Patent Application
20110254138
The present invention relates to an improved low-temperature absorber film and a method of fabricating such a low-temperature absorber film. More specifically, the invention provides an amorphous carbonitride film having improved absorption properties which can be exposed to electromagnetic radiation that has one or more wavelengths between 190 nm and 1000 nm.
Rapid thermal processing (RTP) is commonly used during fabrication of integrated circuits (ICs) for deposition of layers, or to anneal previously deposited layers. For example, fabrication of ultra-shallow junctions requires a minimal overall thermal budget. Instead of RTP, the activation of dopants can be achieved by a rapid laser annealing process or by flash anneals with high intensity lamps.
As described in U.S. Pat. Nos. 7,109,087 and 7,262,106, an absorbing layer of amorphous carbon is typically deposited on top of a material or device to be annealed in order to get adequate and uniform laser energy absorption. These prior art amorphous carbon absorbing layers are used in conjunction with laser anneals to improve heating uniformity across a plurality of surfaces, and devices during IC fabrication. As described in the aforementioned publications, laser anneals have the advantage of not heating the entire thickness of the substrate, which limits the amount of time that a substrate is exposed to elevated temperatures thus minimizing unwanted diffusion of dopants in the substrate and substrate damage.
One potential drawback with prior art amorphous carbon layers is that they lack sufficient absorptivity when deposited at temperatures less than 450° C., because of incorporation of excess amounts of hydrocarbon which reduces absorptivity. Another potential drawback with prior art amorphous carbon layers is that the prior art amorphous carbon layers are highly transparent and thus they exhibit a high reflectance variations from the substrate.
An improved absorber film deposited at temperatures less than 450° C. is provided that has a high absorptivity and is less transparent than prior art amorphous carbon absorber films deposited at comparable temperatures. The improved absorber film disclosed herein is a thinner film than typical prior art amorphous carbon only layers and, in some embodiments, the improved absorber film can be exposed to electromagnetic radiation that has one or more wavelengths between 190 nm and 1000 nm. More particularly, the present invention provides an amorphous carbonitride (ACN) film that can be deposited at a temperature of less than, or equal to, 450° C. The amorphous carbonitride film deposited at such a low-temperature has an extinction coefficient (k) of greater than 0.15, an emissivity of greater than 0.8, and a minimum of hydrocarbon content as observed by FTIR.
The term “amorphous” when used in conjunction with the carbonitride film denotes that the carbonitride film lacks a well defined crystal structure. Moreover, while there may be local ordering of the atoms or molecules in the amorphous carbonitride film, no long-term ordering is present. By “minimum of hydrocarbon content as observed by FTIR” it is meant a normalized hydrocarbon content less than 3 as defined by integrating under the C—H stretching peak in the FTIR spectra from 3170-2750 cm−1 and dividing the integrated peak area by the film thickness in microns.
A high extinction coefficient and/or emissivity are indicative of greater absorptivity of the film, and less transparency which minimizes reflectance variations from the substrate. Additionally, the amorphous carbonitride (ACN) film can be optimized to possess minimal stress in order to avoid delamination during deposition, and anneals.
The applicants of the present invention have discovered through extensive experimentation that by reducing the hydrocarbon content in the film one can increase the extinction coefficient and thus increase the absorptivity of the film. Reduced hydrocarbon content has the additional benefit of minimizing the outgassing during anneals, and increasing the tool life as evidenced by a film shrinkage of less than 15% after a 1000° C., 1 minute anneal in N2.
In one aspect of the invention, an improved absorber film comprising, consisting essentially of, or consisting of, amorphous carbonitride is provided that has superior absorbing properties than existing absorbing films. The improved amorphous carbonitride film has an extinction coefficient (k) of greater than 0.15, and an emissivity of greater than 0.8 and a minimum of hydrocarbon content as observed by FTIR.
In another aspect of the invention, a method of forming such an amorphous carbonitride film is provided that includes a low-temperature deposition process. By “low-temperature”, it is meant a deposition process that is performed at a deposition temperature of less than, or equal to 450° C.
In one embodiment of the invention, an improved absorber film having at least an extinction coefficient (k) of greater than 0.15, and an emissivity of greater than 0.8 can be deposited by plasma enhanced chemical vapor deposition (PECVD) by introducing a carbon precursor source, an oxidant and a nitrogen source into a reactor chamber including a substrate. The introduction of the carbon precursor source, oxidant and nitrogen source produces amorphous carbonitride films of the desired properties at deposition temperatures of less than, or equal to 450° C.
