This application is based on and claims priority under 35 U.S.C. § 119 to Korean Patent Application No. 10-2022-0149356, filed on Nov. 10, 2022, in the Korean Intellectual Property Office, the disclosure of which is incorporated by reference herein in its entirety.
The present inventive concepts relate to field effect transistors, capacitors, and electronic apparatuses each including a domain-controlled ferroelectric material.
As the degree of integration of electronic apparatuses, such as memories or logic circuits, increases, electronic elements in the electronic apparatuses are becoming smaller in size. Accordingly, there is an increasing demand for downsizing and reducing the power consumption of electronic elements, such as transistors or capacitors. However, because the capacitance of a capacitor is proportional to the area of the capacitor, the capacitance may decrease as the size of the capacitor is reduced. When a thickness of a dielectric is reduced so as to increase the capacitance, a leakage current may increase. Accordingly, dielectric materials having a high dielectric constant (high-k) have been used in electronic apparatuses.
Some example embodiments provide a field effect transistor, a capacitor, and/or an electronic apparatus each including a domain-controlled ferroelectric material. Such a field effect transistor, a capacitor, and/or an electronic apparatus may be configured to more effectively control domain characteristics of the ferroelectric material to effectively exhibit negative capacitance characteristics, to thereby enable novel low power apparatuses having improved (e.g., reduced) power consumption.
Some example embodiments provide a field effect transistor, a capacitor, and/or an electronic apparatus with improved low power characteristics and leakage current characteristics.
Additional aspects will be set forth in part in the description which follows and, in part, will be apparent from the description, or may be learned by practice of the presented embodiments of the present inventive concepts.
A field effect transistor according to some example embodiments includes: a source region; a drain region; a channel between the source region and the drain region; a gate insulating layer configured to cover an upper surface of the channel; and a gate electrode configured to cover an upper surface of the gate insulating layer, wherein the gate insulating layer includes a first region where a ferroelectric crystal structure is dominant and a second region where a non-ferroelectric structure is dominant, and the gate electrode includes a first pattern region facing the first region of the gate insulating layer and a second pattern region facing the second region of the gate insulating layer.
The gate insulating layer may include a plurality of first regions that are spaced apart from each other and two-dimensionally arranged in a horizontal direction that is parallel to the upper surface of the channel or a lower surface of the gate electrode, and the second region of the gate insulating layer may be between the plurality of first regions on a same plane as the plurality of first regions.
The second region of the gate insulating layer may be between at least two adjacent first regions of the plurality of first regions, such that the at least two adjacent first regions are separated from each other by at least the second region.
For example, an area of each of the plurality of first regions in a horizontal plane that is parallel to the upper surface of the channel or the lower surface of the gate electrode may be greater than or equal to about 0.25 nm2 and less than or equal to about 1 μm.
The gate insulating layer include a plurality of first regions having a stripe shape extending in a first direction and a plurality of second regions having a stripe shape extending in the first direction. The plurality of first regions and the plurality of second regions may be alternately arranged in a second direction that is perpendicular to the first direction within a plane of the gate insulating layer.
A width of each region of the plurality of first regions and the plurality of second regions in the second direction may be about 0.5 nm or more and about 1 μm or less.
The gate insulating layer may include at least one of hafnium oxide, lead zirconate titanate (PZT), or zinc oxide, and the hafnium oxide may be doped with at least one element selected from zirconium (Zr), silicon (Si), aluminum (Al), lanthanum (La), gadolinium (Gd), and yttrium (Y).
For example, in the first region, a proportion of the ferroelectric crystal structure may be about 65 at % or more and a proportion of the non-ferroelectric structure may be about 35 at % or less, and in the second region, a proportion of the ferroelectric crystal structure may be about 35 at % or less and a proportion of the non-ferroelectric structure may be about 65 at % or more.
For example, in the first region, a proportion of orthorhombic crystals may be about 65 at % or more and a proportion of a sum of monoclinic crystals, tetragonal crystals, and amorphous structures may be about 35 at % or less, and in the second region, a proportion of orthorhombic crystals may be about 35 at % or less and a proportion of a sum of monoclinic crystals, tetragonal crystals, and amorphous structures may be about 65 at % or more.
The first pattern region of the gate electrode may include a first conductive material, and the second pattern region of the gate electrode may include a second conductive material having a thermal expansion coefficient that is different from a thermal expansion coefficient of the first conductive material.
The first pattern region of the gate electrode may include a plurality of first conductive materials that may be spaced apart from each other and two-dimensionally arranged in a direction parallel to the upper surface of the gate insulating layer within a plane of the gate electrode, and the second conductive material may be between the plurality of first conductive materials on a same plane as the plurality of first conductive materials.
