For a more complete understanding of the present invention, and the advantages thereof, reference is now made to the following descriptions taken in conjunction with the accompanying drawings, in which:
As used herein the terms connected and coupled are intended to include both direct and indirect connection and coupling, respectively.
The invention relates to a method of manufacturing a nanowire transistor, a nanowire transistor structure, a nanowire transistor field and a computer program product.
Non-volatile memory devices are widely used, and their further adoption and implementation will require improved scalability, lower programming voltages, faster programming and access speeds, and longer device life. In particular, the planar structure of conventional non-volatile memory devices limits memory cell scalability, particularly below a cell pitch of 50 nm. In addition, the thickness of the tunnel oxide layer in a conventional non-volatile memory device presents a tradeoff between the required programming voltage and retention time. A thin tunnel oxide layer (of e.g., 2.5 nm) can provide a lower programming voltage, albeit with the tradeoff of shorter retention time. A thicker tunnel oxide layer provides a better retention time, but results in the disadvantage of a higher required programming voltage.
It should be pointed out that, although the following exemplary embodiments describe nanowire non-volatile memory cells in more detail, the invention is not limited to a non-volatile memory cell, not even to a memory cell. The invention could also be used for a nanowire transistor such as a nanowire field effect transistor. In this general case, instead of a charge storage region, which is provided in a nanowire non-volatile memory cell, a gate insulation region is provided, e.g., made of an oxide layer.
Referring to the side view illustrated in
As shown, the nanowire non-volatile memory cell 100 further includes a drain region 142, a source region 144 and an active region 146 between the drain region 142 and the source region 144.
A memory structure 150 is disposed above the drain region 142, the source region 144 and the active region 146, e.g., a charge storage region, shown in an exemplary embodiment of the invention as charge trapping region, which extends longitudinally (horizontally as shown in
In an embodiment of the invention, the charge trapping region includes a tunnel dielectric, a trapping dielectric, and a blocking dielectric between the gate region and the bulk semiconductor carrier. The tunnel dielectric may include a plurality of layers, e.g., a first oxide layer, a nitride layer disposed above the first oxide layer, and a second oxide layer disposed above the nitride layer. The first oxide layer may have a thickness in the range of approximately 1 nm to approximately 2 nm (e.g., approximately 1.5 nm), the nitride layer may have a thickness in the range of approximately 1 nm to approximately 3 nm (e.g., approximately 2 nm), and the second oxide layer having a thickness in the range of approximately 1 nm to approximately 2 nm (e.g., approximately 1.5 nm). The blocking dielectric may include silicon oxide or a dielectric material having a dielectric constant that is greater than the dielectric constant of silicon oxide. Furthermore, the blocking dielectric may include a dielectric material having a dielectric constant that is greater than the dielectric constant of silicon oxide and an energy band gap above 5 eV. In an embodiment of the invention, the blocking dielectric may include aluminum oxide or hafnium silicate.
In another embodiment of the invention, the charge trapping region includes one or more dielectric layers (e.g., two dielectric layers, three dielectric layers or even four or more dielectric layers) in a charge trapping layer stack trapping electrical charge carriers.
As those skilled in the art will appreciate, the memory structure 150 may be a single-level structure or single-bit structure, or alternatively, a multi-level structure or a multi-bit structure. In a particular embodiment of the invention, the memory structure 150 is a multi-level charge trapping structure.
In another embodiment of the invention, the charge storage region is a floating gate region, which may be configured as a single-level structure or as a single-bit structure, or alternatively, as a multi-level structure or as a multi-bit structure.
Furthermore, a gate region 160, e.g., made of poly-silicon, is disposed above the memory structure 150.
As shown in
The gate region 160, the memory structure 150, the drain region 142, the source region 144 and the active region 146 are elements of a transistor which serves as the non-volatile memory cell 100, and the isolation regions made of the isolating material 170 serve as isolations between adjacently-located nanowire non-volatile memory cells coupled to separate word lines.
Referring to the construction of the elongated nanowire structure 110, the active region of which may be a p-doped area, in which an electrically conductive channel may be formed in response to the application of appropriate gate, source and drain voltages, respectively, thereby enabling a current flow through the channel from the drain region 142 to the source region 144. Furthermore, the elongated nanowire structure 110 includes the drain region 142 and the source region 144, which may be n-doped or n+-doped. Alternative doping profiles may be implemented for the non-volatile memory cell 100. By way of example, the active region 146 may include an n-doped area, and the drain region 142 and the source region 144 may have a p-doped profile or a p+-doped profile.
