The present disclosure relates generally to arc lamps used, for instance, in and millisecond anneal thermal processing chambers used for processing substrates.
Millisecond anneal systems can be used for semiconductor processing for the ultra-fast heat treatment of substrates, such as silicon wafers. In semiconductor processing, fast heat treatment can be used as an anneal step to repair implant damage, improve the quality of deposited layers, improve the quality of layer interfaces, to activate dopants, and to achieve other purposes, while at the same time controlling the diffusion of dopant species.
Millisecond, or ultra-fast, temperature treatment of semiconductor substrates can be achieved using an intense and brief exposure of light to heat the entire top surface of the substrate at rates that can exceed 104° C. per second. The rapid heating of just one surface of the substrate can produce a large temperature gradient through the thickness of the substrate, while the bulk of the substrate maintains the temperature before the light exposure. The bulk of the substrate therefore acts as a heat sink resulting in fast cooling rates of the top surface.
Aspects and advantages of embodiments of the present disclosure will be set forth in part in the following description, or may be learned from the description, or may be learned through practice of the embodiments.
One example aspect of the present disclosure is directed to a millisecond anneal system. The system can include a processing chamber for thermally treating a semiconductor substrate using a millisecond anneal process. The system can include one or more arc lamp heat sources. Each of the one or more arc lamp heat sources can include a plurality of electrodes for generating an arc through a gas in the arc lamp to generate a plasma. At least one of the plurality of electrodes has an electrode tip (e.g., formed from tungsten) having a surface with at least one groove to reduce lateral transportation of molten material across the surface of the electrode tip.
Another example aspect of the present disclosure is directed to an arc lamp. The arc lamp can include a plurality of electrodes and one or more inlets configured to receive water to be circulated through the arc lamp during operation. The one or more inlets can be configured to receive a gas. During operation of the arc lamp the gas can be converted to a plasma during an arc discharge between the plurality of electrodes. At least one of the plurality of electrodes can have an electrode tip. The electrode tip can have a surface with at least one groove to reduce lateral transportation of molten material across the surface of the electrode tip.
Another example aspect of the present disclosure is directed to an arc lamp. The arc lamp can include a plurality of electrodes and one or more inlets configured to receive water to be circulated through the arc lamp during operation. The one or more inlets can be configured to receive a gas. During operation of the arc lamp the gas can be converted to a plasma during an arc discharge between the plurality of electrodes. At least one of the plurality of electrodes can have an electrode tip and a heat sink. The electrode can have an interface between the electrode tip and the heat sink that is concave or convex.
Variations and modification can be made to the example aspects of the present disclosure. Other example aspects of the present disclosure are directed to systems, methods, devices, and processes for thermally treating a semiconductor substrate.
These and other features, aspects and advantages of various embodiments will become better understood with reference to the following description and appended claims. The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments of the present disclosure and, together with the description, serve to explain the related principles.
Detailed discussion of embodiments directed to one of ordinary skill in the art are set forth in the specification, which makes reference to the appended figures, in which:
Reference now will be made in detail to embodiments, one or more examples of which are illustrated in the drawings. Each example is provided by way of explanation of the embodiments, not limitation of the present disclosure. In fact, it will be apparent to those skilled in the art that various modifications and variations can be made to the embodiments without departing from the scope or spirit of the present disclosure. For instance, features illustrated or described as part of one embodiment can be used with another embodiment to yield a still further embodiment. Thus, it is intended that aspects of the present disclosure cover such modifications and variations.
Example aspects of the present disclosure are directed to extending the lifetime of and arc lamp, specifically, the anode electrode of an arc lamp used in, for instance, a millisecond anneal system. Aspects of the present disclosure will be discussed with reference to arc lamps used in conjunction with millisecond anneal systems for purposes of illustration and discussion. Those of ordinary skill in the art, using the disclosures provided herein, will understand that aspects of the present disclosure can be used with arc lamps in other applications, such as for processing of metals (e.g., melting a surface of steel), and other applications.
