The present invention is directed to a Tilted Filter Imaging Spectrometer (TFIS), which is designed to be a very small optical spectrometer having very high sensitivity and high spectral resolution. These properties suggest the use of the device as a Fraunhofer Line discriminator (FLD) to detect objects that fluoresce in sunlight.
An optical instrument called the Fraunhofer line discriminator (FLD) was built by the U.S. Geological Survey (Stoertz, 1969, Placyk, 1975 and Placyk & Gabriel, 1975) to examine fluorescent phenomena that can be used in identifying mineral deposits, plant fluorescence (Watson et al., 1974), fluorescent die tracking of water masses (Stoetz, 1969, Watson et al., 1974), and fluorescent industrial and natural wastes (Watson et al., 1974). The concept Stoertz and Placyk introduced was to use the known Fraunhofer lines in the solar spectrum to determine the reflected sunlight, which when subtracted from the total light is the fluorescence. The details of the technique are described in a paper discussing sunlight-induced chlorophyll fluorescence (J. Louis et. al., 2005). Since this early work, there have been numerous experiments to measure plant fluorescence using interferometers and spectrometers, the most recent observations have been made using instruments on the Greenhouse Gases Observing Satellite (GOSAT) and the Orbiting Carbon Observatory (OCO) (Crisp et al., 2008). Both these satellites carry very large and expensive Fourier Transform Spectrometers (FTS) that allow the FLD measurements of plant fluorescence. The GOSAT FTS been used to produce global maps of plant fluorescence (Joiner et al., 2011) and the OCO FTS has been used to produce similar maps. An entire satellite devoted to fluorescence measurements, Fluorescence Explorer (FLEX) has been started by the European Space Agency. The cost of these large missions begs for a more modest approach.
With the present invention, we will show that a very simple spectral imaging device can make fluorescence observations that can compete with these large and costly instruments. A dielectric interference filter is in reality a very small Fabry-Perot interferometer (Born & Wolf, 1970) with a cavity material having a fairly high index of refraction. The basic characteristic of these devices is that a narrow spectral region is transmitted through the filter. The wavelength that is transmitted depends on the angle at which the collimated beam strikes the filter.
According to at least one embodiment of the present invention, a tilted filter imaging spectrometer of the present invention comprises at least one dielectric filter; at least one imaging lens structure; and an imaging detector operatively positioned at a focal length of the at least one imaging lens structure, wherein the at least one dielectric filter is operatively positioned at an angle relative to an optical axis of the at least one imaging lens structure.
In at least a second embodiment, a tilted filter imaging spectrometer of the present invention comprises at least one dielectric filter; at least one Fabry-Perot Etalon: at least one imaging lens structure; and an imaging detector operatively positioned at a focal length of the at least one imaging lens structure, wherein the at least one Fabry Perot Etalon and at least one dielectric filter that are operatively positioned at angles relative to an optical axis of the at least one imaging lens structure.
In a further embodiment, the present invention is also directed to a method for tilted filter imaging, comprising the steps of: providing a tilted filter imaging spectrometer having at least one dielectric filter, at least one imaging lens structure and an imaging detector operatively positioned at a focal length of the at least one imaging lens structure; variably positioning the at least one dielectric filter at an angle relative to an optical axis of the at least one imaging lens structure; and scanning an area to be studied wherein light reflected from the area to be studied is filtered through the at least one dielectric filter, imaging the filtered light from the at least one dielectric filter via the imaging lens structure to the imaging detector; and generating a fluorescence spectrum of the area to be studied via the filtered light detected by the imaging detector.
The present invention is illustrated in the accompanying drawings, wherein:
The embodiments of the present invention will be described hereinbelow in conjunction with the above-described drawings. The present invention as embodied in an instrument that implements the Tilted Filter Imaging Spectrometer (TFIS). A dielectric interference filter is in reality a very small Fabry-Perot interferometer (Born & Wolf, 1970) with a cavity of material having a fairly high index of refraction. The basic characteristic of these devices is that a narrow spectral region is transmitted through the filter. The wavelength that is transmitted depends on the angle at which the collimated beam strikes the filter, as expressed in the following formula:
Here λθ is the wavelength of light transmitted at an angle θ through the filter with spacer index μs. At normal incidence, the wavelength transmitted is λo. In most cases, a fairly wide cone of light normal to the surface is detected by a photodetector in the center of the fringe pattern. This is illustrated in
However, if the wavelength of the light is decreased, this pattern changes from a central Gaussian-like bump to a conical ring of transmission as shown in
It becomes obvious that there is a clear analog to a grating spectrometer where here the spectra are distributed arcs; however, there is one considerable difference. A dielectric filter is a Fabry-Perot interferometer and it has the famous Jacquinot's Advantage where the throughput of an interferometer with the same resolution as a spectrometer can transmit from 30 to 50 times as much energy. To implement the FLD technique for detecting reflectance and fluorescence, one must have an instrument that can measure the properties of the Fraunhofer line in the reflected light with a high degree of accuracy. The reflected light is calculated by multiplying the depth of the darkened line by the known ratio of continuum to line depth.
