The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and, together with a general description of the invention given above and the detailed description of the embodiments given below, serve to explain the principles of the invention.
With reference to
A substrate chuck or fixture 24 supports the pallet 22 and the substrates 20 carried on the pallet 22 in the processing space 15 inside the vacuum vessel 12. The substrate fixture 24 is mounted to a tubular access column 26 extending through a sealed opening 28 in an end region 29 of the chamber wall 13. An upper end of the access column 26 has a sealed engagement with the substrate fixture 24. The access column 26 encloses a lumen through which electrical and fluid utilities are routed to the substrate fixture 24.
The substrate fixture 24 is biased by biasing elements having the form of compression springs 30 that are compressed between the substrate fixture 24 and a support plate 32 inside the processing space 15. The support plate 32 is mounted to the access column 26. The compression springs 30 exert a force biasing the substrate fixture 24 in a direction away from the end region 29 of the chamber wall 13. Each of a plurality of actuators (not shown), which may comprise bi-directional pneumatic cylinders, includes a piston moving a rod 34 mechanically coupled with the substrate fixture 24. Motion of the rods 34 moves the substrate fixture 24 relative to the pallet 22 and against the biasing force of the compression springs 30 to provide a clearance between the pallet 22 and substrate fixture 24. A transfer mechanism (not shown) is inserted into the clearance between the pallet 22 and substrate fixture 24 to lift or otherwise remove the pallet 22 during exchanges of processed and unprocessed substrates 20.
The substrate fixture 24 is located inside the inner perimeter of a frame 36. Spanning between the frame 36 and support plate 32 are stanchions 38 that space the support frame 36 from support plate 32. Frame 36 includes stationary lift arms (not shown) disposed at the notched or scalloped corners of the substrate fixture 24, which are best visible in
With reference to
A lower surface or side 56 of the cap plate 42, which is disposed opposite to upper side 52, includes a grid of ribs comprising a plurality of narrow spacers or ribs 58 and a thin spacer or rib 60 having a discontinuity near the center of cap plate 42. Ribs 58 are arranged in a plurality of rows and a thin rib 60 is arranged to bisect the rows of ribs 58. Projecting from the lower side 56 of cap plate 42 is a rim 64 that extends about the periphery of the cap plate 42 and encircles a recess 65. The ribs 58, 60 lend structural support to the cap plate 42.
Posts 66 project from the upper side 50 of the heat exchange plate 44 toward the lower side 56 of cap plate 42. The ribs 58, 60 and posts 66 cooperate with rim 64 to define a grid of partitions that compartmentalize recess 65 into a plurality of, for example, sixteen individual compartments 68. Each of the individual compartments 68 is dimensioned to receive a corresponding one of a plurality of thermoelectric devices 70 (
The upper side 52 of the cap plate 42 is generally planar so that the heat transfer gas space 54 (
A lower surface or side 81 of the heat exchange plate 44, which is disposed opposite to upper side 50, includes a central liquid region 82, a peripheral liquid region 84 near the perimeter of the heat exchange plate 44, a liquid channel 86 coupling the liquid regions 82, 84, and a rim 85 that circumscribes the liquid regions 82, 84 and liquid channel 86. The liquid channel 86 is defined by a thin-walled partition 88 carried by the lower side 81 of heat exchange plate 44. The partition 88 contacts the base plate 40 so that the liquid channel 86 is partially closed by an upper surface or side 99 of the base plate 40. An O-ring 90 (
A liquid passageway 94 in the base plate 40 couples a liquid inlet 96, which is defined by a fitting, with a liquid outlet 98. The liquid outlet 98 emerges from the upper side 99 of the base plate 40 to communicate with the peripheral liquid region 84 of the heat exchange plate 44. Liquid channel 86 winds helically about the central liquid region 82 for directing a coolant or thermally conductive liquid 95 of a pre-selected temperature between the base plate 40 and the heat exchange plate 44. The liquid inlet 96 is coupled by a conduit 101 with an external coolant source 100. Another liquid passageway (not shown) in the base plate 40 communicates with the peripheral liquid region 84 and is coupled by a drain passage 102 with a conduit 103 extending to a coolant drain 104. The coolant drain 104 either disposes of the elevated-temperature thermally liquid 95 heated by flow through liquid channel 86 or cools the elevated-temperature thermally liquid 95 for recirculation. Alternatively, the thermally conductive liquid 95 may be circulated in the opposite direction from the central liquid region 82 to the peripheral liquid region 84. The thermally conductive liquid 95 flowing through the liquid channel 86 may be chilled pure water at 5° C. to 10° C. supplied from a chiller unit integrated into coolant source 100, although the invention is not so limited.
