The present application claims the priority of the Chinese Patent Application No. 201910826836X, filed with the China Patent Office on Aug. 30, 2019, and entitled as “transistor with high withstand voltage and high electron mobility”, the entire contents of which are incorporated by reference in the present application.
The present application relates to semiconductor power devices, in particular, to a transistor with high withstand voltage and high electron mobility and a preparation method therefor.
Group III-V compound semiconductors include at least one group III element and at least one group V element, comprising but not limited to gallium nitride (GaN), aluminum gallium nitride (AlGaN), gallium arsenide (GaAs), indium nitride aluminum gallium (InAlGaN) and indium gallium nitride (InGaN), etc. When the group V element is nitrogen (N), the group III-V compound semiconductor is also called as group III nitride semiconductor, that is, the group III nitride semiconductor comprises nitrogen and at least one group III element, and group III nitride semiconductors include, but are not limited to, GaN, AlGaN, InN, AlN, InGaN, InAlGaN, and the like.
A transistor with high electron mobility (HEMT) utilizes group III-V heterojunction structures, such as group III nitride heterojunction, to generate two-dimensional electron gas (2DEG) at the interface of group III nitride material where the heterojunction is formed, which allows the high density of current to pass therethrough and has relatively low resistance loss, and gradually realizes the withstand voltage capability being increased to 600V, even to 1200V. Conventional group III nitride transistor with high electron mobility is usually a depletion-mode device. Group III nitride transistor with high electron mobility needs to avoid the transistor with high electron mobility from being turned on in the situation of no gate voltage control, so as to protect the circuit and loads, due to the advantages of high breakdown voltage, high current density, and low on-resistance, etc. Therefore, it would be desirable to provide group III nitride transistor with high electron mobility which is normally off, or an enhancement mode transistor.
As such, it is needed to overcome the shortcomings and deficiencies in the prior art to manufacture a transistor with high withstand voltage and high electron mobility, and an enhancement mode group III-V transistor with high electron mobility.
In the related patent applications, we have proposed to realize normally-off devices through structures, such as P-type buried layers, and described the higher withstand voltage capability, and also described the structures of the related devices in detail. However, in the specific implementation process, when the selection area is subjected to the epitaxy, the nucleation area is located at the position of the source. This is mainly because the transistor with high electron mobility is of a symmetrical structure with respect to the source, with a gate electrode and a drain electrode located from the source to both sides. At the same time, the distance from the source electrode to the gate electrode is usually much smaller than the distance from the gate electrode to the drain electrode, and the lateral epitaxy from the source to the gate is much shorter than that from the drain to the gate, which is conducive to the realization of the fabrication accuracy of complex structures at the source and the gate through the epitaxy. At the same time, the voltage in the source region is quite low, and the crystal quality of the nucleation region is relatively poor, so that when the source is located in the low-quality region, the influence is minimal due to the voltage being low.
In contrast, due to the nucleation and the lateral epitaxy from the gate or other regions, the laterally epitaxial structures on both sides are basically symmetrical, which is not conducive to the formation of many asymmetric structures. Moreover, if the lateral epitaxy starts from the gate electrode region, then because the distance from gate to source and the distance from gate to drain are quite different, it is not conducive to the good use of the chip area.
However, the nucleation and the lateral epitaxy from the region corresponding to the projection of the drain region on the substrate can also be achieved. At this time, it is also beneficial to form some special structures in the drain region to improve the performance of a certain aspect. Meanwhile, the crystal quality of the epitaxial layer can be optimized before forming complex structures at the source and gate. In this way, the complex structure at the source and gate can also obtain better crystal quality and achieve good electrical characteristics. Regardless of whether the nucleation is formed from the source or the drain region, the required stacking layout structure can be formed sequentially from the source to the gate to the drain, or from the drain to the gate to the source.
The basic principle of the present application is to adjust the electric field distribution of the high electron mobility transistor device and improve its withstand voltage capability and realize the enhancement mode device, by introducing the P-type group III-V semiconductor layer, by means of doping modulation technology.
The basic structure of the transistor with high electron mobility provided by the present application is to select a region to epitaxially grow the group III-V semiconductor layer from the region corresponding to the drain electrode; form the semiconductor layer regions with different doping concentrations through the modulation doping technology, and finally form a transistor structure with high electron mobility. In this way, the local high electric field of the channel layer is reduced, the electric field distribution is improved, and performance and reliability of the device are improved.
