Embodiments of the present disclosure generally relate to apparatus and methods for plasma processing of a substrate, and specifically to apparatus and methods for controlling an ion energy distribution during plasma processing.
During plasma processing of a substrate, ions play a key role for substrate surface treatment, etching, and deposition. Ions impinging the substrate surface can have a variety of energies which is described by an ion energy distribution function (IEDF). Control over the IEDF can be an important factor for various substrate processing schemes. Controlling the IEDF, however, remains a challenge. For example, when periodic alternating voltage is applied to electrode(s) of a chamber, a plasma sheath can develop above the substrate. The ions flowing towards the substrate are accelerated by the plasma sheath voltage which correlates with the voltage applied to the electrode. At the same time, ion current can charge the substrate and alter the substrate potential, which in turn affects the plasma sheath voltage such that the IEDF at the substrate surface is also affected, e.g., broadened. State-of-the-art methods to control the IEDF in such instances, and others, are based on inefficient iteration loops.
There is a need for new and improved methods for controlling the IEDF.
Embodiments of the present disclosure generally relate to apparatus and methods for plasma processing of a substrate, and specifically to apparatus and methods for controlling an ion energy distribution during plasma processing.
Embodiments of the present disclosure may provide a method of controlling an ion energy distribution function (IEDF). The method includes introducing a voltage to an electrode of a processing chamber by activating a main pulser, the main pulser coupled to an IEDF width control module, and measuring a current of the IEDF width control module and a voltage or a voltage derivative of the IEDF width control module. The method further includes calculating an ion current of the processing chamber and a capacitance of the processing chamber based on the current and the voltage or voltage derivative of the IEDF width control module. The method further includes determining a setpoint for a DC voltage of the main pulser, a setpoint for a voltage or a voltage derivative of the IEDF width control module, or both, and adjusting the DC voltage of the main pulser, the voltage or voltage derivative of the IEDF width control module, or both, to the determined setpoints to control the width of the IEDF.
Embodiments of the present disclosure may also provide an apparatus for controlling an ion energy distribution. The apparatus includes a substrate support that has a body having a substrate support portion having a substrate electrode embedded therein for applying a substrate voltage to a substrate. The body further includes an edge ring portion disposed adjacent to the substrate support portion, the edge ring portion having an edge ring electrode embedded therein for applying an edge ring voltage to an edge ring. The apparatus further includes a substrate voltage control circuit coupled to the substrate electrode and an edge ring voltage control circuit coupled to the edge ring electrode. The substrate electrode is coupled to a power module configured to actively control an energy distribution function width of ions reaching the substrate, or the edge ring electrode is coupled to a power module configured to actively control an energy distribution function width of ions reaching the edge ring, or a combination thereof. The substrate voltage control circuit, the edge ring voltage control circuit, or both comprises a main pulser coupled to a current return path, the current return path coupled to the power module and to a processing chamber, wherein the power module comprises a voltage source, a current source, or a combination thereof
Embodiments of the present disclosure may also provide an apparatus for controlling an ion energy distribution. The apparatus includes a substrate support that has a body having a substrate support portion having a substrate electrode embedded therein for applying a substrate voltage to a substrate. The body further includes an edge ring portion disposed adjacent to the substrate support portion, the edge ring portion having an edge ring electrode embedded therein for applying an edge ring voltage to an edge ring. The apparatus further includes a substrate voltage control circuit coupled to the substrate electrode and an edge ring voltage control circuit coupled to the edge ring electrode. The substrate electrode is coupled to a power module configured to actively control an energy distribution function width of ions reaching the substrate, or the edge ring electrode is coupled to a power module configured to actively control an energy distribution function width of ions reaching the edge ring, or a combination thereof. The substrate voltage control circuit, the edge ring voltage control circuit, or both comprises a main pulser coupled to the power module, the power module coupled to a processing chamber, the power module comprising a voltage source, a current source, or a combination thereof.
Embodiments of the present disclosure may also provide an apparatus for controlling an ion energy distribution. The apparatus includes a substrate support that has a body having a substrate support portion having a substrate electrode embedded therein for applying a substrate voltage to a substrate. The body further includes an edge ring portion disposed adjacent to the substrate support portion, the edge ring portion having an edge ring electrode embedded therein for applying an edge ring voltage to an edge ring. The apparatus further includes a substrate voltage control circuit coupled to the substrate electrode and an edge ring voltage control circuit coupled to the edge ring electrode. The substrate electrode is coupled to a power module configured to actively control an energy distribution function width of ions reaching the substrate, or the edge ring electrode is coupled to a power module configured to actively control an energy distribution function width of ions reaching the edge ring, or a combination thereof. The substrate voltage control circuit, the edge ring voltage control circuit, or both comprises a main pulser coupled to the power module, the power module coupled to a processing chamber, wherein the power module is in parallel with a substrate chucking and bias compensation module, and wherein the power module comprises a voltage source, a current source, or a combination thereof.
Embodiments of the present disclosure may also provide an apparatus for controlling an ion energy distribution that includes an IEDF width control module that comprises a voltage source or a current source, wherein the voltage source or current source is electrically coupled between a main pulser output and ground or between the main pulser output and an electrode within a processing chamber, and wherein the voltage source or the current source comprises a DC current source or a shaped DC pulse voltage source or a DC voltage source electrically coupled in series to a resistor; and a switch electrically coupled in parallel with the voltage source or the current source, and between the main pulser output and the ground or between the main pulser output and an electrode within a processing chamber. The apparatus also includes a non-transitory computer-readable medium that includes instructions that, when executed on a processor, perform operations for controlling a width of an ion energy distribution function (IEDF), the operations comprising delivering a first pulse voltage waveform to an electrode of the processing chamber from a main pulser output of the main pulser, the main pulser output electrically coupled to the IEDF width control module, measuring at least one of a current flowing from the IEDF width control module, a voltage applied by the IEDF width control module, and a voltage derivative at a node between the IEDF width control module and the electrode in the processing chamber, calculating an ion current of the processing chamber and a capacitance of the processing chamber based on at least one of the measured current, the measured voltage and the measured voltage derivative, determining a setpoint for a voltage or a current provided from the IEDF width control module or setpoint for a voltage derivative provided from the IEDF width control module; and adjusting the voltage or the current provided from the IEDF width control module, or voltage derivative provided from the IEDF width control module to control the width of the IEDF.
Embodiments of the present disclosure may also provide a pulsed direct current (DC) power delivery system, comprising a main pulser configured to deliver DC pulse waveforms to a main pulser output, and a power module electrically coupled to the main pulser output of the main pulser, the power module configured to control an ion energy distribution function of ions within a formed plasma. The power module may include a voltage source or a current source, wherein the voltage source or current source is electrically coupled between the main pulser output and ground, and wherein the voltage source or the current source comprises at least one of a DC voltage source electrically coupled in series to a resistor, a DC current source, or a shaped DC pulse voltage source; and a switch electrically coupled in parallel with the voltage source or the current source, and between the main pulser output and the ground.
Embodiments of the present disclosure may also provide a pulsed direct current (DC) power delivery system, comprising a main pulser configured to deliver DC pulse waveforms to a main pulser output; and a power module electrically coupled to the output of the main pulser, the power module configured to control an ion energy distribution function of ions within a formed plasma, the power module comprising a voltage source or a current source, wherein the voltage source or current source is configured to be electrically coupled between the main pulser output and an electrode within a processing chamber, and wherein the voltage source or the current source comprises a DC current source or a shaped DC pulse voltage source or a DC voltage source electrically coupled in series to a resistor, and a switch electrically coupled in parallel to the voltage source or the current source.
So that the manner in which the above recited features of the present disclosure can be understood in detail, a more particular description of the disclosure, briefly summarized above, may be had by reference to embodiments, some of which are illustrated in the appended drawings. It is to be noted, however, that the appended drawings illustrate only exemplary embodiments and are therefore not to be considered limiting of its scope, for the disclosure may admit to other equally effective embodiments.
To facilitate understanding, identical reference numerals have been used, where possible, to designate identical elements that are common to the figures. It is contemplated that elements and features of one embodiment may be beneficially incorporated in other embodiments without further recitation.
Embodiments of the present disclosure generally relate to apparatus and methods for plasma processing of a substrate, and specifically to apparatus and methods for controlling an ion energy distribution during plasma processing. The methods and apparatus, e.g., circuits, described herein enable control over the shape (e.g., narrow, or adjustable width) of the voltage waveform of a pulsed DC power supply. Embodiments described herein further enable, e.g., control over the ion energy distribution function (IEDF) including monoenergetic ion acceleration.
The IEDF is a controllable parameter useful for processing a substrate via a plasma process, such as etching high aspect ratio features in a surface of a substrate. Typically, pulsed DC biases can provide a narrower IEDF as compared to sine wave RF biases according to the following mechanism. Because ions are accelerated by a less time-varying electric field within a pulsed DC period, the energy gained by the ions within the sheath also exhibits a lower time variance than when varying sine wave RF bias. As a result, ions accelerated by the pulsed DC bias have a narrower IEDF than those created by use of a sine wave RF bias. However, an ion current from the bulk plasma to the substrate distorts the voltage waveform at the surface of the substrate and broadens the ion energy distribution. Methods and apparatus described herein can, e.g., compensate this ion current and actively control the width of the ion energy distribution.
Conventional methods and apparatus use an iteration control loop to control the width of the ion energy distribution. Before convergence of the control algorithm, estimation of the plasma parameters (e.g., ion current, sheath thickness, and IEDF width) are inaccurate. Moreover, controlling the width of the IEDF by using iterations is slow and can result in non-convergence of the control algorithm.
In contrast, the methods and apparatus described herein utilize a single loop process, without iteration, to determine the ion current and the compensation current to achieve a given IEDF width. Accordingly, the methods and apparatus described herein reach a desired state of the IEDF, e.g., a narrow IEDF, faster than the state-of-the-art. This is due to, e.g., not using an iteration in determining the solution of the compensation current. As is discussed further below,
Briefly, and in some embodiments, a substrate support assembly includes a body, the body including a substrate support portion and/or an edge ring portion. A substrate electrode is embedded in the substrate support portion for applying a substrate voltage to a substrate. A substrate voltage control circuit is coupled to the substrate electrode. The edge ring portion includes an edge ring electrode embedded therein for applying an edge ring voltage to a region of internal volume of the process chamber near an edge ring. An edge ring voltage control circuit is coupled to the edge ring electrode. At least one DC pulse source, such as a shaped DC pulse source, is coupled to the substrate voltage control circuit and/or the edge ring voltage control circuit. The substrate voltage circuit and/or the edge ring voltage control circuit is tunable to adjust the voltage and/or amount of power provided to each circuit. Adjustment of the voltage amplitude via, e.g., tuning the substrate voltage control circuit and/or the edge ring voltage control circuit results in adjustment and control of the ion energy distribution. In some embodiments, as will be discussed further below, the edge ring voltage control circuit and/or the substrate voltage control circuit are configured to provide a constant current versus apply a desired voltage to adjust and control the ion energy distribution.
In some embodiments, a control circuit of the IEDF width is coupled to the substrate support. The control circuit of the IEDF width can be integrated inside a main pulsed DC power supply, or as a separate module, or as an integrated module with a bias compensation module.
Example Processing System Configurations
The processing chamber 100 includes a chamber body 101 and a lid 102 disposed thereon that together define an internal volume 124. The chamber body 101 is typically coupled to an electrical ground 103. A substrate support assembly 104 is disposed within the inner volume to support the substrate 105 thereon during processing. An edge ring 106 is positioned on the substrate support assembly 104 and surrounds the periphery of the substrate 105. The processing chamber 100 also includes an inductively coupled plasma apparatus 107 for generating a plasma of reactive species within the processing chamber 100, and a controller 108 adapted to control systems and subsystems of the processing chamber 100. In some embodiments, the inductively coupled plasma apparatus 107 can be replaced by a grounded showerhead, which is disposed over the substrate support assembly 104, and RF power is delivered from an electrode (e.g., substrate electrode 109) positioned underneath the substrate to generate capacitively coupled plasma.
The substrate support assembly 104 is disposed in the internal volume 124. The substrate support assembly 104 generally includes a substrate support 152. The substrate support 152 includes an electrostatic chuck 150 comprising a substrate support portion 154 configured to underlay and support the substrate 105 to be processed and an edge ring portion 156 configured to support an edge ring 106. The substrate support assembly 104 can additionally include a heater assembly 169. The substrate support assembly 104 can also include a cooling base 131. The cooling base 131 can alternately be separate from the substrate support assembly 104. The substrate support assembly 104 can be removably coupled to a support pedestal 125. The support pedestal 125 is mounted to the chamber body 101. The support pedestal 125 can optionally include a facility plate 180. The substrate support assembly 104 may be periodically removed from the support pedestal 125 to allow for refurbishment of one or more components of the substrate support assembly 104. Lifting pins 146 are disposed through the substrate support assembly 104 as conventionally known to facilitate substrate transfer.
The facility plate 180 is configured to accommodate a plurality of fluid connections from the electrostatic chuck 150 and the cooling base 131. The facility plate 180 is also configured to accommodate the plurality of electrical connections from the electrostatic chuck 150 and the heater assembly 169. The plurality of electrical connections can run externally or internally of the substrate support assembly 104, while the facility plate 180 provides an interface for the connections to a respective terminus.