In addition, aspects of the present disclosure are discussed with reference to a “wafer” or semiconductor wafer for purposes of illustration and discussion. Those of ordinary skill in the art, using the disclosures provided herein, will understand that the example aspects of the present disclosure can be used in association with any semiconductor substrate or other suitable substrate. The use of the term “about” in conjunction with a numerical value is intended to refer to within 10% of the stated numerical value.
Millisecond, or ultra-fast, thermal treatment of semiconductor wafers can be achieved using an intense and brief exposure of light (e.g., a “flash”) to heat the entire top surface of the wafer at rates that can exceed 104° C. per second. A typical heat treatment cycle can include: (a) loading a cold semiconductor substrate into the chamber; (b) purging the chamber with, for instance, nitrogen gas (atmospheric pressure); (c) heating the semiconductor substrate to an intermediate temperature Ti; (d) millisecond heating by flash exposure of the top surface of the semiconductor substrate, while the bulk of the wafer remains at Ti; (e) rapid cool down by conductive cooling of the top surface of the semiconductor substrate with the bulk of the semiconductor substrate being the conductively coupled heat sink; (f) slow cool down of the bulk of the semiconductor substrate by thermal radiation and convection, with the process gas at atmospheric pressure as cooling agent; and (g) transport the semiconductor substrate back to the cassette.
As discussed in detail below, arc lamps can be used to both heat the semiconductor substrate to an intermediate temperature Ti and to provide millisecond heating by flash. Continuous mode arc lamps located at the bottom side of the millisecond anneal processing chamber can be used to heat the semiconductor substrate to the intermediate temperature Ti. Flash arc lamps located at the top side of the millisecond anneal processing chamber can provide for the flash heating of the semiconductor substrate.
In some embodiments, the continuous mode lamps, like the flash arc lamps, can be open flow arc lamps, where pressurized Argon gas is converted into a high pressure Argon plasma during the arc discharge. The arc discharge takes place between a negatively charged cathode and a positively charge anode spaced, for instance, about 300 mm apart. As soon as the voltage between the electrodes reaches the breakdown voltage (e.g., about 30 kV) of Argon, a stable, low inductive Argon plasma is formed which emits light in the visible and UV range of the spectrum.
The amount of light energy the lamp radiates is controlled by controlling the current through the arc. In order to sustain the arc, the lamp can be operated in an idle mode with a current of about 20 A and corresponding electrical power of about 3.8 kW. To provide light, the lamp current can be increased to about 500 A (an electrical power of about 175 kW). About 50% of the electrical power is converted into light. During the heat treatment of the wafer, the lamp current can be varying between the idle condition and the high current condition. Lamps are in idle mode during wafer transport and cooling.
In the arc lamps, the plasma can be contained within a quartz tube envelope which is water cooled from the inside by a water wall. The water wall is injected at high flow rates on the cathode end of the lamp and exhausted at the anode end. The same is true for the Argon gas, which is also entering the lamp at the cathode side and exhausted from the anode side. The water forming the water wall is injected perpendicular to the lamp axis such that the centrifugal action generates a water vortex. Hence, along the center line of the lamp a channel is formed for the Argon gas. The Argon gas column is rotating in the same direction as the water wall. Once a plasma has formed, the water wall is protecting the quartz tube and confining the plasma to the center axis. Only the water wall and the electrodes are in direct contact with the high energy plasma.
As the electrodes experience a high heat load, the tips are made from tungsten, which is fused to a water cooled copper heat sink. The copper heat sink constitutes one part of the internal cooling system of the electrodes, with the other part being located in the brass base of the electrode.
At high currents (e.g., greater than about 300 A), the melting of the top layer of the tungsten tip of the electrode can be difficult to avoid. The tungsten tip of the anode electrode can be exposed to a high energy, high temperature, high pressure plasma. The tip reaches the melting temperature of tungsten (e.g., about 3422° C.), whereas the interface to the copper heat sink is at about 150° C. Hence, there can be a large thermal gradient through the thickness of the tungsten tip.
