The invention relates generally to semiconductor fabrication technology and, more particularly, to chemical vapor deposition (CVD) processing and associated apparatus, for holding semiconductor wafers during processing.
In the fabrication of light-emitting diodes (LEDs) and other high-performance devices such as laser diodes, optical detectors, and field effect transistors, a chemical vapor deposition (CVD) process is typically used to grow a thin film stack structure using materials such as gallium nitride over a sapphire or silicon substrate. A CVD tool includes a process chamber, which is a sealed environment that allows infused gases to react upon the substrate (typically in the form of wafers) to grow the thin film layers. Examples of current product lines of such manufacturing equipment are the TurboDisc® and EPIK® families of metal organic chemical vapor deposition (MOCVD) systems, manufactured by Veeco Instruments Inc. of Plainview, N.Y.
A number of process parameters are controlled, such as temperature, pressure and gas flow rate, to achieve a desired crystal growth. Different layers are grown using varying materials and process parameters. For example, devices formed from compound semiconductors such as III-V semiconductors typically are formed by growing successive layers of the compound semiconductor using MOCVD. In this process, the wafers are exposed to a combination of gases, typically including a metal organic compound as a source of a group III metal, and also including a source of a group V element which flow over the surface of the wafer while the wafer is maintained at an elevated temperature. Generally, the metal organic compound and group V source are combined with a carrier gas which does not participate appreciably in the reaction as, for example, nitrogen. One example of a III-V semiconductor is gallium nitride, which can be formed by reaction of an organo-gallium compound and ammonia on a substrate having a suitable crystal lattice spacing, as for example, a sapphire wafer. The wafer is usually maintained at a temperature on the order of 1000-1100° C. during deposition of gallium nitride and related compounds.
In a MOCVD process, where the growth of crystals occurs by chemical reaction on the surface of the substrate, the process parameters must be controlled with particular care to ensure that the chemical reaction proceeds under the required conditions. Even small variations in process conditions can adversely affect device quality and production yield. For instance, if a gallium and indium nitride layer is deposited, variations in wafer surface temperature will cause variations in the composition and bandgap of the deposited layer. Because indium has a relatively high vapor pressure, the deposited layer will have a lower proportion of indium and a greater bandgap in those regions of the wafer where the surface temperature is higher. If the deposited layer is an active, light-emitting layer of an LED structure, the emission wavelength of the LEDs formed from the wafer will also vary to an unacceptable degree.
In a MOCVD process chamber, semiconductor wafers on which layers of thin film are to be grown are placed on rapidly-rotating carousels, referred to as wafer carriers, to provide a uniform exposure of their surfaces to the atmosphere within the reactor chamber for the deposition of the semiconductor materials. Rotation speed is on the order of 1,000 RPM. The wafer carriers are typically machined out of a highly thermally conductive material such as graphite, and are often coated with a protective layer of a material such as silicon carbide. Each wafer carrier has a set of circular indentations, or pockets, in its top surface in which individual wafers are placed. Typically, the wafers are supported in spaced relationship to the bottom surface of each of the pockets to permit the flow of gas around the edges of the wafer. Some examples of pertinent technology are described in U.S. Patent Application Publication No. 2012/0040097, U.S. Pat. Nos. 8,092,599, 8,021,487, U.S. Patent Application Publication No. 2007/0186853, U.S. Pat. Nos. 6,902,623, 6,506,252, and 6,492,625, the disclosures of which are incorporated by reference herein.
The wafer carrier is supported on a spindle within the reaction chamber so that the top surface of the wafer carrier having the exposed surfaces of the wafers faces upwardly toward a gas distribution device. While the spindle is rotated, the gas is directed downwardly onto the top surface of the wafer carrier and flows across the top surface toward the periphery of the wafer carrier. The used gas is evacuated from the reaction chamber through ports disposed below the wafer carrier. The wafer carrier is maintained at the desired elevated temperature by heating elements, typically electrical resistive heating elements disposed below bottom surface of the wafer carrier. These heating elements are maintained at a temperature above the desired temperature of the wafer surfaces, whereas the gas distribution device typically is maintained at a temperature well below the desired reaction temperature so as to prevent premature reaction of the gases. Therefore, heat is transferred from the heating elements to the bottom surface of the wafer carrier and flows upwardly through the wafer carrier to the individual wafers.
The gas flow over the wafers varies depending on the radial position of each wafer, with outermost-positioned wafers being subjected to higher flow rates due to their faster velocity during rotation. Even on each individual wafer there can be temperature non-uniformities, i.e., cold spots and hot spots. One of the variables affecting the formation of temperature non-uniformities is the shape of the pockets within the wafer carrier. Generally, pocket shapes form a circular shape in the surface of the wafer carrier. As the wafer carrier rotates, the wafers are subject to substantial centripetal force at their outermost edge (i.e., the furthermost edge from the axis of rotation), causing the wafer to press against the interior wall of the respective pocket in the wafer carrier. Under this condition, there is intimate contact between these outer edges of the wafers and the pocket edge. The increased heat conduction to these outer-most portions of the wafers results in more temperature non-uniformity, further aggravating the problems described above.
