In dynamic random access memory (hereinafter referred to as DRAM), the wiring pitch dimension is being reduced to increase the degree of integration. For this reason, the vertical dimension of structures is becoming greater relative to the horizontal dimension. For example, when structures that are long in the vertical direction are formed, stress occurs more readily in the horizontal direction, and in some cases, the upper portion of the structures where stress is readily concentrated, for example, is tapered to reduce the width dimension of the upper portion between adjacent structures. Thereafter, if an insulating material, for example, is embedded between the structures, the space between the structures may not be filled completely, and voids may be formed in some cases. If a conductive material, for example, is formed in a still later step, the conductive material may be formed in the voids and cause, for example, a short circuit between wiring to occur in some cases.
Various embodiments of the present disclosure will be explained below in detail with reference to the accompanying drawings. The following detailed description refers to the accompanying drawings that show, by way of illustration, specific aspects and various embodiments of the present disclosure. The detailed description provides sufficient detail to enable those skilled in the art to practice these embodiments of the present disclosure. Other embodiments may be utilized, and structure, logical and electrical changes may be made without departing from the scope of the present disclosure. The various embodiments disclosed herein are not necessary mutually exclusive, as some disclosed embodiments can be combined with one or more other disclosed embodiments to form new embodiments.
Hereinafter, a semiconductor device 1 and a method of forming the same according to the embodiment will be described with reference to the drawings. The semiconductor device 1 is described by taking DRAM as an example. In the description of the embodiment, common or related elements and elements that are substantially the same are denoted with the same signs, and the description thereof will be reduced or omitted. In the drawings, the dimensions and dimensional ratios of each portion in each of the drawings do not necessarily match the actual dimensions and dimensional rations in the embodiment. The vertical direction refers to the up and down direction in the case where the semiconductor substrate is on the downside, and the horizontal direction refers to the direction parallel to the surface of the semiconductor substrate.
As illustrated in
In the memory mats 2, a plurality of word lines 10, a plurality of bit lines 12 arranged to intersect the word lines 10, and a plurality of storage capacitors 20 are provided. The plurality of word lines 10 are arranged in parallel so as to elongate in the X direction of the drawings. The plurality of bit lines 12 are arranged in parallel so as to elongate in the Y direction of the drawings. The X direction and Y direction are substantially perpendicular. As illustrated in
A bit contact 12c is provided in a central part of the active regions 14. The bit line 12 is connected to the active region 14 through the bit contact 12c. Adjacent word lines 10 among the plurality of word lines 10 are arranged to sandwich the bit contact 12c.
As illustrated in
A first insulating film 34 is provided on the word line 10. The first insulating film 34 comprises silicon nitride (SiN), for example. A bit-line structure E is provided on the first insulating film 34. The bit-line structure E comprises a bit line 12, a second insulating film 36 provided below the bit line 12, and a third insulating film 38 provided above the bit line 12. The bit-line structure E also comprises a fourth insulating film 40 provided on side-walls of the second insulating film 36, the bit line 12, and the third insulating film 38, and a fifth insulating film 42 provided on a side-wall of the fourth insulating film 40. The second insulating film 36, the third insulating film 38, and the fifth insulating film 42 comprise silicon nitride (SiN). The fourth insulating film 40 is a low-k film comprising silicon oxide (SiO) or a silicon oxycarbide film (SiOC), for example. The bit-line structure E comprises a taper-shaped segment 44 and a protruding segment. The taper-shaped segment 44 is provided across the third insulating film 38, the fourth insulating film 40, and the fifth insulating film 42. Due to the taper-shaped segment 44, the width, in the X direction of the drawings, of the upper portion between adjacent bit-line structures E is widened. The distance D1, in the X direction, between the upper portions of adjacent bit-line structures E is greater than the distance D2, in the X direction, between the lower portions of adjacent bit-line structures E. The taper-shaped segments 44 are disposed on the word line 10. Between the taper-shaped segments 44 is a less taper-shaped segment that is not the taper-shaped segment 44. As illustrated in
A sixth insulating film 46 is provided to be embedded between adjacent bit-line structures E. The sixth insulating film 46 covers the upper and side surfaces of the bit-line structures E. A seventh insulating film 48 is provided on top of the sixth insulating film 46. On top of the seventh insulating film 48, a capacitive insulating film 20b and a top electrode 20c included in the storage capacitor 20 described later are provided. Each of the sixth insulating film 46 and the seventh insulating film 48 comprises an insulating material such as silicon nitride (SiN), for example.
