsystems, temperature control subsystems, electrical control subsystems, and mechanical control subsystems. Such control subsystems may receive various signals provided by sensors, relays, and controllers and make suitable adjustments in response.


The system process controller comprises a computing system that includes a data-holding subsystem and a logic subsystem. The data-holding subsystem may include one or more physical, non-transitory, devices configured to hold data and/or instructions executable by the logic subsystem to implement the methods and processes described herein. The logic subsystem may include one or more physical devices configured to execute one or more instructions stored in the data-holding subsystem. The logic subsystem may include one or more processors that are configured to execute software instructions.


In some embodiments, such instructions may control the execution of process recipes. Generally, a process recipe includes a sequential description of process parameters used to process a substrate, such parameters including time, temperature, pressure, and concentration, etc., as well as various parameters describing electrical, mechanical, and environmental aspects of the tool during substrate processing. The instructions may also control the execution of various maintenance recipes used during maintenance procedures and the like. In some embodiments, such instructions may be stored on removable computer-readable storage media, which may be used to store and/or transfer data and/or instructions executable to implement the methods and processes described herein. It will be appreciated that any suitable removable computer-readable storage media may be employed without departing from the scope of the present disclosure. Non-limiting examples include DVDs, CD-ROMs, floppy discs, and flash drives.


It is to be understood that the configurations and/or approaches described herein are exemplary in nature, and that these specific embodiments or examples are not to be considered in a limiting sense, because numerous variations are possible. The specific routines or methods described herein may represent one or more of any number of processing strategies. Thus, the various acts illustrated may be performed in the sequence illustrated, in other sequences, or omitted in some cases.


The subject matter of the present disclosure includes all novel and nonobvious combinations and subcombinations of the various processes, systems and configurations, and other features, functions, acts, and/or properties disclosed herein, as well as any and all equivalents thereof.

Claims
  • 1. A reaction chamber comprising: a substrate supporting member comprising a shaft and positioned within the reaction chamber;the reaction chamber having a first region and a second region;a shield positioned within the second region and movable with the substrate supporting member; and,a spacer to space apart the shield and the substrate support member and to space apart the shield and the shaft,wherein the shield is adjacent at least a bottom surface of the substrate supporting member.
  • 2. The reaction chamber of claim 1 wherein the shield is adjacent a sidewall of the substrate supporting member.
  • 3. The reaction chamber of claim 1 wherein the first region is a substrate processing region and the second region is a substrate loading region.
  • 4. The reaction chamber of claim 3 wherein the first region is positioned above the second region in the reaction chamber.
  • 5. The reaction chamber of claim 1 further comprising an isolation device at least partially separating the first and second regions.
  • 6. The reaction chamber of claim 5 further comprising a gap formed between the shield and the isolation device.
  • 7. The reaction chamber of claim 6 wherein the gap is between 5 and 10 mm.
  • 8. The reaction chamber of claim 1 wherein the shield is spaced from the substrate supporting member between 5 and 20 mm.
  • 9. The reaction chamber of claim 1 wherein the shield further comprises a bottom member and a sidewall member.
  • 10. The reaction chamber of claim 9 wherein the bottom member and the sidewall member connect to one another at an angle of approximately 90 degrees.
  • 11. The reaction chamber of claim 9 wherein the bottom member and the sidewall member connect to one another at an angle between approximately 25 and 65 degrees.
  • 12. The reaction chamber of claim 1 wherein the shield is secured to the shaft of the substrate supporting member.
  • 13. The reaction chamber of claim 1 wherein the shield retains heat generated by the substrate support assembly.
  • 14. The reaction chamber of claim 1 wherein the substrate support assembly further comprises a heater.
  • 15. A shield for processing a substrate comprising: a bottom member having an aperture to surround a substrate support member shaft;a sidewall member extending upward at an angle from the bottom member;wherein the bottom member is positioned below the substrate support member and the sidewall member is positioned around the substrate support member;wherein the bottom member comprises a central aperture comprising a flat surface to assist securing the shield to a shaft of the substrate support member, and,wherein the shield moves vertically with the substrate support member.
  • 16. The shield for processing a substrate of claim 15 wherein the shield is spaced from the substrate supporting member between 5 and 20 mm.
  • 17. The shield for processing a substrate of claim 15 wherein the shield sidewall member does not contact a reaction chamber wall.
  • 18. The shield for processing a substrate of claim 15 wherein the sidewall further comprises a top surface spaced from a reaction chamber surface between 5 and 10 mm.
  • 19. A reaction chamber comprising: a first region, a second region, and a third region;the first region positioned above the second and third regions, and adapted for processing a substrate;the second region positioned below the first region and adapted for loading the substrate in the reaction chamber;the third region positioned between the first region and the second region; andwherein the third region is movable via a shaft within the second region, andwherein a shield removably attached to the shaft defines a barrier between the second region and the third region.
  • 20. The reaction chamber of claim 19 further comprising a spacer further defining the barrier between the second region and the third region.
  • 21. The reaction chamber of claim 20 wherein the shield is movable within the second region.
  • 22. The reaction chamber of claim 21 wherein a third region volume varies based on a position of the substrate support member.
  • 23. A method of heating a substrate in a processing region comprising: providing a shield within the processing chamber below a substrate support member attached to a shaft;providing a spacer to space apart the shield and the substrate sue sort member and to space apart the shield and the shaft;loading a substrate in a processing region of the processing chamber;activating a heater; and, radiating heat from the shield to the substrate support member.
  • 24. The method of claim 23 further comprising the step of moving the substrate support member from a loading position to a processing position.
