Reactors for conducting thermochemical processes with solar heat input, and associated systems and methods

Information

  • Patent Grant
  • 9103548
  • Patent Number
    9,103,548
  • Date Filed
    Monday, March 17, 2014
    10 years ago
  • Date Issued
    Tuesday, August 11, 2015
    8 years ago
Abstract
Reactors for conducting thermochemical processes with solar heat input, and associated systems and methods. A system may include a reactor having a reaction zone, a reactant source coupled in fluid in communication with the reactant zone, and a solar concentrator having at least one concentrator surface positionable to direct solar energy to a focal area. The system can further include an actuator coupled to the solar concentrator to move the solar concentrator relative to the sun, and a controller operatively coupled to the actuator. The controller can be programmed with instructions that, when executed, direct the actuator to position the solar concentrator to focus the solar energy on the reaction zone when the solar energy is above a threshold level, and direct the actuator to position the solar concentrator to point to a location in the sky having relatively little radiant energy to cool an object positioned at the focal area when the solar energy is below the threshold level.
Description
TECHNICAL FIELD

The present technology is directed generally to reactors for conducting thermochemical processes with solar heat input, and associated systems and methods. In particular embodiments, such reactors can be used to produce clean-burning, hydrogen-based fuels from a wide variety of feedstocks, and can produce structural building blocks from carbon and/or other elements that are released when forming the hydrogen-based fuels.


BACKGROUND

Renewable energy sources such as solar, wind, wave, falling water, and biomass-based sources have tremendous potential as significant energy sources, but currently suffer from a variety of problems that prohibit widespread adoption. For example, using renewable energy sources in the production of electricity is dependent on the availability of the sources, which can be intermittent. Solar energy is limited by the sun's availability (i.e., daytime only), wind energy is limited by the variability of wind, falling water energy is limited by droughts, and biomass energy is limited by seasonal variances, among other things. As a result of these and other factors, much of the energy from renewable sources, captured or not captured, tends to be wasted.


The foregoing inefficiencies associated with capturing and saving energy limit the growth of renewable energy sources into viable energy providers for many regions of the world, because they often lead to high costs of producing energy. Thus, the world continues to rely on oil and other fossil fuels as major energy sources because, at least in part, government subsidies and other programs supporting technology developments associated with fossil fuels make it deceptively convenient and seemingly inexpensive to use such fuels. At the same time, the replacement cost for the expended resources, and the costs of environment degradation, health impacts, and other by-products of fossil fuel use are not included in the purchase price of the energy resulting from these fuels.


In light of the foregoing and other drawbacks currently associated with sustainably producing renewable resources, there remains a need for improving the efficiencies and commercial viabilities of producing products and fuels with such resources





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a partially schematic, partial cross-sectional illustration of a system having a solar concentrator configured in accordance with an embodiment of the present technology.



FIG. 2 is a partially schematic, partial cross-sectional illustration of an embodiment of the system shown in FIG. 1 with the solar concentrator configured to emit energy in a cooling process, in accordance with an embodiment of the disclosure.



FIG. 3 is a partially schematic, partial cross-sectional illustration of a system having a movable solar concentrator dish in accordance with an embodiment of the disclosure.



FIG. 4 is a partially schematic, isometric illustration of a system having a trough-shaped solar concentrator in accordance with an embodiment of the disclosure.



FIG. 5 is a partially schematic illustration of a system having a Fresnel lens concentrator in accordance with an embodiment of the disclosure.



FIG. 6 is a partially schematic illustration of a reactor having a radiation control structure and redirection components configured in accordance with an embodiment of the present technology.





DETAILED DESCRIPTION

1. Overview


Several examples of devices, systems and methods for conducting reactions driven by solar energy are described below. Reactors in accordance with particular embodiments can collect solar energy during one phase of operation and use the collection device to reject heat during another phase of operation. Such reactors can be used to produce hydrogen fuels and/or other useful end products. Accordingly, the reactors can produce clean-burning fuel and can re-purpose carbon and/or other constituents for use in durable goods, including polymers and carbon composites. Although the following description provides many specific details of the following examples in a manner sufficient to enable a person skilled in the relevant art to practice, make and use them, several of the details and advantages described below may not be necessary to practice certain examples of the technology. Additionally, the technology may include other examples that are within the scope of the claims but are not described here in detail.


References throughout this specification to “one example,” “an example,” “one embodiment” or “an embodiment” mean that a particular feature, structure, process or characteristic described in connection with the example is included in at least one example of the present technology. Thus, the occurrences of the phrases “in one example,” “in an example,” “one embodiment” or “an embodiment” in various places throughout this specification are not necessarily all referring to the same example. Furthermore, the particular features, structures, routines, steps or characteristics may be combined in any suitable manner in one or more examples of the technology. The headings provided herein are for convenience only and are not intended to limit or interpret the scope or meaning of the claimed technology.


Certain embodiments of the technology described below may take the form of computer-executable instructions, including routines executed by a programmable computer or controller. Those skilled in the relevant art will appreciate that the technology can be practiced on computer or controller systems other than those shown and described below. The technology can be embodied in a special-purpose computer, controller, or data processor that is specifically programmed, configured or constructed to perform one or more of the computer-executable instructions described below. Accordingly, the terms “computer” and “controller” as generally used herein refer to any data processor and can include internet appliances, hand-held devices, multi-processor systems, programmable consumer electronics, network computers, mini-computers, and the like. The technology can also be practiced in distributed environments where tasks or modules are performed by remote processing devices that are linked through a communications network. Aspects of the technology described below may be stored or distributed on computer-readable media, including magnetic or optically readable or removable computer discs as well as media distributed electronically over networks. In particular embodiments, data structures and transmissions of data particular to aspects of the technology are also encompassed within the scope of the present technology. The present technology encompasses both methods of programming computer-readable media to perform particular steps, as well as executing the steps.


A reactor system in accordance with a particular embodiment includes a reactor having a reaction zone, a reactant source coupled in fluid communication with the reaction zone, and a solar collector having a least one concentrator surface positionable to direct solar energy to a focal area. The system can further include an actuator coupled to the solar concentrator to move the solar concentrator relative to the sun, and a controller operatively coupled to the actuator to control its operation. The controller can be programmed with instructions that, when executed, direct the actuator to position the solar concentrator to focus the solar energy on the reaction zone when the solar energy is above a threshold level (e.g. during the day). When the solar energy is below the threshold level, the controller can direct the actuator to position the solar concentrator to point to a location in the sky having relatively little radiant energy to cool an object positioned at the focal area.


A system in accordance with another embodiment of the technology includes a reactor, a reactant source, a solar concentrator, and a first actuator coupled to the solar concentrator to move the solar concentrator relative to the sun. The system can further include a radiation control structure positioned between a concentrator surface of the solar concentrator and its associated focal area. The radiation control structure has first surface and a second surface facing away from the first surface, each with a different absorptivity and emissivity. In particular, the first surface can have a first radiant energy absorptivity and a first radiant energy emissivity, and the second surface can have a second radiant energy absorptivity less than the first radiant energy absorptivity, and a second radiant energy emissivity greater than the first radiant energy emissivity. The system can further include a second actuator coupled to the radiation control structure to change the structure from a first configuration in which the first surface faces toward the concentrator surface, and a second configuration in which the second surface faces toward the concentrator surface. In particular embodiments, the system can still further include a controller that directs the operation of the radiation control structure depending upon the level of solar energy directed by the solar concentrator.