As above, the semiconductor device 1 according to the embodiment comprises the bit-line structures E which are provided on top of the word lines 10 and on the upper and side portions of the bit lines 12 in the direction along the extension direction of the word lines 10. The bit-line structures E comprise the taper-shaped segments 44 at the upper portion thereof The sixth insulating film 46 is provided between and at the upper portion of adjacent bit-line structures E. The sixth insulating film 46 is embedded between adjacent bit-line structures E and has no voids.
As illustrated in
The semiconductor device 1 comprises the bit contact 12c that connects the bit line 12 with the active region 14. At the bit contact 12c, the bit line 12 and the active region 14 contact each other and are electrically connected. The storage capacitor 20 is provided above the bit-line structure E. The storage capacitor 20 comprises a bottom electrode 20a, a capacitive insulating film 20b, and a top electrode 20c. Each of the bottom electrode 20a and the top electrode 20c comprises a conductive material such as titanium nitride (TiN), for example. The capacitive insulating film 20b comprises a high-k insulating material such as zirconium oxide (ZrO2) or hafnium oxide (HfO2), for example.
The storage capacitor 20 is connected to the active region 14 through a first capacitive contact electrode 58 and a second capacitive contact electrode 60. The first capacitive contact electrode 58 and the second capacitive contact electrode 60 are arranged between adjacent bit-line structures E in the Y direction of the drawings. The first capacitive contact electrode 58 comprises a conductive material such as polysilicon (poly-Si) containing an impurity such as phosphorus (P), for example. The second capacitive contact electrode 60 comprises a conductive material such as titanium nitride (TiN), for example. The first capacitive contact electrode 58 and the second capacitive contact electrode 60 function, as a whole, as a capacitive contact electrode that connects the storage capacitor 20 to the active region 14.
Between the capacitive contact electrode and the bit line 12 adjacent thereto, the third insulating film 38, the fourth insulating film 40, and the fifth insulating film 42 are provided. At the bit contacts 12c, a bit contact insulating portion 56 and a liner insulating film 56b are additionally provided. The capacitive contact electrode and the bit lines 12 are insulated from each other by the third insulating film 38, the fourth insulating film 40, the fifth insulating film 42, the bit contact insulating portion 56, and the liner insulating film 56b. A ninth insulating film 62 is provided between adjacent pairs of the bottom electrodes 20a of storage capacitors 20 and the second capacitive contact electrodes 60. The pairs of the bottom electrodes 20a and the second capacitive contact electrodes 60 are insulated by the ninth insulating film 62 provided on top and partially on the side surfaces of the bit-line structures E. The ninth insulating film 62 comprises silicon nitride (SiN), for example.
When writing data to one of the memory cells 22, a potential that turns on the access transistor 18 is applied to the word line 10, while a low potential or a high potential corresponding to “0” or “1” of the data to be written is applied to the bit line 12. When reading out data from one of the memory cells 22, a potential that turns on the access transistor 18 is applied to the word line 10, and a data determination is made by having a sense amplifier connected to the bit line 12 sense the potential drawn from the storage capacitor 20 to the bit line 12.
