This application is based upon and claims the benefit of priority from the prior Japanese Patent Application No. 2006-146990, filed on May 26, 2006; the entire contents of which are incorporated herein by reference.
1. Field of the Invention
This invention relates to a local clean robot-transport plant where closed-type transport containers are transported to realize a minienvironment, and a robot-transport manufacturing method implemented thereby.
2. Background Art
There is an ongoing transition from 200-mm to 300-mm wafers for increasing the chip yield per wafer. Conventional manufacturing of industrial products requiring cleanliness is based on methods using a clean room. However, products such as LSIs, which are downscaled to enhance their commercial value, require higher cleanliness as the downscaling advances. Failure to improve cleaning performance decreases the product yield rate and profit. Furthermore, the enormous cost of constructing and operating the clean room for enhancing cleanliness also directly leads to profit decrease. Up to the 200-mm wafer generation, the clean room is entirely cleaned by downflow. However, the amount of capital investment in such super clean technology is becoming enormous. In the 300-mm era, the minienvironment approach is going mainstream, where the local space around the wafer is thoroughly cleaned.
The minienvironment approach is the antithesis of the super clean technology. The minienvironment approach is a local clean technology where about 25 semiconductor wafers in a box is placed in a closed-type wafer transport container called FOUP (Front Opening Unified Pod), and an especially clean environment is made only in the FOUP. Thus the trend is shifting to reducing the operating cost as well as the initial investment (see U.S. Pat. No. 4,532,970).
The “FOUP” is a transport container for 300-mm wafers, which is compliant with SEMI (Semiconductor Equipment and Materials Institute) standards. The FOUP is a closed pod where cleanliness comparable to that in the minienvironment system can be maintained. The FOUP is used for robot-transporting semiconductor wafers from the minienvironment of one process to that of another process, or for automatically exchanging semiconductor wafers with a semiconductor manufacturing apparatus.
However, because the FOUP is a closed container, cross-contamination by contaminants (contaminating factors) via FOUP materials may cause the stoppage of the production line and/or decrease the yield, presenting a serious problem in managing the process of manufacturing semiconductor devices.
Currently, besides semiconductor device manufacturing, the minienvironment system based on closed containers typified by FOUPs is also drawing attention in the fields of liquid crystal devices such as flat panel displays (FPDs) and recording media such as hard disks. The above problem is also serious in robot-transport manufacturing techniques in these other technical fields.
According to an aspect of the invention, there is provided a local clean robot-transport plant including: a plurality of manufacturing apparatuses; a plurality of closed-type transport containers, each closed-type transport container storing and transporting an intermediate product of manufacturing processes along a plurality of interprocess transport paths defined among the plurality of manufacturing apparatuses in accordance with a flow of the manufacturing processes; a container discrimination/selection apparatus configured to discriminate and select the closed-type transport container of transport type 1 and the closed-type transport container of transport type 2, respectively, from among the plurality of closed-type transport containers; an apparatus group control server configured to collectively control operation of the plurality of manufacturing apparatuses and the container discrimination/selection apparatus to move the closed-type transport container of transport type 2 to a specific interprocess transport path and to move the closed-type transport container of transport type 1 to the interprocess transport path other than the specific interprocess transport path.
According to another aspect of the invention, there is provided a robot-transport manufacturing method based on a plurality of manufacturing apparatuses controlled by an apparatus group control server, an intermediate product of manufacturing processes being stored in a plurality of closed-type transport containers and transported along a plurality of interprocess transport paths defined among the plurality of manufacturing apparatuses in accordance with a flow of the manufacturing processes, the method including: under control of the apparatus group control server, using the closed-type transport container of transport type 2 only on a specific interprocess transport path, and using only the closed-type transport container of transport type 1 on the interprocess transport paths other than the specific interprocess transport path.
According to another aspect of the invention, there is provided a robot-transport manufacturing method configured to manufacture intended industrial products, an intermediate product of manufacturing processes being stored in closed-type transport containers and transported along a plurality of interprocess transport paths defined among a plurality of manufacturing apparatuses in accordance with a flow of the manufacturing processes, the method including: using the closed-type transport container of transport type 2 only on a specific interprocess transport path; and using only the closed-type transport container of transport type 1 on the interprocess transport paths other than the specific interprocess transport path.
FIGS. 9 to 22 are process cross-sectional views for illustrating a robot-transport manufacturing method according to the embodiment of the invention by way of an example method for manufacturing a semiconductor memory device (nonvolatile semiconductor memory device), where FIGS. 9 to 18 are taken parallel to the word line in
Embodiments of the invention will now be described with reference to the drawings. In the following description of the figures, like or similar elements are marked with like or similar reference numerals. However, the figures are schematic. It should be noted that the relation of the thickness to the planar dimension and the ratio of thickness between various layers may be different from reality. Therefore the specific thickness or dimension should be determined by taking the following description into consideration. It is also understood that the dimensional relationship and/or ratio may be varied between some of the figures.
The embodiments described herein are illustrated with reference to a method for manufacturing a semiconductor device (semiconductor memory device). However, it is understood that the invention is applicable to robot-transport manufacturing methods in technical fields requiring cleanliness such as liquid crystal devices, magnetic recording media, optical recording media, thin-film magnetic heads, and superconducting devices. That is, the following embodiments illustrate facilities, apparatuses, and methods for embodying the technical spirit according to the local clean robot-transport plant and robot-transport manufacturing method of the invention. The spirit of the invention does not limit the contaminating factors responsible for cross-contamination, the material, shape, and structure of the components of the closed-type transport container, and the layout of the robot-transport plant to those described in the following embodiments.
Local Clean Robot-Transport Plant
As shown in
The “interprocess transport path” used herein refers to a logical transport path defined among a plurality of processes arranged in time series. Hence actual mechanical (physical) transport paths may partially or entirely overlap each other because in some cases (situations), the same manufacturing apparatus is used in a plurality of different processes.