A method in accordance with a particular embodiment of the technology includes concentrating solar energy with a solar concentrator, directing the concentrated solar energy to a reaction zone positioned at a focal area of the solar concentrator, and at the reaction zone, dissociating a hydrogen donor into dissociation products via the concentrated solar energy. From the dissociation products, the method can further include providing at least one of a structural building block (based on at least one of carbon, nitrogen, boron, silicon sulfur, and a transition metal) and hydrogen-based fuel. In further particular embodiments, the method can further include taking different actions depending upon whether the solar energy is above or below a threshold level. For example, when the solar energy is above a threshold level, it can be directed to the reaction zone, and when it is below the threshold level, the solar concentrator can be pointed away from the sun to a location in the sky having relatively little radiative energy to cool the structural building block and/or the hydrogen based fuel.


2. Representative Reactors and Associated Methodologies



FIG. 1 is a partially schematic, partial cross-sectional illustration of a system 100 having a reactor 110 coupled to a solar concentrator 120 in accordance with the particular embodiment of the technology. In one aspect of this embodiment, the solar concentrator 120 includes a dish 121 mounted to pedestal 122. The dish 121 can include a concentrator surface 123 that receives incident solar energy 126, and directs the solar energy as focused solar energy 127 toward a focal area 124. The dish 121 can be coupled to a concentrator actuator 125 that moves the dish 121 about at least two orthogonal axes in order to efficiently focus the solar energy 126 as the earth rotates. As will be described in further detail below, the concentrator actuator 125 can also be configured to deliberately position the dish 121 to face away from the sun during a cooling operation.


The reactor 110 can include one or more reaction zones 111, shown in FIG. 1 as a first reaction zone 111a and second reaction zone 111b. In a particular embodiment, the first reaction zone 111a is positioned at the focal area 124 to receive the focused solar energy 127 and facilitate a dissociation reaction or other endothermic reaction. Accordingly, the system 100 can further include a distribution/collection system 140 that provides reactants to the reactor 110 and collects products received from the reactor 110. In one aspect of this embodiment, the distribution/collection system 140 includes a reactant source 141 that directs a reactant to the first reaction zone 111a, and one or more product collectors 142 (two are shown in FIG. 1 as a first product collector 142a and a second product collector 142b) that collect products from the reactor 110. When the reactor 110 includes a single reaction zone (e.g. the first reaction zone 111a) the product collectors 142a, 142b can collect products directly from the first reaction zone 111a. In another embodiment, intermediate products produced at the first reaction zone 111a are directed to the second reaction zone 111b. At the second reaction zone 111b, the intermediate products can undergo an exothermic reaction, and the resulting products are then delivered to the product collectors 142a, 142b along a product flow path 154. For example, in a representative embodiment, the reactant source 141 can include methane and carbon dioxide, which are provided (e.g., in an individually controlled manner) to the first reaction zone 111a and heated to produce carbon monoxide and hydrogen. The carbon monoxide and hydrogen are then provided to the second reaction zone 111b to produce methanol in an exothermic reaction. Further details of this arrangement and associated heat transfer processes between the first reaction zone 111a and second reaction zone 111b are described in more detail in co-pending U.S. application Ser. No. 13/027,060 titled “REACTOR VESSELS WITH PRESSURE AND HEAT TRANSFER FEATURES FOR PRODUCING HYDROGEN-BASED FUELS AND STRUCTURAL ELEMENTS, AND ASSOCIATED SYSTEMS AND METHODS” filed concurrently herewith and incorporated herein by reference.


In at least some instances, it is desirable to provide cooling to the reactor 110, in addition to the solar heating described above. For example, cooling can be used to remove heat produced by the exothermic reaction being conducted at the second reaction zone 111b and thus allow the reaction to continue. When the product produced at the second reaction zone 111b includes methanol, it may desirable to further cool the methanol to a liquid to provide for convenient storage and transportation. Accordingly, the system 100 can include features that facilitate using the concentrator surface 123 to cool components or constituents at the reactor 110. In a particular embodiment, the system 100 includes a first heat exchanger 150a operatively coupled to a heat exchanger actuator 151b that moves the first heat exchanger 150a relative to the focal area 124. The first heat exchanger 150a can include a heat exchanger fluid that communicates thermally with the constituents in the reactor 110, but is in fluid isolation from these constituents to avoid contaminating the constituents and/or interfering with the reactions taking place in the reactor 110. The heat exchanger fluid travels around a heat exchanger fluid flow path 153 in a circuit from the first heat exchanger 150a to a second heat exchanger 150b and back. At the second heat exchanger 150b, the heat exchanger fluid receives heat from the product (e.g. methanol) produced by the reactor 110 as the product proceeds from the second reaction zone 111b to the distribution/collection system 140. The heat exchanger fluid flow path 153 delivers the heated heat exchanger fluid back to the first heat exchanger 150a for cooling. One or more strain relief features 152 in the heat exchanger fluid flow path 153 (e.g., coiled conduits) facilitate the movement of the first heat exchanger 150a. The system 100 can also include a controller 190 that receives input signals 191 from any of a variety of sensors, transducers, and/or other elements of the system 100, and, in response to information received from these elements, delivers control signals 192 to adjust operational parameters of the system 100.



FIG. 2 illustrates one mechanism by which the heat exchanger fluid provided to the first heat exchanger 150a is cooled. In this embodiment, the controller 190 directs the heat exchanger actuator 151 to drive the first heat exchanger 150a from the position shown in FIG. 1 to the focal area 124, as indicated by arrows A. In addition, the controller 190 can direct the concentrator actuator 125 to position the dish 121 so that the concentrator surface 123 points away from the sun and to an area of the sky having very little radiant energy. In general, this process can be completed at night, when it is easier to avoid the radiant energy of the sun and the local environment, but in at least some embodiments, this process can be conducted during the daytime as well. A radiant energy sensor 193 coupled to the controller 190 can detect when the incoming solar radiation passes below a threshold level, indicating a suitable time for positioning the first heat exchanger 150a in the location shown in FIG. 2.


With the first heat exchanger 150a in the position shown in FIG. 2, the hot heat transfer fluid in the heat exchanger 150a radiates emitted energy 128 that is collected by the dish 121 at the concentrator surface 123 and redirected outwardly as directed emitted energy 129. An insulator 130 positioned adjacent to the focal area 124 can prevent the radiant energy from being emitted in direction other than toward the concentrator surface 123. By positioning the concentrator surface 123 to point to a region in space having very little radiative energy, the region in space can operate as a heat sink, and can accordingly receive the directed emitted energy 129 rejected by the first heat exchanger 150a. The heat exchanger fluid, after being cooled at the first heat exchanger 150a returns to the second heat exchanger 150b to absorb more heat from the product flowing along the product flow path 154. Accordingly, the concentrator surface 123 can be used to cool as well as to heat elements of the reactor 110.


