This application claims priority to P.R.C. Patent Application No. 201910990351.4 titled “a semiconductor crystal growth apparatus” filed on Oct. 17, 2019, with the State Intellectual Property Office of the People's Republic of China (SIPO).
The present invention relates to the field of semiconductor technology, and in particular, to a semiconductor crystal growth device.
The Czochralski (CZ) method is an important method for preparing single crystal silicon for semiconductor and solar. The high-purity silicon material placed in the crucible is heated by a thermal field composed of a carbon material to melt it, and then the seed is immersed in the melt and undergoes a series of (seeding, shouldering, body, tailing, cooling) processes to obtain a single crystal ingot.
In the growth of semiconductor single crystal silicon or solar single crystal silicon using the CZ method, the temperature distribution of the crystal and the melt directly affects the quality and growth rate of the crystal. During the growth of CZ crystals, due to the existence of thermal convection in the melt, the distribution of trace impurities is uneven and growth stripes are formed. Therefore, how to suppress the thermal convection and temperature fluctuation of the melt during the crystal pulling process has been a widespread concern.
The crystal growth technology under a magnetic field generator (called MCZ) applies a magnetic field to a silicon melt as a conductor, subjecting the melt to a Lorentz force opposite to its direction of movement, obstructing convection in the melt and increasing the viscosity of the melt reduces impurities such as oxygen, boron, and aluminum from the quartz crucible into the melt, and then into the crystal, so that the grown silicon crystal can have a controlled oxygen content from low to high range, reducing The impurity stripes are widely used in semiconductor crystal growth processes. A typical MCZ technology is so called horizontal magnetic field crystal growth (HMCZ) technology, which applies a horizontal magnetic field to a semiconductor melt, and is widely used for the growth of large-sized and demanding semiconductor crystals.
In the crystal growth technology under a horizontal magnetic field device (HMCZ), the crystal growth furnace, thermal field, crucible, and silicon crystals are as symmetrical as possible in the circumferential direction, and the crucible and crystal rotation make the temperature distribution in the circumferential direction tends to be uniform. However, the magnetic field lines of the magnetic field applied during the application of the magnetic field pass from one end of the silicon melt in the quartz crucible to the other end in parallel. The Lorentz force generated by the rotating silicon melt is different in all directions in the circumferential direction, so the silicon melt flow and temperature distribution are inconsistent in the circumferential direction.
As shown in
According to the Voronkov crystal growth theory, the thermal equilibrium equation of the interface of the crystal and the liquid surface is as follows,
PS*LQ=Kc*Gc—Km*Gm.
Among them, LQ is the potential of silicon melt to silicon crystal phase transition, Kc, Km represent the thermal conductivity of the crystal and the melt, respectively; Kc, Km, and LQ are the physical properties of the silicon material; PS represents the crystal crystallization speed along the on-pull elongation direction that is approximately the pulling speed of the crystal; Gc, Gm are the temperature gradient (dT/dZ) of the crystal and the melt at the interface, respectively. Because the temperature below the interface of the semiconductor crystal and the melt exhibits periodic fluctuations with the change of the circumferential angle during the growth of semiconductor crystals, that is, the Gc of the temperature gradient (dT/dZ) of the crystal and the melt as the interface, Gm fluctuates. Therefore, the crystallization speed PS of the crystal in the circumferential angle direction fluctuates periodically, which is not conducive to controlling the quality of crystal growth.
For the reasons above, it is necessary to propose a new semiconductor crystal growth device to solve the problems in the prior art.
A series of simplified forms of concepts are introduced in the Summary of the Invention section, which will be described in further detail in the Detailed Description section. The summary of the invention is not intended to limit the key features and essential technical features of the claimed invention, and is not intended to limit the scope of protection of the claimed embodiments.
An objective of the present invention is to provide a semiconductor crystal growth apparatus, the semiconductor crystal growth apparatus comprises:
In accordance with some embodiments, the grooves are arranged on opposite sides of the reflector along the direction of the magnetic field.
In accordance with some embodiments, the grooves are arc-shaped grooves and arranged along the circumferential direction of the reflector.
In accordance with some embodiments, the reflector comprises an inner cylinder, an outer cylinder, and a heat insulating material; wherein the bottom of the outer cylinder is extended below the bottom of the inner cylinder and is closed to the bottom of the inner cylinder to form a cavity between the inner cylinder and the outer cylinder, and the heat insulation material is disposed in the cavity.
In accordance with some embodiments, the grooves are located at the bottom of the inner wall of the inner cylinder.
