1. Field of the Invention
Embodiments of the present invention generally relate to a plasma enhanced chemical vapor deposition (PECVD) apparatus.
2. Description of the Related Art
As demands for larger flat panel displays (FPDs) and solar panels for consumers (and consequently, demands for higher manufacturing cost-efficiency from the FPD and solar panel manufacturers), continues to increase, the size of PECVD chambers that are used for depositing thin films used for FPDs and solar panels increases. The chambers used in the deposition process are typically capacitively driven parallel-plate reactors using RF or VHF fields to ionize and dissociate processing gas between the plate electrodes. Due to finite reactor dimensions and boundary conditions on the electrodes, the excited fields inherently form standing waves. If the size of the electrodes becomes comparable with the excitation wavelengths, electromagnetic effects causing non-uniformities in plasma and deposited films becomes inevitable.
The standing waves and plasma non-uniformities have a strong influence on the thickness and properties of thin films deposited by PECVD reactors or on the process uniformity in plasma processing chambers in general. Non-uniform films may lead to the so-called “mura effects” on FPDs or to low-efficient cells in solar panels. In some cases, plasma non-uniformity may lead to non-functioning devices.
The standing wave effects and related plasma non-uniformities may be overcome to an extent by using shaped electrodes, lens electrodes, cavities behind resistive electrodes, lower frequencies, tuning the processing parameters such as chamber pressure, and combinations thereof. However, when the processing chamber size increases to reflect the demand for larger FPDs and solar panels, simply scaling up the aforementioned countermeasures to the standing wave effect and plasma non-uniformities may not be sufficient.
Therefore, there is a need for a plasma reactor designed to increase plasma uniformity and overcome standing wave effects.
Embodiments discussed herein generally include electrodes having parallel ferrite boundaries that suppress RF currents perpendicular to the ferrite boundary and absorb magnetic field components parallel to the boundary. The ferrites cause the standing wave to stretch outside the ferrites and shrink inside the ferrite. A plurality of power sources are coupled to the electrode. The phase of the VHF current delivered from the power sources may be modulated to move the standing wave that is perpendicular to the ferrites in a direction parallel to the ferrites. Thus, the VHF current on the uncovered electrode area will be a plane wave, quasi-uniform (in a direction perpendicular to the ferrites) propagating in the direction parallel to the ferrites.
In one embodiment, an apparatus may include a chamber body having a first wall with a slit valve opening therethrough, an electrode disposed in the chamber body, one or more ferrite pieces extending parallel to the slit valve opening, and a plurality of first VHF power sources coupled to the electrode at a plurality of locations.
In another embodiment, an apparatus may include an electrode, a first power source coupled to the electrode in a first plurality of locations along a first periphery of the electrode, and a second power source separate from the first power source and coupled to the electrode in a second plurality of locations along a second periphery of the electrode parallel to the first periphery. The apparatus may also include one or more first ferrite blocks extending along a third periphery of the electrode perpendicular to the first and second periphery and one or more second ferrite blocks extending along a fourth periphery of the electrode parallel to the third periphery.
In another embodiment, a plasma enhanced chemical vapor deposition apparatus is disclosed. The apparatus may include a processing chamber body having a plurality of sidewalls, at least a first sidewall of the plurality of sidewalls having a slit valve opening therethrough. The apparatus may also include a susceptor disposed within the chamber body and a gas distribution showerhead disposed in the chamber body opposite the susceptor. The apparatus may also include a backing plate disposed in the chamber body adjacent the gas distribution showerhead. The backing plate may have a first side facing the gas distribution showerhead and a second side opposite the first side. The apparatus may also include one or more first ferrite blocks disposed along the second side of the backing plate along a first edge of the second side. The one or more first ferrite blocks may extend substantially parallel to the slit valve opening. The apparatus may also include a first power source coupled to the backing plate on the second side at a second edge perpendicular to the first edge and a second power source separate from the first power source coupled to the backing plate on the second side at a third edge parallel to the second edge.
In another embodiment, a method is disclosed. The method includes applying a first RF or VHF current to an electrode at one or more first locations. The electrode has a generally rectangular shape and one or more ferrite blocks extending along a substantial length of first and second parallel edges. The first RF or VHF current is applied at a first phase, and the first location is located at a third edge of the electrode perpendicular to the first and second edges. The method also includes applying a second RF or VHF current to the electrode at one or more second locations located at a fourth edge of the electrode parallel to the first edge. The second RF or VHF current is applied in a second phase different than the first phase. The phase of the second RF or VHF current relative to the first RF or VHF current can be varied over time.
