This application claims priority to foreign French patent application No. FR 1762569, filed on Dec. 20, 2017, the disclosures of which are incorporated by reference in their entirety.
The field of the invention is that of III-V components and relates to a process for producing a structure for photonic applications, for example a laser structure and more particularly a heterostructure of III-V layer on silicon substrate.
The heterogeneous integration for example of a III-V laser on an SOI substrate containing passive and active elements (waveguide, modulator, etc.) made of silicon generally requires the transfer of crude III-V material chips onto an InP substrate, which must then be cut and bonded.
Currently this transfer according to the prior art may be carried out according to various processes but utilizes in every instance the use of a III-V material substrate (generally an indium phosphide substrate) supporting the various epitaxial layers necessary for obtaining components made of III-V materials.
The main production steps are:
In all cases, the III-V material chips are supported by an InP substrate of which the initial diameter of the wafer is limited, requiring the removal of the support portion (InP substrate) which represents around 98% of the thickness.
More specifically,
It is necessary to have a handle because the receiving substrate has been, beforehand, thinned (on the back face) of all the silicon portion serving as support, the film of a few μm in thickness containing the photonic active and passive elements, having a diameter of 300 mm, not being able to be handled without such a handle.
The major problems encountered are the following:
In this case the major problems are:
In this context and to solve the aforementioned drawbacks, the subject of the present invention is a process using a substrate commonly referred to as a wafer, which may be silicon or SOI as a growth substrate (or else identified as a donor substrate) as a replacement for a substrate made of III-V material (generally InP). The Applicant uses for this purpose a technique described in particular in U.S. Pat. No. 8,173,551 and comprising the epitaxy of III-V material on a first silicon substrate, so as to preform elementary substrates of III-V materials (and no longer use bulk substrates of III-V materials), on which active layers constituting, for example, a laser, can be produced, before the assembly is transferred to a second substrate that may comprise passive and active elements (waveguide, modulator, etc.).
The process of the invention has, in particular, the following advantages:
More specifically, the subject of the present invention is a process for fabricating a heterostructure comprising at least one elementary structure made of III-V material on the surface of a silicon-based substrate successively comprising:
According to variants of the invention, said at least elementary structure is an active photonic elementary structure (laser structure with different wavelengths, modulator, photodetector, etc.).
According to variants of the invention, said at least elementary structure is a passive elementary structure (waveguide, multiplexer, etc.).
According to variants of the invention, said heterostructure may comprise at least one active photonic elementary structure and at least one passive elementary structure.
Advantageously, planarization or chemical-mechanical polishing (CMP) operations can be provided, in order to remove, for example, any non-active layers of III-V materials located above the surface plane of the pattern and to obtain a bonding surface consisting of a single plane and meeting the bonding criteria (flatness, roughness, etc.), this operation being prior to the transfer and assembly operation.
The first epitaxy operation may advantageously be followed by a polishing operation and this being before the second pattern is produced, it being possible for this polishing operation to be of chemical-mechanical type (CMP), enabling the excess of III/V material(s) overflowing from the pattern to be removed.
The polishing step following the second epitaxy operation can perform two functions: remove the excess of III-V material and prepare the surface before bonding. These may be two different processes using different chemistries and process conditions.
The substrate may typically be Si, SOI, Si1-xGex with 0<x<1.
According to variants of the invention, the production of said first pattern comprises:
According to variants of the invention, the production of said first pattern comprises the production of at least one complex primary opening having at least:
According to variants of the invention, the method comprises, for producing said at least first complex opening:
The sacrificial material may advantageously be Si1-xGex with 0<x<1, which is polycrystalline or amorphous. Advantageously, its removal can be carried out in a mixture of gaseous HCl and dihydrogen at high temperature (typically >500° C., the chosen temperature depending on the Ge concentration of said sacrificial layer).
Advantageously, said assembly operation comprises a bonding operation, which may be a molecular bonding operation.
