This application is a continuation of copending International Application No. PCT/EP03/00671, filed Jan. 23, 2003, which designated the United States and was not published in English, and is incorporated herein by reference in its entirety.
1. Field of the Invention
The present invention relates to a method of producing a capacitor and, in particular, to a method of producing a capacitor which is suitable for integrating a capacitor in an intermediate dielectric between two wiring planes.
2. Description of Prior Art
For producing capacitors in integrated circuits, a large number of techniques is known, the capacitance of a capacitor being determined by the surface of its electrodes, the distance at which these electrodes are located from one another and the permittivity ratio, i.e. the relative dielectric constant ∈r of a dielectric layer between the electrodes. In order to achieve a desired high capacitance on the basis of an electrode area which is as small as possible, the smallest possible distance between the electrodes and the smallest possible thickness of the dielectric layer between the electrodes, respectively, are especially necessary in addition to a high relative dielectric constant ∈r.
In conventional methods it is normally necessary to laterally structure the electrodes and the dielectric layer between the electrodes during the production of the capacitor, such lateral structuring being effected e.g. by means of a positive photoresist mask and an etching step or by means of a negative photoresist mask, which is applied prior to the respective layer, and a lift-off step. In the case of any kind of lateral structuring of a layer, the layer to be structured has to satisfy greater or less requirements on chemical and mechanical robustness, since, during the structuring, this layer will at least be exposed to a solvent for the photoresist mask even in the areas which are not to be removed. If a positive photoresist mask is used as an etching mask, the layer to be structured is additionally subjected to a mechanical contact with the photoresist and an exposure mask. The resultant, manufacturing technology-dependent requirements on the robustness of the layers to be structured entail restrictions as far as the selection of the materials is concerned and necessitate minimum thicknesses of the layers.
In the case of a dielectric layer these requirements set undesired limits to an increase of the capacitance of the capacitor and vice versa to the reduction of the electrode area of the capacitor by the use of a thinner dielectric layer.
Another problem is to be seen in that a dielectric layer projecting laterally below the upper capacitor plate will reduce the absorption properties of an anti-reflection coating (ARC; ARC=Anti Reflex Coating) located therebelow. This is disadvantageous during a subsequent exposure step.
Another disadvantage of the conventional production of a capacitor is to be seen in that separate lithographic and etching steps are necessary for structuring the upper capacitor plate.
It is the object of the present invention to create an improved method of producing a capacitor in a dielectric layer.
In accordance with a first aspect, the present invention provides a method of producing a capacitor in a first dielectric layer, said method having the following steps: forming a recess in a surface of the first dielectric layer; producing a first conductive layer on the surface of the first dielectric layer and in the recess; producing a second dielectric layer on the first conductive layer, the sum of a thickness of the first conductive layer and of a thickness of the second dielectric layer in the recess being smaller than a depth of said recess; producing a second conductive layer on the second dielectric layer; planarizing the thus formed layer structure so as to obtain the capacitor; and producing a trench which completely surrounds the second electrode laterally and extends to the first conductive layer.
The present invention is based on the finding that, under specified conditions, it is possible to produce a capacitor in a recess in a first dielectric layer by producing in this recess a layer sequence consisting of two conductive layers and an intermediate dielectric layer and by executing then a planarizing step down to the surface of the first dielectric layer. This has the effect that the layer sequence is laterally structured, whereby the capacitor is formed. It has been recognized that this production method can especially be executed when the depth, i.e. the vertical dimensions of the recess are larger than the thickness of the first conductive layer to be deposited thereon and when the lateral dimensions of the recess are larger than twice the thickness of the first conductive layer.
The present invention is additionally based on the finding that the standard deposition of tungsten (T) for filling via holes can be used for producing via hole contacts, so as to produce the first conductive layer. In this case, the lateral and vertical dimensions of the recess have to be defined such that the recess is not filled completely by the tungsten layer applied for filling the via holes.
