Semiconductor devices, for example, dynamic random access memories (hereinafter referred to as DRAM) are being promoted to be further miniaturized in order to increase data storage capacities thereof. For example, the size of the repeating pitch of wirings such as word lines, etc. of DRAM is reduced, and the distance between word lines is also reduced. However, when the diameters of contact holes to be connected to the word lines are increased during formation of the contact holes, adjacent word lines may be short-circuited.
Various embodiments of the present disclosure will be explained below in detail with reference to the accompanying drawings. The following detailed description refers to the accompanying drawings that show, by way of illustration, specific aspects and various embodiments of the present disclosure. The detailed description provides sufficient detail to enable those skilled in the art to practice these embodiments of the present disclosure. Other embodiments may be utilized, and structure, logical and electrical changes may be made without departing from the scope of the present disclosure. The various embodiments disclosed herein are not necessary mutually exclusive, as some disclosed embodiments can be combined with one or more other disclosed embodiments to form new embodiments.
A semiconductor device according to an embodiment and a method of manufacturing the same will be hereinafter described with reference to the drawings. In the following description, DRAM is exemplified as a semiconductor device. In the description of the embodiment, common or related elements, or substantially the same elements are designated by the same reference numerals, and the description thereof will be omitted. In the figures, the dimensions and dimensional ratios of the respective parts in the respective figures do not necessarily match the dimensions and dimensional ratios of those in the embodiment. The dimensions and dimensional ratios of the corresponding parts in the plan view and the vertical sectional view do not necessary match therebetween. A vertical direction in the following description means an up-and-down direction when a semiconductor substrate 1 is placed on a lower side.
A plurality of word lines 20 are arranged in parallel on each memory mat 2 so as to extend in an X direction as shown in the figures. A plurality of bit lines 18 are arranged in parallel on each memory mat 2 so as to extend in a Y direction in the figures. The respective word lines 20 are connected to a row decoder (not shown) at a peripheral portion thereof. A direction parallel to the word lines 20, in other words, the X direction in the figures is referred to as a word line direction. A direction parallel to the bit lines 18, that is, the Y direction in the figures is referred to as a bit line direction.
The respective bit lines 18 are connected to a column decoder (not shown) at a peripheral portion thereof. When performing reading/writing on the memory cells, a selected column address is input from a column address buffer (not shown) to the column decoder. Each of the plurality of bit lines 18 is paired with an associated one of the plurality of memory cells to control access to a plurality of corresponding memory cells out of the plurality of memory cells.
The access transistor 16 includes, for example, a metal-oxide-semiconductor field-effect transistor (MOSFET). The gate electrode of the access transistor 16 functions as a word line 20 of the DRAM. The word line 20 functions as a control line for controlling selection of the corresponding memory cell. One of the source and drain of the access transistor 16 is connected to a bit line 18, and the other is connected to a storage capacitor 24. The storage capacitor 24 includes a capacitor, and data is stored in the storage capacitor 24 by accumulating electric charges in the capacitor.
When data is written into a memory cell 15, a potential for turning on an access transistor 16 is applied to a word line 20, and a low potential or a high potential which corresponds to write data “0” or “1” is applied to a bit line 18. When data is read out from a memory cell 15, a potential for turning on an access transistor 16 is applied to a word line 20. As a result, a potential drawn out from a storage capacitor 24 to a bit line 18 is sensed by a sense amplifier connected to the bit line 18, thereby determining the data.
As shown in
The bit lines 18 and the word lines 20 are extended from the memory cell array region M in parallel to the dummy memory cell array regions N1 and N2 and the peripheral regions O1 and O2. Word line contact electrodes 201 and word line extraction electrodes 202 connected to the corresponding word lines 20 are provided in the X-direction peripheral region O1. The word line contact electrodes 201 have a plug-like shape (e.g., contact electrodes 201 may be referred to as “contact plugs”). Further, peripheral bit line contact electrodes 181 and bit line extraction electrodes 182 connected to the corresponding bit lines 18 are provided in the Y-direction peripheral region O2. The word line contact electrodes 201 are connected to every other word line 20. The peripheral bit line contact electrodes 181 are connected to every other bit line 18.