In accordance with some embodiments, the reflector comprises an inserting part, the inserting part comprises a protruding portion and an inserting portion, and the inserting portion is inserted between a portion of the bottom of the outer cylinder extended below the bottom of the inner cylinder and the bottom of the inner cylinder, and the protrusion portion is located inside an outer wall of the bottom of the inner cylinder.
In accordance with some embodiments, the grooves are located at the bottom of the protruding portion.
In accordance with some embodiments, an arc length of the arc-shaped groove ranges from 20 mm to 200 mm.
In accordance with some embodiments, a depth of the grooves ranges from 2 mm to 20 mm.
In accordance with some embodiments, an angle between the bottom of the groove and its side wall is greater than or equal to 90°.
According to the semiconductor crystal growth device of the present invention, by setting different distances between the bottom of the reflector and the silicon ingot along the circumferential direction of the silicon crystal ingot, that is, the distance between the bottom of the reflector and the silicon ingot in the direction of the magnetic field is greater than the distance between the bottom of the reflector and the silicon ingot in a direction perpendicular to the magnetic field, the temperature distribution of the silicon melt below the interface between the silicon ingot and the silicon melt is tuned, such that the problem of fluctuations in the temperature distribution of the silicon melt below the interface between the semiconductor crystal and the silicon melt surface resulted from the applied magnetic field can be tuned during the growth of the semiconductor crystal, and effectively improves the uniformity of the temperature distribution of the silicon melt, thereby improving the uniformity of the crystal growth rate and the quality of crystal pulling.
Exemplary embodiments will be more readily understood from the following detailed description when read in conjunction with the appended drawings, in which:
The embodiments of the present invention are described below by way of specific examples, and those skilled in the art can readily understand other advantages and effects of the present invention from the disclosure of the present disclosure. The present invention may be embodied or applied in various other specific embodiments, and various modifications and changes can be made without departing from the spirit and scope of the invention.
In the following description, while the invention will be described in conjunction with various embodiments, it will be understood that these various embodiments are not intended to limit the invention. On the contrary, the invention is intended to cover alternatives, modifications and equivalents, which may be comprised within the scope of the invention as construed according to the Claims. Furthermore, in the following detailed description of various embodiments in accordance with the invention, numerous specific details are set forth in order to provide a thorough understanding of the invention. However, it will be evident to one of ordinary skill in the art that the invention may be practiced without these specific details or with equivalents thereof. In other instances, well known methods, procedures, components, and circuits have not been described in detail as not to unnecessarily obscure aspects of the invention.
To understand the invention thoroughly, the following descriptions will provide detail steps to explain a method for crystal growth control of a shouldering process according to the invention. It is apparent that the practice of the invention is not limited to the specific details familiar to those skilled in the semiconductor arts. The preferred embodiment is described as follows. However, the invention has further embodiments beyond the detailed description.
The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of example embodiments. As used herein, the singular forms “a,” “an” and “the” are intended to comprise the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises,” “comprising,” “includes” and/or “including,” if used herein, specify the presence of stated features, integers, steps, operations, elements and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components and/or groups thereof.
Referring to
A pulling device 14 is provided on the top of the furnace body 1. Driven by the pulling device 14, a seed crystal may be pulled and pulled out of a silicon ingot 10 from the silicon melt surface, and a heat shield device is provided around the silicon ingot 10. The heat shield device, for example, as shown in
In order to achieve stable growth of the silicon ingot, a driving device 15 for driving the crucible 11 to rotate and move up and down is provided at the bottom of the furnace body 1. The driving device 15 drives the crucible 11 to keep rotating during the crystal pulling process in order to reduce silicon melting. The thermal asymmetry of the body causes the silicon crystal columns to grow equally.
In order to hinder the convection of the silicon melt, increase the viscosity in the silicon melt, reduce impurities such as oxygen, boron, and aluminum from the quartz crucible into the melt and then into the crystal, so that the grown silicon crystal can have the controlled low-to-high range oxygen content reduces impurity streaks. The semiconductor growth device further comprises a magnetic field applying device 17 located outside the furnace body 1 to apply a magnetic field to the silicon melt in the crucible.
Since the magnetic field lines of the magnetic field applied by the magnetic field applying device 17 pass from one end of the silicon melt in the crucible to the other end in parallel (see the dotted arrow in
For this reason, in the semiconductor growth device of the present invention, the reflector 16 is arranged along the circumferential direction of the silicon ingot, and the bottom of the reflector and the silicon ingot have different distances.
