Conventional polysilicon resistors in semiconductor processes can have a wide range of values for their temperature coefficient of resistance (TCR), from positive to negative, whereas diffused resistors in monocrystalline silicon typically have a positive TCR. For many device applications, resistors with small or zero TCR are desired. Examples of device applications wherein low or zero TCR resistors are often desirable include voltage dividers, amplifier gains and/or other devices wherein reference voltage is used. In the past, resistors with small or zero TCR have been fabricated using relatively expensive materials and/or with additional processing steps that add complexity to fabrication. In certain applications, controlled TCR is important, even if the TCR is nonzero.
The present disclosure sets forth a device in the form of a resistor, and a method for making the same, having a small or zero TCR without the use of relatively expensive materials and/or fabrication techniques. In one embodiment, an example resistor is fabricated alongside and/or in conjunction with other integrated circuit components on a wafer using fabrication steps and materials already used in fabrication of the other integrated circuit components on a given wafer. As such, aspects of the present disclosure provide for the fabrication of low or zero TCR resistors with virtually no additional cost or processing steps. Also disclosed is a method of lowering the TCR of a resistor, whether the TCR of the base resistor material has a positive or negative TCR.
Disclosed examples include a resistor comprising a semiconductor structure between the first and second ends. The resistor also includes first and second metal-semiconductor compound structures on the semiconductor structure proximate the first and second ends of the semiconductor structure, where the first and second metal-semiconductor compound structures are spaced apart from each other along the length dimension of the semiconductor structure. The resistor further includes at least one intermediate metal-semiconductor compound structure on a portion of the intermediate region of the semiconductor structure between the first and second ends, where the intermediate metal-semiconductor compound structure is spaced apart from the first and second metal-semiconductor compound structures on the semiconductor structure.
Another example resistor includes a resistor region of a semiconductor substrate. The resistor region has a length dimension with first and second ends spaced from one another and an intermediate region between the first and second ends. The resistor further includes an oxide structure formed on or in the semiconductor substrate surrounding the resistor region of the semiconductor substrate, as well as first and second metal-semiconductor compound structures on the first and second ends of the resistor region, where the first and second metal-semiconductor compound structures are spaced apart from each other along the length dimension of the resistor region. The resistor also includes at least one intermediate metal-semiconductor compound structure on a portion of the intermediate region of the resistor region between the first and second ends, where the intermediate metal-semiconductor compound structure is spaced apart from the first and second metal-semiconductor compound structures on the resistor region of the semiconductor substrate.
In the drawings, like reference numerals refer to like elements throughout, and the various features are not necessarily drawn to scale. In the following discussion and in the claims, the terms “including”, “includes”, “having”, “has”, “with”, or variants thereof are intended to be inclusive in a manner similar to the term “comprising”, and thus should be interpreted to mean “including, but not limited to . . . ” Also, the term “couple” or “couples” is intended to include indirect or direct electrical or mechanical connection or combinations thereof. For example, if a first device couples to or is coupled with a second device, that connection may be through a direct electrical connection, or through an indirect electrical connection via one or more intervening devices and connections.
Referring initially to
As illustrated in
It should be appreciated that the example resistor 110 with intermediate silicide structures 132 has a lowered TCR compared to a conventional resistor having only first and second silicide structures at respective ends thereof. In regions of the polysilicon layer 116 between the intermediate silicide portions 132, current traveling between the first and second end silicide structures 118 and 120 is forced to leave the low-ohmic silicide and travel across the interface into the polysilicon layer 116. This is a tunneling process and is enhanced by higher temperature. Thus, the interface between the silicide structures and the polysilicon has a lower resistivity at higher temperatures (i.e., a negative TCR). The TCR of the polysilicon layer 116 and the silicide will remain at their respective baselines, but the interface resistance of the silicide to polysilicon has a negative TCR. By selecting the length and number of silicided and unsilicided intermediate segments between the first and second silicide structures 118 and 120, the resistance and TCR of the resistor 110 can be adjusted over a wide range of values. Thus, if the polysilicon resistor material 116 has a positive TCR to begin with, a resistor with zero or negative TCR can be created by tailoring the intermediate silicide structures in accordance with the present disclosure. In general, the provision of the intermediate silicide portions 132 operates to decrease the TCR of the resulting resistor structure 110.