A substrate electrode 109 is embedded within the substrate support portion 154 of the electrostatic chuck 150 for applying a substrate voltage waveform to a substrate 105 disposed on an upper surface 160 of the substrate support assembly 104. The edge ring portion 156 has an edge ring electrode 111 embedded therein for applying an edge ring voltage waveform to the edge ring 106. An edge ring IEDF width control circuit 155 is coupled to the edge ring electrode 111. A substrate IEDF width control circuit 158 is coupled to the substrate electrode 109. In one embodiment, a first shaped DC pulse voltage source 159 is coupled to one or both of the edge ring IEDF width control circuit 155 and the substrate IEDF width control circuit 158. While the disclosure provided herein refers to the first shaped DC pulse voltage source 159 and second shaped DC pulse voltage source 161 as being “shaped” DC pulse voltage sources this nomenclature or names are not intended to be limiting as to the type of pulsed voltage waveforms that can be supplied by these DC pulse voltage sources. In another embodiment, as shown in
The inductively coupled plasma apparatus 107 is disposed above the lid 102 and is configured to inductively couple RF power to gases within the internal volume 124 of the processing chamber 100 to generate a plasma 116. The inductively coupled plasma apparatus 107 includes first coil 118 and second coil 120 disposed above the lid 102. The relative position, ratio of diameters of each coil 118, 120, and/or the number of turns in each coil 118, 120 can each be adjusted as desired to control the profile or density of the plasma 116 being formed. Each of the first and second coils 118, 120 is coupled to an RF power supply 121 through a matching network 122 via an RF feed structure 123. The RF power supply 121 can illustratively be capable of producing up to about 4000 W (but not limited to about 4000 W) at a tunable frequency in a range from 50 kHz to 13.56 MHz, although other frequencies and powers can be utilized as desired for particular applications.
In some examples, a power divider 126, such as a dividing capacitor, can be provided between the RF feed structure 123 and the RF power supply 121 to control the relative quantity of RF power provided to the respective first and second coils 118, 120. In other embodiments, as discussed below in relation to
A heater element 128 can be disposed on the lid 102 to facilitate heating the interior of the processing chamber 100. The heater element 128 can be disposed between the lid 102 and the first and second coils 118, 120. In some examples, the heater element 128 includes a resistive heating element and is coupled to a power supply 130, such as an AC power supply, configured to provide sufficient energy to control the temperature of the heater element 128 within a desired range.
During operation, the substrate 105, such as a semiconductor substrate or other substrate suitable for plasma processing, is placed on the substrate support assembly 104. Substrate lift pins 146 are movably disposed in the substrate support assembly 104 to assist in transfer of the substrate 105 onto the substrate support assembly 104. After positioning of the substrate 105, process gases are supplied from a gas panel 132 through entry ports 134 into the internal volume 124 of the chamber body 101. The process gases are ignited into a plasma 116 in the internal volume 124 of the processing chamber 100 by applying power from the RF power supply 121 to the first and second coils 118, 120. The pressure within the internal volume 124 of the processing chamber 100 can be controlled using a valve 136 and a vacuum pump 138.
The processing chamber 100 includes the controller 108 to control the operation of the processing chamber 100 during processing. The controller 108 comprises a central processing unit (CPU) 140, a memory 142, and support circuits 144 for the CPU 140 and facilitates control of the components of the processing chamber 100. The controller 108 can be one of any form of general-purpose computer processor that can be used in an industrial setting for controlling various chambers and sub-processors. The memory 142 (e.g., non-volatile memory) stores software (source or object code) that can be executed or invoked to control the operation of the processing chamber 100 in the manner described herein. The software when executed by the processing unit is configured to perform one or more of the methods described herein. For example, the controller 108 is configured to control the first shaped DC voltage source 159, the second shaped DC voltage source 161, the edge ring IEDF width control circuit 155, and the substrate IEDF width control circuit 158 during the processing of a substrate in a process chamber.
The processing chamber 200 includes a substrate 105 disposed on a substrate support assembly 104 as described in
The substrate support assembly 104, facility plate 180, substrate electrode 109, and edge ring electrode 111 illustrated in
Operation of the processing chamber 200 and processing of the substrate 105 can be performed in a similar fashion as that of processing chamber 100. In some embodiments, the processing system configurations include an ion suppressor positioned inside a processing chamber to control the type and quantity of plasma excited species that reach the substrate. In some embodiments, the ion suppressor unit is a perforated plate that may also act as an electrode of the plasma generating unit. In these and other embodiments, the ion suppressor can be the showerhead that distributes gases and excited species to a reaction region (e.g., internal region 124) in contact with the substrate. In some embodiments, ion suppression is realized by a perforated plate ion suppressor and a showerhead, both of which plasma excited species pass through to reach the reaction region.
When voltage is applied to the substrate (or wafer) by the shaped DC voltage source 159, a waveform develops.
At the end of the ion current stage, the substrate voltage rises to the bulk plasma voltage and the sheath collapses, such that electrons travel from the plasma to the substrate surface and neutralizes the positive charges at the substrate surface. As a result, the surface of the substrate is reset for the next pulse waveform cycle.
In general, the output of the first and second shaped DC voltage sources 159 and 161 are configured to generate a voltage waveform that includes at least one portion in which a voltage changes from a first voltage level to a second voltage level, in either a positive or negative voltage direction relative to ground. During processing pulsers generate a pulse voltage waveform that alternates between the first and second voltage levels periodically. The period at the higher voltage level during a portion of the pulse voltage waveform corresponds to the sheath collapse stage. The period at the lower voltage level during a portion of the pulse voltage waveform corresponds to the ion current stage. While the schematic representations of the first and second shaped DC voltage sources 159 and 161 in
Example Circuits
The example circuit 465 includes a pulsed DC power supply 466 coupled to a second power module 470 through a series inductor 468 and a resistor 469 in series. The second power module 470 modulates the width of the ion energy distribution function (IEDF). An optional blocking capacitor 471 may exist between plasma chamber load 472 and the rest of the circuit 465. A controller, not shown, which may be realized by hardware, software, firmware, or a combination thereof, is utilized to control various components represented in
The shaped DC power supply 466 generates a voltage waveform with at least two voltage levels—a low voltage level and a high voltage level. The low voltage level corresponds to the ion current stage. The high voltage level corresponds to the sheath collapse stage. In the ion current stage, the second power module 470 modulates the slope of the voltage vs. time, shown in
The shaped DC voltage source 486 generates a voltage waveform with two voltage levels—a low voltage level and a high voltage level. The low voltage level corresponds to the ion current stage. The high voltage level corresponds to the sheath collapse stage. In the ion current stage, the second power module 488 creates a voltage slope vs. time. The resulting voltage waveform on the substrate is the sum of the output voltage of the shaped DC voltage source 486 and the second power module 488, which can be modulated, and thereby, the IEDF width is modulated.
The shaped DC voltage source 491 generates a voltage waveform with at least two voltage levels—a low voltage level and a high voltage level. The low voltage level corresponds to the ion current stage. The high voltage level corresponds to the sheath collapse stage. In the ion current stage, the second power module 492 creates a voltage slope vs. time. The resulting voltage waveform on the substrate is the sum of the output voltage of the shaped DC voltage source 491 and the second power module 492, which can be modulated, and thereby, the IEDF width is modulated. The switch 495 is open in the ion current stage, such that the chucking and bias compensation module 493 do not modulate the voltage of the plasma chamber load. In the sheath collapse stage, the switch 495 is closed, and the chucking and bias compensation module 493 resets the substrate chucking voltage to a setpoint.
The IEDF width control module 508 can be modeled as a circuit comprising a transistor-transistor logic (TTL) signal source 510 and a switch 512, an optional diode 514, an optional capacitance 516, and a third shaped DC pulse voltage source 518 that are coupled in parallel and coupled to a ground 517. Diode 514 is a flyback diode for protecting the switch 512 and the third shaped DC pulse voltage source 518. In some embodiments, a blocking capacitance 520 exists between the current return path 503 and a chamber capacitance 536. The chamber capacitance 536 can be, for example, a portion of the impedance formed between the substrate electrode 109 and the substrate, or between the edge ring electrode 111 and the edge ring 106. In some embodiments, the blocking capacitance 520 is also coupled to a substrate chucking and bias compensation module 522.
The substrate chucking and bias compensation module 522 is a circuit that includes a diode 524 coupled in series to a resistor 526, and a DC voltage source 528, and a resistor 530 coupled in series to a capacitance 532 and ground 534. The DC voltage source 528 could be configured to have a positive or a negative polarity in any pulse waveform cases as desired for a particular process chamber configuration. The capacitance 536 is further coupled to stray capacitance 538 and the plasma sheath 540 portion of the load. The substrate chucking and bias compensation module 522 is further coupled to stray capacitance 538. The plasma sheath 540 may be modeled (plasma sheath model) as a circuit comprising a sheath capacitance 542 coupled in parallel with a current source 544 and a diode 546 coupled to ground 548. In some embodiments, the series inductor 504 and resistor 506 in the current return path can be replaced by a switch 479 (
In use, and for the configuration illustrated in
As shown in
The intrinsic factor to broaden the IEDF is the ion current, “I0”, depositing positive charges on the substrate such that the voltage of the substrate gradually increases and the ion energy bombarding the substrate drops (e.g., trace 305 of
The method of IEDF modulation includes two parts: (1) determining the ion current I0 and the sheath capacitance C1, and (2) determining the slope of the shaped DC pulse voltage source dV1/dt to achieve a target IEDF width. With a saw-like voltage source V1 and shaped DC voltage source 159 or 161 supplying power to the substrate 105 or edge ring 106, the IEDF width at the substrate or edge ring is the change of substrate or edge ring voltage from the beginning to the end of the ion current stage (
ΔV=I1*T/C1, (1)
where ΔV is the IEDF width and T is the time duration of the ion current stage. In order to obtain the target IEDF width (ΔV), the sheath capacitance C1 and the desired current I1 through the sheath capacitance are to be determined.
To determine the sheath capacitance C1 and the ion current I0, the relationships of the currents and voltages in the control circuit are analyzed. As shown, the currents passing the capacitors C1 through C4 are referred to as I1 through I4, with the arrows in the circuit schematic pointing to the positive direction. Based on Kirchhoff's current law, the ion current I0 equals the sum of the currents through capacitors C1 and C2:
I0=I1+I2. (2)
The current through capacitor C2 equals the sum of the currents through capacitors C3 and C4:
I2=I3+I4. (3)
Based on Kirchhoff's voltage law, the voltage sum of the closed loop of C1, C2, and C3 is zero. The time derivative of the voltage sum of C1, C2, and C3 is also zero. Denote the voltage at the intersection of capacitors C2 and C3 as V3. The time derivative of the voltage across capacitor C3 is dV3/dt=I3/C3. Similar relationships exist for capacitors C1 and C2, and Kirchhoff's voltage law provides equation (4):
I1/C1=I2/C2+I3/C3. (4)
Applying Kirchhoff's voltage law to the closed loop of capacitors C3 and C4 and voltage source V1 provides equation (5):
I3/C3=I4/C4+dV1/dt. (5)
In equations (2)-(5), C2, C3, and C4 are prior determined by the product specification sheet or estimation based on chamber parts dimensions, or by prior measurement, such as direct measurement of the impedance using a multimeter, or extracting the capacitance value from S-parameter or Z-parameter measurements. The current I4 can be measured directly by sensors, such as current probes and/or integrated voltage-current (VI) sensors. Voltage V3 can be measured directly by sensors, such as voltage probes and/or integrated VI sensors. Current I3 can be calculated as I3=C3*dV3/dt. The voltage slope dV1/dt is user-controlled and known, such as zero or 1 Volt/nanosecond (V/nsec). By setting the shaped DC pulse voltage source V1 at two different slopes dV1/dt and dV1′/dt, the currents I4, I4′ and the time derivatives of the voltage dV3/dt, dV3′/dt can be determined. The set of equations (2)-(5) at two slopes dV1/dt and dV1′/dt form eight equations that can be solved to give the sheath capacitance:
and the ion current:
To obtain the target IEDF width (ΔV), the total current through the sheath capacitor C1 is
I1=C1*ΔV/T. (8)
Plugging equations (6)-(8) into equations (2)-(5) gives the voltage slope of the saw-like voltage source V1 for achieving the IEDF width ΔV:
In the case of the narrowest IEDF (ΔV=0), the voltage slope of the saw-like voltage source V1 is
The plasma sheath 540 may be modeled (plasma sheath model) as a circuit comprising a sheath capacitance 542 coupled in parallel with a current source 544 and a diode 546 coupled to ground 548.
In use, and for the configuration illustrated in
As shown in
The intrinsic factor to broaden IEDF is the ion current I0 depositing positive charges on the substrate such that the voltage of the substrate gradually increases and the ion energy bombarding the substrate drops (trace 305 of
The method of IEDF modulation includes two parts: (1) determining the ion current I0 and the sheath capacitance C1, and (2) determining the DC voltage V0 to achieve the target IEDF width. The IEDF width is the spread of the substrate or edge ring voltage from the beginning to the end of the ion current stage (
where ΔV is the IEDF width and T is the time duration of the ion current stage. In order to obtain the target IEDF width (ΔV), the sheath capacitance C1 and the desired current I1 through the sheath capacitance are to be determined.
To determine the sheath capacitance C1 and the ion current I0, the relationships of the currents and voltages in the control circuit are analyzed. Here, for example, the currents passing the capacitors C1 through C5 are referred to as I1 through I5, with the arrows in the circuit schematic pointing to the positive direction. The voltage at the intersection of capacitors C2 and C3 is V3. There is a threshold voltage for the DC voltage source V0, denoted as Vth, below which the diode D3 bypasses the series of the DC voltage source V0 and the resistor R such that the output voltage of the IEDF width control module is zero. Vth is plasma-condition dependent and can be determined experimentally by, e.g., gradually increasing the DC voltage V0 up to the point that the current I4 or voltage V3 is affected by the DC voltage output V0.
In the case of V0≤Vth, based on Kirchhoff's current law, the ion current I0 equals the sum of the currents through capacitors C1 and C2:
I0=1I+I2. (12)
The current through capacitor C2 equals the sum of the currents through capacitors C3 and C4:
I2=I3+I4. (13)
Based on Kirchhoff's voltage law, the voltage sum of the closed loop of C1, C2, and C3 is zero. The time derivative of the voltage sum of C1, C2, and C3 is also zero. The time derivative of the voltage across capacitor C3 is dV3/dt=I3/C3. The same relationships hold for capacitors C1 and C2. Using Kirchhoff's voltage law on capacitors C1 and C2 provides equation (14):
I1/C1=I2/C2+I3/C3. (14)
Applying Kirchhoff's voltage law to the closed loop of capacitors C3 and C4, as well as the diode-bypassed IEDF width control module, provides equation (15):
I3/C3=I4/C4. (15)
In the case of V0>Vth, equations (12)-(14) still hold. Applying Kirchhoff's voltage law to the closed loop of capacitors C3, C4, and C5 provides equation (16):
I3/C3=I4/C4+I5/C5. (16)
Applying Kirchhoff's voltage law to the closed loop of capacitor C5, DC voltage source V0, and resistor R provides equation (17):
where (I4−I5) is the current through the DC voltage source V0 and the resistor R when the diode D3 is inactive.