In the dummy memory cell array region N1, a plurality of dummy bit lines 19 are arranged at the same pitch as the bit lines 18 in parallel with the bit lines 18. In the dummy memory cell array region N2, a plurality of dummy word lines 21 are arranged at the same pitch as the word lines 20 in parallel with the word lines 20. As shown in
The longitudinal direction of the active regions 3 is tilted at a predetermined angle with respect to the bit lines 18. The word line 20 functions as gate electrodes of access transistors of the memory cell provided in the active region 3. As described later, the bit line 18 is connected to a central portion of the active region 3 via a bit line contact 17 shown in
The word lines 20 are arranged so as to extend linearly from the memory cell array region M to the X-direction peripheral region O1 across the dummy memory cell array region N1. The word line contact electrodes 201 which are electrically connected to the word lines 20 are provided in the X-direction peripheral region O1.
The edge region A2 has a layout obtained by interchanging the arrangement of the word line contact electrodes 201 with respect to the arrangement of the edge region A1. In the edge region A2, the word line contact electrodes 201 are connected to word lines 20 to which the word line contact electrodes 201 are not connected in the edge region A1. Similar relationship is established in the edge region A3 and the edge region A4. The edge region A3 has a layout obtained by interchanging the arrangement of the peripheral bit line contact electrodes 181 with respect to the arrangement of the edge region A1. In the edge region A3, the peripheral bit line contact electrodes 181 are connected to bit lines 18 to which the peripheral bit line contact electrodes 181 are not connected in the edge region A1. Similar relationship is established in the edge region A2 and the edge region A4. Assuming that the plurality of word lines 20 are arranged so that even-numbered word lines 20 and odd-numbered word lines 20 are repeated, the word line contact electrodes 201 and the word line extraction electrodes 202 are connected to the even-numbered word lines 20 in the peripheral region O1. The word line contact electrodes 201 and the word line extraction electrodes 202 are connected to the odd-numbered word lines 20 in the peripheral region of the edge region A2. In the peripheral region O1, a fourth insulating film 8 is arranged over the plurality of word lines 20. In the peripheral region O1, the fourth insulating film 8 surrounds the plurality of word line contact electrodes 201 and insulating walls 36.
As shown in
The first insulating film 5 is provided with the word lines 20 in trenches provided in the first insulating film 5, and the second insulating film 6 is provided on the word lines 20. The word line contact electrodes 201 and the word line extraction electrodes 202 are provided so as to be connected to every other word line 20. The eighth insulating film 12 is provided so as to cover the word line extraction electrodes 202. The insulating walls 36 are provided over the word lines 20. The insulating walls 36 are provided so as to extend continuously across the memory cell array region M, the dummy memory cell array region N1, and the peripheral region O1. The word line contact electrodes 201 penetrate the insulating walls 36 and reach the top surfaces of the word lines 20. Each of the word line contact electrodes 201 is connected to an associated one of the word lines. The insulating walls 36 are provided at least in the peripheral region O1.
As shown in
The gate electrode 14 is configured by laminating a first conductive portion 142 and a second conductive portion 143. A cap insulating film 144 is laminated on the second conductive portion 143. The peripheries of the gate electrode 14 and the cap insulating film 144 are covered with a gate insulating film 141 to insulate the semiconductor substrate 1 and the gate electrode 14 from each other.
The storage capacitor 24 comprises a lower electrode 241, a capacitive insulating film 242, and an upper electrode 243. The capacitive insulating film 242 is arranged between the lower electrode 241 and the upper electrode 243. A capacitor is formed by the lower electrode 241, the capacitive insulating film 242, and the upper electrode 243. The lower electrode 241 is connected to the pad electrode 253.
The lower electrode 241 is electrically connected to the active region 3 via the pad electrode 253, the second capacitive contact electrode 252, and the first capacitive contact electrode 251. The cap insulating film 144 is arranged along the gate electrode 14 extending in the Y direction, and electrically insulates and separates the first capacitive contact electrode 251 and the second capacitive contact electrode 252 arranged adjacent to each other.
As shown in
Next, a method of manufacturing the semiconductor device according to the embodiment will be described with reference to
First, as shown in
For example, a silicon monocrystal substrate is used as the semiconductor substrate 1. The first insulating film 5 is formed by forming a groove in the peripheral regions O1 and O2 of the semiconductor substrate 1 and filling the groove with an insulator comprising, for example, silicon nitride (SiN), silicon dioxide (SiO2), or the like. Trenches in which the word lines 20 are formed are formed by using known lithography technique and dry etching technique. The dry etching is performed under a condition that the etching rates of the semiconductor substrate 1 and the first insulating film 5 are substantially equal to each other.