One advantage is to be seen in the fact that especially the second dielectric layer need not be structured separately prior to producing the second conductive layer on top of said second dielectric layer and that it is therefore not necessary to expose this second dielectric layer to a photoresist or to a solvent for this photoresist nor is it necessary to bring it into contact with an exposure mask. On the contrary, the second dielectric layer and the second conductive layer can be produced immediately one after the other. This has the effect that the second dielectric layer is packed in a sandwich-like manner during processing and protected against process influences. This will especially avoid a direct or an indirect etch attack on the second dielectric layer, and it is even possible to avoid any kind of contact of the second dielectric layer with an atmosphere. The thickness of the second dielectric layer can therefore easily be reduced to an almost arbitrary extent, and, in extreme cases, this second dielectric layer may have a thickness of only one or a few atomic layers, since said dielectric layer need not fulfil any requirements on mechanical or chemical robustness.
The second dielectric layer is produced on the first conductive layer preferably over the full area thereof.
With respect to the lateral embedment in a dielectric layer, a capacitor produced in accordance with the present invention is also referred to as GOLCAP (GOLCAP=GlObal Layered CAPacity).
Another advantage of the present invention is to be seen in the fact that, by planarizing the layer structure, the second conductive layer and, in addition, optionally the second dielectric layer and the first conductive layer can be structured laterally in a single method step. Hence, no further step is necessary for laterally structuring the layers, especially the upper capacitor plate, from the second conductive layer, whereby the investment in apparatus and process technology which is necessary for producing the capacitor will be reduced.
A further advantage resides in the fact that the method according to the present invention can be integrated with the production of via hole conductors so that it is e.g. possible to produce a via hole conductor in the first dielectric layer and the first conductive layer in a single step. Also the step of planarizing the layer structure can preferably be carried out in the same step in which the filling of the via holes is planarized. This will minimize the outlay for producing the capacitor.
Another advantage of the present invention is to be seen in the fact that the resultant well shape of the second dielectric layer and thus the lateral and vertical structural designs of the capacitor plates and electrodes, respectively, leads, in comparison with a purely planar structural design of a dielectric layer, to an increase in the electrode area and thus to an increase in the effective capacitance.
Another advantage is that both capacitor plates can be contacted in the same metal plane, i.e. in the same conductor layer. Furthermore, additional stop layers can be dispensed with in the case of the present invention, such stop layers being normally used when the capacitor plates are being contacted.
In addition, high requirements on the (CMP) planarization of the first dielectric layer, which are normally entailed by flat T-electrodes (tungsten electrodes), are eliminated by the present invention. The conventional high requirements on lithography for structuring the lower capacitor plate do not have to be satisfied either.
According to a preferred embodiment the second dielectric layer is present on the surface produced by planarizing not in the form of a planar but in the form of a linear structure. This means that the second dielectric layer exists only on the electrically active area of the T-electrodes but not outside of said electrodes. Problems during a subsequent photoresist exposure caused by absorption properties which have been changed by the dielectric layer are avoided in this way.
In the following preferred embodiments will be explained in detail making reference to the figures enclosed, in which:
Making reference to
The first dielectric layer 20 is produced by applying to the support layer 10 a boron-phosphorus silicate glass (BPSG) or an oxide, which fills spaces between the conductor 12 and additional conductors, which are not shown, and covers said conductors. This results in a wavy surface which is then planarized by chemical-mechanical polishing (CMP) whereby the initially plane surface 22 of the first dielectric layer 20 is produced. The first dielectric layer 20 can be a dielectric layer between two wiring planes on top of a component layer of a semiconductor structure, e.g. a storage element or a microprocessor.
Starting from the structure shown in
As shown in
The surface 22 and the surfaces of the via hole 30 and of the recess 40 have applied thereto a thin liner or a thin intermediate layer 50, which is shown in
In the next step, a first T-layer 60 (T=tungsten) is produced on the intermediate layer 50. As can be seen in
The depth of the recess 40 is preferably larger than the thickness of the first T-layer 60 in said recess and the lateral dimensions of the recess 40 are larger than twice the thickness of the first T-layer 60. Under these preconditions, the recess 40 is, other than the via hole 30, not filled completely by the first T-layer 60, but the first T-layer 60 has essentially the same thickness within the recess 40 and outside of said recess 40 and of the via hole 30.
A thin second dielectric layer 70 comprising e.g. a nitride, oxide, tantalum oxide or aluminium oxide is produced on the first T-layer 60 over the full area thereof. The second dielectric layer 70 can have a thickness of e.g. 30 nm-50 nm. Preferably, it has, however, a very small thickness of 10 atomic layers or less and, according to a specially preferred embodiment, a thickness of only one, two or three atomic layers. It is produced by means of chemical vapour deposition (CVD), deposition of individual atomic layers from the gas phase (ALD; ALD=atomic layer deposition), or by means of some other method which is suitable for depositing such thin layers.
