This invention relates generally to methods of providing electronic device structures, and relates more particularly to such methods for coupling and decoupling flexible substrates from rigid substrates and related methods and electronic device strictures.
Although flexible electronic devices may be used in a variety of ways that rigid electronic devices may not, manufacturing flexible electronic devices can be difficult and/or expensive. However, the difficulty and/or expense of manufacturing flexible electronic devices can be reduced by coupling flexible substrates to rigid substrates such that electronic devices can be manufactured on the flexible substrates using conventional equipment and/or techniques for rigid electronic device manufacturing. Accordingly, a need or potential for benefit exists for a method of decoupling the flexible substrates from the rigid substrates after manufacturing the electronic devices and for methods and electronic device structures related thereto.
To facilitate further description of the embodiments, the following drawings are provided in which:
For simplicity and clarity of illustration, the drawing figures illustrate the general manner of construction, and descriptions and details of well-known features and techniques may be omitted to avoid unnecessarily obscuring the invention. Additionally, elements in the drawing figures are not necessarily drawn to scale. For example, the dimensions of some of the elements in the figures may be exaggerated relative to other elements to help improve understanding of embodiments of the present invention. The same reference numerals in different figures denote the same elements.
The terms “first,” “second,” “third,” “fourth,” and the like in the description and in the claims, if any, are used for distinguishing between similar elements and not necessarily for describing a particular sequential or chronological order. It is to be understood that the terms so used are interchangeable under appropriate circumstances such that the embodiments described herein are, for example, capable of operation in sequences other than those illustrated or otherwise described herein. Furthermore, the terms “include,” and “have,” and any variations thereof, are intended to cover a non-exclusive inclusion, such that a process, method, system, article, device, or apparatus that comprises a list of elements is not necessarily limited to those elements, but may include other elements not expressly listed or inherent to such process, method, system, article, device, or apparatus.
The terms “left,” “right,” “front,” “back,” “top,” “bottom,” “over,” “under,” and the like in the description and in the claims, if any, are used for descriptive purposes and not necessarily for describing permanent relative positions. It is to be understood that the terms so used are interchangeable under appropriate circumstances such that the embodiments of the invention described herein are, for example, capable of operation in other orientations than those illustrated or otherwise described herein.
The terms “couple,” “coupled,” “couples,” “coupling,” and the like should be broadly understood and refer to connecting two or more elements or signals, electrically, mechanically and/or otherwise. Two or more electrical elements may be electrically coupled together, but not be mechanically or otherwise coupled together; two or more mechanical elements may be mechanically coupled together, but not be electrically or otherwise coupled together; two or more electrical elements may be mechanically coupled together, but not be electrically or otherwise coupled together. Coupling may be for any length of time, e.g., permanent or semi-permanent or only for an instant.
“Electrical coupling” and the like should be broadly understood and include coupling involving any electrical signal, whether a power signal, a data signal, and/or other types or combinations of electrical signals. “Mechanical coupling” and the like should be broadly understood and include mechanical coupling of all types.
The absence of the word “removably,” “removable,” and the like near the word “coupled,” and the like does not mean that the coupling, etc. in question is or is not removable.
The term “CTE matched material” as used herein means a material that has a coefficient of thermal expansion (CTE) which differs from the CTE of a reference material by less than about 20 percent (%). In some embodiments, the CTEs differ by less than about 10%, 5%, 3%, or 1%.
Some embodiments include a method of providing one or more electronic devices. The method can comprise: providing a carrier substrate; providing an intermediate substrate comprising a first intermediate substrate surface and a second intermediate substrate surface opposite the first intermediate substrate surface; providing a flexible substrate comprising a first flexible substrate surface and a second flexible substrate surface opposite the first flexible substrate surface; coupling the first intermediate substrate surface to the carrier substrate with a first adhesive; and coupling the second intermediate substrate surface to the first flexible substrate surface with a second adhesive.
Various embodiments include a method of providing one or more electronic devices. The method can comprise: providing a carrier substrate; providing a flexible substrate; and interposing a ruggedization film between the carrier substrate and the flexible substrate in order to couple the flexible substrate to the carrier substrate. The ruggedization film can be configured to substantially relieve stress formed at the flexible substrate when the flexible substrate is decoupled from the carrier substrate.
