Resistive memories make use of a memory element that can change its electrical resistance through suitable programming. Accordingly, the memory element comprises a resistive storage medium which may form a resistive storage region of the memory and which exhibits at least two different states having different electrical resistance. One of these states may be referred to as a high resistive state or an OFF state and the other may be referred to as a low resistive state or ON state, where the electrical resistance of the ON state may be lower than that of the OFF state. The resistive storage medium may be switched between these states through suitable programming.
Details of one or more implementations are set forth in the accompanying drawings and description below. Other features will be apparent from the description and drawings, and from the claims.
Embodiments disclosed herein are generally directed to conductive bridging cells, particularly to resistance control in a conductive bridging memory.
In one embodiment, a memory element may have at least one high resistive state and at least one low resistive state. In one embodiment, a ratio of a resistance of the at least one high resistive state relative to the resistance of the at least one low resistive state may be at least 10, for example. In another embodiment, this ratio may be at least 100. In yet another embodiment, this ratio may be at least 1000 or even more than 104 or more than 105. A high ratio makes it easier to distinguish between the two states when electrically detecting them. Nevertheless, the storage medium is not limited to these examples. In a further embodiment, said resistance ratio may even be smaller than 10. Moreover, in addition to the at least one high resistive state and the at least one low resistive state additional resistive states may exist with a resistance between the at least one high resistive state and the at least one low resistive state. Such state may be particularly applied for multi-level storage cells, for example.
Depending on the applied material for the storage medium and the applied switching mechanism, programming may comprise the application of a thermal, electrical, magnetic, optic, etc. treatment of the storage medium, for example. In one embodiment, a storage medium may be switched or programmed by applying an electrical treatment, i.e. by applying a current or a voltage, such as a current pulse or voltage pulse, for example, to the storage medium. This electrical programming signal may be applied via a first electrode and a second electrode that are electrically connected to the storage medium.
As shown in
The integrated circuit 10, and particularly the conductive bridging cell 28 shown in
In one embodiment, the resistive storage medium 12 may be switched from an OFF state to an ON state by applying an electrical voltage between the first electrode 14 and the second electrode 16. This switching process may be referred to as a WRITE operation. In particular, an electrical WRITE pulse may be applied via the first electrical cell connection 18 and the second electrical cell connection 20. This WRITE pulse may be applied as an electrical WRITE voltage VW that is greater than a threshold voltage Vth.
In one embodiment, the resistive storage medium 12 may, for example, exhibit an OFF state resistance ROFF, i.e. a high resistive state, between about 108Ω and about 1012Ω. In another embodiment, the at least one OFF state resistance ROFF may be at least about 100 kΩ or more than about 1 MΩ or even more than about 10 MΩ or more than about 100 MΩ. In further embodiments, the OFF state resistance ROFF may be more than about 109Ω or even more than about 1010Ω or 1011Ω or even more than about 1012Ω.
In one embodiment, the first electrode 14 may be an inert electrode and the second electrode 16 may be a reactive electrode. An inert electrode 16 may comprise tungsten (W). A reactive electrode 18 may comprise silver (Ag) or copper (Cu), for example. In one embodiment, the reactive electrode may comprise the same material as the metal-doping of the resistive storage medium 12. Nevertheless, the electrodes are not limited to these materials but also other materials may be applied. In another embodiment, other electrode material, such as Ti, Ta, Au, Si, TaN, TiN or combinations thereof may be applied for the inert electrode. In yet another embodiment, Zn and/or a multi-layer or an alloy comprising reactive and inert material, such as AgTa, AgTi, CuRu/AgTa, for example, may be applied for the reactive electrodes.
Moreover, in one embodiment the resistance element 22 may exhibit a resistance RS that is smaller than the OFF state resistance ROFF of the resistive storage medium 12. In one embodiment, the resistance RS of the resistance element 22 may be at least a factor of 10, or even a factor of more than 100 smaller that the OFF state resistance ROFF of the resistive storage medium 12. In another embodiment, the resistance element 22 may exhibit a resistance RS between about 104Ω and about 108Ω, or between about 105Ω and about 107Ω.
