The present invention relates to non-volatile semiconductor memory chips and, more particularly, to magnetoresistive memory cells (MRAM cells) for use in a semiconductor integrated circuit.
In recent years, great efforts have been made to bring new non-volatile memory technology based on magnetoresistive random access memory cells into commercial use. A magnetoresistive memory cell includes a layered structure of ferromagnetic layers separated by a non-magnetic tunneling barrier and arranged into a magnetic tunnel junction (MTJ). Digital information is not maintained by power, as in conventional DRAMs, but rather by specific directions of the magnetic moment vectors in the ferromagnetic layers. More specifically, in an MRAM cell, magnetization (i.e., the magnetic moment vector) of one ferromagnetic layer (“reference layer”) is magnetically fixed or pinned, while magnetization of the other ferromagnetic layer (“free layer”) can switch between two preferred directions, i.e., the same and opposite directions with respect to the fixed magnetization of the reference layer. Depending upon the magnetic states of the free layer, i.e., parallel or antiparallel states of its magnetization with respect to the magnetization of the reference layer, the magnetic memory cell exhibits two different resistance values in response to a voltage applied across the magnetic tunnel junction barrier. The particular resistance of the memory cell thus reflects the magnetization states of the free layer, wherein the resistance is “low” when the magnetization is parallel, and “high” when the magnetization is antiparallel. Accordingly, detection of changes in resistance allows access to information stored in the magnetic memory element, i.e., read information from the magnetic memory cell.
An MRAM cell is written to by application of magnetic fields created by bi- or uni-directional currents flowing through current lines, typically, bit and/or write word lines, to magnetically align the free layer magnetic moment vector in a parallel or an antiparallel state in relation to the fixed magnetization. If a magnetic field in a direction opposite to the magnetization direction of the free layer is applied, then the magnetic moment vector of the free layer is reversed in case a critical magnetic field value is reached (also referred to as reversal magnetic field). The value of the reversal magnetic field is determined from a minimum energy condition. Assuming that a magnetic field applied to the direction of the hard axis of magnetization is represented by Hx and a magnetic field applied to the direction of the easy axis of magnetization is represented by Hy, then a relationship Hx(2/3)+Hy(2/3)=Hc(2/3) is established, where Hc represents the anisotropic magnetic field of the free layer. Since this curve forms an astroid on an Hx-Hy-plane, it is called an astroid curve. As can be seen from above relationship, a composite magnetic field enables the selection of a single MRAM-cell in case the sum of both magnetic fields at least amounts to the reversal magnetic field. Based on the above, the “Stoner-Wohlfahrt”-switching scenario is typically used for switching MRAM cells, and is well-known to those skilled in the art, and is not explained in further detail here.
In recent years, magnetoresistive tunneling junction memory cells where the free layer is designed to be a system of ferromagnetic free layers that are antiferromagnetically coupled. The number of antiferromagnetically coupled layers are selected to increase the effective magnetic switching volume of the MRAM device has been described. For the switching of such magnetoresistive memory cells, another switching scenario, i.e., “adiabatic rotational switching,” is typically used. Adiabatic rotational switching relies on the “spin-flop” phenomenon, which lowers the total magnetic energy in an applied magnetic field by rotating the magnetic moment vectors of the antiferromagnetically coupled ferromagnetic free layers. More specifically, assuming that a bit line magnetic field HBL and a word line magnetic field HWL, respectively, arrive at the MRAM cell for its switching, and that antiferromagnetically coupled magnetic moment vectors M1 and M2 exhibited by the ferromagnetic free layers are inclined at a 45° angle to the word and bit lines, respectively, a timed switching pulse sequence of applied magnetic fields in a typical “toggling write” mode is as follows:
In modern portable equipment, such as portable computers, digital still cameras, and the like, which require large memory performance, one of the most important issues for MRAM cells is to provide high-dense arrays of MRAM cells. However, when scaling down MRAM cells based on antiferromagnetically coupled free layers, coupling of the free layers increases dramatically, thus requiring relatively high spin-flop magnetic fields for switching the cells (i.e., toggling around the toggling point as described above).
A magnetoresistive memory element allowing a memory element size down-scale without thereby causing an increase of the coupling between antiferromagnetically coupled ferromagnetic free layers of the magnetic free system is desirable.
A magnetoresistive memory element, which has a stacked structure, includes a tunneling barrier made of a non-magnetic material and first and second magnetic systems. The first magnetic system includes a ferromagnetic tunneling junction reference layer having a fixed magnetic moment vector arranged on one side of the tunneling barrier adjacent the non-magnetic material. The second magnetic system includes a ferromagnetic tunneling junction free layer having a free magnetic moment vector being arranged on an opposite side of the tunneling barrier adjacent the non-magnetic material. The free magnetic moment vector switches between the same and opposite directions with respect to above fixed magnetic moment vector. In the memory element, the tunneling barrier and the tunneling junction free and tunneling junction reference layers arranged on both sides of the barrier together form a magnetoresistive tunneling junction (MTJ). In the memory element of the invention, the tunneling junction free layer is one of a plurality of N ferromagnetic free layers, which are antiferromagnetically coupled, where N is an integer greater than or equal to two.