  • 25. The method of claim 23 further comprising the step of monitoring the temperature of a cavity between the substrate support member and the shield.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims the benefit of U.S. Provisional Application No. 61/563,428, filed on Nov. 23, 2011, the disclosure of which is hereby incorporated herein by reference.

US Referenced Citations (463)
Number Name Date Kind
2745640 Cushman May 1956 A
2990045 Root Sep 1959 A
3833492 Bollyky Sep 1974 A
3854443 Baerg Dec 1974 A
3862397 Anderson et al. Jan 1975 A
3887790 Ferguson Jun 1975 A
4054071 Patejak Oct 1977 A
4058430 Suntola et al. Nov 1977 A
4145699 Hu et al. Mar 1979 A
4176630 Elmer Dec 1979 A
4181330 Kojima Jan 1980 A
4194536 Stine et al. Mar 1980 A
4322592 Martin Mar 1982 A
4389973 Suntola et al. Jun 1983 A
4393013 McMenamin Jul 1983 A
4436674 McMenamin Mar 1984 A
4499354 Hill et al. Feb 1985 A
4512113 Budinger Apr 1985 A
4570328 Price et al. Feb 1986 A
D288556 Wallgren Mar 1987 S
4653541 Oehlschlaeger et al. Mar 1987 A
4722298 Rubin et al. Feb 1988 A
4735259 Vincent Apr 1988 A
4753192 Goldsmith et al. Jun 1988 A
4789294 Sato et al. Dec 1988 A
4821674 deBoer et al. Apr 1989 A
4827430 Aid et al. May 1989 A
4882199 Sadoway et al. Nov 1989 A
4986215 Yamada Jan 1991 A
4991614 Hammel Feb 1991 A
5062386 Christensen Nov 1991 A
5074017 Toya et al. Dec 1991 A
5119760 McMillan et al. Jun 1992 A
5167716 Boitnott et al. Dec 1992 A
5199603 Prescott Apr 1993 A
5221556 Hawkins et al. Jun 1993 A
5242539 Kumihashi et al. Sep 1993 A
5243195 Nishi Sep 1993 A
5326427 Jerbic Jul 1994 A
5380367 Bertone Jan 1995 A
5421893 Perlov Jun 1995 A
5422139 Fischer Jun 1995 A
5518549 Hellwig May 1996 A
5595606 Fujikawa et al. Jan 1997 A
5616947 Tamura Apr 1997 A
5632919 MacCracken et al. May 1997 A
5681779 Pasch et al. Oct 1997 A
5695567 Kordina Dec 1997 A
5730801 Tepman Mar 1998 A
5732744 Barr et al. Mar 1998 A
5736314 Hayes et al. Apr 1998 A
5796074 Edelstein et al. Aug 1998 A
5836483 Disel Nov 1998 A
5837320 Hampden-Smith et al. Nov 1998 A
5855680 Soininen et al. Jan 1999 A
5920798 Higuchi et al. Jul 1999 A
5979506 Aarseth Nov 1999 A
6013553 Wallace Jan 2000 A
6015465 Kholodenko et al. Jan 2000 A
6035101 Sajoto et al. Mar 2000 A
6060691 Minami et al. May 2000 A
6074443 Venkatesh Jun 2000 A
6083321 Lei et al. Jul 2000 A
6086677 Umotoy et al. Jul 2000 A
6122036 Yamasaki et al. Sep 2000 A
6125789 Gupta et al. Oct 2000 A
6129044 Zhao et al. Oct 2000 A
6148761 Majewski et al. Nov 2000 A
6160244 Ohashi Dec 2000 A
6161500 Kopacz et al. Dec 2000 A
6201999 Jevtic Mar 2001 B1
6274878 Li et al. Aug 2001 B1
6287965 Kang et al. Sep 2001 B1
6302964 Umotoy et al. Oct 2001 B1
6312525 Bright et al. Nov 2001 B1
D451893 Robson Dec 2001 S
D452220 Robson Dec 2001 S
6326597 Lubomirsky et al. Dec 2001 B1
6342427 Choi et al. Jan 2002 B1
6367410 Leahey et al. Apr 2002 B1
6368987 Kopacz et al. Apr 2002 B1
6383566 Zagdoun May 2002 B1
6410459 Blalock et al. Jun 2002 B2
6420279 Ono et al. Jul 2002 B1
6454860 Metzner et al. Sep 2002 B2
6478872 Chae et al. Nov 2002 B1
6482331 Lu et al. Nov 2002 B2
6483989 Okada et al. Nov 2002 B1
6511539 Raaijmakers Jan 2003 B1
6521295 Remington Feb 2003 B1
6534395 Werkhoven et al. Mar 2003 B2
6569239 Arai et al. May 2003 B2
6579833 McNallan et al. Jun 2003 B1
6590251 Kang et al. Jul 2003 B2
6594550 Okrah Jul 2003 B1
6598559 Vellore et al. Jul 2003 B1
6627503 Ma et al. Sep 2003 B2
6633364 Hayashi Oct 2003 B2
6645304 Yamaguchi Nov 2003 B2
6648974 Ogliari et al. Nov 2003 B1
6673196 Oyabu Jan 2004 B1
6682973 Paton et al. Jan 2004 B1
6709989 Ramdani et al. Mar 2004 B2
6710364 Guldi et al. Mar 2004 B2
6734090 Agarwala et al. May 2004 B2
6820570 Kilpela et al. Nov 2004 B2
6821910 Adomaitis et al. Nov 2004 B2
6824665 Shelnut et al. Nov 2004 B2
6847014 Benjamin et al. Jan 2005 B1
