Patent Application
20120113517
The invention relates to a structural body having optical-control function utilizing optical phenomenon such as diffraction and interference, a method for forming the structural body and an apparatus for forming the structural body by executing this method.
In recent years, chemical color development using pigment substances has become unacceptable in view of recycling properties and environmental protection. Under such circumstances, a structural color which develops a color utilizing a phenomenon such as diffraction and interference of light by forming a fine structure has come to be an important technique replacing the chemical color development.
A structural color is generated, for example, by thin film interference, multilayer interference, light scattering phenomenon, diffraction lattice and photonic crystals.
It is difficult to cause such a structural color to be developed artificially. There are very few cases where structural colors are developed on the industrial scale.
As one of these few cases, a method has been proposed in which a fine periodic structure is formed by light irradiation, thereby developing a structural color.
As examples of the fine periodic structure formed by light irradiation, LIPS (Laser Induced Periodic Structures) (see Non-Patent Document 1, for example) can be given, for example. The LIPS are fine periodic structures which are formed by laser irradiation on the surface of a material in a self-organized manner.
As another example, a technology is disclosed in which a diffraction lattice is formed in the inside of glass by means of a femtosecond laser (see Non-Patent Document 2, for example).
Non-Patent Document 1: Sylvain Lazare: “Large scale excimer laser production of submicron periodic structures on polymer surface” Applied Surface Science 69 (1993) 31-37, North-Holland
Non-Patent Document 2: Journal of Japanese Society of Laser Technology, Vol. 30, issue 2, Hideo Hosono and Kenichi Kawamura, “Interaction between Femtosecond Laser and Transparent Substance: Decoration of a Transparent Substance with a Periodic Nanostructure by a Single Pulse Interference”, Japanese Society of Laser Technology, May 2005, pages 7-12.
However, to put a structural color into practical use, high color development efficiency and capability of being produced at low cost are requirements. It is not easy to meet these three requirements.
For example, the technology disclosed in the Non-Patent Document 2 is since a lattice pattern can be formed only on one site by a single laser irradiation, an extremely long period of time is required to decorate a large area, resulting in poor productivity.
In the case of commercial transactions, products must be strictly genuine in order to keep the order of transactions, as well as to protect consumers. However, the circulation of forgeries obtained by duplicating and imitating genuine products with the aim of taking advantage of genuine products to gain illegal profits happens all too often. Circulation of poor-quality forgeries not only decreases the profits of the manufacturers of genuine products but also causes consumers to distrust in the manufacturers of genuine products. As a result, corporate images may deteriorate, and as a result, corporate power of the brand may be impaired.
In order to avoid economical damage caused by the circulation of forgeries, many manufacturers take measures to distinguish genuine products from forgeries. As one of such measures, forgery protection markings can be given. Examples of these include hard-to-duplicate markings which are attached to an object as the proof of a genuine product. Specific examples of these include a hologram seal in which a relief-type hologram image is formed (see JP-A-2006-059612 ((Patent Document 1) and Japanese Patent No. 3546975 (Patent Document 2), for example).
Since not only an advanced level of optical design technology is required but also a complicated material constitution and an expensive hologram original plate are also required, duplication of a hologram seal with the intent of forgery is difficult. Hologram seals are widely used since they have forgery protection effects due to the above-mentioned difficulty in duplication, the capability of being discriminated at one glance due to its unique color tone, and easiness in handling which requires only physical attachment.
However, a hologram seal has the defect that it can be peeled off relatively easily from an existing object and can be reused simply by attaching to another object. A hologram seal is attached as the proof of a genuine product. Therefore, if the removed original seal is attached to a forged product, it becomes impossible to verify that the product to which the seal has been attached is a forgery.
The hologram seal disclosed in Patent Document 2 has a configuration in which a peelable layer is provided on an inner layer of the seal, whereby the seal itself is destroyed when the seal is peeled off intentionally. Due to the destruction, reuse of the peeled seal can be prevented. However, provision of a peelable layer makes the material constitution or manufacturing technique complicated, leading to an increase in cost.
If the hologram seal is duplicated in a more elaborate fashion, to verify whether the attached hologram seal is real or not, fine detailed portions have to be compared carefully. Such comparison cannot be done easily by consumers.
The invention has been made in view of the above-mentioned circumstances, and the object thereof is to provide a structural body, a method for forming a structural body and an apparatus for forming a structural body.
In order to solve the problem, the structural body of the invention has a configuration in which a periodic structure causing optical diffraction is formed on part or the whole of the surface of the substrate.
