The present invention relates to a nitride semiconductor device and a method of manufacturing the same. Specifically, the present invention relates to a vertical nitride semiconductor device and a method of manufacturing the same.
Vertical nitride semiconductor devices are being developed. This type of vertical nitride semiconductor devices is provided with an n-type nitride semiconductor layer and a p-type nitride semiconductor layer stacked on the front surface of the n-type nitride semiconductor layer. A groove is formed in the p-type layer, so as to penetrate the p-type layer. The n-type layer extends within that groove. An n-channel type current path extending in the vertical direction is secured by the n-type layer that extends in the groove of the p-type layer. A vertical semiconductor device (a semiconductor device in which a pair of electrodes is distributedly provided on a front surface and a back surface of a semiconductor substrate) is thus realized.
A patent literature 1 discloses a vertical nitride semiconductor device 500 and a manufacturing method thereof.
Nitride compounds such as GaN and the like are chemically stable materials, and are therefore difficult to etch by wet etching. Therefore, a dry etching such as RIE (Reactive Ion Etching) or the like is used to etch GaN. In dry etching, the surface of GaN is exposed to plasma of an etching gas, and N desorbs out of the GaN surface that is exposed to the plasma. In the manufacturing method of the nitride semiconductor device 500 of the patent literature 1, the third nitride semiconductor layer 109 and the fourth nitride semiconductor layer 108 are formed on the front surfaces of the second nitride semiconductor layers 106a, 106b, then the third nitride semiconductor layer 109 and the fourth nitride semiconductor layer 108 are removed, by dry etching, at the areas where the pair of source electrodes 112a, 112b is to be formed. At this time, the side faces of the nitride semiconductor substrate 102, the side faces of the first nitride semiconductor layer 104, as well as part of the front surfaces and the side faces of the second nitride semiconductor layers 106a, 106b that are uncovered through etching, are exposed to the etching gas plasma, and etching damage is formed thereon as a result. Herein, N desorbs at a region 103 at which etching damage is formed in the nitride semiconductor substrate 102. Also, N desorbs at a region 105 at which etching damage is formed in the first nitride semiconductor layer 104, so that there increases the concentration of n-type impurity at the region 105 where etching damage is formed. Likewise, N desorbs at a region 107 at which etching damage is formed in the second nitride semiconductor layers 106a, 106b, and the region 107 at which etching damage is formed is imparted with n-type conductivity. As a result, an n-type current path forms from the drain electrode 118, through the nitride semiconductor substrate 102 and the regions 105, 107 at which etching damage is formed, up to the source electrodes 112a, 112b. Accordingly, upon application of voltage across the drain electrode 118 and the source electrodes 112; 112b, leakage current may occur between the drain electrode 118 and the source electrodes 112; 112b, via that current path.
The present invention was created in the light of the above problems. It is an object of the present invention to provide a vertical nitride semiconductor device in which occurrence of a leakage current can be suppressed, and to provide a method for manufacturing such a nitride semiconductor device.
The present invention relates to a nitride semiconductor device. The nitride semiconductor device of the present invention comprises a first nitride semiconductor layer, a second nitride semiconductor layer, a third nitride semiconductor layer, and a front surface electrode. The first nitride semiconductor layer is n-type. The second nitride semiconductor layer is formed on a part of a front surface of the first nitride semiconductor layer and p-type. The third nitride semiconductor layer is formed on the front surface of the first nitride semiconductor layer and a front surface of the second nitride semiconductor layer and n-type. The front surface electrode is formed on a part of the front surface of the second nitride semiconductor layer. An opening is formed in the third nitride semiconductor layer at a position isolated from a peripheral edge of the third nitride semiconductor layer, penetrating the third nitride semiconductor layer and reaching the front surface of the second nitride semiconductor layer. The front surface electrode is formed inside the opening. Furthermore, a back surface electrode is formed on a back surface of the nitride semiconductor device.
