The present invention relates to an innovative and optimized system and method for maintaining water quality in large artificial excavated inland water bodies or floating structures using a simplified economic filtration system and degreasing system that requires much smaller filtration equipment than conventional centralized filtration systems and provides for consumption of significantly lower amounts of energy, where the method for maintaining water quality is based on the color of the bottom of the body of water, the amount of surface greases and turbidity of the water. U.S. Pat. No. 8,518,269, No. 8,062,514, No. 8,070,942, No. 7,820,055, No. 8,454,838, No. 8,465,651, No. 8,518,269, No. 8,070,342, and U.S. Patent Application Publication No. 20110110076, 20110108490, No. 20130240432, No. 20130264261, No. 20130213866, No. 20130306532, and No. 20110210076, are hereby incorporated by reference in its entirety.
Water in swimming pools is usually filtered and treated with chemicals to maintain the quality of water within suitable levels and in compliance with local regulations. Filtration systems are designed to eliminate, e.g., suspended solids, including microbial and algal growth, floating debris, and oil and greases in the water. Conventional systems for maintaining water quality in swimming pools typically involve large centralized filtration systems that are expensive to construct and to operate. A conventional centralized filtration system is usually configured to filter the entire volume of water in a pool from about 1 to 6 times per day. The operation of such centralized filtration systems is energy intensive and causes swimming pools to have a large carbon footprint and limits the maximum size of conventional swimming pools.
Water is typically directed to the centralized filtration system from three sources: the main body of water in the pool; water suctioned from the bottom of the pool containing settled impurities; and water drawn from the surface of the pool by skimmers. All three sources are treated by the same centralized filtration system regardless of different levels and types of impurities. In addition, conventional centralized filtration systems operate according to certain defined periods of time, or for certain amount of hours a day without taking into account the real time condition of the water being treated and/or without adjusting operational parameters and filtration requirements to optimize efficiency of the system in view of the real time condition of the water being treated.
Conventional centralized pool filtration systems therefore have high equipment costs and consume large amounts of energy to complete such filtration requirements. The Association of Pool and Spa Professionals estimates that there are more than 5.5 million swimming pools in the United States equipped with conventional centralized filtration systems. According to the U.S. Department of Energy, conventional pool filtration systems are very energy intensive, using up to 3,000 kWh of electricity per year, the equivalent of about 30% of an average household's electricity consumption, as per the Energy Information Administration. The California Energy Commission estimates that a typical backyard swimming pool in California can use enough energy during the summer season as would be needed to power an entire home for three months. Reducing the amount of energy needed for filtration would provide savings in the cost of maintenance of the pools and also reduce CO2 emissions.
The cost and high energy demand of operating a pool with conventional centralized filtration systems has caused closures of some large public swimming pools around the world. For example, according to the Japan Times, the “Ocean Dome” indoor swimming pool located in Japan (which holds the Record Guinness as the largest indoor swimming pool in the world, with over 1 hectare of water surface) had to be closed in 2007 due to high operational costs. Another example is the “Fleishhacker Pool” located in California, with a surface of 1.5 hectares, which had to be closed on 1971 due to water quality problems and high costs.
With a trend toward more sustainable and ecological practices, regulatory agencies throughout the world are enacting regulations that aim to lower energy consumption and reduce CO2 emissions of swimming pool operations. Because of the need for lower energy consumption and more cost effective filtration systems, it is desirable to have a method that is capable of maintaining water quality at a lower capital and operating cost. A trend toward more sustainable operations is also driving the need for more energy efficient systems and methods for maintaining water quality in large water bodies, such as swimming pools.
Turbidity of water can be used as a measure of water quality. Turbidity is caused by microscopic suspended solid particles that result in “cloudiness” of the water. The particles may include many different types of impurities, such as inorganic and organic particles, microbes, and algal growth. Turbidity of water can be reduced, for example, by filtration or by causing the particles to agglomerate or react with chemicals, making them heavy enough to settle to the bottom. U.S. Pat. No. 4,747,978 discloses a method of disinfecting swimming pool water by use of calcium hypochlorite compositions including an inorganic flocculant (e.g., aluminum sulfate) that can provide improved clarity upon addition to a body of water, e.g., a swimming pool. The '978 patent discloses that water clarity can be improved by the simultaneous settling of organic materials and suspended solids due to the addition of the flocculant, but at the same time discourages the use of too much flocculant in order to avoid plugging the filtration system. Also, such method requires filtration of the complete water volume.
Chinese patent publication CN2292798 discloses a water circulation treatment and underwater dirt collecting device for a swimming pool including a treating and circulating water discharging impurities. The '798 publication discloses adding flocculant, algaecide sterilizing agent and pH regulating agent to the water, filtering the water and returning the water back to the swimming pool. The dirt is suctioned from the bottom of the pool by a dirt collecting disc which moves along the bottom, and the sediment accumulated at the bottom of the pool is discharged out of the pool. However, even in this treatment system, the entire body of water is filtered. The '798 publication does not address the issues associated with high filtration volumes and does not disclose controlling the operation of the suctioning system or the filtration system based on observed water quality parameters. The '798 publication also fails to address the treatment of skimmed water that is typically sent through the centralized filtration system, thus adding to the total filtration volume.
The optimized system and method of the present invention replaces conventional centralized filtration systems from traditionally configured swimming pools with a simplified economic filtration system and degreasing system that consumes up to two orders of magnitude less energy, and requires much smaller filtration equipment than conventional filtration systems. The method replaces the three filtration requirements from conventional centralized filtration systems used in swimming pools, which are: the filtration of the entire body of water contained in the swimming pool; the filtration of the water suctioned from the bottom that contains settled impurities; and the filtration of the surface water drawn by a skimmer system. In such a conventional system, the three water flows are sent to the same centralized filtration system in order to remove suspended solids, floating debris and greases.
The disclosed system and method provide for a significantly lowered need for filtration capacity by suctioning a small water flow from the bottom of the large water body (e.g., a pool) that contains settled impurities, thus avoiding filtration of the entire body of water and the centralized filtration of skimmed water is replaced by screening of debris and skimming of oil and grease. The system and method of the invention allows activating the operation of specific systems based on the received information regarding different water quality and physicochemical parameters. These parameters often include turbidity, the color of the bottom of the water body, and amount of greases on the surface water layer of the water body, which can be directly or indirectly measured, empirically estimated, determined according to experience, based on sensorial methods, or calculated. The chemical application system, mobile suctioning device, and degreasing system are each operated only when needed based on the actual need for filtration or purification dictated by the quality and physicochemical parameters of the water in the water body, such as turbidity of the water, amount of settled impurities, and/or amount of greases or oils on the surface water layer of the water body, rather than a pre-set schedule or required filtration rates as in conventional centralized swimming pool filtration systems.
The method additionally provides for adding a chlorine-based additive to the water to maintain a minimum free residual chlorine level in the water body or in a specific bathing zone, where such minimum free residual chlorine concentration is considerably lower than conventional concentrations used in swimming pools as the large water bodies from the present invention have large water volumes that provide an additional dilution effect. The minimum free residual chlorine level from the present invention is based on the WQI which comprises a group of variables that are not usually applied in small water volumes such as swimming pools.