The first pattern region of the gate electrode may include a plurality of first conductive materials having a stripe shape extending in a first direction. The second pattern region of the gate electrode may include a plurality of second conductive materials having a stripe shape extending in the first direction. The plurality of first conductive materials and the plurality of second conductive materials may be alternately arranged in a second direction perpendicular to the first direction within a plane of the gate electrode.
The first conductive material and the first region may be in direct contact with each other in a vertical direction that is perpendicular to the upper surface of the channel or a lower surface of the gate electrode, and second conductive material and the second region may be in direct contact with each other in the vertical direction.
The field effect transistor may further include a non-ferroelectric layer between the channel and the gate insulating layer, wherein the non-ferroelectric layer may include at least one of a paraelectric material, an antiferroelectric material, or an amorphous material.
The field effect transistor may further include a non-ferroelectric layer between the gate insulating layer and the gate electrode, wherein the non-ferroelectric layer may include at least one of a paraelectric material, an antiferroelectric material, or an amorphous material.
The field effect transistor may further include a substrate, wherein the channel may have a rod shape protruding and extending from an upper surface of the substrate, wherein the gate insulating layer may cover and surround three sides of the channel, and wherein the gate electrode may cover and surround three sides of the gate insulating layer.
The gate insulating layer may include a plurality of first regions extending along a surface of the channel in a stripe shape surrounding the three sides of the channel and a plurality of second regions extending along the surface of the channel in a stripe shape surrounding the three sides of the channel. The plurality of first regions and the plurality of second regions may be alternately arranged.
A capacitor according to some example embodiments includes: a first electrode; a second electrode facing the first electrode; and a dielectric layer between the first electrode and the second electrode, wherein the dielectric layer includes a first region where a ferroelectric crystal structure is dominant and a second region where a non-ferroelectric structure is dominant, and the second electrode includes a first pattern region facing the first region of the dielectric layer and a second pattern region facing the second region of the dielectric layer.
The capacitor may further include a non-ferroelectric layer that is between the first electrode and the dielectric layer or between the second electrode and the dielectric layer.
An electronic apparatus according to some example embodiments includes: a field effect transistor; and a capacitor electrically connected to the field effect transistor, wherein the field effect transistor includes: a source region; a drain region; a channel between the source region and the drain region; a gate insulating layer configured to cover an upper surface of the channel; and a gate electrode configured to cover an upper surface of the gate insulating layer, the gate insulating layer includes a first region where a ferroelectric crystal structure is dominant and a second region where a non-ferroelectric structure is dominant, and the gate electrode includes a first pattern region facing the first region of the gate insulating layer and a second pattern region facing the second region of the gate insulating layer.
The above and other aspects, features, and advantages of some example embodiments of the present inventive concepts will be more apparent from the following description taken in conjunction with the accompanying drawings, in which:
Reference will now be made in detail to some example embodiments, examples of which are illustrated in the accompanying drawings, wherein like reference numerals refer to like elements throughout. In this regard, some example embodiments may have different forms and should not be construed as being limited to the descriptions set forth herein. Accordingly, some example embodiments are merely described below, by referring to the figures, to explain aspects. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items. Expressions such as “at least one of,” when preceding a list of elements, modify the entire list of elements and do not modify the individual elements of the list.
Hereinafter, a field effect transistor, a capacitor, and an electronic apparatus each including a domain-controlled ferroelectric material will be described in detail with reference to the accompanying drawings. In the following drawings, the same reference numerals denote the same elements, and the size of each element in the drawings may be exaggerated for clarity and convenience of explanation. In addition, embodiments described herein are merely examples, and various modifications may be made thereto from some example embodiments.
Hereinafter, the terms “above” or “on” may include not only those that are directly on in a contact manner, but also those that are above in a non-contact manner. The singular forms “a,” “an,” and “the” as used herein are intended to include the plural forms as well unless the context clearly indicates otherwise. It will be understood that the terms “comprise,” “include,” or “have” as used herein specify the presence of stated elements, but do not preclude the presence or addition of one or more other elements.
The use of the term “the” and similar demonstratives may correspond to both the singular and the plural. Operations constituting methods may be performed in any suitable order unless otherwise indicated herein or otherwise clearly contradicted by context, and are not necessarily limited to the stated order.
Also, the terms such as “unit” and “module” described in the specification mean units that process at least one function or operation, and may be implemented as hardware, software, or a combination of hardware and software.
Connecting lines or connecting members illustrated in the drawings are intended to represent example functional relationships and/or physical or logical connections between the various elements. It should be noted that many alternative or additional functional relationships, physical connections or logical connections may be present in a practical device.
The use of all illustrations or illustrative terms in some example embodiments is simply to describe the technical ideas in detail, and the scope of the present inventive concepts is not limited by the illustrations or illustrative terms unless they are limited by claims.