By allowing the structural body to have such a configuration, since the periodic structure is formed in the structural body itself, peeling the periodic structure for reusing purposes is impossible. Therefore, it is possible to prevent such an act of removing the periodic structure from an existing object like a hologram seal and attaching the removed seal to a forgery to allow the forgery to be circulated as a genuine product.
In addition, due to a configuration in which a periodic structure is formed on the surface of a substrate, the material constitution is simplified to prevent an increase in cost.
Furthermore, since a periodic structure is formed on the surface of a substrate, a structural color is developed according to the periodic structure.
In addition, the structural body of the invention may have a configuration in which the periodic structure formed on the surface of the substrate (substrate surface periodic structure) has a regular arrangement which develops a structural color.
If the structural body has such a configuration, the substrate surface periodic structure may develop a structural color based on the regular arrangement.
The structural body of the invention may have a protective layer for protecting a periodic structure formed on the substrate surface.
Due to such a configuration, the substrate surface periodic structure can be prevented from being damaged.
In addition, in the structural body of the invention, the substrate surface periodic structure may be formed by light irradiation.
Due to such a configuration of the structural body, the substrate surface periodic structure may be formed by a relatively simple manufacturing technique, whereby an increase in cost can be suppressed.
In the structural body of the invention, the periodic structure on the surface of the substrate may be formed by light irradiation which generating a periodic intensity distribution.
By this method for forming a structural body, due to the generation of the periodic intensity distribution, the substrate surface periodic structure can be formed.
The method for forming a structural body of the invention comprises irradiating by using an apparatus for forming a structural body the substrate with light having a wavelength within a wavelength region which allows the substrate to show opacity, thereby allowing a periodic structure causing optical diffraction to be formed on the surface of the substrate.
By this method for forming a structural body, by irradiating the substrate with light having a wavelength within a wavelength within a wavelength region which allows the substrate to show opacity, a substrate surface periodic structure can be formed on the surface of the substrate.
The method for forming a structural body of the invention comprises irradiating the substrate with light which has a periodic intensity distribution.
By this method for forming a structural body, the periodic structure can be formed on the surface of the substrate by causing a periodic light intensity distribution to be generated.
The apparatus for forming a structural body of the invention is a structural body-forming apparatus which irradiates light to the substrate. The apparatus comprises a laser oscillator which adjusts irradiation pulse number and/or laser output so that a periodic structure causing optical diffraction can be formed in the interface of the cavity which is formed in the inside of the substrate.
By allowing the apparatus for forming a structural body to have such a configuration, by adjusting irradiation pulse number or laser output, a periodic structure causing optical diffraction being formed on the surface of the substrate.
As mentioned above, according to the invention, a structural color satisfying the requirements for practical application on the industrial scale can be obtained.
Furthermore, the structural color of the invention can be effectively used for decorating plastic apparatuses or the like with a high degree of recycling properties.
In addition, since the substrate surface periodic structure are formed in the substrate itself, it is impossible to remove them for reuse. As a result, a damage caused by reusing it in a forgery, which occurs in the case of forgery protection seals, can be prevented.
a is a diagrammatical view showing the cross section of the structural body in which a cavity is formed;
b is a perspective view showing the appearance of the structural body in which a cavity is formed;
c is a diagrammatical view of
d is an enlarged microscopic image of a cavity when the structural body is viewed from top (direction A in
e is an enlarged microscopic image of a cavity when the structural body is viewed from side (direction B in
a is a diagrammatical view showing the cross section of the structural body in which a substrate surface periodic structure is formed;
b is a perspective image showing the appearance of the structural body in which the substrate surface periodic structure is formed;
c is an AFM image showing an enlarged view of the substrate surface periodic structure;
YAG-THG (355 nm), 247 mJ/cm2, 30 laser shots, a PET-INJ sheet as a sample 30;
YAG-SHG (532 nm), 500 mJ/cm2, 10 laser shots, an elongated PET sheet as a sample 30;
Preferred embodiments of the structural body, the method for forming a structural body and the apparatus for forming a structural body will be explained below with reference to the drawings.
In the embodiment, “decorating” implies coloring a package with a chromatic color or shielding light in a specific wavelength region to prevent it from being penetrated into the inside of the package.