The method for treating a large water body generally includes applying an effective amount of a flocculant to water in the water body to maintain turbidity of the water below 2 NTU, wherein the flocculant flocculates impurities in the water into particles that settle to the bottom of the water body; operating a mobile suctioning device to maintain the increase in the black component of the bottom's color below about 30%, wherein the mobile suction device suctions a portion of water from the bottom of the water body containing settled particles; filtering the water suctioned by the mobile suction device and returning the filtered water to the water body, wherein the water suctioned by the mobile suction device does not exceed about 10% of the total water volume of the water body in a 24 hour interval; and activating operation of a degreasing system to maintain a surface water layer having less than about 20 mg/L of floating greases, wherein greases from a surface water flow into the degreasing system are removed by a separation unit comprising a degreaser and the treated water is returned to the water body.
In an embodiment, the system includes a control system that can activate the operation of the chemical application system, mobile suctioning device, and/or degreasing system based on received water quality and physicochemical parameters including turbidity, the color of the bottom of the water body, and amount of greases on the surface water layer of the water body, to adjust the water quality and physicochemical parameters within predetermined limits.
The system for maintaining water quality in a large water body generally includes a chemical application system for dosing a flocculant into the water, wherein the chemical application system is activated to apply flocculants to the water in the water body to maintain turbidity of the water below 2 NTU, and for optionally applying a chlorine based additive to maintain a minimum free residual chlorine level in the water; a mobile suctioning device capable of moving along the bottom of the water body and suctioning a portion of water from the bottom containing settled solids, where the mobile suctioning device is activated when the bottom's color black component increases more than 30% on a CMYK scale; a filtration unit in fluid communication with the mobile suctioning unit, wherein the filtration unit receives the portion of water suctioned by the mobile suction unit; a degreasing system for providing a surface water flow from the water body to the separation unit, wherein the degreasing system is activated to maintain a surface water layer having less than about 20 mg/L of floating greases; and one or more return lines for returning filtered water from the filtration unit and the degreasing system to the water body.
The following detailed description refers to the accompanying drawings. While embodiments of the invention may be described, modifications, adaptations, and other implementations are possible. For example, substitutions, additions, or modifications may be made to the elements illustrated in the drawings, and the methods described herein may be modified by substituting, reordering, or adding stages to the disclosed methods. Accordingly, the following detailed description does not limit the scope of the invention. While systems and methods are described in terms of “comprising” various apparatus or steps, the systems and methods can also “consist essentially of” or “consist of” the various apparatus or steps, unless stated otherwise. Additionally, the terms “a,” “an,” and “the” are intended to include plural alternatives, e.g., at least one, unless stated otherwise. For instance, the disclosure of “a disinfectant agent,” “an inlet line,” “a mobile suction device,” etc., is meant to encompass one, or more than one, disinfectant agent, inlet line, mobile suction device, etc., unless otherwise specified.
Conventional centralized filtration systems in swimming pools typically require filtration of the entire body of water about 1 to 6 times per day. In such filtration systems, water from different sources, such as intake pipes, suctioning devices, drains, skimmers, and overflow is collected and sent to a centralized filter.
The present invention is directed to a method and system for treating large water bodies, where the large water bodies can be artificially constructed on land such as excavated structures, or floating structures installed within natural or artificial lakes, ponds, basins, rivers, the sea, or others. The term “water body” as used herein refers to any body of water, either artificially constructed on land or a floating structure, generally capable of being used for recreational use or for sports, including pools, lagoons, tanks, lakes, water features, artificial ponds, artificial lakes, floating lagoons, and the like. The large water bodies of the present invention generally have a water surface area of at least about 7,000 m2. In some embodiments the large water body may have a surface area of 20,000 m2, 40,000 m2, 100,000 m2, or more.
The water body can be constructed with characteristics that are suitable for performing the method of the present invention, where the bottom comprises a non-porous flexible material such as a flexible membrane. Such non-porous flexible material is not used generally for conventional concrete swimming pools, but it is used for large water bodies such as retention and irrigation ponds, and for example small kids above ground pools, and other large water bodies due to its flexibility that allows for easier installation and provides structural advantages compared with non-flexible materials such as concrete used in conventional swimming pools, also having lower costs.
The non-porous flexible material preferably comprises a liner, such as a membrane or plastic liner, and may have a thickness in the range of about 0.1 mm to about 5 mm. Examples of suitable materials include, but are not limited to, rubbers, plastics, Teflon, low density polyethylene, high density polyethylene, polypropylene, nylon, polystyrene, polycarbonate, polyethylene terephthalate, polyamides, PVC, acrylics, and combinations thereof. In other embodiments, the liner can be constructed of composite materials. According to embodiments, the liner allows avoiding adherence of settled impurities produced by the method's processes or natural falling debris, dust, pollen, or other suspended solids that fall into the bottom of the water body.
In an embodiment, the method and system from the present invention is used on artificially constructed inland water bodies. In order to build such water bodies, earthworks may be required to excavate a hole in the ground to generate a desired depth for the water body. The non-porous flexible material (e.g., a membrane or plastic liner) may be installed on the bottom of the excavated water body. The non-porous material can be thermo fused, or an extruded HDPE concrete embedment strip can be used for liner attachment to provide an even layer in the bottom and provide the non-permeable properties to the bottom of the water body.
Earthworks and soil compaction may be used to provide slopes within the water body (e.g., a sloping bottom). According to an embodiment, the slope of the bottom is preferably no greater than 20% in order to allow a mobile suctioning device to move along the bottom of the water body.
The walls of the water body may be sloped or vertical. In an embodiment, the slope of the walls is no less than about 45% in order to avoid attachment of settling solids, debris, or other impurities on the walls. Preferably, the slope of the walls of the water body are greater than about 60% in order to avoid any accumulation of settled solids, debris, and the like on the walls. In an embodiment, the slope of the walls is greater than about 80%. In another embodiment, the slope of the walls is greater than about 90%.
The soil conditions in the location where the water body is constructed preferably allow for generating a compacted soil with low permeability. During construction of the water body, the soil may be compacted more or less depending on the particle size of the soil. Soil compaction can be measured as a percentage of the relative density (RD) of the soil or as a percentage of the soil's most dense state, the maximum dry density (MDD). Relative density of the soil and methods used to calculate relative density are defined in ASTM D4254-00 (2006). The maximum dry density (MDD) of the soil can be determined according to a modified proctor compaction test according to ASTM D1557-12. The compacted soil should attain a degree of compaction based on a mesh test of No 200 with an opening of 0.075 mm.
According to an embodiment, if the amount of soil passing through the N 200 mesh (the “passage rate”) is less than 12%, the soil should be compacted to at least about 80% of its relative density (RD). If the amount of soil passing through the No 200 mesh is 12% or higher, the soil should be compacted to at least about 85% of its maximum dry density (MDD).