So that the manner in which the above recited features of the present invention can be understood in detail, a more particular description of the invention, briefly summarized above, may be had by reference to embodiments, some of which are illustrated in the appended drawings. It is to be noted, however, that the appended drawings illustrate only typical embodiments of this invention and are therefore not to be considered limiting of its scope, for the invention may admit to other equally effective embodiments.
To facilitate understanding, identical reference numerals have been used, where possible, to designate identical elements that are common to the figures. It is contemplated that elements and features of one embodiment may be beneficially incorporated in other embodiments without further recitation.
Embodiments discussed herein generally include electrodes having parallel ferrite boundaries that suppress RF currents perpendicular to the ferrite boundary and absorb magnetic field components parallel to the boundary. The ferrites cause the standing wave to stretch outside the ferrites and shrink inside the ferrite. A plurality of power sources are coupled to the electrode. The phase of the VHF current delivered from the power sources may be modulated to move the standing wave that is perpendicular to the ferrites in a direction parallel to the ferrites. Thus, the VHF current on the uncovered electrode area will be a plane wave, quasi-uniform (in a direction perpendicular to the ferrites) propagating in the direction parallel to the ferrites.
Embodiments disclosed herein will be discussed with reference to a PECVD apparatus available from Applied Materials, Inc., Santa Clara, Calif. It is to be understood that the embodiments discussed herein may have utility in other chambers including those sold by other manufacturers. The embodiments disclosed herein propose a solution for achievement of uniform plasma in the apparatus and/or uniform process conditions in large area RF or VHF capacitive plasma reactors. The solution includes enhancing RF or VHF current uniformity in one direction (for example, the x-axis of a rectangular electrode), and power coupling scheme that moves the non-uniform standing wave field pattern in the other direction (for example, the y-axis of the rectangular electrode) during the deposition process.
The substrate 110 may be placed on a susceptor 108 when in the apparatus 100. The susceptor 108 may be raised and lowered on a shaft 112. In one embodiment, the shaft 112 and the susceptor 108 may comprise a conductive material. In another embodiment, the shaft 112 and the susceptor 108 may comprise aluminum. The apparatus 100 may be evacuated by a vacuum pump 114. A valve 116 may be coupled between the chamber and the vacuum pump 114 to adjust the vacuum level of the apparatus 100.
Processing gas may be introduced into the apparatus 100 from a gas source 118 through a tube 122 that passes through the chamber lid 124. The tube 122 is coupled to the backing plate 126 to permit the processing gas to pass through the backing plate 126 and enter a plenum 148 between the backing plate 126 and the gas distribution showerhead 128. In one embodiment, the tube 122, the backing plate 126, and the gas distribution showerhead 128 may comprise a conductive material. In another embodiment, the tube 122, backing plate 126, and gas distribution showerhead 128 may comprise aluminum. The processing gas spreads out in the plenum 148 and then passes through gas passages 130 formed through the gas distribution showerhead 128 to the processing area 146. In general, the power may be applied such that ⅛th of the wavelength at the applied frequency is comparable to the chamber diagonal. The chamber diagonal is the distance across a rectangular chamber from one corner to another corner diagonally opposite.
A plurality of power sources 120A, 120B are also coupled to the backing plate 126. In one embodiment, the power sources 120A, 120B comprise RF power sources capable of generating RF currents at a frequency of between about 13.56 MHz and about 100 MHz. In another embodiment, the power sources 120A, 120B comprise VHF power sources capable of generating VHF currents at a frequency of between about 40 MHz and about 60 MHz. In another embodiment, the power sources 120A, 120B comprise VHF power sources capable of generating VHF currents at a frequency of about 27 MHz. In another embodiment, the power sources 120A, 120B are capable of generating VHF currents of about 40 MHz and above. The power sources 120A, 120B may be phase modulated as will be discussed below.