The embodiments of the structural body of the invention will be explained with reference to
a to 2e are views showing a cavity formed inside of the structural body,
a to 3c are views showing a periodic structure (substrate surface periodic structure) formed on the surface of the structural body (substrate surface), in which
As shown in
As shown in
As for the cavity 12, the diameter direction of the gong-like structure is almost in parallel with the plane direction of the structural body 10, and the thickness direction of the gong-like structure is almost in parallel with the thickness direction of the structural body 10.
As shown in
Here, the “periodic structure” means a structure in which a plurality of predetermined shapes is formed at an almost equal interval. In the cavity interface periodic structure 13 of this embodiment, as shown in
One period of the wavy pattern of the periodic structure 13 (the distance between the apices of two adjacent convex portions) is about 1.5 μm to 2.0 μm.
When light is incident on the periodic structure, diffraction occurs. At this time, a wavelength which is diffracted most strongly (a larger amount of photoenergy is diffracted) varies depending on the ratio between the wavelength and the lattice period. Generally, strong diffraction occurs when the ratio of the light wavelength to the lattice period is about 1 or less.
The “regular arrangement which develops a structural color” as referred to herein means that the lattice period is close to the wavelength of visible light (about 400 nm to 700 nm), i.e., about 2.0 μm or less. At this time, since visible light is diffracted strongly, a structural color is observed.
As shown in
A plurality of the cavity 12 is formed within the irradiated area (within the same plane).
These plural cavities 12 are formed at arbitrary positions laterally within the light-irradiated area. Furthermore, they are formed at different depths from the light-irradiated surface.
Here, each cavity 12, which is formed in the same plane at different depths from the surface, functions as a diffraction lattice. Depending on the light incident angle or the viewing angle, the structural body 10 develops different colors (when cavities 12 are present in the same plane, this plane is hereinafter referred to as the “diffraction plane”). If the diffraction plane presents at different depths, i.e. presents in a plurality of layers, diffraction occurs at each of the diffraction planes. At this time, emission is weak if the phase of the diffraction light from each diffraction plane is not uniform. If the phase of diffraction light from each diffraction plane is uniform, strong emission can be obtained. Specifically, strong emission can be obtained with light having a wavelength satisfying the following Bragg's reflection formula (formula 1):
mλ=2D(n2−sin 2θ)1/2 formula 1
In this formula 1, m is the order of diffraction, λ is a wavelength, D is the interval of diffraction planes, n is the refractive index of a material and θ is a viewing angle assuming that the normal angle of the sample surface is 0°.
If the structural body 10, in which the diffraction planes are present at intervals satisfying the formula 1, can be formed, the structural body 10 develops a color only by light having a specific wavelength satisfying the formula 1. Furthermore, if the number of diffraction planes increases, stronger emission can be obtained due to an increase in the intensity of diffraction light.
As a material which develops a color according to the Bragg's Law, photonic crystals are known in which periodic structures are three-dimensionally formed.
The perspective image in
As shown in
Here, the periodic structure is as defined above. In the substrate surface periodic structure 15 of this embodiment, as shown in
One period of the wavy pattern of the substrate periodic structure 15 (distance between the apices of adjacent convex portions) is about 1.0 μm.
The substrate surface periodic structure 15 is formed at a light-irradiated portion of the substrate surface 14. Therefore, as shown in
The images of
As mentioned above, the structural body 10 of this embodiment has a configuration in which the cavity 12 with a fine periodic structure being formed in the interface thereof is formed within the substrate 11, and the substrate surface 14 has a fine periodic structure. By allowing a structural color to be developed from the periodic structures 13 and 15 by an optical phenomenon such as diffraction and interference, whereby a marking is formed.
Here, the “marking” is defined by an area where portions which develop a structural color and/or diffraction light are uniformly formed, or a graphic, a letter or the like which is formed as a result of adequate arrangement of portions which develop a structural color and/or diffraction light.
By forming the cavity interface periodic structure 13 and the substrate surface periodic structure 15 in the substrate itself, it is impossible to remove them for reuse purposes, such as attaching to other objects. Also, it is impossible to delete or alter the periodic structures 13 and 15.
The substrate 11 is an element which serves as the base of the structural body 10.
In the substrate 11, high-molecular compounds such as polystyrene, polyethylene, polypropylene, polycarbonate, nylon resins, acrylic resins, vinyl chloride resins and phenol resins, optical glass such as BK7 and quartz and soda glass may be used as raw materials. It is also possible to use polyester compounds such as polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polybutylene terephthalate (PBT) and polytrimethylene terephthalate (PTT) as raw materials.