6858524 Haukka et al. Feb 2005 B2
6858547 Metzner Feb 2005 B2
6863019 Shamouilian Mar 2005 B2
6874480 Ismailov Apr 2005 B1
6875677 Conley, Jr. et al. Apr 2005 B1
6884066 Nguyen et al. Apr 2005 B2
6884319 Kim Apr 2005 B2
6889864 Lindfors et al. May 2005 B2
6909839 Wang et al. Jun 2005 B2
6930059 Conley, Jr. et al. Aug 2005 B2
6935269 Lee et al. Aug 2005 B2
6955836 Kumagai et al. Oct 2005 B2
6972478 Waite et al. Dec 2005 B1
7045430 Ahn et al. May 2006 B2
7053009 Conley, Jr. et al. May 2006 B2
7071051 Jeon et al. Jul 2006 B1
7115838 Kurara et al. Oct 2006 B2
7122085 Shero et al. Oct 2006 B2
7129165 Basol et al. Oct 2006 B2
7132360 Schaeffer et al. Nov 2006 B2
7135421 Ahn et al. Nov 2006 B2
7147766 Uzoh et al. Dec 2006 B2
7172497 Basol et al. Feb 2007 B2
7192824 Ahn et al. Mar 2007 B2
7192892 Ahn et al. Mar 2007 B2
7195693 Cowans Mar 2007 B2
7204887 Kawamura et al. Apr 2007 B2
7205247 Lee et al. Apr 2007 B2
7235501 Ahn et al. Jun 2007 B2
7238596 Kouvetakis et al. Jul 2007 B2
D553104 Oohashi et al. Oct 2007 S
7298009 Yan et al. Nov 2007 B2
D557226 Uchino et al. Dec 2007 S
7312494 Ahn et al. Dec 2007 B2
7329947 Adachi et al. Feb 2008 B2
7357138 Ji et al. Apr 2008 B2
7393418 Yokogawa Jul 2008 B2
7393736 Ahn et al. Jul 2008 B2
7402534 Mahajani Jul 2008 B2
7405166 Liang et al. Jul 2008 B2
7405454 Ahn et al. Jul 2008 B2
7414281 Fastow Aug 2008 B1
7431966 Derderian et al. Oct 2008 B2
7437060 Wang et al. Oct 2008 B2
7442275 Cowans Oct 2008 B2
7489389 Shibazaki Feb 2009 B2
D593969 Li Jun 2009 S
7547363 Tomiyasu et al. Jun 2009 B2
7575968 Sadaka et al. Aug 2009 B2
7589003 Kouvetakis et al. Sep 2009 B2
7601223 Lindfors et al. Oct 2009 B2
7601225 Tuominen et al. Oct 2009 B2
7640142 Tachikawa et al. Dec 2009 B2
7651583 Kent et al. Jan 2010 B2
D609655 Sugimoto Feb 2010 S
7678197 Maki Mar 2010 B2
D614153 Fondurulia et al. Apr 2010 S
7720560 Menser et al. May 2010 B2
7723648 Tsukamoto et al. May 2010 B2
7740705 Li Jun 2010 B2
7780440 Shibagaki et al. Aug 2010 B2
7833353 Furukawahara et al. Nov 2010 B2
7838084 Derderian et al. Nov 2010 B2
7851019 Tuominen et al. Dec 2010 B2
7884918 Hattori Feb 2011 B2
D634719 Yasuda et al. Mar 2011 S
8041197 Kasai et al. Oct 2011 B2
8055378 Numakura Nov 2011 B2
8071452 Raisanen Dec 2011 B2
8072578 Yasuda Dec 2011 B2
8076230 Wei Dec 2011 B2
8076237 Uzoh Dec 2011 B2
8082946 Laverdiere et al. Dec 2011 B2
8092604 Tomiyasu et al. Jan 2012 B2
8137462 Fondurulia et al. Mar 2012 B2
8147242 Shibagaki et al. Apr 2012 B2
8216380 White et al. Jul 2012 B2
8278176 Bauer et al. Oct 2012 B2
8282769 Iizuka Oct 2012 B2
8287648 Reed et al. Oct 2012 B2
8293016 Bahng et al. Oct 2012 B2
8309173 Tuominen et al. Nov 2012 B2
8323413 Son Dec 2012 B2
8367528 Bauer et al. Feb 2013 B2
8372204 Nakamura Feb 2013 B2
8444120 Gregg et al. May 2013 B2
8506713 Takagi Aug 2013 B2
D691974 Osada et al. Oct 2013 S
8608885 Goto et al. Dec 2013 B2
8683943 Onodera et al. Apr 2014 B2
8711338 Liu et al. Apr 2014 B2
D705745 Kurs et al. May 2014 S
8726837 Patalay et al. May 2014 B2
8728832 Raisanen et al. May 2014 B2
8802201 Raisanen et al. Aug 2014 B2
D716742 Jang et al. Nov 2014 S
8877655 Shero et al. Nov 2014 B2
8883270 Shero et al. Nov 2014 B2
8986456 Fondurulia et al. Mar 2015 B2
8993054 Jung et al. Mar 2015 B2
9005539 Halpin et al. Apr 2015 B2
9017481 Pettinger et al. Apr 2015 B1
9018111 Milligan et al. Apr 2015 B2
9021985 Alokozai et al. May 2015 B2
9029253 Milligan et al. May 2015 B2
9096931 Yednak et al. Aug 2015 B2
20010017103 Takeshita et al. Aug 2001 A1
20010046765 Cappellani et al. Nov 2001 A1
20020001974 Chan Jan 2002 A1
20020011210 Satoh et al. Jan 2002 A1
20020064592 Datta et al. May 2002 A1
20020098627 Pomarede et al. Jul 2002 A1
20020108670 Baker et al. Aug 2002 A1
20020115252 Haukka et al. Aug 2002 A1
20020172768 Endo et al. Nov 2002 A1