In the first aspect, the transistor with high withstand voltage and high electron mobility is provided by the present application, comprising device structures, such as a gate electrode, a source electrode, a drain electrode, a barrier layer, a channel layer, a nucleation layer, and a substrate, etc., wherein the channel layer comprising a P-type group III-V semiconductor layer is located between the barrier layer and the substrate; the P-type group III-V semiconductor layer is located at least partially between the drain electrode and the gate electrode, which is insufficient to significantly deplete the two-dimensional electron gas in the channel except for the gate electrode stack, wherein the nucleation layer corresponds to the drain electrode region, the drain electrode is in electrical contact with the channel layer above the nucleation layer, and the source electrode is in electrical contact with the P-type group III-V semiconductor layer.
Optionally, a low-doped or unintentionally doped group III-V semiconductor layer may be introduced between the barrier layer and the P-type group III-V semiconductor layer.
Optionally, a SiNx passivation layer may be grown in-situ on the barrier layer, and a gate dielectric layer is provided under the gate electrode.
Optionally, a gate dielectric layer may be formed on the barrier layer.
Optionally, a low-doped or unintentionally doped group III-V semiconductor layer may be introduced above the modulation P-type group III-V semiconductor layer.
Optionally, the barrier layer above the P-type group III-V semiconductor layer may further be covered by a passivation layer.
Optionally, the lightly doped group III-V semiconductor layer first doped region is lightly doped or not doped.
Optionally, the P-type group III-V semiconductor layer comprises modulation regions with different doping concentrations; and with the nucleation layer region as a center, a lightly doped group III-V semiconductor layer first doped region, the a strongly P-type group III-V semiconductor layer first doped region and a P-type group III-V semiconductor layer first doped region are provided sequentially outwards; and the drain electrode is formed above the lightly doped group III-V semiconductor layer first doped region, a gate electrode stack structure is correspondingly formed above the strongly P-type group III-V semiconductor layer first doped region, and the source electrode is formed above the P-type group III-V semiconductor layer first doped region.
Optionally, the strongly P-type group III-V semiconductor layer first doped region under the gate electrode can deplete more than 95% of the two-dimensional electron gas under stack of the gate electrode at 0 gate voltage, or concentration of the two-dimensional electron gas under the stake of the gate electrode at 0 gate voltage is made to be less than 5E11/cm2.
Optionally, a doping concentration of the lightly doped group III-V semiconductor layer first doped region is less than 5E17/cm3.
Optionally, the P-type group III-V semiconductor layer comprises modulation regions with different doping concentrations; with the nucleation layer region as a center, a lightly doped group III-V semiconductor layer first doped region, a P-type group III-V semiconductor layer first doped region and a P-type group III-V semiconductor layer second doped region are provided sequentially outwards, the drain electrode is formed above the lightly doped group III-V semiconductor layer first doped region, and a gate electrode stack structure is formed at a part of the P-type group III-V semiconductor layer second doped region close to the P-type group III-V semiconductor layer first doped region, that is, the P-type group III-V semiconductor layer first doped region is located between the drain electrode and the gate electrode, and a doping concentration of the P-type group III-V semiconductor layer first doped region is adjustable, which can improve electric field distribution under the gate electrode, near a drain side, and the source electrode is formed above the P-type group III-V semiconductor layer second doped region.
Optionally, the P-type group III-V semiconductor layer comprises modulation regions with different doping concentrations; and with the nucleation layer region as a center, a lightly doped group III-V semiconductor layer first doped region, a P-type group III-V semiconductor layer first doped region, a strongly P-type group III-V semiconductor layer first doped region, and a P-type group III-V semiconductor layer second doped region are provided sequentially outwards; the drain electrode is provided above the lightly doped group III-V semiconductor layer first doped region, and a gate electrode stack structure is correspondingly formed above the strongly P-type group III-V semiconductor layer first doped region, the P-type group III-V semiconductor layer first doped region is located between the lightly doped group III-V semiconductor layer first doped region and the strongly P-type group III-V semiconductor layer first doped region, a doping concentration of the P-type group III-V semiconductor layer first doped region is adjustable, which can improve electric field distribution under the gate electrode, near a drain side, and the source electrode is formed above the P-type group III-V semiconductor layer second doped region.
Optionally, when the source electrode is in electrical contact with the P-type group III-V semiconductor layer, partial area of the source electrode is in contact with the two-dimensional electron gas and partial area of the source electrode is in direct contact with the P-type group III-V semiconductor layer, passing through the channel layer.