In the above nitride semiconductor device, an opening formed in the third nitride semiconductor layer is provided at a position isolated form a peripheral edge of the third nitride semiconductor layer. Upon formation of the opening in the third nitride semiconductor layer, therefore, an etching damage is formed, within the second nitride semiconductor layer, at a region corresponding to the position at which the opening is formed. However, no etching damage is formed at the region covered by the third nitride semiconductor layer. As a result, the etching damage formed in the second nitride semiconductor layer (the etching damage in contact with the front surface electrode) is surrounded by the region of the second nitride semiconductor layer at which no etching damage is formed. That is, the region at which the etching damage is formed is isolated, by the p-type second nitride semiconductor layer, from sites at which other etching damage is formed. As a result, current paths that extend from the back surface electrode, through regions at which the etching damage is formed, up to the front surface electrode, are rendered discontinuous, and the occurrence of the leakage current between the back surface electrode and the front surface electrode is suppressed.
In the nitride semiconductor device above mentioned, the nitride semiconductor device may further comprise a fourth nitride semiconductor layer of n-type in hetero junction with a front surface of third nitride semiconductor layer. In this case, a HEMT in which a channel is formed at a hetero junction surface between the third nitride semiconductor layer and the fourth nitride semiconductor layer can be realized.
In the nitride semiconductor device above mentioned, the front surface electrode may be isolated from the third nitride semiconductor layer formed between a termination portion of the nitride semiconductor device and the opening. In this case, the amount of material necessary for forming the front surface electrode during manufacture of the nitride semiconductor device can be reduced.
In the nitride semiconductor device above mentioned, the third nitride semiconductor layer may be formed to a termination portion of the nitride semiconductor device. In this case, the region at which the etching damage is formed during the manufacture of the nitride semiconductor device can be reduced. As a result, the occurrence of the leakage current between the back surface electrode and the front surface electrode can be effectively suppressed.
In the nitride semiconductor device above mentioned, a termination portion of the second nitride semiconductor layer may be exposed. The concentration of n-type impurity is higher and the leakage current likelier to occur in the first nitride semiconductor layer having the etching damage formed therein than in the second nitride semiconductor layer having the etching damage formed therein. In the above nitride semiconductor device, the side faces of the second nitride semiconductor layer on a termination portion side are not covered by the first nitride semiconductor layer, so that the region at which the etching damage is formed in the first nitride semiconductor layer can be reduced. As a result, the occurrence of the leakage current between the back surface electrode and the front surface electrode can be effectively suppressed.
In a nitride semiconductor device of another embodiment of the present invention, an etching damage is formed at a portion making contact with the front surface electrode within a region facing to the front surface of the second nitride semiconductor layer. The etching damage is surrounded by the second nitride semiconductor layer not having the etching damage. In this nitride semiconductor device, the etching damage directly below the region at which the opening is formed (the etching damage in contact with the front surface electrode) is discontinuous from the etching damage formed at other sites. As a result, the current paths that extend from the back surface electrode, through regions at which etching damage is formed, up to the front surface electrode, are rendered discontinuous, and the occurrence of the leakage current between the back surface electrode and the front surface electrode is suppressed. The etching damage can be detected by, for instance, TEM (Transmission Electron Microscope) after the manufacture of the nitride semiconductor device.
A method of manufacturing the nitride semiconductor device above mentioned comprises a third nitride semiconductor layer forming step, an opening forming step, and a front surface electrode forming step. The third nitride semiconductor layer forming step is a step for forming the third nitride semiconductor layer on the front surface of the second nitride semiconductor layer. The opening forming step is a step for forming the opening by etching a part of the third nitride semiconductor layer from a front surface of the third nitride semiconductor layer, penetrating the third nitride semiconductor layer and reaching the second nitride semiconductor layer. The front surface electrode forming step is a step for forming the front surface electrode on the front surface of the second nitride semiconductor layer exposed inside the opening after the opening forming step.