20020187650 Blalock et al. Dec 2002 A1
20030019580 Strang Jan 2003 A1
20030025146 Narwankar et al. Feb 2003 A1
20030040158 Saitoh Feb 2003 A1
20030042419 Katsumata et al. Mar 2003 A1
20030066826 Lee et al. Apr 2003 A1
20030075925 Lindfors et al. Apr 2003 A1
20030094133 Yoshidome et al. May 2003 A1
20030111963 Tolmachev et al. Jun 2003 A1
20030141820 White et al. Jul 2003 A1
20030168001 Sneh Sep 2003 A1
20030180458 Sneh Sep 2003 A1
20030228772 Cowans Dec 2003 A1
20030232138 Tuominen et al. Dec 2003 A1
20040009679 Yeo et al. Jan 2004 A1
20040013577 Ganguli et al. Jan 2004 A1
20040018307 Park et al. Jan 2004 A1
20040018750 Sophie et al. Jan 2004 A1
20040023516 Londergan et al. Feb 2004 A1
20040036129 Forbes et al. Feb 2004 A1
20040106249 Huotari Feb 2004 A1
20040077182 Lim et al. Apr 2004 A1
20040101622 Park et al. May 2004 A1
20040144980 Ahn et al. Jul 2004 A1
20040168627 Conley et al. Sep 2004 A1
20040169032 Murayama et al. Sep 2004 A1
20040198069 Metzner et al. Oct 2004 A1
20040200499 Harvey et al. Oct 2004 A1
20040219793 Hishiya et al. Nov 2004 A1
20040221807 Verghese et al. Nov 2004 A1
20040266011 Lee et al. Dec 2004 A1
20050008799 Tomiyasu et al. Jan 2005 A1
20050019026 Wang et al. Jan 2005 A1
20050020071 Sonobe et al. Jan 2005 A1
20050023624 Ahn et al. Feb 2005 A1
20050054228 March Mar 2005 A1
20050066893 Soininen Mar 2005 A1
20050070123 Hirano Mar 2005 A1
20050072357 Shero et al. Apr 2005 A1
20050092249 Kilpela et al. May 2005 A1
20050100669 Kools et al. May 2005 A1
20050106893 Wilk May 2005 A1
20050110069 Kil et al. May 2005 A1
20050123690 Derderian et al. Jun 2005 A1
20050173003 Laverdiere et al. Aug 2005 A1
20050187647 Wang et al. Aug 2005 A1
20050212119 Shero Sep 2005 A1
20050214457 Schmitt et al. Sep 2005 A1
20050214458 Meiere Sep 2005 A1
20050218462 Ahn et al. Oct 2005 A1
20050229848 Shinriki Oct 2005 A1
20050229972 Hoshi et al. Oct 2005 A1
20050241176 Shero et al. Nov 2005 A1
20050263075 Wang et al. Dec 2005 A1
20050271813 Kher et al. Dec 2005 A1
20050282101 Adachi Dec 2005 A1
20050287725 Kitagawa Dec 2005 A1
20060013946 Park et al. Jan 2006 A1
20060014384 Lee et al. Jan 2006 A1
20060019033 Muthukrishnan et al. Jan 2006 A1
20060024439 Tuominen et al. Feb 2006 A2
20060046518 Hill et al. Mar 2006 A1
20060051925 Ahn et al. Mar 2006 A1
20060060930 Metz et al. Mar 2006 A1
20060062910 Meiere Mar 2006 A1
20060063346 Lee et al. Mar 2006 A1
20060068125 Radhakrishnan Mar 2006 A1
20060110934 Fukuchi May 2006 A1
20060113675 Chang et al. Jun 2006 A1
20060128168 Ahn et al. Jun 2006 A1
20060148180 Ahn et al. Jul 2006 A1
20060163612 Kouvetakis et al. Jul 2006 A1
20060193979 Meiere et al. Aug 2006 A1
20060208215 Metzner et al. Sep 2006 A1
20060213439 Ishizaka Sep 2006 A1
20060223301 Vanhaelemeersch et al. Oct 2006 A1
20060226117 Bertram et al. Oct 2006 A1
20060228888 Lee et al. Oct 2006 A1
20060240574 Yoshie Oct 2006 A1
20060257563 Doh et al. Nov 2006 A1
20060257584 Derderian et al. Nov 2006 A1
20060258078 Lee et al. Nov 2006 A1
20060266289 Verghese et al. Nov 2006 A1
20070010072 Bailey et al. Jan 2007 A1
20070020953 Tsai et al. Jan 2007 A1
20070022954 Iizuka et al. Feb 2007 A1
20070028842 Inagawa et al. Feb 2007 A1
20070031598 Okuyama et al. Feb 2007 A1
20070031599 Gschwandtner et al. Feb 2007 A1
20070037412 Dip et al. Feb 2007 A1
20070042117 Kupurao et al. Feb 2007 A1
20070049053 Mahajani Mar 2007 A1
20070059948 Metzner et al. Mar 2007 A1
20070065578 McDougall Mar 2007 A1
20070066010 Ando Mar 2007 A1
20070077355 Chacin et al. Apr 2007 A1
20070084405 Kim Apr 2007 A1
20070096194 Streck et al. May 2007 A1
20070116873 Li et al. May 2007 A1
20070134942 Ahn et al. Jun 2007 A1
20070146621 Yeom Jun 2007 A1
20070155138 Tomasini et al. Jul 2007 A1
20070163440 Kim et al. Jul 2007 A1
20070166457 Yamoto et al. Jul 2007 A1
20070175397 Tomiyasu et al. Aug 2007 A1
