Embodiments of the present principles generally relate to semiconductor processing.
Semiconductor substrate processing systems generally include a process chamber having a pedestal for supporting a substrate, such as a semiconductor substrate, within the chamber proximate a processing zone. The chamber forms a vacuum enclosure defining, in part, the processing zone for performing certain processes upon the substrate. In some processes, plasma may be used for the deposition of materials or etching of materials. The plasma produces a harsh environment within the process chamber. Conventional showerheads utilized in process chambers are composed of a metal-based material and include a gas delivery device that flows gas into the process chamber. The gases are used for various processing purposes such as deposition of a material onto a substrate placed in the process chamber. The delivered gas parameters such as pressure, temperature, and velocity impact the processing of the substrate in the chamber. The inventors have found that showerheads composed of metal-based material can react with some gases used during processing, affecting the quality of the processing.
Thus, the inventors have provided improved methods and apparatus for enhanced gas delivery in a semiconductor process chamber.
Methods and apparatus for enhanced gas delivery in a semiconductor process chamber are provided herein.
In some embodiments, an apparatus for gas distribution in a process chamber may comprise a showerhead composed of a non-metallic material with a first gas channel and a second gas channel, wherein the first gas channel and the second gas channel are independent of each other; a first electrode embedded in the showerhead near a top surface of the showerhead, and a second electrode embedded in the showerhead near a bottom surface of the showerhead.
In some embodiments, the apparatus may further include wherein the showerhead is comprised of a ceramic material, wherein the ceramic material is aluminum nitride or aluminum oxide, wherein the first electrode is configured to provide a radio frequency (RF) ground return path when installed in the process chamber, wherein the second electrode is configured to provide radio frequency (RF) power when installed in the process chamber, wherein at least one channel of the first gas channel extends from a first opening in the top surface of the showerhead and through the showerhead to a second opening at the bottom surface of the showerhead, wherein the first opening and the second opening are different sizes, wherein at least one channel of the second gas channel extends from a gas inlet on a side of the showerhead to at least one third opening at the bottom surface of the showerhead, wherein the showerhead is a single, unitary piece composed of multiple layers of ceramic material bonded together, and/or wherein the showerhead has a plurality of through holes from the top surface of the showerhead to the bottom surface of the showerhead and a plurality of holes on the bottom surface of the showerhead connected to one or more inlets on a side of the showerhead.
In some embodiments, an apparatus for gas distribution in a process chamber may comprise a showerhead composed of a non-metallic material with a first gas channel and a second gas channel, wherein the first gas channel and the second gas channel are independent of each other, and wherein the first gas channel includes a plurality of through holes from a top surface of the showerhead to a bottom surface of the showerhead and the second gas channel includes a plurality of holes on the bottom surface of the showerhead connected to one or more gas inlets on a side of the showerhead, a first electrode embedded in the showerhead near the top surface of the showerhead, and a second electrode embedded in the showerhead near the bottom surface of the showerhead.
In some embodiments, the apparatus may further include wherein the showerhead is comprised of a ceramic material, wherein the ceramic material is aluminum nitride or aluminum oxide, wherein the first electrode is configured to provide a radio frequency (RF) ground return path when installed in the process chamber, wherein the second electrode is configured to provide radio frequency (RF) power when installed in the process chamber, wherein at least one hole of the plurality of through holes of the first gas channel has a first opening in the top surface of the showerhead and a second opening at the bottom surface of the showerhead and wherein the first opening and the second opening are different sizes, and/or wherein the showerhead is a single, unitary piece composed of multiple layers of ceramic material bonded together.
In some embodiments, a system for processing substrates may comprise a process chamber with an inner process volume; a showerhead configured to divide the inner process volume into an upper process volume and a lower process volume, wherein the showerhead has a first gas channel and a second gas channel that are independent of each other, and wherein the first gas channel is configured to fluidly couple the upper process volume to the lower process volume and the second gas channel is configured to fluidly couple at least one external gas to the lower process volume; a first electrode embedded in the showerhead near a top surface of the showerhead, wherein the first electrode is configured to provide a radio frequency (RF) ground return for plasma generation in the upper process volume; and a second electrode embedded in the showerhead near a bottom surface of the showerhead, wherein the second electrode is configured to provide RF power for plasma generation in the lower process volume.
In some embodiments, the system may further include wherein the showerhead composed of a ceramic material and/or wherein the showerhead is composed of a single, unitary piece comprising multiple layers of ceramic material bonded together.
Other and further embodiments are disclosed below.
Embodiments of the present principles, briefly summarized above and discussed in greater detail below, can be understood by reference to the illustrative embodiments of the principles depicted in the appended drawings. However, the appended drawings illustrate only typical embodiments of the principles and are thus not to be considered limiting of scope, for the principles may admit to other equally effective embodiments.