Another subject of the present invention is a process for producing a multiplicity of III-V devices on the same medium, the transfer of these devices being carried out collectively and allowing significant gains in the alignments. The relative alignment of the devices with one another originates from the accuracy of the photolithography processes.
More specifically, this process comprising producing a set of first patterns having first openings in a dielectric material on the surface of a first silicon-based substrate;
The epitaxy steps may advantageously be followed by a polishing operation, which may be of chemical-mechanical type (CMP).
Thus, the first epitaxial operation may be followed by a polishing operation and this being before the second patterns are produced, it being possible for this polishing operation to be of chemical-mechanical type (CMP), enabling the excess III/V material(s) overflowing from the patterns to be removed.
A polishing step following the second epitaxy operation can perform two functions: remove the excess of III-V material and prepare the surface before bonding. These may be two different processes using different chemistries and process conditions.
Another subject of the invention is a process in which several different elementary structures operating at different wavelengths are produced.
To do this, said process may comprise successive epitaxy operations for producing the various elementary structures, for example photonic active elementary structures operating at different wavelengths, said operations being carried out successively at decreasing epitaxy temperatures.
Advantageously, the interface has a support commonly referred to as a “handle” on a face opposite to said second substrate. One subject of the invention is thus a process according to the invention in which said second silicon-based substrate is removed before assembly to leave exposed the interface that may comprise passive and/or active elements, said interface being on the surface of said support.
According to variants of the invention, in order to produce photonic active elementary structures, multiple quantum well structures made of III-V material(s) are advantageously produced.
According to variants of the invention, the elementary base layer made of III-V material may advantageously be InP.
Another subject of the invention is a heterostructure obtained according to the process of the invention, it being possible for said heterostructure to advantageously comprise at least one structure of laser or photodetector or modulator type.
Another subject of the invention is a set of elementary structures made of III-V material on the surface of a silicon-based substrate obtained according to the process of the invention, which may advantageously comprise a set of laser structures operating at different wavelengths.
A better understanding of the invention will be obtained and other advantages will become apparent on reading the description which will follow, given without limitation, and by virtue of the figures, among which:
The present invention is described in more detail within the context of active photonic elementary structure(s), but can also be applied within the context of passive elementary structure(s).
The process of the invention exploits the process of epitaxy by crystalline defect trapping (related to the lattice mismatch) making it possible to use a base substrate made of a semiconductor material such as silicon, produced beforehand on which are elementary base layers made of III-V material intended for the epitaxial growth of photonic active elementary structures such as, for example, multiple quantum well structures, of which the choice of the nature of the layers and their thicknesses determine the operating wavelengths.
The elementary base layers made of III-V material can be produced with high aspect ratios advantageously enabling defects related to the heterostructure to be trapped. High aspect ratio growth techniques have been described in U.S. Pat. No. 8,173,551.
The process of the invention may be available in at least the two following alternatives, which are described in detail in the remainder of the description:
The Applicant hereinafter describes various examples of the process according to the invention.
Step 1: a low-cost first substrate 100 made of silicon is used.
Step 2: starting from this first substrate 100, a dielectric layer 200 is produced.
Step 3: openings O1i are produced in the layer 200 so as to define a pattern with openings as illustrated in
Step 4: a first operation for epitaxy of III-V material that may be InP is carried out so as to define elementary base layers made of III-V material: 201i.
The second openings have widths greater than those of the first openings so as to allow the lateral growth of III-V material(s) from the III-V material substrates. The growth defects can advantageously be confined in the cavities (the dislocations are stopped by the walls of the cavity) of the substrates and make it possible to grow III-V material(s) from the substrates 201i. Typically, from an Si substrate, the defects related to the relaxation of the layers are found mainly in {111} crystal planes forming an angle of 54.7° with the surface of the substrate. Thus, if the height of the cavity O1i is greater than tan (54.7°), the defects of these planes can be confined, typically, if the height is more than 1.4 times the width of the cavity. The higher this ratio, the higher the confinement effect.