20070209590 Li Sep 2007 A1
20070232501 Tonomura Oct 2007 A1
20070237697 Clark Oct 2007 A1
20070249131 Allen et al. Oct 2007 A1
20070252244 Srividya et al. Nov 2007 A1
20070264807 Leone et al. Nov 2007 A1
20080006208 Ueno et al. Jan 2008 A1
20080029790 Ahn et al. Feb 2008 A1
20080054332 Kim et al. Mar 2008 A1
20080057659 Forbes et al. Mar 2008 A1
20080075881 Won et al. Mar 2008 A1
20080085226 Fondurulia et al. Apr 2008 A1
20080113096 Mahajani May 2008 A1
20080113097 Mahajani et al. May 2008 A1
20080124908 Forbes et al. May 2008 A1
20080149031 Chu et al. Jun 2008 A1
20080176375 Erben et al. Jul 2008 A1
20080216077 Emani et al. Sep 2008 A1
20080224240 Ahn et al. Sep 2008 A1
20080233288 Clark Sep 2008 A1
20080237572 Chui et al. Oct 2008 A1
20080248310 Kim et al. Oct 2008 A1
20080261413 Mahajani Oct 2008 A1
20080282970 Heys et al. Nov 2008 A1
20080315292 Ji et al. Dec 2008 A1
20090000550 Tran et al. Jan 2009 A1
20090011608 Nabatame Jan 2009 A1
20090020072 Mizunaga et al. Jan 2009 A1
20090029564 Yamashita et al. Jan 2009 A1
20090035947 Horii Feb 2009 A1
20090061644 Chiang et al. Mar 2009 A1
20090085156 Dewey et al. Apr 2009 A1
20090093094 Ye et al. Apr 2009 A1
20090095221 Tam et al. Apr 2009 A1
20090107404 Ogliari et al. Apr 2009 A1
20090136668 Gregg et al. May 2009 A1
20090139657 Lee et al. Jun 2009 A1
20090211523 Kuppurao et al. Aug 2009 A1
20090211525 Sarigiannis et al. Aug 2009 A1
20090239386 Suzaki et al. Sep 2009 A1
20090242957 Ma et al. Oct 2009 A1
20090246374 Vukovic Oct 2009 A1
20090261331 Yang et al. Oct 2009 A1
20090277510 Shikata Nov 2009 A1
20090283041 Tomiyasu et al. Nov 2009 A1
20090289300 Sasaki et al. Nov 2009 A1
20100024727 Kim et al. Feb 2010 A1
20100025796 Dabiran Feb 2010 A1
20100055312 Kato et al. Mar 2010 A1
20100075507 Chang et al. Mar 2010 A1
20100102417 Ganguli et al. Apr 2010 A1
20100124610 Aikawa et al. May 2010 A1
20100130017 Luo et al. May 2010 A1
20100162752 Tabata et al. Jul 2010 A1
20100170441 Won et al. Jul 2010 A1
20100193501 Zucker et al. Aug 2010 A1
20100230051 Iizuka Sep 2010 A1
20100255198 Cleary et al. Oct 2010 A1
20100275846 Kitagawa Nov 2010 A1
20100294199 Tran et al. Nov 2010 A1
20100307415 Shero et al. Dec 2010 A1
20100322604 Fondurulia et al. Dec 2010 A1
20110000619 Suh Jan 2011 A1
20110061810 Ganguly et al. Mar 2011 A1
20110070380 Shero et al. Mar 2011 A1
20110089469 Merckling Apr 2011 A1
20110097901 Banna et al. Apr 2011 A1
20110108194 Yoshioka et al. May 2011 A1
20110236600 Fox et al. Sep 2011 A1
20110239936 Suzaki et al. Oct 2011 A1
20110254052 Kouvetakis Oct 2011 A1
20110256734 Hausmann et al. Oct 2011 A1
20110275166 Shero et al. Nov 2011 A1
20110308460 Hong et al. Dec 2011 A1
20120024479 Palagashvili et al. Feb 2012 A1
20120070136 Koelmel et al. Mar 2012 A1
20120070997 Larson Mar 2012 A1
20120090704 Laverdiere et al. Apr 2012 A1
20120098107 Raisanen et al. Apr 2012 A1
20120114877 Lee May 2012 A1
20120156108 Fondurulia et al. Jun 2012 A1
20120160172 Wamura et al. Jun 2012 A1
20120240858 Taniyama et al. Sep 2012 A1
20120270393 Pore et al. Oct 2012 A1
20120289053 Holland et al. Nov 2012 A1
20120295427 Bauer Nov 2012 A1
20120304935 Oosterlaken et al. Dec 2012 A1
20120318334 Bedell et al. Dec 2012 A1
20120321786 Satitpunwaycha et al. Dec 2012 A1
20130023129 Reed Jan 2013 A1
20130104988 Yednak et al. May 2013 A1
20130104992 Yednak et al. May 2013 A1
20130115383 Lu et al. May 2013 A1
20130126515 Shero et al. May 2013 A1
20130129577 Halpin et al. May 2013 A1
20130230814 Dunn et al. Sep 2013 A1
20130256838 Sanchez et al. Oct 2013 A1
20130264659 Jung Oct 2013 A1
20130292676 Milligan et al. Nov 2013 A1
20130292807 Raisanen et al. Nov 2013 A1
20130330911 Huang et al. Dec 2013 A1
20140000843 Dunn et al. Jan 2014 A1
20140014644 Akiba et al. Jan 2014 A1
20140020619 Vincent et al. Jan 2014 A1
20140027884 Fang et al. Jan 2014 A1