Extending through the base plate 40, cap plate 42, and heat exchange plate 44 is a central inlet gas passageway 106 (
The invention contemplates that the atmosphere of heat transfer gas in space 54 may be static while the substrates 20 are being treated by ion beam 18 or may dynamically flow through the heat transfer gas space 54. Exemplary dynamic flow devices are described in U.S. Pat. No. 4,949,783, which is hereby incorporated by reference herein in its entirety, and are commercially available in high vacuum processing systems under the Flowcool™ trade name from Veeco Instruments Inc. (Woodbury, N.Y.).
As best shown in
The thickness of the thermoelectric devices 70 is selected relative to the vertical dimension of the ribs 58, 60 and rim 64 such that, when the cap plate 42 and the heat exchange plate 44 are fastened together, the ribs 58, 60 and rim 64 fail to contact the upper side 50 of the heat exchange plate 44 and the posts 66 fail to contact the lower side 56 of the cap plate 42. The thermoelectric devices 70 are clamped between the cap plate 42 and heat exchange plate 44, which constrains lateral movement of the thermoelectric devices 70 within the compartments 68. The lower side 56 of the cap plate 42 and the upper side 50 of the heat exchange plate 44 are separated by a gap defined predominantly by recess 65 (
The thermoelectric devices 70, which operate by the Peltier effect as understood by a person having ordinary skill in the art, convert electrical energy from the power supply 118 to heat pumping energy. In particular, direct current power applied between the lower and upper support plates 112, 114 induces pumped heat flow from the cap plate 42 through the thermoelectric elements 116 to the heat exchange plate 44 as the thermoelectric elements 116 convert electrical energy to heat pumping energy. Heat is conducted through the thermoelectric elements 116 and between the support plates 112, 114 by charge carriers. As heat is continuously absorbed from the upper support plate 114 and transferred by the thermoelectric elements 116 to the lower support plate 112, the upper support plate 114 defines a cold side of each thermoelectric device 70 that absorbs heat and the lower support plate 112 defines a hot side that rejects the heat.
The upper support plate 114 of each thermoelectric device 70 is in physical and thermal contact with the lower side 56 of cap plate 42 to establish a thermal interface for the absorption of thermal energy or heat from the cap plate 42 across the shared areas of thermal contact. The upper support plates 114 contact a majority of the surface area of the lower side 56 of cap plate 42 for absorbing heat from the cap plate 42. The contacting surface area may extend across approximately 90% of the surface area of the lower side 56 of cap plate 42. The lower support plate 112 of each thermoelectric device 70 is in physical and thermal contact with the upper side 50 of heat exchange plate 44 to establish another thermal interface for the flow of the rejected heat from the thermoelectric devices 70 to the heat exchange plate 44 across the shared areas of contact. A thermally conductive medium (not shown), such as a thermal grease or graphite pads, may be placed between the lower support plate 112 of each thermoelectric device 70 and the thermal transfer plate 44 and between the upper support plate 114 of the thermoelectric devices 70 and the cap plate 42 to act as a conductive interface and, thereby, potentially improve the thermal contact.