The “specific interprocess transport path” used herein refers to an interprocess transport path having a specific problem and/or purpose such as cross-contamination via a closed-type transport container caused by contaminating factors due to a specific process. The “specific interprocess transport path” is predetermined on the basis of preliminary experiments or other empirical rules before starting manufacturing processes for industrial products. Here, the contaminating factors do not necessarily need to be identified, but the “specific interprocess transport path” can be determined on the basis of experimental facts of cross-contamination, which will be described later. Contaminating factors include organic and inorganic contaminants, and may also include organisms such as bacteria in the case of biotechnology or pharmaceutical manufacturing. Conversely, the “interprocess transport path having a specific purpose” refers to the case having such a purpose as intentional doping with specific impurities or intentional introduction of different chemicals to compensate for contamination by other contaminants.
As shown in
The local clean robot-transport plant according to the embodiment of the invention does not need to include all the manufacturing apparatuses required for manufacturing the intended industrial products. Part of the processes may be assigned to other local clean robot-transport plants. As described above, the “interprocess transport path” is defined as a logical transport path. Hence, when part of the processes are assigned to other local clean robot-transport plants, the transport rail 54 shown in
Although not shown, the local clean robot-transport plant according to the embodiment of the invention may also include, besides the bay area shown in
There may be a plurality of closed-type transport containers of “transport type 1” and closed-type transport containers of “transport type 2”. Furthermore, within the range of standards satisfying a prescribed level, the inner wall treatment (inner wall structure) of the closed-type transport container of “transport type 1” may be different from the inner wall treatment (inner wall structure) of the closed-type transport container of “transport type 2”.
Under commands from the apparatus group control server 51, the container discrimination/selection apparatuses 53a, 53b discriminate between closed-type transport containers of “transport type 1” and “transport type 2”, select a closed-type transport container for use between each pair of processes, and send it out to the transport rail 54. The transport rail 54 circumscribes the bay area (container transport area), and the manufacturing apparatuses 58i, 58i+1, 58i+2, 58i+3, . . . are connected to the transport rail 54 through associated transfer chambers (apparatus front chambers) 57i, 57i+1, 57i+2, 57i+3, . . . , respectively.
More specifically, as shown in
The apparatus group control server 51 shown in
The spinner 58i+4, the stepper 58i+5, and the developing apparatus 58i+6, which are related to photolithography, may be streamlined into a continuous process line having a clean area for internal transport. A common container passing mechanism for loading (loader) and container passing mechanism for unloading (unloader) may be provided, respectively, at the inlet and outlet of this process line to form an integrated manufacturing apparatus. Similarly, the silazane perhydride coater 58i+8, the silazane perhydride baking apparatus 58i+9, and the PSZ film oxidation apparatus 58i+10 may be streamlined into a continuous process line having a clean area for internal transport, and a common loader and unloader may be provided, respectively, at the inlet and outlet of this process line to form an integrated manufacturing apparatus.
It is understood that, in addition to the configuration shown in
The local clean robot-transport plant according to the embodiment of the invention may also include various inspection and measurement apparatuses such as an interferometric thickness gauge, ellipsometer, contact thickness gauge, microscope, and resistance measurement apparatus. Furthermore, although irrelevant to the transport of intermediate products by closed-type transport containers, it is understood that the local clean robot-transport plant may also include ancillary facilities such as a pure water producer and gas purifier.
An RF tag serving as a “container identification information output means” intended for identifying a closed-type transport container is attached to the container body 61 of the closed-type transport container according to the embodiment of the invention.
The RF tag (container identification information output means) 64 attached to the side face of the container body 61 is populated with container identification information including at least the container number and the type identification information that identifies whether the closed-type transport container is of transport type 2 defined for specific interprocess transport paths or of transport type 1 used on the other interprocess transport paths. Furthermore, product information concerning intermediate products (semiconductor wafers) stored in the closed-type transport container may be also recorded in the RF tag 64, such as the product name, process name, lot number, and the intermediate product numbers of intermediate products included in the lot, and thereby the history of the closed-type transport container may be added to the container identification information.
The container identification information output means is not limited to the RF tag 64, but various two-dimensional codes such as Data Matrix, QR Code, PDF417, Maxi Code, and Veri Code can be used. Furthermore, it is possible to use various codes such as alphanumeric or other character codes other than two-dimensional codes, graphics, one-dimensional codes, and combined graphic codes of one-dimensional and two-dimensional codes. It is also possible to use intermediate codes between one-dimensional and two-dimensional codes such as the stacked barcode, which is made of barcodes (one-dimensional codes) stacked two-dimensionally (however, two-dimensional codes are more preferable in terms of the amount of information per unit area).
The closed-type transport container shown in
In
Lot Processing by Automatic Transport
An example lot processing by automatic transport in the local clean robot-transport plant according to the embodiment of the invention can be schematically described as follows with reference to the manufacturing apparatus (manufacturing apparatus body) 58 shown in
(a) First, upon receiving a lot processing instruction command from the apparatus group control server 51 shown in
(b) Upon receiving the notification from the manufacturing apparatus 58 that the manufacturing apparatus 58 has generated a job, the apparatus group control server 51 uses the job identification number to recognize product information such as the product name, process name, lot number, and the intermediate product numbers of intermediate products included in the lot. Furthermore, from the product information, the apparatus group control server 51 generates container information concerning the closed-type transport container 60 corresponding to the manufacturing apparatus 58 and communicates it to the manufacturing apparatus 58.