The natural terrain may also be leveled to accommodate the water body and related equipment and facilities. The top layer of the natural terrain may contain organic matter and may be removed to avoid using such soil for compaction and structuring the slopes. Preferably, the removed layer of soil is at least 5 cm, more preferably at least 10 cm, and most preferably at least 25 cm. The walls of the excavated water bodies can be built out of soil and can be reinforced with concrete or other materials, or can be built out of structural materials such as concrete or others, which may provide structural stability to the water body. In an embodiment, the walls of the water body may also comprise non-porous flexible membranes.
In some existing systems the skimmers perform a double function, where the water drawn from both the surface water and the main body of water 170 are drawn through the skimmer system 152 to be sent into the centralized filter 180. In this case, the surface water and main body of water are drawn through the skimmer system, and the result of the two water flows is sent into the centralized filter 180. Therefore, the skimmers cover a double function of renovating the water by filtering the total water volume from 1 to 6 times per day and also removing floating surface impurities. However, while the two water flows (surface water and main water body) are drawn through the skimmers, the total water flow and filtered water volume remains unchanged as the filtration requirements for the centralized filter still include the filtration of the total water body from 1 to 6 times per day, and therefore the centralized filter would still be required to have a very large capacity, and hence a very large energy consumption. Also, the filtration requirements of the surface water are usually completely different than the filtration requirements for the main water body. If for example, just the surface water was filtered, the amount of energy consumption for filtration would be reduced by 2 orders of magnitude compared to filtering the surface water together with the main water body from 1 to 6 times per day.
The present invention includes a method and system for maintaining water quality that provides for elimination of the large centralized filtration system in water bodies. The system of the invention includes a chemical application system, mobile suctioning device, filtration system, and/or degreasing system that are activated based on the information received regarding specific water quality and physicochemical parameters such as turbidity, the color of the bottom of the water body, and amount of greases on the surface water layer.
According to a method of the present invention, a chemical agent, such as a flocculant, can be added to prevent the turbidity of the water from exceeding a predetermined Nephelometric Turbidity Unit (NTU) value. The term “flocculant” as used herein refers to a chemical agent or composition that promotes or induces agglomeration, coagulation, or flocculation of impurities, such as suspended solids, organic matter, inorganic matter, bacteria, algae, and the like, in the water body into particles or “floccules” which then settle to the bottom of the water body. As used herein, the term “settled impurities” refers to the particles, floccules, or other debris such as dust, pollen, and the like, that have settled to the bottom of the water body. A mobile suctioning device capable of moving along of the bottom of the water body, can be activated to remove settled particles from the bottom of the water body. The mobile suctioning device can be used in the bottom of the water bodies, where such bottoms comprise a non-porous flexible liner, such as a membrane or plastic liner as described herein.
The water bodies may be artificially constructed inland as excavated structures or floating structures installed within large lakes, basins, ponds, rivers, the sea, or others. In an embodiment, the mobile suctioning device is supported over brushes to avoid damaging the bottom of the land-based artificially constructed excavated structures or of the floating structure. In an embodiment, the suctioning device is a self-propelled device. In another embodiment, the suctioning device allows concentration of suctioning power at suction points distributed along the bottom of the device, which allows avoiding re-suspension of the settled solids and debris found on the bottom of the water bodies, and therefore providing higher suctioning efficiency. In an embodiment, the suctioning device is capable of cleaning at a surface cleaning rate of 10,000 m2 per 24 hours.
The mobile suctioning device suctions a portion of the water from the bottom of the water body containing the settled particles. A filtration unit in fluid communication with the mobile suction device can receive the suctioned water flow from the mobile suctioning device and filter the water, which is then returned to the water body. The timing of the suctioning and filtration of water containing settled particles from the bottom of the water body can be based on actual need and not according to certain defined periods of time or certain amount of hours per day as in a conventional centralized filtration system.
Also, it must be noted that conventional swimming pools require maintaining high and permanent residual chlorine levels to allow proper disinfection in case contamination enters the swimming pools, as swimming pools have small water volumes. On the other hand, the present invention provides an innovative method where the minimum residual chlorine level is based on the Water Quality Index, which allows incorporating different variables that are applicable to large water bodies to determine its water quality and therefore estimate the minimum free chlorine level. This allows providing a minimum residual chlorine level that is considerably lower than for conventional swimming pools, as the quality of large water bodies can be assessed through different parameters not usually applied for conventional swimming pools, and also since large water bodies provide an additional dilution effect which allows maintaining lower chlorine concentrations than for conventional small sized swimming pools.
The Water quality index (WQI) is a dimensionless number that allows combining different water quality parameters into a single index by normalizing values to subjective rating curves. The WQI has been used for evaluating the quality of water of large water bodies such as lakes, lagoons, rivers and others, and factors included in the WQI can be modified depending on the designated water use of the water body or specific preferences. The NSF (National Sanitation Foundation) Water Quality Index can be determined by using eight common water quality parameters including dissolved oxygen, fecal coliform bacteria, pH, 5-day BOD (biochemical oxygen demand), total phosphorus, nitrate-nitrogen, turbidity, and total dissolved solids or may be determined through empirical methods, algorithms based on experience, and analytical methods. The WQI takes the complex scientific information of these variables and synthesizes into a single number.
The water quality of the assessed water body as determined by WQI can range from good, fair, to poor water quality. In an embodiment, the Water Quality Index can be determined by weighting the parameters to allow proper influence in the index:
The weights can be adjusted so that they add up to 1 in case the number of factors is not 9. Generally, the ranges for evaluating the WQI are as follows:
Turbidity, oxygen demand, nutrients, and bacterial counts allow for assessing the water quality of the specific water body that is being analyzed in order to provide proper treatment.
Application of a chlorine-based additive is activated in order to maintain at least a minimum free residual chlorine level. In an embodiment of the invention, the activation of the application of a chlorine-based additive is done through a control system. In an embodiment, application of a chlorine based additive is activated to maintain a minimum free residual chlorine level, where the minimum free residual chlorine level cannot be lower than the value resulting from the following equation:
Minimum Free Residual Chlorine Level=(0.3−0.002(WQI−100))ppm
An exemplary water quality analysis is presented in Table 3 below:
The weights are adjusted for 7 factors. The calculated WQI index is 63, and the minimum free chlorine level in the water may be calculated as follows:
Minimum Free Residual Chlorine Level=(0.3−0.002(63−100))ppm
Minimum Free Residual Chlorine Level=0.374ppm
According to an embodiment, the minimum amount of chlorine in the water is maintained at or above the level determined by the above calculation.
If required, the level of free residual chlorine may be determined through many different methods, including empirical methods, analytical methods, algorithms based on experience, sensorial methods, and regulatory requirements. In one embodiment, the free residual chlorine level is not lower than the value resulting from the equation for determining minimum free residual chlorine level as disclosed above. In an embodiment, the minimum residual chlorine level is maintained continuously in the water. For example, the minimum residual chlorine level is maintained continuously in the water for a period to time, such as for a week or months at a time, for operation during daylight, or for the duration of a swimming season. In another embodiment, the minimum residual chlorine level is maintained while the water body is in use.