Further embodiments include an electronic device structure. The electronic device structure comprises an intermediate substrate. The substrate comprises a first intermediate substrate surface and a second intermediate substrate surface opposite the first intermediate substrate surface. Meanwhile, the first intermediate substrate surface can be configured to be coupled to a carrier substrate by a first adhesive. The electronic device structure further comprises a flexible substrate. The flexible substrate comprises a first flexible substrate surface and a second flexible substrate surface opposite the first flexible substrate surface. The first flexible substrate surface can be configured to be coupled to the second intermediate substrate surface by a second adhesive, and the second flexible substrate surface can be configured such that one or more electronic devices can be formed over the second flexible substrate surface when the first intermediate substrate surface is coupled to the carrier substrate and when the first flexible substrate surface is coupled to the second intermediate substrate surface.
Referring to
Referring to
In many embodiments, procedure 101 can also comprise process 202 of treating the carrier substrate. In many embodiments, process 202 can be performed before performing procedure 106.
In some embodiments, performing procedure 101 can also comprise a process of providing the carrier substrate where the carrier substrate comprises the first adhesive, such as, for example, at the first carrier substrate surface. In these embodiments, process 202 can be omitted (although the carrier substrate could still have been treated before the adhesive was applied thereto).
Referring to
Meanwhile, process 202 can also comprise activity 302 of etching the carrier substrate, such as, for example, by ashing the carrier substrate with an oxygen (O2) plasma. Thus, in some examples, activity 302 can comprise etching the carrier substrate by ashing the carrier substrate in a Tegal 965 asher, manufactured by legal Corporation of Petaluma, Calif., or another suitable device for ashing the carrier substrate. The device for ashing the carrier substrate can be operated at a power level of approximately 250 Watts (or approximately 200-300 Watts). Meanwhile, activity 302 can be performed at a pressure of approximately 0.16 kilopascals (or approximately 0.1-0.2 kilopascals) and/or for a time of approximately 30 minutes (or approximately 15-45 minutes).
Referring to the drawings,
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Procedure 102 can also comprise process 502 of baking the intermediate substrate, such as, for example, with a Yamato oven, manufactured by Yamato Scientific America, Inc. of Santa Clara, Calif., or another suitable device for baking the intermediate substrate without damaging the intermediate substrate. Process 502 can be performed at a preliminary baking condition. The preliminary baking condition can comprise a preliminary baking temperature, a preliminary baking pressure, and/or a preliminary baking time. For example, the preliminary baking temperature can be approximately 200° C. Meanwhile, the preliminary baking pressure can be approximately 0.004 kilopascals (or approximately 0-0.010 kilopascals). Furthermore, the preliminary baking time can be approximately 1 hour. In various embodiments, performing process 502 can comprise an activity of exposing the first intermediate substrate surface and the second intermediate substrate surface to an ionic blower for greater than or equal to approximately 10 seconds prior to baking the intermediate substrate. In some embodiments, process 502 can be omitted.
Procedure 102 can further comprise process 503 of cutting the intermediate substrate. In many embodiments, performing process 503 can comprise sizing the intermediate substrate based on the carrier substrate and/or the flexible substrate. For example, performing process 503 can comprise cutting (e.g., sizing) the intermediate substrate such that the perimeter of the intermediate substrate is offset (e.g., smaller in at least one lateral dimension) from the perimeter of the carrier substrate by greater than or equal to approximately 1.5 millimeters, or 2 millimeters, etc. (or approximately 1-5 millimeters). Likewise, performing process 503 can also comprise cutting (e.g., sizing) the intermediate substrate such that the perimeter of the intermediate substrate is offset (e.g., larger in at least one lateral dimension) than the perimeter of the flexible substrate. Performing process 503 in this manner can aid in performing procedure 112 (
In some embodiments, procedure 102 can also comprise a process of providing the intermediate substrate where the first intermediate substrate surface comprises a first adhesive (e.g., where the intermediate substrate comprises tape). In these embodiments, process 502 and/or process 503 can be omitted. In further embodiments, this process can be omitted.
Meanwhile, in the same or other embodiments, procedure 102 can also comprise a process of providing the intermediate substrate where the second intermediate substrate surface comprises a second adhesive (e.g., where the intermediate substrate comprises tape, such as, for example, double-sided tape). In these embodiments, process 502 and/or process 503 can also be omitted. Likewise, in many embodiments, this process can be omitted like the process of providing the intermediate substrate where the first intermediate substrate surface comprises the first adhesive, as described with respect to procedure 101 (
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The flexible substrate comprises a first flexible substrate surface and a second flexible substrate surface opposite the first flexible substrate surface. The first flexible substrate surface can be configured to be coupled to the second intermediate substrate surface by a second adhesive. Meanwhile, the second flexible substrate surface can be configured such that electronic device(s) are able to be formed over the second flexible substrate surface, such as, for example, when the first intermediate substrate surface is coupled to the carrier substrate and when the first flexible substrate surface is coupled to the second intermediate substrate surface.
