This invention relates generally to electronic memories and particularly to electronic memories that use phase change material.
Phase change materials may exhibit at least two different states. The states may be called the amorphous and crystalline states. Transitions between these states may be selectively initiated. The states may be distinguished because the amorphous state generally exhibits higher resistivity than the crystalline state. The amorphous state involves a more disordered atomic structure. Generally any phase change material may be utilized. In some embodiments, however, thin-film chalcogenide alloy materials may be particularly suitable.
The phase change may be induced reversibly. Therefore, the memory may change from the amorphous to the crystalline state and may revert back to the amorphous state thereafter, or vice versa, in response to temperature changes. In effect, each memory cell may be thought of as a programmable resistor, which reversibly changes between higher and lower resistance states. The phase change may be induced by resistive heating.
Existing phase change memories may exhibit unpredictably current/voltage characteristics in transitioning from the amorphous to the crystalline phases.
Referring to
An electrical potential may be applied to the lower electrode 20 to cause the current to flow through the resistive film 14 to the upper electrode 16. As a result of the resistance of the film 14, the phase change material 12 may be heated. As a result, the material 12 may be transitioned between its amorphous and crystalline states.
Current phase change memory elements exhibit instability in the set/reset behavior. Metal nitride electrodes tend to be unstable at higher temperatures and higher fields. An electrical pulse either melts or quenches the phase change material into an insulating amorphous state or heats and crystallizes the material into a conductive crystalline state. When the phase change material is in the amorphous phase, a large electric field is needed to force sufficient current to heat the memory and to store a bit. This leads to a switching event where the higher resistance insulating material rapidly becomes conductive. The switching process is very non-uniform and there are large variations in the voltage required in the region where the subsequent current conducts. As a result, unpredictable switching in the phase of the material may occur.
For example, referring to
By shunting current around the amorphous phase change material 12 using the resistive film 14, the snapback may be largely reduced or eliminated. The shunt resistance from the resistive film 14 may be significantly higher than the set resistance of the memory element so that the phase change resistance difference is detectable. The shunt resistance of the resistor film 14 may be low enough so that when voltages approaching the threshold voltage of the memory element are present, the resistive film 14 heats up significantly. In other words, the resistance of the film 14 may be higher than the memory's set resistance and lower than its reset resistance.
This heat, generated by the film 14, changes the conductivity of the amorphous phase change material 12 in close proximity to the resistive film 14. This heated phase change material 12 becomes more electrically conductive as indicated in
If the amorphous phase change material becomes conductive enough, the voltage across the memory element never becomes high enough to cause threshold switching. The instabilities resulting from this threshold switching do not occur in the phase transition from the amorphous phase or the reset state to the crystalline phase or set state so that the state transition occurs in a predictable fashion.
In one embodiment shown in
While in the embodiment illustrated in
A variety of materials may be suitable for the resistive film 14, including silicon carbide and metal nitrides. Suitable metals for the metal nitride include titanium, silicon, titanium aluminum, titanium carbon, tantalum, tantalum aluminum, and tantalum carbon, to mention a few examples. In some cases, it may be desirable to use an adhesion promoter between the resistive film 14 and the insulator 18.
Referring to
Referring to
While the present invention has been described with respect to a limited number of embodiments, those skilled in the art will appreciate numerous modifications and variations therefrom. It is intended that the appended claims cover all such modifications and variations as fall within the true spirit and scope of this present invention.
This application is a divisional of U.S. patent application Ser. No. 11/810,228, filed on Jun. 4, 2007, which issued as U.S. Pat. No. 7,916,514, which is a divisional of U.S. patent application Ser. No. 10/318,706, filed on Dec. 13, 2002, which issued as U.S. Pat. No. 7,242,019.
Number | Name | Date | Kind |
---|---|---|---|
5978258 | Manning | Nov 1999 | A |
6487113 | Park et al. | Nov 2002 | B1 |
6861267 | Xu et al. | Mar 2005 | B2 |
7105408 | Dennison | Sep 2006 | B2 |
7214632 | Chiang | May 2007 | B2 |
7217945 | Dennison et al. | May 2007 | B2 |
7242019 | Wicker | Jul 2007 | B2 |
7282730 | Czubatyj et al. | Oct 2007 | B2 |
7323707 | Dennison | Jan 2008 | B2 |
7348590 | Happ | Mar 2008 | B2 |
7382647 | Gopalakrishnan | Jun 2008 | B1 |
7397681 | Cho et al. | Jul 2008 | B2 |
7531378 | Peters | May 2009 | B2 |
7638789 | Peters | Dec 2009 | B2 |
7649191 | Czubatyj et al. | Jan 2010 | B2 |
7804082 | Dennison | Sep 2010 | B2 |
7863596 | Karpov et al. | Jan 2011 | B2 |
Number | Date | Country | |
---|---|---|---|
20110085376 A1 | Apr 2011 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 11810228 | Jun 2007 | US |
Child | 12969756 | US | |
Parent | 10318706 | Dec 2002 | US |
Child | 11810228 | US |