20140036274 Marquardt et al. Feb 2014 A1
20140060147 Sarin et al. Mar 2014 A1
20140067110 Lawson et al. Mar 2014 A1
20140073143 Alokozai et al. Mar 2014 A1
20140077240 Roucka et al. Mar 2014 A1
20140084341 Weeks Mar 2014 A1
20140103145 White et al. Apr 2014 A1
20140120487 Kaneko May 2014 A1
20140159170 Raisanen et al. Jun 2014 A1
20140175054 Carlson et al. Jun 2014 A1
20140217065 Winkler et al. Aug 2014 A1
20140220247 Haukka et al. Aug 2014 A1
20140225065 Rachmady et al. Aug 2014 A1
20140251953 Winkler et al. Sep 2014 A1
20140251954 Winkler et al. Sep 2014 A1
20140346650 Raisanen et al. Nov 2014 A1
20140087544 Tolle Dec 2014 A1
20150004316 Thompson et al. Jan 2015 A1
20150014632 Kim et al. Jan 2015 A1
20150024609 Milligan et al. Jan 2015 A1
20150048485 Tolle Feb 2015 A1
20150091057 Xie et al. Apr 2015 A1
20150096973 Dunn et al. Apr 2015 A1
20150132212 Winkler et al. May 2015 A1
20150140210 Jung et al. May 2015 A1
20150147877 Jung May 2015 A1
20150167159 Halpin et al. Jun 2015 A1
20150184291 Alokozai et al. Jul 2015 A1
20150187568 Pettinger et al. Jul 2015 A1
Foreign Referenced Citations (18)
Number Date Country
1563483 Jan 2005 CN
101330015 Dec 2008 CN
101522943 Sep 2009 CN
101423937 Sep 2011 CN
2036600 Mar 2009 EP
07283149 Oct 1995 JP
08335558 Dec 1996 JP
2001342570 Dec 2001 JP
2004014952 Jan 2004 JP
2004091848 Mar 2004 JP
2004538374 Dec 2004 JP
2005507030 Mar 2005 JP
2006186271 Jul 2006 JP
2008527748 Jul 2008 JP
I226380 Jan 2005 TW
200701301 Jan 2007 TW
2006056091 Jun 2006 WO
2006078666 Jul 2006 WO
Non-Patent Literature Citations (122)
Entry
USPTO; Final Office Action dated Jul. 14, 2014 in U.S. Appl. No. 12/754,223.
USPTO; Notice of Allowance dated Jul. 3, 2014 in U.S. Appl. No. 13/102,980.
USPTO; Office Action dated Jun. 3, 2014 in U.S. Appl. No. 12/854,818.
USPTO; Non-Final Office Action dated Jul. 2, 2014 in U.S. Appl. No. 13/283,408.
USPTO; Non-Final Office Action dated Jul. 30, 2014 in U.S. Appl. No. 13/284,642.
USPTO; Office Action dated Jul. 31, 2014 in U.S. Appl. No. 13/411,271.
USPTO Final Office Action dated Jul. 8, 2014 in U.S. Appl. No. 13/439,528.
USPTO; Final Office Action dated Jun. 18, 2014 in U.S. Appl. No. 13/535,214.
USPTO; Non-Final Office Action dated Aug. 8, 2014 in U.S. Appl. No. 13/563,066.
USPTO; Non-Final Office Action dated Jul. 10, 2014 in U.S. Appl. No. 13/612,538.
USPTO; Non-Final Office Action dated Jun. 2, 2014 in U.S. Appl. No. 13/677,151.
USPTO; Notice of Allowance dated Aug. 13, 2014 in U.S. Appl. No. 13/784,362.
USPTO; Restriction Requirement dated Jun. 26, 2014 in U.S. Appl. No. 13/874,708.
USPTO; Non-Final Office Action dated May 29, 2014 in U.S. Appl. No. 14/183,187.
Chinese Patent Office; Notice on the Third Office Action dated Jul. 1, 2014 in Application No. 201080036764.6.
Taiwan Patent Office; Office Action dated Jul. 4, 2014 in Application No. 099110511.
USPTO; Office Action dated Oct. 8, 2014 in U.S. Appl. No. 12/763,037.
USPTO; Non-Final Office Action dated Sep. 17, 2014 in U.S. Appl. No. 13/187,300.
USPTO; Non-Final Office Action dated Nov. 26, 2014 in U.S. Appl. No. 13/312,591.
UPPTO; Notice of Allowance dated Oct. 21, 2014 in U.S. Appl. No. 13/439,528.
USPTO; Notice of Allowance dated Oct. 23, 2014 in U.S. Appl. No. 13/535,214.
USPTO; Non-Final Office Action dated Oct. 15, 2014 in U.S. Appl. No. 13/597,043.
USPTO; Final Office Action dated Nov. 14, 2014 in U.S. Appl. No. 13/677,151.
USPTO; Non-Final Office Action dated Oct. 9, 2014 in U.S. Appl. No. 13/874,708.
USPTO; Non-Final Office Action dated Sep. 19, 2014 in U.S. Appl. No. 13/791,246.
USPTO; Non-Final Office Action dated Sep. 12, 2014 in U.S. Appl. No. 13/941,134.
USPTO; Restriction Requirement dated Sep. 16, 2014 in U.S. Appl. No. 13/948,055.
USPTO; Non-Final Office Action dated Oct. 30, 2014 in U.S. Appl. No. 13/948,055.