In another embodiment, the resistance RS of the resistance element may be at about 500 kΩ. The resistance element may comprise silicon, such as doped silicon, for example, or silicide, or metal-nitride, of poly-silicon, or W, or Al, for example.
According to one embodiment, the electrical voltage during the WRITE operation, i.e. the electrical WRITE pulse, may have a first polarity such that the reactive electrode 16 is applied as anode, i.e. the positive pole is connected to the second electrical cell connection 20 while the negative pole is connected to the first electrical cell connection 18.
Accordingly, in one embodiment, a method of operating the resistive storage medium 12 may comprise applying an electrical operation signal between a first terminal, such as the first electrical cell connection 18, for example, and a second terminal, such as the second electrical cell connection 20, for example, of a memory cell, such as the storage cell 28, for example, comprising the resistive storage medium 12, with the resistance element 22 of the memory cell being electrically connected in series to the resistive storage medium 12 between the first terminal and the second terminal.
Through this applied voltage during the WRITE operation, metal ions 30, such as Ag+, for example, may be generated by a redox reaction at the reactive electrode 16. The electrical field resulting from the applied voltage may cause an injection of the metal-ions 30 from the anode 16 and an electron current from the cathode 14 reduces an equivalent number of metal-ions 30 as injected from the anode 16, thereby forming in the resistive storage medium metal-rich electro-deposits 32 (as shown in
The resistive storage medium 12 may, for example, exhibit an ON state resistance RON, i.e. a low resistive state, between about 102Ω and about 106Ω. In another embodiment, an ON state resistance RON of the resistive storage medium 12 may be between about 103Ω and about 105Ω. Nevertheless, the resistive storage medium 12 is not limited to these resistance values for a resistive ON state. In other embodiments the ON state resistance RON may be less than about 1 MΩ, or even less than about 100 kΩ or less than about 10 kΩ. In further embodiments, the ON state resistance RON may be below about 1 kΩ, or even below about 0.1 kΩ.
In one embodiment, the resistance element 22 may exhibit a resistance RS that is greater than an ON state resistance RON of the resistive storage medium 12. In one example, the resistance RS of the resistance element 22 may be at least a factor of 10, or even a factor of more than 100 greater than an ON state resistance RON of the resistive storage medium 12. According to one embodiment, the resistance RS of the resistance element 22 may be between an ON state resistance RON and an OFF state resistance ROFF of the resistive storage medium 12.
In some embodiments, for subsequent WRITE operations the ON state resistance RON may fluctuate, i.e. the ON state resistances RON in subsequent WRITE operations may differ from one another. In some cases, RON may fluctuate by a factor of more than about 2, or more than about 5, or even more than about 10. In some particular cases, even fluctuations of the ON state resistance RON between different WRITE operations by a factor of up to 50 or 100 may occur.
At the beginning of the WRITE operation, i.e. when the resistive storage medium is in a high resistive state (OFF state), as shown in
Once the electrically conductive bridge is formed, the electrical resistance of the resistive storage medium 12 drops to a low resistive state corresponding to an ON state resistance RON of the resistive storage medium 12, which may be smaller than the resistance RS of the resistance element 22. Accordingly, once the resistive storage medium is switched to an ON state, the electrical resistance of the series connection of the resistive storage medium 12 and the resistance element 22 may be largely determined by the resistance RS of the resistance element 22. Accordingly, the electrical resistance between the first electrical cell connection 18 and the second electrical cell connection 20 may be largely determined or dominated by the resistance RS of the resistance element 22, which may be larger than the resistance RON of the resistive storage medium 12. Thus, the fluctuations of the electrical resistance between the first and second electrical cell connection 18, 20 in subsequent WRITE operations is largely reduced as compared to the above mentioned fluctuations of the ON state resistance RON of the resistive storage medium 12.