Efforts have been made to minimize the temperature non-uniformities by increasing the gap between the wafer's edge and the interior wall of the pocket, including designing a wafer that is flat on a portion of the edge. This flat portion of the wafer creates a gap and decreases the points of contact with the interior wall of the pocket, thereby mitigating temperature non-uniformities. Other factors affecting the heating uniformity throughout the wafers held by the wafer carrier include the heat transfer and emissivity properties of the wafer carrier, combined with the layout of the wafer pockets.
With the temperature-uniformity needs in mind, another desirable property for wafer carriers is to increase the throughput of the CVD process. The role of the wafer carrier in increasing process throughout is holding a larger quantity of individual wafers. Providing a wafer carrier layout with more wafers affects the thermal model. For instance, the portions of the wafer carrier near the edges tend to be at a lower temperature than other portions due to radiative heat loss from the wafer carrier edges.
Accordingly, a practical solution is needed for wafer carriers in which temperature uniformity and mechanical stresses in high-density layouts are addressed.
A wafer carrier includes an arrangement of pockets and a thermal cover made of a plurality of cover segments. The arrangements described herein facilitate heat uniformity on the wafer carrier and/or enhance throughput of the CVD process.
The invention may be more completely understood in consideration of the following detailed description of various embodiments of the invention in connection with the accompanying drawings, in which:
As shown in
Gas distribution device 12 is connected to sources 14, 16, and 18 for supplying process gases to be used in the wafer treatment process, such as a carrier gas and reactant gases, such as a metalorganic compound and a source of a group V metal. Gas distribution device 12 is arranged to receive the various gases and direct a flow of process gases generally in the downward direction. Gas distribution device 12 desirably is also connected to coolant system 20 arranged to circulate a liquid through gas distribution device 12 so as to maintain the temperature of the gas distribution device at a desired temperature during operation. A similar coolant arrangement (not shown) can be provided for cooling the walls of reaction chamber 10. Reaction chamber 10 is also equipped with exhaust system 22 arranged to remove spent gases from the interior of the chamber 10 through ports (not shown) at or near the bottom of the chamber so as to permit continuous flow of gas in the downward direction from gas distribution device 12.
Spindle 24 is arranged within the chamber so that the central axis 26 of spindle 24 extends in the upward and downward directions. Spindle 24 is mounted to the chamber by a conventional rotary pass-through device 28 incorporating bearings and seals (not shown) so that spindle 24 can rotate about central axis 26, while maintaining a seal between spindle 24 and the wall of reaction chamber 10. The spindle has fitting 30 at its top end, i.e., at the end of the spindle closest to gas distribution device 12. As further discussed below, fitting 30 is an example of a wafer carrier retention mechanism adapted to releasably engage a wafer carrier. In the particular embodiment depicted, fitting 30 is a generally frustoconical element tapering toward the top end of the spindle and terminating at a flat top surface. A frustoconical element is an element having the shape of a frustum of a cone. Spindle 24 is connected to rotary drive mechanism 32 such as an electric motor drive, which is arranged to rotate spindle 24 about central axis 26.
Fitting 30 can also be any number of other configurations. For example, a spindle 24 having an end shaped as a square or rounded-square, a series of posts, an oval or other rounded shape having an aspect ratio other than 1:1, triangle, could be inserted into a matching fitting 30. Various other keyed, splined, or interlocking arrangements between spindle 24 and fitting 30 can be used that maintain rotational engagement between those components and prevent undesirable slipping. In embodiments, keyed, splined, or interlocking arrangements can be used that maintain desired levels of rotational engagement between fitting 30 and spindle 24 despite expected amounts of thermal expansion or contraction of either component.