The current from the power sources 120A, 120B flows along the outside surface of the backing plate 126. RF current and VHF current have a ‘skin effect’ in that the current does not penetrate all the way through a conductive body such as the backing plate 126. RF or VHF current travels along the outside surface of a conductive object and penetrates a predetermined distance into the conductive article. The amount that the RF or VHF current penetrates into the conductive article is a function of the frequency of the current and the material properties. The RF or VHF current then travels down a bracket 134 to the front face of the gas distribution showerhead 128. In one embodiment, the bracket 134 may comprise a conductive material. In another embodiment, the bracket 134 may comprise aluminum. The RF or VHF current flows along a path shown by arrows “A”. Thus, the RF current travels along the back surface of the backing plate 126, the side surface of the backing plate 126 the outside surface of the bracket 134, and the bottom surface of the gas distribution showerhead 128.
The RF or VHF current does not travel along the back surface of the gas distribution showerhead 128 that faces the backing plate 126. Additionally, the RF or VHF current does not travel along the front surface of the backing plate 126 that faces the gas distribution showerhead 128. Thus, the gas in the plenum 148 does not see the RF or VHF current and therefore does not ignite into a plasma in the plenum 148.
In the embodiment shown in
For RF or VHF current, on the other hand, the location where the current couples to the backing plate 126 makes a difference. In the embodiment shown in
In the embodiment shown in
For the embodiment shown in
In the apparatus 100, there are four walls 102. Of those four walls 102, three of the walls 102 are substantially identical and look substantially identical to the RF or VHF current (in absence of the ferrites 132) when it travels thereon returning to the power sources 120A, 120B as shown by arrows “B”. The fourth wall 102, however, is different than the other walls 102 and looks different to the RF or VHF current as it returns to the power sources 120A, 120B. The fourth wall 102 has the slit valve opening 106 therethrough. The RF or VHF current travels a different path along the wall 102 having the slit valve opening 106. The RF or VHF current actually travels along the slit valve opening 106. Thus, the RF or VHF current traveling along the wall 102 having the slit valve opening 106 has a longer inductive path to return to the power sources 120A, 120B as compared to the three other walls 102.
As the RF or VHF current travels back to the power sources 120A, 120B, the potential of the RF or VHF current decreases. Hence, the potential difference between the RF or VHF current flowing along the three substantially identical walls 102 back to the power sources 120A, 120B and the gas distribution showerhead 128 is different than the difference between the RF or VHF current flowing along the wall 102 having the slit valve opening 106 and the gas distribution showerhead 128, in absence of the ferrites 132. The slit valve opening 106 is a part of the RF return path and therefore leads to an asymmetry along the chamber walls. The asymmetric RF return path shifts the standing wave and thus, unevenly distributes the plasma within the apparatus 100. With an uneven plasma distribution, a uniform deposition of material onto the substrate 110 may not occur.
The ferrites 132 may be used to substantially reduce the effect of the slit valve opening 106. Ferrites 132 may be used to lengthen the RF return path along the wall opposite to the slit valve (i.e., the ferrites 132 would be placed, for example, above the electrode or backing plate opposite to the slit valve opening 106). The RF return path may be lengthened by using thicker ferrites 132 or stronger ferrites 132 opposite the slit valve opening 106. In the embodiment shown in
When the susceptor 108 raises the substrate 110 for processing, the susceptor 108 encounters a shadow frame 138 while moving to the processing position. The shadow frame 138 may prevent arcing between the susceptor 108 and the substrate coating top. The shadow frame 138 may rest on a ledge 140 prior to being displaced by the susceptor 108. The shadow frame 138 may also be a part of the RF or VHF return path. One or more straps 142 may be coupled to both the shadow frame 138 as well as the inside surface of the walls 102. The straps 142 may be coupled to the inside surface of the walls 102 with one or more fastening mechanisms 144. In one embodiment, the fastening mechanism 144 may comprise a screw. The RF or VHF current travels along the susceptor 108, the straps 154, the inside surface of the walls 102, the lid 124, and back to the power sources 120A, 120B as shown by arrows “B” to complete the RF or VHF circuit.
By suppressing RF or VHF current with the ferrites spanning a length of the backing plate 126 parallel to the slit valve opening 106, the RF or VHF current in the direction of the slit valve opening (and opposite thereto) is controlled. However, because no ferrites 132 are perpendicular to the slit valve opening 106 (or vice versa), the RF or VHF current that runs parallel to the slit valve opening 106 (or vice versa) is not controlled. Thus, the ferrites 132 remove one degree of uncertainty to control of the RF or VHF current. The control of the RF or VHF current in the direction parallel to the slit valve opening 106 aids in plasma uniformity and thus, deposition uniformity.