In some embodiments, performing procedure 103 can comprise a process of providing the flexible substrate where the flexible substrate comprises a flexible substrate material lacking sufficient mechanical strength to prevent the flexible substrate from being damaged if the flexible substrate were to be coupled to and decoupled from the carrier substrate directly.
Meanwhile, similar to as described above with respect to procedure 101 and/or procedure 102, in some embodiments, performing procedure 103 can comprise a process of providing the flexible substrate where the first flexible substrate surface comprises the second adhesive. In other embodiments, this process can likewise be omitted.
In many embodiments, procedure 103 can comprise a process of treating the flexible substrate. The process can be similar or identical to performing process 202 (
Meanwhile, method 100 can comprise procedure 104 of providing the first adhesive. In various embodiments, performing procedure 104 can comprise applying and/or depositing the first adhesive at the first carrier substrate surface and/or the first intermediate substrate surface. In general, procedure 104 can be performed where the first carrier substrate surface and/or the first intermediate substrate surface do not comprise the first adhesive. Performing procedure 104 can comprise applying and/or depositing the first adhesive at the first carrier substrate surface and/or the first intermediate substrate surface according to any suitable technique for applying and/or depositing the first adhesive (e.g., spin-coating, spray-coating, extrusion-coating, preform laminating, slot die coating, screen laminating, screen printing, etc.). For example, performing process 104 can comprise applying and/or depositing the first adhesive at the first carrier substrate surface and/or the first intermediate substrate surface by spin coating the first adhesive at the first carrier substrate surface and/or the first intermediate substrate surface at a rotational speed of approximately 1000 rotations per minute for approximately 25 seconds and/or at a rotational speed of approximately 3500 rotations per minute for approximately 20 seconds. In some embodiments, procedure 104 can be omitted, such as where the first carrier substrate surface and/or the first intermediate substrate surface already comprise the first adhesive.
Skipping ahead in the drawings,
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In various embodiments, procedure 104 and/or procedure 105 can be performed as part of procedure 106. For example, procedure 104 can be performed prior to performing process 701 and process 702, and procedure 105 can be performed after process 701 but prior to process 702. In a different example, procedure 104 can be performed prior to process 701 and after process 702 while procedure 105 can be performed prior to both process 701 and process 702. In still other examples, procedure 104 and procedure 105 can be performed prior to performing procedure 106, such as where process 701 and process 702 are performed approximately simultaneously with each other.
In some embodiments, the first adhesive and the second adhesive can comprise the same adhesive material, and in other embodiments, the first adhesive and the second adhesive can comprise different adhesive materials. The first adhesive and/or the second adhesive can comprise any suitable adhesive material (e.g., Henkel NS122 adhesive manufactured by Henkel AG & Company, KGaA of Dusseldorf, Germany; EccoCoat 3613 adhesive manufactured by Henkel AG & Company, KGaA of Dusseldorf, Germany; etc.). In these or other embodiments, the adhesive material can comprise a thermally cured adhesive, a pressure sensitive adhesive, an ultraviolet cured adhesive, etc. In many embodiments, the first adhesive can be selected according to the material properties of the carrier substrate and the intermediate substrate. Likewise, the second adhesive can be selected according to the material properties of the intermediate substrate and the flexible substrate. For example, the first adhesive and/or second adhesive can comprise the Henkel NS122 adhesive when the intermediate substrate comprises polyethylene naphthalate or polyethylene terephthalate. Meanwhile, where the intermediate substrate comprises polyimide, the first adhesive and/or the second adhesive can comprise the EccoCoat 3613 adhesive.
Meanwhile, method 100 can comprise procedure 106 of interposing an intermediate substrate between the carrier substrate and the flexible substrate in order to couple the flexible substrate to the carrier substrate. In some embodiments, performing procedure 106 and/or process 702 can comprise coupling the intermediate substrate to the flexible substrate in order to reinforce the flexible substrate.
Referring to
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Performing activity 801 can prevent damage to and/or contamination of the first intermediate substrate surface or the second intermediate substrate surface, as applicable, when performing activity 802. Accordingly, where process 701 is performed prior to process 702, performing activity 801 can comprise providing the protective layer at the second intermediate substrate surface. Alternatively, when process 701 is performed after process 702, performing activity 801 can comprise providing the protective layer at the first intermediate substrate surface. In some embodiments, activity 801 can be omitted.