In some embodiments, there is no capacitor C5. In such cases, there is no equation (17) and equation (16) becomes
I3/C3=I4/C4+R*dI4/dt, (18)
In equations (12)-(18), C2, C3, C4, and C5 are prior determined by the product specification sheet or estimation based on chamber parts dimensions, or by prior measurement, such as direct measurement of the impedance using a multimeter, or extracting the capacitance value from S-parameter or Z-parameter measurements. The current I4 can be measured directly by sensors, such as current probes and/or integrated VI sensors. Voltage V3 can be measured directly by sensors, such as voltage probes and/or integrated VI sensors. Current I3 can be calculated as I3=C3*dV3/dt. The DC voltage V0 is user-controlled and known, such as setting the DC voltage output V0 to a value from zero to a few kV. By setting the DC voltage V0 at two different values V0 and V0′, with at least one of them above the threshold voltage Vth, the currents I4, I4′ and the time derivatives of the voltage dV3/dt, dV3′/dt can be determined. Solving the set of equations (12)-(18) gives the sheath capacitance C1:
and the ion current I0:
I0=(C1/C2+C1/C3+1)*I3+(C1/C2+1)*I4. (20)
Plugging in the sheath capacitance C1 and the ion current I0 in the set of equations (12)-(18), the currents I1 through I5 can be calculated for any DC voltage V0.
Plugging in the expression of I1 into equation (11) by the known capacitances C1 through C5, the resistance R, and the DC voltage V0, the relationship between the IEDF width (ΔV) and the DC voltage V0 can be obtained. Accordingly, for a target IEDF width (ΔV), the required DC voltage V0 is determined.
In some embodiments, the resistor R is large enough (e.g., about 10 kΩ), and the current through the DC voltage source V0 is approximately time constant in the ion current stage and equal to V0/R. In these embodiments, equation (17) becomes
I4=I5+V0/R. (21)
Solving equations (12), (13), (14), (16), and (21) gives the total current through the sheath capacitor C1 as equation (22):
where
k=C3C4+C4C5+C5C3
Using equation (8) for this approximate case of constant current I1, the DC voltage V0 utilized for obtaining the target IEDF width (ΔV) can be found using equation (23):
In the case of narrowest IEDF (ΔV=0), the DC voltage V0 is
The plasma sheath 540 may be modeled (plasma sheath model) as a circuit comprising a sheath capacitance 542 coupled in parallel with a current source 544 and a diode 546 coupled to ground 548.
In use, and for the configuration illustrated in
As shown in
The intrinsic factor to broaden IEDF is the ion current I0 depositing positive charges on the substrate such that the voltage of the substrate gradually increases and the ion energy bombarding the substrate drops (trace 305 of
The method of IEDF modulation includes two parts: (1) determining the ion current I0 and the sheath capacitance C1, and (2) determining the DC current Ic to achieve a target IEDF width. With a DC current source Ic and shaped DC voltage source 159 or 161 supplying power to the substrate 105 or edge ring 106, the IEDF width at the substrate or edge ring is the change of substrate or edge ring voltage from the beginning to the end of the ion current stage (
ΔV=I1*T/C1, (25)
where ΔV is the IEDF width and T is the time duration of the ion current stage. In order to obtain the target IEDF width (ΔV), the sheath capacitance C1 and the desired current I1 through the sheath capacitance are to be determined.
To determine the sheath capacitance C1 and the ion current I0, the relationships of the currents and voltages in the control circuit are analyzed. As shown, the currents passing the capacitors C1 through C4 are referred to as I1 through I4, with the arrows in the circuit schematic pointing to the positive direction. Based on Kirchhoff's current law, the ion current I0 equals the sum of the currents through capacitors C1 and C2:
I0=I1+I2. (26)
The current through capacitor C2 equals the sum of the currents through capacitors C3 and C4:
I2=I3+I4. (27)
The current through capacitor C4 equals the sum of the currents through capacitors C5 and the DC current source Ic:
I4=I5+Ic. (28)
Based on Kirchhoff's voltage law, the voltage sum of the closed loop of C1, C2, and C3 is zero. The time derivative of the voltage sum of C1, C2, and C3 is also zero. Denote the voltage at the intersection of capacitors C2 and C3 as V3. The time derivative of the voltage across capacitor C3 is dV3/dt=I3/C3. Similar relationships exist for capacitors C1 and C2, and Kirchhoff's voltage law provides equation (29):
I1/C1=I2/C2+I3/C3. (29)
Applying Kirchhoff's voltage law to the closed loop of capacitors C3, C4 and C5 (5):
I3/C3=I4/C4+I5/C5. (30)
In equations (26, 27, 28, 29, and 30), C2-C5 are prior determined by the product specification sheet or estimation based on chamber parts dimensions, or by prior measurement, such as direct measurement of the impedance using a multimeter, or extracting the capacitance value from S-parameter or Z-parameter measurements. The current I4 or I5 can be measured directly by sensors, such as current probes and/or integrated voltage-current (VI) sensors. Voltage V3 can be measured directly by sensors, such as voltage probes and/or integrated VI sensors. Current I3 can be calculated as I3=C3*dV3/dt. The current Ic is user-controlled and known, such as zero or 3 A. By setting the DC current source Ic at two values Ic and Ic′, the currents I4 and I4′, or I5 and I5′, or the time derivatives of the voltage dV3/dt and dV3′/dt can be determined. The set of equations (26, 27, 28, 29, and 30) at two DC current values Ic and Ic′ form ten equations that can be solved to give the sheath capacitance C1 in terms of the currents I4 and I4′, or I5 and I5′, or the time derivatives of the voltage dV3/dt and dV3′/dt. For instance, the sheath capacitance in terms of the currents I4 and I4′ is:
and the ion current:
To obtain the target IEDF width (ΔV), the total current through the sheath capacitor C1 is
I1=C1*ΔV/T. (33)
Plugging equations (31, 32, and 33) into equations (26, 27, 28, 29, and 30) gives the DC current Ic for achieving the IEDF width ΔV:
In the case of the narrowest IEDF (ΔV=0), the DC current Ic is
The IEDF width control module 702 may be modeled as a circuit comprising a TTL signal source 704 that is coupled to a switch 706, and is coupled to a ground 716. The TTL signal source 704 and switch 706 are coupled in parallel to diode 708, a DC voltage source 710, and an optional capacitance 714. The DC voltage source 710 is coupled in series to resistor 712. The IEDF width control module 702 is coupled to a chamber capacitance 536. The capacitance 536 can be, for example, a portion of the impedance formed between the substrate electrode 109 and the substrate 105, or between the edge ring electrode 111 and the edge ring 106. In some embodiments, the IEDF width control module 702 is also coupled to the substrate chucking and bias compensation module 522 discussed above. The substrate chucking and bias compensation module 522 is further coupled to stray capacitance 538. The substrate chucking and bias compensation module 522 is a circuit that includes a diode 524 coupled in series to a resistor 526, and a DC voltage source 528, and a resistor 530 coupled in series to a capacitance 532 and ground 534. The diode 708 is a flyback diode for protecting the switch 706 and DC voltage source 710.
The plasma sheath 540 may be modeled (plasma sheath model) as a circuit comprising a sheath capacitance 542 coupled in parallel with a current source 544 and a diode 546 coupled to ground 548.
In use, and for the configuration shown in
The IEDF width control module 802 may be modeled as a circuit comprising a TTL signal source 704 coupled in parallel with a switch 706. The TTL signal source 704 is also coupled to a ground 716. The TTL signal source 704 and switch 706 are coupled in parallel to diode 708, a third shaped DC pulse voltage source 804, and an optional capacitance 714. The IEDF width control module 802 is coupled to a chamber capacitance 536. The capacitance 536 can be, for example, a portion of the impedance formed between the substrate electrode 109 and the substrate 105, or between the edge ring electrode 111 and the edge ring 106. In some embodiments, the IEDF width control module 802 is also coupled to the substrate chucking and bias compensation module 522 discussed above. The substrate chucking and bias compensation module 522 is a circuit that includes a diode 524 coupled in series to a resistor 526, a DC voltage source 528, and a resistor 530 coupled in series to a capacitance 532 and ground 534. The diode 708 is a flyback diode for protecting the switch and the third shaped DC pulse voltage source 804.
The substrate chucking and bias compensation module 522 is further coupled to chamber capacitance 536. The plasma sheath 540 may be modeled (plasma sheath model) as a circuit comprising a sheath capacitance 542 coupled in parallel with a current source 544 and a diode 546 coupled to ground 548.
In use, and for the configuration shown in
The IEDF width control module 702 may be modeled as a circuit comprising a TTL signal source 704 that is coupled to a switch 706, and is coupled to a ground 716. The TTL signal source 704 and switch 706 are coupled in parallel to diode 708, a DC current source 605, and an optional capacitance 714. The IEDF width control module 702 is coupled to a chamber capacitance 536. The capacitance 536 can be, for example, a portion of the impedance formed between the substrate electrode 109 and the substrate 105, or between the edge ring electrode 111 and the edge ring 106. In some embodiments, the IEDF width control module 702 is also coupled to the substrate chucking and bias compensation module 522 discussed above. The substrate chucking and bias compensation module 522 is further coupled to stray capacitance 538. The substrate chucking and bias compensation module 522 is a circuit that includes a diode 524 coupled in series to a resistor 526, and a DC voltage source 528, and a resistor 530 coupled in series to a capacitance 532 and ground 534. The diode 708 is a flyback diode for protecting the switch 706 and DC current source 605.
The plasma sheath 540 may be modeled (plasma sheath model) as a circuit comprising a sheath capacitance 542 coupled in parallel with a current source 544 and a diode 546 coupled to ground 548.
In use, and for the configuration shown in
For the configurations shown in
The IEDF width control module 902 may be modeled as a circuit comprising a TTL signal source 904 coupled to a switch 906, which is also coupled to a ground 916. The TTL signal source 704 and switch 906 are coupled in parallel to a diode 908. The combination of the TTL signal source 904, the switch 906, and the diode 908 controls whether the substrate chucking and bias compensation module 920 is connected to another part of the circuit. The substrate chucking and bias compensation module 920 is a circuit that includes a capacitance 926 coupled in parallel to resistor 922 and a DC voltage source 924. The substrate chucking and bias compensation module 920 is coupled in series with the assembly of the TTL signal source 904 and switch 906, and the diode 908. The substrate chucking and bias compensation module 920 and the switch 906, as a whole, is coupled in parallel to a DC voltage source 910, which is connected in series with a resistor 912, and also in parallel to an optional capacitor 914. The diode 908 is a flyback diode for protecting the switch 906 and DC voltage sources 910 and 924.
A capacitance 536 may exist between stray capacitance 538 and the plasma sheath 540, which can be, for example, a portion of the impedance formed between the substrate electrode 109 and the substrate 105, or between the edge ring electrode 111 and the edge ring 106. Both the IEDF width control module 902 and the substrate chucking and bias compensation module 920 are coupled to either the substrate electrode 109 and/or the edge ring electrode 111. The IEDF width control module 902 is also coupled to stray capacitance 538. The plasma sheath 540 may be modeled (plasma sheath model) as a circuit comprising a sheath capacitance 542 coupled in parallel with a current source 544 and a diode 546 coupled to ground 548.
In use, and for the configuration illustrated in
The IEDF width control module 902 may be modeled as a circuit comprising a TTL signal source 904 coupled to a switch 906, which is also coupled to a ground 916. The TTL signal source 904 and switch 906 are coupled in parallel to a diode 908. The combination of the TTL signal source 904, the switch 906, and the diode 908 controls whether the substrate chucking and bias compensation module 920 is connected to the rest part of the circuit. The substrate chucking and bias compensation module 920 is a circuit that includes a capacitance 926 coupled in parallel to a DC voltage source 924 in series with a resistor 922. The substrate chucking and bias compensation module 920 is coupled in series with the assembly of the TTL signal source 904 and switch 906, and the diode 908. The substrate chucking and bias compensation module 920 and the switch 906, as a whole, is coupled in parallel to a DC current source 605, and also in parallel to an optional capacitor 914. The diode 908 is a flyback diode for protecting the switch 906 and DC current source 605.
A capacitance 536 may exist between stray capacitance 538 and the plasma sheath 540, which can be, for example, a portion of the impedance formed between the substrate electrode 109 and the substrate 105, or between the edge ring electrode 111 and the edge ring 106. Both the IEDF width control module 902 and the substrate chucking and bias compensation module 920 are coupled to either the substrate electrode 109 and/or the edge ring electrode 111. The IEDF width control module 902 is also coupled to stray capacitance 538. The plasma sheath 540 may be modeled (plasma sheath model) as a circuit comprising a sheath capacitance 542 coupled in parallel with a current source 544 and a diode 546 coupled to ground 548.
In use, and for the configuration illustrated in
The IEDF width control module 1002 may be modeled as a circuit comprising a TTL signal source 904 that is coupled to a switch 906, and also coupled to a ground 916. The TTL signal source 904 and switch 906 are coupled in parallel to diode 908. The combination of the TTL signal source 904 and switch 906, and the diode 908 controls whether the substrate chucking and bias compensation module is connected to another part of the circuit. The substrate chucking and bias compensation module 920 is a circuit that includes a capacitance 926 coupled in parallel to resistor 922 and a DC voltage source 924. The diode 908 is a flyback diode for protecting the switch, the DC pulse voltage source 1004, and the DC voltage source 924. The substrate chucking and bias compensation module 920 is coupled in series with the assembly of the TTL signal source 904 and switch 906, and the diode 908. The substrate chucking and bias compensation module 920 and the switch 906, as a whole, is coupled in parallel to a shaped DC pulse voltage source 1004, and also in parallel to an optional capacitor 914.
