The present invention relates to a tire with a radial carcass reinforcement and more particularly to a tire intended for fitting to vehicles carrying heavy loads and travelling on unmade roads such as work site tracks, such as, for example, lorries, tractors or trailers.
In the tires of heavy duty type, the carcass reinforcement is generally anchored on either side in the area of the bead and is surmounted radially by a crown reinforcement made up of at least two layers that are superimposed and formed of threads or cords which are parallel in each layer and crossed from one layer to the next, forming angles of between 10° and 45° with the circumferential direction. The said working layers that form the working reinforcement may be further covered by at least one layer, referred to as a protective layer, formed by reinforcing elements which are advantageously metallic and extensible and referred to as elastic reinforcing elements. It may also comprise a layer of metal threads or cords having low extensibility, forming an angle of between 45° and 90° with the circumferential direction, this ply, called the triangulation ply, being located radially between the carcass reinforcement and the first crown ply, referred to as the working ply, formed by parallel threads or cords lying at angles not exceeding 45° in terms of absolute value. The triangulation ply forms a triangulated reinforcement with at least the said working ply, this reinforcement having low deformation under the various stresses which it undergoes, the triangulation ply essentially serving to absorb the transverse compressive forces acting on all the reinforcing elements in the crown area of the tire.
In the case of tires for “heavy duty” vehicles, just one protective layer is usually present and its protective elements are, in the majority of cases, oriented in the same direction and with the same angle in terms of absolute value as those of the reinforcing elements of the radially outermost and therefore radially adjacent working layer.
The circumferential direction of the tire, or longitudinal direction, is the direction that corresponds to the periphery of the tire and is defined by the direction in which the tire runs.
The transverse or axial direction of the tire is parallel to the axis of rotation of the tire.
The radial direction is a direction intersecting the axis of rotation of the tire and perpendicular thereto.
The axis of rotation of the tire is the axis about which it turns in normal use.
A radial or meridian plane is a plane which contains the axis of rotation of the tire.
The circumferential mid-plane, or equatorial plane, is a plane which is perpendicular to the axis of rotation of the tire and divides the tire into two halves.
Some current tires, referred to as “work site supply” tires are intended to run at relatively modest speeds, over fairly short journeys and over uneven ground. This combination of conditions in which such a tire is called upon to run may lead to significant tread damage although this is combined with a relatively long timewise period of use given the short distances covered; on the other hand, because of the running conditions and the service life, the endurance of the tires is penalized.
The particularly harsh tire running conditions caused by the uneven ground effectively result in there being limits regarding the endurance of these tires.
The elements of the carcass reinforcement are in particular subjected to bending and compressive stresses during running which adversely affect their endurance. Specifically, the cords which form the reinforcing elements of the carcass layers are subjected to high stresses during the running of the tires, in particular to repeated bending actions or variations in curvature, resulting in rubbing actions at the threads and thus in wear, and also in fatigue; this phenomenon is described as “fatigue fretting”.
In order to perform their role of strengthening the carcass reinforcement of the tire, the said cords first of all have to exhibit good flexibility and high flexural endurance, which implies in particular that their threads exhibit a relatively small diameter, preferably less than 0.28 mm, more preferably of less than 0.25 mm, generally smaller than that of the threads used in conventional cords for crown reinforcements of tires.
The cords of the carcass reinforcement are also subject to “fatigue corrosion” phenomena due to the very nature of the cords which favor the passage of and, indeed even drain, corrosive agents such as oxygen and moisture. This is because the air or the water which penetrates into the tire, for example when damaged by a cut or more simply as the result of the permeability, even though low, of the interior surface of the tire, can be conveyed by the channels formed within the cords by the very fact of their structure.
All these fatigue phenomena, which are generally grouped together under the generic term of “fatigue fretting corrosion” cause a progressive deterioration in the mechanical properties of the cords and can, for the most severe running conditions, affect the life of these cords.
In order to improve the endurance of these cords of the carcass reinforcement, it is known in particular to increase the thickness of the layer of rubber which forms the internal wall of the cavity of the tire in order to limit as much as possible the permeability of the said layer. This layer is usually partly composed of butyl, so as to increase the airtightness of the tire. This type of material exhibits the disadvantage of increasing the cost of the tire.
It is also known to modify the construction of the said cords in order in particular to increase their penetrability by the rubber and thus limit the dimension of the passage for the oxidizing agents.