Meanwhile, process 701 can continue with activity 802 of bonding the first intermediate substrate surface to the carrier substrate with the first adhesive using any suitable lamination device (e.g., a roll press, a bladder press, etc.). In many embodiments, bonding the first intermediate substrate surface to the carrier substrate can occur at a first condition. The first condition can comprise a first pressure, a first temperature, and/or a first feed rate. For example, the first pressure can be greater than or equal to approximately 0 kilopascals (i.e., in a vacuum) and less than or equal to approximately 69 kilopascals (e.g., where the intermediate substrate comprises polyimide) or less than or equal to approximately 150 kilopascals in other embodiments. Furthermore, the first feed rate can be greater than or equal to approximately 0.25 meters per minute and less than or equal to approximately 0.5 meters per minute (or approximately 0.10-1.0 meters per minute). Meanwhile, the first temperature can be greater than or equal to approximately 20° C. and less than or equal to approximately 100° C., 160° C., 220° C., 350° C., etc. For example, the first temperature can be less than or equal to approximately 220° C. (e.g., approximately 100° C.) where the intermediate substrate comprises polyethylene naphthalate and can be less than or equal to approximately 160° C. (e.g., approximately 100° C.) where the intermediate substrate comprises polyethylene terephthalate. Meanwhile, the first temperature can be less than or equal to approximately 350° C. (e.g., approximately 100° C.) where the intermediate substrate comprises polyimide. Generally speaking, the first pressure and/or the first temperature can depend on the material properties and/or limitations of the intermediate substrate.
In some embodiments, process 701 can also comprise activity 803 of removing the protective layer from one of the first intermediate substrate surface or the second intermediate substrate surface. In some embodiments, activity 803 can be omitted, such as, for example, where activity 801 is omitted.
Returning to the drawings,
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Process 702 can continue with activity 1002 of bonding the second intermediate substrate surface to the first flexible substrate surface with the second adhesive using any suitable lamination device (e.g., a roll press, a bladder press, etc.). In many embodiments, bonding the second intermediate substrate surface to the first flexible substrate surface occurs at a second condition. The second condition can be similar or identical to the first condition described above with respect to activity 802 (
Process 702 can further comprise activity 1003 of etching the carrier substrate, the intermediate substrate, the flexible substrate, the first adhesive, and the second adhesive after coupling the first intermediate substrate surface to the carrier substrate and after coupling the second intermediate substrate surface to the first flexible substrate surface. In some embodiments, performing activity 1003 can comprise ashing the carrier substrate, the intermediate substrate, the flexible substrate, the first adhesive, and the second adhesive with a Tegal 901 asher, manufactured by Tegal Corporation of Petaluma, Calif., or another suitable device for ashing the carrier substrate, the intermediate substrate, the flexible substrate, the first adhesive, and the second adhesive. Activity 1003 can be performed for greater than or equal to approximately 900 seconds. In many embodiments, performing activity 1003 can remove excess of the first adhesive and/or the second adhesive.
In some embodiments, activity 1003 can be performed as part of process 701 (
In some embodiments, process 702 can also comprise activity 1004 of removing the protective layer at the second flexible substrate. In some embodiments, where process 701 is performed after process 702, activity 1004 can be performed after process 701 is performed.