The method of the invention further provides a degreasing system that replaces the centralized filtration of skimmed water in a conventional centralized filtration system. Operation of the degreasing system of the method of the invention is typically based on the amount of greases found on the surface water layer, which in combination with application of the chemical agent to regulate turbidity of the water body, and the timing of the suctioning and filtration of the portion of water containing settled particles from the bottom of the water body based on actual need, provides a method capable of maintaining water quality without complete filtration of the water body.
In an embodiment, the system 10 includes a control system for maintaining the quality of the water in the water body 1 within predetermined water quality and physicochemical parameters. The control system activates the addition of chemical agents, the removal of impurities from the water, and the removal of greases from the surface water layer based on water quality and physicochemical parameters. The control system is configured to receive information about certain water quality and/or physicochemical parameters, process the information, and initiate processes (e.g., chemical application, suctioning, filtration, and degreasing).
According to an exemplary embodiment shown in
According to an embodiment, the control system for coordinating the addition of chemical agents and filtration comprises an automated system. The automated system may be programmed to monitor water quality parameters continuously or at pre-set time intervals, and to compare the results to a predetermined value. For example, the automated system may initiate addition of chemical agents for removing impurities from the water, operation of the mobile suction device, and/or operation of the degreasing system upon detecting a crossing of a value. According to an alternative embodiment, the control system comprises manually activating the addition of chemical agents, operation of the mobile suction device, and/or operation of the degreasing system based on a determination of water quality and physicochemical parameters.
The control system may comprise an automated system that can be operated on site or remotely through the internet or other similar information-exchange systems. Such control system allows automatically and operating the processes and activating different systems within different periods of time. According to alternative embodiments, the activation of the processes may be completed by one or more people that manually obtain and/or enter and/or process information, or initiate and/or perform processes for maintaining water quality parameters.
In an embodiment, the system 10 provides for adding chemical agents to the water. According to an embodiment shown in
According to an alternative embodiment, as shown in
In yet another embodiment shown in
The system 10 typically comprises a filtration system 40. As seen in the embodiments of
According to an embodiment, the mobile suctioning device 42 is capable of moving along the bottom 2 of the water body 1. However, to maximize the efficiency of removal of debris, particulates, solids, flocs, and/or other impurities that have settled on the bottom 2, the mobile suctioning device 42 can be configured such that its movement creates minimal dispersion of the settled materials. In an embodiment, the mobile suctioning device 42 is configured and operated to avoid the re-suspension of less than 30% of the settled materials that are found on the bottom. In an embodiment, the mobile suctioning device 42 is configured to not include parts, such as rotating brushes that could function to re-disperse a substantial portion of the settled materials from the bottom 2 of the water body 1 during operation of the suctioning device.
The operation of the mobile suctioning device 42 can be controlled by the control unit 22 or manually by an operator. According to an embodiment shown in
The mobile suctioning device 42 may comprise a pump, or a separate pump or pumping station may be provided to suction the water and to pump the suctioned water to the filtration unit 44. The separate pump or pumping station may be located within the large water body 1, along the perimeter of the water body 1, or outside of the water body 1.
It is also considered within the scope of the invention to incorporate a filtration unit directly into the mobile suctioning device 42 itself.
The mobile suctioning device 42 is typically in fluid communication with the filtration unit 44. The filtration unit 44 generally includes one or more filters, such as a cartridge filter, sand filter, micro-filter, ultra-filter, nano-filter, or a combination thereof. The mobile suctioning device 42 is typically connected to the filtration unit 44 by a collecting line 43 comprising a flexible hose, rigid hose, or a pipe, among others. The capacity of the filtration unit 44 is generally scaled to the capacity of the mobile suctioning device 42. The filtration unit 44 filters the water flow from the mobile suctioning device 42, corresponding to a small portion of the volume of water in the water body 1. Filtered water from the filtration unit 44 is returned to the water body 1 by a return line 60 comprising a conduit, which can be a flexible hose, rigid hose, a pipe, an open channel, or a combination thereof. Compared to a conventional centralized filtration system with capacity to filter the entire body of water in a water body 1 to 6 times per day, the filtration unit 44 is generally configured to have a filtration capacity that does not exceed 30% of the total water volume of the water body 1 in a 24 hour interval. Typically, the filtration capacity does not exceed 20% of the total water volume of the water body 1 in a 24 hour interval, and in a preferred embodiment it does not exceed 10% of the total water volume. The energy consumption of the filtration system is roughly proportional to size and, thus, significant costs savings can be expected with lower energy consumption, and requiring smaller equipment for the filtration process.
The system 10 further comprises a degreasing system 50. The degreasing system 50 can be used to separate floating debris and oils and greases from the water. The system 10 can further include a skimmer system hydraulically connected to the degreasing system 50, in order to efficiently purify skimmed water. As shown in
The skimmers provide a surface water flow to the separation unit. The operation of the degreasing system 50 may be continuous or intermittent depending on the actual needs of the water. For example, operation of the degreasing system 50 can be based on the amount of greases on the surface water layer. In an embodiment, the skimmer system is used to maintain a surface layer of water with less than about 40 mg/L of greases, typically less than about 30 mg/L and preferably less than about 20 mg/L. In an embodiment, the degreasing system 50 is activated before the top-most 1 cm of said surface water layer contains more than about 20 mg/L of floating greases. The operation of the skimming system 50 may be controlled by the control unit 22 (
Water quality in the water body 1 is typically maintained by adding chemical agents for removing impurities from the water, activating the mobile suctioning device 42 to remove settled impurities from the bottom 2 of the water body, and/or activating the degreasing system 50 to remove oils and greases from the surface water layer according to monitored or observed water quality parameters. Water quality in the water body 1 may be obtained, for example, for specific parameters such as turbidity, color, pH, alkalinity, hardness (Calcium), chlorine, microbial growth, among others. The chemical application system, filtration system, and/or degreasing system can be timely activated by the control system to maintain the water quality parameters within set limits. The systems can be activated based on an actual need (e.g., exceeding a water quality parameter), resulting in the application of smaller amounts of chemicals and using less energy than in conventional swimming pool water treatment methods.
In some embodiments, water bodies of the present invention are considerably larger than conventional swimming pools, and therefore homogeneity may not be achieved throughout the complete water body by using conventional chemical application systems. Large water bodies tend to generate “dead zones” or “stagnant zones” which are not affected by the chemicals due to currents, mixing, winds, or other effects, and which may not present the same conditions as the rest of the water body. The application of additives in the present invention is done such that the water body does not have considerable water quality differences. According to an embodiment, the differences in water quality between two different locations is not higher than 20%, for periods of time longer than 4 hours. The chemical application systems from the present invention comprise injectors, sprinklers, dispensers, manual application, and piping.