At the same time, there can also be lateral temperature gradient across the surface of the tip. Melting of tungsten occurs first in the center region and along the perimeter of the tip, the edge region. The high velocity of Argon gas acting on the tip, exerts a lateral force to the molten tungsten forming in the center. Molten tungsten is transported as drops to the edge and the center is thinned. At the edge perimeter the drops are getting pinned due to the sudden increase in contact angle (e.g., greater than about 180°).
During the idle mode phases the molten tungsten solidifies and beads are formed. Large size bead formation at the edge typically disturbs the gas and water flow around the anode, increasing the wear rate. For each heat treatment cycle the tungsten beads undergo melting and solidification. Large drops grow at the expense of the smaller drops. The high velocity gas flow exerts a higher force on large drops increasing the amount of material transported to the edge. The center thinning and the large bead formation on the edge is therefore accelerating over time.
According to example embodiments of the present disclosure, the geometry of the surface of the electrode tip is modified to reduce transportation of molten tungsten to the lateral edges. More particularly, the surface of the electrode tip can have one or more grooves to prevent the lateral transport of molten material.
For instance, in one example embodiment, a millisecond anneal system can include a processing chamber for thermally treating a semiconductor substrate using a millisecond anneal process. The system can include one or more arc lamp heat sources. Each of the one or more arc lamp heat sources can include a plurality of electrodes for generating an arc through a gas in the arc lamp to generate a plasma. At least one of the plurality of electrodes has an electrode tip (e.g., formed from tungsten) having a surface with at least one groove to reduce lateral transportation of molten material across the surface of the electrode tip.
In some embodiments, the at least one groove has a rim configured to act as a barrier to reduce the lateral transportation of molten material across the surface of the electrode tip. In some embodiments, the at least one groove includes a circular groove. In some embodiments, the at least one groove includes a plurality of concentric circular grooves. In some embodiments, the at least one groove includes a plurality of intersecting linear grooves. The intersecting linear grooves can form a square grid pattern. The intersecting linear grooves can form a triangular grid pattern.
In some embodiments, the electrode has an interface between the electrode tip (e.g., tungsten electrode tip) and a heat sink (e.g., copper heat sink). The interface can have a concave shape in some embodiments. The interface can have convex shape in some embodiments.
Another example aspect of the present disclosure is directed to an arc lamp. The arc lamp can include a plurality of electrodes and one or more inlets configured to receive water to be circulated through the arc lamp during operation. The one or more inlets can be configured to receive a gas. During operation of the arc lamp the gas can be converted to a plasma during an arc discharge between the plurality of electrodes. At least one of the plurality of electrodes can have an electrode tip. The electrode tip can have a surface with at least one groove to reduce lateral transportation of molten material across the surface of the electrode tip.
In some embodiments, the at least one groove has a rim configured to act as a barrier to reduce the lateral transportation of molten material across the surface of the electrode tip. In some embodiments, the at least one groove includes a circular groove. In some embodiments, the at least one groove includes a plurality of concentric circular grooves. In some embodiments, the at least one groove includes a plurality of intersecting linear grooves. The intersecting linear grooves can form a square grid pattern. The intersecting linear grooves can form a triangular grid pattern.
In some embodiments, the electrode has an interface between the electrode tip (e.g., tungsten electrode tip) and a heat sink (e.g., copper heat sink). The interface can have a concave shape in some embodiments. The interface can have convex shape in some embodiments.
Another example aspect of the present disclosure is directed to an arc lamp. The arc lamp can include a plurality of electrodes and one or more inlets configured to receive water to be circulated through the arc lamp during operation. The one or more inlets can be configured to receive a gas. During operation of the arc lamp the gas can be converted to a plasma during an arc discharge between the plurality of electrodes. At least one of the plurality of electrodes can have an electrode tip and a heat sink. The electrode can have an interface between the electrode tip and the heat sink that is concave or convex.