In another embodiment of the invention, an amorphous carbonitride film can be deposited by plasma enhanced chemical vapor deposition (PECVD) by introducing a carbon precursor source, and a nitrogen source without an oxidant into a reactor chamber including a substrate. The introduction of the carbon precursor source and nitrogen source, without the oxidant, produces amorphous carbonitride films of the desired properties at deposition temperatures of less than, or equal to 450° C.
In yet another embodiment of the invention, an amorphous carbonitride film can be deposited by plasma enhanced chemical vapor deposition (PECVD) by introducing a single carbonitride precursor with both carbon and nitrogen in the molecule, into a reactor chamber including a substrate. The introduction of the single carbonitride precursor produces amorphous carbonitride films of the desired properties at deposition temperatures of less than, or equal to 450° C.
In still another embodiment of the invention, an amorphous carbonitride film can be deposited by plasma enhanced chemical vapor deposition (PECVD) by introducing a single carbonitride precursor with both carbon and nitrogen in the molecule and an oxidant, into a reactor chamber including a substrate. The introduction of the single carbonitride precursor and an oxidant produces amorphous carbonitride films of the desired properties at deposition temperatures of less than, or equal to 450° C.
The improved ACN films disclosed herein can provide adequate laser energy absorption properties and can have the advantage of a minimum of inherent hydrocarbon content (a normalized hydrocarbon content less than 3 as defined by integrating under the C—H stretching peak in the FTIR spectra from 3170-2750 cm−1 and dividing the integrated peak area by the film thickness in microns.). Reduced hydrocarbon content improves film opacity, and minimizes outgassing during laser and arc anneals, which is highly desirable.
The present invention, which provides a low-temperature amorphous carbonitride (ACN) absorbing film, will now be described in greater detail by referring to the following discussion and drawings that accompany the present application. It is noted that the drawings of the present application are provided for illustrative purposes only and, as such, the drawings are not drawn to scale.
In the following description, numerous specific details are set forth, such as particular structures, components, materials, dimensions, processing steps and techniques, in order to provide a thorough understanding of the present invention. However, it will be appreciated by one of ordinary skill in the art that the invention may be practiced without these specific details. In other instances, well-known structures or processing steps have not been described in detail in order to avoid obscuring the invention.
It will be understood that when an element as a layer, region or substrate is referred to as being “on” or “over” another element, it can be directly on the other element or intervening elements may also be present. In contrast, when an element is referred to as being “directly on” or “directly over” another element, there are no intervening elements present. It will also be understood that when an element is referred to as being “connected” or “coupled” to another element, it can be directly connected or coupled to the other element or intervening elements may be present. In contrast, when an element is referred to as being “directly connected” or “directly coupled” to another element, there are no intervening elements present.
Before discussing the present invention in greater detail, the applicants determined through experimentation that in order to achieve a sufficient amorphous carbon only absorbent film, as defined by a k greater than 0.15, an emissivity of about 0.8 or greater, and a film with a minimum of hydrocarbon in it as observed by FTIR, it was necessary to deposit an amorphous carbon only layer (ACL) at 550° C. This is undesirable as the constantly shrinking sizes of transistors put an unavoidable limitation on the processing temperatures of devices. When scaling down the dimensions of metal oxide semiconductor field effect transistor (MOSFET) devices, ultra-shallow contacts and extremely abrupt junctions between the source/drain electrodes and the channel are needed in order to suppress short channel effects. At the same time, the source/drain contacts must be highly doped to keep parasitic resistances as small as possible. Current MOSFET fabrication schemes employ ion implantation for the amorphization and subsequent dopant introduction into a silicon crystal lattice. Silicon amorphization reduces dopant atom channeling during implantation, thereby allowing ultra-shallow junction formation. Although ion implantation offers a number of advantages, the inherent damage to the crystal lattice structure contributes to the mobility degradation in the final device structures. Lattice repair via the application of an annealing step is thus essential. The applicants of the present disclosure have discovered that preamorphized silicon (PAI) regrowth during deposition of the amorphous carbon layer at 550° C. (Sample 1, Table 1) hinders dopant activation at higher subsequent anneals. During the ACL deposition process, the PAI growth rate for implanted wafers is very significant.