Accordingly, in one embodiment the method may comprise forming at least one electrically conductive pathway, such as the electrically conductive bridge 32 shown in
As shown in
Accordingly, in one embodiment of a method of operating the resistive storage medium 12, applying the electrical operation signal between the first terminal 18 and the second terminal 20 may comprise applying an electrical ERASE pulse with an ERASE polarity such that the reactive electrode 16 contacting the resistive storage medium 12 is negatively biased with respect to the inert electrode 14 contacting the resistive storage medium 12. In particular, the method may comprise at least partly removing the electrically conductive pathway 32 within the resistive storage medium 12 between the reactive electrode 16 and the inert electrode 14.
Due to the operation principle a storage cell based on this technology may be called a Programmable Metallization Cell (PMC). Accordingly, in one embodiment, an integrated circuit such as the integrated circuit 10 of
As explained above, the serial connection of the resistive storage medium 12 and the resistance element 22 may reduce the fluctuations of the electrical resistance between the first 18 and second electrical cell connection 20 in the ON states of the resistive storage medium 12 as compared to the fluctuations of the ON state resistance RON of the resistive storage medium 12, itself. Accordingly, in particular when applying the integrated circuit 10 as a storage cell 28 or a storage device, an ON state resistance of the storage cell 28, which comprises the resistive storage medium 12 and the resistance element 22, may be largely determined by the resistance RS of the resistance element 22 and, therefore, fluctuations may be reduced. Accordingly, a READ operation of the stored information, i.e. a determination of the cell resistance may be easier. Moreover, due to a narrow distribution of the ON state resistance of the storage cell 28, an ERASE operation may be performed as a voltage controlled process, where a predetermined voltage may be applied between the first electrical cell connection 18 and the second electrical cell connection 20, while the resulting current is largely independent of the ON state resistance RON of the resistive storage medium 12. This may allow an easy, reliable, and secure operation of the integrated circuit 10.
According to one embodiment of a method of operating the resistive storage medium 12, which may be referred to as a READ operation, applying the electrical operation signal between the first terminal 18 and the second terminal 20 comprises applying an electrical READ signal, such that a voltage drop across the resistive storage medium 12 is smaller than a threshold voltage Vth for switching the resistive storage medium between the at least one high resistive state and the at least one low resistive state, for example. The method may further comprise determining a resistance state of an electrical resistance between the first and second terminal 18, 20.
In this connection, it is not required that a precise resistance of the resistive storage medium 12 is measured. Instead, in one embodiment only a resistance state between the first and second terminal 18, 20 may be determined. Nevertheless, in this embodiment it also not required that a precise resistance value between the first and second terminal 18, 20 is measured. In one particular embodiment, it may be detected whether the resistance between the first and second terminal 18, 20 is considerably higher than the resistance value RS of the resistance element 22 or not. This determination may be performed by comparison of the resistance between the first and second terminal 18, 20 with a resistance value of a reference resistance element. Comparing resistance values may be performed by comparing currents flowing through the reference resistance element, on the one hand, and the first and second terminal 18, 20, on the other hand, while applying a READ voltage, for example.
A determined value of the resistance of the memory cell 28, i.e. a value of the resistance between the first and second terminal 18, 20, that is considerably larger than the resistance RS of the resistance element 22 may be assigned to or referred to as an “OFF” state of the memory cell 28, while a resistance of the memory cell 28 that is close to the resistance RS of the resistance element 22 may be assigned to or referred to as an “ON” state of the memory cell 28.
