The semiconductor integrated circuit (IC) industry has experienced exponential growth. Technological advances in IC materials and design have produced generations of ICs where each generation has smaller and more complex circuits than the previous generation. In the course of IC evolution, functional density (i.e., the number of interconnected devices per chip area) has generally increased while geometry size (i.e., the smallest component (or line) that can be created using a fabrication process) has decreased. This scaling down process generally provides benefits by increasing production efficiency and lowering associated costs. Such scaling down has also increased the complexity of processing and manufacturing ICs.
Therefore, there is a need to improve processing and manufacturing ICs.
Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is noted that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
Further, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “over,” “on,” “top,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
Various embodiments to be described below relate generally to using a solid phase epitaxy regrowth (SPER) process to increase dopant activation, thereby reducing electrical resistance between two components. In some embodiments, the SPER process includes an amorphization process and an annealing process. The SPER process may be performed on one or more layers of a source/drain region. As a result, contact resistance between the source/drain region and a conductive feature and/or contact resistance between the source/drain region and a channel region (i.e., one or more semiconductor layers) is reduced.
While the embodiments of this disclosure are discussed with respect to nanostructure channel FETs, such as gate all around (GAA) FETs, for example Horizontal Gate All Around (HGAA) FETs or Vertical Gate All Around (VGAA) FETs, implementations of some aspects of the present disclosure may be used in other processes and/or in other devices, such as planar FETs, Fin-FETs, and other suitable devices. A person having ordinary skill in the art will readily understand other modifications that may be made are contemplated within the scope of this disclosure. In cases where gate all around (GAA) transistor structures are adapted, the GAA transistor structures may be patterned by any suitable method. For example, the structures may be patterned using one or more photolithography processes, including double-patterning or multi-patterning processes. Generally, double-patterning or multi-patterning processes combine photolithography and self-aligned processes, allowing patterns to be created that have, for example, pitches smaller than what is otherwise obtainable using a single, direct photolithography process. For example, in one embodiment, a sacrificial layer is formed over a substrate and patterned using a photolithography process. Spacers are formed alongside the patterned sacrificial layer using a self-aligned process. The sacrificial layer is then removed, and the remaining spacers may then be used to pattern the GAA structure.
The substrate 101 may include various regions that have been doped with impurities (e.g., dopants having p-type or n-type conductivity). Depending on circuit design, the dopants may be, for example phosphorus for an n-type field effect transistors (NFET) and boron for a p-type field effect transistors (PFET).
The stack of semiconductor layers 104 includes alternating semiconductor layers made of different materials to facilitate formation of nanostructure channels in a multi-gate device, such as nanostructure channel FETs. In some embodiments, the stack of semiconductor layers 104 includes first semiconductor layers 106 and second semiconductor layers 108. In some embodiments, the stack of semiconductor layers 104 includes alternating first and second semiconductor layers 106, 108. The first semiconductor layers 106 and the second semiconductor layers 108 are made of semiconductor materials having different etch selectivity and/or oxidation rates. For example, the first semiconductor layers 106 may be made of Si and the second semiconductor layers 108 may be made of SiGe. In some examples, the first semiconductor layers 106 may be made of SiGe and the second semiconductor layers 108 may be made of Si. Alternatively, in some embodiments, either of the semiconductor layers 106, 108 may be or include other materials such as Ge, SiC, GaAs, GaP, InP, InAs, InSb, GaAsP, AlInAs, AlGaAs, InGaAs, GaInP, GaInAsP, or any combinations thereof.
The first and second semiconductor layers 106, 108 are formed by any suitable deposition process, such as epitaxy. By way of example, epitaxial growth of the layers of the stack of semiconductor layers 104 may be performed by a molecular beam epitaxy (MBE) process, a metalorganic chemical vapor deposition (MOCVD) process, and/or other suitable epitaxial growth processes.