The raw materials for the substrate 11 are not limited to the materials mentioned above, and suitable known materials may also be used insofar as the materials can allow the cavity 12, the cavity interface periodic structure 13 and the substrate surface periodic structure 15 to be formed by light irradiation.
As shown in
The protective layer 16 is a protective film to avoid such an unfavorable phenomenon that the substrate surface periodic structure 15 is damaged to become unable to develop a structural color.
The protective layer 16 may be formed of acrylamino, polyesteramino, polyesteracrylamino or the like, for example.
Next, an explanation is made on an apparatus for forming a structural body. There are two types of apparatuses for forming a structural body, i.e. one which has a transmitting diffraction optical device and one which has a micro-lens array.
First, with reference to
The apparatus for forming the structural body 20 is an apparatus for forming the cavity interface periodic structure 13 or the substrate surface periodic structure 15 in the substrate 11 (structural body 10). As shown in
Here, the laser oscillator 21 is an apparatus which outputs a laser beam. Examples include a YAG laser which performs Q-switch oscillation, a YVO4 laser, a YLF laser and a femtosecond laser such as a Ti:sapphire laser. These pulse lasers have repeated frequency of several Hz to several tens of kHz. The energy accumulated during these repeated periods is released at an extremely short time interval such as several femtoseconds to several tens of nanoseconds. Therefore, a high peak power can be obtained efficiently from a small amount of input energy.
To form the periodic structure 13 in the inside of the substrate 11, 5 to 20 laser shots will suffice. Such laser shots require about several seconds, realizing high-speed production. As a result, products developing a structural color can be produced at a low cost. In addition, a further shortening of production time can be attained by using a light source having a high repeated frequency.
The laser oscillator 21 has a function of adjusting the irradiation pulse number. The laser oscillator 21 can control the energy density (fluence: energy per area irradiated with one pulse) by adjusting the outputs of the laser.
Control of the energy density can be realized not only by adjusting the laser output of the laser oscillator 21 but also by changing the laser beam diameter with the laser output being the same.
To allow the periodic structure to be formed in the inside of the irradiated material, it is required that the irradiation light be penetrated into the inside of the material. To prevent the irradiation light from being absorbed on the polar surface, it is desirable to use light with a wavelength exhibiting an appropriate transmittance at the irradiated material.
A mirror 22 reflects laser light which has been output from the laser oscillator 21. In
The transmitting diffraction optical device 23 is a transmitting optical device which causes diffraction since fine convex and concave portions are periodically formed on the surface thereof, and divides laser light into a plurality of light beams.
As the convex lens 24, a synthetic quartz flat convex lens having a focal distance of 200 mm can be used, for example. In this case, the convex lens 24 is placed at a position 200 mm away from the transmitting diffraction optical device 23. The convex lens 24 allows the plurality of light beams which have been divided by the transmitting diffraction optical device 23 to pass therethrough.
The mask 25 is placed at a position at which the light beams which have been passed through the convex lens 24 focus, and hides light beams which are not required for interference but passes through light beams which are required for interference.
As the convex lens 26, a synthetic quartz flat convex lens having a focal distance of 100 mm can be used, for example. The convex lens 26 condenses light beams which have passed through the mask 25, and causes the light beams to intersect and interfere. The interference region has a high intensity distribution, as shown in
Here, the period d of the interference fringe can be expressed by the following formula:
d=λ/(2 sin(θ/2) formula 2
λ: light wavelength, 0: intersecting angle of light beam
As for the relationship between the division of the laser beam by means of the transmitting diffraction optical device 23 and the selection of the laser beam by means of the mask 25, an explanation will be made in the “Method for forming a periodic structural pattern by using a transmitting diffraction optical device” in the “Method for forming a periodic structural pattern”, which is given later.
Next, an apparatus for forming a structural body will be explained with reference to
As shown in
Here, the laser oscillator 31 has the same function as that of the laser oscillator 21 of the apparatus 20 for forming a structural body shown in
The mirror 32 reflects laser light which has been output from the laser oscillator 31. In
The concave lens 33 enlarges the diameter of the laser beam. The convex lens 34 adjusts the enlarged laser beam diameter to a desired diameter.
The micro-lens array 35 is an optical device in which fine convex lenses are arranged in a checkerboard pattern, and divides the laser light into a plurality of beams.
The mask 36 selects some of the divided light beams. The convex lens 37 collects light beams which have been selected by the mask 36.