In a particular embodiment, the first heat exchanger 150a is positioned as shown in FIG. 1 during the day, and as positioned as shown in FIG. 2 during the night. In other embodiments, multiple systems 100 can be coupled together, some with the corresponding first heat exchanger 150a positioned as shown in FIG. 1, and others with the first heat exchanger 150a positioned as shown in FIG. 2, to provide simultaneous heating and cooling. In any of these embodiments, the cooling process can be used to liquefy methanol, and/or provide other functions. Such functions can include liquefying or solidifying other substances, e.g., carbon dioxide, ethanol, butanol or hydrogen.


In particular embodiments, the reactants delivered to the reactor 110 are selected to include hydrogen, which is dissociated from the other elements of the reactant (e.g. carbon, nitrogen, boron, silicon, a transition metal, and/or sulfur) to produce a hydrogen-based fuel (e.g. diatomic hydrogen) and a structural building block that can be further processed to produce durable goods. Such durable goods include graphite, graphene, and/or polymers, which may produced from carbon structural building blocks, and other suitable compounds formed from hydrogenous or other structural building blocks. Further details of suitable processes and products are disclosed in the following co-pending U.S. Patent Applications: Ser. No. 13/027,208 titled “CHEMICAL PROCESSES AND REACTORS FOR EFFICIENTLY PRODUCING HYDROGEN FUELS AND STRUCTURAL MATERIALS, AND ASSOCIATED SYSTEMS AND METHODS”; Ser. No. 13/027,214 titled “ARCHITECTURAL CONSTRUCT HAVING FOR EXAMPLE A PLURALITY OF ARCHITECTURAL CRYSTALS”; and Ser. No. 13/027,068 titled “CARBON-BASED DURABLE GOODS AND RENEWABLE FUEL FROM BIOMASS WASTE DISSOCIATION”, all of which are filed concurrently herewith and incorporated herein by reference.



FIG. 3 illustrates a system 300 having a reactor 310 with a movable dish 321 configured in accordance another embodiment of the disclosed technology. In a particular aspect of this embodiment, the reactor 310 includes a first reaction zone 311a and a second reaction zone 311b, with the first reaction zone 311a receiving focused solar energy 127 when the dish 321 has a first position, shown in solid lines in FIG. 3. The dish 321 is coupled to a dish actuator 331 that moves the dish 321 relative to the reaction zones 311a, 311b. Accordingly, during a second phase of operation, the controller 190 directs the dish actuator 331 to move the dish 321 to the second position shown in dashed lines in FIG. 3. In one embodiment, this arrangement can be used to provide heat to the second reaction zone 311b when the dish 321 is in the second position. In another embodiment, this arrangement can be used to cool the second reaction zone 311b. Accordingly, the controller 190 can direct the concentrator actuator 125 to point the dish 321 to a position in the sky having little or no radiant energy, thus allowing the second reaction zone 311b to reject heat to the dish 321 and ultimately to space, in a manner generally similar to that described above with reference to FIGS. 1 and 2.


In other embodiments, the systems can include solar collectors having arrangements other than a dish arrangement. For example, FIG. 4 illustrates a system 400 having a reactor 410 that is coupled to a solar concentrator 420 in the form of a trough 421. The trough 421 is rotated by one or more trough actuators 431, and includes a concentrator surface 423 that directs incident solar energy 126 toward the reactor 410 for heating. In a particular embodiment shown in FIG. 4, the reactor 410 can include a first reaction zone 411a and a second reaction zone 411b that can operate in a manner generally similar to that described above with reference to FIGS. 1 and 2. The system 400 can further include a first heat exchanger 450a that can be moved toward or away from a focal area 424 provided by the trough 421 at the underside of the reactor 410. Accordingly, the first heat exchanger 450a can be positioned as shown FIG. 4 when the incident solar energy 126 is directed to the first reaction 411a for heating, and can be moved over the focal area 424 (as indicated by arrows A) to reject heat in a manner generally similar to that described above with respect to FIGS. 1 and 2. The reactor 410 can include an insulator 430 positioned to prevent heat losses from the reactor 410 during heating. The insulator 430 can also prevent heat from leaving the reactor 410 other than along the emitted energy path 128, in manner generally similar to that described above.



FIG. 5 is a partially schematic illustration of a system 500 that includes a solar concentrator 520 having a Fresnel lens 521 positioned to receive incident solar energy 126 and deliver focused solar energy 127 to a reactor 510. This arrangement can be used in conjunction with any of the systems and components described above for heating and/or cooling constituents and/or components of the reactor 510.



FIG. 6 is partially schematic illustration of a system 600 having a reactor 610 that receives radiation in accordance with still further embodiments of the disclosed technology. In one aspect of these embodiments, the reactor 610 can have an overall layout generally similar to that described above with reference to FIGS. 1 and 2. In other embodiments, the reactor can be configured like those shown in any of FIGS. 3-5, with the components described below operating in a generally similar manner.


The reactor 610 can include a transmissive component 612 that allows focused solar energy 127 to enter a first reaction zone 611a. In one embodiment, the transmissive component 112 includes glass or another material that is highly transparent to solar radiation. In another embodiment, the transmissive component 612 can include one or more elements that absorb energy (e.g., radiant energy) at one wavelength and re-radiate energy at another wavelength. For example, the transmissive component 612 can include a first surface 613a that receives incident solar energy at one wavelength and a second surface 613b that re-radiates the energy at another wavelength into the first reaction zone 611a. In this manner, the energy provided to the first reaction zone 611a can be specifically tailored to match or approximate the absorption characteristics of the reactants and/or products placed within the first reaction zone 611a. For example, the first and second surfaces 613a, 613b can be configured to receive radiation over a first spectrum having a first peak wavelength range and re-radiate the radiation into the first reaction zone 611a over a second spectrum having a second peak wavelength range different than the first. The second peak wavelength range can, in particular embodiments be closer than the first to the peak absorption of a reactant or product in the first reaction zone 611a. Further details of representative re-radiation devices are described in co-pending U.S. patent application Ser. No. 13/027,015 titled “CHEMICAL REACTORS WITH RE-RADIATING SURFACES AND ASSOCIATED SYSTEMS AND METHODS” filed concurrently herewith and incorporated herein by reference.