It will be understood that elements and/or properties thereof (e.g., structures, surfaces, directions, or the like), which may be referred to as being “perpendicular,” “parallel,” “coplanar,” or the like with regard to other elements and/or properties thereof (e.g., structures, surfaces, directions, or the like) may be “perpendicular,” “parallel,” “coplanar,” or the like or may be “substantially perpendicular,” “substantially parallel,” “substantially coplanar,” respectively, with regard to the other elements and/or properties thereof.
Elements and/or properties thereof (e.g., structures, surfaces, directions, or the like) that are “substantially perpendicular” with regard to other elements and/or properties thereof will be understood to be “perpendicular” with regard to the other elements and/or properties thereof within manufacturing tolerances and/or material tolerances and/or have a deviation in magnitude and/or angle from “perpendicular,” or the like with regard to the other elements and/or properties thereof that is equal to or less than 10% (e.g., a. tolerance of ±10%).
Elements and/or properties thereof (e.g., structures, surfaces, directions, or the like) that are “substantially parallel” with regard to other elements and/or properties thereof will be understood to be “parallel” with regard to the other elements and/or properties thereof within manufacturing tolerances and/or material tolerances and/or have a deviation in magnitude and/or angle from “parallel,” or the like with regard to the other elements and/or properties thereof that is equal to or less than 10% (e.g., a. tolerance of ±10%).
Elements and/or properties thereof (e.g., structures, surfaces, directions, or the like) that are “substantially coplanar” with regard to other elements and/or properties thereof will be understood to be “coplanar” with regard to the other elements and/or properties thereof within manufacturing tolerances and/or material tolerances and/or have a deviation in magnitude and/or angle from “coplanar,” or the like with regard to the other elements and/or properties thereof that is equal to or less than 10% (e.g., a. tolerance of ±10%)).
It will be understood that elements and/or properties thereof may be recited herein as being “the same” or “equal” as other elements, and it will be further understood that elements and/or properties thereof recited herein as being “identical” to, “the same” as, or “equal” to other elements may be “identical” to, “the same” as, or “equal” to or “substantially identical” to, “substantially the same” as or “substantially equal” to the other elements and/or properties thereof. Elements and/or properties thereof that are “substantially identical” to, “substantially the same” as or “substantially equal” to other elements and/or properties thereof will be understood to include elements and/or properties thereof that are identical to, the same as, or equal to the other elements and/or properties thereof within manufacturing tolerances and/or material tolerances. Elements and/or properties thereof that are identical or substantially identical to and/or the same or substantially the same as other elements and/or properties thereof may be structurally the same or substantially the same, functionally the same or substantially the same, and/or compositionally the same or substantially the same.
It will be understood that elements and/or properties thereof described herein as being “substantially” the same and/or identical encompasses elements and/or properties thereof that have a relative difference in magnitude that is equal to or less than 10%. Further, regardless of whether elements and/or properties thereof are modified as “substantially,” it will be understood that these elements and/or properties thereof should be construed as including a manufacturing or operational tolerance (e.g., ±10%) around the stated elements and/or properties thereof.
When the terms “about” or “substantially” are used in this specification in connection with a numerical value, it is intended that the associated numerical value include a tolerance of ±10% around the stated numerical value. When ranges are specified, the range includes all values therebetween such as increments of 0.1%.
While the term “same,” “equal” or “identical” may be used in description of some example embodiments, it should be understood that some imprecisions may exist. Thus, when one element is referred to as being the same as another element, it should be understood that an element or a value is the same as another element within a desired manufacturing or operational tolerance range (e.g., ±10%).
When the terms “about” or “substantially” are used in this specification in connection with a numerical value, it is intended that the associated numerical value includes a manufacturing or operational tolerance (e.g., ±10%) around the stated numerical value. Moreover, when the words “about” and “substantially” are used in connection with geometric shapes, it is intended that precision of the geometric shape is not required but that latitude for the shape is within the scope of the disclosure. Further, regardless of whether numerical values or shapes are modified as “about” or “substantially,” it will be understood that these values and shapes should be construed as including a manufacturing or operational tolerance (e.g., ±10%) around the stated numerical values or shapes. When ranges are specified, the range includes all values therebetween such as increments of 0.1%.
As described herein, when an operation is described to be performed, or an effect such as a structure is described to be established “by” or “through” performing additional operations, it will be understood that the operation may be performed and/or the effect/structure may be established “based on” the additional operations, which may include performing said additional operations alone or in combination with other further additional operations.
As described herein, an element that is described to be “spaced apart” from another element, in general and/or in a particular direction (e.g., vertically spaced apart, laterally spaced apart, etc.) and/or described to be “separated from” the other element, may be understood to be isolated from direct contact with the other element, in general and/or in the particular direction (e.g., isolated from direct contact with the other element in a vertical direction, isolated from direct contact with the other element in a lateral or horizontal direction, etc.). Similarly, elements that are described to be “spaced apart” from each other, in general and/or in a particular direction (e.g., vertically spaced apart, laterally spaced apart, etc.) and/or are described to be “separated” from each other, may be understood to be isolated from direct contact with each other, in general and/or in the particular direction (e.g., isolated from direct contact with each other in a vertical direction, isolated from direct contact with each other in a lateral or horizontal direction, etc.). Similarly, a structure described herein to be between two other structures to separate the two other structures from each other may be understood to be configured to isolate the two other structures from direct contact with each other.