Moreover, the use of tires on heavy duty vehicles of the “work site supply” type, notably when these tires are mounted in tandem on a drive axle or on trailers leads to undesired use in underinflated mode. Specifically, analysis has revealed that tires are often used underinflated without the driver being aware of this. Thus underinflated tires are regularly used. A tire used in this way experiences greater deformation than under normal conditions of use and this may lead to carcass reinforcement cord deformation of the “buckling” type which carries a high penalty notably in terms of ability to withstand the stresses associated with the inflation pressures.
In order to limit this problem associated with the risk of the buckling of the carcass reinforcement reinforcing elements, it is known practice to use cords that are wrapped by an additional thread surrounding the cord and preventing any risk of buckling of the cord or of the threads of which the cord is composed. Tires produced in this way, although less at risk from damage associated with running at low inflation pressures, do have lessened flexural endurance performance notably because of the rubbing between the wrapping thread and the outer threads of the cord as the tire is deformed during running
The inventors thus set themselves the task of providing tires for heavy vehicles for “heavy duty” vehicles of the “work site supply” type, the wear performance of which is retained and the performance, notably endurance performance, of which is improved in particular from the viewpoint of the “fatigue corrosion” or “fatigue fretting corrosion” phenomena, whatever the running conditions, notably in terms of inflation, and of which the manufacturing cost is reduced.
This objective has been achieved according to the invention by a tire with a radial carcass reinforcement, made up of at least one layer of reinforcing elements, the said tire comprising a crown reinforcement, itself capped radially by a tread, the said tread being connected to two beads by two sidewalls, the metal reinforcing elements of at least one layer of the carcass reinforcement being wrapped cords which, in the test referred to as the permeability test, return a flow rate of less than 20 cm3/min, and, in a radial plane and over the whole of the meridian profile of the tire, the thickness of rubber compound between the interior surface of the tire cavity and the point of a metal reinforcing element of the carcass reinforcement closest to the said interior surface of the cavity being greater than 1.0 mm and less than or equal to 3.0 mm.
The test referred to as the permeability test makes it possible to determine the longitudinal permeability to air of the cords tested, by measuring the volume of air passing along a test specimen under constant pressure over a given period of time. The principle of such a test, which is well known to those skilled in the art, is to demonstrate the effectiveness of the treatment of a cord to make it impermeable to air; it has been described for example in standard ASTM D2692-98.
The test is carried out on cords extracted directly, by stripping, from the vulcanized rubber plies which they reinforce, thus penetrated by the cured rubber.
The test is carried out on a 2 cm length of cord, which is therefore coated with its surrounding rubber compound (or coating rubber) in the cured state, in the following way: air is injected into the inlet end of the cord at a pressure of 1 bar and the volume of air at the outlet end is measured using a flow meter (calibrated for example from 0 to 500 cm3/min) During the measurement, the sample of cord is immobilized in a compressed airtight seal (for example, a seal made of dense foam or of rubber) so that only the amount of air passing along the cord from one end to the other, along its longitudinal axis, is taken into account by the measurement; the airtightness of the airtight seal itself is checked beforehand using a solid rubber test specimen, that is to say one devoid of cord.
The lower the mean air flow rate measured (mean over 10 test specimens), the higher the longitudinal impermeability of the cord. As the measurement is carried out with an accuracy of ±0.2 cm3/min, measured values less than or equal to 0.2 cm3/min are regarded as zero; they correspond to a cord which can be described as airtight (completely airtight) along its axis (i.e. in its longitudinal direction).
This permeability test also constitutes a simple means of indirect measurement of the degree of penetration of the cord by a rubber composition. The lower the flow rate measured, the greater the degree of penetration of the cord by the rubber.
The degree of penetration of a cord can also be estimated according to the method described below. In the case of a layered cord, the method consists, in a first step, in removing the outer layer from a sample with a length of between 2 and 4 cm in order to subsequently measure, in a longitudinal direction and along a given axis, the sum of the lengths of rubber compound in relation to the length of the sample. These measurements of lengths of rubber compound exclude the spaces not penetrated along this longitudinal axis. These measurements are repeated along three longitudinal axes distributed over the periphery of the sample and are repeated on five samples of cord.
When the cord comprises several layers, the first step of removal is repeated with what is now the outer layer and the measurements of lengths of rubber compound along longitudinal axes.