One potential solution is to lower the deposition temperature of amorphous carbon only films, however as the deposition temperature of the amorphous carbon only films was decreased below 550° C., hydrocarbon content in the film increased rapidly which reduced the absorptive capabilities of the film, k was reduced and emissivity was reduced. As detailed in Table 1, the normalized hydrocarbon content rapidly increases as the deposition temperature is reduced from 550° C. to 480° C. and 400° C. As summarized in Table 1, the k decreased with lower deposition temperature.
FTIR analysis of the resultant amorphous carbon only films (See,
The increased hydrocarbon content lowered the extinction coefficient (k) of the amorphous carbon only films and resulted in a higher level of outgassing during laser and flash anneals. Higher extinction coefficient (k) is desirable because it results in greater absorbance and minimizes reflectance variations from the underlying substrate.
The applicants have also discovered that the overall higher hydrocarbon content adversely affects the optical properties of the film, and lowers the extinction coefficient (k), and the emissivity of the film making the film more transparent to the impinging laser.
In one aspect of the present invention, an improved electromagnetic radiation absorber is provided that comprises, consists essentially of, or consists of, an amorphous carbonitride (ACN) film having an extinction coefficient of greater than 0.15, and an emissivity of greater than 0.8. In some embodiments of the invention, the amorphous carbonitride film can be characterized as having a low hydrocarbon content as observed by FTIR. ACN films having the low hydrocarbon content, minimize outgassing during a subsequent laser annealing or flash annealing process. The ACN films can be easily removed after annealing by plasma oxygen ashing. Such an amorphous carbonitride film represents an improvement over conventionally used amorphous carbon only films.
Reference is now made to
When a semiconductor material is employed as an element of substrate 10, the semiconductor material can include, but is not limited to Si, Ge, SiGe, SiC, SiGeC, GaAs, GaN, InAs, InP and all other III/V or II/VI compound semiconductors. The semiconductor material may also comprise an organic semiconductor or a layered semiconductor such, as for, example, Si/SiGe, a silicon-on-insulator (SOI), a SiGe-on-insulator (SGOI) or a germanium-on-insulator (GOI). In some embodiments of the invention, the semiconductor material is a Si-containing semiconductor material that includes silicon. The semiconductor material may be doped, undoped or contain doped and undoped regions therein. The semiconductor material can include a single crystal orientation or it may include at least two coplanar surface regions that have different crystal orientations (the latter semiconductor material can be referred to as a hybrid orientation substrate). The semiconductor material can be process utilized techniques well known to those skilled in the art to include one or more well regions, and/or one or more isolation regions. The semiconductor material can also be processed utilizing techniques well known to those skilled in the art to include one or more semiconductor devices atop an uppermost surface of the semiconductor substrate.
When a dielectric material is employed as an element of substrate 10, the dielectric material can include an organic insulator, an inorganic insulator or any combination thereof including multilayers. In one embodiment, the dielectric material is an oxide, a nitride, and/or an oxynitride. In yet another embodiment, the dielectric material has a dielectric constant, as measured in a vacuum of equal to, or greater than, the dielectric constant of silicon oxide.
When a conductive material is employed as an element of substrate 10, the conductive material can include, for example, a doped Si-containing material, an elemental metal, an alloy of an elemental metal, a metal silicide, a metal nitride or any combination thereof including multilayers.
It is observed that the semiconductor material, dielectric material and/or conductive material may be part of a device or structure, which may be discrete or interconnected.
As stated above, and as illustrated in
The amorphous carbonitride film 12 also has an emissivity of greater than 0.8. Typically, the amorphous carbonitride film 12 has an emissivity from 0.8 to 0.95. More typically, film 12 has an emissivity from 0.85 to 0.92.
A further feature of the amorphous carbonitride film 12 is that it has a minimum hydrocarbon content as measured by FTIR. By “a minimum of hydrocarbon content as observed by FTIR” it is meant a normalized hydrocarbon content less than 3 as defined by integrating under the C—H stretching peak in the FTIR spectra from 3170-2750 cm−1 and dividing the integrated peak area by the film thickness in microns.