Although not illustrated, the field effect transistor 100 may further include a source electrode and a drain electrode respectively on the source region 102 and the drain region 103. In addition, additional functional layers may be further between the source region 102 and the source electrode and between the drain region 103 and the drain electrode so as to reduce contact resistance between a semiconductor and a metal or reduce, minimize, or prevent diffusion of a metal.
The source region 102 and the drain region 103 may each be doped with a first conductivity type (e.g., doped with dopants having the first conductivity type), and the substrate 101 may be doped with a second conductivity type (e.g., doped with dopants having the second conductivity type) electrically opposite to the first conductivity type. For example, the substrate 101 may include a p-type semiconductor and the source region 102 and the drain region 103 may each include an n-type semiconductor. In some example embodiments, the substrate 101 may include an n-type semiconductor and the source region 102 and the drain region 103 may each include a p-type semiconductor. The substrate 101 may be doped with a relatively low concentration of about 1014/cm3 to about 1018/cm3, and the source region 102 and the drain region 103 may each be doped with a relatively high concentration of about 1019/cm3 to 1021/cm3 for low resistance. The source region 102 and the drain region 103 may be respectively formed by doping impurities into both sides (e.g., opposite sides) of the upper portion of the substrate 101. The upper portion of the substrate 101, in which the source region 102 and the drain region 103 are not formed, may be defined as the channel 104. Accordingly, the channel 104 may be between the source region 102 and the drain region 103.
The substrate 101, the source region 102, and the drain region 103 may include, for example, at least one semiconductor material selected from Group IV semiconductors, such as silicon (Si), germanium (Ge), or SiGe, Group III-V compound semiconductors, such as GaAs or GaP, Group II-VI compound semiconductors, oxide semiconductors, and/or two-dimensional material semiconductors. When the substrate 101, the source region 102, and the drain region 103 each include Si, Ge, SiGe, or the like, the substrate 101 may be doped with at least one dopant selected from boron (B), aluminum (Al), gallium (Ga), and indium (In), and the source region 102 and the drain region 103 may each be doped with at least one dopant selected from lead (Pb), arsenic (As), and stibium (Sb). In this case, the field effect transistor 100 is an n-channel metal-oxide semiconductor field effect transistor (NMOS). In contrast, the substrate 101 may be doped with at least one dopant selected from lead (Pb), arsenic (As), and stibium (Sb), and the source region 102 and the drain region 103 may each be doped with at least one dopant selected from B, Al, Ga, and In. In this case, the field effect transistor 100 is a p-channel metal-oxide semiconductor field effect transistor (PMOS).
The gate electrode 106 may have a conductivity of about 1 M ohm/square or less (e.g., about 0.01 ohm/square to about 1.00 M ohm/square). The gate electrode 106 may include at least one conductive material selected from a metal, metal nitride, metal carbide, polysilicon, and any combination thereof. For example, the metal may include aluminum (Al), tungsten (W), molybdenum (Mo), titanium (Ti), or tantalum (Ta), the metal nitride layer may include a titanium nitride (TiN) layer, or a tantalum nitride (TaN) layer, and the metal carbide may include an aluminum- or silicon-doped (containing) metal carbide. As a specific example, the metal carbide may include TiAlC, TaAlC, TiSiC, or TaSiC. The gate electrode 106 may have a structure in which a plurality of materials are stacked. For example, the gate electrode 106 may have a stacked metal nitride layer/metal layer structure, such as TiN/AI, or a stacked metal nitride layer/metal carbide layer/metal layer structure, such as TiN/TiAlC/W. The gate electrode 106 may include titanium nitride (TiN) or molybdenum (Mo) and may be variously modified. The gate electrode 106 may include a conductive two-dimensional material in addition to the materials described above. For example, the conductive two-dimensional material may include at least one of graphene, black phosphorus, amorphous boron nitride, two-dimensional hexagonal boron nitride (h-BN), or phosphorene.
The gate insulating layer 105 may include a ferroelectric material. For example, the gate insulating layer 105 may include a ferroelectric material having a fluorite structure, a perovskite structure, and/or a wurtzite structure. The ferroelectric material having the fluorite structure may include, for example, hafnium oxide (HfO2). The hafnium oxide may be doped with at least one element selected from, for example, zirconium (Zr), silicon (Si), aluminum (Al), lanthanum (La), gadolinium (Gd), and yttrium (Y). In addition, the ferroelectric material having the perovskite structure may include, for example, lead zirconate titanate (PZT). The ferroelectric material having the wurtzite structure may include, for example, zinc oxide (ZnO).