To facilitate understanding, identical reference numerals have been used, where possible, to designate identical elements that are common to the figures. The figures are not drawn to scale and may be simplified for clarity. Elements and features of one embodiment may be beneficially incorporated in other embodiments without further recitation.
The methods and apparatus provide enhanced gas delivery for plasma processes. In some embodiments, an intermediate showerhead assembly for installation between an upper showerhead and a substrate support in a process chamber provides a dual channel gas delivery system that is impervious to harsh gas environments. The intermediate showerhead assembly may be composed of a non-metallic material such as a ceramic material including but not limited to aluminum nitride or aluminum oxide which is compatible with radicals and gasses based on chlorine, fluorine, hydrogen, nitrogen, silane, and other aggressive chemistries that are typically used in process chambers at high temperatures (above approximately 300 degrees Celsius). The intermediate showerhead assembly provides a dual channel gas delivery showerhead with the capability to strike radio frequency (RF) plasma above the intermediate showerhead assembly as well as below the intermediate showerhead assembly. The intermediate showerhead assembly has an embedded RF mesh electrode near the top side and an embedded RF mesh electrode near the bottom side of the intermediate showerhead assembly.
The inventors have found that for some processes to be accomplished a dual channel gas delivery method should be utilized. The intermediate showerhead assembly provides the compatible material, dual channel gas delivery, and provides the capability to strike plasma above and below the intermediate showerhead assembly. The ability to form plasma above and below the intermediate showerhead assembly enables a remote plasma condition (above the intermediate showerhead assembly) as well as a direct plasma condition (below the intermediate showerhead assembly) based on the process requirement. The advantage of having remote plasma capability in a process chamber is that the plasma species are easier to control. With remote plasma, both ions and radicals are produced. The ions are very directional and are mostly filtered by the intermediate showerhead assembly and stay within the remote plasma (above the intermediate showerhead assembly). The radicals can diffuse and are not directional, easily passing through the intermediate showerhead assembly towards the substrate. In some processes, the radicals are used to react with other elements to create a desired effect on the substrate. The remote plasma allows precise control over the processes such as, for example, chemical vapor deposition (CVD) titanium silicide processes and the like.
In some embodiments, the intermediate showerhead assembly may operate at high temperatures (above approximately 300 degrees Celsius) while delivering gases through dual channels and support remote and direct plasma processes for deposition processes. The inventors have found that the intermediate showerhead assembly provides a solution to a unique process which has many elements of complexity including material, RF, high temperature, and gas delivery compatibility issues. The inventors have also found that ceramic materials such as, for example, aluminum nitride, aluminum oxide (Al2O3, alumina), yttrium oxide (Y2O3), and silicon carbide (SiC) may be non-reactive with silane gas at high temperatures. The inventors have also found that formation of the intermediate showerhead assembly is a complex procedure that may be simplified by constructing the intermediate showerhead assembly as two separate pieces that are then bonded together to form a single, unitary piece or layer by layer bonding to form the entire piece. Each piece has an embedded RF mesh such that the single, unitary piece has an upper embedded electrode for supporting remote plasma and a lower embedded electrode to support direct plasma (relative to the substrate support).
With the dual gas delivery channels, dual electrodes for remote and direct plasma capability, and composed of a material impervious to hazardous chemistries, the intermediate showerhead assembly may allow for more complex processes to be performed. The advantage of having separate dual channels in the intermediate showerhead assembly is that harsh chemistries may be transferred to the substrate without intermixing with gases in the other channel. For example, the dual channels allow for deposition of films that may help to increase production throughput. When titanium is deposited on silicon, the process consumes the silicon and reduces the electrical benefits gained by using the silicon. By introducing silane into the process, titanium silicide can be formed to stop the consumption of silicon. The intermediate showerhead assembly uses a non-metallic material such as a ceramic composition which is impervious to harsh chemistries such as silane, and with the dual gas delivery channels, allows the silane to be used in processes without mixing with gases from the other channel. The intermediate showerhead assembly provides unique and highly advantageous features that allow previously complicated processes to be performed in a single process chamber, increasing throughput and decreasing costs.