(c) Upon notification of the container information from the apparatus group control server 51 to the manufacturing apparatus 58, the RF tag receiver (container identification information input means) 59 installed on the transfer chamber (apparatus front chamber) 57 locally cleaned as a clean area reads a signal (container identification information) from the RF tag (container identification information output means) 64 provided on the closed-type transport container 60 and determines whether the closed-type transport container 60 transported via the transport rail 54 to the container passing mechanism for loading (loader) 55 has a correct transport type. That is, the signal (container identification information) from the RF tag 64 is used for checking the transport type to determine whether the closed-type transport container 60 is a closed-type transport container of transport type 2 or of transport type 1 which is to be transported between the process of the manufacturing apparatus 58 in question and the immediately preceding process. If it is determined that the transport type is correct, the lid of the closed-type transport container 60 is automatically opened in the container passing mechanism for loading (loader) 55, and intermediate products are transferred from the closed-type transport container 60 to the manufacturing apparatus 58 through the transfer chamber (apparatus front chamber) 57 locally cleaned as a clean area. If it is determined that the transport type of the closed-type transport container 60 is not correct, a notification of “type rejected” is communicated to the apparatus group control server 51. Then the apparatus group control server 51 performs an alarm handling by transmitting a command for stopping the operation (shutdown) of the manufacturing apparatus 58, and reports it to the process administrator and plant administrator, thereby canceling the processing of the lot.
(d) If it is determined that the transport type of the closed-type transport container 60 is correct, the manufacturing apparatus 58 starts an associated lot processing such as lithography, etching, heat treatment, ion implantation, CVD, sputtering, evaporation, and washing in accordance with a prescribed recipe. The prescribed recipe is managed by the apparatus group control server 51 shown in
(e) While the manufacturing apparatus 58 is performing the associated lot processing in accordance with the prescribed recipe, the apparatus group control server 51 uses the product information to derive the process following the current processing of the manufacturing apparatus 58, generates container information concerning the type of the closed-type transport container 60 used in transporting intermediate products to the manufacturing apparatus of the next process, and communicates it to the manufacturing apparatus 58. If the transport to the next process involves no type change for the closed-type transport container 60, the empty closed-type transport container 60 is moved from the container passing mechanism for loading (loader) 55 to the container passing mechanism for unloading (unloader) 56 and waits until the processing of the prescribed process of the manufacturing apparatus 58 is completed.
(f) On the other hand, if the transport of intermediate products to the next process involves any type change for the closed-type transport container 60, the empty closed-type transport container 60 is transported from the container passing mechanism for loading (loader) 55 via the transport rail 54 to the container discrimination/selection apparatus 53a, 53b shown in
(g) When the processing of the prescribed process is completed by the manufacturing apparatus 58 in accordance with the recipe, the resulting intermediate products are transferred to the container passing mechanism for unloading (unloader) 56 through the transfer chamber (apparatus front chamber) 57 locally cleaned as a clean area. Inside the container passing mechanism for unloading (unloader) 56, the intermediate products are automatically stored in the closed-type transport container 60. The lid of the closed-type transport container 60 is automatically closed. Then, under the command from the apparatus group control server 51, the closed-type transport container 60 is robot-transported via the transport rail 54 to the container passing mechanism for loading (loader) of the manufacturing apparatus of the next process.
In the foregoing method, while the manufacturing apparatus 58 is performing the processing of an associated process, the apparatus group control server generates container information concerning the type of the closed-type transport container 60 used in transporting intermediate products to the manufacturing apparatus of the next process. However, this is for illustrative purpose only. For example, before starting the lot processing, the container information for all the interprocess transport paths may be predetermined. The transport type of the closed-type transport container for every interprocess transport path may be preprogrammed on the basis of the predetermined container information, and the program may be stored in a program memory device. The closed-type transport containers 60 may be successively exchanged under the program stored in the program memory device.
Cross-Contamination Via a Closed-Type Transport Container Due to PSZ Film: Case 1
The shallow trench isolation (STI) structure is widely used for device isolation in semiconductor devices. In this structure, a groove is formed in the device isolation region of the semiconductor substrate, and silicon oxide (SiO2) film or the like serving as device isolation insulating film is buried in this groove. With the downscaling of semiconductor devices, the aspect ratio of the groove increases, which makes it difficult to fill the STI groove with the conventional ozone (O3)/tetraethylorthosilicate (TEOS) CVD oxide (SiO2) film or high-density plasma (HDP) CVD oxide (SiO2) film without generating voids and seams.
Thus, in a proposed method for manufacturing semiconductor devices from the 100-nm generation onward, coating-type solution SOG (spin-on-glass) is used to fill the STI groove with device isolation insulating film. In particular, among SOG-based chemicals, a silazane perhydride polymer solution having relatively small volume shrinkage recently draws attention.
As shown in Formula (1), silazane perhydride has a structure of —(SiH2—NH)n—. Hence it reacts with water (H2O) in the atmosphere to generate ammonia (NH3). On the other hand, the closed-type transport container is made of polycarbonate (PC) or polybutylene terephthalate (PBT), and hence the material of the closed-type transport container reacts with NH3. That is, as described below, when a semiconductor wafer with exposed polysilazane (PSZ) film formed by baking silazane perhydride coating is stored in the closed-type transport container, NH3 generated from the PSZ film reacts with the material of the closed-type transport container and causes cross-contamination.
Three closed-type transport containers, that is, a closed-type transport container (FOUP) 1 shown in
(a) First, for preparing “intermediate products”, 48 semiconductor wafers (Si wafers) measuring 300 mm in diameter were each coated with a silazane perhydride polymer solution to a thickness of 600 nm by spin coating. Then the silazane perhydride coating was baked at 150° C. for three minutes. Thus PSZ film was formed on each of the 48 semiconductor wafers.