In the present method, during the formation of the opening in the opening forming step, the third nitride semiconductor layer remains on the second nitride semiconductor layer between the termination portion of the nitride semiconductor device and the opening. Therefore, no etching damage is formed at the region covered by the third nitride semiconductor layer, within the front surface of the second nitride semiconductor layer. As a result, the etching damage of the second nitride semiconductor layer formed directly below the opening is surrounded by the second nitride semiconductor layer at which no etching damage is formed. That is, the etching damage formed at the termination portion of the second nitride semiconductor layer is discontinuous from the etching damage of the second nitride semiconductor layer formed directly below the opening. The occurrence of the leakage current between the back surface electrode and the front surface electrode is suppressed accordingly in the nitride semiconductor device manufactured in accordance with the present method.
In the method above mentioned, the method may further comprise an ion doping step for doping ionized nitride, aluminum, carbon, or magnesium to a portion between a termination portion of the nitride semiconductor device and the opening before the opening forming step. Flow of the leakage current may occur even if the current paths that extend from the back surface electrode up to the front surface electrode, via the regions at which the etching damage is formed, are discontinuous. In the above method, the resistivity of the third nitride semiconductor layer is increased as a result of the ion implantation process. This allows suppressing flow of leakage current at a region, within the front surface of the second nitride semiconductor layer, that is covered by the third nitride semiconductor layer. As a result, the occurrence of the leakage current between the back surface electrode and the front surface electrode can be effectively suppressed.
The present invention succeeds in providing a vertical nitride semiconductor device in which occurrence of a leakage current can be suppressed, and in providing a method for manufacturing such a nitride semiconductor device.
Preferred aspects of below embodiments will be listed.
(Characterizing feature 1) The formula of a third nitride semiconductor layer is AlxGayIn1-X-YN (where 0≦X≦1, 0≦Y≦1, 0≦1-X-Y≦1). In this case, a hetero junction surface can be formed between the third nitride semiconductor layer and a fourth nitride semiconductor layer.
(Characterizing feature 2) A spacing of the region at which an etching damage is discontinuous is 1 μm or greater. In this case, flow of a leakage current at regions where the etching damage is discontinuous can be suppressed effectively.
Embodiments are explained next with reference to accompanying drawings.
A pair of openings 11a, 11b is formed at parts of the fourth nitride semiconductor layer 8 and at parts of the third nitride semiconductor layer 9, from the front surface of the fourth nitride semiconductor layer 8 and penetrating the third nitride semiconductor layer 9, reaching the front surfaces of the second nitride semiconductor layers 6a, 6b. A pair of n+ type source regions 14a, 14b is provided at respective parts of the front surfaces of the second nitride semiconductor layers 6a, 6b. The source regions 14a, 14b are formed over the extent of the third nitride semiconductor layer 9 and the fourth nitride semiconductor layer 8, at positions facing the openings 11, such that hetero junction surfaces run across the interior of the source regions 14a, 14b. A pair of source electrodes 12a, 12b is provided in the respective openings 11a, 11b. The pair of source electrodes 12a, 12b is in contact with parts of the front surfaces of the second nitride semiconductor layers 6a, 6b and in contact with the source regions 14a, 14b. The source electrodes 12a, 12b are conductive with the third nitride semiconductor layer 9 and the fourth nitride semiconductor layer 8 via the source regions 14a, 14b. The front surface of the fourth nitride semiconductor layer 8 is covered by a gate insulating film 10. A gate electrode (control electrode) 16 is provided on an area intervened by the pair of source electrodes 12a, 12b, on the front surface of the gate insulating film 10. The termination portion of the nitride semiconductor device 100 is in contact, for instance, with an element isolating section (not shown). For instance, an element isolating trench (not shown) is provided at the element isolating section, such that the nitride semiconductor device 100 is electrically isolated from other nitride semiconductor devices.