In embodiments, water quality parameters can be obtained manually, for example by visual inspection based on experience, by sensorial methods, by using a water quality meter (e.g., a probe such as a pH probe, a turbidity meter, or a colorimeter), or by obtaining a sample and measuring water quality using an analytical method. Information about the water quality parameters can be obtained by or entered into the control system. In an embodiment, an automated control system may be programmed to monitor water quality parameters continuously or at pre-set time intervals, to compare the results to a predetermined parameter and to activate one or more systems when the parameter has been crossed. For example, the automated system may initiate addition of chemical agents, operation of the suctioning device, or operation of the degreasing system upon detecting a crossing of a predetermined parameter. In an alternative embodiment, water quality parameters may be obtained manually or visually through sensorial methods and the information entered into the control system, or the results may be compared to a predetermined value and addition of chemical agents, operation of the suctioning device, and/or operation of the degreasing system may be initiated manually. Chemical agents used to maintain water quality in the water body may comprise any suitable water quality treatment chemicals. For example, the chemical agents may comprise oxidants, flocculants, coagulants, algaecides, sterilizing agents, or pH regulating agents.
The turbidity of the water can be determined by a monitoring device 24 (system of
Generally, the flocculant is applied or dispersed into the water by the chemical application system. The flocculant may comprise a composition with synthetic polymers such as quaternary ammonium-containing polymers and polycationic polymers (e.g., polyquaternium), or other components with flocculant or coagulant properties. Suitable flocculants include but are not limited to multivalent cations (e.g., quats and polyquats); synthetic polymers (e.g., cationic polymers and anionic polymers); aluminum salts, such as aluminum chlorhydrate, alum, and aluminum sulfate; calcium oxide; calcium hydroxide; ferrous sulphate; ferric chloride; polyacrylamide; sodium aluminate; sodium silicate; and some natural agents such as chitosan, gelatin, guar gum, alginates, moringa seeds; starch derivatives; and combinations thereof. In embodiments, the flocculant has algaecide properties which kills and/or prevents the growth of algae in the water body. The use of flocculants having algaecide properties can reduce the amount of chlorine or other disinfectants in the water body, thus reducing chemical consumption and providing a sustainable operation.
In an embodiment, addition of flocculants is initiated before turbidity is equal to or exceeds a predetermined value, such as 2 NTU, 3 NTU, 4 NTU, or 5 NTU. The control system may be used to initiate the addition of flocculants before turbidity of the water exceeds a predetermined value in order to cause the flocculation and settling of organic and inorganic matter. Typically an effective amount of flocculant is added to the water to prevent the turbidity from exceeding the 2 NTU. The fraction of water in which the floccules collect or settle is generally the layer of water along the bottom of the water body. The floccules settle at the bottom 2 of the water body 1 and can then be removed by the mobile suctioning device 42 without requiring that all of the water in the water body 1 be filtered, e.g., only a small fraction is filtered. The “small fraction” of water being filtered is preferably less than about 10% of the total water volume of the water body in a 24 hour interval. In an embodiment, the small fraction of water being filtered is less than about 20% of the total water volume of the water body in a 24 hour interval. In another embodiment, the small fraction of water being filtered is preferably less than about 30% of the total water volume of the water body in a 24 hour interval. The amount of flocculant added to the water can be predetermined or can be calculated (e.g., by the control device 22 in
The color of the bottom of the water body can have a significant influence on the coloration of the water, providing an aesthetically appealing coloration to the water in the water body. The bottom of the water body typically has a color that lends an aesthetically pleasing color and appearance to the water in the water body. For example, the bottom 2 of the water body 1 may have a colored material with a white, yellow or blue color, among other colors. The settling of particulates, solids, flocs, and/or other impurities to the bottom of the water body may cause a change in the appearance of color of the bottom of the water body. For example, the settled impurities can make the color of the bottom 2 of the water body 1 appear darker than the original color. As the settled impurities collect on the bottom 2 of the water body 1, the color of the bottom 2 will become darker and thus the coloration of the bottom 2 will not be visible.
According to one method of the present invention, the operation of the suctioning device 42 is activated when the color of the bottom of the water body exceeds a predetermined value. In an exemplary embodiment shown in
In an exemplary embodiment, the color of the bottom of the water body can be monitored for changes in the black component on a CMYK. The CMYK color scale uses four colors expressed in percentages: cyan, magenta, yellow and black. The K-component of the CMYK scale is the black component of the color. For example, a color with CMYK 15%, 0%, 25%, and 36% represents a color with 15% cyan, 0% magenta, 25% yellow, and 36% black component. The black component of the bottom of the water body can be assessed by visually comparing the bottom color of the water body with standard CMYK charts or color palettes, by sensorial methods, empirical methods or algorithms based on experience, and determining the black component according to the percentage found in the CMYK chart.
Alternative color scales, such as the L*a*b* (or “Lab”) scale, can also be used. In the L*a*b* scale, color is measured on three axis, L, a, and b, where the L-axis measures lightness. An L-value of 100 indicates white and L=0 indicates black. Thus, if the actual or original color of the bottom of the water body has, for example, an L-value 75, the second value can be experimentally set at some lower L-value, such as L=50. For example, when impurities settle on the bottom 2 of the water body 1 and before the perceived color of the bottom 2 reaches L=50, the operation of the suctioning device 42 can be initiated.
According to an embodiment shown in
The bottom of the water body ordinarily has a color that lends a pleasing color and appearance to the water in the water body. For example, the bottom 2 of the water body 1 comprises a non-porous flexible membrane that may have a colored material such as white, yellow or blue. In an exemplary embodiment, the color of the bottom 2 of the water body 1 is measured by a monitoring device 24 (e.g., a colorimeter) of the control assembly 20. The perceived color of the bottom 2 of the water body 1 can be compared to its actual, original or desired color by empirical or analytical methods, such as algorithms based on experience, visual inspection, sensorial methods, comparison with color guides, colorimeters, spectrophotometers, and others.
The operation of the mobile suctioning device 42 can be activated through the control system. In an embodiment shown in
According to an embodiment, before an increase in the measured or perceived color of the bottom of the water body exceeds a predetermined value (such as black component equals about 30% on a CMYK scale (or other suitable color scale)), the operation of the mobile suctioning device 42 can be initiated by the control unit 22 of the coordinating assembly 20. The increase in the black color component can be compared to its actual, original or desired color. For example, a pump of the mobile suctioning device 42 can be actuated by a signal from the control unit 22. The color of the bottom of the water body can be further monitored and compared to another predetermined value to determine an end point of the operation of the suctioning device 42. For example, if the black component of the color of the bottom 2 of the water body 1 decreases below the predetermined value, the operation of the suctioning device 42 is discontinued. The predetermined value may be, for example, where the black component is 10%-units above value of the black component of the actual color of the bottom 2, or 5 units above, or 3 units above. For example, if the original color of the bottom 2 on the CMYK scale is 15%, 0%, 25%, 10% (the black component being 10%), the predetermined value can be set at 20% black, 15% black, or 13% black. Alternatively, the predetermined value may be predetermined based on the actual color of the bottom 2 of the water body 1 and the desired level of cleanliness of the water body 1.
