The invention relates to a semiconductor device and method for fabricating the same, and more particularly to a magnetoresistive random access memory (MRAM) and method for fabricating the same.
Magnetoresistance (MR) effect has been known as a kind of effect caused by altering the resistance of a material through variation of outside magnetic field. The physical definition of such effect is defined as a variation in resistance obtained by dividing a difference in resistance under no magnetic interference by the original resistance. Currently, MR effect has been successfully utilized in production of hard disks thereby having important commercial values. Moreover, the characterization of utilizing GMR materials to generate different resistance under different magnetized states could also be used to fabricate MRAM devices, which typically has the advantage of keeping stored data even when the device is not connected to an electrical source.
The aforementioned MR effect has also been used in magnetic field sensor areas including but not limited to for example electronic compass components used in global positioning system (GPS) of cellular phones for providing information regarding moving location to users. Currently, various magnetic field sensor technologies such as anisotropic magnetoresistance (AMR) sensors, GMR sensors, magnetic tunneling junction (MTJ) sensors have been widely developed in the market. Nevertheless, most of these products still pose numerous shortcomings such as high chip area, high cost, high power consumption, limited sensibility, and easily affected by temperature variation and how to come up with an improved device to resolve these issues has become an important task in this field.
According to an embodiment of the present invention, a method for fabricating a semiconductor device includes the steps of first forming an inter-metal dielectric (IMD) layer on a substrate, forming a contact hole in the IMD layer, forming a barrier layer and a metal layer in the contact hole, planarizing the metal layer, forming a spin orbit torque (SOT) layer on the barrier layer and the metal layer, and then forming a magnetic tunneling junction (MTJ) on the SOT layer.
According to another aspect of the present invention, a semiconductor device includes an inter-metal dielectric (IMD) layer on a substrate, a metal interconnection in the IMD layer as the metal interconnection includes a barrier layer in the IMD layer and extended to a surface of the IMD layer and a metal layer on the barrier layer, a spin orbit torque (SOT) layer on the barrier layer and the metal layer, and a magnetic tunneling junction (MTJ) on the SOT layer.
According to yet another aspect of the present invention, a semiconductor device includes an inter-metal dielectric (IMD) layer on a substrate, a metal interconnection in the IMD layer, a spin orbit torque (SOT) layer on the metal interconnection, an interface layer on the SOT layer, and a magnetic tunneling junction (MTJ) on the interface layer.
These and other objectives of the present invention will no doubt become obvious to those of ordinary skill in the art after reading the following detailed description of the preferred embodiment that is illustrated in the various figures and drawings.
Referring to
Active devices such as metal-oxide semiconductor (MOS) transistors, passive devices, conductive layers, and interlayer dielectric (ILD) layer 16 could also be formed on top of the substrate 12. More specifically, planar MOS transistors or non-planar (such as FinFETs) MOS transistors could be formed on the substrate 12, in which the MOS transistors could include transistor elements such as gate structures (for example metal gates) and source/drain region, spacer, epitaxial layer, and contact etch stop layer (CESL). The ILD layer 16 could be formed on the substrate 12 to cover the MOS transistors, and a plurality of contact plugs could be formed in the ILD layer 16 to electrically connect to the gate structure and/or source/drain region of MOS transistors. Since the fabrication of planar or non-planar transistors and ILD layer is well known to those skilled in the art, the details of which are not explained herein for the sake of brevity.
Next, metal interconnect structures 18, 20 are sequentially formed on the ILD layer 16 to electrically connect the aforementioned contact plugs, in which the metal interconnect structure 18 includes an inter-metal dielectric (IMD) layer 22 and metal interconnections 24 embedded in the IMD layer 22, and the metal interconnect structure 20 includes a stop layer 26, an IMD layer 28, and metal interconnections 30, 32 embedded in the stop layer 26 and the IMD layer 28.