The first semiconductor layers 106 or portions thereof may form nanostructure channel(s) of the semiconductor device structure 100 in later fabrication stages. The term nanostructure is used herein to designate any material portion with nanoscale, or even microscale dimensions, and having an elongate shape, regardless of the cross-sectional shape of this portion. Thus, this term designates both circular and substantially circular cross-section elongate material portions, and beam or bar-shaped material portions including, for example, a cylindrical in shape or substantially rectangular cross-section. The nanostructure channel(s) of the semiconductor device structure 100 may be surrounded by a gate electrode. The semiconductor device structure 100 may include a nanostructure transistor. The nanostructure transistors may be referred to as nanosheet transistors, nanowire transistors, gate-all-around (GAA) transistors, multi-bridge channel (MBC) transistors, or any transistors having the gate electrode surrounding the channels. The use of the first semiconductor layers 106 to define a channel or channels of the semiconductor device structure 100 is further discussed below.
Each first semiconductor layer 106 may have a thickness in a range between about 5 nm and about 30 nm. Each second semiconductor layer 108 may have a thickness that is equal, less, or greater than the thickness of the first semiconductor layer 106. In some embodiments, each second semiconductor layer 108 has a thickness in a range between about 2 nm and about 50 nm. Three first semiconductor layers 106 and three second semiconductor layers 108 are alternately arranged as illustrated in
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The sacrificial gate dielectric layer 132 may include one or more layers of dielectric material, such as a silicon oxide-based material. The sacrificial gate electrode layer 134 may include silicon such as polycrystalline silicon or amorphous silicon. The mask layer 136 may include more than one layer, such as an oxide layer and a nitride layer. The portions of the fin structures 112 that are covered by the sacrificial gate electrode layer 134 of the sacrificial gate structure 130 serve as channel regions for the semiconductor device structure 100.
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After removing edge portions of each second semiconductor layers 108, a dielectric layer is deposited in the cavities to form dielectric spacers 144. The dielectric spacers 144 may be made of a low-K dielectric material, such as SiON, SiCN, SiOC, SiOCN, or SiN. The dielectric spacers 144 may be formed by first forming a conformal dielectric layer using a conformal deposition process, such as ALD, followed by an anisotropic etching to remove portions of the conformal dielectric layer other than the dielectric spacers 144. The dielectric spacers 144 are protected by the first semiconductor layers 106 during the anisotropic etching process. The remaining second semiconductor layers 108 are capped between the dielectric spacers 144 along the X direction.
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In some embodiments, a cap layer (not shown) may be formed on the third semiconductor material 156. The cap layer may include a semiconductor material. In some embodiments, the cap layer includes the same material as the third semiconductor material. The cap layer may be epitaxially grown from the third semiconductor material 156.
In some embodiments, the second and third semiconductor materials 154, 156 may be in-situ doped during growth. If the dopant concentrations of the second and third semiconductor materials 154, 156 are greater than the above-mentioned respective ranges, the quality of the second and third semiconductor material 154, 156 may be negatively affected. Thus, subsequent processes may be performed to increase the dopant concentration and/or dopant activation in order to decrease electrical contact resistance.
The second semiconductor material 154 and the third semiconductor material 156 together may be the source/drain (S/D) region. In this disclosure, a source region and a drain region are interchangeably used, and the structures thereof are substantially the same. Furthermore, source/drain region(s) may refer to a source or a drain, individually or collectively dependent upon the context. In some embodiments, p-type S/D regions and n-type S/D regions may be formed separately using one or more mask layers. In some embodiments, the second semiconductor material 154 and the third semiconductor material 156 are crystalline semiconductor materials.
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After the ILD layer 164 is formed, a planarization operation, such as CMP, is performed on the semiconductor device structure 100 until the sacrificial gate electrode layer 134 is exposed, as shown in
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The second semiconductor layers 108 may be removed using a selective wet etching process. In cases where the second semiconductor layers 108 are made of SiGe and the first semiconductor layers 106 are made of Si, the chemistry used in the selective wet etching process removes the SiGe while not substantially affecting Si, the dielectric materials of the first gate spacers 138, and the dielectric spacers 144. In one embodiment, the second semiconductor layers 108 can be removed using a wet etchant such as, but not limited to, hydrofluoric (HF), nitric acid (HNO3), hydrochloric acid (HCl), or phosphoric acid (H3PO4).