A capacitance 536 may exist between stray capacitance 538 and the plasma sheath 540, which can be, for example, a portion of the impedance formed between the substrate electrode 109 and the substrate 105, or between the edge ring electrode 111 and the edge ring 106. Both the IEDF width control module 1002 and the substrate chucking and bias compensation module 920 are coupled to either the substrate electrode 109 and/or the edge ring electrode 111. The IEDF width control module 1002 is also coupled to stray capacitance 538. The plasma sheath 540 may be modeled (plasma sheath model) as a circuit comprising a sheath capacitance 542 coupled in parallel with a current source 544 and a diode 546 coupled to ground 548.
In use, and for the configuration illustrated in
The control mechanism of
The method 1100 begins with applying, or otherwise introducing, a voltage to a suitable processing chamber by activating, or turning on, a main pulser (e.g., main pulser 502) coupled to a power module (e.g., the IEDF width control module). The main pulser can be the first shaped DC pulse voltage source 161, or the second shaped DC pulse voltage source 159. The IEDF width control module can be the substrate IEDF width control circuit 158, or the edge ring IEDF width control circuit 155, respectively. Here, the voltage is introduced to the substrate electrode, e.g., substrate electrode 109, and/or the edge ring electrode, e.g., edge ring electrode 111. The bias voltage on the substrate electrode and/or the edge ring electrode develops in the ion current stage and accelerates ions at an energy of, e.g., the product of the sheath voltage multiplied by the charge of the ions. In the collisionless sheath model, most of the ions can reach this maximum energy when bombarding the substrate electrode and/or edge ring electrode. However, due to, e.g., the ion current depositing positive charges on the substrate electrode and/or edge ring electrode, the voltage of the substrate electrode and/or edge ring electrode increases over time, reducing the sheath voltage and resulting in a spread of the ion energy.
At operation 1110, a current of the power module (e.g., the IEDF width control module), and/or a voltage or a voltage derivative of the IEDF width control module are measured under two or more conditions to determine the sheath capacitance C1 and/or the ion current I0. Here the current measured can be the current I4, which is the current through the capacitor C4 in
As an example, and for the configurations of
At operation 1115, the ion current I0 and the sheath capacitance C1 are calculated based on equations (6) and (7) for the configurations of
At operation 1120, a desired setpoint for a voltage (V0) or a current (Ic) or a voltage derivative (dV1/dt) of the IEDF width control module are determined to achieve a targeted IEDF width (ΔV). This determination is based on, e.g., determining a desired setting of the IEDF width control module to achieve a user-specified ion energy distribution width (ΔV). The DC voltage (V0) of the DC voltage source or the DC current (Ic) of the DC current source or the slope (dV1/dt) of the shaped DC pulse voltage (V1), can be determined from equations (23), (34), and (9), respectively. At operation 1125, the DC voltage (V0) or the DC current (Ic) or voltage derivative (dV1/dt) of the IEDF width control module are adjusted to the determined setpoints.
In contrast to conventional processes for controlling the IEDF, the method described herein is free of looping to determine the desired setpoint of the IEDF width control module. However, and in some embodiments, looping can be used to determine the desired set point. In such embodiments, the controller can monitor I4 and V3 in the ion current stage to detect any changes in the plasma conditions and to adjust the setpoint of the IEDF width control module accordingly.
A pulsed direct current (DC) power delivery system, comprising a main pulser configured to deliver DC pulse waveforms to a main pulser output, and a power module electrically coupled to the output of the main pulser, the power module configured to control an ion energy distribution function of ions within a formed plasma, the power module comprising a voltage source or a current source, wherein the voltage source or current source is electrically coupled between the main pulser output and ground, and wherein the voltage source or the current source comprises a DC current source or a DC voltage source electrically coupled in series to a resistor, and a switch electrically coupled in parallel with the voltage source or the current source, and between the main pulser output and the ground.
A pulsed direct current (DC) power delivery system, comprising a main pulser configured to deliver DC pulse waveforms to a main pulser output, and a power module electrically coupled to the output of the main pulser, the power module configured to control an ion energy distribution function of ions within a formed plasma, the power module comprising a voltage source or a current source, wherein the voltage source or current source is electrically coupled between the main pulser output and ground, and wherein the voltage source or the current source comprises a shaped pulse voltage source, and a switch electrically coupled in parallel with the voltage source or the current source, and between the main pulser output and the ground.
A pulsed direct current (DC) power delivery system, comprising a main pulser configured to deliver DC pulse waveforms to a main pulser output; and a power module electrically coupled to the output of the main pulser through a capacitance, wherein the power module is configured to be electrically coupled between the main pulser output and an electrode within a processing chamber, the power module configured to control an ion energy distribution function of ions within a formed plasma, the power module comprising a voltage source or a current source, and wherein the voltage source or the current source comprises a DC current source or a DC voltage source electrically coupled in series to a resistor; and a switch electrically coupled in parallel to the voltage source or the current source.
A pulsed direct current (DC) power delivery system, comprising a main pulser configured to deliver DC pulse waveforms to a main pulser output; and a power module electrically coupled to the output of the main pulser through a capacitance, wherein the power module is configured to be electrically coupled between the main pulser output and an electrode within a processing chamber, the power module configured to control an ion energy distribution function of ions within a formed plasma, the power module comprising a voltage source or a current source, and wherein the voltage source or the current source comprises a shaped pulse voltage source; and a switch electrically coupled in parallel to the voltage source or the current source.
A pulsed direct current (DC) power delivery system, comprising a main pulser configured to deliver DC pulse waveforms to a main pulser output; and a power module electrically coupled between the main pulser output and an electrode within a processing chamber, the power module configured to control an ion energy distribution function of ions within a formed plasma, the power module comprising a voltage source or a current source, and wherein the voltage source or the current source comprises a DC current source or a DC voltage source electrically coupled in series to a resistor; and a switch electrically coupled in parallel to the voltage source or the current source.
A pulsed direct current (DC) power delivery system, comprising a main pulser configured to deliver DC pulse waveforms to a main pulser output; and a power module electrically coupled between the main pulser output and an electrode within a processing chamber, the power module configured to control an ion energy distribution function of ions within a formed plasma, the power module comprising a voltage source or a current source, and wherein the voltage source or the current source comprises a shaped pulse voltage source; and a switch electrically coupled in parallel to the voltage source or the current source.
A non-transitory computer-readable medium storing instructions that, when executed on a processor, perform operations for controlling a width of an ion energy distribution function (IEDF), the operations comprising introducing a voltage to an electrode of a processing chamber by activating a main pulser, the main pulser having a main pulser output electrically coupled to an IEDF width control module, wherein the IEDF width control module comprises a voltage source or a current source, wherein the voltage source or current source is electrically coupled between the main pulser output and ground, or between the main pulser output and an electrode within a processing chamber, and wherein the voltage source or the current source comprises a shaped pulse voltage source or a DC current source or a DC voltage source electrically coupled in series to a resistor, and a switch electrically coupled in parallel with the voltage source or the current source, and between the main pulser output and the ground, or between the main pulser output and an electrode within a processing chamber, measuring a current of the IEDF width control module and a voltage or a voltage derivative of the IEDF width control module or a node between the main pulser and the chamber plasma load, calculating an ion current of the processing chamber and a capacitance of the plasma load based on the current and the voltage or voltage derivative of the IEDF width control module, determining a setpoint for a current or a voltage or a voltage derivative of the IEDF width control module, or any combination of, and adjusting the current or the voltage or voltage derivative of the IEDF width control module, or any combination of, to the determined setpoints to control the width of the IEDF.
In some embodiments of a pulsed direct current (DC) power delivery system, a main pulser output is electrically coupled to an IEDF width control module, wherein the IEDF width control module comprises a voltage source or a current source, wherein the voltage source or current source is electrically coupled between the main pulser output and ground, or between the main pulser output and an electrode within a processing chamber, and wherein the voltage source or the current source comprises a DC current source or a shaped DC pulse voltage source or a DC voltage source electrically coupled in series to a resistor, and a switch electrically coupled in parallel with the voltage source or the current source, and between the main pulser output and the ground or between the main pulser output and an electrode within a processing chamber. The pulsed direct current (DC) power delivery system also includes a non-transitory computer-readable medium that includes software instructions that, when executed on a processor, perform operations for controlling a width of an ion energy distribution function (IEDF), the operations comprising delivering a first pulse voltage waveform to an electrode of a processing chamber from a main pulser output of a main pulser, measuring a current flowing from the IEDF width control module, a voltage or a voltage derivative of a node between the main pulser and the chamber plasma load, calculating an ion current of the processing chamber and a capacitance of the processing chamber based on the measured current, the measured voltage or measured voltage derivative, determining a setpoint for a voltage provided from the IEDF width control module or setpoint for a voltage derivative provided from the IEDF width control module, and adjusting the voltage provided from the IEDF width control module or voltage derivative provided from the IEDF width control module to control the width of the IEDF.
The methods and apparatus, e.g., circuits, described herein enable control over the shape (e.g., narrow, or adjustable width) of the waveform of a pulsed DC substrate voltage. Embodiments described herein further enable, e.g., control over the ion energy distribution, including monoenergetic ion acceleration.
As is apparent from the foregoing general description and the specific embodiments, while forms of the present disclosure have been illustrated and described, various modifications can be made without departing from the spirit and scope of the present disclosure. Accordingly, it is not intended that the present disclosure be limited thereby. Likewise, the term “comprising” is considered synonymous with the term “including.” Likewise whenever a composition, an element or a group of elements is preceded with the transitional phrase “comprising,” it is understood that we also contemplate the same composition or group of elements with transitional phrases “consisting essentially of,” “consisting of,” “selected from the group of consisting of,” or “is” preceding the recitation of the composition, element, or elements and vice versa.
While the foregoing is directed to examples of the present disclosure, other and further examples of the disclosure may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow.
This application is a continuation-in-part of co-pending U.S. patent application Ser. No. 17/099,342, entitled “Apparatus and Methods for Controlling Ion Energy Distribution” and filed Nov. 16, 2020, which is herein incorporated by reference in its entirety.