An exemplary manufacturing process of the elongated nanowire structure 110 will be described in more detail below.
In a particular embodiment of the invention, the tunnel oxide layer 152 is 4.0 nm thick (as measured vertically in
In an alternative embodiment of the invention, the charge storage region includes a floating gate structure, in which an isolated (e.g., encapsulated) conductive layer is provided for storing the electric charge. Poly-silicon may be used for the conductive layer. In such an embodiment of the invention, a tunnel oxide layer is also provided which is configured as described above in the context of a charge trapping region. In another embodiment of the invention, the tunnel oxide layer has a thickness of greater than 4.0 nm and may be for example, 4.25 nm, 4.5 nm, 4.75 nm, 5.0 nm, 5.25 nm or thicker up to 10 nm. Furthermore, a control oxide layer may be provided on or above the conductive layer.
The gate region 160 provides electrical contact to the external environment (e.g., via a gate contact region (not shown), e.g., made of a silicide such as tungsten silicide) and may be composed of poly-silicon in accordance with one embodiment of the invention, although other materials such as a metal (e.g., tantalum nitride (TaN), titanium nitride (TiN), aluminium (Al), copper (Cu)), e.g., a metal having a suitably high work function may be used alternatively. When poly-silicon is used as the material for the gate region 160, the poly-silicon may be undoped poly-silicon, p-doped poly-silicon or n-doped poly-silicon.
The spacer portion 122 of the insulation layer 120 may be formed from an oxide, e.g., silicon oxide, in an alternative embodiment of the invention, from another isolating material. The spacer portion 122 is an artifact of the nanowire structure manufacturing process, which will be described in more detail below, and permits the construction of the non-volatile memory cell 100 in a silicon-on-insulator structure without the need for a conventional SOI wafer.
As will be described in more detail below, the manufacturing process in accordance with an embodiment of the invention provides techniques whereby memory cells can be manufactured in an SOI structure without the need for an SOI base wafer, thereby achieving higher performance characteristics of SOI-based memory cells at significantly lower cost. In a particular embodiment of the invention, the spacer portion 122 has a width in the range of about 5 nm to about 30 nm and a height of about 10 nm to about 40 nm, although other dimensions may be used in alternative embodiments of the invention.
The memory cell 100 also includes the drain region 142. In a particular embodiment of the invention, the drain region 142 of the elongated nanowire structure 110 is an n+-doped portion of the elongated nanowire structure 110, although in an alternative embodiment of the invention, the drain region 142 of the elongated nanowire structure 110 may have a p-doped profile.
The non-volatile memory cell 100 further includes the source region 144. In a particular embodiment of the invention, the source region 144 of the elongated nanowire structure 110 is an n+-doped portion of the elongated nanowire structure 110, although in an alternative embodiment of the invention, the source region 144 of the elongated nanowire structure 110 may have a p-doped profile.
Also included in the non-volatile memory cell 100 are isolation regions 170 operable as isolating barriers between adjacently-located memory cells. In a particular embodiment of the invention, the isolation regions 170 are composed of silicon oxide. In one embodiment of the invention, the isolation regions 170 may be formed of TEOS (Tetra-Ethyl-Ortho-Silicate) or SOG (Spin-on-Glass) material operable to provide the desired isolation between adjacent memory cells.
In accordance with an embodiment of the invention, the gate region 160 has a cross-section (in the width direction of the elongated nanowire structure 110) which is rounded in a semi-cylindrical shape, e.g., around at least 180 degrees of the cross-section, the exemplary embodiment shown in
Furthermore, due to imperfections in the photolithographic/semiconductor processing steps, the cross-section over which rounding occurs may not be perfectly cylindrical. In such instances, the rounded cross-section will have maximum and minimum radii. In accordance with an embodiment of the invention, the maximum radius is defined as being no larger than 1.5 times the minimum radius within the rounded cross-section. Further embodiments of the ratio between maximum and minimum radii include 1.4, 1.3, 1.2, 1.1.