To deposit material on the substrate 110, processing gas is introduced from the gas source 118 through the backing plate 126 and into the plenum 148. Then, the processing gas passes through the gas passages 130 formed in the gas distribution showerhead 128 and into the processing area 146. The RF or VHF current flows along the tube 122, the back surface of the backing plate 126, the bracket 134, and the front surface of the showerhead 128. The induced RF or VHF fields then ignite the processing gas into a plasma which deposits material onto the substrate 110. The RF or VHF current propagates through the plasma to the substrate 110 and along the shadow frame 138, the straps 142, the walls 102, and the lid 124 back to the power source 120A, 120B. In one embodiment, the straps 142 may be present along the walls 102 perpendicular to the ferrites 132 but not present on the walls parallel to the ferrites 132. In another embodiment, the straps 142 may be coupled to all walls 102.
It is to be understood that while the ferrites 132 have been discussed as being located behind the backing plate 126 on the atmosphere side of the chamber, the ferrites 132 may be placed in other locations as well. When the ferrites 132 are placed on the front surface of the gas distribution showerhead 128, the ferrites 132 may be enclosed in a cover such as a dielectric or ceramic cover to prevent the ferrites 132 from sputtering. Other potential locations for the ferrites 132 include under the susceptor 108, adjacent the backing plate 126, and adjacent the chamber walls 102 between the substrate 110 and the gas distribution showerhead 128. Additionally, while ferrites 132 have been described, it is to be understood that any ferromagnetic material, conducting or non-conducting, non-oriented, or ferromagnetic material, or oriented material such as magnets may be used.
A non-uniform standing wave profile in the y-direction can be moved by means of time-varying asymmetric (in phase or amplitude or both) drive (i.e., two feeds on electrode sides (non-ferrite sides) or a feed on one side and variable capacitor on the other side. Thus, a time-averaged uniform field plasma may be formed. The profiles can be controlled/improved by using multiple contact points 264, 266, 268, 270, 272, 274, 276, 278 on each side with uneven power distribution, or by multiple ferrite boundaries. Anisotropy in the excited RF/VHF fields/currents on the electrodes may also help with the slit valve effect issue. The currents are driven in parallel to the slit valve (ferrite boundaries parallel with the slit valve). Additionally, due to multiple contact points 264, 266, 268, 270, 272, 274, 276, 278 the current delivered to the different contact points 264, 266, 268, 260, 262, 264, 266, 268 may be different.
The boundary condition is affected by the magnetic material. By shortening the magnetic component parallel to the edge, a high magnetic permeability material will force the magnetic field, and thus the wave front, to be perpendicular to the edges and help form plane waves. In other words, a high magnetic permeability may increase the electrical length to the side and effectively extend the electrode.
It is to be understood that while the ferrites 252 have been shown as a single piece spanning the entire length of the electrode 256, the ferrites 252 may comprise multiple pieces. The multiple pieces may each span the entire length or the multiple pieces may be coupled together to collectively span the entire length. Additionally, if desired, the multiple ferrite 252 pieces may be spaced apart. Additionally, the contact points 264, 266, 268, 270, 272, 274, 276, 278 may be moved laterally. The electrode 256 may be a scooped gas distribution showerhead having a concave bottom surface facing the susceptor 258. In one embodiment, the electrode 256 may comprise a gas distribution showerhead having a substantially planar surface facing the susceptor 258. The ferrites 252 may be spaced from the electrode 206.
It is possible to deliver the VHF current from all sides and phasing in each direction, but such complexity is not necessary when using a ferrite system. The complexity is due to the plane waves that are launched from the power sources which make a linear wave front and makes the problem one dimension. Deflection from edges makes plane waves difficult and results in the domed wave front.
By utilizing ferrites strategically placed in a parallel plate reactor, better control of the RF or VHF current may occur. The ferrites may compensate for the standing wave effect and increase plasma uniformity. Due to an increased plasma uniformity, a more uniform and repeatable deposition may occur in the parallel plate reactor.
While the foregoing is directed to embodiments of the present invention, other and further embodiments of the invention may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow.
This application claims priority to U.S. Provisional Patent Application Ser. No. 61/108,393 (APPM/013758L02), filed Oct. 24, 2008, which is herein incorporated by reference.
Number | Date | Country | |
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61108393 | Oct 2008 | US |