The gate insulating film 141 contains, for example, silicon dioxide. The gate insulating film 141 is formed, for example, by subjecting the semiconductor substrate 1 to thermal oxidation. The first conductive portion 142 includes a conductive material, for example, includes titanium nitride (TiN). The second conductive portion 143 includes a conductive material, for example, includes polysilicon (Si) doped with impurities such as phosphorus (P) or arsenic (As). The cap insulating film 144 includes, for example, silicon nitride (SiN). The first conductive portion 142, the second conductive portion 143, and the cap insulating film 144 are formed, for example, by forming conductive materials in the trenches using a known chemical vapor deposition (CVD) and then performing etch-back by anisotropic dry etching.. In some embodiments, the trenches are filled with a first conductive film, which is then etched back to a middle of the trenches in the memory cell array region to expose an upper portion of the trenches in the memory cell array region. The upper portion of the trenches in the memory cell array region is filled with a second conductive film. The first conductive film in the trenches represents first conductive portions 142, and the second conductive film in the upper portion of the trenches represents second conductive portions 143.
As shown in
As shown in
As shown in
Further, a resist 44 is formed so as to cover the peripheral regions O1 and O2. The resist 44 is formed by using a known lithography technique. The resist 44 is not formed over the memory cell array region M and the dummy memory cell array regions N1 and N2, and is opened over these regions.
Next, as shown in
By this step, trenches 42 are formed just above the word lines 20 in the memory cell array region M, the dummy memory cell array regions N1 and N2, and the X-direction peripheral region O1.
Next, as shown in
As shown in
The top surfaces and side surfaces of the bit line 18 are surrounded by a bit line insulating film 18a. The bit line insulating film 18a comprises a laminated film of a first bit line insulating film 183, a second bit line insulating film 184, and a third bit line insulating film 185. The first bit line insulating film 183 is provided on the upper portion of the bit line 18 so as to extend in the Z direction. The second bit line insulating film 184 and the third bit line insulating film 185 are provided so as to be laminated on the side surfaces of the bit line 18 and the first bit line insulating film 183.
The first bit line insulating film 183 and the third bit line insulating film 185 contain silicon nitride. The second bit line insulating film 184 includes a silicon acid carbide (SiOC) which is a low-K film having a low relative permittivity. A fifth insulating film 9 is provided between the bit line insulating films 18a. In the steps described with respect to
Next, as shown in
Next, anisotropic dry etching is performed on the memory cell array region M with the resist 46 as a mask. This anisotropic dry etching is performed under a condition that the etching rates of silicon nitride and silicon are low and the etching rate of silicon dioxide is higher than those of silicon nitride and silicon. As shown in
Next, the resist 46 is removed as shown in
The polysilicon 25a is etched back to the extent that upper parts 361 of the insulating walls 36 are exposed and lower parts of the insulating walls 36 are filled with the remaining polysilicon 25a. The remaining polysilicon 25a will serve as the first capacitive contact electrodes 251. The first capacitive contact electrodes 251 are connected to the active regions 3.
Next, as shown in
The insulating walls 36, the third insulating film 7, and the second insulating film 6 are etched in the word line contact holes 204 by the above step. The seventh insulating film 11 and the sixth insulating film 10 are etched at the upper portions of the word line contact holes 204. The top surfaces of the word lines 20 are exposed at the bottom portions of the word line contact holes 204.
In this etching, the etching rate of the fifth insulating film 9 containing silicon dioxide is low, so that displacement of the word line contact holes 204 in the lateral direction is suppressed even if the position of a resist for forming the word line contact holes 204 is displaced. Therefore, even if a word line contact hole 204 expands to an adjacent word line 20 due to a pretreatment performed before a film of a conductive material is formed in the word line contact holes 204, it is possible to suppress occurrence of a short circuit between adjacent word lines 20 when the conductive material is filled in the word line contact holes 204.
Next, as shown in
Next, etch back is performed on this conductive material film. The film formation of the conductive material is performed, for example, by using the CVD technique. For example, tungsten (W) is used as the conductive material. For example, anisotropic dry etching can be used as the etch back.
The etch back is performed to the extent that the upper surface of the conductive material is flush with the upper surfaces of the insulating walls 36 and the sixth insulating film 10. The upper surfaces of the insulating walls 36 and the sixth insulating film 10 are exposed by the etch back. The conductive material remaining in the word line contact holes 204 will serve as the word line contact electrodes 201.