Along the circumference of the silicon ingot, a different distance is set between the bottom of the reflector and the silicon ingot, and the distance between the bottom of the reflector and the silicon ingot in the direction of the magnetic field is greater than that of perpendicular in the direction of the magnetic field. The distance between the bottom of the reflector and the silicon ingot in the direction of the magnetic field, where the distance is greater, the silicon melt surface radiates more heat to the silicon ingot and the inside of the reflector. At a small distance, the heat from the silicon melt surface radiates to the silicon ingot and the inside of the reflector, so that the temperature of the silicon melt surface at a longer distance is lower than that of the silicon melt at a smaller distance. The temperature of the body fluid surface is much reduced, making up for the problem that the temperature in the direction of the magnetic field application is higher than the temperature perpendicular to the direction of the magnetic field application due to the effect of the applied magnetic field on the silicon melt flow. According to this, by setting the distance between the bottom of the reflector and the silicon crystal ingot, the temperature distribution of the silicon melt below the interface between the silicon ingot and the silicon melt can be tuned, so that the caused by the applied magnetic field can be tuned. The fluctuation of the temperature distribution of the silicon melt in the circumferential direction effectively improves the uniformity of the temperature distribution of the silicon melt, thereby improving the uniformity of the speed of crystal growth and the quality of crystal pulling.
Meanwhile, along the circumferential direction of the silicon ingot, there is a different distance between the bottom of the reflector and the silicon ingot, so that at a larger distance, the top of the furnace body communicates with the pressure and flow rate of the silicon melt liquid level flowing back through the reflector are reduced, and the shear force of the silicon melt liquid level is reduced. At a small distance, the top of the furnace body passes through the reflector, the pressure and flow rate at the position of the silicon melt surface increase, and the shear force of the silicon melt surface increases. Accordingly, by setting the distance between the bottom of the reflector and the silicon ingot, the flow of the silicon melt is increased. The structure is further tuned to make the flow state of the silicon melt more uniform along the circumferential direction, which further improves the uniformity of the crystal growth speed and the quality of the crystal pull. At the same time, by changing the flow state of the silicon melt, the uniformity of the oxygen content distribution in the crystal can be improved, and defects in crystal growth can be reduced.
Specifically, according to the present invention, grooves are provided at the bottom of the inner wall of the reflector 16, so that the distance between the reflector and the silicon ingot in the direction of the magnetic field is greater than that in the vertical direction. The distance between the reflector and the silicon ingot is increased in the direction of the magnetic field, so that the heat dissipation of the silicon melt surface along the direction of the magnetic field is increased as well, and is more conducive to tune because of the influence of the applied horizontal magnetic field on the uneven temperature distribution of the silicon melt. At the same time, the area of the inner wall of the reflector is increased by forming grooves on the inner wall of the reflector, so that the liquid surface of the silicon ingot can increase the efficiency of heat dissipation by radiating heat to the inner wall of the reflector, and the crystal pulling is improved. During the process, the uniformity of temperature distribution on the upper and lower sides of the crystal ingot improves the quality of the crystal pulling. At the same time, by forming grooves at the bottom of the reflector, the structure of the existing reflector is fully utilized without redesigning the reflector structure, and the technical effects of the present invention can be realized, and the production cost is effectively reduced.
According to an embodiment of the present invention, the cross section of the bottom of the reflector cylinder 16 is circular. The reflector is arranged in a circular barrel shape, and the grooves are arranged on two opposite sides of the bottom of the reflector along the application direction of the magnetic field.
Further, exemplarily, the grooves are set as an arc-shaped groove arranged along the circumferential direction of the reflector.
Referring to
In an example, as shown in
It should be understood that in this embodiment, the grooves are set to be arranged on the opposite sides of the reflector along the direction of the magnetic field, and the grooves are set in an arc shape, and the angle θ between the bottom and the side wall is greater than or equal to 90° are purely exemplary, and those skilled in the art should understand that any grooves arranged at the bottom of the reflector can make the distance between the reflector and the silicon ingot in the direction of applying the magnetic field greater than in the direction perpendicular to the magnetic field can achieve the technical effect of the present invention.
Exemplarily, the arc length of the arc-shaped groove ranges from 20 mm to 200 mm.
Exemplarily, the depth of the grooves is in the range of 2-20 mm.
In one embodiment, the reflector comprises an inner cylinder, an outer cylinder and a heat-insulation material, in which a bottom of the outer cylinder is extended below a bottom of the inner cylinder and is closed with the bottom of the inner cylinder to form a cavity between the inner cylinder and the outer cylinder, and the heat-insulation material is disposed in the cavity.
In one embodiment, the grooves are located at the bottom of the inner wall of the inner cylinder.