As for the relationship between the division of the laser beam by means of the micro-lens array 35 and the selection of the laser beam by means of the mask 36, an explanation will be given in the “Method for forming a periodic structural pattern by using a transmitting diffraction optical device” in the “Method for forming a periodic structural pattern by using a micro-lens array”, which is given later.
Next, an explanation will be made on the method for forming the structural body of this embodiment with reference to
As shown in
On the other hand, by irradiating the substrate 11 with light 2 which has a periodic intensity distribution, the periodic structure 15 is formed on the substrate surface 14. At this time, the fine periodic structure 15 is formed with the same period as that of the periodic intensity distribution.
Here, the light 1 is light having a wavelength within a wavelength region which allows the substrate 11 to show transparency. The light 2 is light having a wavelength within a wavelength region which allows the substrate 11 to show opacity. This means that, in the method for forming the structural body 10, dependency of the optical characteristics of the substrate 11 on the light wavelength is utilized.
For light with a specific wavelength, the substrate 11 has any of the following properties: transparency with a transmittance of 70% or more, semi-transparency with a transmittance of less than 70%, and opacity with a transmittance of less than 10%. When the substrate 11 shows transparency for a certain wavelength, the light penetrates into the inside of the substrate. If the substrate 11 shows opacity for a certain wavelength, the light enters only in the proximity of the surface of the substrate.
Specifically, as shown in
There is no specific order of irradiation between the light having a wavelength within a wavelength region which allows the substrate 11 to show transparency and the light having a wavelength within a wavelength region which allows the substrate 11 to show opacity. However, it is preferred that the substrate 11 be irradiated with the light having a wavelength within a wavelength region which allows the substrate 11 to show transparency at first, followed by the irradiation with the light having a wavelength within a wavelength region which allows the substrate 11 to show opacity.
The reason for this is to prevent the following unfavorable phenomenon from occurring. Specifically, if the substrate surface periodic structure 15 has been formed in advance, the periodic optical intensity distribution is disarranged when forming the cavity interface periodic structure 13. As a result, a well-arranged periodic structure is not formed, and development of a structural color is deteriorated.
Irradiation of light having a periodic intensity distribution can be performed by the irradiation of parallel rays by means of a mask with periodically arranged openings or by the irradiation of the interference region obtained by intersecting a plurality of parallel rays.
Generally, a single pulse laser shot will suffice to form the cavity interface periodic structure 13. About 5 to 20 pulse laser shots will suffice to form the substrate surface periodic structure 15. This takes only several seconds. In addition, by using a laser light source having a large pulse repetition frequency, a further shortening of time can be realized.
As the substrate surface periodic structure, LIPS (Laser Induced Periodic Structures) may be given other than those mentioned above.
This is a fine periodic structure formed in a self-organized manner by spontaneously generating a periodic intensity distribution on the surface of a material by laser irradiation. In addition, it is also possible to use a hot stamp method in which a pattern having a periodic structure is pushed to the substrate after heating or a pattern having a periodic structure is pushed to the heated substrate.
The above-mentioned LIPS are disclosed in the following Non-Patent Document.
Non-Patent Document: Sylvain Lazare: “Large scale excimer laser production of submicron periodic structures on polymer surface”, Applied Surface Science 69 (1993), pages 31 to 37, North Holland
The periodic light intensity distribution for forming the cavity 12 or the cavity interface periodic structure 13 can be formed by the following three methods, for example.
As the first method, as shown in
As the second method, as shown in
As the third method, as shown in
The above-mentioned irradiation of light having a periodic intensity distribution can be formed by the irradiation of parallel rays through a mask having periodically-arranged openings or by the irradiation of an interference area obtained by intersecting a plurality of light beams.
The method for forming a periodic structural pattern when the transmitting diffraction optical device or the micro-lens array is functioned as an optical control device is explained with reference to
When light is incident on the periodic structure, diffraction light appears in the direction of periodicity.
The optical control device is defined as a device which controls the pattern (direction, angle and wavelength) of diffraction light. This control is performed by adjusting the pattern (the number of the axis of periodicity, the angle of periodicity and the periodicity of lattice) of the periodic structure. As a result, optical information (diffraction pattern) can be recorded as a sort of bar code utilizing diffraction.
The pattern of the periodic structure of the structural body is the same as that of the periodic intensity distribution of light to be irradiated. That is, by using different periodic intensity distribution patterns, it is possible to create various patterns of periodic structures.
The pattern of the periodic intensity distribution can be changed by changing the position of an opening, if parallel rays are irradiated through a mask having an opening. The pattern of the periodic intensity distribution can be changed by changing the number, intersecting direction, intersecting angle and wavelength of light beams if irradiating with an interference area which is obtained by intersecting a plurality of light beams.