Step 9: For the purposes of the transfer, this second substrate is positioned on a support referred to as a handle 302 and the assembly operation is carried out with the elementary structure or structures produced at the same time, as illustrated in
Step 10: the lower portion 100 of the first substrate is removed as shown in
Step 11: finally, the portion of the substrate comprising the dielectric 200 and the elementary base layers made of III-V material 201i are removed to release the photonic active elementary structures 202i as also illustrated in
Example of a process of the invention according to the second alternative:
Advantageously, the elementary base layer made of III-V material may be made to comprise a first narrow vertical lower portion capable of trapping growth defects from the first substrate and a wider upper horizontal portion, said lower portion being off-center with respect to said horizontal portion, in order to be able to carry out the growth of the photonic active elementary structure in an offset manner.
Step 1: a low-cost first substrate 100 made of silicon is used.
Step 2: starting from this first substrate 100, a dielectric layer 200 is produced.
Step 3: openings O1i are produced in the layer 200 so as to define a pattern with openings, having a vertical lower portion and a horizontal portion, said lower vertical portion being off-center with respect to said horizontal portion. The box shows an enlargement highlighting the type of straight or beveled sidewalls that can be obtained in the vertical portion of the openings.
Step 4: a sacrificial material is deposited so as to define elements 203i in the previously formed openings. A dielectric layer 200 is then deposited.
Step 5: defined in the dielectric layer 200 are new openings constituting the upper vertical portion of the first complex openings O′1i, while also removing the sacrificial material.
The advantage of this first complex opening lies in the fact that the horizontal portion is partially covered with dielectric, which makes it possible to avoid a subsequent CMP step for making the surface of the elementary base layer made of III-V material uniform.
Step 6: a first operation for epitaxy of III-V material is carried out that makes it possible to form the elementary base layers made of III-V material 201i. The box highlights the offset appearance of the dislocations in the lower vertical portion of the elementary base layer relative to the horizontal portion of said elementary base layer.
Step 7: second openings (not shown) are produced in which new epitaxy operations are carried out in order to produce the photonic active elementary structures 202i.
The following steps of transferring the second silicon-based substrate and active and/or passive components may be identical to those of the first process example described above and are illustrated in
Step 8: the two substrates comprising on the one hand the elementary base layers made of III-V material and on the other hand the support comprising an interface with active and/or passive components are assembled and bonded.
Step 9: the portion 100 is removed from the first substrate, exposing the elementary base layers made of III-V material 201i by a mechanical thinning operation.
Step 10: finally, the portion of the upper substrate comprising the dielectric 200, and the elementary base layers made of III-V material 201i are removed to release the photonic active elementary structures 202i.
Examples of dimensions of the photonic active elementary structures that can be produced according to the process of the invention are illustrated by means of
Typically, the first complex openings O′1i may have surfaces of 50 to 100 μm×500 μm.
The thicknesses of the successive dielectric layers making it possible to define said first complex openings may be respectively 1 μm and 5 μm, as illustrated in
In general, the charge effect corresponds to the difference in thickness observed when a same epitaxy process is performed on (i) an unpatterened substrate, (ii) a patterned substrate, i.e. a substrate partially covered with SiO2 type pattern material.
The thickness obtained is often greater in case (ii). The ratio of thickness in case (ii) to thickness obtained in case (i) defines the charge effect.
In the present invention, an equivalent thickness of 5 to 10 μm on an unpatterned substrate should make it possible to produce a lateral growth of 10 to 50 μm in the cavities by lateral growth on a patterned substrate, thus benefiting from the presence of the charge effect.
The process of the present invention makes it possible to sequence localized epitaxy operations, thus making it possible to produce different photonic active elementary structures, and in particular consisting of different III-V materials or different multiple quantum well structures, so as to fabricate within the same assembly several different photonic functions that can operate at different wavelengths.
It could also be a question of different components (lasers, photodetector, modulator made of III-V).
According to the process of the invention, it is thus possible to produce, owing to each of the epitaxy operations, an optimized component: laser/modulator/photodetector, having a size of the order of a few tens of microns.
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