A mean of all the ratios of lengths of rubber compound to the lengths of samples thus determined is then calculated in order to define the degree of penetration of the cord.
The thickness of rubber compound between the interior surface of the tire cavity and that point of a reinforcing element that is closest to the said surface is equal to the length of the orthogonal projection onto the interior surface of the tire cavity of the end of that point of a reinforcing element that is closest to the said surface.
The measurements of the thickness of rubber compound are carried out on a cross section of a tire, the tire thus being in a non-inflated state.
According to a preferred embodiment of the invention, the cords of the carcass reinforcement in the test referred to as the permeability test return a flow rate of less than 10 cm3/min and more preferably of less than 2 cm3/min
The inventors have been able to demonstrate that a tire thus produced according to the invention results in highly advantageous improvements in terms of the compromise between endurance and manufacturing costs. Specifically, the endurance properties with such a tire intended for running of the “work site supply” type are at least as good as with the best solutions mentioned hereinabove, whether under normal running conditions or even under underinflated running conditions. Moreover, since the thickness of the layer of rubber compound between the carcass reinforcement and the cavity of the tire is reduced over the whole of the meridian profile of the tire in comparison with conventional tires and because this layer is one of the most expensive components of the tire, the cost of manufacture of the tire is lower than that of a conventional tire.
The carcass reinforcement cords which, in the test referred to as the permeability test, return a flow rate of less than 20 cm3/min make it possible on the one hand to limit the risk associated with corrosion and, on the other hand, appear to have an effect that counters the buckling of the cords thus making it possible to reduce the thickness of rubber compounds between the interior surface of the cavity of the tire and the carcass reinforcement.
The inventors have also been able to demonstrate that the nature of the cords as recalled hereinabove, which may be sufficient in other types of applications to limit the buckling of the said cords may run up against limits in applications of the “work site supply” type if run underinflated because of the extreme stresses experienced by the tires on highly uneven and notably highly rocky ground. The inventors have thus demonstrated that combining cords which, on what is referred to as the permeability test, return a flow rate of less than 20 cm3/min with the presence of a wrap on this cord makes it possible to combat the buckling of the cords, even in the aforementioned extreme situations.
Furthermore, these same extreme conditions of use of the tires if run under-inflated, because of the extreme stresses experienced by the tires on excessively uneven ground have brought to light risks of unwinding of the carcass reinforcement. The various tests carried out have demonstrated that the presence of cords comprising a wrap, advantageously a metallic wrap, encourages better holding of the carcass around the bead wires whatever the running conditions. The wrap present at the periphery of the cords appears to provide mechanical anchorage in the surrounding masses of rubber, thus preventing potential unwinding.
In order to encourage this anchoring, the wrap of the carcass reinforcement cords is advantageously metallic.
The inventors have thus been able to find a compromise between the cost of manufacture of the tire and the endurance performance thereof, while at the same time maintaining satisfactory tire wear properties.
According to one preferred embodiment of the invention, with the rubber compound between the cavity of the tire and the reinforcing elements of the radially innermost layer of carcass reinforcement made up of at least two layers of rubber compound, the radially innermost layer of rubber compound that forms the interior surface of the cavity of the tire has a thickness of less than 1.4 mm and preferably less than 1.2 mm. As explained previously, this layer is usually composed in part of butyl so as to increase the airtightness of the tire and because this type of material has a not insignificant cost, reducing the thickness of this layer is beneficial.
Preferably too according to the invention, the layer of rubber compound radially adjacent to the radially innermost layer of rubber compound has a thickness of less than 1.4 mm and preferably less than 1.2 mm. The thickness of this layer, the constituents of which notably allow oxygen from the air to be fixed, may also be reduced so as to further reduce the cost of the tire.
The thicknesses of each of these two layers are equal to the length of the orthogonal projection of a point of one surface onto the other surface of the said layer.
According to one advantageous embodiment of the invention, the metal reinforcing elements of at least one layer of the carcass reinforcement are cords having at least two layers, at least an inner layer being sheathed with a layer consisting of a crosslinkable or crosslinked rubber composition, preferably based on at least one diene elastomer.