(b) As shown in
(c) Then, as shown in
(d) Then the inner wall of each closed-type transport container (FOUP) 1, 2, 3 was wiped with waste soaked with pure water, the waste was subjected to pure water extraction, and the amount of NH3 attached to the closed-type transport container was determined by ion chromatography. Furthermore, NH3 adsorbed on the non-silazane SOG film 1, 2, 3 for checking cross-contamination was also determined by pure water extraction and ion chromatography.
The result of the above procedure (a) to (d) for examining the contamination of the closed-type transport containers caused by silazane perhydride is listed on TABLE 1.
It can be seen in TABLE 1 that the amount of NH3 adsorbed on the inner wall of the closed-type transport container (FOUP) 2 having stored wafers with PSZ film is about four times larger than that on the inner wall of the reference closed-type transport container (FOUP) 1. On the other hand, the amount of NH3 adsorbed on the inner wall of the closed-type transport container (FOUP) 3 having stored wafers with PSZ film is smaller than that on the inner wall of the reference closed-type transport container (FOUP) 1. Hence it turns out that the adsorbed NH3 is eliminated by washing the closed-type transport container.
However, as seen in the result of cross-contamination due to adsorption on the non-silazane SOG film formed on the surface of the semiconductor wafer shown in the right column of TABLE 1, NH3 contamination was detected not only from the SOG wafer (SOG2) stored in the closed-type transport container (FOUP) 2 with NH3 adsorbed on the inner wall, but also from the SOG wafer (SOG3) stored in the washed closed-type transport container (FOUP) 3. This indicates that, even if NH3 adsorbed on the inner wall surface of the closed-type transport container was washed away, NH3 remains trapped in the material of the closed-type transport container and is gradually released into the closed-type transport container. This is adsorbed on the non-silazane SOG film formed on the surface of the stored semiconductor wafer to cause cross-contamination.
Cross-Contamination Via a Closed-Type Transport Container Due to PSZ Film: Case 2
Next, a description is given of NH3 cross-contamination from the polysilazane (PSZ) film which is formed by baking silazane perhydride coating at 150° C. for three minutes and is further oxidized in water vapor-containing atmosphere at a temperature higher than 200° C. and not higher than 600° C. When the temperature of oxidation of the PSZ film is lower than 400° C., silazane structures such as Si—H, N—H, and Si—N remain in the PSZ film. That is, the PSZ film is not a perfect SiO2 film. Thus:
(a) First, for preparing “intermediate products”, 24 semiconductor wafers (Si wafers) measuring 300 mm in diameter were each coated with a silazane perhydride polymer solution to a thickness of 600 nm by spin coating, which was baked at 150° C. for three minutes to form PSZ film. The PSZ film was further oxidized in water vapor at a temperature lower than 400° C., e.g. 300° C. (the resulting PSZ film being hereinafter referred to as “oxidized PSZ film”). Thus 24 semiconductor wafers with the oxidized PSZ film on the surface thereof were prepared.
(b) The 24 semiconductor wafers with the oxidized PSZ film formed thereon were inserted into grooves (slots) 1 to 24, respectively, of a closed-type transport container (FOUP) 4 and retained for three days.
(c) After three days, the 24 semiconductor wafers with the oxidized PSZ film formed thereon were retrieved from the closed-type transport container (FOUP) 4. Then, in the closed-type transport container (FOUP) 4, two wafers (SOG4) with non-silazane SOG film for checking cross-contamination were inserted into grooves 1 and 24 and retained for three days.
(d) Then the two wafers (SOG4) with non-silazane SOG film were retrieved from the closed-type transport container (FOUP), and NH3 adsorbed on the non-silazane SOG film 4 for checking cross-contamination was determined by pure water extraction and ion chromatography.
According to the ion chromatography, NH3 cross-contamination of 9.5 μg was detected also from the oxidized PSZ film which was oxidized at 300° C. It can be seen by comparison with the result of TABLE 1 that cross-contamination from the PSZ film oxidized at a temperature of 300° C., which is higher than in the case of TABLE 1, is also serious.
Influence of Cross-Contamination on Manufacturing Processes
As described above, NH3 contamination in a closed-type transport container causes cross-contamination where semiconductor wafers subsequently stored as “intermediate products” in the closed-type transport container are contaminated.
Some kinds of photoresist film react with NH3. Such photoresist film causes adhesion failure and patterning distortion. In particular, if the photoresist film is processed into a thin line-and-space pattern followed by reacting with NH3 contamination, a shape called “skirt” as shown in
Robot-Transport Manufacturing Method Discriminating Between Closed-Type Transport Containers
With reference to FIGS. 9 to 22, a method for manufacturing a NAND nonvolatile semiconductor memory device will be described, where interprocess transport paths for transporting semiconductor wafers with exposed PSZ film are defined as “specific interprocess transport paths”, and a silazane perhydride polymer solution is used as an STI filling material. However, by way of introduction, a completed NAND nonvolatile semiconductor memory device is described with reference to FIGS. 6 to 8.
A floating electrode 13 for storing charge, an interelectrode insulating film 20 on the floating electrode 13, and a control electrode 22 on the interelectrode insulating film 20 are located on the gate insulating film (tunnel oxide film) 12 to constitute a gate electrode of each memory cell transistor. Although not shown, the select transistor also has a gate electrode structure comprising a gate insulating film (tunnel oxide film) 12, a floating electrode 13, an interelectrode insulating film 20, and a control electrode 22 electrically continuous with the floating electrode 13 through an opening in the interelectrode insulating film 20. However, the control electrode 22 is electrically continuous with the floating electrode 13 through an interelectrode insulating film short-circuit window of the interelectrode insulating film 20. As can be understood from
The floating electrode 13 serving as a charge storage layer is formed from polycrystalline silicon film doped with n-type dopants such as phosphorus (P) or arsenic (As) (hereinafter referred to as “doped polycrystalline silicon film”).