Next,
First, the steps until the structure illustrated in
Next, trenches are formed in the regions where the word lines 10 are to be formed, and in the trench, the gate insulating film 32, the first word-conducting part 10a, the second word-conducting part 10b, and the first insulating film 34 are formed sequentially. When forming the trenches, the eighth insulating film 54 is removed. The gate insulating film 32 comprises silicon oxynitride (SiON), for example. The gate insulating film 32 is formed by thermal oxynitridation of the semiconductor substrate 30, for example. The first word-conducting part 10a comprises titanium (Ti), for example, and the second word-conducting part 10b comprises polysilicon (poly-Si) doped with an impurity such as phosphorus (P), for example.
The first word-conducting part 10a, the second word-conducting part 10b, and the first insulating film 34 are formed inside the trenches by repeatedly depositing respective films and etching back using anisotropic dry etching technology. The first word-conducting part 10a is deposited by CVD, for example, and then is etched back using anisotropic dry etching technology. The second word-conducting part 10b is deposited using CVD, for example, while introducing an impurity such as phosphorus (P) during the deposition, for example. Thereafter, etchback is performed using anisotropic dry etching technology. The first insulating film 34 comprises silicon nitride (SiN), for example. The first insulating film 34 is deposited by CVD, for example. Thereafter, etchback is performed using anisotropic dry etching technology.
As illustrated in
Thereafter, the second insulating film 36 is formed on top of the first insulating film 34 and on top of the eighth insulating film 54. The second insulating film 36 comprises an insulating material such as silicon nitride (SiN), for example. Next, as illustrated in
Next, a first bit-conducting part 12a, a second bit-conducting part 12b, and the third insulating film 38 are deposited. The first bit-conducting part 12a comprises a conductive material such as polysilicon (poly-Si) doped with an impurity such as phosphorus (P), for example. The second bit-conducting part 12b comprises a conductive material such as titanium nitride (TiN), for example. The third insulating film 38 comprises an insulating material such as silicon nitride (SiN), for example. The first bit-conducting part 12a, the second bit-conducting part 12b, and the third insulating film 38 are deposited by CVD, for example.
On the side surface of the first bit-conducting part 12a at the bit contacts 12c, the liner insulating film 56b and the bit contact insulating portion 56 are formed. The liner insulating film 56b comprises silicon oxide, for example, and is formed by CVD, for example. The bit contact insulating portion 56 comprises silicon nitride, for example, and is formed by CVD, for example.
Thereafter, known lithography technology and anisotropic dry etching technology are used to sequentially etch the third insulating film 38, the second bit-conducting part 12b, the first bit-conducting part 12a, and the second insulating film 36 to form the bit lines 12. As illustrated in
Next, the fourth insulating film 40 is formed to cover the upper surface of the first insulating film 34, the side surfaces of the second insulating film 36, the first bit-conducting part 12a, the second bit-conducting part 12b, and the third insulating film 38, and upper surface of the third insulating film 38. The fourth insulating film 40 comprises an insulating material such as silicon dioxide (SiO2) or a low-k film such as silicon oxycarbide (SiOC), for example. The fourth insulating film 40 is formed by CVD, for example. Next, the fourth insulating film 40 is etched back by anisotropic dry etching to remove the fourth insulating film 40 on top of the third insulating film 38 and top of the first insulating film 34. With this process, the fourth insulating film 40 is made to remain on the side surfaces of the second insulating film 36, the first bit-conducting part 12a, the second bit-conducting part 12b, and the third insulating film 38.
Next, the fifth insulating film 42 is formed to cover the top of the first insulating film 34, the side and upper surfaces of the fourth insulating film 40, and the upper surface of the third insulating film 38. The fifth insulating film 42 comprises silicon nitride, for example, and is formed by CVD, for example.
Next, as illustrated in
Next, as illustrated in
Next, the hard mask 68 is used as an etching mask to remove the second sacrificial insulating film 66 and a portion of the first sacrificial insulating film 64 in the opening by etching. The second sacrificial insulating film 66 is etched under etching conditions such that silicon nitride and silicon dioxide have substantially the same etching rate, for example. At this time, the upper portions of the third insulating film 38, the fourth insulating film 40, and the fifth insulating film 42 are also etched simultaneously. With this process, the bit-line structures E that cover the upper and side-surface portions of the bit lines 12 are formed. Next, the upper portion of the first sacrificial insulating film 64 is partially removed by an etching. This etching is performed under conditions such that the etching rate of the bit-line structures E is lower than the etching rate of the first sacrificial insulating film 64. Consequently, little or no etching of the bit-line structures E occurs, and only the upper portion of the first sacrificial insulating film 64 is etched. Through this etching, a recess F is formed in the upper portion of the first sacrificial insulating film 64.