In some embodiments, the interface can be a faceted concave interface. In some embodiments, the interface can be a rounded concave interface. In some embodiments, the interface can be a faceted convex interface. In some embodiments, the interface can be a faceted concave interface. In some embodiments, the electrode tip includes tungsten and the heat sink includes copper.
An example millisecond anneal system can be configured to provide an intense and brief exposure of light to heat the top surface of a wafer at rates that can exceed, for instance, about 104° C./s.
An example millisecond anneal system can include a plurality of arc lamps (e.g., four Argon arc lamps) as light sources for intense millisecond long exposure of the top surface of the semiconductor substrate—the so called “flash.” The flash can be applied to the semiconductor substrate when the substrate has been heated to an intermediate temperature (e.g., about 450° C. to about 900° C.). A plurality of continuous mode arc lamps (e.g., two Argon arc lamps) can be used to heat the semiconductor substrate to the intermediate temperature. In some embodiments, the heating of the semiconductor substrate to the intermediate temperature can be accomplished through the bottom surface of the semiconductor substrate at a ramp rate which heats the entire bulk of the wafer.
As shown in
A plurality of continuous mode arc lamps 240 (e.g., two Argon arc lamps) located proximate the bottom chamber 204 can be used to heat the semiconductor substrate 60 to the intermediate temperature. In some embodiments, the heating of the semiconductor substrate 60 to the intermediate temperature is accomplished from the bottom chamber 204 through the bottom surface of the semiconductor substrate at a ramp rate which heats the entire bulk of the semiconductor substrate 60.
As shown in
As further illustrated in
The temperature uniformity of the semiconductor substrate can be controlled by manipulating the light density falling onto different regions of the semiconductor substrate. In some embodiments, uniformity tuning can be accomplished by altering the reflection grade of small size reflectors to the main reflectors and/or by use of edge reflectors mounted on the wafer support plane surrounding the wafer.
For instance, edge reflectors can be used to redirect light from the bottom lamps 240 to an edge of the semiconductor substrate 60. As an example,
In some embodiments, additional reflectors can also be mounted on chamber walls near the wafer plane plate 210. For example,
In some embodiments, as the electrodes experience a high heat load, one or more of the electrodes can each include a tip 232. The tip can be made from tungsten. The tip can be coupled to and/or fused to a water cooled copper heat sink 234. The copper heat sink 234 can include at least a portion the internal cooling system of the electrodes (e.g., one or more water cooling channels 236. The electrodes can further include a brass base 235 with water cooling channels 236 to provide for the circulation of water or other fluid and the cooling of the electrodes.
The arc lamps used in example millisecond anneal systems according to aspects of the present disclosure can be an open flow system for water and Argon gas. However, for conservation reasons, both media can be circulated in a close loop system in some embodiments. In some embodiments, nitrogen gas can be injected into the arc lamp during operation to control the pH of water circulating through the arc lamp during operation. An example water loop system will be discussed in detail with respect to
Millisecond anneal systems according to example embodiments of the present disclosure can include the ability to independently measure temperature of both surfaces (e.g., the top and bottom surfaces) of the semiconductor substrate.
A simplified representation of the millisecond anneal system 200 is shown in
The readings of the temperature sensors 152 and 154 can be emissivity compensated. As shown in
In some embodiments, the millisecond anneal system 200 can include water windows. The water windows can provide an optical filter that suppresses lamp radiation in the measurement band of the temperature sensors 152 and 154 so that the temperature sensors 152 and 154 only measure radiation from the semiconductor substrate.
The readings of the temperature sensors 152 and 154 can be provided to a processor circuit 160. The processor circuit 10 can be located within a housing of the millisecond anneal system 200, although alternatively, the processor circuit 160 may be located remotely from the millisecond anneal system 200. The various functions described herein may be performed by a single processor circuit if desired, or by other combinations of local and/or remote processor circuits.