In the former method, of the parallel rays incident on the mask, only light near the openings passes through the mask. The light then advances straightforwardly, and is incident on an object. Therefore, the pattern of the periodic intensity distribution coincides with the arrangement of the mask openings.
In the case where irradiation is performed with an interference area, as the method for obtaining a plurality of beams by dividing a single beam, two methods are available; i.e. the use of a transmitting diffraction optical device and the use of a micro-lens array.
Each of these methods is explained below.
When a transmitting diffraction optical device is used, a laser beam is incident on a transmitting diffraction optical device. The incident laser beam is divided into two beams, i.e. a beam which advances straightforwardly and a beam which diffracts. The light beam to be diffracted appears in the direction of periodicity.
From the relationship between the division of the light beam by the transmitting diffraction optical device and the opening of the mask, the pattern of the periodic structure shown in
Here, as shown in
As shown in
As is apparent from the above, the periodic structural pattern varies depending on the combination of the light-dividing pattern of the transmitting diffraction optical device and the pattern of mask openings. As a result, optical information can be recorded as a sort of barcode utilizing diffraction.
The method using a micro-lens array is a method which can be compared to gelidium jelly (tokoroten)-making. Specifically, a laser beam is allowed to be incident on the micro-lens array as in the case where the gelidium jelly is pushed out by means of a gelidium jelly-making instrument. As a result, the laser light is divided into a plurality of laser beams in a checkerboard pattern.
For example, from the relationship between the division of the light beam by the micro-lens and the mask opening, the periodic structural pattern to be recorded as the cavity interface periodic structure 13 or the substrate surface periodic structure 15 is as shown in
Here, as shown in
Furthermore, as shown in
Furthermore, as shown in
As apparent from the above, the periodic structural pattern varies depending on the combination of the light division pattern of the micro-lens array and the mask opening pattern. As a result, optical information can be recorded utilizing diffraction as a sort of bar code.
Then, a method for reading a marking is explained.
Here, the “method for reading a structural color or diffraction light” is explained.
As shown in
If natural light (sun light, for example) is used as a light source, light in the UV region, visible region and infrared region is diffracted at different angles. At this time, diffracted light in the visible region (same as the light in other wavelength regions) is diffracted at different angles for each wavelength (that is, separated). Therefore, a different color is seen depending on the position at which diffraction light in the visible region is visually observed. The “structural color” as referred to herein means diffracted light in the visible region or a color observed by the diffraction light in the visible region.
Here, the visible region is a wavelength region which can be observed by human eyes, and has a wavelength of about 400 to 700 nm. A wavelength region shorter than the visible region is referred to as the “UV region” and a wavelength region longer than the visible region is referred to as the “infrared region”, and these wavelength regions cannot be observed by human eyes.
An angle β at which light having a specific wavelength is diffracted can be obtained by the following formula using a wavelength λ, an incident light α and a period d of the periodic structure:
d(sin α±sin β)=mλ formula 3
Here, m indicates the order of diffraction.
For example, when a monochromatic spotlight like a laser beam is incident on a marking, spot-like diffraction light appears only at a specific angle. If a surface having a marking is uniformly irradiated with monochromatic optical diffraction occurs only at the portion of the marking. Diffraction light appears in the same shape as that of the marking only at the specific angle.
Here, the marking indicates a graphic, a letter or the like formed by adequately arranging areas in which diffraction-causing portions are uniformly formed or by adequately arranging diffraction-causing portions.
From the above, “reading diffraction light” or “reading a structural color” indicates any of the following.
i. Detecting diffraction light at a diffraction angle obtained from the formula 3 by using a known lattice period when known monochromatic light is incident at a specific angle;
ii. Measuring an angle at which diffraction light is detected when known monochromatic light is incident at a specific angle;
iii. At a diffraction angle obtained from the formula 3 using a known lattice period, measuring an angle capable of detecting diffraction light at which known monochromic light is incident;
iv. When light including a plurality of wavelengths is incident at a specific angle, detecting diffraction light having a specific wavelength at a diffraction angle obtained from the formula 3 by using a known lattice period;
v. When light including a plurality of wavelengths is incident, measuring an angle capable of detecting diffraction light having a specific wavelength; and
vi. At a diffraction angle obtained from the formula 3 using a known lattice period, measuring an angle capable of detecting diffraction light having a specific wavelength at which light including a plurality of wavelengths is incident.