The thickness of the amorphous carbonitride film 12 that is formed may vary depending on the conditions in which the amorphous carbonitride film 12 is deposition. Typically, the amorphous carbonitride film 12 that is formed atop the substrate 10 has a thickness from 50 nm to 5000 nm, with a thickness from 100 nm to 500 nm being more typical. Other thicknesses can also be employed so long as the thickness does not interfere with the amorphous carbonitride film being employed as an absorbing layer for exposures to various wavelengths of electromagnetic radiation including, for an example, an exposure wavelength between 190 nm and 1000 nm.
The amorphous carbonitride film 12 can be formed utilizing any low temperature (e.g., of less than, or equal to, 450° C.) deposition process. Suitable examples of low temperature deposition processes that can be used in forming the amorphous carbonitride film 12 include, but are not limited to chemical vapor deposition (CVD) and plasma enhanced chemical vapor deposition (PECVD). In one embodiment of the invention, the amorphous carbonitride film 12 is formed utilizing a low temperature PECVD process.
As stated above, any deposition process can be used in forming the amorphous carbonitride film 12 having the above properties so long as the deposition temperature is less than, or equal to, 450° C. In one embodiment of the invention, the amorphous carbonitride film 12 having the above properties can be produced using a deposition temperature from 250° C. to 450° C. In yet another embodiment of the invention, the amorphous carbonitride film 12 having the above properties can be produced using a deposition temperature from 350° C. to 400° C.
In one embodiment of the invention, the amorphous carbonitride film 12 having the above properties can be produced using a combination of at least a carbon precursor source, and a nitrogen source. An oxidant is also typically, but not necessarily always, employed to facilitate decomposition, fragmentation and hydrogen removal. Such a combination of gases can be referred to herein as a reactant gas mixture. The reactant gas mixture may further include an inert gas such as helium or argon. The inert gas may be introduced as a separate component of the reactant gas mixture or it can be present within at least one of the carbon precursor source, the nitrogen source and the oxidant.
In some embodiments of the invention, the amorphous carbonitride film 12 having the above properties can be produced using a single carbonitride precursor that includes both carbon and nitrogen in the molecule. An oxidant is also typically, but not necessarily always, employed in this embodiment of the invention as well.
The carbon precursor source that can be employed in the invention is selected from alkanes, alkenes, alkynes and mixtures thereof. The carbon precursor sources may be linear, branched, and/or cyclic. In one embodiment of the invention, the carbon precursor sources have a minimal C/H ratio. By “minimal C/H ratio” it is meant less than 3 hydrogens for every carbon atom in the precursor.
The term “alkane” denotes a chemical compound that consists only of the elements carbon and hydrogen (i.e., hydrocarbons), wherein these atoms are linked together exclusively by single bonds (i.e., they are saturated compounds). In one embodiment of the invention, the alkane includes from 1 to 22, typically from 1 to 16, more typically, from 1 to 12 carbon atoms.
The term “alkene” denotes an unsaturated chemical compound containing at least one carbon-to-carbon double bond, In one embodiment, the alkene is an acyclic alkene, with only one double bond and no other functional groups. In such an embodiment, the acylic alkene forms a homologous series of hydrocarbons with the general formula CnH2n, wherein n is an integer from 2 to 22, typically 2 to 16, more typically 2 to 12 carbon atoms.
The term “alkyne” denotes a hydrocarbon that has a triple bond between two carbon atoms, with the formula CnH2n-2, wherein n is an integer from 2 to 22, typically 2 to 16, more typically 2 to 12 carbon atoms. Alkynes are traditionally known as acetylenes.
Some examples of typical carbon precursor sources that can be employed in forming the amorphous carbonitride film 12 include, but are not limited to ethylene, propylene, butene, acetylene, and/or methyl acetylene. In one embodiment, propylene (C3H6) is employed as the carbon precursor source.
The nitrogen source that can be employed in forming the amorphous carbonitride film 12 can be selected from nitriding sources including, but not limited to nitrogen, ammonia, amines, azides, and/or hydrazines. In one embodiment of the invention, nitrogen (N2) and/or ammonium (NH3) is employed as the nitrogen source. The oxidant that can be employed in forming the amorphous carbonitride film 12 can be selected from oxidizing sources including oxygen, nitrous oxide, water, and/or ozone. In one embodiment of the invention, oxygen is employed as the oxidant.