Optionally, when the source electrode is in electrical contact with the two-dimensional electron gas, metal material in contact with the P-type group III-V semiconductor layer is electrically connected to the source electrode, which facilitates being controlled together with a potential of the source electrode.
In the second aspect, the present application provides a transistor with high withstand voltage and high electron mobility, comprising a gate electrode, a source electrode, a drain electrode, a barrier layer, a channel layer, a nucleation layer, and a substrate, wherein a projection of the nucleation layer on the substrate and a projection of the drain electrode on the substrate at least partially overlap each other, the channel layer comprising the P-type group III-V semiconductor layer is located between the barrier layer and the substrate, which is not sufficient to significantly deplete two-dimensional electron gas in the channel except for a gate stack, and both the source electrode and the drain electrode are in electrical contact with two-dimensional electron gas, the gate electrode is located on the barrier layer, and an independent body electrode is in electrical contact with the P-type group III-V semiconductor layer, near the source electrode.
In the third aspect, the present application provides a method for preparing a transistor with high electron mobility mentioned above, comprising forming and growing a P-type group III-V semiconductor layer on the nucleation layer by lateral epitaxy; forming, on the P-type group III-V semiconductor layer, when lateral epitaxy growth, modulation-doped P-type group III-V semiconductor layer depending on different doping concentrations of different regions; and using a mixed atmosphere of precursors containing hydrogen and/or chlorine, when laterally epitaxially growing the P-type group III-V semiconductor layer.
Optionally, one insulating layer is provided on the substrate; after being subjected to masking, etching and other processes to form an opening, the insulating layer forms a nucleation layer at the opening, and then the epitaxial layer structure including the P-type group III-V semiconductor layer is grown in the lateral epitaxy manner; or one nucleation layer is grown on the substrate, and one insulating layer is formed on the nucleation layer; the insulating layer is subjected to masking, etching and other processes to form an opening to expose the nucleation layer, and then the epitaxial layer structure including the P-type group III-V semiconductor layer is grown by lateral epitaxy manner.
Optionally, an epitaxial layer structure is grown on the substrate in a lateral epitaxy manner; taking as a center the region where the drain electrode is located, it is expanded outward to form a symmetrical transistor structure with high electron mobility, with the drain electrode region as a center.
Optionally, when an epitaxial layer structure is grown on the substrate in lateral epitaxy manner, firstly, the lightly doped group III-V semiconductor layer first doped region, the strongly P-type group III-V semiconductor layer first doped region, the P-type group III-V semiconductor layer first doped region are epitaxially formed on the nucleation layer; a partial region in a height direction of the group III-V semiconductor layer is removed by a planarization or etching process to expose a modulation P-type group III-V semiconductor layer of the lightly doped group III-V semiconductor layer first doped region, the strongly P-type group III-V semiconductor layer first doped region, and the P-type group III-V semiconductor layer first doped region; and a drain electrode is formed above the lightly doped group III-V semiconductor layer first doped region, and a gate electrode stack structure is correspondingly formed above the strongly P-type group III-V semiconductor layer first doped region, and a source electrode is formed above the P-type group III-V semiconductor layer first doped region.
Optionally, when the epitaxial layer structure is grown on the substrate in lateral epitaxy manner, firstly, the lightly doped group III-V semiconductor layer first doped region is epitaxially formed on the nucleation layer, and then the P-type group III-V semiconductor layer first doped region and the P-type group III-V semiconductor layer second doped region are epitaxially formed, and a partial region in a height direction of the group III-V semiconductor layer is removed by a planarization or etching process to expose a modulation P-type group III-V semiconductor layer of the lightly doped group III-V semiconductor layer first doped region, the P-type group III-V semiconductor layer first doped region and the P-type group III-V semiconductor layer second doped region; the drain electrode is formed above the lightly doped group III-V semiconductor layer first doped region, and a gate electrode stack structure is formed in a part of the P-type group III-V semiconductor layer second doped region close to the P-type group III-V semiconductor layer first doped region, that is, the P-type group III-V semiconductor layer first doped region is located between the drain electrode and the gate electrode, and a doping concentration of the P-type group III-V semiconductor layer first doped region is adjustable, which can improve electric field distribution under the gate electrode, near a drain side, and the source electrode and/or a body electrode is formed above the P-type group III-V semiconductor layer second doped region.