As further shown in
In an embodiment of the invention, the cross-sectional radius (in average) of the gate region 160 is about 8 nm, and the thickness dimensions (in average) of the tunnel oxide layer 152, the charge trapping layer 154, and the top oxide layer 156, are about 4.0 nm, about 7 nm and about 5 nm, respectively. These dimensions are exemplary and others may be used in alternative embodiments of the invention. For example, the thickness of the tunnel oxide layer 152 may range from about 4.0 nm to about 6.5 nm, which is significantly greater than the thickness of a conventional tunnel oxide layer, such a thickness aiding in the retention of the tunnel oxide layer over a high number of programming and erase cycles. Exemplary thicknesses of the tunnel oxide layer 152 include 4.0 nm, 4.25 nm, 4.5 nm, 4.75 nm, 5.0 nm, 5.25 nm, 5.5 nm, 5.75 nm, and 6.0 nm. Further exemplary, the thickness of the charge trapping layer 154 may range from about 4 nm to about 10 nm, and the thickness of the top oxide layer 156 may range from about 3 nm to about 8 nm. In particular, if for the top dielectric a material with higher dielectric constant then SiO2 is used, for instance Al2O3 or Hf based, then a substantially larger thickness of approximately 10 nm to approximately 20 nm for the top dielectric may be required. Alternatively the top dielectric may be a combination of SiO2 and a material with higher dielectric constant than SiO2. The indicated dimensions are exemplary, and those skilled in the art will appreciate that layers of other dimensions may be used in alternative embodiments of the invention.
In an alternative embodiment, the nanowire active region 146 has a rounded cross section of about 190 degrees. Further particularly, the largest radius within the 190 degree rounded cross section is a ratio of 1.5 when normalized to the shortest radius of the rounded cross section.
In another embodiment of the invention, the drain region 142, the active region 146 and the source region 144 are rounded around at least 180 degrees, forming rounded cross-sectional areas, respectively. In further specific embodiments of the invention, each of the rounded cross-sectional areas ranges from about 190 degrees to about 350 degrees, from about 210 degrees to about 330 degrees, or from about 240 degrees to about 290 degrees. Further specifically, the ratio of maximum radius to minimum radius within the rounded cross-sectional areas ranges from about 1.5 to about 1.0. The drain region 142 and the source region 144 are implanted with the desired doping profiles and annealed at the desired temperature to form respective drain and source junctions. In a particular embodiment of the invention, the gate region 160, the drain region 142, the active region 146 and the source region 144 are formed concurrently, and accordingly have substantially the same rounded cross-sectional areas and ratio of maximum radius to minimum radius.
In an alternative embodiment of the invention, the drain region 142 and the source region 144 are formed in a manner dissimilar to the active region 146. As an example, the drain region 142 and the source region 144 may have different rounded cross-sectional areas from that of the active region 146, or have a different ratio of maximum radius to minimum radius. In a further alternative embodiment of the invention, the drain region 142 and the source region 144 may be formed in a shape different from that of the active region 146.
The method starts at 202, at which at least a portion of a semiconductor carrier, the semiconductor carrier comprising a first carrier portion and a second carrier portion being offset from the first carrier portion, is oxidized.
At 204, a portion of the oxidized portion is removed, thereby forming an oxide spacer between a portion of the second carrier portion and the first carrier portion.
At 206, a charge storage region is formed above at least a portion of the second carrier portion.
At 208, a gate region is formed above at least a portion of the charge storage region.
At 210, a first source/drain region and a second source/drain region are formed.
The method starts at 502, whereby an elongated nanowire structure 110 is formed from semiconductor material. In a specific embodiment of the invention, the elongated nanowire structure 110 is formed to have a rounded cross-sectional area of at least 180 degrees.
It should be noted that in an alternative embodiment of the invention, the elongated nanowire structure 110 does not necessarily be rounded.
At 504, gate material is deposited on a first portion of the elongated nanowire structure 110, thereby forming the gate region 160.
At 506 and 508, respective second and third portions of the elongated nanowire structure 110 are doped and optionally annealed to form the drain region 142 and the source region 144. It should be mentioned that the drain region 142 and the source region 144 may in one embodiment of the invention be formed simultaneously in one common process.