USPTO; Final Office Action dated Nov. 7, 2014 in U.S. Appl. No. 14/183,187.
Chinese Patent Office; Notice on the Second Office Action dated Sep. 16, 2014 in Application No. 201110155056.
Koutsokeras et al. Texture and Microstructure Evolution in Single-Phase TixTal-xN Alloys of Rocksalt Structure. Journal of Applied Physics, 110, pp. 043535-1-043535-6, (2011).
USPTO; Office Action dated Aug. 27, 2010 in U.S. Appl. No. 12/118,596.
USPTO; Office Action dated Feb. 15, 2011 in U.S. Appl. No. 12/118,596.
USPTO; Notice of Allowance dated Aug. 4, 2011 in U.S. Appl. No. 12/118,596.
USPTO; Notice of Allowance dated Jun. 16, 2011 in U.S. Appl. No. 12/430,751.
USPTO; Notice of Allowance dated Jul. 27, 2011 in U.S. Appl. No. 12/430,751.
USPTO; Office Action dated Apr. 23, 2013 in U.S. Appl. No. 12/763,037.
USPTO; Office Action dated Jan. 15, 2013 in U.S. Appl. No. 12/754,223.
USPTO; Office Action dated Feb. 26, 2013 in U.S. Appl. No. 12/754,223.
PCT; International Search report and Written Opinion dated Nov. 12, 2010 in Application No. PCT/US2010/030126.
PCT; International Search report and Written Opinion dated Jan. 12, 2011 in Application No. PCT/US2010/045368.
PCT; International Search report and Written Opinion dated Feb. 6, 2013 in Application No. PCT/US2012/065343.
PCT; International Search report and Written Opinion dated Feb. 13, 2013 in Application No. PCT/US2012/065347.
USPTO; Office Action dated Dec. 6, 2012 in U.S. Appl. No. 12/854,818.
USPTO; Office Action dated Jan. 10, 2013 in U.S. Appl. No. 13/339,609.
USPTO; Office Action dated Feb. 11, 2013 in U.S. Appl. No. 13/339,609.
Chinese Patent Office; Office Action dated Jan. 10, 2013 is Serial No. 201080015699.9.
Chang et al. Small-Subthreshold-Swing and Low-Voltage Flexible Organic Thin-Film Transistors Which Use HfLaO as the Gate Dielectric; IEEE Electron Device Letters; Feb. 2009; 133-135; vol. 30, No. 2; IEEE Electron Device Society.
Maeng et al. Electrical properties of atomic layer disposition Hf02 and Hf0xNy on Si substrates with various crystal orientations, Journal of the Electrochemical Society, Apr. 2008, p. H267-H271, vol. 155, No. 4, Department of Materials Science and Engineering, Pohang University of Science and Technology, Pohang, Korea.
Novaro et al. Theoretical Study on a Reaction Pathway of Ziegler-Natta-Type Catalysis, J. Chem. Phys. 68(5), Mar. 1, 1978 p. 2337-2351.
USPTO; Notice of Allowance dated Jan. 27, 2015 in U.S. Appl. No. 12/763,037.
USPTO; Final Office Action dated Jan. 29, 2015 in U.S. Appl. No. 13/283,408.
USPTO; Notice of Allowance dated Feb. 11, 2015 in U.S. Appl. No. 13/284,642.
USPTO; Final Office Action dated Jan. 16, 2015 in U.S. Appl. No. 13/411,271.
USPTO; Final Office Action dated Feb. 12, 2015 in U.S. Appl. No. 13/563,066.
USPTO; Non-Final Office Action dated Feb. 12, 2015 in U.S. Appl. No. 13/597,108.
USPTO; Notice of Allowance dated Feb. 26, 2015 in U.S. Appl. No. 13/677,151.
USPTO; Notice of Allowance dated Jan. 20, 2015 in U.S. Appl. No. 13/941,134.
USPTO; Non-Final Office Action dated Feb. 12, 2015 in U.S. Appl. No. 14/457,058.
USPTO; Non-Final Office Action dated Jan. 16, 2015 in U.S. Appl. No. 14/563,044.
Chinese Patent Office; Office Action dated Jan. 12, 2015 in Application No. 201080015699.9.
Chinese Patent Office; Notice on the Third Office Action dated Feb. 9, 2015 in Application No. 201110155056.
Japanese Patent Office; Office Action dated Dec. 1, 2014 in Application No. 2012-504786.
Taiwan Patent Office; Office Action dated Dec. 30, 2014 in Application No. 099114330.
Taiwan Patent Office; Office Action dated Dec. 19, 2014 in Application No. 099127063.
USPTO; Final Office Action dated Jun. 28, 2013 in U.S. Appl. No. 12/754,223.
USPTO; Office Action dated Feb. 25, 2014 in U.S. Appl. No. 12/754,223.
USPTO; Restriction Requirement dated Sep. 25, 2012 in U.S. Appl. No. 12/854,818.
USPTO; Final Office Action dated Mar. 13, 2013 in U.S. Appl. No. 12/854,818.
USPTO; Office Action dated Aug. 30, 2013 in U.S. Appl. No. 12/854,818.
USPTO; Final Office Action dated Mar. 26, 2014 in U.S. Appl. No. 12/854,818.
USPTO; Restriction Requirement dated May 8, 2013 in U.S. Appl. No. 13/102,980.
USPTO; Office Action dated Oct. 7, 2013 in U.S. Appl. No. 13/102,980.
USPTO; Final Office Action dated Mar. 25, 2014 in U.S. Appl. No. 13/102,980.