In particular embodiments, the system can also include a radiation control structure 660 powered by a control structure actuator 661. The radiation control structure 660 can include multiple movable elements 662, e.g. panels that pivot about corresponding pivot joints 664 in the manner of a Venetian blind. One set of elements 662 is shown in FIG. 6 for purposes of illustration—in general, this set is duplicated circumferentially around the radiation-receiving surfaces of the reactor 610. Each movable element 662 can have a first surface 663a and a second surface 663b. Accordingly, the radiation control structure 660 can position one surface or the other to face outwardly, depending upon external conditions (e.g. the level of focused solar energy 127), and/or whether the reactor 610 is being used in a heating mode or a cooling mode. In a particular aspect of this embodiment, the first surface 663a can have a relatively high absorptivity and a relatively low emissivity. This surface can accordingly readily absorb radiation during the day and/or when the focused solar energy 127 is above a threshold level, and can transmit (e.g., by conduction) the absorbed energy to the second surface 663b. The second surface 663b can have a relatively low absorptivity and a relatively high emissivity can accordingly emit energy conducted to it by the first surface 663a. In one orientation, this effect can operate to heat the first reaction zone 611a, and in the opposite orientation, this effect can operate to cool the first reaction zone 611a (or another component of the reactor 110, e.g. the first heat exchanger 150a described above), for example, at night. Accordingly, the radiation control structure 660 can enhance the manner in which radiation is delivered to the first reaction zone 611a, and the manner in which heat is removed from the reactor 610.


In still further embodiments, the reactor 610 can include a redirection component 670 coupled to a redirection actuator 671 to redirect radiation that “spills” (e.g. is not precisely focused on the transmissive component 612) due to collector surface aberrations, environmental defects, non-parallel radiation, wind and/or other disturbances or distortions. In a particular embodiment, the redirection 670 can include movable elements 672 that pivot about corresponding pivot joints 674 in a Venetian blind arrangement generally similar to that discussed above. Accordingly, these elements 672 can be positioned circumferentially around the radiation-receiving surfaces of the reactor 610. In one aspect of this embodiment, the surfaces of the movable elements 672 are reflective in order to simply redirect radiation into the first reaction zone 611a. In other embodiments, the surfaces can include wavelength-shifting characteristics described above and described in co-pending U.S. patent application Ser. No. 13/027,015 titled “CHEMICAL REACTORS WITH RE-RADIATING SURFACES AND ASSOCIATED SYSTEMS AND METHODS” previously incorporated by reference.


One feature of embodiments of the systems and processes described above with reference to FIGS. 1-6 that they can use a solar collector or concentrator surface to provide cooling as well heating, in effect, operating the concentrator surface in reverse. This arrangement can provide a useful heat transfer process for cooling products and/or other constituents produced by the reactor, while reducing or eliminating the need for separate elements (e.g., refrigeration systems) to provide these functions.


Another feature of at least some of the foregoing embodiments is that they can include surfaces specifically tailored to enhance the absorption and/or emission of radiation entering or rejected by the system. These elements can provide further thermodynamic efficiencies and therefore reduce the cost of producing the reactants described above.


Certain aspects of the technology described in the context of particular embodiments may be combined or eliminated in other embodiments. For example, particular embodiments were described above in the context of a reactor having two reaction zones. In other embodiments, similar arrangements for rejecting heat can be applied to reactors having a single reaction zone, or more than two reaction zones. The reaction zone(s) can be used to process constituents other than those described above in other embodiments. The solar concentrators described above can be used for other cooling processes in other embodiments. The solar concentrators can have other configurations (e.g., heliostat configurations) in other embodiments. In at least some embodiments, the reaction zone(s) can move relative to the solar concentrator, in addition to or in lieu of the solar concentrator moving relative to the reaction zone(s). The redirection component and radiation control structures described above can be used alone, in combination with each other, and/or in combination with any of the arrangements described above in association with FIGS. 1-5.


Further, while advantages associated with certain embodiments of the technology have been described in the context of those embodiments, other embodiments may also exhibit such advantages, and not all embodiments need necessarily exhibit such advantages to fall within the scope of the present disclosure. Accordingly, the present disclosure and associated technology can encompass other embodiments not expressly shown or described herein.


To the extent not previously incorporated herein by reference, the present application incorporates by reference in their entirety the subject matter of each of the following materials: U.S. patent application Ser. No. 12/857,553, filed on Aug. 16, 2010 and titled SUSTAINABLE ECONOMIC DEVELOPMENT THROUGH INTEGRATED PRODUCTION OF RENEWABLE ENERGY, MATERIALS RESOURCES, AND NUTRIENT REGIMES; U.S. patent application Ser. No. 12/857,553, filed on Aug. 16, 2010 and titled SYSTEMS AND METHODS FOR SUSTAINABLE ECONOMIC DEVELOPMENT THROUGH INTEGRATED FULL SPECTRUM PRODUCTION OF RENEWABLE ENERGY; U.S. patent application Ser. No. 12/857,554, filed on Aug. 16, 2010 and titled SYSTEMS AND METHODS FOR SUSTAINABLE ECONOMIC DEVELOPMENT THROUGH INTEGRATED FULL SPECTRUM PRODUCTION OF RENEWABLE MATERIAL RESOURCES USING SOLAR THERMAL; U.S. patent application Ser. No. 12/857,502, filed on Aug. 16, 2010 and titled ENERGY SYSTEM FOR DWELLING SUPPORT; U.S. patent application Ser. No. 13/027,235, filed on Feb. 14, 2011 and titled DELIVERY SYSTEMS WITH IN-LINE SELECTIVE EXTRACTION DEVICES AND ASSOCIATED METHODS OF OPERATION; U.S. Patent Application No. 61/401,699, filed on Aug. 16, 2010 and titled COMPREHENSIVE COST MODELING OF AUTOGENOUS SYSTEMS AND PROCESSES FOR THE PRODUCTION OF ENERGY, MATERIAL RESOURCES AND NUTRIENT REGIMES; U.S. patent application Ser. No. 13/027,208, filed on Feb. 14, 2011 and titled CHEMICAL PROCESSES AND REACTORS FOR EFFICIENTLY PRODUCING HYDROGEN FUELS AND STRUCTURAL MATERIALS, AND ASSOCIATED SYSTEMS AND METHODS; U.S. patent application Ser. No. 13/026,996, filed on Feb. 14, 2011 and titled REACTOR VESSELS WITH TRANSMISSIVE SURFACES FOR PRODUCING HYDROGEN-BASED FUELS AND STRUCTURAL ELEMENTS, AND ASSOCIATED SYSTEMS AND METHODS; U.S. patent application Ser. No. 13/027,015, filed on Feb. 14, 2011 and titled CHEMICAL REACTORS WITH RE-RADIATING SURFACES AND ASSOCIATED SYSTEMS AND METHODS; U.S. patent application Ser. No. 13/027,244, filed on Feb. 14, 2011 and titled THERMAL TRANSFER DEVICE AND ASSOCIATED SYSTEMS AND METHODS; U.S. patent application Ser. No. 13/026,990, filed on Feb. 14, 2011 and titled CHEMICAL REACTORS WITH ANNULARLY POSITIONED DELIVERY AND REMOVAL DEVICES, AND ASSOCIATED SYSTEMS AND METHODS; U.S. patent application Ser. No. 13/027,215, filed on Feb. 14, 2011 and titled INDUCTION FOR THERMOCHEMICAL PROCESS, AND ASSOCIATED SYSTEMS AND METHODS; U.S. patent application Ser. No. 13/027,198, filed on Feb. 14, 2011 and titled COUPLED THERMOCHEMICAL REACTORS AND ENGINES, AND ASSOCIATED SYSTEMS AND METHODS; U.S. Patent Application No. 61/385,508, filed on Sep. 22, 2010 and titled REDUCING AND HARVESTING DRAG ENERGY ON MOBILE ENGINES USING THERMAL CHEMICAL REGENERATION; U.S. patent application Ser. No. 13/027,060, filed on Feb. 14, 2011 and titled REACTOR VESSELS WITH PRESSURE AND HEAT TRANSFER FEATURES FOR PRODUCING HYDROGEN-BASED FUELS AND STRUCTURAL ELEMENTS, AND ASSOCIATED SYSTEMS AND METHODS; U.S. patent application Ser. No. 13/027,214, filed on Feb. 14, 2011 and titled ARCHITECTURAL CONSTRUCT HAVING FOR EXAMPLE A PLURALITY OF ARCHITECTURAL CRYSTALS; U.S. patent application Ser. No. 12/806,634, filed on Aug. 16, 2010 and titled METHODS AND APPARATUSES FOR DETECTION OF PROPERTIES OF FLUID CONVEYANCE SYSTEMS; U.S. patent application Ser. No. 12/806,634, filed on Feb. 14, 2011 and titled METHODS, DEVICES, AND SYSTEMS FOR DETECTING PROPERTIES OF TARGET SAMPLES; U.S. patent application Ser. No. 13/027,068, filed on Feb. 14, 2011 and titled SYSTEM FOR PROCESSING BIOMASS INTO HYDROCARBONS, ALCOHOL VAPORS, HYDROGEN, CARBON, ETC.; U.S. patent application Ser. No. 13/027,196 filed on Feb. 14, 2011 and titled CARBON RECYCLING AND REINVESTMENT USING THERMOCHEMICAL REGENERATION; U.S. patent application Ser. No. 13/027,195, filed on Feb. 14, 2011 and titled OXYGENATED FUEL; U.S. Patent Application No. 61/237,419, filed on Aug. 27, 2009 and titled CARBON SEQUESTRATION; U.S. Patent Application No. 61/237,425, filed on Aug. 27, 2009 and titled OXYGENATED FUEL PRODUCTION; U.S. patent application Ser. No. 13/027,197, filed on Feb. 14, 2011 and titled MULTI-PURPOSE RENEWABLE FUEL FOR ISOLATING CONTAMINANTS AND STORING ENERGY; U.S. Patent Application No. 61/421,189, filed on Dec. 8, 2010 and titled LIQUID FUELS FROM HYDROGEN, OXIDES OF CARBON, AND/OR NITROGEN; AND PRODUCTION OF CARBON FOR MANUFACTURING DURABLE GOODS; and U.S. patent application Ser. No. 13/027,185, filed on Feb. 14, 2011 and titled ENGINEERED FUEL STORAGE, RESPECIATION AND TRANSPORT.