The ferroelectric material may have a non-linear relationship between electric field and polarization. In particular, an inverse relationship may be formed between electric field and polarization in a section in which a polarization direction changes. A negative capacitance phenomenon may appear in this section. However, because pure ferroelectric materials have high free energy in this section and are thus unstable, it is difficult to observe an actual negative capacitance phenomenon.
According to some example embodiments, in order to implement optimal or improved negative capacitance characteristics, the gate insulating layer 105 may have a plurality of regions where ferroelectric materials and paraelectric or antiferroelectric materials are locally distributed. For example, the gate insulating layer 105 may include a plurality of first regions 105a and a plurality of second regions 105b between the first regions 105a. The first regions 105a and the second regions 105b may be arranged within a plane of the gate insulating layer 105. In other words, the first regions 105a and the second regions 105b may be arranged in a direction (e.g., horizontal direction), plane (e.g., horizontal plane), or the like parallel to the lower surface of the gate electrode 106 or the upper surface of the channel 104 contacting the gate insulating layer 105.
Referring to
Referring to
In some example embodiments, the gate electrode 106 may include first pattern regions P1 and second pattern regions P2 respectively matching (e.g., overlapping in a vertical direction that is perpendicular to the upper surface of the channel 104 or the lower surface of the gate electrode 106) the first regions 105a and the second regions 105b of the gate insulating layer 105. The first pattern regions P1 and the second pattern regions P2 may include the same conductive material and may be distinguished by a step. The size and shape of the first pattern region P1 may match the size and shape of the first region 105a of the gate insulating layer 105, and the size and shape of the second pattern region P2 may match the size and shape of the second region 105b of the gate insulating layer 105. For example, like the first regions 105a and the second regions 105b of the gate insulating layer 105 illustrated in
The first pattern regions P1 and the second pattern regions P2 of the gate electrode 106 may be formed in the process of forming the first regions 105a and the second regions 105b of the gate insulating layer 105 according to a method illustrated in
According to some example embodiments, the size, shape, arrangement, number, and composition of the first regions 105a and the second regions 105b in the gate insulating layer 105 may be controlled so that the gate insulating layer 105 has optimal or improved negative capacitance characteristics. For example, in the example of
In addition, according to some example embodiments, the first region 105a may be a domain-controlled region where a ferroelectric crystal structure is dominant, and the second region 105b may be a domain-controlled region where a non-ferroelectric (e.g., paraelectric, antiferroelectric, or amorphous) structure is dominant. In some example embodiments, a region where a ferroelectric crystal structure is dominant is a region, structure, layer, or the like in which the ferroelectric crystal structure comprises a majority (e.g., the proportion of the ferroelectric crystal structure is more than 50%) by volume and/or mass of the total material composition of the region, structure, layer, or the like and the non-ferroelectric crystal structure comprises a minority (e.g., the proportion of the non-ferroelectric crystal structure is less than 50%) by volume and/or mass of the total material composition of the region, structure, layer, or the like. In some example embodiments, a region where a non-ferroelectric crystal structure is dominant is a region, structure, layer, or the like in which the non-ferroelectric crystal structure comprises a majority (e.g., the proportion of the non-ferroelectric crystal structure is more than 50%) by volume and/or mass of the total material composition of the region, structure, layer, or the like and the ferroelectric crystal structure comprises a minority (e.g., the proportion of the ferroelectric crystal structure is less than 50%) by volume and/or mass of the total material composition of the region, structure, layer, or the like. For example, in the first region 105a, the proportion of the ferroelectric crystal structure may be about 65 at % or more or about 80 at % or more and the proportion of the non-ferroelectric structure may be about 35 at % or less or about 20 at % or less. In addition, in the second region 105b, the proportion of the ferroelectric crystal structure may be about 35 at % or less or about 20 at % or less and the proportion of the non-ferroelectric structure may be about 65 at % or more or about 80 at % or more. In another example, in the first region 105a, the proportion of the ferroelectric crystal structure may be about 51 at % or more or and the proportion of the non-ferroelectric structure may be about 49 at % or less, and, in the second region 105b, the proportion of the ferroelectric crystal structure is about 49 at % or less and the proportion of the non-ferroelectric structure may be about 51 at % or more. In some example embodiments, the first region 105a may be a domain-controlled region where a non-ferroelectric structure is dominant, and the second region 105b may be a domain-controlled region where a ferroelectric crystal structure is dominant. It will be understood that, in a region where the ferroelectric crystal structure is dominant, the proportion of the non-ferroelectric structure may be about 0.01 at % or more, 0.1 at % or more, 1 at % or more, or the like. It will be understood that, in a region where the non-ferroelectric crystal structure is dominant, the proportion of the ferroelectric structure may be about 0.01 at % or more, 0.1 at % or more, 1 at % or more, or the like.