In one embodiment, the electrical READ signal may be applied with a READ polarity such that the reactive electrode 16 contacting the resistive storage medium 12 is positively biased with respect to the inert electrode 14 contacting the resistive storage medium 12. In one embodiment, the READ signal may be applied with the WRITE polarity such that a voltage drop across the resistive storage medium 12 is smaller than the threshold voltage Vth for switching the resistive storage medium from the high resistive state to the low resistive state. Particularly, a READ voltage VR may be applied between the first and second terminal 18, 20 that is smaller than said threshold voltage Vth. Accordingly, for a schematic principle of a READ operation in an “OFF” state of the storage cell 28 it may also be referred to
Accordingly, in one embodiment, a distribution variation of the resistance of a programmed state or “ON” state of a non-volatile memory using CBRAM technology may be reduced. In another embodiment, an “ON” state resistance may be precisely tuned, independent of the resistive storage material. In yet another embodiment, the integrated circuit may provide self-protection for the resistive storage medium due to a provision of a minimum resistance of a storage cell, i.e. a limitation of a current, in particular during a programming operation. Moreover, in another embodiment, freedom of circuit design may be increased though allowing various operation modes, such as a current controlled operation mode (I-mode) or a voltage controlled operation mode (V-mode) for example.
In one embodiment not directly shown but similar to the example of
Accordingly, the integrated circuit 10 may comprise one or more resistive storage cells, such as the resistive storage cell 28. Each resistive storage cell may comprise a resistive storage medium, such as the resistive storage medium 12 described herein that is switchable between at least one high resistive state and at least one low resistive state. Moreover, the resistive storage cell may comprise a resistance element, such as the resistance element 22 described herein, that is serially connected to the resistive storage medium.
In one embodiment, the resistive storage medium may comprise a solid state electrolyte material arranged between a first electrode and a second electrode. The resistive storage medium may comprise a metal-doped solid state electrolyte material, for example. Accordingly, the resistive storage medium, such as the resistive storage medium 12 described herein, may form at least part of a solid state ionic memory element which may form a polar memory element with a WRITE and an ERASE signal having opposite polarity. The resistive storage medium may particularly comprise metal-doped chalcogenide material. One of first and second electrodes 14, 16 may be formed as a reactive electrode, such as the reactive electrode 16 described herein, that may comprise a metal that is also comprised in the resistive storage medium as dopant of the metal-doped solid state electrolyte material.
According to one embodiment, the resistance element, such as the resistance element 22 described herein, may exhibit an ohmic resistance. Particularly, the resistance element may exhibit substantially the same electrical resistance for both polarities of applied voltages, for example. Moreover, the resistive storage medium may be switchable within an operation voltage range and the electrical resistance element may exhibit a substantially ohmic behavior, i.e. a substantially constant resistance, for applied voltage within the operation voltage range. In one example, the operation voltage range may be between about −1.5V and 1.5V, for example. A set voltage or WRITE voltage VW may be between about 0.2V and 0.5V, particularly at about 0.3V, for example. A reset voltage or ERASE voltage VE may be between about 0.05V and about 0.15V, particularly at about 0.1V, for example. Nevertheless, depending on the particular materials applied for the electrodes, the resistive storage medium and/or the resistance element, for example, also other voltages may be applied.
According to another embodiment, the storage cell 28 may comprise a stacked arrangement of the first and second electrode, the resistive storage medium and the resistance element, such as the stacked layer sequence described in connection with
In another embodiment, a resistive storage medium, such as the resistive storage medium 12 describe above, of more than one resistive storage cell may be comprised in or formed by a common resistive storage layer such as the resistive storage layer 38 describe above. In another embodiment, a resistance element, such as the resistance element 22 described above, of more than one resistive storage cell may be formed as at least part of a common resistive layer, such as the resistive layer 36 described above, for example. According to yet another embodiment, one or more of the first and second electrode, such as the electrodes 14, 16 described above, of more than one resistive storage cell may be comprised in or formed by a common electrode layer, such as the electrode layer 40, for example.