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It is understood that the semiconductor device structure 100 may undergo further processes, such as cut metal gate (CMG) process and/or continuous poly on diffusion edge (CPODE) process. The CMG process separates the gate electrode layer 172 into multiple segments that can be individually controlled. The CPODE process forms isolation between devices.
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As described above, in order to reduce the electrical contact resistance, one or more processes may be performed to increase dopant concentration and/or dopant activation in the third semiconductor material 156 and/or the second semiconductor material 154. In some embodiments, a SPER process is performed on the second and/or third semiconductor material 154, 156. The SPER process may include an amorphization process and an annealing process. In some embodiments, a portion of the third semiconductor material 156, which is a crystalline semiconductor material, is amorphized by the amorphization process. For example, impurities may be injected into the third semiconductor material 156 to form an amorphous region 186, as shown in
In some embodiments, the amorphization process is an ion implantation process which introduces first species into the exposed third semiconductor material 156, such that at least a top portion of the third semiconductor material 156 is converted into an amorphous structure (i.e., the amorphous region 186). The first species of the ion implantation process may be a group IV element, such as C, Si, Ge; a group III element, such as B, Al, Ga, In; a group V element, such as P, As, Sb, or a group VIII element, such as He, Ar, Xe. The implantation process may have an implantation energy ranging from about 0.3 keV to about 60 keV, a dosage greater than about 1×1013 cm−2, and a processing temperature ranging from about-150 degrees Celsius to about 500 degrees Celsius.
In some embodiments, a dopant implantation process may be performed to introduce a second species (e.g., dopants) into the third semiconductor material 156. In some embodiments, the dopant implantation process is performed after the amorphization process. For p-type FETs, the second species may include B, A. Ga, or In. For n-type FETs, the second species may include As, P, or Sb. In an example embodiment, the second species (e.g., B or As) is implanted using an energy in a range between about 0.3 keV and about 20 keV, with a dosage in a range from about 1×1012 cm−2 to about 1×1017 cm−2. The dopant implantation process may further include an implantation tilt angle ranging from about 0 degrees to about 15 degrees. As a result of the dopant implantation process, the dopant concentration of the amorphous region 186 is increased, which leads to decreased contact resistance. In some embodiments, the second species are located within the amorphous region 186, because the amorphous region 186 can prevent the second species from channeling through the spaces between the crystal lattice structure.
In some embodiments, the dopant implantation process is performed before the amorphization process. For example, the dopant implantation process is performed to form a doped region in the third semiconductor material 156, and the doped region is located at the top of the third semiconductor material 156 and is exposed to the opening 180. The doped region of the third semiconductor material 156 has a dopant concentration substantially greater than the dopant concentration of the rest of the third semiconductor material.
In some embodiments, the second species (e.g., dopants) may be also introduced into the second semiconductor material 154 by the dopant implantation process. As a result, the dopant concentration of the second semiconductor material 154 in contact with the topmost first semiconductor layers 106 is increased, while the dopant concentration of the second semiconductor material 154 in contact with the first semiconductor layers 106 located below the topmost first semiconductor layers 106 is not affected by the dopant implantation process. Thus, in some embodiments, the dopant concentration of the second semiconductor material 154 in contact with the topmost first semiconductor layers 106 is substantially greater than the dopant concentration of the second semiconductor material 154 in contact with the first semiconductor layers 106 located below the topmost first semiconductor layers 106. Increasing the dopant concentration in the second semiconductor material 154 may lead to reduced electrical contact resistance between the second semiconductor material 154 and the first semiconductor layer 106.