The properties and number of thermoelectric devices 70 may be tailored to provide a targeted reduction in the temperature of the cap plate 42. The thermoelectric devices 70 may be selected from among the XLT series of thermoelectric coolers commercially available from Marlow Industries Inc. (Dallas, Tex.), which exhibit a durability adequate to survive a high number of continuous cycles over a broad temperature range. Although the invention is not so limited, a specific thermoelectric device 70 suitable for use in the invention is the model XLT2385 thermoelectric cooler commercially available from Marlow Industries Inc. (Dallas, Tex.), which is capable of providing a maximum temperature drop for an unloaded state of 56.5° C.-dry N2 from the cold side to the hot side with the hot side at a temperature of 27° C. and a maximum temperature drop for an unloaded state of 64.0° C.-dry N2 from the cold side to the hot side with the hot side at a temperature of 50° C. The thermoelectric devices 70 may comprise single stage thermoelectric devices or, alternatively, may comprise stacked or cascaded thermoelectric devices.
In use and with reference to
The incident ion beam 18 on the pallet 22 and the substrates 20 carried on the pallet 22 represents a heat load in that a fraction of the ion kinetic energy of each incident ion is converted to heat. The backside heat transfer gas in the heat transfer gas space 54 transfers heat away from the substrates 20 and pallet 22 to the cap plate 42. A significant portion of the generated heat is subsequently transferred from the cap plate 42 to the upper support plate 114 of each thermoelectric device 70, which cools the cap plate 42. The thermoelectric devices 70 operate as temperature-modifying elements for corresponding portions of the pallet 22 to extract heat from portions of the substrates 20 to which each is closest. A portion of the heat is transferred by thermal conduction between contacting portions of the cap plate 42 and heat exchange plate 44. The heat is subsequently transferred from the lower support plate 112 of each thermoelectric device 70 to the heat exchange plate 44 and to the thermally conductive liquid 95 flowing through the liquid channel 86. A temperature gradient exists because of heat flow from the heated substrates 20 to the heat exchange plate 44. The thermally conductive liquid 95, which is warmed from its inflow temperature by the transferred heat, removes the heat from the substrate fixture 24 for external dissipation.
The temperature of the processed substrates 20 reflects the temperature of the cap plate 42. The presence of the thermoelectric devices 70 increases the net drop in temperature across the cap plate 42 and the heat exchange plate 44 of substrate fixture 24 so that the substrates 20 are maintained at a lower temperature while exposed to the ion beam 18. As a result, heat is more efficiently transferred away from the substrates 20. Because of the additional incremental temperature reduction provided by the thermoelectric devices 70, the current of the ion beam 18 in the high vacuum processing system 10 used to process the substrates 20 may be increased to increase the etching rate and system throughput. Certain temperature-sensitive materials, such as gallium nitride, may be processed in the high vacuum processing system 10 without damaging the substrates 20. The temperature reduction of the substrate fixture 24 is achieved without adding common freezing-point additives, such as ethylene glycol or propylene glycol, to the thermally conductive liquid 95 flowing through the liquid channel 86.
In an alternative embodiment of the invention, a drive mechanism (not shown) may be coupled with the substrate fixture 24 for rotating and/or tilting all, or part, of the substrate fixture 24 and, therefore, the substrates 20 carried on the pallet 22 relative to the ion beam 18 and chamber wall 13. Electrical connections for the drive mechanism may be routed through the access column 26 to a drive mechanism inside the vacuum vessel 12 or the access column 26 may actively participate in the rotation and/or tilting. The electrical interface electrically coupling the thermoelectric devices 70 with the power supply 118 may comprise a slip ring (not shown) often used to provide a signal transmission path when transmitting electrical signals between a stationary structure and a structure that rotates with respect to the stationary structure. Generally, slip rings typically include conductive brushes that contact conductive bands to pass electrical current from the stationary structure to the rotating structure.