Next, as illustrated in
Next, as illustrated in
Next, as illustrated in
At this time, for example, thermal stress due to heat treatment, stress due to the deposited films, or the like may cause the bit-line structure E on the left side in
Next, the sixth insulating film 46 is etched back by anisotropic dry etching to reduce the thickness of the sixth insulating film 46. The etchback is performed until the surface of the second sacrificial insulating film 66 is exposed. In this step, the thickness of the sixth insulating film 46 may be reduced using CMP instead of anisotropic dry etching. The vertical section of the portion along the line C-C in
Next, as illustrated in
Next, as illustrated in
Also, in the region illustrated in
In the region illustrated in
Next, polysilicon (poly-Si) containing phosphorus (P), for example, is deposited to fill the gap J and cover the third insulating film 38, the fourth insulating film 40, and the fifth insulating film 42. Polysilicon is deposited using CVD while introducing phosphorus, for example. Next, the polysilicon is etched back by anisotropic dry etching such that the polysilicon only remains in the lower portion of the gap J, thereby forming the first capacitive contact electrode 58. The first capacitive contact electrode 58 contacts the active region 14 in the lower portion and is electrically connected to the active region 14. According to the above, the structure illustrated in
Next, as illustrated in
The second capacitive contact electrode 60 and the bottom electrode 20a are formed by, for example, forming and then patterning titanium nitride using known lithography technology and anisotropic dry etching technology. The ninth insulating film 62 is formed by, for example, depositing and then etching back silicon nitride by anisotropic dry etching. The capacitive insulating film 20b and the top electrode 20c are formed by CVD, for example.
According to the above steps, the semiconductor device 1 according to the embodiment is formed.
According to the semiconductor device 1 and the method for forming the same according to the embodiment, the following effects are achieved.
In the semiconductor device 1, the taper-shaped segments 44 are provided in the upper portions of the bit-line structures E, and therefore voids are not formed in the sixth insulating film 46 embedded in the gap G between adjacent bit-line structures E. With this arrangement, the occurrence of a short circuit between adjacent memory cells 22 is suppressed, for example.
As above, DRAM is described as an example of the semiconductor device according to the embodiment, but the above description is merely one example and not intended to be limited to DRAM. Memory devices other than DRAM, such as static random access memory (SRAM), flash memory, erasable programmable read only memory (EPROM), magnetoresistive random access memory (MRAM), and phase-change memory, for example, are also applicable as the semiconductor device. Furthermore, devices other than memory, including a microprocessor and logic ICs such as an application specific integrated circuit (ASIC), for example, are also applicable as the semiconductor device according to the above embodiment. Furthermore, functional devices such as micro electro mechanical systems (MEMS) are also applicable as the semiconductor device according to the above embodiment.
Although various embodiments have been disclosed in the context of certain preferred embodiments and examples, it will be understood by those skilled in the art that the scope of the present disclosure extends beyond the specifically disclosed embodiments to other alternative embodiments and/or uses of the embodiments and obvious modifications and equivalents thereof. In addition, other modifications which are within the scope of this disclosure will be readily apparent to those of skill in the art based on this disclosure. It is also contemplated that various combination or sub-combination of the specific features and aspects of the embodiments may be made and still fall within the scope of the disclosure. It should be understood that various features and aspects of the disclosed embodiments can be combined with or substituted for one another in order to form varying modes of the disclosed embodiments. Thus, it is intended that the scope of at least some of the present disclosure should not be limited by the particular disclosed embodiments described above.