Accordingly, in one embodiment the select device 26 may comprise a field effect transistor, where source and drain contacts of the field effect transistor may form the at least two connection terminals 25, 27. Depending on an electrical potential applied to a gate contact as the additional control terminal of the field effect transistor a channel conductance can be changed, thereby selectively allowing or preventing current flow between the connection terminals 25, 27 (source/drain contacts). In another embodiment, the select device 26 may comprise a diode, where the anode and cathode of the diode may form the at least two connection terminals 25, 27 of the select device 26.
Accordingly, in one embodiment the select device 26 may exhibit a selection state and a non-selection state where an electrical resistance or differential electrical resistance R1 in the selection state may be smaller than the electrical resistance or differential resistance R0 in the non-selection state of the select device 26. In one particular embodiment, the resistance element 22 may exhibit a resistance value RS between the selection state resistance or differential resistance R1 and the non-selection state resistance or differential resistance R0. According to yet another additional or alternative embodiment, the OFF state resistance ROFF of the resistive storage medium 12 may be between the selection state resistance or differential resistance R1 and the non-selection state resistance or differential resistance R0 of the select device 26.
In one embodiment, the integrated circuit 10 may form at least one memory cell in a storage device, where the select device 26 may be applied to selectively address at least one cell among a plurality of cells for READ, WRITE, or ERASE operation to be carried out at said at least one cell, for example. Accordingly, in yet another example the select device 26 may comprise any other select circuit suitable for selecting one or more cells among a plurality of cells in a storage device, such as a random access memory (RAM).
In the embodiment shown in
In another embodiment, shown in
Further embodiments of an integrated circuit 10 are described in connection with
In the example of
The second electrode 16 may comprise a layer sequence with the resistance element 22 formed by a common resistive layer 36 that is arranged at the resistive storage layer 38, and a common reactive layer 17 arranged at the common resistive layer 36. The reactive layer 17 may form at least part of a common electrode layer and it may comprise reactive electrode material (e.g. metal) as described above for the reactive electrode 16.
As shown in
As shown in
Moreover, each of the storage cells 28a, 28b, 28c comprises a select device 26a, 26b, 26c that may be formed by a field effect transistor. One of the source/drain contacts of the field effect transistor 26a, 26b, 26c may be electrically connected to the first electrode 14a, 14b, 14c while the other source/drain contact forms the first electrical cell connection 18a, 18b, 18c that may be electrically connected to a bit line of a storage device, such as a random access memory. Moreover, the field effect transistor 26a, 26b, 26c comprises a gate contact 44a, 44b, 44c that may be electrically connected to a word line of the storage device, such as the random access memory.
Accordingly, in one embodiment, a memory device, such as one of the integrated circuits 10 described above, may comprise a plurality of resistive storage cells, such as one or more of the above described storage cells 28, 28a, 28b, 28c, for example, that are arranged in rows and columns of at least one array. At least some of these storage cells may comprise a resistive storage region that may be formed by a resistive storage medium 12 according to one or more of the above described examples that is switchable between at least one high resistive state and at least one low resistive state. Moreover, each of the storage cells may comprise a resistance element, such as one of the above described resistance elements, for example, that is serially connected to the resistive storage region. Furthermore, a select device, such as a select device 26 described above with reference to
According to one embodiment, for each storage cell the at least one high resistive state exhibits a first electrical resistance ROFF and the at least one low resistive state exhibits a second electrical resistance RON smaller than the first electrical resistance ROFF. Moreover, the resistance element of the respective storage cell may exhibit a resistance value RS between the first electrical resistance ROFF and the second electrical resistance RON. In another embodiment, the resistance element of all storage cells within the at least one array may exhibit substantially the same resistance value RS. In particular, the resistance element may form a constant or prescribed resistor, while the resistive storage region, such as the resistive storage medium may form a switchable or variable resistor.