Returning again to the drawings,
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Method 100 can comprise procedure 108 of cleaning the carrier substrate, the intermediate substrate, the flexible substrate, the first adhesive, and the second adhesive. Procedure 108 can be similar to activity 301 (
Method 100 can comprise procedure 109 of baking the carrier substrate, the intermediate substrate, the flexible substrate, the first adhesive, and the second adhesive. Procedure 109 can be similar to process 502 (
Method 100 can also comprise procedure 110 of cleaning the carrier substrate, the intermediate substrate, the flexible substrate, the first adhesive, and the second adhesive. Procedure 110 can be similar to activity 301 (
Method 100 can additionally comprise procedure 111 of drying the carrier substrate, the intermediate substrate, the flexible substrate, the first adhesive, and the second adhesive. In some embodiments, procedure 111 can comprise drying the carrier substrate, the intermediate substrate, the flexible substrate, the first adhesive, and the second adhesive in an oven, such as, for example, with a Yamato Oven, manufactured by Yamato Scientific America, Inc. of Santa Clara, Calif., or another suitable device for baking the intermediate substrate. Process 502 can be performed at a dry baking condition. The dry baking condition can comprise a dry baking temperature (e.g., approximately 80-120° C., for example, approximately 100° C.) and/or a dry baking time (e.g., greater than or equal to approximately 1 hours and less than or equal to approximately 4 hours, for example, approximately 3 hours). In many embodiments, procedure 111 can be performed after procedure 110. Procedure 111 can also comprise cooling and/or permitting to cool the carrier substrate, the intermediate substrate, the flexible substrate, the first adhesive, and the second adhesive for greater than or equal to approximately 30 minutes. Performing procedure 111 can remove moisture from and/or outgas the carrier substrate, the intermediate substrate, the flexible substrate, the first adhesive, and the second adhesive. Accordingly, the length of the dry baking time can depend on the materials used for the carrier substrate, the intermediate substrate, the flexible substrate, the first adhesive, and/or the second adhesive as well as the out-gassing rate and/or out-diffusion rate of the carrier substrate, the intermediate substrate, the flexible substrate, the first adhesive, and the second adhesive.
Method 100 can further comprise procedure 112 of depositing a nitride barrier layer over the second flexible substrate surface. Procedure 112 can comprise depositing the nitride barrier to a nitride barrier thickness of approximately 0.3 micrometers (or approximately 0.2-0.5 micrometers). In many embodiments, procedure 112 can be performed after procedure 111.
Method 100 can also comprise procedure 113 of inspecting the carrier substrate, the intermediate substrate, the flexible substrate, the first adhesive, and the second adhesive, such as, for example, to determine if any of the carrier substrate, the intermediate substrate, and/or the flexible substrate are damaged. In some embodiments, procedure 113 can be omitted. Procedure 113 can be performed after procedure 112.
Method 100 can comprise procedure 114 of forming one or more electronic devices over the second flexible substrate surface. The electronic device(s) can comprise one or more electronic sensors, one or more electronic displays, one or more electronic transistors (e.g., thin film transistors), one or more electronic diodes, one or more micro-electromechanical systems, or any other suitable electronic device(s). In many embodiments, procedure 114 can be performed after performing procedures 101 through 113.
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In many embodiments, procedure 115 can comprise mechanically decoupling the first intermediate substrate surface from the carrier substrate. For example, in these embodiments, procedure 115 can comprise inserting a tool (e.g., a bladed edge) at the first intermediate substrate surface (e.g., between the first adhesive and the first intermediate substrate surface) and pushing the tool along the first intermediate substrate surface at an angle greater than or equal to approximately 0 degrees and less than or equal to approximately 45 degrees with respect to the first intermediate substrate surface in order to release the first intermediate substrate surface from the carrier substrate.
In other embodiments, procedure 115 can comprise decoupling the first intermediate substrate surface from the carrier substrate according to any other suitable technique (e.g., chemical, laser, ultraviolet, thermal, etc.) for decoupling the first intermediate substrate surface from the carrier substrate. Accordingly, any suitable debonding techniques described in United States Patent Publication Serial No. 20100297829, United States Patent Publication Serial No. 20110023672, United States Patent Publication Serial No. 20110064953, United States Patent Publication Serial No. 20110228492, the technical paper of S. M. O'Rourke, et al., Direct Fabrication of a-Si:H Thin Film Transistor Arrays on Plastic and Metal Foils for Flexible Displays, ADM002187, Proceedings of the Army Science Conference (26th), pp. 1-4, December 2008, and the technical paper of Satoshi Inoue, et al., Surfac-Free Technology by Laser Annealing (SUFTLA) and Its Application to Poly-Si TFT-LCDs on Plastic Film With Integrated Drivers, IEEE Transactions on Electron Devices, Vol. 49, No. 8, pp. 1353-1360, August 2002, each of which is incorporated by reference herein, can be used to perform procedure 115.
In many embodiments, procedure 115 can be performed in such a manner that the first adhesive remains with the carrier substrate. However, in some embodiments, the first intermediate substrate surface can be etched in a manner similar to activity 302 (
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Notwithstanding those embodiments where it is desirable to leave the intermediate substrate coupled to the flexible substrate, procedure 116 can comprise mechanically decoupling the second intermediate substrate surface from the first flexible substrate surface. For example, mechanically decoupling the second intermediate substrate surface from the first flexible substrate surface can comprise manually pulling the intermediate substrate away from the flexible substrate with a continuous force and at a low angle (e.g., approximately 5-45 degrees) with respect to the flexible substrate in order to release the second intermediate substrate surface form the first flexible substrate surface. In these examples, procedure 116 can comprise providing a protective layer over the second flexible substrate surface to protect any electronic device(s) formed thereon while performing procedure 116.