It should also be appreciated that the example resistor 110 can be fabricated with little or no additional cost or processing time in any fabrication process that includes both a polysilicon deposition step and a silicidation step.
Turning to
The method in
In process step 306, polysilicon is deposited on the oxide above the bulk semiconductor substrate and patterned by a process 402 to form silicon structures 116, as shown in
The doping level of the material at the metallic contact interface can be greater than 1E18 cm-3 for Si/GaAs/InP with bandgap voltage around 1 eV (may be different for high bandgap material such as SiC or GaN), else the contact forms a Schottky diode and has non-linear current-voltage behavior. The doping level of the material further away than a depletion length can be lower doped than 1E18 cm-3 to fit the need of the resistor, typically in the 1E15 to 1E20 cm-3 range.
In one example, the regions 140 are implanted as shown in
In process step 308, a silicide block 134 is applied over the polysilicon structures 116 and insulating layer 214, for example, using a deposition process 502 in
In process step 310, a photoresist 612 is applied over the silicide block 134, as shown by a deposition process 602 in
In process step 312, the photoresist 612 is exposed to leave a pattern to be transferred to the silicide block layer 134, as shown by process 702 in
In process step 314, the silicide block layer 134 is etched to remove portions thereof not covered by the remaining photoresist 612, as shown by process 802 in
In process step 316, the remaining photoresist is removed, as shown by process 902 in
In process step 320, the assembly undergoes a silicidation step whereat silicide is formed at the interface of the polysilicon layer and the metal layer through an annealing process 1102 in
In process step 322, excess metal 1012 is removed, as shown by process 1202 in
In the illustrated example, a further annealing step is performed at 322 to complete the silicide formation. An optional implant may be performed at this step to modulate the contact resistance of the silicide. Resistors 110 and 410 are now ready for contact formation and other back-end processing, at 324 in
A further optional process step can include doping via implantation through the silicide structures 118, 120, 132 to modify the response of the interface resistance between the silicide and the polysilicon 212. This increases the doping level just at the metal semiconductor interface and can assist electron transport through the interface.
It should be appreciated that the silicide structures of the disclosed examples can be formed by any suitable silicide formation techniques. In one possible implementation, a nitride mask is formed and patterned to expose portions of the polysilicon, and cobalt or other suitable metal is deposited so as to contact the exposed portions of the polysilicon. The polysilicon and metal are then heated (e.g., 800-900° C.) to react the polysilicon with the deposited metal to form the silicide structure, to a thickness of about several hundred angstroms in one possible implementation. In another possible implementation, the silicide structures are formed (e.g., Titanium Silicide TiSi2, or Tungsten Silicide WSix) by chemical vapor deposition (CVD) using monosilane or dichlorosilane with tungsten hexafluoride as source gases, followed by annealing at 800-900° C. to create conductive stoichiometric silicide structures. In another possible implementation, titanium or tungsten metal is sputter deposited onto the polysilicon and remaining silicide block and is then heated to a certain temperature (e.g., 800-900° C.) to react the polysilicon with the deposited metal to form the silicide structures, preferably to a thickness of about several hundred angstroms. In materials not suitable for silicide formation such as III-V a metal stack using suitable metals such as Ti, Pt, Pd, W, Ni or Au may be used. Also, a chemical mechanical polishing (CMP) process may be performed to create a smooth surface appropriate for wafer bonding.
In another example, particularly when using III-IV materials and/or in CMOS or other processing where a silicide block layer typically is not used, a photoresist lift-off process can be used for patterning a metal layer on the semiconductor substrate. In such process, an undercut photoresist is typically applied to the semiconductor substrate and patterned to expose specific portions of the semiconductor substrate. A metal is then deposited over the photoresist and semiconductor substrate. The photoresist and upper layer of the metal is removed leaving behind only the portions of the metal layer in contact with the semiconductor substrate. Then, an annealing process is used to create metal-semiconductor compound structures on the semiconductor substrate.