USPTO; Restriction Requirement dated Dec. 16, 2013 in U.S. Appl. No. 13/284,642.
USPTO; Restriction Requirement dated Apr. 21, 2014 in U.S. Appl. No. 13/284,642.
USPTO; Office Action dated Jan. 28, 2014 in U.S. Appl. No. 13/312,591.
USPTO; Final Office Action dated May 14, 2014 in U.S. Appl. No. 13/312,591.
USPTO; Final Office Action dated May 17, 2013 in U.S. Appl. No. 13/339,609.
USPTO; Office Action dated Aug. 29, 2013 in U.S. Appl. No. 13/339,609.
USPTO; Final Office Action dated Dec. 18, 2013 in U.S. Appl. No. 13/339,609.
USPTO; Notice of Allowance dated Apr. 7, 2014 in U.S. Appl. No. 13/339,609.
USPTO; Office Action dated Feb. 13, 2014 in U.S. Appl. No. 13/411,271.
USPTO; Restriction Requirement dated Oct. 29, 2013 in U.S. Appl. No. 13/439,258.
USPTO; Office Action dated Mar. 24, 2014 in U.S. Appl. No. 13/439,258.
USPTO; Office Action dated May 23, 2013 in U.S. Appl. No. 13/465,340.
USPTO; Final Office Action dated Oct. 30, 2013 in U.S. Appl. No. 13/465,340.
USPTO; Notice of Allowance dated Feb. 12, 2014 in U.S. Appl. No. 13/465,340.
USPTO; Office Action dated Dec. 20, 2013 in U.S. Appl. No. 13/535,214.
USPTO; Office Action dated Nov. 15, 2013 in U.S. Appl. No. 13/612,538.
USPTO; Office Action dated Apr. 24, 2014 in U.S. Appl. No. 13/784,362.
Chinese Patent Office; Notice on the First Office Action dated May 24, 2013 in Serial No. 201080036764.6.
Chinese Patent Office; Notice on the Second Office Action dated Jan. 2, 2014 in Serial No. 201080036764.6.
Japanese Patent Office; Office Action dated Dec. 25, 2014 in Serial No. 2012-504786.
USPTO; Final Office Action dated Apr. 15, 2015 in U.S. Appl. No. 13/187,300.
USPTO; Final Office Action dated Mar. 20, 2015 in U.S. Appl. No. 13/312,591.
USPTO; Notice of Allowance dated May 14, 2015 in U.S. Appl. No. 13/312,591.
USPTO; Final Office Action dated Mar. 13, 2015 in U.S. Appl. No. 13/597,043.
USPTO; Final Office Action dated Jun. 1, 2015 in U.S. Appl. No. 13/597,108.
USPTO; Non-Final Office Action dated May 28, 2015 in U.S. Appl. No. 13/651,144.
USPTO; Non-Final Office Action dated Apr. 3, 2015 in U.S. Appl. No. 13/677,133.
USPTO; Final Office Action dated Mar. 25, 2015 in U.S. Appl. No. 13/791,246.
USPTO; Notice of Allowance dated Mar. 10, 2015 in U.S. Appl. No. 13/874,708.
USPTO; Restriction Requirement dated Apr. 30, 2015 in U.S. Appl. No. 13/941,216.
USPTO; Non-Final Office Action dated Apr. 7, 2015 in U.S. Appl. No. 14/018,345.
USPTO; Non-Final Office Action dated Apr. 28, 2015 in U.S. Appl. No. 14/040,196.
USPTO; Non-Final Office Action dated Mar. 19, 2015 in U.S. Appl. No. 14/079,302.
USPTO; Non-Final Office Action dated Mar. 19, 2015 in U.S. Appl. No. 14/166,462.
USPTO; Non-Final Office Action dated Mar. 16, 2015 in U.S. Appl. No. 14/183,187.
USPTO; Non-Final Office Action dated Mar. 16, 2015 in U.S. Appl. No. 29/447,298.
Bearzotti, et al., “Fast Humidity Response of a Metal Halide-Doped Novel Polymer,” Sensors and Actuators B, 7, pp. 451-454, (1992).
Crowell, “Chemical methods of thin film deposition: Chemical vapor deposition, atomic layer deposition, and related technologies,” Journal of Vacuum Science & Technology A 21.5, (2003): S88-S95.
Varma, et al., “Effect of Mtal Halides on Thermal, Mechanical, and Electrical Properties of Polypyromelitimide Films,” Journal of Applied Polymer Science, vol. 32, pp. 3987-4000, (1986).
USPTO; Final Office Action dated Aug. 12, 2015 in U.S. Appl. No. 12/754,223.
USPTO; Non-Final Office Action dated Jun. 17, 2015 in U.S. Appl. No. 13/283,408.
USPTO; Notice of Allowance dated Jun. 12, 2015 in U.S. Appl. No. 13/563,066.
USPTO; Notice of Allowance dated Jul. 16, 2015 in U.S. Appl. No. 13/563,066.
USPTO; Notice of Allowance dated Aug. 4, 2015 in U.S. Appl. No. 13/677,133.
USPTO; Non-Final Office Action dated Jul. 30, 2015 in U.S. Appl. No. 13/941,216.
USPTO; Non-Final Office Action dated Jun. 29, 2015 in U.S. Appl. No. 13/966,782.
USPTO; Final Office Action dated Jul. 14, 2015 in U.S. Appl. No. 14/457,058.
USPTO; Notice of Allowance dated Jul. 6, 2015 in U.S. Appl. No. 29/447,298.
Related Publications (1)
Number Date Country
20130126515 A1 May 2013 US
Provisional Applications (1)
Number Date Country
61563428 Nov 2011 US