If spot light is incident, the above-mentioned diffraction light is in the form of a spot, and if uniform light is incident on a surface including a marking, the diffraction light has the same shape as that of the marking.
Here, the “reading diffraction light” and the “reading a structural color” differ as follows.
“Reading diffraction light” is one of the above-mentioned methods applied for diffraction light in any of the UV region, the visible region and the infrared region. “Reading a structural color” is one of the above-mentioned methods applied for diffraction light in the visible region.
In the case of the “reading diffraction light”, diffraction light in the visible region is detected by human eyes in addition to a light receiver (detector). On the other hand, in the case of the “reading a structural color”, the structural color is detected by both human eyes and a light receiver.
By observing whether diffraction light can be detected or not by the above-mentioned “reading” method or by observing the measured angle, it can be judged whether or not the value of the lattice period is the one which has already been known.
Irradiating a surface including a marking with natural light, and observing, at an angle of visible observation, a different color and the shape of a marking correspond to iv. as mentioned above.
Examples of the formation of a structural body are explained below.
By passing the light beam emitted from a Q-switch pulse YAG laser through a transmitting diffraction optical device, the light beam was divided into a plurality of light beams.
Each of the light beams was caused to pass through a synthetic quartz flat convex lens with a focal length of 200 mm, which was placed 200 mm away from the transmitting diffraction optical device. At a position where the light beams which had passed the lens was focused, unnecessary light beams were hidden by a mask, thereby allowing only necessary light beams to pass through. The light beam which had passed through was focused by means of a synthetic quartz convex lens having a focal length of 100 mm. The light beam was caused to intersect and interfere. A biaxial elongated PET sheet was irradiated with the interference area. In advance, irradiation was performed with a laser beam having a wavelength of 355 nm (transmission for PET sheet of 83%).
Then, the wavelength was switched to 266 nm (transmittance for PET sheet: 0.3%), and irradiation was performed. The two-dimensional lattice period of the diffraction optical device was 6 μm. The pulse YAG laser has the following specification:
Pulse width: 5 ns
Repeated frequency: 10 Hz
When the laser wavelength was 355 nm, the average power of irradiated light was 1.35 W. Since the irradiated area was 4.5 maw), the light power density per unit area was 1 W/cm2.
As a result of 25 laser shots, cavities were generated in the inside of the elongated PET sheet, and in the interface of the cavity, two-dimensional periodic structure with a period of 1.5 μm was formed. A structural color caused by this structure could be observed.
Similarly, at a laser wavelength of 266 nm, the average power of the irradiated light was 240 mW. Since the irradiated area was 4.5 mmφ, the density of light power per unit area was 179 mW/cm2.
As a result of a single laser shot, a two-dimensional periodic structure with a period of 1 μm was formed on the outside surface of the elongated PET sheet. A structural color caused by this structure was observed.
If the cavity 12 was formed under the conditions of Example 1, a microscopic observation as shown in
For example, the cavity 12 formed by using a PET-INJ sheet as a sample 30 under the condition of YAG-THG (355 nm), 247 mJ/cm2 and 30 laser shots had a shape shown in
Furthermore, the cavity 12 formed by using a PET-INJ sheet as the sample 30 under the condition of YAG-SHG (532 nm), 500 mJ/cm2 and 10 shots had a shape shown in
A biaxial elongated PET sheet was irradiated with a laser having a wavelength of 266 nm in the same manner as in Example 1. A structural color was observed by the formed two-dimensional periodic structure.
To this periodic structure, an ester oil (CAS-Nr: 195371-10-9) having a refractive index of 1.518 which is close to that of the elongated PET sheet (1.64) was applied. As a result, the sheet was observed like the original transparent elongated PET sheet since no structural color was observed.
Next, comparison between the structural body of this embodiment and the structural body of the comparative example is explained with reference to
(Comparison Between the Cavity of this Embodiment and Pores of the Comparative Example)
JP-A-2004-359344 discloses a technology of developing a color by forming a plurality of fine pores (“Plastic package and a method for decorating the same”, hereinafter abbreviated as “Comparative Example 1”).
The structural body of Comparative Example 1 and the structural body of this embodiment are compared to clarify the difference.
In Comparative Example 1, the pores formed by gasification due to heat generation are arranged according to the periodic light intensity distribution.
On the other hand, in the invention, cavities are formed by a photochemical reaction between laser light and a material, and a periodic structure is formed in the interface according to a periodic light intensity distribution. The cavities are not necessarily formed periodically.