Referring to
The grooves are arranged on the bottom side wall of the inner cylinder 161 to realize that the distance between the reflector and the silicon ingot in the direction of applying the magnetic field is greater than the distance between the reflector and the silicon ingot in the direction perpendicular to the magnetic field. The distance between the bottom of the reflector and the silicon melt surface is still determined by the distance between the bottom of the outer cylinder of the reflector and the silicon melt surface, so as to avoid the reduction of the distance between the bottom of the reflector and the silicon melt due to the existence of the grooves, thereby avoiding the change of the distance between the bottom of the reflector and the silicon melt surface that affects the temperature distribution of the silicon melt surface (in general, the bottom of the reflector is closer to the silicon melt liquid level, the faster the silicon melt will dissipate heat).
According to an embodiment of the present invention, the reflector comprises a tuning device for tuning the distance between the reflector and the silicon ingot. By adopting an additional tuning device to change the distance between the reflector and the silicon ingot, the manufacturing process of the reflector can be simplified on the existing reflector structure.
With continued reference to
Since the existing reflector is generally set in a conical barrel shape, the bottom of the reflector is usually set with a circular cross section, and the reflector is set to include between the inner cylinder and the outer cylinder without changing the structure of the existing reflector, the shape of the bottom of the reflector can be flexibly tuned by tuning the structure and shape of the inserting part without changing the structure of the existing reflector to tune the distance between the reflector and the silicon ingot; without changing the existing semiconductor growth device, the effect of the present invention can be achieved by arranging a tuning device with an inserting part. At the same time, the inserting part can be manufactured and replaced in a modular manner, so as to adapt to various semiconductor crystal growth processes of different sizes, thereby saving costs.
At the same time, the position where the inserting part is inserted between the bottom of the outer cylinder and the bottom of the inner cylinder effectively reduces the heat conduction from the outer cylinder to the inner cylinder, reduces the temperature of the inner cylinder, and further reduces the radiant heat transfer from the inner cylinder to the ingot, effectively. The difference between the axial temperature gradient of the center and the periphery of the silicon ingot is reduced, and the quality of the crystal pulling is improved. Exemplarily, the tuning device is employed a material with low thermal conductivity, such as SiC ceramic, quartz, or the like.
Exemplarily, the tuning device may be arranged along the bottom circumference of the reflector, such as an elliptical ring with grooves on the ring.
It should be understood that the setting of the tuning device in an elliptical ring is merely exemplary, and any tuning device capable of tuning the distance between the bottom of the reflector and the silicon ingot is suitable for use in the present invention.
The above is an exemplary introduction to the semiconductor crystal growth device according to the present invention. According to the semiconductor crystal growth device of the present invention, grooves are provided at the bottom of the inner wall of the reflector to make the distance between the bottom of the reflector and the silicon ingot in the direction of the magnetic field is greater than the distance between the bottom of the reflector and the silicon ingot in the direction perpendicular to the magnetic field, so that the temperature distribution of the silicon melt under the interface between the silicon ingot and the silicon melt plays a role in regulating, so that the fluctuation of the silicon melt temperature in the circumferential direction caused by the applied magnetic field can be tuned, which effectively improves the uniformity of the silicon melt temperature distribution, thereby improving the uniformity of crystal growth speed and improving the quality of crystal pulling. At the same time, the flow structure of the silicon melt is tuned to make the flow state of the silicon melt more uniform along the circumferential direction, which further improves the uniformity of crystal growth speed and reduces crystal growth defects.
While various embodiments in accordance with the disclosed principles been described above, it should be understood that they are presented by way of example only, and are not limiting. Thus, the breadth and scope of exemplary embodiment(s) should not be limited by any of the above-described embodiments, but should be defined only in accordance with the claims and their equivalents issuing from this disclosure. Furthermore, the above advantages and features are provided in described embodiments, but shall not limit the application of such issued claims to processes and structures accomplishing any or all of the above advantage.
Additionally, the section headings herein are provided for consistency with the suggestions under 37 C.F.R. 1.77 or otherwise to provide organizational cues. These headings shall not limit or characterize the invention(s) set out in any claims that may issue from this disclosure. Specifically, a description of a technology in the “Background” is not to be construed as an admission that technology is prior art to any invention(s) in this disclosure. Furthermore, any reference in this disclosure to “invention” in the singular should not be used to argue that there is only a single point of novelty in this disclosure. Multiple inventions may be set forth according to the limitations of the multiple claims issuing from this disclosure, and such claims accordingly define the invention(s), and their equivalents, that are protected thereby. In all instances, the scope of such claims shall be considered on their own merits in light of this disclosure, but should not be constrained by the headings herein.
Number | Date | Country | Kind |
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201910990351.4 | Oct 2019 | CN | national |