The present invention relates to apparatus and method for performing wet processing on a substrate. More particularly, this invention relates to a wet processing tool having site isolation, which does not contact the surface of the substrate to be processed.
Combinatorial processing enables rapid evaluation of semiconductor, solar, or energy processing operations. The systems supporting the combinatorial processing are flexible to accommodate the demands for running the different processes either in parallel, serial or some combination of the two.
Some exemplary processing operations include operations for adding (depositions) and removing layers (etch), defining features, preparing layers (e.g., cleans), doping, etc. Similar processing techniques apply to the manufacture of integrated circuit (IC) semiconductor devices, flat panel displays, optoelectronics devices, data storage devices, magneto electronic devices, magneto optic devices, packaged devices, and the like. As feature sizes continue to shrink, improvements, whether in materials, unit processes, or process sequences, are continually being sought for the deposition processes. However, semiconductor and solar companies conduct research and development (R&D) on full wafer processing through the use of split lots, as the conventional deposition systems are designed to support this processing scheme. This approach has resulted in ever escalating R&D costs and the inability to conduct extensive experimentation in a timely and cost effective manner. Combinatorial processing as applied to semiconductor, solar, or energy manufacturing operations enables multiple experiments to be performed at one time in a high throughput manner. Equipment for performing the combinatorial processing and characterization must support the efficiency offered through the combinatorial processing operations.
Various embodiments of the invention are disclosed in the following detailed description and the accompanying drawings:
A detailed description of one or more embodiments is provided below along with accompanying figures. The detailed description is provided in connection with such embodiments, but is not limited to any particular example. The scope is limited only by the claims and numerous alternatives, modifications, and equivalents are encompassed. Numerous specific details are set forth in the following description in order to provide a thorough understanding. These details are provided for the purpose of example and the described techniques may be practiced according to the claims without some or all of these specific details. For the purpose of clarity, technical material that is known in the technical fields related to the embodiments has not been described in detail to avoid unnecessarily obscuring the description.
Generally, the present invention provides a substrate processing tool that allows portions of the upper surface of the substrate to be isolated from liquids on the other portions of the upper surface of the substrate, without contacting the upper surface of the substrate. The isolation is accomplished using, for example, a combination of fluid barriers as seals and vacuum removal.
At each location to be isolated, an isolation unit (or reactor) is placed in close proximity with the upper surface of the substrate. The reactor has an outlet (or array of outlets) that is sized and shaped similar to a periphery of the location on the substrate to be isolated. Barrier fluid (e.g., a gas or liquid) is driven through (either out of or in to) the outlet, which causes a fluid barrier to be formed around the respective location. The gas barrier prevents processing fluid (e.g., a gas or liquid) on the substrate from flowing between the respective location and the remainder of the substrate. The barrier may be used to contain processing fluid within the particular location or prevent processing fluid on the remainder of the substrate from flowing onto the particular location.
The outlet may be an annular trench that surrounds a central receptacle of the reactor. A second, annular trench/outlet may also be provided, which surrounds the first trench/outlet. The second trench may be provided with a gas flow opposite the first trench. For example, if gas is driven out of the first trench, a vacuum may be applied to the second trench, and vice versa. Positive pressure may also be applied to the central receptacle of the reactor when the reactor is being used to prevent liquid from flowing onto the respective location of the substrate. Additionally, the flow of gas may generate Bernoulli forces (suction) that may be used to lift the substrate, without contacting the substrate.
According to one aspect of the present invention, a substrate processing tool is provided. The substrate processing tool includes a housing defining a chamber. A substrate support is coupled to the housing and configured to support a substrate within the chamber. The substrate has an upper surface with a first portion and a second portion surrounding the first portion. An isolation unit including a body (or reactor) is coupled to the housing and positioned within the chamber above and spaced apart from the first portion of the upper surface of the substrate. The body includes at least one outlet on a lower surface thereof. At least one fluid pump is in fluid communication with the at least one outlet and is configured to drive fluid through the at least one outlet to form a barrier around the first portion of the upper surface of the substrate.
The wet processing tool 12 includes a housing 18 enclosing (or defining) a processing chamber 20, a substrate support 22, and a wet processing assembly 24. The substrate support 22 is positioned within the processing chamber 20 and is configured to hold a substrate 26.
Although not shown in detail, the substrate support 22 may be configured to secure the substrate using, for example, a vacuum chuck, electrostatic chuck, or other known mechanism. Further, although not shown, the substrate support 22 may be coupled to the housing 18 via an actuator (e.g., a pneumatic cylinder) configured to vertically move the substrate support 22, such as for positioning the substrate 26.