Preferably immediately after the production of the second dielectric layer 70, a second T-layer 80 is produced on top of the second dielectric layer 70., whereby the condition shown in
The fact that the second dielectric layer 70 and the second T-layer 80 are deposited immediately one after the other especially means that, prior to the production of the second T-layer 80, the second dielectric layer 70 is neither coated with a photoresist mask nor brought into mechanical contact with an exposure mask nor exposed to any solvent or etching bath nor subjected to an exposure. When the second dielectric layer 70 and the second T-layer 80 are produced within the same device or within the same (vacuum) receptacle, the second dielectric layer 70 will not be subjected to any influence of air or of a protective atmosphere. An influence of light on the second dielectric layer can easily be avoided as well. Furthermore, the period between the production of the second dielectric layer 70 and the production of the second T-layer 80 can be as short as desired. Hence, the second dielectric layer 70 need not satisfy any requirements with respect to chemical or mechanical robustness, light resistance or aging resistance. Insofar, no restrictions whatsoever exist as far as the selection of a material for the second dielectric layer 70 is concerned; on the contrary, an unlimited optimization is possible with respect to a minimum thickness, a maximum relative dielectric constant ∈r, a desired frequency dependence thereof, a high dielectric strength or a high breakdown electric field strength or other parameters which are important to a respective case of use.
In a further method step, the layer structure shown in
The thickness of the first T-layer 60 and the thickness of the second dielectric layer 70 are, in common, smaller than the thickness of the recess 40 so that, after the planarizing step, not only the first T-layer 60 but also the intermediate layer 50 and the second T-layer 80 partially remain in the recess 40. The remaining portion of the first T-layer 60 forms a first electrode 90 of a capacitor 92, the remaining portion of the second t-layer 80 forms a second electrode 94 of the capacitor 92, the first electrode 90 and the second electrode 94 of the capacitor 92 being spatially separated and electrically insulated from one another by a remaining portion 96 of the second dielectric layer 70. The lateral dimensions of the electrodes 90, 94 and thus their areas and the capacitance of the capacitor 92 are determined by the area of the portion 96 of the second dielectric layer 70 and therefore essentially by the lateral dimensions of the recess 40. In particular, an edge 100 of the first electrode 90 essentially corresponds to an edge 102 of the recess 40. An edge 104 of the second electrode 94 is located at a distance from the edge 102 of the recess 40 which is essentially determined by the thickness of the first T-layer 60, the depth of the recess 40 and an inclination of the side wall of the recess 40.
A portion of the first T-layer 60 remaining in the via hole 30 forms a via hole conductor 110. By means of the planarizing step, especially the intermediate layer 50 and the first T-layer 60 are removed in an area between the via hole 30 and the recess 40 so that, initially, there is no conductive connection between the via hole conductor 110 and the first electrode 90 of the capacitor 92. In order to guarantee this, also part of the first dielectric layer 20 is preferably removed during the planarizing step so that, after the planarizing step, the surface 22 of the first dielectric layer 20 can be located on a lower level, i.e. closer to the support layer 10.
The formation of the capacitor 92 is now finished. In the subsequent method steps, contact pads and conductors are produced for wiring,
In
In
Alternatively, the first electrode 90 of the capacitor 92 is additionally shown with a further conductor 126 in
Subsequently, a stop layer 160 is applied to the oxide hats 150, 152 and the oxide in the spaces 140, 142, 144, as shown in
The stop layer 160 has deposited thereon a thick silane layer 170 so as to produce the condition shown in
Just as in the case of the first embodiment, the silane layer 170 is then planarized by means of CMP so as to obtain a flat surface corresponding to the surface 22 of the first dielectric layer 20 of the first embodiment. The structure produced in this way is shown in
Again as in the case of the first embodiment, a via hole 30 is then etched so as to obtain the structure shown in
In a further etching step, a recess 40 is etched with an etchant, which is selective with respect to the stop layer 160, so as to obtain the condition shown in
Instead of a using stop layer in the first dielectric layer 20, as shown on the basis of the embodiment represented in
Subsequently, a via hole 30 and a recess 40 are produced in the first dielectric layer 20 so as to successively produce the structures which are shown in
The two capacitors 92, 92a are therefore coupled and can e.g. be connected in parallel so as to form an overall capacitance. It is also possible to connect a plurality of such capacitors in parallel; in this case, individual capacitances can be separated, e.g. by means of laser fusing or electric fusing, so as to finely tune the overall capacitance.
