This application claims priority from European Patent application No. 22187143.7, filed on Jul. 27, 2022, which is incorporated by reference in its entirety.
The present disclosure relates to a method for forming an interconnect structure for an integrated circuit.
Modern circuit fabrication includes processes for forming electrical interconnection structures for interconnecting active and passive devices in a functioning integrated circuit. An interconnection structure may include one or more interconnection levels or tiers, which are formed above a semiconductor substrate. An interconnection level includes horizontal metal paths or lines arranged in an insulating material layer. Metal lines of different interconnection levels may be interconnected by metal vias extending vertically through the insulating layers.
In conventional circuit fabrication, an interconnection level may be formed in what in the art is known as a “dual damascene process”. According to this approach, horizontally extending trenches are etched in the insulating layer. Further, vertically extending via holes are formed in the insulating layer. Thereafter, the trenches and via holes are simultaneously filled with metal to form lines in the trenches and vias in the via holes.
More recently, an alternative approach which may be referred to as a “semi-damascene process” has been proposed wherein metal lines instead are directly etched in a metal layer. Via holes for vias connecting successive interconnect layers are patterned in a dielectric layer in a single-damascene fashion, then overfilled with metal such that a metal layer is formed over the dielectric layer. This metal layer is then masked and etched to form the metal lines.
While the semi-damascene flow removes the need for a chemical mechanical polishing (CMP) of the metal layer, which typically forms part of the dual damascene process, two separate lithography and etching process steps (“litho-etch”) are involved, one for the via hole patterning and one for the direct metal layer etch. Hence, there is still room for more efficient processes for forming interconnect structures.
In light of the above, it is an objective to provide a method for forming an interconnect structure for an integrated circuit which enables forming of horizontal metal lines and vertical metal vias (i.e. metal pillars) in an efficient and reliable manner. Further and alternative objectives may be understood from the following.
According to an aspect of the presently disclosed concept, a method is provided for forming an interconnect structure for an integrated circuit, the method comprising:
The method aspect enables forming a metal line pattern and a metal pillar/via pattern using a first and a second resist pattern. Similar to the above-discussed conventional semi-damascene process, the metal lines are according to the present method etched in a metal layer (“direct metal etch”, DME). However in contrast, rather than forming vias by filling via holes patterned in an insulating layer prior to the DME, metal pillars may, according to the present method, be formed on top of the metal lines using a hard mask pillar pattern defined using the first and second resist patterns. Compared to the “litho-etch-litho-etch” sequence of the conventional semi-damascene process, the present method hence enables a “litho-litho-etch” process.
The method can be enabled by the use of dual resist layers, i.e. the first and second resist layers formed of different resist materials. The first and second resist layers and respective resist patterns may thus be selectively processed (e.g. lithographically patterned and etched) with respect to each other. In particular, the second resist pattern may be used as an etch mask for the first resist pattern such that portions of the first resist pattern not overlapped by the second resist pattern (“non-overlapped first resist pattern portions”) may be removed selectively to the second resist pattern. Conversely, the second resist pattern may be removed selectively to the first resist pattern.
The metal pillar pattern may be formed in accordance with the hard mask pillar pattern, i.e. using the hard mask pillar pattern. As the hard mask pillar pattern is defined by the portions of the first resist pattern overlapped by the resist lines of the second resist pattern, the metal pillars of the pattern may be self-aligned with the metal lines of the metal line pattern. Different approaches for forming the metal pillar pattern are possible, both metal line etch back (using the hard mask pillar pattern as an etch mask), and a damascene type approach (filling pillar/via holes formed an insulating layer using the hard mask pillar pattern in a tone-inversion approach).
As used herein, the term “line” (e.g. as in “resist line” and “metal line”) refers to an elongated feature (e.g. of resist material or metal) with a longitudinal dimension oriented along the substrate (e.g. along the first direction).
Terms such as “over”, “underneath”, “vertical”, “upper”, “lower”, “top”, “bottom”, “stacked on top of”, are herein to be understood as denoting locations or orientations within a frame of reference of the substrate. In particular, the terms may be understood as locations or orientations along a normal direction to the substrate. Correspondingly, terms such as “horizontal” and “lateral” are to be understood as locations or orientations parallel to the substrate, i.e. parallel to an upper surface or the main plane of extension of the substrate.
In some embodiments, the first resist material may be a metal-comprising resist material, and the second resist material may be an organic resist material, or vice versa. This combination of resist materials facilitate individual processing with a favorable degree of selectivity. The organic resist material may in particular be a chemically amplified resist material. Beneficially, the first resist material may be a metal-comprising resist material, and the second resist material is an organic resist material. The second resist layer may be formed with a greater thickness than the first resist layer.
In some embodiments, only a portion of the first resist pattern is overlapped by the second resist pattern. This allows the first resist pattern to be patterned at relaxed horizontal dimensions (as seen in a horizontal plane parallel to the substrate) compared to the metal pillars of the metal pillar pattern, since metal pillars may be defined at positions where the second resist pattern forms defines overlap with the first resist pattern.
In some embodiments, the method may further comprise patterning the first resist pattern using the second resist pattern as an etch mask. The method may accordingly comprise patterning both the first resist pattern and the hard mask layer using the second resist pattern as an etch mask. The non-overlapped portions of the first resist pattern may hence be removed prior to proceeding with patterning the metal layers.
In some embodiments, the first resist pattern may comprise a pattern of resist pillars, and wherein the second resist layer may be patterned such that at least a portion of each resist pillar is overlapped by a resist line of the second resist pattern.
Accordingly, a pattern of resist pillars for defining locations for metal pillars may be formed and subsequently be overlapped with resist lines of the second resist pattern. A resist pillar of the first resist pattern may be completely overlapped by a resist line of the second resist pattern. Alternatively, a resist pillar of the first resist pattern may be only partly overlapped by a resist line of the second resist pattern. In line with the above discussion, non-overlapped portions of a resist pillar may then be removed prior to proceeding with patterning the hard mask and metal layers. This allows the first resist layer to be patterned to define resist pillars with relaxed horizontal dimensions compared to the final metal pillars of the metal pillar pattern.
In some embodiments, the first resist pattern may comprise a pattern of resist bars extending in parallel along a second direction transverse to the first direction, and wherein the second resist layer may be patterned such that each respective resist bar of the first resist pattern is overlapped by at least two resist lines of the second resist pattern.
Accordingly, only a portion of the first resist pattern is overlapped by the second resist pattern. More specifically, each resist bar may be overlapped by at least two parallel resist lines of the second resist pattern. The metal pillars may hence be aligned with each other as seen along the second direction. This enables a two defining two metal pillars at a same horizontal location along a pair of parallel metal lines of the metal line pattern. The two metal pillars may, in a precise and reproducible manner, be formed directly opposite each other on a respective metal line.
As used herein, the term “bar” refers to an elongated feature (e.g. of the second resist material) with a longitudinal dimension oriented along the substrate (e.g. along the second direction). The resist bars may hence, like the features of the second resist pattern, be referred to as resist lines (albeit oriented transverse to the resist lines of the second resist pattern). The longitudinal dimension of the resist bars of the first resist pattern may, however, typically be smaller than the longitudinal dimensions of the resist lines of the second resist pattern.
In some embodiments, forming the metal pillar pattern may comprise partially etching back the metal line pattern using said at least a portion of the first resist pattern and/or the hard mask pillar pattern as an etch mask.
Both the metal pillars and the metal lines may hence be formed in a DME approach. A pattern of metal pillars (forming the vertical interconnects) may hence be formed on top of metal lines of the partially etched back metal line pattern.
The first resist pattern may optionally be removed prior to the metal line pattern etch back, wherein the hard mask pillar pattern may be used as an etch mask during the metal line pattern etch back.
In some embodiments, the method may further comprise forming an insulating layer surrounding the metal line pattern and the hard mask pillar pattern, and wherein forming the metal pillar pattern may comprise removing the hard mask pillar pattern to form pillar openings in the insulating layer, and depositing a second metal layer in the pillar openings.
The metal pillars (forming the vertical interconnects) may accordingly be formed by in a damascene style approach. As the pillar openings are formed in a tone inversion approach by removing the hard mask pillar pattern, the pillar openings and the metal pillars may be self-aligned with the metal lines.
In some embodiments, the method may further comprise surrounding said at least a portion of the first resist pattern with the insulating layer and removing both the hard mask pillar pattern and said at least a portion of the first resist pattern to form the pillar openings in the insulating layer.
The pillar openings and the metal pillars may hence be formed with a vertical dimension (height) corresponding to a combined vertical dimension (height or thickness) of the hard mask pillar pattern and the first resist pattern.
Alternatively, the first resist pattern may optionally be removed prior to forming the insulating layer, in case the vertical dimension of the hard mask pillar pattern is of a sufficient height.
In some embodiments, the first resist pattern may comprise a first sub-pattern of resist lines extending in parallel along the first direction, and a second sub-pattern of second resist features. The second resist layer may be patterned such that each respective resist line of the first sub-pattern, along at least a part of its length, is overlapped by a respective first resist line of the second resist pattern, and such that at least a portion of each second resist feature of the second sub-pattern is overlapped by a respective second resist line of the second resist pattern.
Thereby, said at least a portion of the first resist pattern used as the etch mask when patterning the hard mask line pattern may comprise: said at least a part of each resist line of the first sub-pattern and said at least a portion of each second resist feature of the second sub-pattern.
The method may further comprise, subsequent to removing the second resist pattern, patterning the hard mask line pattern using said at least a portion of the first resist pattern (i.e. said at least a part of each resist line of the first sub-pattern and said at least a portion of each second resist feature of the second sub-pattern) as an etch mask to define a combined hard mask pillar-and-line pattern over the metal line pattern, and subsequently partially etching back the metal line pattern using said at least a portion of the first resist pattern and/or the combined hard mask pillar-and-line pattern as an etch mask.
The first and second sub-pattern of the first resist pattern hence enables a combined hard mask pillar-and-line pattern to be formed, comprising a first sub-pattern of hard mask lines and a second sub-pattern of hard mask pillars.
Accordingly, a pattern of parallel metal lines comprising partially etched back and non-etched back metal lines may be formed, wherein a pattern of metal pillars are be formed on top of the partially etched back metal lines. More specifically, a metal line of a first height (“greater height) may be formed at positions defined by the first sub-pattern of the first resist pattern and the first resist lines of the second resist pattern while a metal line of a second height (“reduced height”) smaller than the first height may be formed at positions defined by the second resist lines of the second resist pattern. Meanwhile, the second sub-pattern of second resist features of the first resist pattern may be used to define locations of the metal pillars of the metal pillar pattern on top of the reduced height metal lines.
A line height of the metal lines may hence be varied between and/or along metal lines. This RC performance to be improved along selected metal lines of the metal line pattern.
The second sub-pattern may either be a pattern of resist pillars, or a pattern of resist bars extending in parallel along a second direction transverse to the first direction. For a discussion of respective details and merits related to resist pillars and resist bars, reference is made to above discussion of embodiments comprising resist pillars or resist bars.
The above, as well as additional objects, features and benefits, may be better understood through the following illustrative and non-limiting detailed description, with reference to the appended drawings. In the drawings like reference numerals will be used for like elements unless stated otherwise.
Various embodiments of a method for forming an interconnect structure for an integrated circuit in accordance with an aspect of the presently disclosed concept will in the following be described with reference to the drawings. A common denominator of the method embodiments is the forming of a first resist pattern in a first lithography process and a second resist pattern in a second lithography process, and using the second resist pattern to define a hard mask line pattern in a hard mask layer and a metal line pattern in a metal layer, and after removing the second resist pattern using the first resist pattern (after optionally being patterned using the second resist pattern) to form a metal pillar pattern for the metal line pattern.
As will be further set forth herein, the first resist pattern (which may comprise a resist pillar or resist bar pattern) can be formed by patterning a first resist layer of a first resist material in a first lithography process. The second resist pattern (comprising a resist line pattern) can be formed by patterning a second resist layer of a second different resist material in a second lithography process. The first and second resist materials may be selected to be so that the first resist material and the second resist material are etchable selectively to each other. That is, the first and second resist materials are selected such that an etch rate (i.e. material removal rate) of the first resist material exceeds an etch rate of the second resist material when the first and second resist materials are subjected to a first etching process, and conversely such that an etch rate of the second resist material exceeds an etch rate of the first resist material when the first and second resist materials are subjected to a second etching process. The respective etch selectivity of the first and second materials should hereby be understood to refer to the etch selectivity after the first and second materials having been subjected to the respective first and second lithography processes. Each one of the first and second lithography processes may comprise processing which per se is well known in the art, such as an exposure step and a development step. For instance, extreme ultraviolet lithography (EUVL) may be used to define a tight pitch pattern in a photoresist layer but the type of lithography technique may more generally be selected in accordance with the dimensions of the target pattern. As may be appreciated by the skilled person the first and second lithography processes may be supplemented with further steps such as a soft bake prior to exposure, a post-exposure bake and a post-development hard bake. Positive as well as negative resists are possible. The first resist material may be a metal-comprising resist material such as a metal-oxide resist. The second resist material may be an organic resist material such as a chemically amplified resist (CAR). This combination of resist materials lends itself favorably to mutually selective processing of the first and second resist materials of the respective resist patterns. For instance, a ratio of etch rates of metal-comprising resist to CAR of 10:1 or greater may be achieved, and similarly for CAR to metal-comprising resist. However, it is contemplated that the method can more generally be used also with other combinations of first and second resist materials allowing selective processing as set forth herein.
A method for forming an interconnection structure according to a first embodiment will now be disclosed with reference to
A metal layer 110 can be formed over the substrate 100, e.g. on the capping layer 102. The metal layer 110 may, for example, be formed of a layer of Ru, Mo, W, Al, Co or TiN, or a combination of two or more of such layers. The metal layer 110 may be deposited using conventional deposition processes such as physical vapor deposition (PVD), chemical vapor deposition (CVD) or atomic layer deposition (ALD).
A hard mask layer 120 can further be formed over the metal layer 110, e.g. on top of the metal layer 120. The hard mask layer 120 may comprise a hard mask material such as an oxide, nitride or carbide, for instance SiOx, SiN, SiCN, SiOC, or an amorphous carbon film.
A first resist layer 130 can be formed over the hard mask layer 120. The first resist layer 130 may be formed of a first resist material, such as a metal-comprising resist material or any of the other examples of first resist materials discussed above.
While not individually shown, the deposition of the first resist material may be preceded by forming of one of more further layers a single layer, the hard mask layer 120 may more generally comprise a stack of intermediate layers, such as, one or more anti-reflective coatings such as SiOC layers, spin-on-glass (SOG) layers and a planarization layer such as an organic spin-on layer, e.g. a spin-on-carbon (SOC) layer.
As further indicated in
In
The second resist pattern 142 can be formed such that each resist pillar 132′ of the first resist pattern 132 is overlapped by a resist line 142′ of the second resist pattern 142. As will be understood from the following, the positions of the resist lines 142′ of the resist pattern 142 define the positions (as seen in the horizontal plane XY) of the metal lines of the interconnect structure which are to be formed. The positions where the resist lines 142′ define an overlap with the resist pillars 132′, a metal pillar will be formed on top of a metal line.
In
Subsequently, the metal layer 110 can be patterned by etching to define a metal line pattern 112 underneath the hard mask line pattern 122. The second resist pattern 142 may be used as an etch mask during the patterning of both the hard mask layer 120 and the metal layer 110. Thereby the resist pillars 132′ overlapped may be masked during the etching of the metal layer 110. However it is also possible to remove the second resist pattern 142 subsequent to patterning the hard mask layer 120 and prior to patterning the metal layer 110, wherein the metal layer 110 may be patterned while using the hard mask line pattern 122 as an etch mask. In either case, the pattern (originally) defined by the second resist pattern 142 has thus been transferred into the metal layer 110 (i.e. via the hard mask layer 120). The metal line pattern 112 accordingly comprises a pattern of metal lines 112′ corresponding to the pattern of resist lines 142′ of the second resist pattern 142. For reasons which will become apparent from the below the metal lines 112′ may be denoted “initial” metal lines 112′.
The hard mask layer 120 and the metal layer 110 may each be etched using conventional etching processes enabling high fidelity pattern transfer into hard mask and metal layers. The hard mask layer 120 and the metal layer 110 may be etched top-down (seen along the Z-direction) using an anisotropic dry etching process. The hard mask layer 120 and the metal layer 110 may for instance be etched using a Reactive Ion Etch (RIE) process making use of a F-based plasma and an O2-based plasma, respectively.
Provided the second resist pattern 142 not already has been removed or consumed during the patterning, the second resist pattern 142 may as shown in
In
Subsequently, the (initial) metal lines 112′ of the metal line pattern 112 have been partially etched back using the first resist pattern 132 and the hard mask pillar pattern 124 as an etch mask (in case the first resist pattern 132 is preserved after patterning the hard mask line pattern 122) or using the hard mask pillar pattern 124 as an etch mask (in case the first resist pattern 132 has been removed or consumed after/during the patterning of the hard mask line pattern 122).
In either case, the pattern defined by the first resist pattern 132 can thus be transferred into the metal lines 112′ (i.e. via the hard mask line pattern 122) to form a pattern 116 of metal pillars 116′ on etched back “final” metal lines 114′ of a “final” metal line pattern 114. Accordingly, the metal pillars 116′ are by an upper thickness portion of initial metal lines 112′ preserved underneath respective hard mask pillars 124′. The metal line pattern 114 and the metal pillar pattern 116 are hence formed from a same metal layer 110.
The amount of partial etch back determines the height of the metal pillars 116′ and the height (thickness) of the remaining portion of the final metal lines 114′. As may be appreciated, the metal layer 110 should accordingly be deposited with a thickness such that final metal lines 114′ and metal pillars 116′ of respective desired heights may be accommodated therein. The term “partially etched back” hereby refers to that the etch back of the metal lines 112′ is stopped prior to completely etching through the metal lines 112′.
The patterning of the hard mask line pattern 122 and the etch back of the initial metal lines 112′ may be performed using any of the etching processes discussed above in connection with the patterning of the hard mask layer 120 and the metal layer 110.
A method for forming an interconnection structure according to a second embodiment will now be disclosed with reference to
With reference to
In
Similar to the first embodiment, the positions of the resist lines 1142′ of the second resist pattern 1142 define the positions (as seen in the horizontal plane XY) of the metal lines of the interconnect structure which are to be formed. However, in contrast to the first embodiment, only a portion of the first resist pattern 1132 is overlapped by the second resist pattern 1142. More specifically, the second resist pattern 1142 is formed such that each resist bar 1132′ of the first resist pattern 1132 is overlapped by at least two resist lines 1142′ of the second resist pattern 1142. The positions of the overlapped portions of the resist bars 1132′ of the first resist pattern 1132 define the locations (as seen in the horizontal plane XY) of the metal pillars to be formed on top of the metal lines, as will become apparent from the following.
In
Due to the merely partial overlap between the second resist pattern 1142 and the first resist pattern 1132, the pattern can be transferred into the hard mask layer 120 via the first resist pattern 1132. Hence, non-overlapped portions of the first resist pattern 1132, more specifically portions of each resist bar 1132′ not overlapped by a resist line 1142′, can be removed. Thereby a resist pillar pattern 1134 of resist pillars 1134′ (i.e. a now twice patterned first resist layer 130) can be formed in the first resist pattern 1132. Each resist pillar 1134′ can be formed over a respective hard mask line 1122′. Due to the transverse orientation of the resist bars 1132′ and the resist lines 1142′, the resist pillars 1134′ resulting from a same resist bar 1132′ may be aligned with each other as seen along the second direction Y. While the illustrated example depicts only a single resist bar 1132′ and two resulting resist pillars 1134′, the number of aligned metal pillars formed along a resist bar 1132′ is more generally determined by the number of resist lines 1142′ overlapping the resist bar 1132′.
Subsequent to patterning the first resist pattern 1132 and the hard mask layer 120, the metal layer 110 can, as shown, be patterned by etching to define a metal line pattern 1112 of metal lines 1112′ underneath the hard mask line pattern 1122. The description of the patterning of the metal layer 120 in connection with the first embodiment applies correspondingly to the second embodiment.
In
A method for forming an interconnection structure according to a third embodiment will now be disclosed with reference to 11a-b to 13a-b.
In
In
A method for forming an interconnection structure according to a fourth embodiment will now be disclosed with reference to
In contrast to the first and second embodiments, the first resist layer 130 as shown in
In
Each resist line 3132a′ of the first sub-pattern 3132a of the first resist pattern 3132 can be overlapped, along at least a part of its length, by a first resist line 3142a′ of the first sub-pattern 3142a of the second resist pattern 3142. Each second resist feature 3132b′ (e.g. resist pillar or resist bar) of the second sub-pattern 3132b of the first resist pattern 3132 can be overlapped, completely or only partly (as shown), by a second resist line 3142b′ of the second sub-pattern 3142b of the second resist pattern 3142.
In
The illustrated embodiment shows as an example that a width dimension (along the Y direction) of the first and second resist lines 3142a′, 3142b′ may be smaller than a corresponding width dimension of the resist lines and resist features 3132a′, 3132b. Hence, a width dimension of the resist lines and resist features 3132a′, 3132b of the first resist pattern 3132 may be trimmed in accordance with the width dimensions of the first and second resist lines 3142a′, 3142b′. This is however optional and it is also possible to form the first and second resist lines 3142a′, 3142b′ with a width dimension similar to or greater than a width dimension of the resist lines and resist features 3132a′, 3132b.
Subsequent to patterning the hard mask layer 120 (and the first resist pattern 3132), the metal layer 110 can, as shown, be patterned by etching to define a metal line pattern 3112 underneath the hard mask line pattern 3122. The pattern (originally) defined by the second resist pattern 3142 can thus be transferred into the metal layer 110, via the hard mask layer 120 (and the first resist pattern 3132). The metal line pattern 3112 accordingly comprises a first sub-pattern 3112a of first metal lines 3112a′ corresponding to the first sub-pattern 3142a of the second resist pattern 3142 and a second sub-pattern 3112b of second metal lines 3112b′ corresponding to the second sub-pattern 3142b of the second resist pattern 3142.
In
Subsequently, the metal line pattern 3112 can be partially etched back using the first resist pattern 3132 and the combined hard mask pillar-and-line pattern 3124 as an etch mask (in case the first resist pattern 3132 is preserved after patterning the hard mask line pattern 3122) or using the combined hard mask pillar-and-line pattern 3124 as an etch mask (in case the first resist pattern 3132 has been removed or consumed after/during the patterning of the hard mask line pattern 3122). In either case, the pattern defined by the first resist pattern 3132 can thus be transferred into the metal line pattern 3112 (i.e. via the hard mask line pattern 3122).
More specifically, during the metal line etch back, the first metal lines 3112a′ of the first sub-pattern 3112a of the metal line pattern 3112 can be masked by the resist lines 3132a′ of the first sub-pattern 3132a of the first resist pattern 3132 and/or the hard mask lines 3124a′ of the first sub-pattern 3124a of the combined hard mask pillar-and-line pattern 3124. The original height of the first metal lines 3112a′ can hence be preserved after the metal line etch back.
Meanwhile, during the metal line etch back, the second metal lines 3112b′ of the second sub-pattern 3112b of the metal line pattern 3112 can be masked by the second resist features 3132b′ of the second sub-pattern 3132b of the first resist pattern 3132 and/or the hard mask pillars 3124b′ of the second sub-pattern 3124b of the combined hard mask pillar-and-line pattern 3124. The second metal lines 3112b′ of the second sub-pattern 3112b of the metal line pattern 3112 can thus partially etched back in regions not masked by the second resist features 3132b′ and/or the hard mask pillars 3124b′ (see e.g. the cross-section along B-B′). The etched back “final” second metal lines are designated 3114. Accordingly, the pattern defined by the second resist features 3132b′ of the second sub-pattern 3132b of the first resist pattern 3132 can be transferred into the second metal lines 3112b′ (i.e. via the hard mask line pattern 3122) to form a pattern 3116 of metal pillars 3116′ on etched back “final” second metal lines 3114.
In the above, the presently disclosed concept has mainly been described with reference to a limited number of examples. However, as is readily appreciated by a person skilled in the art, other examples than the ones disclosed above are equally possible within the scope of the presently disclosed concept, as defined by the appended claims.
Number | Date | Country | Kind |
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22187143.7 | Jul 2022 | EP | regional |