According to a characteristic feature of the invention, first magnetic system is sandwiched between the tunneling junction free layer and at least one of the ferromagnetic free layers of the second magnetic system that antiferromagnetically coupled therewith. Therefore, the first magnetic system between the antiferromagnetically coupled ferromagnetic free layers and using the a further down-scale of the memory element is possible without the undesired effects on the coupling of antiferromagnetically coupled free layers. In other words, the first magnetic system is used as a “spacer” in between the antiferromagnetically coupled free layers. Furthermore, long etching times and an increased critical dimensional loss can be avoided.
In an exemplary embodiment of the invention, the first magnetic system and the ferromagnetic free layer, that is antiferromagnetically coupled with above tunneling junction free layer, are separated by a first underlayer. The first underlayer is used as a diffusion barrier and seed layer for the stack growth of the first magnetic system. Furthermore, the first underlayer is used as an etch stop layer in case etching of the first magnetic system and the ferromagnetic free layer, which is antiferromagnetically coupled with the tunneling junction free layer, is decoupled.
In another exemplary embodiment of the invention, the ferromagnetic free layer, which is antiferromagnetically coupled with the tunneling junction free layer, is sandwiched between the first underlayer and a second underlayer. The second underlayer is used as a diffusion barrier and seed layer for stack growth of the ferromagnetic free layer, which is antiferromagnetically coupled with the tunneling junction free layer. Each one of the first and second underlayers may have several sublayers, as necessary.
In yet another exemplary embodiment of the invention, the first magnetic system has a first subsystem with the tunneling junction reference layer having a fixed magnetic moment vector and a second subsystem for fixing (pinning) of the fixed magnetic moment vector. Each of above subsystems may include one or a plurality of layers.
In another exemplary embodiment of the invention, in order to a further decrease the spin-flop magnetic switching field(s), a ferromagnetic offset field layer exhibits a magnetic moment vector adapted to shift a toggling point for switching of above free magnetic moment vector towards a smaller spin-flop field. In other words, in a coordinate plane spanned by the magnetic fields arriving at the memory element of orthogonally aligned first and second current lines for switching the element, such as bit and word lines, the magnetic field of such a ferromagnetic offset field layer shifts the toggling point for switching the memory element towards the origin of coordinates. To achieve this effect, the ferromagnetic offset field layer, for instance, exhibits a magnetic moment vector along an easy axis direction of the tunneling junction free layer. The ferromagnetic offset field layer (i.e., first magnetic moment vector) is pinned by the second reference subsystem. Alternatively, there is a further multi-purpose layer system arranged adjacent the ferromagnetic offset field layer.
In yet another exemplary embodiment of the invention, a side wall spacer is arranged around at least a part, or the whole, of the perimeter (peripheral surface) of at least the ferromagnetic tunneling junction free layer. At least surrounding the tunneling junction free layer, the side wall spacer surrounds several or all layers included in the stacked structure of the memory element of the invention. In particular, the ferromagnetic layers of the second magnetic system and the layers laying between the ferromagnetic layers are surrounded. Providing a side wall spacer allows for a linear dimension of the tunneling junction free layer in a direction perpendicular to a stacking direction of the stacked structure, which is less than a linear dimension ferromagnetic free layer which is antiferromagnetically coupled therewith. By this measure, there is a further reduction of dipole coupling between antiferromagnetically coupled ferromagnetic free layers and a further lowered spin-flop magnetic field. Similarly, a linear dimension of the tunneling junction free layer in a direction perpendicular to a stacking direction of the stacked structure is less than a linear dimension of the ferromagnetic offset field layer, and results in a relatively more homogeneous magnetic stray field arriving at the tunneling junction free layer. Apart from enabling different linear dimensions of the layers, especially in structuring the second magnetic system, the side wall spacer forms a “shield” at least around the tunneling junction ferromagnetic free layer and reduces etch damage of the tunneling junction free layer or tunneling barrier due to etch chemistry and undesired precipitates during etching.
The accompanying drawings, which are incorporated in and constitute a part of the specification, illustrate presently preferred embodiments of the invention, and together with the general description given above and the detailed description given below, serve to explain the principles of the invention. Embodiments of the present invention will be described in detail below with reference to the accompanying drawings, where like designations denote like elements.
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In previous embodiments of the memory element of the invention, the ferromagnetic layers FL1, FL2 are, for instance, made of one or more materials selected from NiFe, CoFeB and CoFe/Py, the first and second underlayers UL1, UL2 are, for instance, made of one or more materials selected from TaN/NiFeCr, Ru, Ta, NiFeCr and Ta/TaN/Ru, the ferromagnetic offset field layer OL1 is, for instance, made of one or more materials selected from CoFeB, NiFe and CoFe/Ru/CoFeB, the reference sub layer Ra is, for instance, made of one or more materials selected from Co/CoTb and CoFe/Ru/CoFe/CoFeB, the reference sub layer Rb is, for instance, made of one or more materials selected from PtMn, Ru, TaN/Ta/PtMn and Ru/NiFeCr/PtMn, the multi-purpose system MPS1 may for instance be made of one or more materials selected from Ru, TaN/Ta/PtMn and Ru/NiFeCr/PtMn, the side wall spacer IS1 is, for instance, made of one or more materials selected from SiO2/SiN and Al2o3/SiO2, and, the tunneling barrier B1 is, for instance, made of one or more materials selected from Al2O3, MgO and BN, however, given as examples, there is no limitation to such materials.
While the invention has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof. Accordingly, it is intended that the present invention covers the modifications and variations of this invention provided they come within the scope of the appended claims and their equivalents.