Heating element 34 is mounted within the chamber and surrounds spindle 24 below fitting 30. Reaction chamber 10 is also provided with entry opening 36 leading to antechamber 38, and door 40 for closing and opening the entry opening. Door 40 is depicted only schematically in
The apparatus also includes a plurality of wafer carriers. In the operating condition shown in
In operation, wafer 54, such as a disc-like wafer formed from sapphire, silicon carbide, or other crystalline substrate, is disposed within each pocket 56 of each wafer carrier. Typically, wafer 54 has a thickness which is small in comparison to the dimensions of its major surfaces. For example, a circular wafer of about 2 inches (50 mm) in diameter or a circular wafer of about 4 inches (100 mm) in diameter or a circular wafer of about 150 mm (6 inches) may be used with a thickness of about 770 μm or less. As illustrated in
In a typical MOCVD process, wafer carrier 42 with wafers loaded thereon is loaded from antechamber 38 into reaction chamber 10 and placed in the operative position shown in
Heating elements 34 transfer heat to the bottom surface 52 of wafer carrier 42, principally by radiant heat transfer. The heat applied to bottom surface 52 of wafer carrier 42 flows upwardly through the body 46 of the wafer carrier to the top surface 48 of the wafer carrier. Heat passing upwardly through the body also passes upwardly through gaps to the bottom surface of each wafer, and upwardly through the wafer to the top surface of wafer 54. Heat is radiated from the top surface 48 of wafer carrier 42 and from the top surfaces of the wafer to the colder elements of the process chamber as, for example, to the walls of the process chamber and to gas distribution device 12. Heat is also transferred from the top surface 48 of wafer carrier 42 and the top surfaces of the wafers to the process gas passing over these surfaces.
In the embodiment depicted, the system includes a number of features designed to assess uniformity of heating of the surfaces of each wafer 54. In this embodiment, temperature profiling system 58 receives temperature information that can include a temperature and temperature monitoring positional information from temperature monitor 60. In addition, temperature profiling system 58 receives wafer carrier positional information, which in one embodiment can come from rotary drive mechanism 32. With this information, temperature profiling system 58 constructs a temperature profile of the pockets 56 on wafer carrier 42. The temperature profile represents a thermal distribution on the surface of each of the pockets 56 or wafers 54 contained therein.
Radially outward from inner portion 202 is disc 204 that has an inner circumference extending around inner portion 202. Radially outward from disc 204 are a plurality of cover segments 206. The plurality of cover segments 206, taken in combination, define an inner circumference extending around disc 204. Lip 208 is arranged radially outward from plurality of cover segments 206, and defines an inner circumference extending around the plurality of cover segments 206. Each of these interfaces can include a “knife edge”, overhang, or bevel such that lip 208 prevents radially outward or upward movement of cover segments 206, and disc 204 prevents upward movement of segments 206 at their radially inner edges.
Each of the plurality of cover segments 206 defines a substantially circular aperture that exposes a portion of plate 210. In the embodiment shown in
Staples 212 are arranged to hold each of the plurality of cover segments 206 to the plate 210. Staples 212 also hold disc 204 to plate 210. Staples 212 are shown in exploded view along with one of the plurality of cover segments 206 and disc 204 to depict holes 214 that are configured to receive staples 212. Each staple 212 includes a back-span and one or more projections configured to extend through the plate 210. In alternative embodiments, staples 212 could have two projections (as shown in the Figures), or more than two projections (for example, three projections that couple three cover segments). The number and arrangement of projections attached to the back-span of staples 212 can be determined based on the particular orientation of cover segments 206 and expected stresses thereon during the MOCVD process. Staples 212 can also be centrifugally balanced, in embodiments, such that rotation of plate 210 is not significantly imbalanced by the mass of staples 212 during rotation at expected speeds of several thousand rotations per minute.
In alternative embodiments, fasteners other than staples could be used. For example, in an embodiment a central screw and nut could be used to affix cover segments 206 to plate 210, as could a clamp or any of a number of other fasteners. Such fasteners can be made of materials that correspond in thermal expansion coefficient to the remainder of wafer carrier 200, but with sufficient mechanical strength to prevent movement during rotation, such as silicon carbide, tungsten, or molybdenum.
Likewise, in the partially exploded view of wafer carrier 200, the portion of plate 210 arranged underneath one of the segments 206 is shown. Pedestals 215 are also arranged along the circular border of the aperture formed by the segments 206. As shown in
Outer pedestal portion 215B, in contrast, is configured to hold segments 206 such that the segments 206 are not in direct thermal contact with plate 210 except at the relatively small upper surface of outer pedestal portion 215B.
In embodiments, wafer carrier 200 is configured such that a wafer within the portion of plate 210 at each pedestal has approximately the same height as a cover segment 206 positioned on radially outer pedestal portions 215B. By modifying the heights of the pedestal portions 214A and 214B, as well as the materials that make up cover portions 206, net vertical thermal conductivity at operational conditions of between about 700° C. and about 900° C. can be achieved that is consistent as between portions of the wafer carrier 200 that are undergoing epitaxial growth and those that are not. In alternative embodiments, different heights of pedestals 214A and 214B can be used that will achieve beneficial thermal conductivity patterns under these and other operational conditions and temperatures. This desired net thermal conductivity effect can be, for example, consistent thermal conductivity between the wafers and the thermal covers, or consistent thermal conductivity across the entire plate 210, for example.