In some embodiments, the second species is introduced into the second semiconductor material 154, such as the second semiconductor material 154 in contact with the topmost first semiconductor layers 106, but not the third semiconductor material 156. In other words, the dopant implantation process is performed to increase the dopant concentration of the second semiconductor material 154 in contact with the topmost first semiconductor layers 106 without increasing the dopant concentration of the third semiconductor material 156. The implantation tilt angle may range from about 15 degrees to about 45 degrees.
In some embodiments, because the dopant implantation process is performed before the amorphization process, the second species is not limited to being located within the amorphous region 186. As a result, the reducing of the contact resistance between the third semiconductor material 156 and a subsequently formed conductive feature and between the second semiconductor material 154 and the first semiconductor material 106 can be fine-tuned. In some embodiments, the height along the Z-direction of the doped region formed by the dopant implantation process is substantially greater than the height of the amorphous region 186. In some embodiments, when the amorphization process is performed after the dopant implantation process, the process temperature of the amorphization process is lower than the process temperature of the amorphization process when performed before the dopant implantation process. A lower process temperature may reduce the risk of damaging the gate electrode layers 172.
In some embodiments, the dopant implantation process is not performed.
After the amorphization process (with or without the dopant implantation process), the annealing process is performed to recrystallize the amorphous region 186. In some embodiments, the annealing process recrystallize any of the source/drain regions that were amorphous. For example, the annealing process may reorder the crystal structure of the amorphous region 186, redistribute the dopant atoms (e.g., first and second species) by incorporating the dopant atoms into the crystalline lattice of the third semiconductor material 156. Ordering the crystal lattice can reduce resistivity of the doped regions. Furthermore, the SPER process, which includes the amorphization process to convert a crystalline region to an amorphous region and the annealing process to recrystallize the amorphous region, can boost dopant activation. One of the reasons that the SPER process can boost dopant activation is that the dopant solubility after the SPER process may be greater than the maximum equilibrium solid solubility. Higher dopant activation also reduces resistivity. In addition, the high dopant concentration (if the n-type or p-type dopant is used in the amorphization process or the dopant implantation process is performed) can lead to reduced resistivity.
In some embodiments, as shown in
Similarly, in some embodiments, the first species of the amorphization process and the second species of the dopant implantation process (if performed) are the same as the first dopant, and the amorphous region 186 includes the first dopant and a second dopant concentration substantially greater than the first dopant concentration. In some embodiments, the first species of the amorphization process is different from the first dopant and the second species of the dopant implantation process is the same as the first dopant. As a result, the amorphous region 186 includes the first dopant and the first species, and the dopant concentration of the first dopant is substantially the same as the first dopant concentration of the crystalline region 190. In some embodiments, the first species of the amorphization process and the second species of the dopant implantation process are different from the first dopant, and the amorphous region 186 includes the first dopant, the first species, and the second species, and the dopant concentration of the first dopant is substantially the same as the first dopant concentration of the crystalline region 190.
The annealing process may be any suitable thermal process, such as rapid thermal annealing (RTA), millisecond annealing (MSA), microsecond annealing, flash annealing, laser annealing, or melting laser annealing. The annealing process may have an annealing temperature ranging from about 200 degrees Celsius to about 1200 degrees Celsius.
In some embodiments, the MSA process utilizes a laser anneal process to achieve the annealing times in the range of milliseconds. It is contemplated that a flash lamp annealing process or any advanced process using suitable optical radiation for performing an anneal for a very short amount of time, e.g., on a millisecond time scale, may also be used.