In view of at least the above, it will be understood that a field effect transistor 100 may be configured to implement optimal or improved negative capacitance characteristics based on the field effect transistor 100 including at least a gate insulating layer 105 with a first region 105a where a ferroelectric crystal structure is dominant and a second region 105b where a non-ferroelectric structure is dominant, thereby configuring the field effect transistor 100 to have improved low power characteristics and leakage current characteristics, reduced power consumption, or the like. The field effect transistor 100 may thus have improved operation performance and/or efficiency, together with reduced size (e.g., improved downscaling, compactness, etc.) and thus may be configured to enable an electronic apparatus architecture, electronic device, or the like including the field effect transistor 100 to have improved operational performance and/or efficiency (e.g., improved low power characteristics and leakage current characteristics) together with improved downscaling (e.g., improved compactness).
Referring to
Thereafter, still referring to
Referring to
Referring to
Thereafter, still referring to
Then, as a result of the PMA process at S1910, most (e.g., more than 50% by volume and/or by mass) of the gate insulating layer material 105′ under the gate electrode pattern 106′ has ferroelectric characteristics, and most (e.g., more than 50% by volume and/or by mass) of the gate insulating layer material 105′ between (e.g., horizontally between, vertically offset and exposed from, etc.) the gate electrode patterns 106′ has antiferroelectric characteristics. Accordingly, the gate insulating layer 105 including the first region 105a, the domain of which is controlled so that the ferroelectric crystal structure is dominant, and the second region 105b, the domain of which is controlled so that the non-ferroelectric structure is dominant may be formed. For example, in the first region 105a, the proportion of the orthorhombic crystals may be about 65 at % or more or about 80 at % or more and the proportion of the sum of the monoclinic crystals, the tetragonal crystals, and the amorphous structure may be about 35 at % or less or about 20 at % or less. In addition, in the second region 105b, the proportion of the orthorhombic crystals is about 35 at % or less or about 20 at % or less, and the proportion of the sum of the monoclinic crystals, the tetragonal crystals, and the amorphous structure may be about 65 at % or more or about 80 at % or more. In another example, in the first region 105a, the proportion of the orthorhombic crystals may be about 51 at % or more and the proportion of the sum of the monoclinic crystals, the tetragonal crystals, and the amorphous structure may be about 49 at % or less, and, in the second region 105b, the proportion of the orthorhombic crystals is about 49 at % or less and the proportion of the sum of the monoclinic crystals, the tetragonal crystals, and the amorphous structure may be about 51 at % or more. It will be understood that, in a region where the proportion of the orthorhombic crystals is about 51 at % or more, the proportion of the sum of the monoclinic crystals, the tetragonal crystals, and the amorphous structure may be about 0.01 at % or more, 0.1 at % or more, 1 at % or more, or the like. It will be understood that, in a region where the proportion of the sum of the monoclinic crystals, the tetragonal crystals, and the amorphous structure is about 51 at % or more, the proportion of the orthorhombic crystals may be about 0.01 at % or more, 0.1 at % or more, 1 at % or more, or the like.
However, the present inventive concepts are not necessarily limited thereto, the position where the crystal structure of the gate insulating layer material 105′ changes may vary depending on the thermal expansion coefficient of the gate electrode pattern 106′ and the thermal expansion coefficient of the material of the filler 107 between the gate electrode patterns 106′. For example, when tensile stress applied to the gate insulating layer material 105′ by the material of the filler 107 between the gate electrode patterns 106′ is greater than tensile stress applied to the gate insulating layer material 105′ by the gate electrode pattern 106′, the crystal structure of the gate insulating layer material 105′ under the gate electrode pattern 106′ may hardly change during the PMA process, and the crystal structure of the gate insulating layer material 105′ between the gate electrode patterns 106′ may change to an orthorhombic crystal structure. In this case, the non-ferroelectric structure may be dominant in the first region 105a under the gate electrode pattern 106′, and the ferroelectric crystal structure may be dominant in the second region 105b between the gate electrode patterns 106′.
After the gate insulating layer 105 is formed, still referring to
While the process S1902 is described above with reference to manufacturing a field effect transistor as shown in
Still referring to
The first conductive material 106a may be disposed above the first region 105a of the gate insulating layer 105, and the second conductive material 106b may be disposed above the second region 105b of the gate insulating layer 105. In other words, the first conductive material 106a and the first region 105a are in direct contact with each other in the vertical direction (i.e., the third direction), and the second conductive material 106b and the second region 105b may be in direct contact with each other in the third direction. Accordingly, the arrangement of the first conductive material 106a and the second conductive material 106b may be the same as the arrangement of the first region 105a and the second region 105b. The first conductive material 106a and the second conductive material 106b may be arranged within the plane of the gate electrode 106. In other words, the first conductive material 106a and the second conductive material 106b may be arranged in a direction parallel to the upper surface of the gate insulating layer 105 that is in contact with the gate electrode 106.