In this embodiment, each of the metal interconnections 24 from the metal interconnect structure 18 preferably includes a trench conductor and each of the metal interconnections 30, 32 from the metal interconnect structure 20 includes a via conductor. Preferably, each of the metal interconnections 24, 30, 32 from the metal interconnect structures 18, 20 could be embedded within the IMD layers 22, 28 and/or stop layer 26 according to a single damascene process or dual damascene process. For instance, each of the metal interconnections 24, 30, 32 could further include a barrier layer 34 and a metal layer 36, in which the barrier layer 34 could be selected from the group consisting of titanium (Ti), titanium nitride (TiN), tantalum (Ta), and tantalum nitride (TaN) and the metal layer 36 could be selected from the group consisting of tungsten (W), copper (Cu), aluminum (Al), titanium aluminide (TiAl), and cobalt tungsten phosphide (CoWP). Since single damascene process and dual damascene process are well known to those skilled in the art, the details of which are not explained herein for the sake of brevity. In this embodiment, the metal layers 36 in the metal interconnections 24 are preferably made of copper, the metal layers 36 in the metal interconnections 30, 32 are preferably made of tungsten, the IMD layers 22, 28 are preferably made of silicon oxide or ultra low-k (ULK) dielectric layer, and the stop layers 26 is preferably made of nitrogen doped carbide (NDC), silicon nitride, silicon carbon nitride (SiCN), or combination thereof.
It should be noted that during the formation of the metal interconnections 30, 32 in the IMD layer 28 as shown in
In this embodiment, the barrier layer 34 preferably includes a dual-layer structure, in which the lower barrier layer 82 closer and directly contacting the IMD layer 28 preferably includes Ti while the upper barrier layer 84 includes TiN. Nevertheless, according to other embodiment of the present invention, each of the barrier layers 82, 84 could all be selected from the group consisting of titanium (Ti), titanium nitride (TiN), tantalum (Ta), and tantalum nitride (TaN), which is also within the scope of the present invention.
Moreover, even though the barrier layer 34 of this embodiment pertains to be a dual-layer structure made of dual barrier layers 82, 84, according to other embodiment of the present invention the barrier layer 34 could also be a single-layered structure disposed between the IMD layer 28 and the metal layer 36, in which the single-layered barrier layer 34 could also be selected from the group consisting of titanium (Ti), titanium nitride (TiN), tantalum (Ta), and tantalum nitride (TaN). In other words, if the barrier layer 34 were to be a single-layered structure, the bottom surface of the barrier layer 34 made of TiN for instance would directly contacting the IMD layer 28 or metal interconnections 34 while the top surface of the same barrier layer 34 also made of TiN would directly contacting the metal layer 36 made of tungsten above.
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In this embodiment, the formation of the MTJ stack 48 could be accomplished by sequentially depositing a free layer 52, a barrier layer 54, and a pinned layer 56 on the SOT layer 50. Preferably, the free layer 52 could be made of ferromagnetic material including but not limited to for example iron, cobalt, nickel, or alloys thereof such as cobalt-iron-boron (CoFeB), in which the magnetized direction of the free layer 52 could be altered freely depending on the influence of outside magnetic field. The barrier layer 54 could be made of insulating material including but not limited to for example oxides such as aluminum oxide (AlOx) or magnesium oxide (MgO). The pinned layer 56 could be made of antiferromagnetic (AFM) material including but not limited to for example ferromanganese (FeMn), platinum manganese (PtMn), iridium manganese (IrMn), nickel oxide (NiO), or combination thereof, in which the pinned layer 56 is formed to fix or limit the direction of magnetic moment of adjacent layers. It should be noted that since the present embodiment pertains to fabricating a SOT MRAM device, the free layer 52 is preferably disposed on the bottommost layer to contact the SOT layer 50 directly.
Preferably, the SOT layer 50 is serving as a channel for the MRAM device as the SOT layer 50 could include metals such as tantalum (Ta), tungsten (W), platinum (Pt), or hafnium (Hf) and/or topological insulator such as bismuth selenide (BixSe1-x). The cap layer 60 preferably includes metal such as Ta and the hard mask 62 preferably includes conductive material such as metal or metal nitride, in which metal could include Ti whereas metal nitride could include TiN. Nevertheless, the cap layer 60 or hard mask 62 could all include conductive or dielectric material including but not limited to for example Ta, TaN, Ti, TiN, Pt, Cu, Au, Al, or combination thereof.