The invention also proposes a tire with a radial carcass reinforcement, made up of at least one layer of reinforcing elements, the said tire comprising a crown reinforcement, itself capped radially by a tread, the said tread being connected to two beads by two sidewalls, the metal reinforcing elements of at least one layer of the carcass reinforcement being wrapped cords having at least two layers, at least an inner layer being sheathed with a layer consisting of a crosslinkable or crosslinked rubber composition, preferably based on at least one diene elastomer and in a radial plane, at least over part of the meridian profile of the tire, in a radial plane and over the whole of the meridian profile of the tire, the thickness of rubber compound between the interior surface of the cavity of the tire and the point of a metal reinforcing element of the carcass reinforcement closest to the said interior surface of the cavity being greater than 1.0 mm and less than or equal to 3.0 mm.
Within the meaning of the invention, cords, having at least two layers, at least one inner layer being sheathed with a layer consisting of a polymer composition, return, in the test referred to as the permeability test, a flow rate of less than 20 cm3/min and advantageously of less than 2 cm3/min.
The expression “composition based on at least one diene elastomer” is understood to mean, in a known way, that the composition predominantly comprises (i.e. in a fraction of more than 50% by weight) this or these diene elastomers.
It should be noted that the sheath according to the invention extends continuously around the layer that it covers (that is to say that this sheath is continuous in the “orthoradial” direction of the cord which is perpendicular to its radius), so as to form a continuous sleeve having a cross section which is advantageously practically circular.
It will also be noted that the rubber composition of this sheath is crosslinkable or crosslinked; in other words that it comprises, by definition, a crosslinking system adapted to allow the composition to be crosslinked in the course of its curing (i.e. allowing it to harden, not melt); thus, this rubber composition may be described as non-meltable because it cannot be melted by heating, regardless of the temperature.
The term “diene” elastomer or rubber is understood to mean, in a known way, an elastomer which is based, at least partially (i.e. is a homopolymer or a copolymer), on diene monomers (monomers bearing two conjugated or non-conjugated carbon-carbon double bonds).
Preferably, the system for crosslinking the rubber sheath is what is referred to as a vulcanization system, i.e. one based on sulphur (or on a sulphur donor) and a primary vulcanization accelerator. This basic vulcanization system may be supplemented with various known secondary accelerators or vulcanization activators.
The rubber composition of the sheath according to the invention comprises, in addition to the said crosslinking system, all the customary ingredients that can be used in rubber compositions for tires, such as reinforcing fillers based on carbon black and/or on an inorganic reinforcing filler such as silica, anti-ageing agents, for example antioxidants, extension oils, plasticizers or agents facilitating the workability of the compositions in the raw state, methylene acceptors and donors, resins, bismaleimides, known adhesion promoter systems of the RFS (resorcinol formaldehyde silica) type, or metal salts, notably cobalt salts.
Preferably, the composition of this sheath is chosen to be identical to the composition used for the rubber matrix which the cords according to the invention are intended to reinforce. Thus, there is no problem of possible incompatibility between the respective materials of the sheath and of the rubber matrix.
According to one alternative form of the invention, the metal reinforcing elements of at least one layer of the carcass reinforcement are layered metal cords of [L+M] or [L+M+N] construction that can be used as reinforcing elements in a tire carcass reinforcement, comprising a first layer C1 of L threads of diameter d1, with L ranging from 1 to 4, surrounded by at least one intermediate layer C2 of M threads of diameter d2 wound together in a helix at a pitch p2 with M ranging from 3 to 12, the said layer C2 possibly being surrounded by an outer layer C3 of N threads of diameter d3 wound together in a helix at a pitch p3 with N ranging from 8 to 20, a sheath made of a crosslinkable or crosslinked rubber composition based on at least one diene elastomer covering the said first layer C1 in the [L+M] construction and at least the said layer C2 in the [L+M+N] construction.
Preferably, the diameter of the threads of the first layer of the inner layer (C1) is between 0.10 and 0 5 mm and the diameter of the threads of the external layers (C2, C3) is between 0.10 and 0.5 mm.
Also preferably, the helical pitch at which the said threads of the external layer (C3) are wound is between 8 and 25 mm.
Within the meaning of the invention, the pitch represents the length, measured parallel to the axis of the cord, at the end of which a thread having this pitch completes a full turn around the axis of the cord; thus, if the axis is sectioned by two planes perpendicular to the said axis and separated by a length equal to the pitch of a thread of a layer forming the cord, the axis of this thread has, in these two planes, the same position on the two circles corresponding to the layer of the thread in question.