In one embodiment, each parameter has predetermined values, and the appropriate corrective measure is taken (e.g., addition of additives or activation of the suctioning device 42) to adjust the water quality and maintain such parameters within their predetermined ranges or values. The corrective measure can be activated for a predetermined period of time, or until the parameters are adjusted. For example, if the turbidity has a predetermined value of 2 NTU, flocculants and other additives can be added to the water and the value re-determined until the value reaches 2 NTU or lower.
In an embodiment, the method is applied to different zones within a water body, such as bathing zones. In this embodiment, different areas of the water body can have different predetermined values. For example, in one area, the turbidity is adjusted to be less than 2 NTU, respectively, while a second area may have maximum value of 3 NTU. By having different maximum values for different areas, it is possible to maintain higher water quality in predetermined areas, for example, in areas designated for bathing, i.e., bathing zones, while allowing for slightly lower water quality levels in other areas.
The development of different water quality zones can be accomplished by determining the water quality parameters in each zone, as described herein, and comparing the determined parameter in each zone to the maximum predetermined value of that zone and applying the appropriate activity (e.g., adding flocculant, starting one or more skimmers and/or activating the suctioning device 42) only in the zone requiring such activity.
The system 10 and method of the present application provide the benefits of a smaller and more cost-efficient filtration system as compared to a conventional centralized filtration system and cheaper, more energy efficient operation. By using the system 10 and method of the present application, the scale and operation of the filtration system can be determined by actual water quality parameters and, therefore, by actual need for filtration or purification as described herein, rather than a pre-set schedule of 1 to 6 pool volumes per day regardless of real need. According to exemplary embodiments, a filtration system with a capacity up to 60 times smaller than conventional systems may be used. Compared to a conventional filtration system with capacity to filter the entire body of water in the pool 6 times per day, the system of the present application can be configured to have a filtration capacity that is 1/60 of the conventional system, or capacity to filter 1/10 (one tenth—10%) of the water body's volume per day. According to alternative embodiments, the system can be configured to a filtration capacity that is capable of filtering up to ⅕ (one fifth—20%) of the water body's volume per day or more. The energy consumption of the filtration system is roughly proportional to size and, thus, significant energy savings can be expected when the filtration system is operated according to the present method.
The following examples are illustrative, and other embodiments exist and are within the scope of the present invention.
The filtration needs of a large water body with a surface area of 2.2 ha (approximately 5.5 acres) and water volume of approximately 55,000 m3 (approximately 1,950,000 cubic feet or 14.5 million gallons) was studied by comparing a theoretical conventional filtration system with the method according to the present application. In the conventional filtration system, water drawn from the main body of water, the bottom of the artificially built water body, and surface water drawn by a skimmer system are all sent through a centralized filtration system sized for filtering the complete water volume 4 times per day.
In the method according to the present application, the water quality is maintained based on the different water quality parameters, where the parameters are determined by algorithms or based on experience and operated to maintain such parameters within its limits. Also, only the water from the bottom of the water body is sent through a filtration system. Surface water drawn from the degreasing system is sent through a degreaser and screens to eliminate oil, grease and floating debris. Table 4 shows the calculated filtration capacity, filter size and energy consumption for each system.
According to this example, the area utilized by the conventional centralized filtration system is more than 150 times larger than the area required by the filtration system of the present method, and the monthly energy consumption is about 100 times greater. As demonstrated by this Example, the present method allow for the use of much smaller, cost and energy efficient filtration systems for maintenance of water quality in water bodies.
The method of the present application was applied to a large recreational lagoon with a surface area of about 9,000 m2 and a volume of about 22,500 m3. The lagoon was equipped with a suctioning device capable of suctioning water and settled impurities from the bottom of the lagoon having a flow rate of about 25 L/s, and 22 skimmers around the perimeter of the lagoon each having a flow rate of about 2.2 L/s. Water from the suctioning device was sent to a filtration system to remove impurities, and filtered water was returned into the lagoon. The filtration system was equipped with a QMA 180 filter having a diameter of 1.8 m. Water from the skimmers was sent through a degreaser and screens to remove floating debris. Purified water was returned back into the lagoon.
The color of the bottom of the lagoon was visually inspected and was assessed against a CMYK color palette by an experienced technician. Turbidity was initially determined to be 0.55 NTU using a turbidimeter. Before turbidity exceeded 2 NTU, addition of treatment chemicals was initiated. The treatment chemical used was a cationic polymer flocculant that was added to achieve a concentration in the range of 0.02-1.0 ppm. After addition of the flocculant, the impurities causing turbidity agglomerated and settled to the bottom of the pool.
Sodium Hypochlorite was added to the water and a minimum residual concentration of 0.4 ppm was maintained. The minimum residual chlorine level was obtained by performing a series of experiments that involved measuring the microbiological count of the water for different residual chlorine levels until acceptable levels were achieved. It is important to note that the minimum residual chlorine level was not lower than the value resulting from the equation as follows:
Minimum Free Residual Chlorine Level=0.3−0.002(WQI−100))ppm
It must be noted that such minimum free residual chlorine level is lower than for conventional swimming pools, due to the large water volumes that allow providing an additional dilution effect and since the minimum free residual chlorine level is based on the WQI which assesses water quality parameters applicable to large water bodies.
The color of the bottom of the pool was again visually inspected to estimate the color black component. As an increase in the black color component approached 30% on the CMYK scale, operation of the suctioning device was initiated. The color of the bottom was further monitored, and suctioning was discontinued when the deviation in color black from the original color of the bottom was down to about 3%-units. At the same time, surface water was drawn by the skimmers and was cleaned of grease and floating debris. The method was applied to the bathing zones of the water body while such zones were in use.
To maintain an appropriate water quality for recreational use, the filtration needs, compared to the same size pool filtered with conventional centralized filtration, were as follows:
The filtration need when using the present method was only 25 L/s when filtration was based on monitoring actual water quality parameters. The filtration need using a conventional centralized filtration system for the same size pool, configured to filter the entire body of water two times per day (turnover rate of 12 hours) was 567 L/s, which is about 23 times higher.
While certain embodiments of the invention have been described, other embodiments may exist. While the specification includes a detailed description, the invention's scope is indicated by the following claims. Furthermore, while the specification has been described in language specific to structural features and/or methodological acts, the claims are not limited to the features or acts described above. Rather, the specific features and acts described above are disclosed as illustrative aspects and embodiments of the invention. Various other aspects, embodiments, substitutions, additions, modifications, and equivalents thereof which, after reading the description herein, may suggest themselves to one of ordinary skill in the art without departing from the spirit of the present invention or the scope of the claimed subject matter.
This application claims benefit of U.S. Provisional Ser. No. 61/915,331, filed 12 Dec. 2013 and which application is incorporated herein by reference. To the extent appropriate, a claim of priority is made to the above disclosed application.