Claims
  • 1. A method for processing a hydrogen donor, comprising: determining a level of radiant energy, the radiant energy detected from a radiant energy sensor;in response to a determination that the detected radiant energy is equal to or greater than a threshold, i) positioning a solar concentrator to direct concentrated radiant energy to a reaction zone positioned at a focal area of the solar concentrator, andii) dissociating, at the reaction zone, a hydrogen donor into dissociation products via the concentrated radiant energy, wherein the dissociation products include at least one of: (a) a structural building block based on at least one of carbon, nitrogen, boron, silicon, a transition metal, and sulfur; and (b) a hydrogen-based fuel; andin response to a determination that the detected radiant energy is less than the threshold, positioning the solar concentrator to disperse heat from the reaction zone positioned at the focal area of the solar concentrator.
  • 2. The method of claim 1 wherein the hydrogen donor includes methane, and wherein providing includes providing hydrogen and at least one of carbon, carbon dioxide and carbon monoxide.
  • 3. The method of claim 1 wherein the hydrogen donor includes a hydrocarbon.
  • 4. The method of claim 1 wherein the hydrogen donor includes a nitrogenous compound.
  • 5. The method of claim 1, further comprising operating a radiation control structure positioned between the solar concentrator and the focal area by: positioning a first surface of the radiation control structure having a first radiant energy absorptivity and a first radiant energy emissivity to face toward the solar concentrator when the radiant energy is equal to or greater than a threshold value; andpositioning a second surface of the radiation control structure having a second radiant energy absorptivity less than the first radiant energy absorptivity and a second radiant energy emissivity greater than the first radiant energy emissivity to face toward the focal area when the radiant energy is less than the threshold value.
  • 6. The method of claim 1, further comprising: in response to a determination that the radiant energy is equal to or greater than the threshold level, pointing the solar concentrator toward the sun; andin response to a determination that the radiant energy is less than the threshold level, placing at least one of the structural building block and the hydrogen-based fuel in thermal communication with the focal area, wherein dispersing heat at the focal area includes positioning the solar concentrator away from the sun and to another location having relatively little radiant energy to cool the at least one of the structural building block and the hydrogen-based fuel.
  • 7. The method of claim 6 wherein placing at least one of the structural building block and the hydrogen-based fuel in thermal communication with the focal area includes: aligning a heat exchanger with the focal area; anddirecting a heat exchange fluid from the heat exchanger to the at least one of the structural building block and the hydrogen-based fuel.
  • 8. A system for processing a hydrogen donor, comprising: a solar concentrator positionable to direct radiant energy to a focal area;a reactor having a reaction one positioned at the focal area of the solar concentrator;a reactant source coupled in fluid communication with the reaction zone of the reactor;a radiant energy sensor detecting a level of radiant energy;an actuator coupled to the solar concentrator to move the solar concentrator relative to the sun; anda controller operatively coupled to the actuator and the radiant energy sensor, the controller configured to: a) in response to a determination that the detected radiant energy is equal to or greater than a threshold, i) causing the actuator to position a solar concentrator to direct-concentrated radiant energy to the reaction zone, andii) dissociate, at the reaction zone, a hydrogen donor into dissociation products via the concentrated radiant energy, wherein the dissociation products include at least one of: (a) a structural building block based on at least one of carbon, nitrogen, boron, silicon, a transition metal and sulfur; and (b) a hydrogen-based fuel; andb) in response to a determination that the detected radiant energy is less than the threshold, causing the actuator to position the solar concentrator to disperse heat from the reaction zone positioned at the focal area of the solar concentrator.
  • 9. The system of claim 8 wherein the hydrogen donor includes a hydrocarbon.
  • 10. The system of claim 8 wherein the hydrogen donor includes methane.
  • 11. The system of claim 8 wherein the hydrogen donor includes a nitrogenous compound.
  • 12. The system of claim 8, further comprising: a radiation control structure positioned between a surface of the solar concentrator and the focal area, wherein the controller is further configured to: causing the actuator to position a first surface of the radiation control structure having a first radiant energy absorptivity and a first radiant energy emissivity to face toward the solar concentrator when the radiant energy is equal to or greater than a threshold value; andcausing the actuator to position a second surface of the radiation control structure having a second radiant energy absorptivity less than the first radiant energy absorptivity and a second radiant energy emissivity greater than the first radiant energy emissivity to face toward the focal area when the radiant energy is less than the threshold value.
  • 13. The system of claim 8, wherein the controller is further configured to: in response to a determination that the radiant energy is equal to or greater than the threshold level, causing the actuator to point the solar concentrator toward the sun; andin response to a determination that the radiant energy is less than the threshold level, place at least one of the structural building block and the hydrogen-based fuel in thermal communication with the focal area wherein dispersing heat at the focal area includes positioning the solar concentrator away from the sun and to another location having relatively little radiant energy to cool the at least one of the structural building block and the hydrogen-based fuel.
  • 14. The system of claim 13 wherein the controller is configured to place at least one of the structural building block and the hydrogen-based fuel in thermal communication with the focal area includes the controller configured to: align a heat exchanger with the focal area; anddirect a heat exchange fluid from the heat exchanger to the at least one of the structural building block and the hydrogen-based fuel.
CROSS-REFERENCE TO RELATED APPLICATIONS