The gate region 160, the drain region 142 and the source region 144 of the elongated nanowire structure 110 are components of a transistor that is operable as a memory cell in accordance with an embodiment of the invention. As those skilled in the art will appreciate, manufacture of a nanowire memory cell transistor in accordance with
Initially at 512, a first surface of a bulk semiconductor material substrate is etched to form an elongated fin-shaped portion, in other words, an elongated raised portion (e.g., the second carrier portion), of the bulk semiconductor material, and a base of the bulk semiconductor material (e.g., the first carrier portion). In a particular embodiment of the invention, the bulk semiconductor material is silicon and the elongated fin-shaped portion has a substantially rectangular shape with a width and a height which are at least the desired radius of the elongated nanowire structure 110 to be formed. In a specific example, the fin-shaped portion extends 50 nm above the base of the bulk semiconductor material.
At 514, at least a portion of the base of the bulk semiconductor material is oxidized. Through this process, the base of the bulk semiconductor material is transformed into a semiconductor base layer 120, as shown in
At 516, the cross-section of the elongated fin-shaped portion is rounded over at least 180 degrees of its cross-sectional area along its width direction, thereby forming a rounded cross-sectional area. In a particular embodiment of the invention, the cross-sectional area over which the rounding is provided, includes at least the active region 146, the drain region 142, and the source region 144. In a further embodiment of the invention, the rounding process is performed over the entire length of the fin-shaped portion, the active region 146, the drain region 142, and the source region 144. Such an embodiment may be implemented in the construction of a NAND memory array, whereby the elongated nanowire structure 110 forms a NAND string of (serially) source-to-drain coupled memory cells. In such an embodiment, the rounding process is performed over the length of the nanowire structure 110 which forms the NAND string of memory cells.
It should be mentioned that the invention is not limited to a NAND architecture, but can also be applied to any other kind of memory field architecture such as a NOR architecture, for example.
As those skilled in the art will appreciate, variations in the semiconductor process may result in imperfections in the rounding process. In such embodiments of the invention, the rounded cross-sectional areas will have a minimum radius and a maximum radius. In accordance with an embodiment of the present invention, the maximum radius does not exceed about 1.5 times the minimum radius over the rounded cross-sectional areas. The rounding process may be performed by employing a conventional rounding thermal oxidation (RTO) process in which an oxide layer is grown over the rounded raised portion. In a specific embodiment of this process, the oxidation temperature is about 800° C. or higher, wherein higher oxidation temperatures help the formation of rounded surfaces. In another embodiment of the invention, hydrogen annealing is used to round the fin-shaped portion.
At 518, the memory structure is formed above or onto the surface of the elongated nanowire structure 110, the memory structure extending over at least a portion of the nanowire active region 146. As noted above, the memory structure may be, e.g., a charge trapping structure (in other words, a charge trapping region), such as an oxide-nitride-oxide layer structure, or a floating gate structure (in other words, a floating gate region). In exemplary embodiments of the invention, the memory structure extends from about 190 degrees to about 350 degrees around the active region 146. In other embodiments of the invention, the memory structure may extend from about 210 degrees to about 330 degrees or from about 240 degrees to about 290 degrees around the active region 146.
In accordance with one embodiment of the invention, the rounding process is performed concurrently along the active region 146, the drain region 142 and the source region 144, so that these regions are substantially uniform at this stage in the process. In another embodiment of the invention, the rounding operation is performed along the entire length of the elongated nanowire structure 110.
As readily appreciated by those skilled in the art, the described processes may be implemented in hardware, software, firmware or a combination of these implementations as appropriate. As an example, each of the described processes may be carried out by semiconductor processing equipment known in the art. Furthermore, some or all of the described processes may be implemented as computer readable instruction code that is resident on a computer readable medium (removable disk, volatile or non-volatile memory, embedded processors, etc.), the instruction code operable to program a computer, semiconductor processing equipment, or other such programmable device to carry out the intended functions.
The foregoing description has been presented for purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form disclosed, and obviously many modifications and variations are possible in light of the disclosed teaching. The described embodiments were chosen in order to best explain the principles of the invention and its practical application to thereby enable others skilled in the art to best utilize the invention in various embodiments and with various modifications as are suited to the particular use contemplated. It is intended that the scope of the invention be defined solely by the claims appended hereto.