The operation of the nitride semiconductor device 100 is explained next. The nitride semiconductor device 100 is used with a voltage being applied across the source electrodes 12a, 12b and the drain electrode 18. If no positive voltage is applied to the gate electrode 16, no 2DEG forms at the hetero junction surface of the third nitride semiconductor layer 9 and the fourth nitride semiconductor layer 8. As a result, the nitride semiconductor device 100 is kept in an off state. When the positive voltage is applied to the gate electrode 16, a 2DEG forms at that hetero junction surface between the third nitride semiconductor layer 9 and the fourth nitride semiconductor layer 8, at a position between the pair of source regions 14a, 14b. As a result, the nitride semiconductor device 100 is turned on. The nitride semiconductor device 100 causes electrons to move by way of the 2DEG. Electron mobility is high, which enables high-speed operation.
Next, a method for manufacturing the nitride semiconductor device 100 is explained. First, the n− type first nitride semiconductor layer 4 is grown by MOCVD, using GaN as a material, on the front surface of the n+ type nitride semiconductor substrate 2 that has GaN as a material. The impurity concentration of the nitride semiconductor substrate 2 is 3×1018 cm -3. The introduced impurity is Si, and the thickness is 200 μm. The impurity concentration of the first nitride semiconductor layer 4 is 3×1016 cm-3, the introduced impurity is Si, and the grown thickness is 6 μm. Next, as shown in
Next, as shown in
Next, 100 nm of the n− type third nitride semiconductor layer 9 are formed, by MOCVD, on the front surfaces of the first nitride semiconductor layer 4 and the second nitride semiconductor layers 6a, 6b. The material and impurity concentration of the third nitride semiconductor layer 9 are identical to those of the first nitride semiconductor layer 4. Next, as shown in
Next the third silicon oxide film 24 covering the fourth nitride semiconductor layer 8 on an outside of the source regions 14a, 14b is removed. Next, as shown in
Next, the fourth silicon oxide film 26 is removed. Next, 50 nm of the gate insulating film 10 is formed by performing HTO (High-Temperature-Oxide)-CVD on the front surfaces of the fourth nitride semiconductor layer 8 and the source regions 14a, 14b. Next, as shown in
In the method for manufacturing the nitride semiconductor device 100, the etching damage 3 is formed at the termination portion of the nitride semiconductor substrate 2. In the part of the first nitride semiconductor layer 4 at the termination portion of the nitride semiconductor device 100, an etching damage 5 whose n-type impurity concentration is higher than that at other portions of the first nitride semiconductor layer 4 is formed. Etching damages 7a, 7b are formed at areas within the front surface of the second nitride semiconductor layers 6a, 6b that are not in contact with the third nitride semiconductor layer 9. The etching damages 7a, 7b are imparted with n-type conductivity. As a result, the etching damages 7b formed directly below the front surface electrodes 12a, 12b are surrounded by the second nitride semiconductor layers 6a, 6b in which no etching damage is formed. That is, the etching damage 5 and the etching damages 7b are discontinuous. In the nitride semiconductor device 100, as a result, the current paths between the drain electrode 18 and the source electrodes 12a, 12b are discontinuous. The occurrence of the leakage current between the drain electrode 18 and the source electrodes 12a, 12b is thus suppressed. The spacing of the region at which etching damage is discontinuous (spacing between the etching damage 7a and the etching damage 7b) is 1 μm or greater. As a result, this allows effectively suppressing the flow of the leakage current at regions where the etching damage is discontinuous.
In the process of forming the openings 61a, 61b (process corresponding to
Specific embodiment of the present invention is described above, but this merely illustrates some representative possibilities for utilizing the invention and does not restrict the claims thereof. The subject matter set forth in the claims includes variations and modifications of the specific examples set forth above. The technical elements disclosed in the specification or the drawings may be utilized separately or in all types of combinations, and are not limited to the combinations set forth in the claims at the time of filing of the application. Furthermore, the subject matter disclosed herein may be utilized to simultaneously achieve a plurality of objects or to only achieve one object.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2009/053834 | 3/2/2009 | WO | 00 | 9/2/2011 |