Optionally, when an epitaxial layer structure is grown on the substrate in lateral epitaxy manner, firstly, the lightly doped group III-V semiconductor layer first doped region is epitaxially formed on the nucleation layer, and then the P-type group III-V semiconductor layer first doped region, the strongly P-type group III-V semiconductor layer first doped region, and the P-type group III-V semiconductor layer second doped region are epitaxially formed, a partial region in a height direction of the group III-V semiconductor layer is removed by a planarization or etching process, to expose a modulation P-type group III-V semiconductor layer of the lightly doped group III-V semiconductor layer first doped region, the P-type group III-V semiconductor layer first doped region, the strongly P-type group III-V semiconductor layer first doped region, and the P-type group III-V semiconductor layer second doped region; the drain electrode is formed above the lightly doped group III-V semiconductor layer first doped region, a gate electrode stack structure is correspondingly formed above the strongly P-type group III-V semiconductor layer first doped region, and the P-type group III-V semiconductor layer first doped region is located between the lightly doped group III-V semiconductor layer first doped region and the strongly P-type group III-V semiconductor layer first doped region, and a doping concentration of the P-type group III-V semiconductor layer first doped region is adjustable, which can improve electric field distribution under the gate electrode, near a drain side, and the source electrode and/or a body electrode is formed above the P-type group III-V semiconductor layer second doped region.
Optionally, a mixed atmosphere of precursors containing hydrogen and/or chlorine is used during a lateral epitaxial growth of a structure containing the P-type group III-V semiconductor layer.
As for the P-type group III-V semiconductor layer of the present application, the lateral epitaxial growth starts from the region corresponding to the drain electrode, and the P-type doping concentration can be adjusted by adjusting the proportion of the doped carrier gas atmosphere according to the needs in the growth process. The electric field distribution is adjusted by P-type doping, and high-quality P-type doping and its spatial adjustment to the two-dimensional electron gas 2DEG at the AlGaN/GaN heterojunction interface can be obtained; and by modulating the doping concentration of the semiconductor layer under the drain electrode, the gate electrode and the source electrode, the modulation of the potential of the P-type group III-V semiconductor layer can be controlled by the source electrode or the body electrode, which can improve the withstand voltage capability of the transistor with high electron mobility and realize functions, such as normally-off operation, etc.
In order to illustrate the technical solutions of the embodiments of the present application more clearly, the drawings that are used in the embodiments of the present application are briefly introduced as follows. It should be understood that the following drawings only show some embodiments of the present application, and therefore should not be regarded as a limitation to the scope. For those skilled in the art, other related drawings can also be obtained from these drawings without any creative efforts.
The technical solutions in the embodiments of the present application will be described below with reference to the drawings in the embodiments of the present application.
It should be noted that similar reference numbers and letters refer to similar items in the following figures, so that once an item is defined in one figure, it is not required to further define and explain it in subsequent figures. Meanwhile, in the description of the present application, the terms “first”, “second”, etc. are only used to describe the distinguishing, and cannot be understood as indicating or implying importance of the relativity. “Up” and “down”, etc. indicate a relative positional relationship, and do not indicate that the two are directly adjacent.
The basic idea of the transistor with high withstand voltage and high electron mobility of the present application is to start the lateral epitaxial growth from the region corresponding to the drain electrode. Since the selected region epitaxy can achieve higher crystal quality, which has certain advantages over the existing planar growth.
On the basis of the above basic structure, by doping and modulating the doping concentration in lateral epitaxy, the following structures and their combinations can be formed, wherein a strong P-type region is formed at the gate electrode stack, at which the two-dimensional electron gas is depleted, so as to achieve the device of normally-off enhancement mode; and in addition to forming a strong P-type region at the gate electrode stack, a P-type layer is formed near the source electrode, and the P-type layer does not significantly deplete two-dimensional electron gas between the source electrode and the gate electrode, but can connect with the strong P-type region at the gate electrode stack and connect to the electrode. The electrode can be a source electrode or a separate body electrode. A P-type region is formed between the gate electrode and the drain electrode, and the P-type region does not significantly deplete the two-dimensional electron gas but can improve the electric field distribution and reduce the maximum electric field strength.
In the transistor with high electron mobility of the present application, the doping concentration of strong doping is generally above 5E18/cm3, and the doping concentration of light doping is generally below 5E18/cm3. In transistor with high electron mobility, the strong doping or the light doping is relative and is related to the two-dimensional electron gas concentration at the channel layer/barrier layer interface. Generally, the higher the concentration of the intrinsic two-dimensional electron gas at the interface of the channel layer/barrier layer (in the absence of doping) is, the higher the doping concentration corresponding to the strong doping is, and the light doping can also have relatively higher doping concentration. On the contrary, the lower the intrinsic two-dimensional electron gas concentration is, the lower the doping concentration corresponding to the strong doping is, and therefore the light doping also has a relatively lower doping concentration.