For example,
Referring to
The first conductive materials 106a may be deposited in the process illustrated in
In addition, referring to
Although the field effect transistors 100, 100a, 100b, and 100c are illustrated as having the planar channel 104, the present inventive concepts are not necessarily limited thereto. For example, the principle described above may also be applied to a fin field effect transistor (FinFET), a gate-all-around FET (GAAFET), or a multi bridge channel FET (MBCFET) each having a three-dimensional channel structure.
The field effect transistor 200a illustrated in
The domain-controlled ferroelectric material described above may also be applied not only to field effect transistors but also to other electronic apparatuses, such as capacitors. For example,
The configurations and the manufacturing methods of the capacitors 300, 300a, and 300b illustrated in
According to some example embodiments described above, the domains of the ferroelectric material may be easily controlled in a desired shape by patterning the electrode on the ferroelectric material and then performing PMA thereon. For example, the size, number, and distribution of the domains may be easily controlled according to the shape of the gate electrode pattern 106′. Therefore, negative capacitance characteristics may be improved through the domain control of the ferroelectric material. By using negative capacitance characteristics of the ferroelectric material, the field effect transistor, the capacitor, and the electronic apparatus (collectively, one or more devices according to any of the example embodiments), which are capable of being ultra-miniaturized with low power consumption and leakage current, may be provided. In view of at least the above, it will be understood that the field effect transistor, the capacitor, and the electronic apparatus (collectively, one or more devices according to any of the example embodiments) may be configured to implement optimal or improved negative capacitance characteristics based on the one or more devices including at least a gate insulating layer with a first region where a ferroelectric crystal structure is dominant and a second region where a non-ferroelectric structure is dominant, thereby configuring the one or more devices to have improved low power characteristics and leakage current characteristics, reduced power consumption, or the like. The one or more devices may thus have improved operation performance and/or efficiency, together with reduced size (e.g., improved downscaling, compactness, etc.) and thus may be configured to enable an electronic apparatus architecture, electronic device, or the like including the one or more devices to have improved operational performance and/or efficiency (e.g., improved low power characteristics and leakage current characteristics) together with improved downscaling (e.g., improved compactness, miniaturization, etc.).
The circuit diagram of the electronic apparatus 1000 is for one cell of a dynamic random access memory (DRAM), and the electronic apparatus 1000 includes one transistor TR, one capacitor CA, a word line WL, and a bit line BL. The capacitor CA may be one of the capacitors 300, 300a, or 300b described with reference to
A method of writing data to the DRAM is as follows. After a gate voltage (high) for turning the transistor TR on (“ON” state) is applied to a gate electrode through the word line WL, VDD (hereinafter, referred to as a “high voltage”) or 0 (hereinafter, referred to as a “low voltage”), which is a data voltage value to be input, is applied to the bit line BL. When a high voltage is applied to the word line WL and the bit line BL, the capacitor CA is charged, that is, data “1” is written. When a high voltage is applied to the word line WL and a low voltage is applied to the bit line BL, the capacitor CA is discharged, that is, data “0” is written.
Upon reading data, a high voltage is applied to the word line WL to turn on the transistor TR of the DRAM, and a voltage of VDD/2 is applied to the bit line BL. When the data of the DRAM is “1,” that is, when the voltage of the capacitor CA is VDD, charges stored in the capacitor CA slowly move to the bit line BL and the voltage of the bit line BL becomes slightly higher than VDD/2. In contrast, when the data of capacitor CA is “0,” charges of the bit line BL move to the capacitor CA and the voltage of the bit line BL becomes slightly lower than VDD/2. A sense amplifier may sense and amplify the potential difference of the bit line and determine whether the data is “0” or “1.”
Referring to
The transistor TR may be a field effect transistor. The transistor TR includes a semiconductor substrate SU and a gate stack GS. The semiconductor substrate SU includes a source region SR, a drain region DR, and a channel CH. The gate stack GS is disposed on the semiconductor substrate SU, faces the channel CH, and includes a gate insulating layer GI and a gate electrode GA. The channel CH is a region between the source region SR and the drain region DR, and is electrically connected to the source region SR and the drain region DR. The source region SR may be electrically connected to or in contact with one end of the channel CH, and the drain region DR may be electrically connected to or in contact with the other end of the channel CH. The channel CH may be defined as a substrate region between the source region SR and the drain region DR in the semiconductor substrate SU. The transistor TR may be one of the field effect transistors described with reference to
One of the first electrode 301 or the second electrode 303 of the capacitor CA1 and one of the source region SR or the drain region DR of the transistor TR may be electrically connected to each other through the contact 20. The contact 20 may include an appropriate conductive material, for example, tungsten, copper, aluminum, or polysilicon.