It should now be appreciated that resistor 110 can be fabricated using steps common to the fabrication of a resistor, such as resistor 410, that does not include the intermediate silicide portion through etching of the photoresist in additional regions to leave a pattern that blocks silicide formation in certain intermediate regions in addition to the end regions of the resistor. Additionally, or in the alternative, example resistor 110 can be fabricated alongside a transistor in shared process steps including polysilicon deposition and patterning, oxide formation, masking/etching, and silicidation steps. As such, the present disclosure sets forth a low or zero cost adding method of fabricating low or zero TCR resistors in fabrication processes that include at least a polysilicon deposition step and a silicidation step.
With reference to
To this end, it will be appreciated that the resistor 1310 includes a resistor region 1314 of the semiconductor substrate 1312 that is isolated from the remainder of the semiconductor substrate 1312. The semiconductor substrate 1310 can be a silicon substrate, although aspects of the disclosure can be carried out in association with SOI wafers, epitaxial silicon layers formed over silicon wafers, and any other semiconductor body including III-V materials. The bulk semiconductor substrate can be plain Si substrate, or an epitaxially grown Si layer on top of a plain Si substrate, for example. The bulk substrate could have received an implant (e.g. well). The resistor region 1314 can be formed by, for example, an oxide structure 1316 surrounding the resistor region 1314 (e.g., LOCOS or shallow trench isolation (STI)), or by various other isolation techniques such as junction isolation. The resistor 1310 includes first and second silicide end structures 1318 and 1320, and a plurality of intermediate silicide structures 1332. The semiconductor material beneath the end structures 1318 and 1320 can be doped, as shown in regions 1340 in
The above examples are merely illustrative of several possible embodiments of various aspects of the present disclosure, wherein equivalent alterations and/or modifications will occur to others skilled in the art upon reading and understanding this specification and the annexed drawings. Modifications are possible in the described embodiments, and other embodiments are possible, within the scope of the claims.
Under 35 U.S.C. § 119, this application claims priority to, and the benefit of, U.S. provisional patent application No. 62/440,614, entitled “SEMICONDUCTOR RESISTOR STRUCTURE AND METHOD FOR MAKING”, and filed on Dec. 30, 2016, the entirety of which is hereby incorporated by reference.
Number | Name | Date | Kind |
---|---|---|---|
5656524 | Eklund et al. | Aug 1997 | A |
5682060 | Tung et al. | Oct 1997 | A |
6727133 | Baldwin | Apr 2004 | B1 |
8748256 | Zhao et al. | Jun 2014 | B2 |
20030178697 | Lee | Sep 2003 | A1 |
20050248977 | Liaw | Nov 2005 | A1 |
20060177978 | Tsutsumi | Aug 2006 | A1 |
20070096183 | Ogawa | May 2007 | A1 |
20080030297 | Ohtsuka et al. | Feb 2008 | A1 |
20080054405 | Wang et al. | Mar 2008 | A1 |
20080217741 | Young | Sep 2008 | A1 |
20120098071 | Aggarwal et al. | Apr 2012 | A1 |
20120126370 | Harmon | May 2012 | A1 |
20130307074 | Cheng et al. | Nov 2013 | A1 |
20130320497 | Zhang | Dec 2013 | A1 |
20140035061 | Aggarwal et al. | Feb 2014 | A1 |
20140183657 | Lim et al. | Jul 2014 | A1 |
20150187759 | Aggarwal et al. | Jul 2015 | A1 |
20160247875 | Aggarwal et al. | Aug 2016 | A1 |
20170011826 | Hiroshima | Jan 2017 | A1 |
Number | Date | Country |
---|---|---|
104064520 | Sep 2014 | CN |
Number | Date | Country | |
---|---|---|---|
20180190753 A1 | Jul 2018 | US |
Number | Date | Country | |
---|---|---|---|
62440614 | Dec 2016 | US |