The control electrode 22 may have a three-layer structure composed of a polycrystalline silicon film doped with n-type dopants, a tungsten silicide (WSi2) film, and a cap insulating film. The tungsten silicide (WSi2) film may be replaced by any other metal silicide film such as cobalt silicide (CoSi2) film, titanium silicide (TiSi2) film, or molybdenum silicide (MoSi2) film. Instead of silicide film, high-melting-point metal such as tungsten (W), cobalt (Co), titanium (Ti), or molybdenum (Mo), or polycide film based on these silicide films may be used. Instead of using silicide film, a highly conductive metal film made of aluminum (Al) or copper (Cu) may be placed on the polycrystalline silicon film to also serve as the word lines WL1k, WL2k, . . . , WL32k, WL1k−1, . . . . Alternatively, the silicide film may be replaced by a laminated film made of one or more of tungsten nitride (WN) film and titanium nitride (TiN, TiN2) film on the polycrystalline silicon film.
Although not shown, the peripheral transistor is configured as a transistor having nearly the same laminated structure as the select transistor, or as a transistor having a gate electrode corresponding to the structure only with the control electrode 22 where the floating electrode 13 and the interelectrode insulating film 20 are removed from the laminated structure of the select transistor.
As is obvious from the cross-sectional view taken along the bit line direction shown in
In
Having made preliminary remarks, a robot-transport manufacturing method according to the embodiment of the invention is now described with reference to FIGS. 9 to 22. Here, FIGS. 9 to 18 are cross-sectional views taken parallel to the word lines WL1k, WL2k, . . . , WL32k, WL1k−1, . . . shown in
The flow of manufacturing processes shown in FIGS. 9 to 22 is presented for convenience of describing a robot-transport manufacturing method according to the embodiment of the invention. In practice, some other processes such as an ion implantation process for threshold control may be added to the flow of the method for manufacturing a NAND nonvolatile semiconductor memory device (flash memory) shown in the following (a) to (w). That is, the method for manufacturing a NAND nonvolatile semiconductor memory device described below is an example for understanding of the content of the robot-transport manufacturing method. It is understood that NAND nonvolatile semiconductor memory devices can be manufactured by various other flows of manufacturing processes, including the above variation, within the spirit and scope of the invention.
(a) For simplicity of description, it is assumed that, under the command from the apparatus group control server 51 shown in
(b) The lid of the type 1 container is automatically opened in the loader 55i+1 of the gate oxidation apparatus 58i+1, and the semiconductor wafer 11 is transferred from the type 1 container to the gate oxidation apparatus 58i+1 through the local clean transfer chamber 57i+1. In accordance with the recipe transmitted from the apparatus group control server 51, a tunnel oxide film 12p is formed on the semiconductor wafer 11. The tunnel oxide film 12p is formed to a thickness of about 1 to 15 nm, e.g. about 8 nm. Then the semiconductor wafer 11 is transferred to the unloader 56i+1 through the transfer chamber 57i+1. Inside the unloader 56i+1, the semiconductor wafer 11 is automatically stored in the type 1 container. The lid of the type 1 container is automatically closed. Then the type 1 container is robot-transported via the transport rail 54 to the loader 55i+2 of the polysilicon reduced-pressure CVD apparatus 58i+2.
(c) The lid of the type 1 container is automatically opened in the loader 55i+2 of the polysilicon reduced-pressure CVD apparatus 58i+2, and the semiconductor wafer 11 is transferred from the type 1 container to the polysilicon reduced-pressure CVD apparatus 58i+2 through the transfer chamber 57i+2. In accordance with the recipe transmitted from the apparatus group control server 51, a polycrystalline silicon film (first conductive layer) 13p serving as a floating electrode 13 is deposited on the tunnel oxide film 12p. The first conductive layer (polycrystalline silicon film) 13p is deposited to a thickness of about 10 to 200 nm, e.g. about 150 nm. Then the semiconductor wafer 11 is transferred to the unloader 56i+2 through the transfer chamber 57i+2. Inside the unloader 56i+2, the semiconductor wafer 11 is automatically stored in the type 1 container. The lid of the type 1 container is automatically closed. Then the type 1 container is robot-transported via the transport rail 54 to the loader 55i+3 of the nitride film reduced-pressure CVD apparatus 58i+3.
(d) The lid of the type 1 container is opened in the loader 55i+3 of the nitride film reduced-pressure CVD apparatus 58i+3, and the semiconductor wafer 11 is transferred from the type 1 container to the nitride film reduced-pressure CVD apparatus 58i+3 through the transfer chamber 57i+3. In accordance with the recipe transmitted from the apparatus group control server 51, an Si3N4 film serving as a CMP stopper layer 14p is deposited on the first conductive layer (polycrystalline silicon film) 13p. The CMP stopper layer (Si3N4 film) 14p is deposited to a thickness of about 80 to 300 nm, e.g. about 100 nm. Then the semiconductor wafer 11 is transferred to the unloader 56i+3 through the transfer chamber 57i+3. Inside the unloader 56i+3, the semiconductor wafer 11 is stored in the type 1 container. The lid of the type 1 container is closed. Then the type 1 container is robot-transported via the transport rail 54 to the loader 55i+4 of the spinner 58i+4.
(e) The lid of the type 1 container is opened in the loader 55i+4 of the spinner 58i+4, and the semiconductor wafer 11 is transferred from the type 1 container to the rotary stage of the spinner 58i+4 through the transfer chamber 57i+4. In accordance with the recipe transmitted from the apparatus group control server 51, a photoresist film 15 is applied onto the entire surface of the CMP stopper layer 14p. The semiconductor wafer 11 coated with the photoresist film 15, after prebaking, is transferred to the unloader 56i+4 through the transfer chamber 57i+4. Inside the unloader 56i+4, the semiconductor wafer 11 is stored in the type 1 container. The lid of the type 1 container is closed. Then the type 1 container is robot-transported via the transport rail 54 to the loader 55i+5 of the stepper 58i+5.