When, as shown in
In the case of the preceding embodiments, the danger exists that, during planarizing by means of CMP, a T-bridge may be formed across the edge of the portion 96 of the second dielectric layer 70 between the electrodes 90, 94 of the capacitor 92. Such a T-bridge produces a short circuit between the electrodes 90, 94 and destroys in this way the operability of the capacitor 92. The risk of dishing, i.e. the formation of a tungsten bridge can be reduced e.g. by selective overetching during structuring of the wiring conductors 120, 122, 124, as in the case of the capacitor shown on the basis of
The present embodiment differs from the first embodiment insofar as an additional first planarizing step is carried out already subsequent to the production of the first T-layer 60, which is shown in
As in the case of the preceding embodiments, a second dielectric layer 70 is then applied to the surface 22 of the dielectric layer 20, the first electrode 90 and the via hole conductor 110 over the full area thereof of these components, so as to obtain the structure shown in
The second dielectric layer 70 has deposited thereon a second T-layer 80, again over the full area thereof, so as to obtain the structure shown in
In a subsequent planarizing step, which corresponds essentially to the planarizing step of the preceding embodiments, planarizing is carried out down to the second dielectric layer 70, so as to obtain the structure shown in
By means of defined overpolishing or an additional wet-cleaning step, the second dielectric layer 70 is removed with exception of a portion 96 between the electrodes 90, 94. This results in the structure which is shown in
One advantage of the seventh embodiment of the method according to the present invention, which is shown on the basis of
In all embodiments, the first dielectric layer 20 can be a first layer bordering directly on a component layer of a semiconductor structure, the support layer 10 representing the component layer and the via hole 30 reaching preferably directly down to a component in the component layer 10, i.e. down to a contact of the component, instead of reaching down to the conductor 12. However, the present invention may just as well be used for producing a capacitor in a dielectric layer 20 spaced from a component layer of a semiconductor structure; the first dielectric layer 20 may then be located between two arbitrary wiring planes or it may also be the uppermost dielectric layer.
A special advantage of the material T used in the embodiments as a material for the via hole conductor 110 and the electrodes 90, 94 is that it is excellently suitable for polishing. If a via hole 30 is provided, a use of T for the electrodes 90, 94 is also advantageous insofar as the first electrode 90 can be formed in one step together with the via hole conductor 110. The production method according to the present invention is, however, also adapted to be used with other materials for the electrodes 90, 94, provided that these materials permit planarization with sufficient precision and reliability. Furthermore, different conductive materials can be used for the first electrode 90 and the second electrode 94.
Especially if the depth of the recess 40 is chosen such that it is much larger than the thickness of the first conductive layer 60, a capacitor 92 is obtained with pot-shaped electrodes 90, 94 and a pot-shaped portion 96 of the second dielectric layer 70 between the electrodes 90, 94, as has already been shown in
The method according to the present invention permits in an advantageous manner the simultaneous production of one or of a plurality of capacitors and of one or of a plurality of via hole conductors in the same dielectric layer, said via hole conductors being directly or indirectly connected to the capacitors or being electrically insulated therefrom. The method according to the present invention can, however, also be used and is also advantageous in cases in which a simultaneous production of a via hole conductor does not take place. Furthermore, it is also possible to simultaneously produce a plurality of capacitors, which are connected in parallel e.g. for forming an overall capacitance; for finely tuning the overall capacitance, individual ones of these capacitors can be separated by means of laser fusing.
While this invention has been described in terms of several preferred embodiments, there are alterations, permutations, and equivalents which fall within the scope of this invention. It should also be noted that there are many alternative ways of implementing the methods and compositions of the present invention. It is therefore intended that the following appended claims be interpreted as including all such alterations, permutations, and equivalents as fall within the true spirit and scope of the present invention.
Number | Date | Country | Kind |
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10202697.1-33 | Jan 2002 | DE | national |
Number | Date | Country | |
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Parent | PCT/EP03/00671 | Jan 2003 | US |
Child | 10898672 | Jul 2004 | US |