Referring specifically to
The substrate 26 may be a conventional, round substrate (or wafer) having a diameter of, for example, 200 millimeter (mm) or 300 mm. In other embodiments, the substrate 26 may have other shapes, such as a square or rectangular. It should be understood that the substrate 26 may be a blanket substrate (i.e., having a substantial uniform surface), a coupon (e.g., partial wafer), or even a patterned substrate having predefined regions (e.g., regions 30). The regions 30 may have any convenient shape, e.g., circular, rectangular, elliptical, wedge-shaped, etc. In the semiconductor field a region may be, for example, a test structure, single die, multiple die, portion of a die, other defined portion of substrate, or a undefined area of a, e.g., blanket substrate which is defined through the processing.
Referring again to both
As shown in
Further, the isolation units 36 may be configured in a variety of ways to provide common mechanisms used in wet processing, such as stiffing and/or mechanical agitation, brush cleans, polishing, and electroplating.
Referring again to
The processing fluid supply system 14 includes one or more supplies of various processing fluids, both liquids and gases, as well as temperature control units to regulate the temperatures of the various fluids. Additionally, the processing supply system 14 includes one or more fluid pumps for delivering the fluids to the isolation units 36 and/or providing vacuum supplies to the isolation units 36, as well as a series of valves interconnecting the various supplies and the isolation units 36. The control system 16 includes, for example, a processor and memory (i.e., a computing system) in operable communication with the processing fluid supply system 14 and the isolation units 36 and is configured to control the operation thereof as described below.
Referring now to
Although not specifically illustrated, the central receptacle 48 is in fluid communication with the processing fluid supply 14 (e.g., via fluid lines 44 shown in
In operation, after the wet processing assembly 24 (
Referring again to
In order to create a barrier around the region 30, a fluid (hereinafter referred to as a “barrier fluid”), such as argon or nitrogen gas, is delivered to the annular plenum 52 in the body 42 of each of the isolation units 36 by the processing fluid supply 14. The barrier fluid flows from the annular plenum 52 through the annular trench outlet 50 and onto the substrate 26, where it flows both inwards towards the center of the respective region 30 on the upper surface of the substrate 26 and outwards, away from the region 30. This gas flow creates an annular fluid barrier around the respective region 30 on the substrate that prevents processing fluid (e.g., a liquid) on the substrate 26 from passing between the region 30 and the interstitial portion of the substrate 26.
Still referring to
It should be understood that although the barrier fluid may cover the region 30 on the substrate 26 before the processing fluid is delivered into the central receptacle 48, this portion of the barrier may have a relatively low pressure such that the processing fluid “pushes” it back, substantially off the region 30. In contrast, the portion(s) of the barrier directly under the annular trench outlet 50 may have a relatively high pressure, preventing the processing fluid from passing between the region 30 and the interstitial portion of the substrate 26. It should also be understood that in other embodiments, as described below, the flow of the barrier fluid may be reversed, such as for processing the interstitial portion of the substrate 26.
After a predetermined amount of time (i.e., depending on the particular wet process being performed), the liquid may be removed from the central receptacle 48 by the processing fluid supply 14 (i.e., a vacuum supply). As such, the present invention allows for wet processes to be performed on only particular portions of the substrate 26, without any of the components of the tool 10 contacting the upper surface of the substrate 26. Thus, the likelihood that any contaminates will be left on the substrate 26 are reduced.
In operation, according to one embodiment, gas (i.e., barrier fluid) is driven from the second annular trench outlet 56 by the processing fluid supply 14 (
Processing fluid, such a processing liquid, is then delivered into the central receptacle 48, as described above, to perform a wet process on the respective region 30 of the substrate 26. The gas driven from the second annular trench outlet 56 combined with the gas pulled through the first annular trench outlet 50 forms a gas or fluid barrier similar to that described above.
However, the embodiment shown in
As shown in
During operation, in one embodiment, positive pressure is applied to the central receptacle 48 (e.g., barrier gas is delivered to the central receptacle 48) while the annular plenum 52 is “vented” (i.e., connected to a vent at atmospheric pressure). As a result, barrier fluid (e.g., a gas) is driven from the central outlet 60 towards the substrate 26. Because of the angle 64 at which the outlets 60 are arranged, the gas extends outwards towards the annular trench outlet 50 in a “swirling” motion and is directed upwards into the annular trench outlet 50, as is a small portion of gas and/or air from outside of the isolation unit 36. Thus, a fluid barrier is formed around the respective isolation region 30 (
Referring again to
Further, the embodiment shown in
Additionally, similar to the embodiment shown in
During operation, barrier fluid is driven from the outlets 60, a vacuum is applied to the second annular plenum 58, and the first annular plenum 52 is vented (as described above). As a result, gas flows down from the outlets 60 onto the isolation region 30 of the substrate in a “swirling” motion and outwards towards the first annular trench outlet 50. A portion of the barrier fluid is directed upwards through the first annular trench outlet 50, while some of the barrier fluid is pulled into the second annular trench outlet 56. This flow of gas forms a gas barrier around the respective isolation region 30 similar to that described above.