Number | Name | Date | Kind |
---|---|---|---|
4070589 | Martinkovic | Jan 1978 | A |
4340462 | Koch | Jul 1982 | A |
4464223 | Gorin | Aug 1984 | A |
4504895 | Steigerwald | Mar 1985 | A |
4585516 | Corn et al. | Apr 1986 | A |
4683529 | Bucher, II | Jul 1987 | A |
4931135 | Horiuchi et al. | Jun 1990 | A |
4992919 | Lee et al. | Feb 1991 | A |
5099697 | Agar | Mar 1992 | A |
5140510 | Myers | Aug 1992 | A |
5242561 | Sato | Sep 1993 | A |
5449410 | Chang et al. | Sep 1995 | A |
5451846 | Peterson et al. | Sep 1995 | A |
5464499 | Moslehi et al. | Nov 1995 | A |
5554959 | Tang | Sep 1996 | A |
5565036 | Westendorp et al. | Oct 1996 | A |
5595627 | Inazawa et al. | Jan 1997 | A |
5597438 | Grewal et al. | Jan 1997 | A |
5610452 | Shimer et al. | Mar 1997 | A |
5698062 | Sakamoto et al. | Dec 1997 | A |
5716534 | Tsuchiya et al. | Feb 1998 | A |
5770023 | Sellers | Jun 1998 | A |
5796598 | Nowak et al. | Aug 1998 | A |
5810982 | Sellers | Sep 1998 | A |
5830330 | Lantsman | Nov 1998 | A |
5882424 | Taylor et al. | Mar 1999 | A |
5928963 | Koshiishi | Jul 1999 | A |
5933314 | Lambson et al. | Aug 1999 | A |
5935373 | Koshimizu | Aug 1999 | A |
5948704 | Benjamin et al. | Sep 1999 | A |
5997687 | Koshimizu | Dec 1999 | A |
6043607 | Roderick | Mar 2000 | A |
6051114 | Yao et al. | Apr 2000 | A |
6055150 | Clinton et al. | Apr 2000 | A |
6074518 | Imafuku et al. | Jun 2000 | A |
6089181 | Suemasa et al. | Jul 2000 | A |
6099697 | Hausmann | Aug 2000 | A |
6110287 | Arai et al. | Aug 2000 | A |
6117279 | Smolanoff et al. | Sep 2000 | A |
6125025 | Howald et al. | Sep 2000 | A |
6133557 | Kawanabe et al. | Oct 2000 | A |
6136387 | Koizumi | Oct 2000 | A |
6187685 | Hopkins et al. | Feb 2001 | B1 |
6197151 | Kaji et al. | Mar 2001 | B1 |
6198616 | Dahimene et al. | Mar 2001 | B1 |
6201208 | Wendt et al. | Mar 2001 | B1 |
6214162 | Koshimizu | Apr 2001 | B1 |
6232236 | Shan et al. | May 2001 | B1 |
6252354 | Collins et al. | Jun 2001 | B1 |
6253704 | Savas | Jul 2001 | B1 |
6277506 | Okamoto | Aug 2001 | B1 |
6309978 | Donohoe et al. | Oct 2001 | B1 |
6313583 | Arita et al. | Nov 2001 | B1 |
6355992 | Via | Mar 2002 | B1 |
6358573 | Raoux et al. | Mar 2002 | B1 |
6367413 | Sill et al. | Apr 2002 | B1 |
6392187 | Johnson | May 2002 | B1 |
6395641 | Savas | May 2002 | B2 |
6413358 | Donohoe | Jul 2002 | B2 |
6423192 | Wada et al. | Jul 2002 | B1 |
6433297 | Kojima et al. | Aug 2002 | B1 |
6435131 | Koizumi | Aug 2002 | B1 |
6451389 | Amann et al. | Sep 2002 | B1 |
6456010 | Yamakoshi et al. | Sep 2002 | B2 |
6483731 | Isurin et al. | Nov 2002 | B1 |
6535785 | Johnson et al. | Mar 2003 | B2 |
6621674 | Zahringer et al. | Sep 2003 | B1 |
6664739 | Kishinevsky et al. | Dec 2003 | B1 |
6733624 | Koshiishi et al. | May 2004 | B2 |
6740842 | Johnson et al. | May 2004 | B2 |
6741446 | Ennis | May 2004 | B2 |
6777037 | Sumiya et al. | Aug 2004 | B2 |
6808607 | Christie | Oct 2004 | B2 |
6818103 | Scholl et al. | Nov 2004 | B1 |
6818257 | Amann et al. | Nov 2004 | B2 |
6830595 | Reynolds, III | Dec 2004 | B2 |
6830650 | Roche et al. | Dec 2004 | B2 |
6849154 | Nagahata et al. | Feb 2005 | B2 |
6861373 | Aoki et al. | Mar 2005 | B2 |
6863020 | Mitrovic et al. | Mar 2005 | B2 |
6896775 | Chistyakov | May 2005 | B2 |
6902646 | Mahoney et al. | Jun 2005 | B2 |
6917204 | Mitrovic et al. | Jul 2005 | B2 |
6947300 | Pai et al. | Sep 2005 | B2 |
6962664 | Mitrovic | Nov 2005 | B2 |
6970042 | Glueck | Nov 2005 | B2 |
6972524 | Marakhtanov et al. | Dec 2005 | B1 |
7016620 | Maess et al. | Mar 2006 | B2 |
7046088 | Ziegler | May 2006 | B2 |
7059267 | Hedberg et al. | Jun 2006 | B2 |
7104217 | Himori et al. | Sep 2006 | B2 |
7115185 | Gonzalez et al. | Oct 2006 | B1 |
7126808 | Koo et al. | Oct 2006 | B2 |
7147759 | Chistyakov | Dec 2006 | B2 |
7151242 | Schuler | Dec 2006 | B2 |
7166233 | Johnson et al. | Jan 2007 | B2 |
7183177 | Al-Bayati et al. | Feb 2007 | B2 |
7206189 | Reynolds, III | Apr 2007 | B2 |
7218503 | Howald | May 2007 | B2 |
7218872 | Shimomura | May 2007 | B2 |
7226868 | Mosden et al. | Jun 2007 | B2 |
7265963 | Hirose | Sep 2007 | B2 |
7274266 | Kirchmeier | Sep 2007 | B2 |
7305311 | van Zyl | Dec 2007 | B2 |
7312974 | Kuchimachi | Dec 2007 | B2 |
7408329 | Wiedemuth et al. | Aug 2008 | B2 |
7415940 | Koshimizu et al. | Aug 2008 | B2 |
7440301 | Kirchmeier et al. | Oct 2008 | B2 |
7452443 | Gluck et al. | Nov 2008 | B2 |
7479712 | Richert | Jan 2009 | B2 |
7509105 | Ziegler | Mar 2009 | B2 |
7512387 | Glueck | Mar 2009 | B2 |
7535688 | Yokouchi et al. | May 2009 | B2 |
7586099 | Eyhorn et al. | Sep 2009 | B2 |
7586210 | Wiedemuth et al. | Sep 2009 | B2 |
7588667 | Cerio, Jr. | Sep 2009 | B2 |
7601246 | Kim et al. | Oct 2009 | B2 |
7609740 | Glueck | Oct 2009 | B2 |
7618686 | Colpo et al. | Nov 2009 | B2 |
7633319 | Arai | Dec 2009 | B2 |
7645341 | Kennedy et al. | Jan 2010 | B2 |
7651586 | Moriya et al. | Jan 2010 | B2 |
7652901 | Kirchmeier et al. | Jan 2010 | B2 |
7692936 | Richter | Apr 2010 | B2 |
7700474 | Cerio, Jr. | Apr 2010 | B2 |
7705676 | Kirchmeier et al. | Apr 2010 | B2 |
7706907 | Hiroki | Apr 2010 | B2 |
7718538 | Kim et al. | May 2010 | B2 |
7740704 | Strang | Jun 2010 | B2 |
7758764 | Dhindsa et al. | Jul 2010 | B2 |
7761247 | van Zyl | Jul 2010 | B2 |
7782100 | Steuber et al. | Aug 2010 | B2 |
7791912 | Walde | Sep 2010 | B2 |
7795817 | Nitschke | Sep 2010 | B2 |
7808184 | Chistyakov | Oct 2010 | B2 |
7821767 | Fujii | Oct 2010 | B2 |
7825719 | Roberg et al. | Nov 2010 | B2 |
7858533 | Liu et al. | Dec 2010 | B2 |
7888240 | Hamamjy et al. | Feb 2011 | B2 |
7898238 | Wiedemuth et al. | Mar 2011 | B2 |
7929261 | Wiedemuth | Apr 2011 | B2 |
RE42362 | Schuler | May 2011 | E |
7977256 | Liu et al. | Jul 2011 | B2 |
7988816 | Koshiishi et al. | Aug 2011 | B2 |
7995313 | Nitschke | Aug 2011 | B2 |
8044595 | Nitschke | Oct 2011 | B2 |
8052798 | Moriya et al. | Nov 2011 | B2 |
8055203 | Choueiry et al. | Nov 2011 | B2 |
8083961 | Chen et al. | Dec 2011 | B2 |
8110992 | Nitschke | Feb 2012 | B2 |
8128831 | Sato et al. | Mar 2012 | B2 |
8129653 | Kirchmeier et al. | Mar 2012 | B2 |
8133347 | Gluck et al. | Mar 2012 | B2 |
8133359 | Nauman et al. | Mar 2012 | B2 |
8140292 | Wendt | Mar 2012 | B2 |
8217299 | Ilic et al. | Jul 2012 | B2 |
8221582 | Patrick et al. | Jul 2012 | B2 |
8236109 | Moriya et al. | Aug 2012 | B2 |
8284580 | Wilson | Oct 2012 | B2 |
8313612 | McMillin et al. | Nov 2012 | B2 |
8313664 | Chen et al. | Nov 2012 | B2 |
8333114 | Hayashi | Dec 2012 | B2 |
8361906 | Lee et al. | Jan 2013 | B2 |
8382999 | Agarwal et al. | Feb 2013 | B2 |
8383001 | Mochiki et al. | Feb 2013 | B2 |
8384403 | Zollner et al. | Feb 2013 | B2 |
8391025 | Walde et al. | Mar 2013 | B2 |
8399366 | Takaba | Mar 2013 | B1 |
8419959 | Bettencourt et al. | Apr 2013 | B2 |
8422193 | Tao et al. | Apr 2013 | B2 |
8441772 | Yoshikawa et al. | May 2013 | B2 |
8456220 | Thome et al. | Jun 2013 | B2 |
8460567 | Chen | Jun 2013 | B2 |
8466622 | Knaus | Jun 2013 | B2 |
8542076 | Maier | Sep 2013 | B2 |
8551289 | Nishimura et al. | Oct 2013 | B2 |
8568606 | Ohse et al. | Oct 2013 | B2 |
8603293 | Koshiishi et al. | Dec 2013 | B2 |
8632537 | McNall, III et al. | Jan 2014 | B2 |
8641916 | Yatsuda et al. | Feb 2014 | B2 |
8685267 | Yatsuda et al. | Apr 2014 | B2 |
8704607 | Yuzurihara et al. | Apr 2014 | B2 |
8716114 | Ohmi et al. | May 2014 | B2 |
8716984 | Mueller et al. | May 2014 | B2 |
8735291 | Ranjan et al. | May 2014 | B2 |
8796933 | Hermanns | Aug 2014 | B2 |
8809199 | Nishizuka | Aug 2014 | B2 |
8821684 | Ui et al. | Sep 2014 | B2 |
8828883 | Rueger | Sep 2014 | B2 |
8845810 | Hwang | Sep 2014 | B2 |
8852347 | Lee et al. | Oct 2014 | B2 |
8884523 | Winterhalter et al. | Nov 2014 | B2 |
8884525 | Hoffman et al. | Nov 2014 | B2 |
8889534 | Ventzek et al. | Nov 2014 | B1 |
8895942 | Liu et al. | Nov 2014 | B2 |
8907259 | Kasai et al. | Dec 2014 | B2 |
8916056 | Koo et al. | Dec 2014 | B2 |
8926850 | Singh et al. | Jan 2015 | B2 |
8963377 | Ziemba et al. | Feb 2015 | B2 |
8979842 | McNall, III et al. | Mar 2015 | B2 |
8993943 | Pohl et al. | Mar 2015 | B2 |
9011636 | Ashida | Apr 2015 | B2 |
9039871 | Nauman et al. | May 2015 | B2 |
9042121 | Walde et al. | May 2015 | B2 |
9053908 | Sriraman et al. | Jun 2015 | B2 |
9059178 | Matsumoto et al. | Jun 2015 | B2 |
9087798 | Ohtake et al. | Jul 2015 | B2 |
9101038 | Singh et al. | Aug 2015 | B2 |
9105447 | Brouk et al. | Aug 2015 | B2 |
9105452 | Jeon et al. | Aug 2015 | B2 |
9123762 | Lin et al. | Sep 2015 | B2 |
9129776 | Finley et al. | Sep 2015 | B2 |
9139910 | Lee et al. | Sep 2015 | B2 |
9147555 | Richter | Sep 2015 | B2 |
9150960 | Nauman et al. | Oct 2015 | B2 |
9159575 | Ranjan et al. | Oct 2015 | B2 |
9208992 | Brouk et al. | Dec 2015 | B2 |
9209032 | Zhao et al. | Dec 2015 | B2 |
9209034 | Kitamura et al. | Dec 2015 | B2 |
9210790 | Hoffman et al. | Dec 2015 | B2 |
9224579 | Finley et al. | Dec 2015 | B2 |
9226380 | Finley | Dec 2015 | B2 |
9228878 | Haw et al. | Jan 2016 | B2 |
9254168 | Palanker | Feb 2016 | B2 |
9263241 | Larson et al. | Feb 2016 | B2 |
9287086 | Brouk et al. | Mar 2016 | B2 |
9287092 | Brouk et al. | Mar 2016 | B2 |
9287098 | Finley | Mar 2016 | B2 |
9306533 | Mavretic | Apr 2016 | B1 |
9309594 | Hoffman et al. | Apr 2016 | B2 |
9313872 | Yamazawa et al. | Apr 2016 | B2 |
9355822 | Yamada et al. | May 2016 | B2 |
9362089 | Brouk et al. | Jun 2016 | B2 |
9373521 | Mochiki et al. | Jun 2016 | B2 |
9384992 | Narishige et al. | Jul 2016 | B2 |
9396960 | Ogawa et al. | Jul 2016 | B2 |
9404176 | Parkhe et al. | Aug 2016 | B2 |
9412613 | Manna et al. | Aug 2016 | B2 |
9435029 | Brouk et al. | Sep 2016 | B2 |
9483066 | Finley | Nov 2016 | B2 |
9490107 | Kim et al. | Nov 2016 | B2 |
9495563 | Ziemba et al. | Nov 2016 | B2 |
9496150 | Mochiki et al. | Nov 2016 | B2 |
9503006 | Pohl et al. | Nov 2016 | B2 |
9520269 | Finley et al. | Dec 2016 | B2 |
9530667 | Rastogi et al. | Dec 2016 | B2 |
9536713 | Van Zyl et al. | Jan 2017 | B2 |
9544987 | Mueller et al. | Jan 2017 | B2 |
9558917 | Finley et al. | Jan 2017 | B2 |
9564287 | Ohse et al. | Feb 2017 | B2 |
9570313 | Ranjan et al. | Feb 2017 | B2 |
9576810 | Deshmukh et al. | Feb 2017 | B2 |
9576816 | Rastogi et al. | Feb 2017 | B2 |
9577516 | Van Zyl | Feb 2017 | B1 |
9583357 | Long et al. | Feb 2017 | B1 |
9593421 | Baek et al. | Mar 2017 | B2 |
9601283 | Ziemba et al. | Mar 2017 | B2 |
9601319 | Bravo et al. | Mar 2017 | B1 |
9607843 | Rastogi et al. | Mar 2017 | B2 |
9620340 | Finley | Apr 2017 | B2 |
9620376 | Kamp et al. | Apr 2017 | B2 |
9620987 | Alexander et al. | Apr 2017 | B2 |
9637814 | Bugyi et al. | May 2017 | B2 |
9644221 | Kanamori et al. | May 2017 | B2 |