The laser anneal process may be performed by scanning a laser beam from an energy source across the exposed surface of the third semiconductor material 156. The laser beam may be applied/scanned sequentially to portions of the third semiconductor material 156. The energy source may be any type of laser such as gas laser, excimer laser, solid-state laser, fiber laser, semiconductor laser, etc. The laser beam may have a constant energy flux. The laser beam may be operated at a desired range of wavelengths and intensities. In some embodiments, the laser beam may have a wavelength in a range from about 200 nm to about 20 micrometers, such as from about 700 nm to about 1200 nm, for example about 950 nm to about 1000 nm, and an energy density in a range from about 0.1 W/cm2 to about 10 W/cm2. The laser anneal process can be performed so that each portion having the laser beam incident thereon can be momentarily elevated to a temperature of about 800 degrees Celsius or greater, such as about 850 degrees Celsius or greater, for example in a range from about 900 degrees Celsius to about 1200 degrees Celsius. During the laser anneal process, the chamber pressure may be maintained at about 10 Torr to about 850 Torr. The dwell time of the laser beam may be in a range from about 0.01 milliseconds to about 10 milliseconds, such as about 0.5 milliseconds to about 5 milliseconds, for example 0.1 milliseconds to 3 milliseconds.
As described above, in some embodiments, the entire amorphous region 186 shown in
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The silicide layer 192 may be formed by any suitable process. In some embodiments, a metal layer (not shown) is first formed on the semiconductor device structure 100. The metal layer may include Ti, Ni, Ru, Co, W, or other suitable metal. In some embodiments, the metal layer is a multi-layer structure. The multi-layer structure may include a metal layer and a metal nitride or metal oxide layer. The metal layer may be deposited by any suitable process, such as ALD, CVD, or PVD. After the metal layer deposition, an annealing process is performed to react the amorphous region 186 with the metal layer, thereby forming the silicide layers 192. In some embodiments, the entire amorphous region 186 is converted to the silicide layer 192. In other words, no amorphous region remains in the third semiconductor material 156 after the formation of the silicide layers 192. The silicide layer 192 may include any suitable material, such as NiSi, TiSi, CoSi, RuSi, or wSi.
As described above, in some embodiments, voids may be formed near the top of the third semiconductor material 156 as a result of growing the third semiconductor material 156 from the second semiconductor material 154. In some embodiments, voids may be formed at the interface between the third semiconductor material 156 and the silicide layer 192, if the SPER process is not performed. By performing the SPER process, which is forming the amorphous region 186 and partially or fully recrystallizing the amorphous region 186, voids formed near the top of the third semiconductor material 156 may be substantially removed, and there would be no or less voids formed at the interface between the third semiconductor material 156 and the silicide layer 192. In some embodiments, void defect may be decreased to less than about 10 percent, such as less than about five percent, for example less than about one percent (void per silicide to S/D region).
In some embodiments, the silicide layer 192, which is converted from the amorphous region 186, includes the first dopant (as a result of the in-situ doping during the growth of the third semiconductor material 156), the first species (as a result of the amorphization process), and optionally the second species (as a result of the dopant implantation process). In some embodiments, the first dopant and the first species (or the second species) include the same material. For example, the first dopant and the first species (or the second species) are boron. Boron from the epitaxy growth process includes two isotopes: about 20 percent of 10B and about 80 percent of 11B. Boron from the ion implantation process of the amorphization process or the dopant implantation process includes 100 percent of 11B. Thus, in some embodiments, the silicide layer 192 includes a dopant having a first percentage of a first isotope and a second percentage of a second isotope. The crystalline region 190 of the third semiconductor material 156 includes the dopant having the third percentage of the first isotope and a fourth percentage of the second isotope. The first percentage of the first isotope may be substantially smaller than the third percentage of the first isotope, and the second percentage of the second isotope may be substantially greater than the fourth percentage of the second isotope. In some embodiments, the first percentage of the first isotope ranges from about 0 percent to about 5 percent, the second percentage of the second isotope ranges from about 95 percent to about 100 percent, the third percentage of the first isotope ranges from about 15 percent to about 25 percent, and the fourth percentage of the second isotope ranges from about 75 percent to about 85 percent.
After the formation of the silicide layer 192, the portion of the metal layer (not shown) not reacted may be removed by any suitable process, such as a selective etch process. A conductive feature is then formed in the opening 180 in contact with the silicide layer 192. The contact resistance between the S/D region (the third semiconductor material 156) and the conductive feature is reduced as a result of the thicker silicide layer 192, higher dopant activation in the crystalline region 188 of the third semiconductor material 156, and higher dopant concentration in the crystalline region 188 of the third semiconductor material 156.