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Next, an IMD layer 66 is formed on the cap layer 60 and one or more photo-etching process is conducted to remove part of the IMD layer 66 and part of the cap layer 60 to form at least a contact hole (not shown) exposing the hard mask 62. Next, conductive materials are deposited into the contact hole and planarizing process such as CMP is conducted to form metal interconnection 68 connecting the hard mask 62 underneath, and another stop layer 74 is formed on the surface of the metal interconnection 68 thereafter. Similar to the aforementioned metal interconnections 24, the metal interconnection 68 could be embedded within the IMD layer 66 according to a single damascene process or dual damascene process. For instance, the metal interconnection 68 could further include a barrier layer 70 and a metal layer 72, in which the barrier layer 70 could be selected from the group consisting of titanium (Ti), titanium nitride (TiN), tantalum (Ta), and tantalum nitride (TaN) and the metal layer 72 could be selected from the group consisting of tungsten (W), copper (Cu), aluminum (Al), titanium aluminide (TiAl), and cobalt tungsten phosphide (CoWP).
In this embodiment, the IMD layer 66 preferably include an ultra low-k (ULK) dielectric layer including but not limited to for example porous material or silicon oxycarbide (SiOC) and the stop layer 74 preferably includes nitrogen doped carbide (NDC), silicon nitride (SiN), silicon carbon nitride (SiCN), or combination thereof and most preferably includes SiN. This completes the fabrication of a semiconductor device according to an embodiment of the present invention.
Referring again to
Specifically, the MRAM device also includes an interface layer 42 disposed on the surface of the metal layer 36, in which the top surface of the interface layer 42 is even with top surface of the barrier layer 34 while the top surface of both the interface layer 42 and the barrier layer 34 is higher than the top surface of the IMD layer 28 and the bottom surface of the SOT layer 50 preferably contacts the barrier layer 34 and interface layer 42 directly but not contacting the IMD layer 28. In this embodiment, the interface layer 42 and the barrier layer 34 are preferably made of different materials, in which the interface layer 42 preferably includes metal nitride such as WN while the barrier layer 34 includes metal nitride such as TiN, but not limited thereto.
Referring to
Active devices such as metal-oxide semiconductor (MOS) transistors, passive devices, conductive layers, and interlayer dielectric (ILD) layer 16 could also be formed on top of the substrate 12. More specifically, planar MOS transistors or non-planar (such as FinFETs) MOS transistors could be formed on the substrate 12, in which the MOS transistors could include transistor elements such as gate structures (for example metal gates) and source/drain region, spacer, epitaxial layer, and contact etch stop layer (CESL). The ILD layer 16 could be formed on the substrate 12 to cover the MOS transistors, and a plurality of contact plugs could be formed in the ILD layer 16 to electrically connect to the gate structure and/or source/drain region of MOS transistors. Since the fabrication of planar or non-planar transistors and ILD layer is well known to those skilled in the art, the details of which are not explained herein for the sake of brevity.
Next, metal interconnect structures 18, 20 are sequentially formed on the ILD layer 16 to electrically connect the aforementioned contact plugs, in which the metal interconnect structure 18 includes an inter-metal dielectric (IMD) layer 22 and metal interconnections 24 embedded in the IMD layer 22, and the metal interconnect structure 20 includes a stop layer 26, an IMD layer 28, and metal interconnections 30, 32 embedded in the stop layer 26 and the IMD layer 28.
Similar to the aforementioned embodiment, each of the metal interconnections 24 from the metal interconnect structure 18 preferably includes a trench conductor and each of the metal interconnections 30, 32 from the metal interconnect structure 20 includes a via conductor. Preferably, each of the metal interconnections 24, 30, 32 from the metal interconnect structures 18, 20 could be embedded within the IMD layers 22, 28 and/or stop layer 26 according to a single damascene process or dual damascene process. For instance, each of the metal interconnections 24, 30, 32 could further include a barrier layer 34 and a metal layer 36, in which the barrier layer 34 could be selected from the group consisting of titanium (Ti), titanium nitride (TiN), tantalum (Ta), and tantalum nitride (TaN) and the metal layer 36 could be selected from the group consisting of tungsten (W), copper (Cu), aluminum (Al), titanium aluminide (TiAl), and cobalt tungsten phosphide (CoWP). Since single damascene process and dual damascene process are well known to those skilled in the art, the details of which are not explained herein for the sake of brevity. In this embodiment, the metal layers 36 in the metal interconnections 24 are preferably made of copper, the metal layers 36 in the metal interconnections 30, 32 are preferably made of tungsten, the IMD layers 22, 28 are preferably made of silicon oxide or ultra low-k (ULK) dielectric layer, and the stop layers 26 is preferably made of nitrogen doped carbide (NDC), silicon nitride, silicon carbon nitride (SiCN), or combination thereof.