9651957 | Finley | May 2017 | B1 |
9655221 | Ziemba et al. | May 2017 | B2 |
9663858 | Nagami et al. | May 2017 | B2 |
9666446 | Tominaga et al. | May 2017 | B2 |
9666447 | Rastogi et al. | May 2017 | B2 |
9673027 | Yamamoto et al. | Jun 2017 | B2 |
9673059 | Raley et al. | Jun 2017 | B2 |
9685297 | Carter et al. | Jun 2017 | B2 |
9706630 | Miller et al. | Jul 2017 | B2 |
9711331 | Mueller et al. | Jul 2017 | B2 |
9711335 | Christie | Jul 2017 | B2 |
9728429 | Ricci et al. | Aug 2017 | B2 |
9734992 | Yamada et al. | Aug 2017 | B2 |
9741544 | Van Zyl | Aug 2017 | B2 |
9754768 | Yamada et al. | Sep 2017 | B2 |
9761419 | Nagami | Sep 2017 | B2 |
9761459 | Long et al. | Sep 2017 | B2 |
9767988 | Brouk et al. | Sep 2017 | B2 |
9786503 | Raley et al. | Oct 2017 | B2 |
9799494 | Chen et al. | Oct 2017 | B2 |
9805916 | Konno et al. | Oct 2017 | B2 |
9805965 | Sadjadi et al. | Oct 2017 | B2 |
9812305 | Pelleymounter | Nov 2017 | B2 |
9831064 | Konno et al. | Nov 2017 | B2 |
9837285 | Tomura et al. | Dec 2017 | B2 |
9840770 | Klimczak et al. | Dec 2017 | B2 |
9852889 | Kellogg et al. | Dec 2017 | B1 |
9852890 | Mueller et al. | Dec 2017 | B2 |
9865471 | Shimoda et al. | Jan 2018 | B2 |
9865893 | Esswein et al. | Jan 2018 | B2 |
9870898 | Urakawa et al. | Jan 2018 | B2 |
9872373 | Shimizu | Jan 2018 | B1 |
9881820 | Wong et al. | Jan 2018 | B2 |
9922802 | Hirano et al. | Mar 2018 | B2 |
9922806 | Tomura et al. | Mar 2018 | B2 |
9929004 | Ziemba et al. | Mar 2018 | B2 |
9941097 | Yamazawa et al. | Apr 2018 | B2 |
9941098 | Nagami | Apr 2018 | B2 |
9960763 | Miller et al. | May 2018 | B2 |
9972503 | Tomura et al. | May 2018 | B2 |
9997374 | Takeda et al. | Jun 2018 | B2 |
10020800 | Prager et al. | Jul 2018 | B2 |
10026593 | Alt et al. | Jul 2018 | B2 |
10027314 | Prager et al. | Jul 2018 | B2 |
10041174 | Matsumoto et al. | Aug 2018 | B2 |
10042407 | Grede et al. | Aug 2018 | B2 |
10063062 | Voronin et al. | Aug 2018 | B2 |
10074518 | Van Zyl | Sep 2018 | B2 |
10085796 | Podany | Oct 2018 | B2 |
10090191 | Tomura et al. | Oct 2018 | B2 |
10102321 | Povolny et al. | Oct 2018 | B2 |
10109461 | Yamada et al. | Oct 2018 | B2 |
10115567 | Hirano et al. | Oct 2018 | B2 |
10115568 | Kellogg et al. | Oct 2018 | B2 |
10176970 | Nitschke | Jan 2019 | B2 |
10176971 | Nagami | Jan 2019 | B2 |
10181392 | Leypold et al. | Jan 2019 | B2 |
10199246 | Koizumi et al. | Feb 2019 | B2 |
10217618 | Larson et al. | Feb 2019 | B2 |
10217933 | Nishimura et al. | Feb 2019 | B2 |
10224822 | Miller et al. | Mar 2019 | B2 |
10229819 | Hirano et al. | Mar 2019 | B2 |
10249498 | Ventzek et al. | Apr 2019 | B2 |
10268846 | Miller et al. | Apr 2019 | B2 |
10269540 | Carter et al. | Apr 2019 | B1 |
10276420 | Ito et al. | Apr 2019 | B2 |
10282567 | Miller et al. | May 2019 | B2 |
10283321 | Yang et al. | May 2019 | B2 |
10290506 | Ranjan et al. | May 2019 | B2 |
10297431 | Zelechowski et al. | May 2019 | B2 |
10304661 | Ziemba et al. | May 2019 | B2 |
10304668 | Coppa et al. | May 2019 | B2 |
10312048 | Dorf et al. | Jun 2019 | B2 |
10312056 | Collins et al. | Jun 2019 | B2 |
10320373 | Prager et al. | Jun 2019 | B2 |
10332730 | Christie | Jun 2019 | B2 |
10340123 | Ohtake | Jul 2019 | B2 |
10348186 | Schuler et al. | Jul 2019 | B2 |
10354839 | Alt et al. | Jul 2019 | B2 |
10373755 | Prager et al. | Aug 2019 | B2 |
10373804 | Koh et al. | Aug 2019 | B2 |
10373811 | Christie et al. | Aug 2019 | B2 |
10381237 | Takeda et al. | Aug 2019 | B2 |
10382022 | Prager et al. | Aug 2019 | B2 |
10387166 | Preston et al. | Aug 2019 | B2 |
10388544 | Ui et al. | Aug 2019 | B2 |
10389345 | Ziemba et al. | Aug 2019 | B2 |
10410877 | Takashima et al. | Sep 2019 | B2 |
10431437 | Gapi{right arrow over (n)}ski et al. | Oct 2019 | B2 |
10438797 | Cottle et al. | Oct 2019 | B2 |
10446453 | Coppa et al. | Oct 2019 | B2 |
10447174 | Porter, Jr. et al. | Oct 2019 | B1 |
10448494 | Dorf et al. | Oct 2019 | B1 |
10448495 | Dorf et al. | Oct 2019 | B1 |
10453656 | Carducci et al. | Oct 2019 | B2 |
10460910 | Ziemba et al. | Oct 2019 | B2 |
10460911 | Ziemba et al. | Oct 2019 | B2 |
10460916 | Boyd, Jr. et al. | Oct 2019 | B2 |
10483089 | Ziemba et al. | Nov 2019 | B2 |
10483100 | Ishizaka et al. | Nov 2019 | B2 |
10510575 | Kraus et al. | Dec 2019 | B2 |
10522343 | Tapily et al. | Dec 2019 | B2 |
10535502 | Carducci et al. | Jan 2020 | B2 |
10546728 | Carducci et al. | Jan 2020 | B2 |
10553407 | Nagami et al. | Feb 2020 | B2 |
10555412 | Dorf et al. | Feb 2020 | B2 |
10580620 | Carducci et al. | Mar 2020 | B2 |
10593519 | Yamada et al. | Mar 2020 | B2 |
10607813 | Fairbairn et al. | Mar 2020 | B2 |
10607814 | Ziemba et al. | Mar 2020 | B2 |
10658189 | Hatazaki et al. | May 2020 | B2 |
10659019 | Slobodov et al. | May 2020 | B2 |
10665434 | Matsumoto et al. | May 2020 | B2 |
10666198 | Prager et al. | May 2020 | B2 |
10672589 | Koshimizu et al. | Jun 2020 | B2 |
10672596 | Brcka | Jun 2020 | B2 |
10672616 | Kubota | Jun 2020 | B2 |
10685807 | Dorf et al. | Jun 2020 | B2 |
10707053 | Urakawa et al. | Jul 2020 | B2 |
10707054 | Kubota | Jul 2020 | B1 |
10707055 | Shaw et al. | Jul 2020 | B2 |
10707086 | Yang et al. | Jul 2020 | B2 |
10707090 | Takayama et al. | Jul 2020 | B2 |
10707864 | Miller et al. | Jul 2020 | B2 |
10714372 | Chua | Jul 2020 | B2 |
10720305 | Van Zyl | Jul 2020 | B2 |
10734906 | Miller et al. | Aug 2020 | B2 |
10748746 | Kaneko et al. | Aug 2020 | B2 |
10755894 | Hirano et al. | Aug 2020 | B2 |
10763150 | Lindley | Sep 2020 | B2 |
10773282 | Coppa et al. | Sep 2020 | B2 |
10774423 | Janakiraman et al. | Sep 2020 | B2 |
10777388 | Ziemba et al. | Sep 2020 | B2 |
10790816 | Ziemba et al. | Sep 2020 | B2 |
10791617 | Dorf et al. | Sep 2020 | B2 |
10796887 | Prager et al. | Oct 2020 | B2 |
10804886 | Miller et al. | Oct 2020 | B2 |
10811227 | Van Zyl et al. | Oct 2020 | B2 |
10811228 | Van Zyl et al. | Oct 2020 | B2 |
10811229 | Van Zyl et al. | Oct 2020 | B2 |
10811230 | Ziemba et al. | Oct 2020 | B2 |
10811296 | Cho et al. | Oct 2020 | B2 |
10847346 | Ziemba et al. | Nov 2020 | B2 |
10892140 | Ziemba et al. | Jan 2021 | B2 |
10892141 | Ziemba et al. | Jan 2021 | B2 |
10896807 | Fairbairn et al. | Jan 2021 | B2 |
10896809 | Ziemba et al. | Jan 2021 | B2 |
10903047 | Ziemba | Jan 2021 | B2 |
10904996 | Koh et al. | Jan 2021 | B2 |
10916408 | Dorf et al. | Feb 2021 | B2 |
10923320 | Koh et al. | Feb 2021 | B2 |
10923321 | Dorf et al. | Feb 2021 | B2 |
10923367 | Lubomirsky et al. | Feb 2021 | B2 |
10923379 | Liu et al. | Feb 2021 | B2 |
10971342 | Engelstaedter et al. | Apr 2021 | B2 |
10978274 | Kubota | Apr 2021 | B2 |
10978955 | Ziemba et al. | Apr 2021 | B2 |
10985740 | Prager et al. | Apr 2021 | B2 |
10991553 | Ziemba et al. | Apr 2021 | B2 |
10991554 | Zhao et al. | Apr 2021 | B2 |
10998169 | Ventzek et al. | May 2021 | B2 |
11004660 | Prager et al. | May 2021 | B2 |
11011349 | Brouk et al. | May 2021 | B2 |
11075058 | Ziemba et al. | Jul 2021 | B2 |
11095280 | Ziemba et al. | Aug 2021 | B2 |
11101108 | Slobodov et al. | Aug 2021 | B2 |
11108384 | Prager et al. | Aug 2021 | B2 |
11430635 | Ziemba | Aug 2022 | B2 |
20010003298 | Shamouilian et al. | Jun 2001 | A1 |
20010009139 | Shan et al. | Jul 2001 | A1 |
20010033755 | Ino et al. | Oct 2001 | A1 |
20020069971 | Kaji et al. | Jun 2002 | A1 |
20020078891 | Chu et al. | Jun 2002 | A1 |
20030026060 | Hiramatsu et al. | Feb 2003 | A1 |
20030029859 | Knoot et al. | Feb 2003 | A1 |
20030049558 | Aoki et al. | Mar 2003 | A1 |
20030052085 | Parsons | Mar 2003 | A1 |
20030079983 | Long et al. | May 2003 | A1 |
20030091355 | Jeschonek et al. | May 2003 | A1 |
20030137791 | Arnet et al. | Jul 2003 | A1 |
20030151372 | Tsuchiya et al. | Aug 2003 | A1 |
20030165044 | Yamamoto | Sep 2003 | A1 |
20030201069 | Johnson | Oct 2003 | A1 |
20040040665 | Mizuno et al. | Mar 2004 | A1 |
20040040931 | Koshiishi et al. | Mar 2004 | A1 |
20040066601 | Larsen | Apr 2004 | A1 |
20040112536 | Quon | Jun 2004 | A1 |
20040223284 | Iwami et al. | Nov 2004 | A1 |
20050022933 | Howard | Feb 2005 | A1 |
20050024809 | Kuchimachi | Feb 2005 | A1 |
20050039852 | Roche et al. | Feb 2005 | A1 |
20050092596 | Kouznetsov | May 2005 | A1 |
20050098118 | Amann et al. | May 2005 | A1 |
20050151544 | Mahoney et al. | Jul 2005 | A1 |
20050152159 | Isurin et al. | Jul 2005 | A1 |
20050286916 | Nakazato et al. | Dec 2005 | A1 |
20060075969 | Fischer | Apr 2006 | A1 |
20060130767 | Herchen | Jun 2006 | A1 |
20060139843 | Kim | Jun 2006 | A1 |
20060158823 | Mizuno et al. | Jul 2006 | A1 |
20060171848 | Roche et al. | Aug 2006 | A1 |
20060219178 | Asakura | Oct 2006 | A1 |
20060278521 | Stowell | Dec 2006 | A1 |
20070113787 | Higashiura et al. | May 2007 | A1 |
20070114981 | Vasquez et al. | May 2007 | A1 |
20070196977 | Wang et al. | Aug 2007 | A1 |
20070284344 | Todorov et al. | Dec 2007 | A1 |
20070285869 | Howald | Dec 2007 | A1 |
20070297118 | Fujii | Dec 2007 | A1 |
20080012548 | Gerhardt et al. | Jan 2008 | A1 |
20080037196 | Yonekura et al. | Feb 2008 | A1 |
20080048498 | Wiedemuth et al. | Feb 2008 | A1 |
20080106842 | Ito et al. | May 2008 | A1 |
20080135401 | Kadlec et al. | Jun 2008 | A1 |
20080160212 | Koo et al. | Jul 2008 | A1 |
20080185537 | Walther et al. | Aug 2008 | A1 |
20080210545 | Kouznetsov | Sep 2008 | A1 |
20080236493 | Sakao | Oct 2008 | A1 |
20080252225 | Kurachi et al. | Oct 2008 | A1 |
20080272706 | Kwon et al. | Nov 2008 | A1 |
20080289576 | Lee et al. | Nov 2008 | A1 |
20090016549 | French et al. | Jan 2009 | A1 |
20090059462 | Mizuno et al. | Mar 2009 | A1 |
20090078678 | Kojima et al. | Mar 2009 | A1 |
20090133839 | Yamazawa et al. | May 2009 | A1 |
20090236214 | Janakiraman et al. | Sep 2009 | A1 |
20090295295 | Shannon et al. | Dec 2009 | A1 |
20100018648 | Collins et al. | Jan 2010 | A1 |
20100025230 | Ehiasarian et al. | Feb 2010 | A1 |
20100029038 | Murakawa | Feb 2010 | A1 |
20100072172 | Ui et al. | Mar 2010 | A1 |
20100101935 | Chistyakov et al. | Apr 2010 | A1 |
20100118464 | Matsuyama | May 2010 | A1 |
20100154994 | Fischer et al. | Jun 2010 | A1 |
20100193491 | Cho et al. | Aug 2010 | A1 |
20100271744 | Ni et al. | Oct 2010 | A1 |
20100276273 | Heckman et al. | Nov 2010 | A1 |
20100321047 | Zollner et al. | Dec 2010 | A1 |
20100326957 | Maeda et al. | Dec 2010 | A1 |
20110096461 | Yoshikawa et al. | Apr 2011 | A1 |
20110100807 | Matsubara et al. | May 2011 | A1 |
20110143537 | Lee et al. | Jun 2011 | A1 |
20110157760 | Willwerth et al. | Jun 2011 | A1 |
20110177669 | Lee et al. | Jul 2011 | A1 |
20110177694 | Chen et al. | Jul 2011 | A1 |
20110259851 | Brouk et al. | Oct 2011 | A1 |
20110281438 | Lee et al. | Nov 2011 | A1 |
20110298376 | Kanegae et al. | Dec 2011 | A1 |