Number | Name | Date | Kind |
---|---|---|---|
2071520 | Harrison | Feb 1937 | A |
2141811 | Everson | Dec 1938 | A |
2314767 | Burrell | Mar 1943 | A |
2646889 | August | Jul 1953 | A |
2923954 | Babcock | Feb 1960 | A |
3132773 | Hampton | May 1964 | A |
3247053 | Hodge | Apr 1966 | A |
3266631 | Snaper | Aug 1966 | A |
3317925 | Vance | May 1967 | A |
3361150 | Horner | Jan 1968 | A |
3406416 | Presby et al. | Oct 1968 | A |
3412862 | Chaplin | Nov 1968 | A |
3419916 | Schankler | Jan 1969 | A |
3470091 | Budd et al. | Sep 1969 | A |
3540274 | Shore | Nov 1970 | A |
3641594 | Hough | Feb 1972 | A |
3660957 | Schankler | May 1972 | A |
3695434 | Whitten, Jr. | Oct 1972 | A |
3748810 | Mattingly | Jul 1973 | A |
3788982 | Zsoldoes, Jr. et al. | Jan 1974 | A |
3844760 | Nelson | Oct 1974 | A |
3887666 | Heller et al. | Jun 1975 | A |
3949442 | Chandler | Apr 1976 | A |
3950809 | Schatzmann | Apr 1976 | A |
4055491 | Porath-Furedi | Oct 1977 | A |
4060575 | Uhlirsch et al. | Nov 1977 | A |
4063419 | Garrett | Dec 1977 | A |
4090266 | Price | May 1978 | A |
4100641 | Pansini | Jul 1978 | A |
4117683 | Rasmussen | Oct 1978 | A |
4119535 | White | Oct 1978 | A |
4129904 | Pansini | Dec 1978 | A |
4176058 | Grobler | Nov 1979 | A |
4254525 | Combest | Mar 1981 | A |
4254818 | Melamed | Mar 1981 | A |
4263759 | Miller | Apr 1981 | A |
4304022 | Sommer | Dec 1981 | A |
4306967 | Trautwein | Dec 1981 | A |
4338697 | Broadwater | Jul 1982 | A |
4343696 | Hung | Aug 1982 | A |
RE31087 | Sohl | Nov 1982 | E |
4402101 | van Zyl | Sep 1983 | A |
4464215 | Cogliano | Aug 1984 | A |
4519914 | Etani | May 1985 | A |
4548371 | Dempsey | Oct 1985 | A |
4572767 | McCord | Feb 1986 | A |
4581075 | St. Martin | Apr 1986 | A |
4592291 | Sullivan, III | Jun 1986 | A |
4640784 | Cant | Feb 1987 | A |
4652378 | Marikovsky et al. | Mar 1987 | A |
4692956 | Kassis | Sep 1987 | A |
4752740 | Steininger | Jun 1988 | A |
4767511 | Aragon | Aug 1988 | A |
4768532 | Johnson | Sep 1988 | A |
4776053 | Kiraly | Oct 1988 | A |
4835810 | Hugo | Jun 1989 | A |
4849024 | Supra | Jul 1989 | A |
4880547 | Etani | Nov 1989 | A |
4889622 | Newcombe-Bond | Dec 1989 | A |
4909266 | Massa | Mar 1990 | A |
4931187 | Derham et al. | Jun 1990 | A |
4948296 | Salter | Aug 1990 | A |
4952398 | Tapin | Aug 1990 | A |
5028321 | Stone et al. | Jul 1991 | A |
5039427 | Conover | Aug 1991 | A |
5106229 | Blackwell | Apr 1992 | A |
5107872 | Meincke | Apr 1992 | A |
5108514 | Ksiner | Apr 1992 | A |
5143623 | Kroll | Sep 1992 | A |
5164094 | Stuckart | Nov 1992 | A |
5172445 | Chandler | Dec 1992 | A |
5245723 | Sommer | Sep 1993 | A |
5268092 | Eden | Dec 1993 | A |
5293659 | Rief et al. | Mar 1994 | A |
5337434 | Erlich | Aug 1994 | A |
5342570 | Ledoux et al. | Aug 1994 | A |
5346566 | White | Sep 1994 | A |
5398361 | Cason | Mar 1995 | A |
5411889 | Hoots | May 1995 | A |
5422014 | Allen et al. | Jun 1995 | A |
5454129 | Kell | Oct 1995 | A |
5569371 | Perling | Oct 1996 | A |
5616239 | Wendell et al. | Apr 1997 | A |
5662940 | Hight et al. | Sep 1997 | A |
5782480 | Phillips | Jul 1998 | A |
5802631 | Friedman | Sep 1998 | A |
5833841 | Koslowsky | Nov 1998 | A |
5842243 | Horvath et al. | Dec 1998 | A |
5985156 | Henkin et al. | Nov 1999 | A |
6017400 | Clark et al. | Jan 2000 | A |
6149819 | Martin et al. | Nov 2000 | A |
6224826 | Katakura et al. | May 2001 | B1 |
6228272 | Gola | May 2001 | B1 |
6231268 | Hausenbauer | May 2001 | B1 |
6280639 | Ortiz | Aug 2001 | B1 |
6284144 | Itzhak | Sep 2001 | B1 |
6303038 | Sanders et al. | Oct 2001 | B1 |
6317901 | Corpuel | Nov 2001 | B1 |
6358409 | Jacoby, Jr. | Mar 2002 | B1 |
6409926 | Martin | Jun 2002 | B1 |
6419840 | Meincke | Jul 2002 | B1 |
6444176 | Yoshinaga et al. | Sep 2002 | B1 |
6539573 | Caccavella | Apr 2003 | B1 |
6620315 | Martin | Sep 2003 | B2 |
6896799 | Ohanian | May 2005 | B2 |
7163619 | Wang | Jan 2007 | B2 |
7189314 | Pace et al. | Mar 2007 | B1 |
7252843 | Moore et al. | Aug 2007 | B2 |
7820055 | Fischmann Torres | Oct 2010 | B2 |
7832959 | Groen et al. | Nov 2010 | B1 |
7862712 | Tak | Jan 2011 | B2 |
8153010 | Duarte et al. | Apr 2012 | B2 |
8388837 | Tormaschy et al. | Mar 2013 | B2 |
8454838 | Fischmann T. | Jun 2013 | B2 |
8465651 | Fischmann T. | Jun 2013 | B2 |
8518269 | Fischmann T. | Aug 2013 | B2 |
8524088 | Arbogast et al. | Sep 2013 | B2 |
20020117430 | Navarro et al. | Aug 2002 | A1 |
20030046933 | Moss et al. | Mar 2003 | A1 |
20030091467 | Kmec et al. | May 2003 | A1 |
20030094421 | Gargas | May 2003 | A1 |
20030228195 | Mizutani | Dec 2003 | A1 |
20040025269 | Pichon | Feb 2004 | A1 |
20040129644 | Unhoch | Jul 2004 | A1 |
20040211450 | Stoltz | Oct 2004 | A1 |
20040217326 | Souter et al. | Nov 2004 | A1 |
20040226896 | Lovestead et al. | Nov 2004 | A1 |
20050009192 | Page | Jan 2005 | A1 |
20050016906 | Gettman | Jan 2005 | A1 |
20050063782 | Stoecker et al. | Mar 2005 | A1 |
20050091934 | Kantor | May 2005 | A1 |
20050145552 | Sheets | Jul 2005 | A1 |
20050194322 | Palmer | Sep 2005 | A1 |
20050207939 | Roussi et al. | Sep 2005 | A1 |
20060054568 | Jones et al. | Mar 2006 | A1 |