The substrate support 108 generally comprises a body 143 having a substrate support surface 141 for supporting a substrate 110 thereon. In some embodiments, the substrate support 108 may include an apparatus that retains or supports the substrate 110 on the surface of the substrate support 108, such as an electrostatic chuck, a vacuum chuck, a substrate retaining clamp, or the like (not shown). In some embodiments, the substrate support 108 may include a radio frequency (RF) bias electrode 168. The RF bias electrode 168 may be coupled to one or more RF bias power sources through one or more respective matching networks (one RF bias power source 148A and one matching network 146A shown in
In some embodiments, the substrate support 108 may include one or more mechanisms for controlling the temperature of the substrate support surface 141 and the substrate 110 disposed thereon. For example, one or more channels (not shown) may be provided to define one or more flow paths beneath the substrate support surface to flow a heat transfer medium similar to as described below with respect to the upper showerhead assembly 114. The upper showerhead assembly 114 may be coupled to a gas supply 116 for providing one or more process gases into the upper process volume 104A of the process chamber 100. The intermediate showerhead assembly 170 may be coupled to a gas supply 172 for providing one or more process gases into the lower process volume 1046 of the process chamber. The intermediate showerhead assembly 170 is discussed in detail below. Additional gas inlets may be provided such as nozzles or inlets disposed in the ceiling or on the sidewalls of the process chamber 100 or at other locations suitable for providing gases to the process chamber 100, such as the base of the process chamber 100, the periphery of the substrate support 108, or the like.
In some embodiments, the RF plasma power source 148B and/or the RF plasma power source 148C may be coupled to the process chamber 100 through one or more matching networks 146B, 146C for providing power for processing. In some embodiments, the process chamber 100 may utilize capacitively coupled RF power provided to an upper electrode 140 proximate an upper portion of the process chamber 100. The upper electrode 140 may be a conductor in an upper portion of the process chamber 100 or formed, at least in part, by one or more of a ceiling 142, the upper showerhead assembly 114, or the like, fabricated from a suitable conductive material. For example, in some embodiments, one or more RF plasma power sources 148B may be coupled to a conductive portion of the ceiling 142 of the process chamber 100 or to a conductive portion of the upper showerhead assembly 114. The ceiling 142 may be substantially flat, although other types of ceilings, such as dome-shaped ceilings or the like, may also be utilized.
In some embodiments, the intermediate showerhead assembly 170 may have a first electrode 190 embedded near a top surface of the intermediate showerhead assembly that acts as an RF ground return for the one or more RF plasma power sources 148B to support plasma in an upper process volume 104A above the intermediate showerhead assembly 170. The first electrode 190 may be grounded 180 to a wall of the process chamber 100. In some embodiments, a second electrode 192 in the intermediate showerhead assembly 170 may be coupled to RF plasma power source 148B or to another RF plasma power source 148C via matching network 146C to support plasma in the lower process volume 104B. The RF plasma power sources 148B, 148C may be capable of producing up to 6000 W at a frequency of approximately 350 kHz, approximately 13.56 MHz, or higher frequency, such as approximately 27 MHz and/or approximately 60 MHz and/or approximately 162 MHz. Alternatively, the one or more RF plasma power sources 148B may be coupled to inductive coil elements (not shown) disposed proximate the ceiling of the process chamber 100 to form a plasma with inductively coupled RF power.
In some embodiments, the upper process volume 104A and the lower process volume 104B may be fluidly coupled to an exhaust system 120. The exhaust system 120 may facilitate uniform flow of the exhaust gases from the upper process volume 104A and the lower process volume 104B of the process chamber 100. The exhaust system 120 generally includes a pumping plenum 124 and a plurality of conduits (not shown) that couple the pumping plenum 124 to the upper process volume 104A and the lower process volume 104B of the process chamber 100. A conduit has an inlet 122 coupled to the upper process volume 104A and the lower process volume 104B (or, in some embodiments, the exhaust volume 106) and an outlet (not shown) fluidly coupled to the pumping plenum 124. For example, a conduit may have an inlet 122 disposed in a lower region of a sidewall or a floor of the process chamber 100. In some embodiments, the inlets are substantially equidistantly spaced from apart.
A vacuum pump 128 may be coupled to the pumping plenum 124 via a pumping port 126 for pumping out the exhaust gases from the process chamber 100. The vacuum pump 128 may be fluidly coupled to an exhaust outlet 132 for routing the exhaust to appropriate exhaust handling equipment. A valve 130 (such as a gate valve, or the like) may be disposed in the pumping plenum 124 to facilitate control of the flow rate of the exhaust gases in combination with the operation of the vacuum pump 128. Although a z-motion gate valve is shown, any suitable, process compatible valve for controlling the flow of the exhaust may be utilized.