20120000421 | Miller et al. | Jan 2012 | A1 |
20120052599 | Brouk et al. | Mar 2012 | A1 |
20120081350 | Sano et al. | Apr 2012 | A1 |
20120088371 | Ranjan et al. | Apr 2012 | A1 |
20120097908 | Willwerth et al. | Apr 2012 | A1 |
20120171390 | Nauman et al. | Jul 2012 | A1 |
20120319584 | Brouk et al. | Dec 2012 | A1 |
20130059448 | Marakhtanov et al. | Mar 2013 | A1 |
20130087447 | Bodke et al. | Apr 2013 | A1 |
20130175575 | Ziemba et al. | Jul 2013 | A1 |
20130213935 | Liao et al. | Aug 2013 | A1 |
20130214828 | Valcore, Jr. et al. | Aug 2013 | A1 |
20130340938 | Tappan et al. | Dec 2013 | A1 |
20130344702 | Nishizuka | Dec 2013 | A1 |
20140057447 | Yang et al. | Feb 2014 | A1 |
20140061156 | Brouk et al. | Mar 2014 | A1 |
20140062495 | Carter et al. | Mar 2014 | A1 |
20140077611 | Young et al. | Mar 2014 | A1 |
20140109886 | Singleton et al. | Apr 2014 | A1 |
20140117861 | Finley et al. | May 2014 | A1 |
20140125315 | Kirchmeier et al. | May 2014 | A1 |
20140154819 | Gaff et al. | Jun 2014 | A1 |
20140177123 | Thach et al. | Jun 2014 | A1 |
20140238844 | Chistyakov | Aug 2014 | A1 |
20140262755 | Deshmukh et al. | Sep 2014 | A1 |
20140263182 | Chen et al. | Sep 2014 | A1 |
20140273487 | Deshmukh et al. | Sep 2014 | A1 |
20140305905 | Yamada et al. | Oct 2014 | A1 |
20140356984 | Ventzek et al. | Dec 2014 | A1 |
20140361690 | Yamada et al. | Dec 2014 | A1 |
20150002018 | Lill et al. | Jan 2015 | A1 |
20150043123 | Cox | Feb 2015 | A1 |
20150076112 | Sriraman et al. | Mar 2015 | A1 |
20150084509 | Yuzurihara et al. | Mar 2015 | A1 |
20150111394 | Hsu et al. | Apr 2015 | A1 |
20150116889 | Yamasaki et al. | Apr 2015 | A1 |
20150130354 | Leray et al. | May 2015 | A1 |
20150130525 | Miller et al. | May 2015 | A1 |
20150170952 | Subramani et al. | Jun 2015 | A1 |
20150181683 | Singh et al. | Jun 2015 | A1 |
20150235809 | Ito et al. | Aug 2015 | A1 |
20150256086 | Miller et al. | Sep 2015 | A1 |
20150303914 | Ziemba et al. | Oct 2015 | A1 |
20150315698 | Chistyakov | Nov 2015 | A1 |
20150318846 | Prager et al. | Nov 2015 | A1 |
20150325413 | Kim et al. | Nov 2015 | A1 |
20150366004 | Nangoy et al. | Dec 2015 | A1 |
20160004475 | Beniyama et al. | Jan 2016 | A1 |
20160020072 | Brouk et al. | Jan 2016 | A1 |
20160027678 | Parkhe et al. | Jan 2016 | A1 |
20160056017 | Kim et al. | Feb 2016 | A1 |
20160064189 | Tandou et al. | Mar 2016 | A1 |
20160196958 | Leray et al. | Jul 2016 | A1 |
20160241234 | Mavretic | Aug 2016 | A1 |
20160284514 | Hirano et al. | Sep 2016 | A1 |
20160314946 | Pelleymounter | Oct 2016 | A1 |
20160322242 | Nguyen et al. | Nov 2016 | A1 |
20160327029 | Ziemba et al. | Nov 2016 | A1 |
20160351375 | Valcore, Jr. et al. | Dec 2016 | A1 |
20160358755 | Long et al. | Dec 2016 | A1 |
20170011887 | Deshmukh et al. | Jan 2017 | A1 |
20170018411 | Sriraman et al. | Jan 2017 | A1 |
20170022604 | Christie et al. | Jan 2017 | A1 |
20170029937 | Chistyakov et al. | Feb 2017 | A1 |
20170069462 | Kanarik et al. | Mar 2017 | A1 |
20170076962 | Engelhardt | Mar 2017 | A1 |
20170098527 | Kawasaki et al. | Apr 2017 | A1 |
20170098549 | Agarwal | Apr 2017 | A1 |
20170110335 | Yang et al. | Apr 2017 | A1 |
20170110358 | Sadjadi et al. | Apr 2017 | A1 |
20170113355 | Genetti et al. | Apr 2017 | A1 |
20170115657 | Trussell et al. | Apr 2017 | A1 |
20170117172 | Genetti et al. | Apr 2017 | A1 |
20170154726 | Prager et al. | Jun 2017 | A1 |
20170162417 | Ye et al. | Jun 2017 | A1 |
20170163254 | Ziemba et al. | Jun 2017 | A1 |
20170169996 | Ui et al. | Jun 2017 | A1 |
20170170449 | Alexander et al. | Jun 2017 | A1 |
20170178917 | Kamp et al. | Jun 2017 | A1 |
20170221682 | Nishimura et al. | Aug 2017 | A1 |
20170236688 | Caron et al. | Aug 2017 | A1 |
20170236741 | Angelov et al. | Aug 2017 | A1 |
20170236743 | Severson et al. | Aug 2017 | A1 |
20170243731 | Ziemba et al. | Aug 2017 | A1 |
20170250056 | Boswell et al. | Aug 2017 | A1 |
20170263478 | McChesney et al. | Sep 2017 | A1 |
20170278665 | Carter et al. | Sep 2017 | A1 |
20170287791 | Coppa et al. | Oct 2017 | A1 |
20170311431 | Park | Oct 2017 | A1 |
20170316935 | Tan et al. | Nov 2017 | A1 |
20170330734 | Lee et al. | Nov 2017 | A1 |
20170330786 | Genetti et al. | Nov 2017 | A1 |
20170334074 | Genetti et al. | Nov 2017 | A1 |
20170358431 | Dorf et al. | Dec 2017 | A1 |
20170366173 | Miller et al. | Dec 2017 | A1 |
20170372912 | Long et al. | Dec 2017 | A1 |
20180019100 | Brouk et al. | Jan 2018 | A1 |
20180076032 | Wang et al. | Mar 2018 | A1 |
20180102769 | Prager et al. | Apr 2018 | A1 |
20180139834 | Nagashima et al. | May 2018 | A1 |
20180166249 | Dorf et al. | Jun 2018 | A1 |
20180189524 | Miller et al. | Jul 2018 | A1 |
20180190501 | Ueda | Jul 2018 | A1 |
20180204708 | Tan et al. | Jul 2018 | A1 |
20180205369 | Prager et al. | Jul 2018 | A1 |
20180218905 | Park et al. | Aug 2018 | A1 |
20180226225 | Koh et al. | Aug 2018 | A1 |
20180226896 | Miller et al. | Aug 2018 | A1 |
20180253570 | Miller et al. | Sep 2018 | A1 |
20180286636 | Ziemba et al. | Oct 2018 | A1 |
20180294566 | Wang et al. | Oct 2018 | A1 |
20180309423 | Okunishi et al. | Oct 2018 | A1 |
20180331655 | Prager et al. | Nov 2018 | A1 |
20180350649 | Gomm | Dec 2018 | A1 |
20180366305 | Nagami et al. | Dec 2018 | A1 |
20180374672 | Hayashi et al. | Dec 2018 | A1 |
20190027344 | Okunishi et al. | Jan 2019 | A1 |
20190080884 | Ziemba et al. | Mar 2019 | A1 |
20190090338 | Koh et al. | Mar 2019 | A1 |
20190096633 | Pankratz et al. | Mar 2019 | A1 |
20190157041 | Zyl et al. | May 2019 | A1 |
20190157042 | Van Zyl et al. | May 2019 | A1 |
20190157044 | Ziemba et al. | May 2019 | A1 |
20190172685 | Van Zyl et al. | Jun 2019 | A1 |
20190172688 | Ueda | Jun 2019 | A1 |
20190180982 | Brouk et al. | Jun 2019 | A1 |
20190198333 | Tokashiki | Jun 2019 | A1 |
20190259562 | Dorf et al. | Aug 2019 | A1 |
20190267218 | Wang et al. | Aug 2019 | A1 |
20190277804 | Prager et al. | Sep 2019 | A1 |
20190295769 | Prager et al. | Sep 2019 | A1 |
20190295819 | Okunishi et al. | Sep 2019 | A1 |
20190318918 | Saitoh et al. | Oct 2019 | A1 |
20190333741 | Nagami et al. | Oct 2019 | A1 |
20190341232 | Thokachichu et al. | Nov 2019 | A1 |
20190348258 | Koh et al. | Nov 2019 | A1 |
20190348263 | Okunishi | Nov 2019 | A1 |
20190363388 | Esswein et al. | Nov 2019 | A1 |
20190385822 | Marakhtanov et al. | Dec 2019 | A1 |
20190393791 | Ziemba et al. | Dec 2019 | A1 |
20200016109 | Feng et al. | Jan 2020 | A1 |
20200020510 | Shoeb et al. | Jan 2020 | A1 |
20200024330 | Chan-Hui et al. | Jan 2020 | A1 |
20200035457 | Ziemba et al. | Jan 2020 | A1 |
20200035458 | Ziemba et al. | Jan 2020 | A1 |
20200035459 | Ziemba et al. | Jan 2020 | A1 |
20200036367 | Slobodov et al. | Jan 2020 | A1 |
20200037468 | Ziemba et al. | Jan 2020 | A1 |
20200051785 | Miller et al. | Feb 2020 | A1 |
20200051786 | Ziemba et al. | Feb 2020 | A1 |
20200058475 | Engelstaedter et al. | Feb 2020 | A1 |
20200066497 | Engelstaedter et al. | Feb 2020 | A1 |
20200066498 | Engelstaedter et al. | Feb 2020 | A1 |
20200075293 | Ventzek et al. | Mar 2020 | A1 |
20200090905 | Brouk et al. | Mar 2020 | A1 |
20200106137 | Murphy et al. | Apr 2020 | A1 |
20200126760 | Ziemba et al. | Apr 2020 | A1 |
20200126837 | Kuno et al. | Apr 2020 | A1 |
20200144030 | Prager et al. | May 2020 | A1 |
20200161091 | Ziemba et al. | May 2020 | A1 |
20200161098 | Cui et al. | May 2020 | A1 |
20200161155 | Rogers et al. | May 2020 | A1 |
20200162061 | Prager et al. | May 2020 | A1 |
20200168436 | Ziemba et al. | May 2020 | A1 |
20200168437 | Ziemba et al. | May 2020 | A1 |
20200176221 | Prager et al. | Jun 2020 | A1 |
20200227230 | Ziemba et al. | Jul 2020 | A1 |
20200227289 | Song et al. | Jul 2020 | A1 |
20200234921 | Dorf et al. | Jul 2020 | A1 |
20200234922 | Dorf et al. | Jul 2020 | A1 |
20200234923 | Dorf et al. | Jul 2020 | A1 |
20200243303 | Mishra et al. | Jul 2020 | A1 |
20200251371 | Kuno et al. | Aug 2020 | A1 |
20200266022 | Dorf et al. | Aug 2020 | A1 |
20200266035 | Nagaiwa | Aug 2020 | A1 |
20200294770 | Kubota | Sep 2020 | A1 |
20200328739 | Miller et al. | Oct 2020 | A1 |
20200352017 | Dorf et al. | Nov 2020 | A1 |
20200357607 | Ziemba et al. | Nov 2020 | A1 |
20200373114 | Prager et al. | Nov 2020 | A1 |
20200389126 | Prager et al. | Dec 2020 | A1 |
20200407840 | Hayashi et al. | Dec 2020 | A1 |
20200411286 | Koshimizu et al. | Dec 2020 | A1 |
20210005428 | Shaw et al. | Jan 2021 | A1 |
20210013006 | Nguyen et al. | Jan 2021 | A1 |
20210013011 | Prager et al. | Jan 2021 | A1 |
20210013874 | Miller et al. | Jan 2021 | A1 |
20210027990 | Ziemba et al. | Jan 2021 | A1 |
20210029815 | Bowman et al. | Jan 2021 | A1 |
20210043472 | Koshimizu et al. | Feb 2021 | A1 |
20210051792 | Dokan et al. | Feb 2021 | A1 |
20210066042 | Ziemba et al. | Mar 2021 | A1 |
20210082669 | Koshiishi et al. | Mar 2021 | A1 |
20210091759 | Prager et al. | Mar 2021 | A1 |
20210125812 | Ziemba et al. | Apr 2021 | A1 |
20210130955 | Nagaike et al. | May 2021 | A1 |
20210140044 | Nagaike et al. | May 2021 | A1 |
20210151295 | Ziemba et al. | May 2021 | A1 |
20210152163 | Miller et al. | May 2021 | A1 |
20210210313 | Ziemba et al. | Jul 2021 | A1 |
20210210315 | Ziemba et al. | Jul 2021 | A1 |
20210249227 | Bowman et al. | Aug 2021 | A1 |
20210272775 | Koshimizu | Sep 2021 | A1 |
20210288582 | Ziemba et al. | Sep 2021 | A1 |
20220157561 | Cui | May 2022 | A1 |
20220157577 | Cui | May 2022 | A1 |
Number | Date | Country |
---|---|---|
101990353 | Mar 2011 | CN |
102084024 | Jun 2011 | CN |
101707186 | Feb 2012 | CN |
105408993 | Mar 2016 | CN |
106206234 | Dec 2016 | CN |
104752134 | Feb 2017 | CN |
665306 | Aug 1995 | EP |
983394 | Mar 2000 | EP |
1119033 | Jul 2001 | EP |
1203441 | May 2002 | EP |
1214459 | Jun 2002 | EP |
1418670 | May 2004 | EP |
1691481 | Aug 2006 | EP |
1701376 | Sep 2006 | EP |
1708239 | Oct 2006 | EP |
1780777 | May 2007 | EP |
1852959 | Nov 2007 | EP |
2096679 | Sep 2009 | EP |
2221614 | Aug 2010 | EP |
2407998 | Jan 2012 | EP |
2541584 | Jan 2013 | EP |
2580368 | Apr 2013 | EP |
2612544 | Jul 2013 | EP |
2838112 | Feb 2015 | EP |
2991103 | Mar 2016 | EP |
3086359 | Oct 2016 | EP |
3396700 | Oct 2018 | EP |
3616234 | Mar 2020 | EP |
H08236602 | Sep 1996 | JP |
2748213 | May 1998 | JP |
H11025894 | Jan 1999 | JP |
2002-313899 | Oct 2002 | JP |
2002299322 | Oct 2002 | JP |
4418424 | Feb 2010 | JP |
2011035266 | Feb 2011 | JP |
5018244 | Sep 2012 | JP |
2014112644 | Jun 2014 | JP |
2016-225439 | Dec 2016 | JP |
6741461 | Aug 2020 | JP |
100757347 | Sep 2007 | KR |
10-2007-0098556 | Oct 2007 | KR |
20160042429 | Apr 2016 | KR |
20200036947 | Apr 2020 | KR |
498706 | Aug 2002 | TW |
201312622 | Mar 2013 | TW |