The present application is a continuation of U.S. Ser. No. 13/481,673, filed May 25, 2012, which is a continuation of U.S. patent application Ser. No. 13/027,181, filed Feb. 14, 2011, now U.S. Pat. No. 8,187,550 issued May 29, 2012, which claims benefit of priority to U.S. Provisional Application 61/304,403, filed Feb. 13, 2010. Each of these applications are incorporated herein by reference in their entirety.

US Referenced Citations (198)
Number Name Date Kind
3613792 Hyde et al. Oct 1971 A
3633372 Kimmel et al. Jan 1972 A
3662832 Keeler et al. May 1972 A
3675699 Ocone Jul 1972 A
3757860 Pritchett Sep 1973 A
3788389 Waters Jan 1974 A
3807491 Van Hulsen Apr 1974 A
3830508 Endicott Aug 1974 A
3840068 Waters Oct 1974 A
3882937 Robinson May 1975 A
3936652 Levine Feb 1976 A
3975912 Greene Aug 1976 A
3986362 Baciu Oct 1976 A
3990502 Best Nov 1976 A
3991817 Clay Nov 1976 A
4019868 Sebacher et al. Apr 1977 A
4053576 Fletcher Oct 1977 A
4070861 Scragg et al. Jan 1978 A
4082865 Ban et al. Apr 1978 A
4099489 Bradley Jul 1978 A
4138993 Conley Feb 1979 A
4161211 Duffy et al. Jul 1979 A
4169460 Popovich et al. Oct 1979 A
4172506 Terry Oct 1979 A
4178987 Bowman et al. Dec 1979 A
4229184 Gregg Oct 1980 A
4257239 Partin et al. Mar 1981 A
4343338 Hart Aug 1982 A
4382189 Wilson May 1983 A
4386801 Chapman et al. Jun 1983 A
4455045 Wheeler Jun 1984 A
4549078 Monahan Oct 1985 A
4549528 Gibson Oct 1985 A
4601508 Kerian Jul 1986 A
4611847 Sullivan Sep 1986 A
4620580 Groezinger et al. Nov 1986 A
4650651 Fuderer Mar 1987 A
4706651 Yudow Nov 1987 A
4746160 Wiesemeyer May 1988 A
4921580 Martes et al. May 1990 A
4978162 Labbe Dec 1990 A
5058945 Elliott, Sr. et al. Oct 1991 A
5119897 Moriwake Jun 1992 A
5132090 Volland Jul 1992 A
5222698 Nelson et al. Jun 1993 A
5280990 Rinard Jan 1994 A
5287004 Finley Feb 1994 A
5315868 Jacobi et al. May 1994 A
5348774 Golecki et al. Sep 1994 A
5407245 Geropp Apr 1995 A
5442934 Wolflick Aug 1995 A
5498059 Switlik Mar 1996 A
5558721 Kohmura et al. Sep 1996 A
5560443 DuBose Oct 1996 A
5618134 Balch Apr 1997 A
5647877 Epstein Jul 1997 A
5844324 Spriggle Dec 1998 A
5882382 Hachisuka et al. Mar 1999 A
5986429 Mula, Jr. Nov 1999 A
6012065 Boucher et al. Jan 2000 A
6068328 Gazdzinski May 2000 A
6074696 Sato Jun 2000 A
6081183 Mading et al. Jun 2000 A
6089224 Poulek Jul 2000 A
6092861 Whelan Jul 2000 A
6155212 McAlister Dec 2000 A
6200069 Miller Mar 2001 B1
6216599 Cavanagh Apr 2001 B1
6220193 Dilks Apr 2001 B1
6242752 Soma et al. Jun 2001 B1
6309010 Whitten Oct 2001 B1
6334928 Sekine et al. Jan 2002 B1
6378932 Fasel et al. Apr 2002 B1
6409252 Andrus Jun 2002 B1
6464755 Nakanishi et al. Oct 2002 B2
6502533 Meacham Jan 2003 B1
6508209 Collier, Jr. Jan 2003 B1
6531704 Yadav et al. Mar 2003 B2
6534210 Luken et al. Mar 2003 B2
6571747 Gerstweiler Jun 2003 B1
6585785 Warren et al. Jul 2003 B1
6630267 Badding et al. Oct 2003 B2
6749043 Brown et al. Jun 2004 B2
6756140 McAlister Jun 2004 B1
6756565 Suenaga et al. Jun 2004 B2
6838782 Vu Jan 2005 B2
6854788 Graham Feb 2005 B1
6886249 Smalc May 2005 B2
6889755 Zuo et al. May 2005 B2
6897575 Yu May 2005 B1
6919062 Vasileiadis et al. Jul 2005 B1
6923004 Chandran et al. Aug 2005 B2
6926345 Ortega et al. Aug 2005 B2
6979049 Ortega et al. Dec 2005 B2
6984305 McAlister Jan 2006 B2
7014737 Harutyunyan et al. Mar 2006 B2
7033570 Weimer et al. Apr 2006 B2
7140181 Jensen et al. Nov 2006 B1
7152908 Shahbazi Dec 2006 B2
7165804 Shahbazi Jan 2007 B2
7179383 Porter et al. Feb 2007 B1
7185944 Shahbazi Mar 2007 B2
7207620 Cosgrove et al. Apr 2007 B2
7210467 Kweon et al. May 2007 B2
7211905 McDavid, Jr. May 2007 B1
7237827 Shahbazi Jul 2007 B2
7243980 Vala Jul 2007 B2
7250151 Tonkovich et al. Jul 2007 B2
7285350 Keefer et al. Oct 2007 B2
7293533 Hemsath Nov 2007 B2
7306781 Retallick et al. Dec 2007 B2
7337612 Skinnes et al. Mar 2008 B2
7343971 Pfefferle Mar 2008 B2
7397141 Gouker Jul 2008 B2
7420004 Hardy et al. Sep 2008 B2
7426959 Wang et al. Sep 2008 B2
7449158 Haueter et al. Nov 2008 B2
7504739 Enis Mar 2009 B2
7527094 McKinzie et al. May 2009 B2
7582167 Kaszuba et al. Sep 2009 B2
7587998 Hotta et al. Sep 2009 B2
7597068 Arai et al. Oct 2009 B2
7608120 Wunning Oct 2009 B2
7621262 Zubeck Nov 2009 B2
7628137 McAlister Dec 2009 B1
7692170 Gaus et al. Apr 2010 B2
7695709 Miki et al. Apr 2010 B2
7713642 Warner et al. May 2010 B2
7714258 Dalton May 2010 B2
7745026 Fan et al. Jun 2010 B2
7753122 Curlett Jul 2010 B2
7788924 Hines Sep 2010 B2
7789182 Bradley et al. Sep 2010 B2
7799315 Amendola Sep 2010 B2
7808121 Glynn Oct 2010 B1
7856843 Enis et al. Dec 2010 B2
7884308 Mejia Feb 2011 B1
7910258 Steinberg Mar 2011 B2
7943045 Rohrich et al. May 2011 B2