In certain embodiments of the invention, the substrate fixture 24 may include at least one temperature sensor 120 (
A temperature controller 122 receives the temperature information as input from the temperature sensor 120 across an insulated conductor or wire 119 that establishes a communications path. The temperature controller 112 may utilize the temperature feedback information to regulate the operating power delivered from the power supply 118 to the thermoelectric devices 70 so as to improve the ability to precisely control the temperature of the substrates 20. The temperature controller 122 may include a programmable system, such as a microprocessor, capable of being programmed to execute instructions effective to control the temperature of the cap plate 42 of the substrate fixture 24 and the substrates 20 at one uniform temperature. In particular, the temperature controller 122 calculates control signals for the thermoelectric devices 70 and sends the calculated control signals to the power supply 118. The power supply 118 responds to the control signals by changing the electrical current supplied to the thermoelectric devices 70. The electrical current through the thermoelectric devices 70 is increased or decreased by the power supply 118, as required, in relation to a difference between the measured temperature and a temperature set point established in a comparative control circuit or by a software control residing in the temperature controller 122. Maintaining the cap plate 42 of the substrate fixture 24 at, or near, a measured temperature operates to maintain the substrates 20 below a certain temperature.
The program executed by the temperature controller 122 may provide for varying the temperature as a function of time and may include cycling the cap plate 42 of the substrate fixture 24 and the substrates 20 through ranges of temperatures during processing. The temperature controller 122 may be a proportional, a proportional-derivative (PD), a proportional-integral (PI), or a proportional-integral-derivative (PID) controller that uses feedback information from the temperature sensor 120 to control the substrate temperature based upon deviations of the measured temperature from the temperature set point. In this manner, the sensor 120 and temperature controller 122 cooperate to provide a closed loop control system.
The temperature controller 122 may also calculate and send additional control signals to the coolant source 100 to control the flow of the thermally conductive liquid 95 to liquid inlet 96 and, ultimately, liquid channel 86. The temperature controller 122 may also control the temperature of the thermally conductive liquid 95.
For expanded temperature control, the temperature controller 122 may be configured to switch the thermoelectric devices 70 between heating and cooling by reversing the current delivered from the power supply 118 to the support plates 112, 114. In this switched condition in which the temperature controller 122 is configured for bipolar operation, the thermoelectric devices 70 may be used to heat the substrate fixture 24, for example, before venting the vacuum vessel 12 of the high vacuum processing system 10 to atmosphere. The temperature controller 122 may include a relay that permits bipolar operation.
The thermoelectric devices 70 are shown wired or otherwise electrically connected in series with the power supply 118. Alternatively, the thermoelectric devices 70 may be wired or otherwise electrically connected in parallel with the power supply 118. In an alternative embodiment of the invention, some of the thermoelectric devices 70 may be serially coupled to the power supply 118 for cooling the substrate fixture 24 and the remainder of the thermoelectric devices 70 may be serially coupled for heating the substrate fixture 24. The ability to heat and cool the substrate fixture 24 improves the precision of temperature regulation. The power supply 118 is operated under the control of temperature controller 122 to regulate the currents through the thermoelectric devices 70 to maintain a desired substrate temperature for the nearest substrate 20 (or substrate portion) by heating or cooling the portion of the pallet 22 carrying the substrate 20. The thermoelectric devices 70 may be used to establish a controlled substrate temperature above ambient temperature in some processes to volatilize etch products from the ion beam process and, thereby, increase the reactive etching rate.
Further details and embodiments of the invention will be described in the following example.
A substrate fixture, substantially similar to substrate fixture 24, was equipped with an array of sixteen thermoelectric devices arranged as shown in
Under the same conditions and for purposes of comparison, a substrate supported by the cap plate of a substrate fixture lacking thermoelectric devices was exposed to an ion beam having a beam voltage of 700 volts and a beam current of 1100 milliamps. This ion beam, which delivered a beam power of 770 watts, is characterized by an etch rate of about 45 nm/min. While exposed to the ion beam, the observed temperature of the cap plate was approximately 70° C.
While the present invention has been illustrated by a description of various embodiments and while these embodiments have been described in considerable detail, it is not the intention of the applicants to restrict or in any way limit the scope of the appended claims to such detail. Additional advantages and modifications will readily appear to those skilled in the art. Thus, the invention in its broader aspects is therefore not limited to the specific details, representative apparatus and method, and illustrative example shown and described. Accordingly, departures may be made from such details without departing from the spirit or scope of applicants' general inventive concept.