The arrangement of the capacitor CA1 and the transistor TR may be variously modified. For example, the capacitor CA1 may be disposed on the semiconductor substrate SU, or may be buried in the semiconductor substrate SU. In addition,
Referring to
An interlayer insulating layer 25 may be disposed on the semiconductor substrate SU to cover the gate stack GS. The interlayer insulating layer 25 may include an insulating material. For example, the interlayer insulating layer 25 may include Si oxide (e.g., SiO2), Al oxide (e.g., Al2O3), or a high-k material (e.g., HfO2). The contact 21 passes through the interlayer insulating layer 25 to electrically connect the transistor TR to the capacitor CA2.
The capacitor CA2 includes a first electrode 301, a second electrode 303, and a dielectric layer 302 between the first electrode 301 and the second electrode 303. The first and second electrodes 301 and 303 may be provided in a shape capable of increasing or maximizing the contact area with the dielectric layer 302. The capacitor CA2 may be one of the capacitors 300, 300a, or 300b described with reference to
The capacitors, the field effect transistors, the electronic apparatuses, and the like, according to some example embodiments described above, may be applied to various application fields. For example, the electronic apparatuses according to some example embodiments may be applied as logic devices or memory devices. The electronic apparatuses according to some example embodiments may be used for arithmetic operations, program execution, temporary data retention, and the like in devices, such as mobile devices, computers, laptop computers, sensors, network devices, and neuromorphic devices. In addition, the electronic apparatuses according to some example embodiments may be useful for devices in which an amount of data transmission is large and data transmission is continuously performed.
Referring to
The memory unit 1010, the ALU 1020, and the control unit 1030 may be interconnected in an on-chip manner via a metal line to perform direct communication. The memory unit 1010, the ALU 1020, and the control unit 1030 may be monolithically integrated on a single substrate to constitute a single chip. Input/output devices 2000 may be connected to the electronic apparatus architecture (chip) 1100. In addition, the memory unit 1010 may include both a main memory and a cache memory. The electronic apparatus architecture (chip) 1100 may be an on-chip memory processing unit. The memory unit 1010 may include the capacitor and the electronic apparatus including the same, which have been described above. The ALU 1020 or the control unit 1030 may also include the capacitor described above.
Referring to
As described herein, any devices, systems, modules, units, controllers, circuits, architectures, and/or portions thereof according to any of the example embodiments (including, without limitation, the field effect transistor 100, the field effect transistor 100a, the field effect transistor 100b, the field effect transistor 100c, the field effect transistor 200, the field effect transistor 200a, the capacitor 300, the capacitor 300a, the capacitor 300b, the electronic apparatus 1000, the electronic apparatus 1001, the electronic apparatus 1002, the electronic apparatus architecture (chip) 1100, the memory unit 1010, the arithmetic logic unit (ALU) 1020, the control unit 1030, the input/output devices 2000, the CPU 1500, the cache memory 1510, the ALU 1520, the control unit 1530, the main memory 1600, the auxiliary storage 1700, the input/output devices 2500, or the like) may include, may be included in, and/or may be implemented by one or more instances of processing circuitry such as hardware including logic circuits; a hardware/software combination such as a processor executing software; or any combination thereof. For example, the processing circuitry more specifically may include, but is not limited to, a central processing unit (CPU), an arithmetic logic unit (ALU), a graphics processing unit (GPU), an application processor (AP), a digital signal processor (DSP), a microcomputer, a field programmable gate array (FPGA), and programmable logic unit, a microprocessor, application-specific integrated circuit (ASIC), a neural network processing unit (NPU), an Electronic Control Unit (ECU), an Image Signal Processor (ISP), and the like. In some example embodiments, the processing circuitry may include a non-transitory computer readable storage device (e.g., a memory), for example a solid state drive (SSD), storing a program of instructions, and a processor (e.g., CPU) configured to execute the program of instructions to implement the functionality and/or methods performed by some or all of any devices, systems, modules, units, controllers, circuits, architectures, and/or portions thereof according to any of the example embodiments, and/or any portions thereof.
Any of the memories, memory units, memory chips, storages, storage devices, or the like as described herein may be a non-transitory computer readable medium and may store a program of instructions. Any of the memories, memory units, memory chips, storages, storage devices, or the like described herein may be a nonvolatile memory, such as a flash memory, a phase-change random access memory (PRAM), a magneto-resistive RAM (MRAM), a resistive RAM (ReRAM), or a ferro-electric RAM (FRAM), or a volatile memory, such as a static RAM (SRAM), a dynamic RAM (DRAM), or a synchronous DRAM (SDRAM).
It should be understood that some example embodiments described herein should be considered in a descriptive sense only and not for purposes of limitation. Descriptions of features or aspects within each example embodiment should typically be considered as available for other similar features or aspects in other example embodiments. While some example embodiments have been described with reference to the figures, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope as defined by the following claims.
Number | Date | Country | Kind |
---|---|---|---|
10-2022-0149356 | Nov 2022 | KR | national |