In operation, the substrate 110 may enter the process chamber 100 via an opening 112 in the chamber body 102. The opening 112 may be selectively sealed via a slit valve 118, or other apparatus for selectively providing access to the interior of the chamber through the opening 112. The substrate support 108 may be coupled to a lift apparatus 134 that may control the position of the substrate support 108 between a lower position (as shown) suitable for transferring substrates into and out of the chamber via the opening 112 and a selectable upper position suitable for processing. The process position may be selected to maximize process uniformity for a particular process step. When in an elevated processing position, the substrate support 108 may be disposed above the opening 112 to provide a symmetrical processing region. After the substrate 110 is disposed within the process chamber 100, the chamber may be pumped down to a pressure suitable for forming a plasma and one or more process gases may be introduced into the process chamber 100 via the upper showerhead assembly 114 and/or the intermediate showerhead assembly 170 (and/or other gas inlets). RF power may be provided to strike and maintain a plasma in the upper process volume 104A and/or the lower process volume 104B from the process gases to process the substrate 110. During processing, such as in the above example, the temperature of the upper showerhead assembly 114 may be controlled to provide a more uniform temperature profile across a substrate-facing surface of the upper showerhead assembly 114. A heat transfer medium source 136 may be coupled to the channels to provide the heat transfer medium to the one or more channels. A controller 137 may control the operation of the one or more valves 139 and/or of the heat transfer medium source 136.
In
Second channels 212 are embedded into the intermediate showerhead assembly 170 and allow a second gas to flow independently and separately from gases that flow through the first channels 210. The second channels 212, unlike the first channels 210, are interconnected inside the intermediate showerhead assembly 170. In some embodiments, the second channels 212 may have one or more gas inlets 250 on a side of the intermediate showerhead assembly 170 that are configured to accept an external gas source such as gas supply 172 of
A first electrode 220 is embedded near the top surface 204 of the intermediate showerhead assembly 170. The first electrode 220 is embedded to protect the first electrode 220 from coming into direct contact with harmful gas chemistries in the process chamber. The first electrode 220 is embedded to form a mesh that allows for the first channels 210 to pass through the intermediate showerhead assembly 170 without interfering with the functioning of the first electrode 220 (see, for example,
A second electrode 222 is embedded near the bottom surface 206 of the intermediate showerhead assembly 170. The second electrode 222 is embedded to protect the second electrode 222 from coming into direct contact with harmful gas chemistries in the process chamber. The second electrode 222 is embedded to form a mesh that allows for the first channels 210 to pass through the intermediate showerhead assembly 170 without interfering with the functioning of the second electrode 222 (see, for example,
In some embodiments, the intermediate showerhead assembly 170 may be formed in an upper portion 230 and a lower portion 232. The upper portion 230 and the lower portion 232 are then bonded together such that the first channels 210 and the second channels 212 remain vacuum tight and gas leak tight to prevent gas intermixing between a gas in the first channels 210 and a gas in the second channels 212. By constructing each part separately and then combining, the second channels 212 can be formed such that the upper portion 230 provides a ceiling for the second channels 212. See
In some embodiments, due to the difficulties involved with forming ceramic bodies with small holes, electrodes, and cavities for the gas channels, the intermediate showerhead assembly 170 may be formed as a series of laminated or bonded ceramic layers. The advantage of constructing the intermediate showerhead assembly 170 as laminated layers (ceramic layers bonded together into a single piece) is that the size of the holes may be made extremely small in each layer and an electrode or mesh is easier to introduce and locate within the intermediate showerhead assembly 170. The first openings 240, the second openings 241, and/or the third openings 214 may have an opening with a size as small as approximately 0.015 (15 mils) or larger that are formed in the ceramic layers. The layout of the mesh/electrode is also easier to control and the location of the electrode layer may be easily adjusted within the stack of ceramic layers.
In
In some embodiments, the second set of layers 504 is formed starting at the bottom with a third type layer 512. The third type layer 512 has holes 518 for the third openings 214 and holes 520 for forming the lower portion of the first channels 210. A fourth layer type 514 is then bonded to the third type layer 512. The fourth layer type 514 has holes 518 for the third openings 214 and holes 520 for forming the lower portion of the first channels 210. Two more layers of the third type layer 512 are then bonded to the fourth layer type 514. Four more layers of a fifth type layer 516 are then bonded to the other layers completing the second set of layers to form the lower portion 232 of the intermediate showerhead assembly 170. The fifth layer type 516 has holes 518 for the third openings 214, holes 520 for forming the lower portion of the first channels 210, and channels to form the second channels 212. In some embodiments, the number of the third type layers 512 and the number of fifth type layers 516 may differ and the placement of the fourth layer type 514 in respect to the bottom of the second set of layers 504 may be different from the example illustrated in
While the foregoing is directed to embodiments of the present principles, other and further embodiments of the principles may be devised without departing from the basic scope thereof.
This application claims benefit of U.S. provisional patent application Ser. No. 62/880,218, filed Jul. 30, 2019 which is herein incorporated by reference in its entirety.
Number | Date | Country | |
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62880218 | Jul 2019 | US |