7943808 Hershkowitz et al. May 2011 B2
7955478 McClure Jun 2011 B2
7963328 Khinkis et al. Jun 2011 B2
7971861 Soininen Jul 2011 B2
7972471 Sant Jul 2011 B2
8043592 Krass Oct 2011 B2
8053916 Edwards et al. Nov 2011 B2
8083520 Mueller et al. Dec 2011 B2
8136740 Hagen et al. Mar 2012 B2
8187550 McAlister May 2012 B2
8202817 Yuge et al. Jun 2012 B2
8220539 Vinegar et al. Jul 2012 B2
8449634 Tamura et al. May 2013 B2
8673220 McAlister Mar 2014 B2
8771636 McAlister Jul 2014 B2
20030008183 Hsu Jan 2003 A1
20030178195 Agee et al. Sep 2003 A1
20040200618 Piekenbrock Oct 2004 A1
20040219737 Quon Nov 2004 A1
20040253168 Chu Dec 2004 A1
20040265448 Shiau et al. Dec 2004 A1
20040266615 Watson et al. Dec 2004 A1
20050029120 Bar-Gadda Feb 2005 A1
20050079977 Choi et al. Apr 2005 A1
20050272856 Cooper et al. Dec 2005 A1
20060005738 Kumar Jan 2006 A1
20060005739 Kumar Jan 2006 A1
20060048808 Ruckman et al. Mar 2006 A1
20060266043 Jerome Nov 2006 A1
20070031718 Fujimura et al. Feb 2007 A1
20070138006 Oakes et al. Jun 2007 A1
20070199339 Ishihara et al. Aug 2007 A1
20070205298 Harrison et al. Sep 2007 A1
20070220810 Leveson et al. Sep 2007 A1
20070295477 Mueller et al. Dec 2007 A1
20080073066 Chang et al. Mar 2008 A1
20080086946 Weimer et al. Apr 2008 A1
20080098654 Cherry et al. May 2008 A1
20080175766 Mankins et al. Jul 2008 A1
20080241033 Nazri Oct 2008 A1
20080295883 Ducellier et al. Dec 2008 A1
20080314411 Mueller et al. Dec 2008 A1
20090206666 Sella et al. Aug 2009 A1
20090313886 Hinman et al. Dec 2009 A1
20100043404 Hebbale et al. Feb 2010 A1
20100107994 Moriarty et al. May 2010 A1
20100140950 Pitre Jun 2010 A1
20100242352 Perkins et al. Sep 2010 A1
20110061295 McAlister Mar 2011 A1
20110061383 McAlister Mar 2011 A1
20110100731 Hassan May 2011 A1
20110197599 Stewart et al. Aug 2011 A1
20110214986 Brown Sep 2011 A1
20110220040 McAlister Sep 2011 A1
20110284298 Ajisaka Nov 2011 A1
20110315539 Zadik et al. Dec 2011 A1
20120009119 Yampolsky Jan 2012 A1
20120118878 Kim et al. May 2012 A1
20120119510 Herzen et al. May 2012 A1
Foreign Referenced Citations (82)
Number Date Country
2521698 Aug 2005 CA
692927 Dec 2002 CH
101042261 Sep 2007 CN
101091900 Dec 2007 CN
101597025 Dec 2009 CN
200702287 Apr 2008 EA
1394103 Mar 2004 EP
1658892 May 2006 EP
2923731 May 2009 FR
24256 Jul 1911 GB
S54069616 Jun 1979 JP
S57136097 Aug 1982 JP
59046375 Mar 1984 JP
562203328 Sep 1987 JP
S63282102 Nov 1988 JP
S64015132 Jan 1989 JP
H01215701 Aug 1989 JP
H02025571 Jan 1990 JP
H03125822 May 1990 JP
H04044314 Feb 1992 JP
05096149 Apr 1993 JP
H0637348 May 1994 JP
0725637 Mar 1995 JP
H07238289 Sep 1995 JP
0940491 Feb 1997 JP
09055374 Feb 1997 JP
10172960 Jun 1998 JP
H11108465 Apr 1999 JP
2000271472 Oct 2000 JP
2000353690 Dec 2000 JP
2001080902 Mar 2001 JP
2001181846 Jul 2001 JP
2001262353 Sep 2001 JP
03215670 Oct 2001 JP
2002158175 May 2002 JP
2002198082 Jul 2002 JP
2003031506 Jan 2003 JP
2003040601 Feb 2003 JP
2003166059 Jun 2003 JP
2005511467 Jun 2003 JP
2003229161 Aug 2003 JP
2004045339 Feb 2004 JP
2004351292 Dec 2004 JP
2005021876 Jan 2005 JP
2005175069 Jun 2005 JP
2005213069 Aug 2005 JP
2005243955 Sep 2005 JP
2007139399 Jun 2007 JP
2007150012 Jun 2007 JP
2007208076 Aug 2007 JP
2007527348 Sep 2007 JP
2007254180 Oct 2007 JP
2008503709 Feb 2008 JP
2008215322 Sep 2008 JP
2008310995 Dec 2008 JP
2009010263 Jan 2009 JP
2009500274 Jan 2009 JP
2009513466 Apr 2009 JP
2009121412 Jun 2009 JP
2009129701 Jun 2009 JP
2009274881 Nov 2009 JP
2009296957 Dec 2009 JP
2010003568 Jan 2010 JP
2010006653 Jan 2010 JP
2011507218 Mar 2011 JP
1020120077307 Jul 2012 KR
2011864 Apr 1994 RU
2120913 Oct 1998 RU
2312059 Dec 2007 RU
2403379 Nov 2010 RU
1498908 Aug 1989 SU
1776298 Nov 1992 SU
2007053370 May 2007 WO
WO-2007140441 Dec 2007 WO
WO-2008031488 Mar 2008 WO
WO-2008035776 Mar 2008 WO
WO-2008076840 Jun 2008 WO
2008093661 Aug 2008 WO
WO-2009098375 Aug 2009 WO
WO-2010097890 Sep 2010 WO
2011154945 Dec 2011 WO
2012014197 Feb 2012 WO
Non-Patent Literature Citations (25)
Entry
“Carnot Thermochemical Cycles.” Digital image. Wikipedia, the Free Encyclopedia, Published: Aug. 31, 2010. Accessed: Jan. 4, 2011. Printed: May 20, 2011. <http://en.wikipedia.org/wiki/File:Carnot—thermochemical—cycles.PNG>. p. 1.
“Closed Loop Thermochemical Energy Storage System Using Ammonia.” Australian National University College of Engineering & Computer Science—Solar Thermal Group. Accessed: Jan. 4, 2011. Printed: May 20, 2011. <http://solar-thermal.anu.edu.au/high-temperature/thermochemical-energy-storage/>. pp. 1-2.
“SI Cycle.” Digital image. Sandia National Laboratories: Energy, Resources and Nonproliferation. Accessed: Jan. 4, 2011. Printed: Jun. 13, 2011. <http://www.sandia.gov/ERN/images/SI-cycle2.jpg>. p. 1.