As shown in
In alternative embodiments the platform profile can have any of a variety of profiles, such as flat, convex, contoured, or textured. Tabs and bow of the pocket can be similar to conventional pockets, but raised from the plate surface rather than sunken into the plate surface based on the thickness of the cover segments 206.
In embodiments, a thickness 226 of each of the plurality of cover segments 206 can be set such that the thickness of the radially outer pedestal 215B in addition to the thickness of the platform 226 is approximately equal to the thickness of the outer edge of the platform 218 plus the thickness of the radially inner pedestals 215A plus the thickness of a desired substrate and wafer (not shown). Thus the thicker the pedestal 218 that is used, the thicker the plurality of cover segments 206 will be. In embodiments, segments 206 can be made of quartz or another material that has thermal transfer characteristics that are similar to a substrate or wafer that is to be grown. In embodiments, segments 206 with different material compositions can be interchanged between uses to match thermal characteristics of a wafer grown epitaxially on platforms 218 or a substrate arranged thereon.
The embodiment shown in
In alternative embodiments, further features could be added to locking bar 313 that would prevent movement in other directions. For example, surface portion 313A could have burrs or other locking features that prevent radial movement, in addition to circumferential movement, of adjacent cover segments 306 with respect to plate 310.
Although locking screws 413 are used in the embodiment shown in
The design illustrated in
In use, cover segments 506 can be coupled to the remainder of wafer carrier 500 by arranging the cover segments 506 such that the apertures defined therein are each positioned over a platform, as described above in more detail. In the embodiment shown in
Jigsaw structures (620, 622) are relatively easy to fasten against centripetal forces trying to lift and throw the covers (since it is almost centered and quite heavy). Similarly, a jigsaw layout such as the structure shown in
In alternative embodiments, various other fasteners could be used in addition to locking bars, nuts, or staples. Furthermore, various alternative arrangements of wafer pockets can be used, such as wafer pocket arrangements that include one ring, two rings, or even many rings of pockets. As described above, pedestals can be incorporated into these designs that result in wafer height at a predetermined relationship with the height of the cover segments. Cover segment material and thickness can likewise be selected so that thermal transmission through the wafer before, during, or at the end of MOCVD is similar to thermal transmission through the cover segments.
As described herein, a wafer carrier configured to be used with a chemical vapor deposition device includes one or more plates having a top surface and a bottom surface arranged opposite one another, a plurality of platforms defined on the top surface of the plate, a plurality of cover segments configured to engage with the top surface of the plate, each of the plurality of cover segments defining at least one aperture corresponding to one of the plurality of platforms. These wafer carriers improve upon conventional systems at least in that, for each platform and a corresponding cover segment, a plurality of radially inner pedestals are arranged on only the platform to support a corresponding substrate, and a plurality of radially outer pedestals arranged on only the top surface and configured to support the corresponding cover segment.
In embodiments, screws, clamps, ties, staples, rivets, or other fasteners could be used to hold the plate to the cover segments. In alternative embodiments each cover segment can define one or more than one aperture, or two cover segments can combine to define an aperture. In some embodiments, there could be only one cover segment that defines all of the apertures. In embodiments, the radially inner pedestals and radially outer pedestals could be arranged differently or have different heights corresponding to any of a number of desired vertical thermal profiles, including thermal profiles in which the wafers are hotter, cooler, or the same temperature as the surrounding thermal cover segments.
Persons of ordinary skill in the relevant arts will recognize that the subject matter hereof may comprise fewer features than illustrated in any individual embodiment described above. The embodiments described herein are not meant to be an exhaustive presentation of the ways in which the various features of the subject matter hereof may be combined. Accordingly, the embodiments are not mutually exclusive combinations of features; rather, the various embodiments can comprise a combination of different individual features selected from different individual embodiments, as understood by persons of ordinary skill in the art. Moreover, elements described with respect to one embodiment can be implemented in other embodiments even when not described in such embodiments unless otherwise noted.
Although a dependent claim may refer in the claims to a specific combination with one or more other claims, other embodiments can also include a combination of the dependent claim with the subject matter of each other dependent claim or a combination of one or more features with other dependent or independent claims. Such combinations are proposed herein unless it is stated that a specific combination is not intended.
Any incorporation by reference of documents above is limited such that no subject matter is incorporated that is contrary to the explicit disclosure herein. Any incorporation by reference of documents above is further limited such that no claims included in the documents are incorporated by reference herein. Any incorporation by reference of documents above is yet further limited such that any definitions provided in the documents are not incorporated by reference herein unless expressly included herein.
The embodiments are intended to be illustrative and not limiting. Additional embodiments are within the claims. In addition, although aspects of the present invention have been described with reference to particular embodiments, those skilled in the art will recognize that changes can be made in form and detail without departing from the scope of the invention, as defined by the claims.