The cord of the invention is also provided with an outer wrap, made for example of a single thread, advantageously metallic, wound in a helix around the cord at a pitch that is shorter than that of the outer layer (C2, C3) and in a direction of winding that is the opposite of or the same as that of the said outer layer. In one alternative form of embodiment of the invention, the wrapping wire may even be selected as a textile material.
In the conventional case in which the threads of the outer layer of the cord are made of a carbon steel, the wrapping wire is advantageously selected to be made of stainless steel so as to reduce the wrapping wear of the carbon steel threads of the outer layer of the cord, as taught for example in application WO-A-98/41682. The stainless steel wrapping wire may alternatively be replaced by a composite thread only the skin of which is made of stainless steel with the core being made of carbon steel, as described for example in document EP-A-976 541.
Advantageously also according to the invention, the wrap has a diameter greater than 0.12 mm and preferably less than the diameter of the threads of the outer layer of the cord.
Advantageously too according to the invention, the wrap is laid in a helix at a pitch greater than 2.5 mm and preferably less than or equal to the pitch at which the threads that make up the outer layer are laid.
According to preferred alternative forms of embodiment of the invention, the wrap is made so that it crosses with the threads that make up the outer layer of the cord.
Advantageously, the cord has one, or even more preferably, all, of the following characteristics:
Preferably, the rubber sheath has a mean thickness ranging from 0.010 mm to 0.040 mm.
Generally, the invention can be implemented, in order to form the above-described cords of the carcass reinforcement, with any type of metal threads, in particular made of steel, for example threads made of carbon steel and/or threads made of stainless steel. A carbon steel is preferably used, but it is, of course, possible to use other steels or other alloys.
Where a carbon steel is used, its carbon content (% by weight of steel) is preferably comprised between 0.1% and 1.2%, more preferably from 0.4% to 1.0%; these contents represent a good compromise between the mechanical properties required for the tire and the workability of the thread. It should be noted that a carbon content of between 0.5% and 0.6% ultimately make such steels less expensive as they are easier to draw. Another advantageous embodiment of the invention may also consist, depending on the intended applications, in using steels with a low carbon content, for example between 0.2% and 0.5%, notably on account of a lower cost and greater ease of drawing.
The cord according to the invention may be obtained by various techniques known to a person skilled in the art, for example in two steps, initially by sheathing the core or intermediate L+M structure (layers C1+C2) via an extrusion head, this step being followed, in a second step, by a final operation in which the remaining N threads (layer C3) are cabled or twisted around the layer C2 thus sheathed. The problem of tackiness in the raw state posed by the rubber sheath during any intermediate operations of winding and unwinding may be overcome in a manner known to those skilled in the art, for example by using an interlayer film of plastics material.
According to an alternative form of embodiment of the invention, the crown reinforcement of the tire is formed of at least two working crown layers of inextensible reinforcing elements, crossed from one layer to the other, forming, with the circumferential direction, angles of between 10° and 45°.
According to other alternative forms of embodiment of the invention, the crown reinforcement further comprises at least one layer of circumferential reinforcing elements.
One preferred embodiment of the invention also plans for the crown reinforcement to be supplemented radially on the outside by at least one additional layer, referred to as a protective layer, of reinforcing elements, referred to as elastic reinforcing elements, oriented with respect to the circumferential direction at an angle of between 10° and 45° and in the same direction as the angle formed by the inextensible elements of the working layer radially adjacent to it.
The protective layer may have an axial width less than the axial width of the least wide working layer. The said protective layer may also have an axial width greater than the axial width of the least wide working layer, such that it covers the edges of the least wide working layer and, if the radially uppermost layer is the least wide layer, such that it is coupled, in the axial extension of the additional reinforcement, to the widest working crown layer over an axial width and is then decoupled, axially on the outside, from the said widest working layer by profiled elements with a thickness of at least 2 mm. In the aforementioned case, the protective layer formed of elastic reinforcing elements may, on the one hand, be decoupled if required from the edges of the said least wide working layer by profiled elements with a thickness substantially less than the thickness of the profiled elements separating the edges of the two working layers, and, on the other hand, have an axial width less than or greater than the axial width of the widest crown layer.