Referring to
In some possible embodiments, the transistor with high withstand voltage and high electron mobility provided by the embodiment of
It should be noted that with certain substrates (such as Al2O3 substrates) and under certain process conditions, the nucleation layer can be selectively grown on the exposed substrate but not on the insulating layer. However, when using a silicon substrate, it is usually necessary to use AlN as the nucleation layer, and however, when AlN is used as the nucleation layer, the growth selectivity is poor. At this time, the AlN on the insulating layer can be etched/removed after the nucleation layer is grown. However, under certain growth conditions, the deposition of AlN on the insulating layer is very small, and the nucleation growth matrix of the subsequent nitride epitaxy layer cannot be formed on the insulating layer. Except for the growth in the nucleation region, there is no obvious subsequent growth of the P-type group III-V semiconductor layer in other regions, so that the step of removing the AlN on the insulating layer can be omitted and the subsequent growth can be performed directly.
Alternatively, as the AlN on the insulating layer is polycrystalline or amorphous, nucleation and growth can be carried out only on the single crystal AlN in the opening region under appropriate process conditions, but not on the polycrystalline AlN on the insulating layer. At this time, the AlN layer of the polycrystalline structure plays an insulating role to a large extent.
In another possible embodiment, as shown in
In another possible embodiment, as shown in
The transistor structure with high electron mobility shown in
In another possible embodiment, as shown in
In the specific implementation, as shown in
Optionally, the strong P-type group III-V semiconductor layer disposed under the gate electrode can deplete more than 95% of the two-dimensional electron gas under the gate electrode stack at 0 gate voltage, or cause the concentration of the two-dimensional electron gas below the gate electrode stack at 0 gate voltage to be less than 5E11/cm2.
In addition, in order to strengthen the control of the source electrode on the group III-V semiconductor layer second doped region, then potential of the strong P-type group III-V semiconductor layer is controlled through this layer to obtain a stable threshold voltage of the transistor with high electron mobility, as shown in
In addition, a gate dielectric layer 807 can also be provided. The gate dielectric layer can be in-situ SiNx or other dielectric materials such as SiO2, high-k, etc., and is provided under the gate electrode 810 to completely cover the barrier layer 806.
The difference from the embodiment shown in
In another possible embodiment, as shown in
In the transistor with high withstand voltage and high electron mobility shown in
Optionally, as shown in
The difference from the embodiment shown in
While reducing the drain electric field strength under the gate electrode and enhancing the withstand voltage capability of the transistor with high electron mobility, the transistor with high withstand voltage and high electron mobility shown in
The P-type group III-V semiconductor layer (1304-4) and the barrier layer 1306 are exposed in a stepped manner through processes, such as masking, etching, etc., and then the source electrode 1309 is formed by deposition, so that the partial region of the source electrode 1309 is in contact with the two-dimensional electron gas; the partial region of the source electrode 1309 passes through the channel layer 1305 to be in direct contact with the P-type group III-V semiconductor layer 804-3. The source electrode 1309 and the P-type group III-V semiconductor layer second doped region (1304-4) are in good electrical contact and the potential of the strong P-type group III-V semiconductor layer (1304-3) is controlled through the P-type group III-V semiconductor layer second doped region (1304-4) so as to obtain a stable threshold voltage. The P-type group III-V semiconductor layer first doped region (1304-2) is located in the region between the gate electrode 1310 and the drain electrode 1308, which can improve the high electric field distribution under the gate electrode and near the drain electrode region, avoiding the device failure caused by the local electric field strength being too large. It should be noted that the channel layer, the in-situ SiN passivation layer, and the gate insulating layer, etc. are optional but not necessary.
In addition, in another embodiment with a potential control method different from that in the embodiment shown in
The above descriptions are merely embodiments of the present application, and are not intended to limit the protection scope of the present application. For those skilled in the art, the present application may have various modifications and changes. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principle of the present application shall be included within the protection scope of the present application.
By applying the technical solutions of the present application, high-quality P-type doping and its spatial adjustment to the two-dimensional electron gas 2DEG at the AlGaN/GaN heterojunction interface can be obtained, and the withstand voltage capability of the transistor with high electron mobility can also be improved, to realize functions, such as normally-off operations.
Number | Date | Country | Kind |
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201910826836.X | Aug 2019 | CN | national |
Filing Document | Filing Date | Country | Kind |
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PCT/CN2019/115426 | 11/4/2019 | WO |