According to example aspects of the present disclosure, the life of an anode, cathode or other electrode used in arc lamps can be extended by mitigating the material loss of molten tungsten. The lifetime of the electrode can be directly correlated to the loss rate of molten tungsten in the center of the electrode tip. According to example aspects of the present disclosure, the geometry of the electrode is configured to locally keep tungsten in the center of the tip and prevent transport from the center to the tip edge. An additional effect can be to prevent the large bead formation on the edge perimeter of the tip, thus maintaining an undisturbed flow pattern around the anode.
In one example embodiment of the present disclosure, the transport of molten tungsten is reduced by modifying the geometry of the tungsten tip surface such that the surface includes one or more circular grooves. A purpose of the circular grooves can be to keep the bead formation localized and act as a barrier to the lateral transport of molten material. Hence, the transport of material is limited by way of the surface structure. The transport is reduced until the molten drop reaches a critical size, at which time the aerodynamical forces dominate the adhesion forces, and the drop flows over the barrier. Bead size can be automatically lowered by the flow action and the process can repeat itself at the next barrier. As a result, the dwell time of the molten material can be extended over the nominal case with flat surface structure.
In the embodiment of
The surface of an electrode tip according to example aspects of the present disclosure can have a variety of different groove patterns to impair the lateral flow of molten material from a center portion of the electrode tip to an edge portion of the electrode tip. For instance, in some embodiments, the electrode tip can include concentric circular grooves. In some embodiments, the concentric circular grooves are not equidistant from the center of the electrode tip.
In some embodiments, the groove pattern can include a plurality of intersecting linear grooves disposed across a surface of the electrode tip. The plurality of intersecting linear grooves can form a grid of lines. The intersecting angle between the grooves can be, for instance, in the range of about 10° to 180°.
In some embodiments, a shape of the tungsten-copper interface between an electrode tip and a heat sink of an electrode used in an arc lamp is designed to influence the lateral temperature distribution across the electrode tip. The lateral heat distribution across the surface of an electrode tip can have impact on the lifetime of the anode by reducing the flow of molten material across the surface, and by reducing the heat load density.
To provide for reducing the flow of molten material across the surface of the electrode tip, a large lateral temperature gradient can be desired, with the edge of the tip being much colder than the center of the tip. In the case where the edge of the tip remains below the melting point of tungsten, the lateral transport of molten material can be inhibited, and the drops and beads can remain localized in the center.
To provide for reducing the heat load density, a low lateral temperature gradient can be desired. With a low temperature gradient, the heat load is evenly distributed across the tip surface and local overheating is mitigated.
The lateral temperature distribution across the surface of the electrode tip can a function of the amount of heat conducted through the electrode tip. The thermal conductivity can be a function of the distance between the surface of the electrode tip and the interface between the electrode tip and a heat sink coupled to the electrode tip. For a flat interface, the distance for the heat conduction is increasing center to edge for geometric reasons. For a concave shaped interface, the increase in distance is smaller from center to edge, hence the temperature gradient is lower. The reverse is true for a convex shaped interface.
According to example aspects of the present disclosure, the interface between electrode tip (e.g., tungsten electrode tip) and the heat sink (e.g., the copper heat sink) is facetted or rounded.
While the present subject matter has been described in detail with respect to specific example embodiments thereof, it will be appreciated that those skilled in the art, upon attaining an understanding of the foregoing may readily produce alterations to, variations of, and equivalents to such embodiments. Accordingly, the scope of the present disclosure is by way of example rather than by way of limitation, and the subject disclosure does not preclude inclusion of such modifications, variations and/or additions to the present subject matter as would be readily apparent to one of ordinary skill in the art.
The present application claims the benefit of priority of U.S. Provisional Application Ser. No. 62/272,921, filed on Dec. 30, 2015, entitled “Lamp Electrode Tip for a Millisecond Anneal System.”
Number | Date | Country | |
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62272921 | Dec 2015 | US |