Although any combination of carbon precursor source, nitrogen source and oxidant can be employed in forming the amorphous carbonitride film 12, one embodiment of the present invention employs propylene (C3H6) as the carbon precursor source, nitrogen (N2) or ammonium (NH3) as the nitrogen source, and oxygen (O2) as the oxidant. Such a reactant gas mixture can be used as is or diluted with an inert gas such as helium or argon.
In one embodiment of the present invention, as mentioned above, a single carbonitride precursor that includes both carbon and nitrogen in the molecule can be used to form the amorphous carbonitride film 12. One example of such a single carbonitride precursor that can be employed in the present invention is acetonitrile (C□N). Other single carbonitride precursors beside acetonitrile can be used as long as the precursor includes carbon and nitrogen atoms therein. When a single carbonitride precursor is employed, an oxidant, as described above can also be used. The single carbonitride precursor can be used as is or diluted with an inert gas such as helium or argon. Other potential single carbonitride precursors include heterocyclic compounds such as pyrrole, imidazole, pyrazole, pyridine, pyrazine, pyrimidine, pyridazine, pyrazinyl, imidazolyl, pyrimidinyl, piperazine, triazine, amines such as methylamine, diamine ethane, diamine methane, aminoethane, aminopropane, azo, hydrzo, dimethylhydrazine, alkylazo compounds such as diethyldiazene, and amidines including acetamidine.
The gases may be introduced separately into a reactor chamber of a deposition tool, or some, or all of the gases may be admixed prior to being introduced into a reactor chamber of a deposition tool. Typically, the various gases are admixed in a mixing system prior to being introduced into the reactor chamber of a deposition tool. The reactor chamber of the deposition tool typically includes a substrate holder in which the substrate 10 is positioned within the reactor chamber. The distance of the substrate holder from the nozzle (or nozzles or showerhead) in which the reactant gas mixture (or gasses) is (are) introduced may vary within typical ranges well known to those skilled in the art. Typically, the substrate holder and hence substrate 10 is positioned a distance from 600 mils to 200 mils from the nozzle (or nozzles).
In addition, the gases may be introduced in a deposition tool in different stochiometries. In some embodiments of the invention, the carbon source may be introduced at a flow rate between 50 sccm and 2000 sccm, the nitrogen source may be introduced at a flow rate between 10 sccm and 50000 sccm, and the oxidant may be introduced at a flow rate between 10 sccm and 500 sccm. In another embodiment of the invention, the carbon source may be introduced at a flow rate between 50 sccm and 5000 sccm, the nitrogen source may be introduced at a flow rate between 10 sccm and 5000 sccm, and the oxidant may be introduced at a rate between 1 sccm and 1000 sccm. The inert gas may be introduced at a flow rate from 50 sccm to 50000 sccm.
In some further embodiments of the invention, the process pressure used in forming the amorphous carbonitride film 12 can be varied from 1 torr to 8 torr. In yet another embodiment of the invention, the substrate temperature during the deposition process can be fixed at 400° C. or 350° C. In an even further embodiment of the invention, the plasma can be generated using either a low frequency radio frequency (LFRF) plasma source at 100 MHz or a high frequency radio frequency HFRF plasma source at 13.56 GHz. The process pressure, substrate temperature and power used in generating the plasma are exemplary and other conditions are possible provided the selected conditions are capable of forming an amorphous carbonitride film having an extinction coefficient of greater than 0.15, an emissivity of greater than 0.8 and a minimum of hydrocarbon content.
In one embodiment of the invention, the amorphous carbonitride film 12 is formed by positioning substrate 10 within a parallel plate plasma enhanced chemical vapor deposition chamber. A reactant gas mixture, as defined above, is then introduced into the reactor chamber and thereafter an amorphous carbonitride film 12 having an extinction coefficient of greater than 0.15, an emissivity of greater than 0.8 and a minimum of hydrocarbon is formed.
Reference is now made to
The amorphous carbonitride films described hereinabove can be used for absorbing electromagnetic radiation having one or more wavelengths between 190 nm and 1000 nm. The amorphous carbonitride films described hereinabove can also be used in conjunction with conventional laser anneals to improve the heating uniformity across a plurality of surfaces.
The following examples are provided to illustrate the formation of amorphous carbonitride films having an extinction coefficient (k) of greater than 0.15, an emissivity of greater than 0.8 and a minimum of hydrocarbon. The following examples illustrate some advantages and/or improvements that can be obtained from such amorphous carbonitride films.