Referring again to
The embodiments described herein provide details for a multi-region processing system and associated processing heads that enable processing a substrate in a combinatorial fashion. Exemplary details of combinatorial processing techniques are provided in U.S. Pat. No. 7,544,574, filed on Feb. 10, 2006, and claiming priority from Oct. 11, 2005, U.S. Pat. No. 7,824,935, filed on Jul. 2, 2008, U.S. Pat. No. 7,871,928, filed on May 4, 2009, and claiming priority from Oct. 15, 2005, U.S. Pat. No. 7,902,063, filed on Feb. 10, 2006, and claiming priority from Oct. 15, 2005, and U.S. Pat. No. 7,947,531 filed on Aug. 28, 2009, all of which are assigned to Intermolecular, Inc. (San Jose, Calif.) and incorporated by reference herein. Exemplary details of combinatorial processing techniques are further provided in U.S. patent application Ser. No. 11/352,077, filed on Feb. 10, 2006, and claiming priority from Oct. 15, 2005, U.S. patent application Ser. No. 11/419,174, filed on May 18, 2006, and claiming priority from Oct. 15, 2005, U.S. patent application Ser. No. 11/674,132, filed on Feb. 12, 2007, and claiming priority from Oct. 15, 2005, and U.S. patent application Ser. No. 11/674,137, filed on Feb. 12, 2007, and claiming priority from Oct. 15, 2005, all of which are also assigned to Intermolecular, Inc. (San Jose, Calif.) and are incorporated by reference herein.
As such, according to one aspect of the present invention, the substrate processing tool 10 also is provided with a variation generating system (or subsystem) configured to intentionally vary (or create differences between) the wet processes performed on two or more of the regions 30 and/or the interstitial portion of the substrate 26. The variation generating system may include, for example, the processing fluid supply system 14, the transducers (in embodiments having transducers), and/or the control system 16.
It should be understood that the size, shape, and number of the isolation units 36 and/or the corresponding regions 30 on the substrate 26 may be different in other embodiments. For example, the substrate 26 may include four isolation regions, each substantially covering a “quadrant” of the upper surface, and the isolation units 36 (and/or the bodies 42 thereof) may be appropriately sized and shaped to match.
Thus, in one embodiment, a substrate processing tool is provided. The substrate processing tool includes a housing defining a chamber. A substrate support is coupled to the housing and configured to support a substrate within the chamber. The substrate has an upper surface with a first portion and a second portion surrounding the first portion. An isolation unit including a body is coupled to the housing and positioned within the chamber above and spaced apart from the first portion of the upper surface of the substrate. The body includes at least one outlet on a lower surface thereof. At least one fluid pump is in fluid communication with the at least one outlet and is configured to drive fluid through the at least one outlet to form a barrier around the first portion of the upper surface of the substrate.
In another embodiment, a method for processing a substrate is provided. An isolation unit comprising a body is positioned above and spaced apart from an isolation portion of the upper surface of a substrate. The upper surface of the substrate also includes interstitial portion surrounding the isolation portion. The body includes at least one outlet on a lower surface thereof. Fluid is caused to be driven through the at least one outlet such that a fluid barrier is formed around the isolation portion of the upper surface of the substrate.
In a further embodiment, a substrate processing tool is provided. The substrate processing tool includes a housing defining a chamber. A substrate support is coupled to the housing and configured to support a substrate within the chamber. The substrate has an upper surface with a plurality of isolation portions and an interstitial portion surrounding each of the isolation portions. A plurality of isolation units comprising a body coupled to the housing are positioned within the chamber, each being above a respective one of the isolation portions of the upper surface of the substrate. The body of each of the plurality of isolation units includes an annular outlet on a lower surface thereof. At least one gas pump is in fluid communication with the annular outlet of the body of each of the plurality of isolation units and is configured to drive gas through the annular outlet of the body of each of the plurality of isolation units to form a gas barrier around each of the isolation portions of the upper surface of the substrate.
Although the foregoing examples have been described in some detail for purposes of clarity of understanding, the invention is not limited to the details provided. There are many alternative ways of implementing the invention. The disclosed examples are illustrative and not restrictive.