In the memory cell array region M, the conductive material is likewise etched back to the extent that the upper surface of the conductive material is flush with the upper surfaces of the insulating walls 36. The conductive material remaining in trenches at the upper portions of the first capacitive contact electrodes 251 will serve as the second capacitive contact electrodes 252. In the memory cell array region M, for example, cobalt silicide (CoSi) may be formed between the first capacitive contact electrode 251 and the second capacitive contact electrode 252. Before the formation of cobalt silicide, a pretreatment using diluted hydrogen fluoride is performed. The first capacitive contact electrodes 251, the second capacitive contact electrodes 252, and the pad electrodes 253 will serve as electrodes for connecting the storage capacitors 24 and the active regions 3 as described later. The insulating walls 36 have a function of insulating and separating the adjacent first and second capacitive contact electrodes 251 and 252 from each other.
As shown in
Next, as shown in
Further, in the memory cell array region M, the pad electrodes 253 to be connected to the second capacitive contact electrodes 252 are formed on the second capacitive contact electrodes 252. The pad electrodes 253 include a conductive material, for example, tungsten (W). The pad electrodes 253 are formed by patterning a conductive material using a known lithography technique and a known anisotropic dry etching technique. Further, the pad electrodes 253 may be formed by using a known double patterning technique or a quad patterning technique. The conductive material is formed, for example, by using the CVD technique. During the formation of the pad electrodes 253, only the memory cell array region M can be processed, for example, by forming appropriate masks on the peripheral regions O1 and O2 and the dummy memory cell array regions N1 and N2.
Next, as shown in
The storage capacitors 24 are formed by the following steps. The eighth insulating film 12 is formed in a region comprising the memory cell array region M. The eighth insulating film 12 contains silicon dioxide, and is formed, for example, by the CVD technique. Next, a hall hole reaching an upper part of each pad electrode 253 is formed. The hall holes are formed by known lithography technique and anisotropic dry etching.
Next, the lower electrodes 241 are filled in the hall holes. Next, the eighth insulating film 12 surrounding the lower electrodes 241 is etched and removed to the extent that it has a height at which the pad electrodes 253 have not yet been exposed. The etching of the eighth insulating film 12 is performed, for example, by using isotropic dry etching or wet etching using buffered hydrofluoric acid (BHF). The lower electrode 241 includes a conductive material, for example titanium nitride (TiN). The lower electrode 241 is formed, for example, by the CVD technique. The upper electrodes 243 are connected to a potential (not shown) and function as plate electrodes of the storage capacitors 24.
Next, the capacitive insulating film 242 is formed so as to cover the lower electrodes 241. The capacitive insulating film 242 contains, for example, hafnium oxide (HfO2). The capacitive insulating film 242 is formed, for example, by using the CVD technique. Next, the upper electrodes 243 are formed so as to integrally cover the plurality of lower electrodes 241 covered with the capacitive insulating film 242. The upper electrodes 243 include a conductive material, for example, titanium nitride (TiN). The upper electrodes 243 are formed, for example, by the CVD technique.
The semiconductor device according to the embodiment is formed by the above steps.
As described above, in the semiconductor device according to the embodiment, the insulating walls 36 are formed just above the word lines 20 not only in the memory cell array region M, but also in the X-direction peripheral region O1. When the word line contact electrodes 201 to be connected to the word lines 20 are formed in the X-direction peripheral region O1, the word line contact holes 204 are formed under a condition that the etching rate of the insulating walls 36 is high, whereby it is suppressed that the word line contact holes 204 are displaced from the word lines 20. As a result, it is possible to suppress occurrence of a short circuit between the adjacent word lines 20. As a result, the manufacturing yield of the semiconductor device can be enhanced, and the reliability of the semiconductor device can be enhanced.
As described above, the semiconductor device according to the embodiment has been described by exemplifying DRAM. However, this is an example, and there is no intention of limiting to DRAM. Memory devices other than DRAM, for example, a static random access memory (SRAM), a flash memory, an erasable programmable read only memory (EPROM), a magnetoresistive random access memory (MRAM), a phase-change memory and the like may be applied as the semiconductor device.
Although various embodiments have been disclosed in the context of certain preferred embodiments and examples, it will be understood by those skilled in the art that the scope of the present disclosure extends beyond the specifically disclosed embodiments to other alternative embodiments and/or uses of the embodiments and obvious modifications and equivalents thereof. In addition, other modifications which are within the scope of this disclosure will be readily apparent to those of skill in the art based on this disclosure. It is also contemplated that various combination or sub-combination of the specific features and aspects of the embodiments may be made and still fall within the scope of the disclosure. It should be understood that various features and aspects of the disclosed embodiments can be combined with or substituted for one another in order to form varying mode of the disclosed embodiments. Thus, it is intended that the scope of at least some of the present disclosure should not be limited by the particular disclosed embodiments described above.