Meanwhile, procedure 116 can also comprise decoupling the second intermediate substrate surface from the first flexible substrate surface according to any other suitable technique (e.g., chemical, laser, ultraviolet, thermal, etc.) for decoupling the first intermediate substrate surface from the carrier substrate. Accordingly, procedure 116 can be similar or identical to procedure 115.
In some embodiments, procedure 116 can further comprise etching the flexible substrate in a manner similar to activity 302 (
In many embodiments, procedure 102 through procedure 116 can be performed for both sides of the carrier substrate of procedure 101 of method 100. In these embodiments, one or more of procedure 102 through procedure 116 can be performed approximately simultaneously for both sides of the carrier substrate. Meanwhile, in these or other embodiments, one or more of procedure 102 through procedure 116 can be repeated and performed separately for each side of the carrier substrate.
Although the invention has been described with reference to specific embodiments, it will be understood by those skilled in the art that various changes may be made without departing from the spirit or scope of the invention. Accordingly, the disclosure of embodiments of the invention is intended to be illustrative of the scope of the invention and is not intended to be limiting. It is intended that the scope of the invention shall be limited only to the extent required by the appended claims. For example, to one of ordinary skill in the art, it will be readily apparent that procedures 101-116 of
All elements claimed in any particular claim are essential to the embodiment claimed in that particular claim. Consequently, replacement of one or more claimed elements constitutes reconstruction and not repair. Additionally, benefits, other advantages, and solutions to problems have been described with regard to specific embodiments. The benefits, advantages, solutions to problems, and any element or elements that may cause any benefit, advantage, or solution to occur or become more pronounced, however, are not to be construed as critical, required, or essential features or elements of any or all of the claims, unless such benefits, advantages, solutions, or elements are expressly stated in such claim.
Moreover, embodiments and limitations disclosed herein are not dedicated to the public under the doctrine of dedication if the embodiments and/or limitations: (1) are not expressly claimed in the claims; and (2) are or are potentially equivalents of express elements and/or limitations in the claims under the doctrine of equivalents.
This application is a continuation application of PCT Application No. PCT/US2012/066833, filed Nov. 28, 2012, and is a continuation-in-part application of U.S. patent application Ser. No. 13/913,141, filed Jun. 7, 2013. PCT Application No. PCT/US2012/066833 claims the benefit of U.S. Provisional Patent Application No. 61/564,535, filed Nov. 29, 2011. Meanwhile, U.S. patent application Ser. No. 13/913,141 is a continuation application of U.S. patent application Ser. No. 13/118,225, filed May 27, 2011, and U.S. Non-Provisional application Ser. No. 13/118,225 is a continuation application of PCT Application No. PCT/US2009/066259, filed on Dec. 1, 2009. PCT Application No. PCT/US2009/066259 claims the benefit of (a) U.S. Provisional Application 61/230,051, filed Jul. 30, 2009, (b) U.S. Provisional Application 61/182,464, filed May 29, 2009, and (c) U.S. Provisional Application 61/119,217, filed Dec. 2, 2008. PCT Application No. PCT/US2012/066833, U.S. Provisional Patent Application No. 61/564,535, U.S. patent application Ser. No. 13/913,141, U.S. patent application Ser. No. 13/118,225, PCT Application No. PCT/US2009/066259, U.S. Provisional Application 61/230,051, U.S. Provisional Application 61/182,464, and U.S. Provisional Application 61/119,217 are incorporated herein by reference in their entirety.
This invention was made with government support under W911NF-04-2-0005 awarded by the Army Research Office. The government has certain rights in the invention.
Number | Date | Country | |
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61564535 | Nov 2011 | US | |
61230051 | Jul 2009 | US | |
61182464 | May 2009 | US | |
61119217 | Dec 2008 | US |
Number | Date | Country | |
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Parent | PCT/US12/66833 | Nov 2012 | US |
Child | 14288771 | US | |
Parent | 13118225 | May 2011 | US |
Child | 13913141 | US | |
Parent | PCT/US09/66259 | Dec 2009 | US |
Child | 13118225 | US |
Number | Date | Country | |
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Parent | 13913141 | Jun 2013 | US |
Child | PCT/US12/66833 | US |