The structure of the pore of Comparative Example 1 and the structure of the cavity of the invention are shown in
As shown in
On the contrary, in the invention (Example), a periodic structure is formed in the interface of the cavity, and this periodic structure has a regular arrangement which enables decoration.
In Comparative Example 1, since heat generation by laser light irradiation is utilized, a light-absorbing heat generator was kneaded to efficiently convert light energy to heat energy.
In contrast, in the invention, use of a specific additive is not necessary.
The difference between these samples is shown in
The method in Comparative Example 1 is a method in which heat generation by laser beam irradiation is utilized. In contrast, in the invention, a structural body is formed by using laser light irradiation, without using heat generation.
Here, the laser light irradiation conditions in the Example of the invention and the laser light irradiation conditions of Comparative Example 1, which is described in the background of the JP-A-2004-359344 as the third embodiment, are shown in
In
As shown in
It is also understood that the forming method of the invention needs a smaller fluence as compared with Comparative Example 1.
As mentioned hereinabove, according to the structural body, the method for forming a structural body and the apparatus for forming a structural body, a cavity is formed in the inside of a material to be irradiated, and a periodic structure having a periodic intensity distribution of irradiation light is formed in the interface of the cavity.
As a result, the structural body may have resistance to scars or spots which cause color developability to be lowered. Furthermore, by forming the cavity three-dimensionally, color developability can be significantly improved. In addition, due to the shortened formation time, productivity can be enhanced. As mentioned above, while satisfying the requirements for practically putting a structural color into practical use, decoration of a material is enabled with a high degree of recycling properties.
Since no chemical colorant such as a pigment and a dye is used, the structural body of the invention is a material which imposes a lesser burden on the environment due to the decrease in use of the amount of chemicals.
Furthermore, in the structural body of the invention, decoration is made by a periodic structure formed in the interface of the cavity. Therefore, the decoration can be deleted easily by heating and kneading (re-pelletizing) at the time of recycling. Therefore, although the structural body is decorated when used as a container, it becomes colorless and transparent after re-treatment, and hence, exhibits a high degree of recycling properties.
In addition, unlike chemical color development, since a vivid color tone having a deep shade and gloss can be obtained, differentiation of products can be performed effectively by decoration.
Furthermore, by using a structural color and/or diffraction light due to the periodic structure formed in the structural body itself, it is possible to verify whether an object is genuine or not. In addition, since the periodic structure is formed in the inside of the structural body, it is impossible to remove it for application to other objects. Therefore, unlike the conventional hologram seal, the act of removing and reusing by attaching to a forgery product with the aim of allowing the forgery product to be put on the market as a genuine product can be prevented.
In addition, since the periodic structure is formed on a single substrate, it is not required to form a complicated structure by combining a plurality of materials. Therefore, constitution of the material can be simplified, thereby eliminating an increase of the raw material cost.
Furthermore, since the periodic structure can be formed by light irradiation, the structural body can be formed at a low cost without the need of introducing an expensive apparatus for forming the structural body.
Hereinabove, the preferred embodiments of the structural body, the method for forming a structural body and the apparatus for forming a structural body are explained. However, the structural body, the method for forming a structural body and the apparatus for forming a structural body are not limited to the above-mentioned embodiments. It is needless to say that various modifications are possible within the scope of the invention.
For example, in the above-mentioned embodiments, PET was used as the sample. PET can be used, for example, as a material for containers, cups, pouches, trays, and tubular containers. In this case, the invention can be provided as a technology of decorating plastic containers with a high degree of recycling properties.
In the above-mentioned embodiment, the substrate surface periodic structure is formed only on one surface of the substrate. However, the substrate surface periodic structure is formed not only on a single surface, but may be formed on two or more surfaces. For example, the substrate surface periodic structure may be formed on both sides of a sheet element, or on two or more sides of a cubic element.
In the above-mentioned embodiment, a forgery-protection marking is given as the application of the invention. The application of the invention is not limited to the forgery-protection marking. For example, the invention can be applied to decoration, utilizing the effect in which an internal marking appears by the above-mentioned reading method.
The invention is provided for realizing development of a structural color on the industrial scale. Therefore, the invention can be applied to a field where a material requiring decoration is used.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2006-109958 | Apr 2006 | JP | national |
| 2007-059529 | Mar 2007 | JP | national |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 12225810 | Sep 2008 | US |
| Child | 13343343 | US |