As noted above, in this implementation, the filter structure 10 uses a single filter. High quality optics are important since aberrations will cause the light being viewed by a single pixel on the detector 14 to pass through the filter structure 10 in a fashion that broadens the spectral bandpass of the filter structure 10. This being especially true at larger angles through the filter structure 10. The filter structure 10 are arranged at an angle to the optical axis φ of the lens system 12. This angle φ can be fixed or can be scanned creating either a fixed fringe pattern on the detector 14 or a moving or scanning fringe pattern. The angle of the filter structure 10 must be known accurately in order to calibrate the spectrum being viewed by the detector 14. If the filter structure 10 is being scanned in angle, the integration time and scan rate must be such that the spectrum is not smeared significantly during the integration period. Similarly, if the filter angle is fixed and the scene is scanned as the TFIS is moved, again integration time and scene motion must be such that the spectrum is not significantly broadened.
The first embodiment shown in
As discussed above, the detector 14 receives the light filtered via the dielectric filter in the form of a fringe pattern that is then used to generate a fluorescence spectrum. It is to be understood that the imaging detector of every embodiment of the present invention includes the necessary hardware (not shown), including data processing circuitry, memory, data input devices, data display devices, operating software, signal processing software and data calculating software, to generate data representing or relating to a fluorescence spectrum, as would be understood by those of skill in the art.
In
In order to compensate for the fact that the filter spacer and the FPI spacer have different indices of refraction, the divergence and tilt angles of the FPI and filter structure must satisfy the condition that lambda FPI=lambda TFIS. That is achieved when the angles satisfy the condition that
and the divergence of the beams of light at the two must satisfy the condition
Since etendue must be conserved, the optics must be added in general to increase the divergence of the beams in the high index filter section.
The final optic implemented by the imaging lens system 42 focuses the combined fringe pattern on the detector 44 with a focal length of lb=L·(μFPI/μFilter)). These conditions conserve etendue and assure that the FPI and filter peaks are coincident.
The principles for how a spectrum of light is transmitted through an imaging system consisting of a combined dielectric filter tilted at an angle φ1 and a Fabry-Perot interferometer (FPI) tilted at a different angle φ2 and azimuth angle Ψ2 followed by an imaging detector, according to the embodiment of
Consider that a point on an imaging system detector being the image of a point source of light coming from infinity. That set of rays will pass through the plane of a filter or interferometer at an angle given by the equation:
where x and y are the positions of pixels on the detector and Fo is the focal length of the imaging system and the angles are relative to the axis of tilt. In a dielectric filter the transmitted wavelength depends on the center band wavelength and the angle that the ray passes through the filter:
and the transmittance for a Lorentzian filter is given by the simple formula
where γ is FWHH/2 of the filter in the units of Δ.
For a Fabry Perot interferometer the equation is somewhat more complex:
Here R is etalon reflectivity; Afpi is etalon absorption and θ is the angle that the light ray makes with the normal to the etalon. Generally, the FPI transmission peaks at a set of periodic wavelengths where
where n is an integer. Here
is the order of interference Mo. Thus, the combined transmission of the dielectric filter and FPI
The signal reaching each pixel is then the product of the spectral radiance and the complete instrument function.
Signali,j=AtelescopeΩpixel
There are several ways to invert the signal to get the spectrum.
Taking the basic equation for the signal using the linear L index to replace the i,j indices
S
L
=A
telescopeΩpixel
Now let WL and Spec be expanded into Fourier Series
Since WL and Spec are real, AL,−k=AL,k and B−k=Bk.