In some embodiments, the contact resistance between a conductive feature and an n-type FET is different from the contact resistance between a conductive feature and a p-type FET. For example, in some embodiments, p-type FET has a higher contact resistance than the n-type FET. Thus, in some embodiments, the SPER process and the optional dopant implantation process are performed to one type of FET, while the other type of FET is covered by a mask layer during the SPER process and the optional dopant implantation process. In some embodiments, as shown in
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Furthermore, the third semiconductor material 156 located in the first region 202 may include a crystalline region 188 (
By performing the SPER process and the optional dopant implantation process on one of the PMOS and NMOS regions, the contact resistance between the conductive feature and the S/D region in both the NMOS region and the PMOS region may be substantially the same.
In some embodiments, the SPER process is performed on the third semiconductor material 156 to reduce contact resistance between the conductive feature and the S/D region, as described in
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In some embodiments, the contact resistance between the S/D region and the channel regions (all of the first semiconductor layers 106) is reduced without substantially affecting the contact resistance between the S/D region and the conductive feature by performing the SPER process on the second semiconductor material 154 in contact with all of the first semiconductor layers 106. As shown in
Embodiments of the present disclosure provide a semiconductor device structure and methods of forming the same. In some embodiments, the method includes performing an amorphization process on a portion of the third semiconductor material 156 and/or second semiconductor material 154. A dopant implantation process may be optionally performed before or after the amorphization process. The doped region may be greater than, the same as, or smaller than the amorphous region formed by the amorphization process. The amorphous region is then partially or fully recrystallized. Some embodiments may achieve advantages. For example, partially recrystallized amorphous region can enhance the growth of the silicide layer 192. In addition, the dopant concentration and dopant activation of the recrystallized region are increased, which leads to reduced contact resistance.
An embodiment is a method. The method includes forming a fin structure from a substrate, depositing a first semiconductor material on a first semiconductor layer of the fin structure, depositing a second semiconductor material on the first semiconductor material, depositing an interlayer dielectric layer over the second semiconductor material, forming an opening in the interlayer dielectric layer to expose the second semiconductor material, and performing a dopant implantation process to form a doped region. The doped region includes a first portion of the second semiconductor material. Then, the method further includes performing an amorphization process to form an amorphous region, and the amorphous region includes a second portion of the second semiconductor material. The method further includes performing an annealing process to recrystallize the amorphous region.
Another embodiment is a method. The method includes forming a fin structure from a substrate, recessing a portion of the fin structure to expose a portion of the substrate, depositing a first semiconductor material over the portion of the substrate, depositing an interlayer dielectric layer over the first semiconductor material, forming an opening in the interlayer dielectric layer to expose the first semiconductor material, and performing an amorphization process to form an amorphous region. The amorphous region includes a portion of the first semiconductor material. The method further includes performing an annealing process to convert a first portion of the amorphous region to a first crystalline region and forming a silicide layer from a second portion of the amorphous region.
A further embodiment is a semiconductor device structure. The structure includes a plurality of semiconductor layers disposed over a substrate and a source/drain region disposed adjacent the plurality of semiconductor layers. The source/drain region includes a first semiconductor material in contact with each semiconductor layer of the plurality of semiconductor layers, the first semiconductor material in contact with a topmost semiconductor layer of the plurality of semiconductor layers has a first dopant concentration, and the first semiconductor material in contact with a semiconductor layer of the plurality of semiconductor layers disposed below the topmost semiconductor layer has a second dopant concentration substantially less than the first dopant concentration. The source/drain region further includes a second semiconductor material surrounding the first semiconductor material.
The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.
This application claims priority to U.S. Provisional Application Ser. No. 63/540,920 filed Sep. 27, 2023, which is incorporated by reference in its entirety.
Number | Date | Country | |
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63540920 | Sep 2023 | US |