20060169322 | Torkelson | Aug 2006 | A1 |
20060174430 | Pareti | Aug 2006 | A1 |
20060283808 | Kadlec et al. | Dec 2006 | A1 |
20070059562 | Hattori et al. | Mar 2007 | A1 |
20070181498 | Kaas | Aug 2007 | A1 |
20070181510 | Harvey et al. | Aug 2007 | A1 |
20080116142 | Fischmann Torres | May 2008 | A1 |
20080295615 | Sihalla | Dec 2008 | A1 |
20090050572 | McGuire et al. | Feb 2009 | A1 |
20090087549 | Zhou et al. | Apr 2009 | A1 |
20100320147 | McGuire et al. | Dec 2010 | A1 |
20110009019 | Neira et al. | Jan 2011 | A1 |
20110061194 | Fischmann Torres | Mar 2011 | A1 |
20110062067 | Fischmann Torres | Mar 2011 | A1 |
20110132815 | Angellili et al. | Jun 2011 | A1 |
20110137465 | Angelilli | Jun 2011 | A1 |
20110210076 | Fischmann Torres | Sep 2011 | A1 |
20120024794 | Fischmann T. | Feb 2012 | A1 |
20120024796 | Fischmann T. | Feb 2012 | A1 |
20140190897 | Wilson | Jul 2014 | A1 |
Number | Date | Country |
---|---|---|
1256250 | Jun 2000 | CN |
102092824 | Jun 2011 | CN |
2 141 460 | Feb 1973 | DE |
38 44 374 | Jul 1990 | DE |
19515428 | Nov 1996 | DE |
297 16 994 | Jan 1998 | DE |
198 14 705 | Oct 1998 | DE |
198 60 568 | Dec 1998 | DE |
10 2010 019 510 | Nov 2011 | DE |
0 352 487 | Jan 1990 | EP |
0 468 876 | Jan 1992 | EP |
0 483 470 | May 1992 | EP |
1 420 130 | May 2004 | EP |
168 85 62 | Aug 2006 | EP |
200 14 29 | May 1998 | ES |
2 544 005 | Oct 1984 | FR |
2 668 527 | Apr 1992 | FR |
2 685 374 | Jun 1993 | FR |
2 740 493 | Apr 1997 | FR |
2 785 898 | May 2000 | FR |
1494005 | Dec 1977 | GB |
2045606 | Nov 1980 | GB |
2 243 151 | Oct 1991 | GB |
59-012287 | Jan 1984 | JP |
59-222294 | Dec 1984 | JP |
4-115008 | Apr 1992 | JP |
5-220466 | Aug 1993 | JP |
04073612 | Aug 1993 | JP |
5-261395 | Oct 1993 | JP |
7-310311 | Nov 1995 | JP |
3026643 | Jan 1996 | JP |
10-169226 | Jun 1998 | JP |
2001-3586 | Jan 2001 | JP |
2001-9452 | Jan 2001 | JP |
2002-90339 | Mar 2002 | JP |
2002-282860 | Oct 2002 | JP |
2003-190989 | Jul 2003 | JP |
2003-200173 | Jul 2003 | JP |
2004-958 | Jan 2004 | JP |
2005-288392 | Oct 2005 | JP |
2006-68624 | Mar 2006 | JP |
2007-500073 | Jan 2007 | JP |
2011-5463 | Jan 2011 | JP |
20-0162956 | Sep 1999 | KR |
432013 | Aug 1987 | TW |
482186 | Dec 1990 | TW |
30184 | May 2007 | UY |
WO 8101585 | Jun 1981 | WO |
WO 9848132 | Oct 1998 | WO |
WO 03010388 | Feb 2003 | WO |
WO 2006069418 | Jul 2006 | WO |
WO 2007029277 | Mar 2007 | WO |
WO 2007059562 | May 2007 | WO |
WO 2009114206 | Sep 2009 | WO |
WO 2010074770 | Jul 2010 | WO |
Entry |
---|
International Search Report and Written Opinion for International Application No. PCT/IB2014/002891 mailed Apr. 29, 2015 (14 pages). |
African Regional Intellectual Property Organization (ARIPO) report for corresponding application No. AP/P/2007/004242 dated Dec. 7, 2010. |
Ballentine, “Ambient Water Quality Criteria for Bacteria—1986”, Jan. 1986, United States EPA, EPA440/5-84-002, p. 16. |
Chilean Examiner's report from Application No. 3900-08 issued Aug. 31, 2009. |
Communication from EPO for corresponding application No. 09835402.0 dated Jan. 30, 2013. |
Eurasian Office Action for corresponding application No. 201001477/31 and response to Office Action dated Apr. 2, 2013 with English Translation. |
European Search Report from European Application No. 07 07 5995 mailed Mar. 9, 2010. |
International Search Report and Written Opinion for International Application No. PCT/US2011/051129 mailed Feb. 8, 2012. |
International Search Report and Written Opinion for International Application No. PCT/US2011/051236 mailed Jan. 26, 2012. |
International Search Report and Written Opinion for International Application No. PCT/US2011/051244 mailed Jan. 25, 2012. |
International Search Report and Written Opinion for PCT/EP2012/076170 mailed Aug. 5, 2013. |
International Search Report mailed May 6, 2009, in co-pending related PCT Application No. PCT/US2009/036809. |
Japanese Office Action for corresponding application No. 2007-299975 dated May 31, 2011—translation provided. |
Norwegian Search Report from Norwegian Application No. 20075880 dated Feb. 4, 2010. |
Panama Search Report from Panama Application No. 88509-01 dated Oct. 7, 2010. |
Peruvian Technical Report for corresponding application No. 000244-2007 dated Sep. 2, 2010—translation provided. |
Response filed for EP 09835402.0 dated Aug. 14, 2013. (9 pages). |
Response filed for EP 09835402.0 dated Jul. 23, 2013. (11 pages). |
Second Singapore Office Action for corresponding application No. 200717963-3 dated Dec. 23, 2010. |
Singapore Office Action for corresponding application No. 200717963-3 dated Dec. 23, 2010. |
World Health Organization: Guidelines for safe recreational waters. vol. 2. Swimming pools and similar recreational water environments. Switzerland. Jun. 27, 2006 ISBN 92-4-154680-8 Chapter 4. |
World Health Organization: Guidelines for safe recreational waters. vol. 2. Swimming pools and similar recreational water environments. Switzerland. Jun. 27, 2006 ISBN 92-4-154680-8 Chapter 5. |
Number | Date | Country | |
---|---|---|---|
20150166361 A1 | Jun 2015 | US |
Number | Date | Country | |
---|---|---|---|
61915331 | Dec 2013 | US |