201717247 | May 2017 | TW |
201801224 | Jan 2018 | TW |
201916091 | Apr 2019 | TW |
201933422 | Aug 2019 | TW |
201935511 | Sep 2019 | TW |
1998053116 | Nov 1998 | WO |
2000017920 | Mar 2000 | WO |
2000030147 | May 2000 | WO |
2000063459 | Oct 2000 | WO |
2001005020 | Jan 2001 | WO |
2001012873 | Feb 2001 | WO |
2001013402 | Feb 2001 | WO |
2002052628 | Jul 2002 | WO |
2002054835 | Jul 2002 | WO |
2002059954 | Aug 2002 | WO |
2003037497 | May 2003 | WO |
2003052882 | Jun 2003 | WO |
2003054911 | Jul 2003 | WO |
2003077414 | Sep 2003 | WO |
2004084394 | Sep 2004 | WO |
2005124844 | Dec 2005 | WO |
2007118042 | Oct 2007 | WO |
2008016747 | Feb 2008 | WO |
2008050619 | May 2008 | WO |
2008061775 | May 2008 | WO |
2008061784 | May 2008 | WO |
2008062663 | May 2008 | WO |
2009012804 | Jan 2009 | WO |
2009069670 | Jun 2009 | WO |
2009111473 | Sep 2009 | WO |
2011073093 | Jun 2011 | WO |
2011087984 | Jul 2011 | WO |
2011156055 | Dec 2011 | WO |
2012030500 | Mar 2012 | WO |
2012109159 | Aug 2012 | WO |
2012122064 | Sep 2012 | WO |
2013000918 | Jan 2013 | WO |
2013016619 | Jan 2013 | WO |
2013084459 | Jun 2013 | WO |
2013088677 | Jun 2013 | WO |
2013099133 | Jul 2013 | WO |
2013114882 | Aug 2013 | WO |
2013118660 | Aug 2013 | WO |
2013125523 | Aug 2013 | WO |
2013187218 | Dec 2013 | WO |
2014035889 | Mar 2014 | WO |
2014035894 | Mar 2014 | WO |
2014035897 | Mar 2014 | WO |
2014036000 | Mar 2014 | WO |
2014124857 | Aug 2014 | WO |
2014197145 | Dec 2014 | WO |
2015060185 | Apr 2015 | WO |
2014124857 | May 2015 | WO |
2015134398 | Sep 2015 | WO |
2015198854 | Dec 2015 | WO |
2016002547 | Jan 2016 | WO |
2016059207 | Apr 2016 | WO |
2016060058 | Apr 2016 | WO |
2016060063 | Apr 2016 | WO |
2015073921 | May 2016 | WO |
2016104098 | Jun 2016 | WO |
2016128384 | Aug 2016 | WO |
2016131061 | Aug 2016 | WO |
2016170989 | Oct 2016 | WO |
2017172536 | Oct 2017 | WO |
2017208807 | Dec 2017 | WO |
2018048925 | Mar 2018 | WO |
2018111751 | Jun 2018 | WO |
2018170010 | Sep 2018 | WO |
2018197702 | Nov 2018 | WO |
2019036587 | Feb 2019 | WO |
2019040949 | Feb 2019 | WO |
2019099102 | May 2019 | WO |
2019099870 | May 2019 | WO |
2019185423 | Oct 2019 | WO |
2019225184 | Nov 2019 | WO |
2019239872 | Dec 2019 | WO |
2019244697 | Dec 2019 | WO |
2019244698 | Dec 2019 | WO |
2019244734 | Dec 2019 | WO |
2019245729 | Dec 2019 | WO |
2020004048 | Jan 2020 | WO |
2020017328 | Jan 2020 | WO |
2020022318 | Jan 2020 | WO |
2020022319 | Jan 2020 | WO |
2020026802 | Feb 2020 | WO |
2020036806 | Feb 2020 | WO |
2020037331 | Feb 2020 | WO |
2020046561 | Mar 2020 | WO |
2020051064 | Mar 2020 | WO |
2020112921 | Jun 2020 | WO |
2020121819 | Jun 2020 | WO |
2020145051 | Jul 2020 | WO |
2021003319 | Jan 2021 | WO |
2021062223 | Apr 2021 | WO |
2021097459 | May 2021 | WO |
2021134000 | Jul 2021 | WO |
Entry |
---|
PCT International Search Report and Written Opinion dated Nov. 9, 2018, for International Application No. PCT/US2018/043032. |
Taiwan Office Action for Application No. 107125613 dated Dec. 24, 2020, 16 pages. |
PCT International Search Report and Written Opinion dated Nov. 7, 2018, for International Application No. PCT/US2018/042965. |
International Search Report and Written Opinion for PCT/US2019/052067 dated Jan. 21, 2020. |
Electrical 4 U webpage—“Clamping Circuit,” Aug. 29, 2018, 9 pages. |
Kyung Chae Yang et al., A study on the etching characteristics of magnetic tunneling junction materials using DC pulse-biased inductively coupled plasmas, Japanese Journal of Applied Physics, vol. 54, 01AE01, Oct. 29, 2014, 6 pages. |
PCT Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority for International Application No. PCT/US2019/048392; dated Dec. 16, 2019; 13 pages. |
PCT International Search Report and Written Opinion dated Nov. 7, 2018, for International Application No. PCT/US2018/042961. |
PCT International Search Report and Written Opinion dated Nov. 7, 2018, for International Application No. PCT/US2018/042956. |
U.S. Appl. No. 62/433,204; entitled Creating Arbitrarily-Shaped Ion Energy Distribution Function (IEDF) Using Shaped-Pulse (EV) Bias; by Leonid Dorf, etal.; filed Dec. 16, 2016; 22 total pages. |
U.S. Appl. No. 15/424,405; entitled System for Tunable Workpiece Biasing in a Plasma Reactor; by Travis Koh, et al.; filed Feb. 3, 2017; 29 total pages. |
U.S. Appl. No. 15/618,082; entitled Systems and Methods for Controlling a Voltage Waveform at a Substrate During Plasma Processing; by Leonid Dorf, et al.; filed Jun. 8, 2017; 35 total pages. |
PCT Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority for International Application No. PCT/US2018/046171; dated Nov. 28, 2018; 10 total pages. |
PCT Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority for International Application No. PCT/US2018/046182; dated Nov. 30, 2018; 10 total pages. |
Eagle Harbor Technologies presentation by Dr. Kenneth E. Miller—“The EHT Long Pulse Integrator Program,” ITPA Diagnostic Meeting, General Atomics, Jun. 4-7, 2013, 18 pages. |
Lin, Jianliang, et al.,—“Diamond like carbon films deposited by HiPIMS using oscillatory voltage pulses,” Surface & Coatings Technology 258, 2014, published by Elsevier B.V., pp. 1212-1222. |
PCT/US2020/014453 Interanational Search Report and Written Opinion dated May 14, 2020 consists of 8 pages. |
S.B. Wang et al. “lon Bombardment Energy and SiO 2/Si Fluorocarbon Plasma Etch Selectivity”, Journal of Vacuum Science & Technology A 19, 2425 (2001). |
Korean Office Action for 10-2020-7007495 dated Jun. 14, 2021. |
Zhen-hua Bi et al., A brief review of dual-frequency capacitively coupled discharges, Current Applied Physics, vol. 11, Issue 5, Supplement, 2011, pp. S2-S8. |
Chang, Bingdong, “Oblique angled plasma etching for 3D silicon structures with wiggling geometries” 31(8), [085301]. https://doi.org/10.1088/1361-6528/ab53fb. DTU Library. 2019. |
Michael A. Lieberman, “A short course of the principles of plasma discharges and materials processing”, Department of Electrical Engineering and Computer Sciences University of California, Berkeley, CA 94720. |
Dr. Steve Sirard, “Introduction to Plasma Etching”, Lam Research Corporation. 64 pages. |
Zhuoxing Luo, B.S., M.S, “RF Plasma Etching With a DC Bias” A Dissertation in Physics. Dec. 1994. |
Michael A. Lieberman, “Principles of Plasma Discharges and Material Processing”, A Wiley Interscience Publication. 1994. |
Yiting Zhang et al. “Investigation of feature orientation and consequences of ion tilting during plasma etching with a three-dimensional feature profile simulator”, Nov. 22, 2016. |
Richard Barnett et al. A New Plasma Source for Next Generation MEMS Deep Si Etching: Minimal Tilt, Improved Profile Uniformity and Higher Etch Rates, SPP Process Technology Systems. 2010. |
The International Search Report and the Written Opinion for International Application No. PCT/US2021/040380; dated Oct. 27, 2021; 10 pages. |
United States Patent Application, U.S. Appl. No. 17/346, 103, filed Jun. 11, 2021. |
United States Patent Application, U.S. Appl. No. 17/349,763, filed Jun. 16, 2021. |
United States Patent Application, U.S. Appl. No. 63/242,410, filed Sep. 9, 2021. |
United States Patent Application, U.S. Appl. No. 17/410,803, filed Aug. 24, 2021. |
United States Patent Application, U.S. Appl. No. 17/537,107, filed Nov. 29, 2021. |
United States Patent Application, U.S. Appl. No. 17/352,165, filed Jun. 18, 2021. |
United States Patent Application, U.S. Appl. No. 17/352,176, filed Jun. 18, 2021. |
United States Patent Application, U.S. Appl. No. 17/337,146, filed Jun. 2, 2021. |
United States Patent Application, U.S. Appl. No. 17/361,178, filed Jun. 28, 2021. |
United States Patent Application, U.S. Appl. No. 63/210,956, filed Jun. 15, 2021. |
United States Patent Application, U.S. Appl. No. 17/475,223, filed Sep. 14, 2021. |
United States Patent Application, U.S. Appl. No. 17/537,314, filed Nov. 29, 2021. |
Chinese Office Action for 201880053380.1 dated Dec. 2, 2021. |
Taiwan Office Action for 108132682 dated Mar. 24, 2022. |
International Search Report and Written Opinion dated Feb. 4, 2022 for Application No. PCT/US2021/054806. |
International Search Report and Written Opinion dated Feb. 4, 2022 for Application No. PCT/US2021/054814. |
Wang, S.B., et al.—“Control of ion energy distribution at substrates during plasma processing, ” Journal of Applied Physics, vol. 88, No. 2, Jul. 15, 2000, pp. 643-646. |
Eagle Harbor Technologies presentation by Dr. Kenneth E. Miller—“The EHT Integrated Power Module (IPM): An IGBT-Based, High Current, Ultra-Fast, Modular, Programmable Power Supply Unit,” Jun. 2013, 21 pages. |
Eagle Harbor Technologies presentation by Dr. Kenneth E. Miller—“The EHT Long Pulse Integrator Program, TPA Diagnostic Meeting, General Atomics,” Jun. 4-7, 2013, 18 pages. |
Eagle Harbor Technologies webpage—“In Situ Testing of EHT Integrators on a Tokamak,” 2015, 1 page. |
Eagle Harbor Technologies webpage—High Gain and Frequency Ultra-Stable Integrators for Long Pulse and/or High Current Applications, 2018, 1 page. |
Eagle Harbor Technologies webpage—“EHT Integrator Demonstration at DIII-D,” 2015, 1 page. |
Eagle Harbor Technologies webpage—“High Gain and Frequency Ultra-Stable Integrators for ICC and Long Pulse ITER Applications,” 2012, 1 page. |
Eagle Harbor Technologies webpage—“Long-Pulse Integrator Testing with DIII-D Magnetic Diagnostics,” 2016, 1 page. |
Sunstone Circuits—“Eagle Harbor Tech Case Study,” date unknown, 4 pages. |
Prager, J.R., et al.—“A High Voltage Nanosecond Pulser with Variable Pulse Width and Pulse Repetition Frequency Control for Nonequilibrium Plasma Applications,” IEEE 41st International Conference on Plasma Sciences (ICOPS) held with 2014 IEEE International Conference on High-Power Particle Beams (BEAMS), pp. 1-6, 2014. |
Kamada, Keiichi, et al., Editors—“New Developments of Plasma Science with Pulsed Power Technology,” Research Report, NIFS-PROC-82, presented at National Institute for Fusion Science, Toki, Gifu, Japan, Mar. 5-6, 2009, 109 pages. |
Prager, J.R et al., A High Voltage Nanosecond Pulser With Variable Pulse Width and Pulse Repetition Frequency Control for Nonequilibrium Plasma Applications, IEEE 2014, 6 pages. |
Semiconductor Components Industries, LLC (SCILLC)—“Switch-Mode Power Supply” Reference Manual, SMPSRM/D, Rev. 4, Apr. 2014, ON Semiconductor, 73 pages. |
Taiwan Office Action dated Aug. 23, 2023 for Application No. 110140739. |
Taiwanese Patent Application No. 110140681 Office Action dated Nov. 21, 2023. |
Number | Date | Country | |
---|---|---|---|
20220157561 A1 | May 2022 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 17099342 | Nov 2020 | US |
Child | 17159133 | US |