“The Carbon Cycle : Feature Articles.” NASA Earth Observatory : Home. Web. Accessed: Jul. 1, 2010. Printed: Jun. 13, 2011. 12 Pages. <http://earthobservatory.nasa.gov/Features/CarbonCycle>.
“The Solar Zinc Route.” Digital image. Swiss Federal Institute of Technology, Department of Mechanical and Process Engineering, Zurich. Accessed: Jan. 4, 2011. Printed: May 20, 2011. <http://www.pre.ethz.ch/research/projects/imgs/solzinc—1.jpg>. p. 1.
“Zinc Zinc-oxide Thermochemical Cycle.” Digital image. Wikipedia, the Free Encyclopedia, Published: Dec. 21, 2008. Accessed: Jan. 4, 2011. Printed: May 20, 2011. <http://en.wikipedia.org/wiki/File:Zinc—zinc-oxide—thermochemical—cycle.jpg>. p. 1.
Chen et al. “Thermochemistry Concept Map.” Teacherknowledge Wikispace, Published: Nov. 20, 2006. <http://teacherknowledge.wikispaces.com/file/view/Thermochemistry+concept+map+-+Extended.pdf>. p. 1.
Food and Agriculture Organization of the United Nations. “Carbon Sequestration Options under the Clean Development Mechanism to Address Land Degradation.” World Soil Resources Reports. Rome, 2000. pp. 1-45.
Foust et al. “An Economic and Environmental Comparison of a Biochemical and a Thermochemical Lignocellulosic Ethanol Conversion Processes.” Cellulose, vol. 16, Issue 4. Jun. 10, 2009. pp. 547-565.
Funk, James E. “Thermochemical Processes for the Production of Hydrogen from Water.” College of Engineering, University of Kentucky, Lexington, Kentucky. 1975. pp. 1-9.
Hackett et al. “Evaluation of Conversion Technoloigy Processes and Products: Appendix A—Discussion of Thermochemical Process Definitions.” University of California, Davis. Sep. 2004. pp. 1-7.
International Search Report and Written Opinion for PCT Application No. PCT/US11/024796; Applicant: McAlister Technologies, LLC; Date of Mailing: Oct. 25, 2011; 13 pages.
Kasting, James F. “The Carbon Cycle, Climate, and the Long-Term Effects of Fossil Fuel Burning.” U.S. Global Change Research Information Office. 1998. Web. Accessed: Jul. 1, 2010. Printed: Jun. 13, 2011. <http://www.gcrio.org/CONSEQUENCES/vol4no1/carbcycle.html>.
Solar Collectors, Energy Storage, and Materials, pp. 443-444 (DeWinter, Francis, 1991).
U.S. Energy Information Administration.“Greenhouse Gases—Energy Explained, Your Guide to Understanding Energy.” Web. Accessed: Jul. 1, 2010. Printed: Jun. 13, 2011. 1 Pages. <http://www.eia.gov/energyexplained/index.cfm?page=environment—about—ghg>.
US Environmental Protection Agency. “Cap and Trade.” Web. Accessed: Jul. 1, 2010. Printed: Jun. 13, 2011. <http://www.epa.gov/captrade/>.
US Environmental Protection Agency. “Carbon Dioxide—Geologic Sequestration | Climate Change—Greenhouse Gas Emissions | U.S. EPA.” Web. Accessed: Jul. 1, 2010. Printed: Jun. 13, 2011. <http://www.epa.gov/climatechange/emissions/co2—geosequest.html>.
US Environmental Protection Agency. “Carbon Dioxide | Climate Change—Greenhouse Gas Emissions | U.S. EPA”. Web. Accessed: Jul. 1, 2010. Printed: Jun. 13, 2011. 1 Page. <http://www.epa.gov/climatechange/emissions/co2.html>.
US Environmental Protection Agency. “EPA Preliminary Analysis of the Waxman-Markey Discussion Draft”. Web. Accessed: Jul. 1, 2010. Printed: Jun. 13, 2011. <http://www.epa.gov/climatechange/economics/pdfs/WM-Analysis.pdf>.
Vegners, Raimonds Maris; “Collodial Carbon and Silica : Their Use in Solar Energy” Table of Contents and Introduction of Thesis, University of Sydney, Feb. 1985, 5 pages.
“Solar Hydrogen.” Digital image. Swiss Federal Institute of Technology, Department of Mechanical and Process Engineering, Zurich. Accessed: Jan. 4, 2011. Printed: May 23, 2011. P. 1. <http://www.pre.ethz.ch/research/projects/imgs/solarhydro—1.jpg>.
N. Muradov: “Catalysis of Methane decomposition over elemental carbon”, Catalysis Communications, No. 3-4, Jul. 1, 2001, pp. 89-94, p. 89, right-hand column, paragraph 2.
Wikipedia > Aerogel > Carbon—“Carbon aerogels are also extremely ‘black’ in the infrared spectrum, reflecting only 0.3% of radiation between 250 nm and 14.3 pm, making them efficient for solar energy collectors,” 1 page. Accessed in 2011.
Muradov et al: “Catalytic Dissociation of Hydrocarbons: a Route to CO2-free Hydrogen”, 15th Annual Symposium on Catalysis in Petroleum Refining & Petrochemicals, No Date.
Supplemental European Search Report; Application EP 11742983.7 Dated Apr. 25, 2014; pp. 7.
Related Publications (1)
Number Date Country
20140339068 A1 Nov 2014 US
Provisional Applications (1)
Number Date Country
61304403 Feb 2010 US
Continuations (2)
Number Date Country
Parent 13481673 May 2012 US
Child 14215348 US
Parent 13027181 Feb 2011 US
Child 13481673 US