(f) The lid of the type 1 container is opened in the loader 55i+5 of the stepper 58i+5, and the semiconductor wafer 11 is transferred from the type 1 container to the exposure stage of the stepper 58i+5 through the transfer chamber 57i+5. In accordance with the recipe transmitted from the apparatus group control server 51, an image of a prescribed mask pattern is projected on the photoresist film 15 by the step-and-repeat exposure, and thereby the image of a desired mask pattern is transferred. The semiconductor wafer 11 with the image of the mask pattern transferred thereon, after postbaking, is transferred to the unloader 56i+5 through the transfer chamber 57i+5. Inside the unloader 56i+5, the semiconductor wafer 11 is stored in the type 1 container. The lid of the type 1 container is closed. Then the type 1 container is robot-transported via the transport rail 54 to the loader 55i+6 of the developing apparatus 58i+6.
(g) The lid of the type 1 container is opened in the loader 55i+6 of the developing apparatus 58i+6, and the semiconductor wafer 11 is transferred from the type 1 container to the developing apparatus 58i+6 through the transfer chamber 57i+6. In accordance with the recipe transmitted from the apparatus group control server 51, the photoresist film 15 is developed by developer liquid. As a result, as shown in
(h) The lid of the type 1 container is opened in the loader 55i+7 of the RIE apparatus 58i+7, and the semiconductor wafer 11 is transferred from the type 1 container into the etching chamber of the RIE apparatus 58i+7 through the transfer chamber 57i+7. In accordance with the recipe transmitted from the apparatus group control server 51, the resist mask 15 is used to continuously etch the CMP stopper layer 14p, the first conductive layer 13p, and the tunnel oxide film 12p, thereby forming a sequentially laminated pattern of a tunnel oxide film 12, a first conductive layer 13, a silicon nitride film 14, and the resist mask 15. Continuous RIE is further carried on in the etching chamber of the RIE apparatus 58i+7 to etch the silicon substrate 11. After completion of the continuous RIE, the semiconductor wafer 11 is transferred to the unloader 56i+7 through the transfer chamber 57i+7. Inside the unloader 56i+7, the semiconductor wafer 11 is stored in the type 1 container. The lid of the type 1 container is closed. Then the type 1 container is robot-transported via the transport rail 54 to the loader 55i of the washer 58i.
(i) The lid of the type 1 container is opened in the loader 55i of the washer 58i, and the semiconductor wafer 11 is transferred from the type 1 container to the washer 58i through the transfer chamber 57i. In accordance with the recipe transmitted from the apparatus group control server 51, the resist mask 15 is removed. Upon removal of the resist mask 15, as shown in
(j) The lid of the type 2 container is opened in the loader 55i+8 of the silazane perhydride coater 58i+8, and the semiconductor wafer 11 is transferred from the type 2 container to the rotary stage of the silazane perhydride coater 58i+8 through the transfer chamber 57i+8. In accordance with the recipe transmitted from the apparatus group control server 51, a silazane perhydride polymer solution 18p is applied, by spin coating, onto the entire surface of the silicon substrate 11, the tunnel oxide film 12p, the floating electrode 13, and the Si3N4 film 14 so as to completely fill the device isolation grooves 31 as shown in
(k) The lid of the type 2 container is opened in the loader 55i+9 of the silazane perhydride baking apparatus 58i+9, and the semiconductor wafer 11 is transferred from the type 2 container to the silazane perhydride baking apparatus 58i+9 through the transfer chamber 57i+9. In accordance with the recipe transmitted from the apparatus group control server 51, the silazane perhydride polymer solution (silazane perhydride coating) 18p applied by the silazane perhydride coater 58i+8 is baked at 200° C. or less, e.g. about 150° C., for about three minutes. By this baking process, the solvent of the silazane perhydride polymer solution 18p is volatilized to form a polysilazane (PSZ) film 18q as shown in
(l) The lid of the type 2 container is opened in the loader 55i+10 of the PSZ film oxidation apparatus 58i+10, and the semiconductor wafer 11 is transferred from the type 2 container to the PSZ film oxidation apparatus 58i+10 through the transfer chamber 57i+10. In accordance with the recipe transmitted from the apparatus group control server 51, the PSZ film 18q formed by the silazane perhydride baking apparatus 58i+9 is oxidized at a temperature higher than 200° C. and not higher than 600° C. By this oxidation, the PSZ film 18q is transformed to an SiO2 film 18r. The semiconductor wafer 11 with the PSZ film 18q transformed to the SiO2 film 18r is transferred to the unloader 56i+10 through the transfer chamber 57i+10. Inside the unloader 56i+10, the semiconductor wafer 11 is stored in the type 2 container. The lid of the type 2 container is closed. Then the type 2 container is robot-transported via the transport rail 54 to the loader 55i+11 of the CMP apparatus 58i+11.