According to any one of the embodiments of the invention mentioned hereinabove, the crown reinforcement may be further supplemented, radially on the inside between the carcass reinforcement and the radially interior working layer closest to the said carcass reinforcement, by a triangulation layer made of metal inextensible reinforcing elements made of steel and forming, with the circumferential direction, an angle of more than 60° and the same direction as the angle formed by the reinforcing elements of the radially closest layer of the carcass reinforcement.
Further details and advantageous features of the invention will become apparent hereinafter from the description of the exemplary embodiments of the invention, with reference to
In order to make them easier to understand, the figures are not shown to scale.
In
This combination of layers constituting the crown reinforcement 5 is not depicted in detail in the figures.
These thickness measurements are carried out on a cross section of the tire, the latter consequently not being fitted or inflated.
The value E measured is equal to 2.6 mm
The values of e1 and e2 are respectively equal to 1.2 mm and 1.2 mm.
It exhibits the following characteristics (d and p in mm):
The metal wrap 26 has a diameter of 0.15 mm and is laid in a helix at a pitch of 3.5 mm to cross with the threads 25 that form the outer layer of the cord.
The core of the cord, composed of the central nucleus formed of the thread 22 and of the intermediate layer formed of the six threads 23 is sheathed with a rubber composition 24 based on non vulcanized elastomer (in the raw state). The sheathing is obtained via a head for extrusion of the core composed of the thread 22 surrounded by the six threads 23, followed by a final operation in which the 12 threads 25 are twisted or cabled around the core thus sheathed.
The aptitude for penetration of the cord 31, measured according to the method described above, is equal to 95%.
The elastomeric composition constituting the rubber sheath 24 is produced from the composition as described above and exhibits, in the present case, the same formulation, based on natural rubber and on carbon black, as that of the calendering layers 13 of the carcass reinforcement which the cords are intended to reinforce.
It exhibits the following characteristics (d and p in mm):
The metal wrap 26 has a diameter of 0.15 mm and is laid in a helix at a pitch of 3.5 mm to cross with the threads 25 that form the outer layer of the cord.
The central core composed of a cord formed of the three threads 32 was sheathed with a rubber composition 34 based on non-vulcanized diene elastomer (in the raw state). The sheathing is obtained via a head for extrusion of the cord 32, followed by a final operation in which the 9 threads 33 are cabled around the core thus sheathed.
The aptitude for penetration of the cord 31, measured according to the method described hereinabove, is equal to 95%.
It exhibits the following characteristics (d and p in mm):
The metal wrap 26 has a diameter of 0.15 mm and is laid in a helix at a pitch of 3.5 mm to cross with the threads 25 that form the outer layer of the cord.
The central nucleus composed of the thread 42 was sheathed with a rubber composition 44 based on non-vulcanized diene elastomer (in the raw state). The sheathing is obtained via a head for extrusion of the thread 42, followed by an operation in which the 6 threads 43 are cabled around the nucleus thus sheathed.
The aptitude for penetration of the cord 41, measured according to method described hereinabove, is equal to 95%.
Tests have been carried out on tires produced according to the invention in accordance with the depiction of
These reference tires differ from the tires according to the invention through carcass reinforcement cords that do not have the sheathing layer 24 and by the fact that the thickness E of rubber compound between the interior surface of the cavity of the tire and the point of a reinforcing element closest to the said surface is equal to 3.9 mm, each of the thicknesses e1 and e2 being respectively equal to 1.7 mm and 2.0 mm across the entire meridian profile of the tire.
Endurance testing with running on a drive axle of a vehicle were carried out, with the tires being subjected to a load of 3680 daN and a speed of 40 km/h, with the tires inflated to 0.2 bar. The tests were carried out on tires according to the invention under conditions identical to those applied to the reference tires. The running operations are halted as soon as the tires exhibit carcass reinforcement degradation.
The tests thus carried out demonstrated that the distances covered during each of these tests with the tires according to the invention made it possible to achieve distances covered that are similar to those covered by the reference tires.
Furthermore, the cost of manufacture of the tires according to the invention is not as high, being 3% lower in the case of the tires according to the invention as compared with that of the reference tires.
Moreover, the tires according to the invention offer the advantage of being less heavy, with a 3% lightening of weight in comparison with the reference tires.
Number | Date | Country | Kind |
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1361984 | Dec 2013 | FR | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2014/075542 | 11/25/2014 | WO | 00 |