Next, a spin orbit torque (SOT) layer 50 is formed on the surface of the metal interconnections 30, 32 and the IMD layer 28, in which the SOT layer 50 is serving as a channel for the MRAM device as the SOT layer 50 could include metals such as tantalum (Ta), tungsten (W), platinum (Pt), or hafnium (Hf) and/or topological insulator such as bismuth selenide (BixSe1-x).
Next, a doping process 40 is conducted to implant nitrogen based or oxygen based dopants into the surface of the SOT layer 50 to transform part of the SOT layer 50 into an interface layer 42. Preferably, nitrogen based dopants could include nitrogen gas (N2) or ammonia (NH3) while oxygen based dopants could include oxygen gas and if the SOT layer 50 were made of tungsten (W) or platinum (Pt) for instance, the SOT layer 50 after being implanted with nitrogen or oxygen based dopants through the doping process 40 would be transformed into an interface layer 42 made of metal nitride or metal oxide such as tungsten nitride (WN), platinum nitride (PtN), tungsten oxide (WO), or platinum oxide (PtO). According to an embodiment of the present invention, the thickness of the interface layer 42 could be equal to, slightly less than, or slightly greater than the thickness of the remaining SOT layer 50. If the thickness of the interface layer 42 were to be less than or greater than the thickness of the SOT layer 50, the thickness of the interface layer 42 is preferably to be within 20% of the thickness of the SOT layer 50.
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The cap layer 60 preferably includes metal such as Ta and the hard mask 62 preferably includes conductive material such as metal or metal nitride, in which metal could include Ti whereas metal nitride could include TiN. Nevertheless, the cap layer 60 or hard mask 62 could all include conductive or even dielectric material including but not limited to for example Ta, TaN, Ti, TiN, Pt, Cu, Au, Al, or combination thereof.
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Next, a cap layer 64 and an IMD layer 66 are formed on the MTJ 58, and one or more photo-etching process is conducted to remove part of the IMD layer 66 and part of the cap layer 64 to form at least a contact hole (not shown) exposing the hard mask 62. Next, conductive materials are deposited into the contact hole and a planarizing process such as CMP is conducted to form metal interconnection 68 connecting the hard mask 62 underneath, and another stop layer 74 is formed on the surface of the metal interconnection 68 thereafter. Similar to the aforementioned metal interconnections 24, the metal interconnection 68 could be embedded within the IMD layer 66 according to a single damascene process or dual damascene process. For instance, the metal interconnection 68 could further include a barrier layer 70 and a metal layer 72, in which the barrier layer 70 could be selected from the group consisting of titanium (Ti), titanium nitride (TiN), tantalum (Ta), and tantalum nitride (TaN) and the metal layer 72 could be selected from the group consisting of tungsten (W), copper (Cu), aluminum (Al), titanium aluminide (TiAl), and cobalt tungsten phosphide (CoWP).
In this embodiment, the IMD layer 66 preferably include an ultra low-k (ULK) dielectric layer including but not limited to for example porous material or silicon oxycarbide (SiOC) and the stop layer 74 preferably includes nitrogen doped carbide (NDC), silicon nitride (SiN), silicon carbon nitride (SiCN), or combination thereof and most preferably includes SiN. This completes the fabrication of a semiconductor device according to an embodiment of the present invention.
Referring again to
In contrast to the barrier layer 34 in the metal interconnections 30, 32 is extended to the surface of the IMD layer 28 as disclosed in the previous embodiment, the barrier layer 34 in the metal interconnections 30, 32 of this embodiment is disposed in the contact holes completely and the top surface of the barrier layer 34 is not higher than the top surface of the IMD layer 28 on two adjacent sides. In this embodiment, an interface layers 42 is disposed between the SOT layer 50 and the MTJ 58, in which the interface layer 42 could be made of a material of the SOT layer 50 underneath with nitride or oxide dopants. For instance, the interface layer 42 could include tungsten nitride (WN), platinum nitride (PtN), tungsten oxide (WO), or platinum oxide (PtO).
Those skilled in the art will readily observe that numerous modifications and alterations of the device and method may be made while retaining the teachings of the invention. Accordingly, the above disclosure should be construed as limited only by the metes and bounds of the appended claims.
Number | Date | Country | Kind |
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112123091 | Jun 2023 | TW | national |