Amorphous carbonitride films of the current invention were deposited onto an oxide coated silicon substrate using the following conditions: 400° C. deposition temperature, 500 watts LFRF, 220 mils, and 3 torr pressure. Propylene (C3H6) was fixed at 1000 sccm, while the reactant gases (i.e., nitrogen and ammonia), and the oxidant (N2O) were varied as detailed in Table 2. Refractive index (n) and extinction coefficient (k) were measured using an n&k tool.
As summarized in the Table 2, for Sample 1 deposited from propylene and N2O only, the extinction coefficient was 0.15. However, by formation of the carbonitride in Sample 2 of this example with the addition of nitrogen, and ammonia the extinction coefficient, k was increased to 0.19. In Sample 3 of this example an additional increase in N2O increased k to 0.3. The oxidant, N2O in this case was essential in increasing k.
Amorphous carbonitride films of the current invention were deposited onto an oxide coated silicon substrate with deposition conditions as summarized in Table 3 at 400° C. Propylene (C3H6) was fixed at 500 sccm, oxygen was fixed at 50 sccm, mil spacing was fixed at 220 mils and pressure was fixed at 4 torr. Refractive index (n) and extinction coefficient (k) were measured using an n&k tool. Oxygen was used as the oxidant as shown in Table 3.
Switching from HFRF to LFRF plasma power resulted in a halving of the normalized hydrocarbon content as observed by FTIR. The normalized hydrocarbon content is defined by integrating under the C—H stretching peak in the FTIR spectra from 3170-2750 cm−1 and dividing the integrated peak area by the film thickness in microns.
Thin layers of amorphous carbonitride (ACN) films were deposited on top of each other with varying plasma frequencies to achieve thicker films. Such a structure is shown, for example, in
Surface resistance measurements were taken with the last four conditions. As shown in
As shown in
The effect of He dilution on k was also observed, and it was determined that by increasing the He dilution resulted in an ACN film having a larger k. In this example, the deposition temperature was 350° C., 220 mil, the pressure was 4 torr. Table 6 includes the other conditions used in this example. As shown in the table by increasing He flow k can be increased.
Amorphous carbonitride films of this invention were deposited at 350° C. with varying amounts of oxygen and other conditions as mentioned in this example. The carbon precursor, i.e., C3H6, was flowed at 350 sccm, N2 at 2500 sccm, NH3 at 300 sccm, He at 5000 sccm and a LFRF power of 500 watts (approximately 100 MHz) and a pressure of 4 ton were employed. The optical properties measured on the films indicated that extinction coefficient of such films were very high. See Table 7.
These films were then subjected to flash lamp annealing and SEM micrographs were obtained on ACN films after flash anneal applications. It was evident from the SEM micrographs that ACN films deposited at 350° C. survived the flash lamp annealing and also they are very conformal with intact microstructure after annealing. One such SEM micrograph is shown, for example, in
As shown in
Reduction in reflectivity enables higher front surface temperatures during flash anneal which, in turn, enables lower backside substrate temperatures to minimize dopant movement, source/drain junction profile broadening and increased junction depth. Shown in
Flash anneal and laser spike anneals have been introduced to activate dopants in milliseconds. Boron dopant deactivation is proposed to be due to the formation of inactive boron-interstitial clusters (BICs) as a result of the release of silicon interstitials from the end-of-range (EOR) defects upon annealing. Carbon atoms are reported to be an effective sink for silicon interstitials and that extended defect levels are reduced or eliminated with increasing carbon dose. See, Chyiu Hyia Poon, JOURNAL OF APPLIED PHYSICS 103, 084906 —2008. In this example, the carbonitride absorber layer deposited at 350° C. of this invention (Sample 2, Table 7) was employed as an efficient absorber coating for a flash anneal so that the arc-lamp light from the flash anneal is efficiently absorbed and subsequently increased the temperature jump for the SOI device substrate to achieve improved C substitution in SiC source/drain and to maximize junction activation for 22 nm CMOS technology devices and beyond.
Shown in
While the present invention has been particularly shown and described with respect to preferred embodiments thereof, it will be understood by those skilled in the art that the foregoing and other changes in forms and details may be made without departing from the spirit and scope of the present invention. It is therefore intended that the present invention not be limited to the exact forms and details described and illustrated, but fall within the scope of the appended claims.