As described above for the integrated circuit 10, the memory device may comprise a resistive storage layer which comprises or forms the resistive storage region of more than one resistive storage cells of the memory device. For example, the resistive storage regions of all storage cells within the at least one array may be comprised in or formed by the common resistive storage layer, such as the resistive storage layer 38 shown in
In another embodiment, the memory device may comprise a common resistive layer, such as the resistive layer 36, which comprises or forms the resistance element of more than one resistive storage cells of the memory device.
In one embodiment, the resistance elements of all storage cells within the at least one array may be comprised in or formed by the common resistive layer, such as the resistive layer 36 shown in
In yet another embodiment, the memory device may comprise a common electrode layer which comprises or forms one of the first and second electrode of more than one resistive storage cells of the memory device. In one embodiment, one of the first and second electrode of all storage cells within the at least one array are comprised in or formed by a common electrode layer analogous to the above described integrated circuit 10 as shown in
In one embodiment, for each storage cell the select device may comprise a select transistor having a source region and a drain region via which the select transistor is connected in series to the resistive storage region and the resistance element as shown in
According to another embodiment, for each storage cell the select device may comprise a diode that is electrically connected in series to the resistive storage region and the resistance element between a first electrical cell connection and a second electrical cell connection of the storage cell, such as the first 18 and second electrical cell connection 20 described above. Moreover, for each row of the at least one array the word line may be electrically connected to at least some first electrical cell connections of the storage cells in the respective row and for each column of the at least one array the bit line may be electrically connected to at least some of the second electrical cell connections of the storage cells in the respective column. In this embodiment the memory device may be implemented as a cross-point cell array.
In yet another embodiment shown in
In one embodiment, the system 46 may comprise a processing unit 52 and a system bus 54 that couples various system components including the storage component 48 to the processing unit 52. The processing unit 52 may perform arithmetic, logic and/or control operations by accessing the storage component 48, for example. The storage component 48 may store information and/or instructions for use in combination with the processing unit 52. The storage component 48 may comprise volatile and/or non-volatile memory cells 50. The storage component 48 may be implemented as a random access memory (RAM) or a read only memory (ROM), for example. In one example, a basic input/output system (BIOS) storing the basic routines that helps to transfer information between elements within the electronic device or system 46, such as during start-up, may be stored in the storage component 48. The system bus 54 may be any of several types of bus structures including a memory bus or memory controller, a peripheral bus, and a local bus using any of a variety of bus architectures.
The electronic device or system 46 may further comprise a video input and/or output device 56, such as a display interface or a display device or a camera, connected to the system bus 54, for example. Alternatively or in addition to the video device 56 the system 46 may comprise an audio device 58 for inputting and/or outputting acoustic signals, such as a speaker and/or a microphone, for example. Moreover, in one embodiment, the system 46 may comprise an input interface 60, such as input keys and/or an interface for connecting a keyboard, a joystick or a mouse, for example. In yet another embodiment, the electronic device may comprise a network interface 62 for connecting the electronic device to a wired and/or a wireless network. Furthermore, one or more additional memory components 64 may be included in the electronic device.
In one embodiment, the storage component 48 is implemented as a data memory for storing computer readable instructions, data structures, program modules and/or other data for the operation of the system 46. In another embodiment, the storage component 48 may be implemented as a graphical memory or an input/output buffer. In one embodiment the storage component 48 is fixedly connected to the system 46. In another embodiment, the storage component 48 is implemented as a removable component, such as a memory card or chip card, for example.
In general, an integrated circuit may comprise a two-terminal switching device that comprises a first terminal, a second terminal, a switchable resistor the electrical resistance of which is electrically switchable between at least one high resistive state and at least one low resistive state, and a constant resistor electrically connected in series to the switchable resistor between the first and second terminal. In one embodiment, the switching device may be a polar switching device. In this embodiment, the first terminal may be electrically connected to an inert electrode, while the second terminal may be electrically connected to a reactive electrode.
While the foregoing is directed to embodiments of the present invention, other and further embodiments of the invention may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow.