This application claims the benefit of priority of Chinese patent application submitted on Aug. 2, 2022, entitled “METHOD OF FABRICATION FOR A SEMICONDUCTOR STRUCTURE”, with the application number 202210922714.2, the contents of which are incorporated herein by reference in its entirety.
The present disclosure relates to the field of semiconductor technology, in particular to a method for fabricating a semiconductor structure and a semiconductor structure.
The integration density of the dynamic memory has been developing toward higher levels, and higher demands have been imposed on the size of the transistors and how they are arranged in array structures.
At present time, in order to increase the memory integration density, at the same time, maintain a high speed and low power consumption, 3D stacked memory has lead the research direction in the industry. The 3D stacked memory has the advantage of high density, large capacity and high speed.
However, the currently fabricated 3D stacked semiconductor structures have the problem of poor morphology, which affects the performance of the memory devices.
An embodiment of the present disclosure provides a method for fabricating a semiconductor structure, comprising: providing a substrate; forming a stacked structure arranged at intervals along a first direction on the substrate, the stacked structure comprising alternately stacked first sacrificial layer and the semiconductor column; forming an isolation structure, the isolation structure is disposed between the adjacent stacked structures along the first direction; etching the isolation structure to form a through-hole, and the through-hole exposes the surface of the substrate part, and also exposes the side of each of the stacked structures, along the second direction, the width of the bottom of the through-hole is greater than the width of the top of the through-hole, the second direction is the same as the first The direction is vertical; the first sacrificial layer exposed by the through-hole is laterally etched, and part of the first sacrificial layer is removed to expose the top surface and the bottom surface of each of the semiconductor columns.
In some embodiments, the ratio of the width of the top of the through-hole to the width of the bottom of the through-hole is in the range of 0.75-0.95.
In some embodiments, the method for forming the through-hole includes: performing an etching process on the isolation structure to form two grooves spaced along the second direction in the isolation structure. The groove exposes a part of the surface of the substrate, and also exposes a part of the side of the stack structure extending along the second direction; in the second direction, the top width of the groove is larger than the bottom width of the groove; a support layer structure is formed in the groove, and the sides of the two support layer structures are in contact with the isolation structure; the isolation structure disposed between the two support layer structures is etched to expose The side of the support layer structure forms the through-hole.
In some embodiments, the cross-sectional shape of the groove perpendicular to the first direction is an inverted trapezoid.
In some embodiments, along the second direction, the ratio of the width of the top of the groove to the width of the bottom of the groove ranges from 1.05 to 1.25.
In some embodiments, the through-holes include: a first through-hole and a second through-hole connected to each other, the first through-hole is disposed on a side of the second through-hole away from the substrate, so the cross-sectional shape of the first through-hole perpendicular to the first direction is rectangular, and the cross-sectional shape of the second through-hole is trapezoidal.
In some embodiments, the method for forming the through-hole includes: performing an etching process on the isolation structure to form two first grooves distributed along the second direction in the isolation structure, the first groove exposes part of the isolation structure, and in the second direction, the cross-sectional shape of the first groove perpendicular to the first direction is rectangular; on the side of the first groove, the wall forms a mask layer; the isolation structure exposed at the bottom of the first groove is etched to form a second groove, the second groove connects with the first groove, and In the second direction, the cross-sectional shape of the second groove perpendicular to the first direction is an inverted trapezoid; a first sub-supporting layer is formed in the first groove, and in the second groove forming a second sub-support layer; etching the isolation structure disposed between the two first sub-support layers to form the first through-hole; etching the isolation structure disposed between the two second sub-support layers, the isolation structure forms the second through-hole; the first through-hole connects with the second through-hole to form one through-hole.
In some embodiments, in a direction perpendicular to the substrate, the ratio of the height of the first through-hole to the height of the second through-hole is in a range of 0.1-0.3.
In some embodiments, along the second direction, the width of the first groove is greater than the top width of the second groove, after forming the first groove, the method includes: using a deposition process to form the mask layer on the surface of the isolation structure exposed on the side wall of the first groove, the mask layer surrounds the first sub-groove, and along the second direction, the mask layer width of the first sub-groove is smaller than the width of the first groove; the isolation structure exposed at the bottom of the first sub-groove is etched to form a second groove, along the second direction Above, the top width of the second groove is equal to the width of the first sub-groove; the mask layer is removed.
In some embodiments, along the second direction, the width of the first groove is equal to the width of the top of the second groove, after forming the first groove, the method including: processing the isolation structure exposed on the side wall of the first groove, so as to convert the isolation structure exposed on the side wall of the first groove into the mask layer with a preset thickness; The isolation structure exposed at the bottom of the first groove is etched to form a second groove, and along the second direction, the width of the top of the second groove is equal to the width of the first groove.
In some embodiments, the isolation structure is silicon oxide, and the processing of the isolation structure exposed on the side wall of the first groove includes: exposing the side wall of the first groove, performing nitriding treatment on the isolation structure to form silicon nitride with a predetermined thickness.
In some embodiments, the method for forming the groove includes: performing a modification process on the isolation structure, in a direction along the isolation structure to the substrate, in the etching process, the etching ratio of the top of the isolation structure is greater than that of the bottom of the isolation structure; an etching process is performed on the isolation structure to form the groove.
In some embodiments, in a direction along the isolation structure to the substrate, the etching ratio of the isolation structure by the etching process gradually decreases.
In some embodiments, the through-holes include: a first through-hole and a second through-hole connected together, and along the second direction, the cross-sectional shape of the first through-hole is a rectangle, so the cross-sectional shape of the second through-hole is trapezoidal, and the method for forming the first through-hole and the second through-hole includes: performing a modification process on the isolation structure to form a first region and a second region. The isolation structure of the first region is disposed on the side of the isolation structure of the second region away from the substrate, and in the direction along the isolation structure pointing to the substrate, the etching process for the first region. The etching ratio of the isolation structure is constant, and the etching ratio of the isolation structure in the second region is gradually reduced by the etching process; the etching process is performed on the isolation structure to form in the first region a third groove, forming a fourth groove in the second region; forming a third sub-support layer in the third groove, forming a fourth sub-support layer in the fourth groove; etching at the isolation structure between the two third sub-support layers forms the first through-hole; the isolation structure between the two fourth sub-support layers is etched to form the second through-hole.
In some embodiments, the etching ratio of the first region by the etching process is equal to the etching ratio of the top of the second region by the etching process.
In some embodiments, the semiconductor columns further includes: a channel region, and the removal of part of the first sacrificial layer to expose the top surface and the bottom surface of each of the semiconductor columns is: exposing the channel on the top and side surfaces of the semiconductor columns in the region further include: forming word lines, the word lines wrapping the side surfaces of the channel region of a column of the semiconductor columns.
Correspondingly, an embodiment of the present disclosure also provides a semiconductor structure on the other hand, including: a substrate; on the substrate, semiconductor columns arranged in an array along a first direction and a vertical direction; an isolation structure between adjacent semiconductor columns, the isolation structure includes an isolation substructure and supporting layer structures disposed on both sides of the isolation substructure along the second direction; in the second direction, the bottom width of the isolating substructure is larger than the top width of the isolation substructure, the top width of the support layer structure is larger than the bottom width of the support layer structure, and the second direction is perpendicular to the first direction.
One or more embodiments are illustrated by the pictures in the accompanying drawings corresponding thereto, and these exemplary illustrations do not constitute a limitation to the embodiments, and unless otherwise stated, the figures in the accompanying drawings do not constitute scale restriction; in order to more clearly illustrate the technical solutions in the embodiment of the present disclosure or the conventional technology, the following will briefly introduce the accompanying drawings that need to be used in the embodiment. Obviously, the accompanying drawings in the following description are only the disclosure of the present disclosure For some embodiments, those of ordinary skill in the art can also obtain other drawings based on these drawings without any creative effort.
Known from the background technology, the currently fabricated 3D stacked semiconductor structures have the problem of poor morphology, which affects the performance of the semiconductor structures.
Analysis has found that one of the reasons for the poor morphology of the semiconductor structure to affect its performance is that, in the semiconductor structure, many transistors are stacked together, their stacked channel regions have to connect the same one word line. In the process of actually fabricating a semiconductor structure, usually multiple rows of stacked semiconductor columns are formed first, with a sacrificial layer disposed between the semiconductor columns for isolation and support. Moreover, an isolation structure is provided between two adjacent semiconductor columns. In order to expose part of the top and bottom surfaces of the semiconductor columns, the isolation structure needs to be etched first to expose the side surfaces of the semiconductor columns and the sacrificial layer, and then expose the side surface of the sacrificial layer and etch to expose the top surface and the bottom surface of the semiconductor column, so that the word line can surround the side surface of the semiconductor columns in the channel region. However, due to too many stacked semiconductor columns, after etching the isolation structure, the formed through-hole has a relatively large aspect ratio. Due to process limitations, when etching the sacrificial layer exposed by the through-hole, the larger aspect ratio means that more likely that the etched amount of the sacrificial layer exposed at the top of the through-hole is larger, and the etched amount of the sacrificial layer exposed at the bottom of the through-hole is smaller, so that after the etching is completed, the exposed top surface and bottom surface of the top semiconductor columns are large, and the exposed top surface and bottom surface of the semiconductor columns at the bottom are small, which makes the morphology of the semiconductor structure poor and affects the performance of the semiconductor structure.
An embodiment of the present disclosure provides a method for fabricating a semiconductor structure, forming stacked structures arranged at intervals along a first direction on a substrate, and forming an isolation structure between adjacent stacked structures, and forming a semiconductor structure in the isolation structure. The through-hole exposes part of the side surfaces of the semiconductor columns and the first sacrificial layer in the stacked structure. Along the second direction, the width of the bottom of the through-hole is greater than the width of the top of the through-hole, that is, the area of the sacrifice layer exposed at the top of the through-hole is smaller than that of the through-hole area of the sacrificial layer exposed at the bottom; the first sacrificial layer exposed by the through-hole is etched, and part of the first sacrificial layer is removed to expose the top surface and the bottom surface of each semiconductor column, because the area of the first sacrificial layer exposed at the top of the through-hole is smaller than the area of the first sacrificial layer exposed at the bottom of the through-hole, so that the etching amount of the first sacrificial layer at the top of the through-hole will not be too large, and the etching amount of the first sacrificial layer at the bottom will not be too small, thereby It can compensate the problem that the etching degree of the sacrificial layer on the top of the through-hole is large and the etching degree of the first sacrificial layer at the bottom of the through-hole is small due to process reasons, so that each semiconductor columns finally exposed has the same or similar shape.
The various embodiments of the present disclosure will be described in detail below in conjunction with the accompanying drawings. However, those of ordinary skill in the art can understand that, in each embodiment of the present disclosure, many technical details are provided for readers to better understand the embodiments of the present disclosure. However, even without these technical details and various changes and modifications based on the following embodiments, the technical solutions claimed in the embodiments of the present disclosure can be realized.
The method for fabricating a semiconductor structure includes: providing a substrate, and forming a stacked structure arranged at intervals along a first direction on the substrate, the stacked structure including first sacrificial layers and semiconductor columns stacked alternately along a vertical direction.
The material of the substrate is a semiconductor material, and in some embodiments, the substrate is a silicon substrate. In some other embodiments, the substrate may also be a germanium substrate, a silicon germanium substrate, a silicon carbide substrate or a silicon-on-insulator substrate.
The semiconductor columns is used to form the semiconductor channel of the transistor, and in some embodiments, the material of the semiconductor columns may be the same as that of the substrate. In one example, the material of the semiconductor columns may be silicon. The first sacrificial layer is disposed between two adjacent semiconductor columns and is in contact with the two adjacent semiconductor columns. On the one hand, it plays a role in supporting the semiconductor columns; on the other hand, the first sacrificial layer covers the surface of the semiconductor columns. Space is reserved for subsequent formation of other conductive structures. Specifically, when part of the first sacrificial layer is subsequently removed, the remaining first sacrificial layer acts as a support, and the removed part of the first sacrificial layer exposes the top and bottom surfaces of the semiconductor columns, thereby providing enough space for forming other conductive structures.
In some embodiments, the method for forming multiple rows of sequentially stacked first sacrificial layers and semiconductor columns may include:
Referring to
After forming the initial semiconductor layer 1 and the initial sacrificial layer, the initial semiconductor layer 1 positioned on the top surface is patterned to define the opening of the isolation groove (not shown), and the isolation groove is used for subsequent formation of the isolation structure, to isolate two adjacent columns of semiconductor columns; etch the patterned initial semiconductor columns until the surface of the substrate 100 is exposed, so as to form multiple rows of first sacrificial layers and semiconductor columns stacked in sequence, and the bottom surface of the isolation groove exposes part of the top surface of the substrate 100. The sides of the isolation trench expose the stacked semiconductor columns and the sides of the first sacrificial layer.
Each semiconductor columns is used to form at least one transistor. In each row of stacked semiconductor columns and the first sacrificial layer, the number of semiconductor columns is multiple, which is beneficial to realize the transistor in a direction perpendicular to the surface of the substrate 100. The multi-layer stacking is beneficial to integrate a larger number of transistors in a limited space, increase the integration density of semiconductor structures, and achieve smaller volume integration while ensuring better performance. In some embodiments, the semiconductor columns has a channel region for use as a channel of a transistor. In some embodiments, the semiconductor columns further includes: doped regions disposed on both sides of the channel region, wherein one doped region is used as a source of the transistor, and the other doped region is used as a drain of the transistor. In some embodiments, the type of doping ions in the doped region can be the same as that of the channel region, so that the type of transistor formed is joint free transistor, for example, the type of doping ions in the first channel region can be P-type, the dopant ion type in the source region and the drain region may be P-type. In some other embodiments, the type of doping ions in the doped region is different from the type of doping ions in the channel region, so that the type of transistor formed is a junction transistor, for example, the type of doping ions in the first channel region can be P-type, and the dopant ion type in the source region and the drain region can be N-type.
In some embodiments, the initial semiconductor layer 1 can be doped before forming the semiconductor columns, so that after the initial semiconductor layer 1 is etched to form a plurality of semiconductor columns distributed at intervals, each semiconductor columns has a first channel region, a source region and a drain region. In other embodiments, after the semiconductor columns are formed, a doping process may be performed on the semiconductor columns to form the first channel region and source regions and drain regions disposed on both sides of the first channel region. Wherein, the doping process may be any one of ion implantation or thermal diffusion.
Referring to
In some embodiments, the material of the isolation structure 103 may be silicon oxide. The isolation structure 103 may be formed in the isolation trench by a deposition process, for example, any one of atomic layer deposition or thermal oxidation process may be used.
Referring to
It can be understood that, by controlling the width of the top of the through-hole 105, to limit the etching amount of the first sacrificial layer 101 on the top of the through-hole 105 by the etching process, by controlling the width of the bottom of the through-hole 105 to be larger. Therefore, the etching amount of the first sacrificial layer 101 at the bottom of the through-hole 105 is increased by the etching process. It can be seen that, only by controlling the ratio of the width of the top of the through-hole 105 to the width of the bottom of the through-hole 105, the etching amount of the first sacrificial layer 101 on the top of the through-hole 105 and the impact of the etching process on the first sacrificial layer 101 at the top of the through-hole 105 can be balanced. The amount of etching of the first sacrificial layer 101 at the bottom of the through-hole 105 is such that the shape of the channel region exposed by each semiconductor columns 102 is the same or similar in the direction from the top of the through-hole 105 to the bottom of the through-hole 105, so that the subsequent formation, the area of the channel region of each semiconductor columns 102 covered by the word line is the same or similar, so that the control ability of the word line on the channel region of each semiconductor columns 102 is the same or similar, thereby improving the overall performance of the semiconductor structure. Based on this, in some embodiments, the ratio of the width of the top of the through-hole 105 to the width of the bottom of the through-hole 105 ranges from 0.75 to 0.95. Within this range, after the etching process etches the first sacrificial layer 101 exposed by the through-hole 105, the shape of the channel region exposed by each semiconductor columns 102 is the same or similar. Specifically, in some embodiments, the difference between the width of the top of the through-hole 105 and the width of the bottom of the through-hole 105 may range from 0.5 nm to 3 nm.
In some embodiments, the method of forming the through-hole 105 includes:
Referring to
Referring to
Specifically, in some embodiments, the material of the supporting layer structure 20 may be silicon nitride, and a deposition process may be used to form the supporting layer structure 20 in the groove 10.
Referring to
In some embodiments, the isolation structure 103 disposed between two adjacent support layer structures 20 may be removed by etching dry etching or wet etching process.
Referring to
In some embodiments, along the second direction Y, the ratio of the width of the top of the groove 10 to the width of the bottom of the groove 10 ranges from 1.05 to 1.25. Because the shape of the groove 10 is controlled, the shape of the formed supporting layer structure 20 can be controlled, and the supporting layer structure 20 is used as a mask layer to define the shape of the formed through-hole 105 in advance, that is, to control the formed concave shape. The shape of the groove 10, that is, the shape of the formed through-hole 105 can be adjusted. Therefore, controlling the ratio of the width of the top of the groove 10 to the width of the bottom of the groove 10 within this range can make the shape of the formed through-hole 105 meet expectations.
Referring to
In some embodiments, the method of forming the through-hole 105 includes:
Referring to
Specifically, in some embodiments, the method for forming the first groove 11 may include: performing a patterning process on the top surface of the isolation structure 103 to define the opening of the first groove 11; performing an etching process on the isolation structure 103, wherein this etch goes to form a first groove 11 with a preset depth.
Referring to
Referring to
Specifically, in some embodiments, along the second direction Y, the width of the first groove 11 is greater than the top width of the second groove 13, after forming the first groove 11, the method includes:
Referring to
In some embodiments, a deposition process may be used to form the mask layer 104 on the surface of the isolation structure 103 exposed on the side wall of the first groove 11, so that the process of forming the mask layer 104 is relatively simple. The material of the mask layer 104 is different from the material of the isolation structure 103. In this way, the etching selectivity ratio of the mask layer 104 and the isolation structure 103 can be used in the etching process, so during the process subsequently etching the isolation structure 103 to form the second groove 13, the mask layer 104 will not be etched, so the mask layer 104 plays a better protective role. In some embodiments, the material of the mask layer 104 may be a low-k dielectric material.
In some embodiments, after the mask layer 104 is deposited on the surface of the isolation structure 103 exposed by the first groove 11, the mask layer 104 will also be formed at the bottom of the first groove 11 at the same time. Therefore, before forming the second the groove 13, the mask layer 104 at the bottom of the first groove 11 needs to be removed to expose the top surface of the isolation structure 103.
Referring to
Referring to
In other embodiments, along the second direction Y, the width of the first groove 11 is equal to the width of the top of the second groove 13, after forming the first groove 11, the method includes:
Referring to
In some embodiments, the isolation structure 103 is silicon oxide, and processing the isolation structure 103 exposed on the side wall of the first groove 11 includes: performing nitriding treatment on the isolation structure 103 exposed on the side wall of the first groove 11, to form silicon nitride with a predetermined thickness. Specifically, in some embodiments, the method for performing nitriding treatment may include: a gas nitriding process, for example, nitrogen gas may be passed through, so that the nitrogen gas reacts with silicon oxide to form silicon nitride. Specifically, in some embodiments, a hard mask layer may be formed on the top surface of the isolation structure 103 to only expose the isolation structure 103 on the side wall of the first groove 11 and the isolation structure 103 on the bottom of the first groove 11. Next, nitrogen gas is passed into the first groove 11, so that the nitrogen gas reacts with the isolation structure 103 exposed on the side wall of the first groove 11 and the bottom, so that the isolation structure 103 on the side wall and bottom of the first groove 11 is transformed into silicon nitride.
In some embodiments, before forming the second groove 13, the silicon nitride at the bottom of the first groove 11 needs to be removed to expose the isolation structure 103 at the bottom of the first groove 11.
Referring to
Referring to
Etching the isolation structure 103 between the two first sub-support layers 21 to form a first through-hole; etching the isolation structure 103 between the two second sub-support layers 22 to form a second through-hole, the first through-hole connects with the second through-hole to form one through-hole. Since the cross-sectional shapes of the two first sub-support layers 21 are rectangular, when the isolation structure 103 between the two first sub-support layers 21 is etched to form the first through-hole, the shape of the first through-hole is different from that of the first sub-support layer. The shape of the supporting layer 21 matches, so that the shape of the first through-hole is also rectangular. The cross-sectional shape of the second sub-support layer 22 is an inverted trapezoid, so that the shape of the second through-hole matches the shape of the second sub-support layer 22 and is trapezoidal.
Considering that the cross-sectional shape of the first through-hole is rectangular, that is, the width of the top of the first through-hole is equal to the width of the bottom, therefore, the formation of the first through-hole will not affect the exposed first sacrificial layer 101 at the top of the first through-hole. The amount of etching between the first sacrificial layer 101 exposed at the bottom of the first through-hole is compensated. Therefore, it is necessary to set the height of the first through-hole to be small to prevent etching due to the large aspect ratio of the first through-hole. There is a problem that the etching amount of each first sacrificial layer 101 exposed by the first through-hole is different in the process. Based on this, in some embodiments, in a direction perpendicular to the substrate 100, the ratio of the height of the first through-hole to the height of the second through-hole ranges from (0.1 to 0.3. Within this range, the aspect ratio of the first through-hole is not too large, so that the difference between the etching amount of each first sacrificial layer 101 exposed by the first through-hole in the etching process is small, so that Each channel region exposed by the semiconductor columns 102 in the first through-hole has a similar shape, so that the area of the channel region of each semiconductor columns 102 covered by the subsequently formed word line is similar, so that the word line. The ability to control the channel region of each semiconductor columns 102 is close to improve the overall performance of the semiconductor structure.
In other embodiments, the method for forming groove 10 may also include:
The modification process is performed on the isolation structure 103. In the direction along the isolation structure 103 to the substrate 100, the etching ratio of the etching process on the top of the isolation structure 103 is greater than that on the bottom of the isolation structure 103. Specifically, in some embodiments, the modification process may include: performing a doping process on the isolation structure 103 to implant dopant ions into the isolation structure 103, and controlling the concentration of the dopant ions in the isolation structure 103, thereby regulating the etch selectivity ratio of the etching process to the top and bottom of the isolation structure 103. Specifically, in some embodiments, when the material of the isolation structure 103 is silicon oxide, boron can be doped into the isolation structure 103, wherein the doping concentration of the boron element at the top of the isolation structure 103 is lower than the doping concentration of boron element at the bottom of the isolation structure 103.
An etching process is performed on the isolation structure 103 to form the groove 10. Since the etching selectivity ratio of the etching process to the top of the isolation structure 103 is greater than the etching selectivity ratio to the bottom, the etching amount of the etching process to the top of the isolation structure 103 is greater than the etching amount to the bottom, so that the formed groove's top width of 10 is greater than the bottom width, so that the top width of the formed through-hole 105 is smaller than the bottom width of the through-hole 105.
In some embodiments, in the direction along the isolation structure 103 to the substrate 100, the etching ratio of the isolation structure 103 by the etching process gradually decreases. In this way, during the etching process of the isolation structure 103, in the direction along the isolation structure 103 to the substrate 100, the etching amount of the isolation structure 103 gradually decreases, so that the cross-sectional shape of the formed groove 10 is inverted trapezoid. Further, the shape of the formed through-hole 105 is controlled to be trapezoidal.
In some other embodiments, the through-hole 105 includes: a first through-hole and a second through-hole connected together. Along the second direction Y, the cross-sectional shape of the first through-hole is rectangular, and the cross-sectional shape of the second through-hole is trapezoidal, and the method for forming the first through-hole and the second through-hole includes:
Specifically, in some embodiments, along the direction from the top of the isolation structure 103 to the bottom of the isolation structure 103, the etching process can be controlled to keep the doping ion concentration of the isolation structure 103 in the first region 41 constant, and control the etching process gradually increases the doping ion concentration of the isolation structure 103 in the second region 42.
Referring to
Etching the isolation structure 103 disposed between the two third sub-support layers to form a first through-hole. Since the cross-sectional shape of the third sub-support layer is rectangular, in the isolation structure 103 between adjacent third sub-support layers, the width of the top is consistent with the width of the bottom, so when using the third sub-support layer as a mask to etch After the isolation structure 103 between the third sub-support layers, the formed first through-hole is rectangular.
Etching the isolation structure 103 disposed between the two fourth sub-support layers to form a second through-hole. Since the cross-sectional shape of the fourth sub-supporting layer is an inverted trapezoid, when the fourth sub-supporting layer is used as a mask to place behind the isolation structure 103 between adjacent fourth sub-supporting layers, the cross-sectional shape of the formed second through-hole is trapezoidal.
In some embodiments, the etching ratio of the etching process to the first region is equal to the etching ratio of the etching process to the top of the second region. That is to say, the difference between the etch ratio of the etching process to the joining point of the first region and the second region is small, so that the difference between the etching ratio of the etching process to the first region and the etching process to the second region can be avoided. The difference between the etching ratio is too large, resulting in the formation of the side of the joining point of the first through-hole and the second through-hole is not a smooth transition shape, resulting in the exposure of the first through-hole and the second through-hole after etching When the first sacrificial layer 101 is used, the difference in etching amount between the first sacrificial layer 101 at the joining point of the first through-hole and the second through-hole is too large, so that the joining point of the first through-hole and the second through-hole Correspondingly, the shape of the channel region exposed by the semiconductor columns 102 is inconsistent.
Referring to
Specifically, in some embodiments, the material of the first sacrificial layer 101 is silicon germanium, the first sacrificial layer 101 can be etched by a dry etching process, and the gas used for the dry etching can be It is an F (fluorine)-containing gas, for example, hydrogen fluoride gas.
Referring to
After forming the gate dielectric layer, it also includes: using a deposition process to form a barrier layer on the surface of the gate dielectric layer, and the barrier layer prevents the interdiffusion between the ions in the word line and the ions in the semiconductor columns 102. In some embodiments, the material of the barrier layer may be silicon nitride.
After forming the barrier layer, a word line 106 is formed on the barrier layer surface of each semiconductor columns 102 in a column of semiconductor columns 102 by using a deposition process, and the word line 106 surrounds the surface of each barrier layer in a column of semiconductor columns 102. Since in a column of semiconductor columns 102, the shape of each channel region exposed after etching the first sacrificial layer 101 is the same or similar, so that the area of the surface of the channel region where the word line is formed to cover each semiconductor columns 102 is the same or similar. Therefore, the control ability of the word line on the channel region 70 of each semiconductor columns 102 is the same or similar, and the overall performance of the semiconductor structure is improved.
In the method for forming the semiconductor structure provided in the foregoing embodiments, the width of the bottom of the formed through-hole 105 is greater than the width of the top of the through-hole 105, that is, the area of the sacrificial layer exposed at the top of the through-hole 105 is smaller than the area of the sacrificial layer exposed at the bottom of the through-hole 105. In this way, the first sacrificial layer 101 exposed by the through-hole 105 is etched, and part of the first sacrificial layer 101 is removed to expose the top surface and the bottom surface of each semiconductor columns 102, so that finally the top of the through-hole 105. The etching amount of the first sacrificial layer 101 is not too large, and the etching amount of the first sacrificial layer 101 at the bottom is not too small, so as to compensate for the large etching degree of the sacrificial layer at the top of the through-hole 105 due to process reasons, the etching degree of the first sacrificial layer 101 at the bottom of the through-hole 105 is small, so that each semiconductor columns finally exposed has the same or similar morphology.
Correspondingly, refer to
In some embodiments, the semiconductor columns also includes a channel region, and the channel region is used as a channel of a transistor. In a vertically arranged semiconductor column, the corresponding semiconductor columns morphology of each channel region same or similar.
In some embodiments, it also includes: a word line, the word line covers the sides of each channel region of a column of semiconductor columns vertically arranged along the second direction, the word line can be used as the gate of the transistor, and It is used to control the conduction of the source and drain of the transistor.
In some embodiments, it also includes an isolation layer, the isolation layer is disposed between the vertically adjacent semiconductor columns, and the isolation layer is disposed on both sides of the word line, respectively on the two sides opposite to the word line touch. The isolation layer can be used as an isolation structure and a support structure between vertically stacked semiconductor columns, and plays the role of isolation and support. In some embodiments, the material of the isolation layer may be silicon oxide.
Semiconductor structure can be a memory, and in some embodiments, memory can be DRAM (Dynamic Random Access Memory), SRAM (Static Random-Access Memory) or SDRAM (Synchronous Dynamic Random-Access Memory).
Those of ordinary skill in the art can understand that above-mentioned each embodiment is the concrete embodiment that realizes the present disclosure, and in actual application, can make various changes to it in form and detail, and not depart from this disclosure spirit and scope. Any person skilled in the art can make respective changes and modifications without departing from the spirit and scope of the present disclosure, so the protection scope of the present disclosure should be based on the scope defined by the claims.
Number | Date | Country | Kind |
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202210922714.2 | Aug 2022 | CN | national |
Filing Document | Filing Date | Country | Kind |
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PCT/CN2023/098676 | 6/6/2023 | WO |