(m) The lid of the type 2 container is opened in the loader 55i+11 of the CMP apparatus 58i+11, and the semiconductor wafer 11 is transferred from the type 2 container to the CMP apparatus 58i+11 through the transfer chamber 57i+11. In accordance with the recipe transmitted from the apparatus group control server 51, the Si3N4 film is used as a CMP stopper layer 14 to polish the SiO2 film 18r outside the trench and to planarize the surface by the CMP process as shown in
(n) The lid of the type 2 container is opened in the loader 55i+q of the wet etching apparatus 58i+q, and the semiconductor wafer 11 is transferred from the type 2 container to the wet etching apparatus 58i+q through the transfer chamber 57i+q (not shown). In accordance with the recipe transmitted from the apparatus group control server 51, the upper portion of the SiO2 film 18r is removed by wet etching with dilute hydrofluoric acid (HF) solution to bury the device isolation insulating film 18 in the deep recesses of the device isolation groove 31 as shown in
(o) The lid of the type 2 container is opened in the loader 55i+12 of the interelectrode insulating film reduced-pressure CVD apparatus 58i+12, and the semiconductor wafer 11 is transferred from the type 2 container to the interelectrode insulating film reduced-pressure CVD apparatus 58i+12 through the transfer chamber 57i+12. In accordance with the recipe transmitted from the apparatus group control server 51, as shown in
(p) The lid of the type 1 container is automatically opened in the loader 55i+2 of the polysilicon reduced-pressure CVD apparatus 58i+2, and the semiconductor wafer 11 is transferred from the type 1 container to the polysilicon reduced-pressure CVD apparatus 58i+2 through the transfer chamber 57i+2. In accordance with the recipe transmitted from the apparatus group control server 51, as shown in
(q) The process by the spinner 58i+4, the subsequent process by the stepper 58i+5, and the further subsequent process by the developing apparatus 58i+6 are similar to the above processes (e) to (g). A photoresist film 24 is applied onto the second conductive layer 22p formed in the polysilicon reduced-pressure CVD apparatus 58i+2, and is patterned by projection exposure by the stepper 58i+5 and by the subsequent developing process by the developing apparatus 58i+6. As a result, as shown in
(r) The lid of the type 1 container is opened in the loader 55i+7 of the RIE apparatus 58i+7, and the semiconductor wafer 11 is transferred from the type 1 container into the etching chamber of the RIE apparatus 58i+7 through the transfer chamber 57i+7. In accordance with the recipe transmitted from the apparatus group control server 51, the pattern of the photoresist film 24 is used as an etching mask for isolation between cells within a column to selectively etch the second conductive layer 22p, the interelectrode insulating film 20, the first conductive layer 13, and the gate insulating film (tunnel oxide film) 12 until the silicon substrate 11 is exposed, thereby forming a plurality of slit-like cell isolation grooves extending in the row direction (word line direction). As a result, as shown in
(s) The lid of the type 1 container is opened in the loader 55i of the washer 58i, and the semiconductor wafer 11 is transferred from the type 1 container to the washer 58i through the transfer chamber 57i. In accordance with the recipe transmitted from the apparatus group control server 51, the resist mask 24 is removed. The semiconductor wafer 11 from which the resist mask 24 has been removed is transferred to the unloader 56i through the transfer chamber 57i. Inside the unloader 56i, the semiconductor wafer 11 is stored in the type 1 container. The lid of the type 1 container is closed. Then the type 1 container is robot-transported via the transport rail 54 to the loader 55i+13 of the ion implantation apparatus 58i+13.
(t) The lid of the type 1 container is automatically opened in the loader 55i+13 of the ion implantation apparatus 58i+13, and the semiconductor wafer 11 is transferred from the type 1 container to the ion implantation apparatus 58i+13 through the transfer chamber 57i+13. In accordance with the recipe transmitted from the apparatus group control server 51, as shown in
(u) The lid of the type 1 container is automatically opened in the loader 55i+14 of the annealing furnace 58i+14, and the semiconductor wafer 11 is transferred from the type 1 container to the annealing furnace 58i+14 through the transfer chamber 57i+14. In accordance with the recipe transmitted from the apparatus group control server 51, activation annealing following ion implantation is performed. As a result, as shown in
(v) The lid of the type 1 container is automatically opened in the loader 55i+15 of the interlayer insulating film CVD apparatus 58i+15, and the semiconductor wafer 11 is transferred from the type 1 container to the interlayer insulating film CVD apparatus 58i+15 through the transfer chamber 57i+15. In accordance with the recipe transmitted from the apparatus group control server 51, an SiOF film is deposited as an interlayer insulating film 26 by the HDP method using difluorofuran (SiH2F2) gas, for example. As a result, as shown in
(w) The process by the spinner 58i+4, the subsequent process by the stepper 58i+5, and the further subsequent process by the developing apparatus 58i+6 are similar to the above processes (e) to (g). A new photoresist film is applied on the entire surface, and then the new photoresist film is patterned using the conventional photolithography technique. The new photoresist film is used as an etching mask to open a via hole (contact hole) between the two select transistors by the RIE apparatus 58i+7. The contact hole is filled with a contact plug made of tungsten or other conductor by a sputtering apparatus, a vacuum evaporation apparatus, and a metal CVD apparatus in the adjacent bay area, not shown. Furthermore, a metal film (conductor film) is deposited by these sputtering apparatus, vacuum evaporation apparatus, and metal CVD apparatus. Then the metal film (conductor film) is patterned by the photolithography technique similar to that used in the above processes (e) to (g) and RIE similar to that used in the process (h) (or using the damascene technique) to form the interconnect of bit lines 27 on the interlayer insulating film 26 as shown in
The robot-transport manufacturing method according to the embodiment of the invention illustrated above in (a) to (w) can prevent the influence of cross-contamination via the closed-type transport container caused by contaminating factors (NH3) that occurs during the transport associated with the process of applying a silazane perhydride polymer solution, the baking process following this applying process, and the oxidation process following this baking process. Hence, in particular, shape anomaly is eliminated in the fine pattern of the photoresist film in the photolithography process. Thus the semiconductor manufacturing line composed of numerous manufacturing apparatuses (semiconductor manufacturing apparatuses) can introduce the minienvironment technology using closed-type transport containers, and thereby NAND nonvolatile semiconductor memory devices (flash memories) with high precision and quality can be manufactured at high manufacturing yield.