Replacing WL and Spec with the two series leads to the equation below:
This is a simple set of linear equations for the Fourier coefficients of spectrum, in matrix form the equations can be written as:
S
L
=B
k
M
L,k where ML,0=AL,0 and ML,k=2AL,k for k>0
Reducing the Integral to a Sum and Fitting with Continuous Functions
A very interesting property of the FPI is that at high reflectance the transmission peaks are very narrow, that is the finesse is quite high. Under these conditions, the integral for the signal can be carried out analytically, in integrating one order at a time, the integral of an order in the FPI is a simple constant.
Thus, assuming that the filter transmission and Spec can be considered to be at best a linear variation over the individual orders, then the signali,j is a simple sum over the orders where the filter has finite transmission.
where
will have few or many orders depending on the free spectral range of the interferometer and the width of the filter, generally the number of orders required at each pixel will be about
where No is the number of filter width required to have a negligible effect on the sum contributing to the signali,j.
Approximating the Spectrum with a Set of Continuous Functions
In order to fit the spectrum from the multitude of pixel data, the spectrum should be expressed in as few parameters as possible. One obvious approach is to expand the spectrum in a series of function, orthogonal or not. B-splines are one approach, but starting with the assumption that a set of orthogonal functions Γn(λ) are used, that is
Substituting this expansion into the expression for the signal yields the relation that
This is a linear set of equations for the expansion coefficients Am
In practice, the I,j array can be replaced by a linear array of length Nx*Ny called sub L then the set of equations becomes simpler to handle, that is Signali,j=SL
Here the λnL's are the wavelength of the center of the FPI orders where the filter has peak transmission on the Lth pixel.
There are many applications of the Tilted Filter Imaging Spectrometer (TFIS). In terms of airborne or space borne imaging of fluorescence and reflectance,
There are many possible variations of this basic instrument depending on the spectral features of interest. The only limitation to the spectral range is when the two polarizations begin to separate, but even in that case a polarizer will maintain the bandpass to higher angles (Swenson 1975, Lissberger 1959). The optics are very small and can be easily combined to provide multiple channels on a single detector.
In the most simplistic form, the reflectance and fluorescence can be resolved from the spectrum using the FLD technique described hereinabove. However, much more accurate inversion techniques have been devised using least squares, singular value decomposition, or principal component analysis (Crisp et al., 2008, Joiner et al., 2011). These techniques could be used to invert the spectra in real time on the moving vehicle to transmit maps of reflectance and fluorescence rather that retrieving the full data cube, thus greatly reducing the information transmitted to the ground.
In other implementations, working in the 600-800 nm region fluorescence from vegetation can be used to monitor the health of crops, forests, and grasslands (Smorenburg et al., 2002) This application can reproduce the results obtained from huge and expensive satellite missions such as GOSAT, OCO, and FLEX (Crisp et al., 2008, Joiner et al., 2011, Frankenberg et al., 2012).
Working in the 400-600 nm region, fluorescence from crude oil floating on sea water, in rivers, and on land (Watson et al., 1974) can help greatly in the remediation of oil contamination. Laser induced fluorescence LIF spectra were compared to solar induced fluorescence SIF to show that SIF (V. Raimondi 1, 2013) can be used to detect crude oil floating on water. The source of the crude oil can also be determined from its fluorescence spectrum.
The 640-720 nm region is where chlorophyll fluorescence is directly linked to physiology of phytoplankton or plants in the sea (Wolanin, 2015). A large percentage of biomass production of carbon is thru phytoplankton growth and death (Roesler et al., 1995). Careful monitoring of the density and health of phytoplankton through their fluorescence is important to understanding the health and productivity of this important source of carbon fixation (Xing, 2007, BABIN, 1996) in the oceans.
The TFIS instrument according to the present invention embodies small, high-throughput, high resolution spectrometers for laboratory or field studies of spectral regions in the visible, near and far infrared. Applications of the present invention further include mineral prospecting with handheld fluorometers using the TFIS, or drones mounting TFIS devices for pushbroom imaging (Watson et al., 1974) as discussed earlier, and in situ measurement of chlorophyll fluorescence in the field and in the laboratory.
While specific embodiments have been described in detail in the foregoing detailed description and illustrated in the accompanying drawings, those with ordinary skill in the art will appreciate that various modifications and alternatives to those details could be developed in light of the overall teachings of the disclosure. Accordingly, the particular arrangements disclosed are meant to be illustrative only and not limiting as to the scope of the invention, which is to be given the full breadth of the appended claims and any and all equivalents thereof.
Number | Date | Country | |
---|---|---|---|
62443957 | Jan 2017 | US |