In the above robot-transport manufacturing method, during the process of removing the resist mask 15 in the washer 58i, the apparatus group control server 51 determines that the next interprocess transport path to the silazane perhydride coater 58i+8 is to be a “specific interprocess transport path”, generates container information for the “specific interprocess transport path”, and instructs the washer 58i on the type change of the closed-type transport container 60. Furthermore, during the process of depositing an interelectrode insulating film 20 in the interelectrode insulating film reduced-pressure CVD apparatus 58i+12, the apparatus group control server 51 determines that the next interprocess transport path to the polysilicon CVD process for the second conductive layer 22p is to be a “non-specific interprocess transport path” and instructs the interelectrode insulating film reduced-pressure CVD apparatus 58i+12 on the type change of the closed-type transport container 60. However, this is for illustrative purpose only. For example, before starting the lot processing in accordance with the method for manufacturing a NAND nonvolatile semiconductor memory device described above in (a) to (w), the apparatus group control server 51 may predetermine the container information for all the interprocess transport paths for the processes including (a) to (w), and preprogram the transport type of the closed-type transport container for every interprocess transport path on the basis of the predetermined container information. More specifically, a program regarding the container information may be stored in a program memory device, and the apparatus group control server 51 may send a notification of the container information and an instruction of the type change to the associated manufacturing apparatuses 58i, 58i+1, 58i+2, 58i+3, . . . on the basis of the program stored in the program memory device. Thus the closed-type transport containers 60 may be successively exchanged along the required interprocess transport paths.
In the above process (v) of burying the interlayer insulating film 26 between each pair of memory cell transistors isolated from each other by the cell isolation groove and between the memory cell transistor and the select transistor, the silazane perhydride coater 58i+8, the silazane perhydride baking apparatus 58i+9, and the PSZ film oxidation apparatus 58i+10 may be used to bury PSZ film in the cell isolation groove. In this case, another occurrence of the type change from the type 1 container to the type 2 container and a subsequent type change from the type 2 container to the type 1 container are to be added.
The flow of the method for manufacturing a NAND nonvolatile semiconductor memory device (flash memory) described above in (a) to (w) is presented for convenience of describing a robot-transport manufacturing method according to the embodiment of the invention. In practice, before the ion implantation process shown in
The invention has been described with reference to the above embodiment. However, the description and drawings constituting part of this disclosure should not be understood as limiting the present invention. Various alternative embodiments, examples, and practical applications will be apparent to those skilled in the art from this disclosure.
The foregoing embodiment is described with reference to a NAND nonvolatile semiconductor memory device (flash memory), and a method for manufacturing the same is illustratively described. However, the invention is similarly applicable to AND or DINOR flash memories other then NAND flash memories, and further applicable to various other semiconductor memory devices such as DRAM and SRAM. Moreover, it is understood that the invention is also applicable to manufacturing various semiconductor devices such as logic integrated circuits.
Semiconductor device manufacturing may be a typical example of technical fields requiring cleanliness. However, besides semiconductor device manufacturing, there is also a growing demand for cleanliness in methods for manufacturing liquid crystal devices, magnetic recording media, optical recording media, thin-film magnetic heads, superconducting devices, acoustoelectric conversion devices, biotechnology products, and chemical agents. It will be readily understood from the above description that the invention is applicable to the operation of closed-type transport containers in the local clean technology (robot-transport manufacturing method) of these various fields and local clean robot-transport plants based thereon.
The foregoing embodiment is described with reference to a NAND nonvolatile semiconductor memory device (flash memory), and a description is illustratively made of the case where ammonia (NH3) derived from silazane perhydride reacts with the material of the closed-type transport container to cause cross-contamination. However, a process of burying a solution of polysilasilazane given by the following formula (2), for example, in the device isolation groove by spin coating may also cause cross-contamination due to NH3 in the associated interprocess transport paths.
Hence the invention is not limited to manufacturing processes based on silazane perhydride polymer solution.
Furthermore, besides NH3, contaminating factors (chemicals) reacting with the material of the closed-type transport container to cause cross-contamination also include nitrogen oxides (NOx), sulfur oxides (SOx), halogens such as chlorine (Cl) and fluorine (F), amines such as monoethanolamine (MEA), phthalate esters, and siloxane compounds. Cross-contamination by these substances may cause problems depending on technical fields, product specifications, and the contamination levels. In some cases, problems caused by water associated with the washing process and particles associated with the CMP process may be also contemplated depending on technical fields and product specifications. Hence the invention should not be construed as being limited by the above embodiment.
In practical applications to these various fields, there may be a plurality of kinds of “specific interprocess transport paths”, and two kinds of specific interprocess transport paths may partially overlap each other depending on product specifications. More specifically, closed-type transport containers used in the example described above are grouped into two transport types: closed-type transport containers of transport type 2 for transporting semiconductor wafers on the predetermined specific interprocess transport paths and closed-type transport containers of transport type 1 for transporting semiconductor wafers on interprocess transport paths other than these specific interprocess transport paths. However, if there are a plurality of kinds of specific interprocess transport paths, closed-type transport containers of three or more transport types can be naturally used as a logical conclusion.
Furthermore, the “specific interprocess transport paths” can be defined even if the contaminating factors are not identified. In particular, in gate oxidation, which may cause contamination problems due to heavy metals and alkali ions, the path from the washing apparatus 58i for the preprocessing of gate oxidation to the gate oxidation apparatus 58i+1 may be defined as a “specific interprocess transport path”. Moreover, the closed-type transport containers used on the specific interprocess transport path of gate oxidation may be subjected to special treatment such as intentional injection of chlorine gas into the inner wall thereof.
Thus it is understood that the present invention includes various embodiments not described herein. Therefore the scope of the invention is to be defined only by the elements recited in the accompanying claims, which are supported by the above description.
Number | Date | Country | Kind |
---|---|---|---|
2006-146990 | May 2006 | JP | national |