OPTICAL CHARACTERISTICS MEASURING DEVICE AND OPTICAL CHARACTERISTICS MEASURING METHOD

Abstract

An optical characteristics measuring device includes a first light source capable of irradiating a sample with light and a second light source capable of irradiating the sample with microwaves. A measuring device measures microwave power of the reflection of the microwaves from the sample. A calculation unit calculates a parameter relating to the electrical conductivity of the sample using the microwave power of the reflected waves measured by the measuring device. A control unit controls the intensity of the light of the first light source so that the parameter becomes approximately a predetermined value. The calculation unit specifies first to n-th intensities of the light at which the parameter becomes approximately the predetermined value for each of the first to n-th wavelengths of the light and obtains relationships between the first to n-th wavelengths and the first to n-th intensities corresponding to the respective first to n-th wavelengths.

Description

CROSS-REFERENCE TO RELATED APPLICATION

This application is based upon and claims the benefit of priority from Japanese Patent Application No. 2018-158564, filed on Aug. 27, 2018, the entire contents of which are incorporated herein by reference.

FIELD

Embodiments described herein relate generally to an optical characteristics measuring device and an optical characteristics measuring method.

BACKGROUND

The optical characteristics of materials such as semiconductors are closely related to the electrical characteristics and physical characteristics of the materials, and are utilized in various fields such as advanced material development, device development, mass production line, and the like. However, the film thickness of a material film in a sample sharply decreases in miniaturized semiconductor devices such as semiconductor memories. For this reason, it is difficult for a measuring instrument such as a spectroscopic ellipsometer, which measures optical characteristics by using reflected light, to accurately measure optical characteristics of the material film.

As a method for measuring the optical characteristics of a material regardless of the film thickness, constant photocurrent method (CPM) is available. However, in order to measure the current flowing in the material film, it is necessary to provide a plurality of electrodes on the material film for the CPM. Therefore, the size of the sample is increased, and the shape of the sample is also limited. In addition, a step of forming electrodes on a sample is required.

Examples of related art include Toshihiro Iki et al. “Construction of Constant Photocurrent Experimental Method for High-Sensitivity Optical Absorption Coefficient Measurement”, Journal of Faculty of Engineering, Miyazaki University No. 38; and Marthin Schofthaler et. al. “Sensitivity and transient response of microwave reflection measurements”, pp. 3162-3173, J. Appl. Phys. 77(7), 1 Apr. 1995.

DESCRIPTION OF THE DRAWINGS

FIG. 1 is a block diagram showing a configuration example of an optical characteristics measuring device according to a first embodiment.

FIG. 2 is a graph showing a parameter ΔP/P.

FIG. 3 is an example of a graph displayed on a display unit.

FIG. 4 is a flowchart showing an example of an optical characteristics measuring method according to the first embodiment.

DETAILED DESCRIPTION

Embodiments herein provide an optical characteristics measuring device and an optical characteristics measuring method capable of easily measuring the optical characteristics of a sample regardless of the film thickness and shape of the sample.

In general, according to one embodiment, an optical characteristics measuring device includes a first light source that is capable of irradiating a sample with light. A second light source is capable of irradiating the sample with microwaves. A measuring device measures microwave power of the reflected waves of the microwaves reflected by the sample (i.e., measures reflection information relating to the microwave energy). A calculation unit calculates a parameter relating to the electrical conductivity of the sample by using the microwave power of the reflected waves measured by the measuring device. A control unit controls the intensity of the light of the first light source so that a parameter becomes approximately a predetermined value. The calculation unit identifies first to n-th intensities of the light at which the parameter becomes approximately the predetermined value for each of the first to n-th wavelengths (n is an integer of 2 or more) of the light and obtains relationships between the first to n-th wavelengths and the first to n-th intensities corresponding to the respective first to n-th wavelengths.

Hereinafter, embodiments of the present disclosure will be described with reference to drawings. The present embodiment does not limit the present disclosure. The drawings are schematic or conceptual, and the ratio of each part is not necessarily the same as the actual one. In the specification and drawings, elements similar to those described above with reference to the drawings are given the same reference numerals, and the detailed description thereof will be omitted as appropriate.

First Embodiment

FIG. 1 is a block diagram showing a configuration example of an optical characteristics measuring device according to a first embodiment. An optical characteristics measuring device 1 includes a stage 5, a light source 10, a monochromator 20, a microwave light source 30, a microwave measuring device 40 (detector), a calculation unit 50 (calculator), a control unit 60 (controller), a storage unit 70 (storage), and a display unit 80 (display). In some embodiments, the calculation unit 50 and control unit 60 may be integrated into a computer. In some embodiments, the measuring device 40, calculation unit 50 and control unit 60 may be integrated into a computer.

The stage 5 is configured so that a sample S to be measured can be placed on it. The light source 10 as a first light source generates light L to be radiated to the sample S. The light L from the light source 10 is light including various wavelengths, for example, white light with wavelengths in the range of 190 nm to 2500 nm. The light source 10 may change the intensity (output) of the light L under the control of the control unit 60.

The monochromator 20 as a wavelength adjusting unit allows light L from the light source 10 of a specific wavelength (any one of Lλ1 to Lλn) to pass and irradiate the sample S. The light beams Lλ1 to Lλn are light beams of different wavelengths or wavelength bands. n is an integer of 2 or more. The monochromator 20 may adjust the light to be transmitted to the sample S in the range of Lλ1 to Lλn under the control of the control unit 60. For example, when passing light Lλk (1≤k≤n), the monochromator 20 blocks light other than the light Lλk.

The light source 10 may have a plurality of single-wavelength light sources that generate light of different wavelengths. For example, the light source 10 may be a plurality of laser light sources that generate light of different wavelengths. In this case, the monochromator 20 may be provided or may be omitted. The control unit 60 may select and drive one of the single-wavelength light sources from among the light sources 10.

The microwave light source 30 as a second light source irradiates the sample S with microwaves μi. The microwaves μi used in the present embodiment have a wavelength corresponding to a frequency range of 0.3 GHz to 300 GHz, for example. The microwaves μi are reflected by the sample S and enters the microwave measuring device 40 as reflected waves μr. The microwave measuring device 40 as a measuring device measures the microwave power of the reflected waves μr. The microwave power of the reflected waves μr is the microwave power reflected by the free electrons of the sample S.

The calculation unit 50 calculates a parameter relating to electrical conductivity of the sample S based on the microwave power of the reflected waves μr measured by the microwave measuring device 40. This parameter is expressed by a ratio (ΔP/P) of P and ΔP (ΔP=P_L−P), where the microwave power of the reflected waves μr when no light is radiated is set as P and the microwave power of the reflected waves μr is set as P_L when light (any one of Lλ1 to Lλn) is radiated. That is, the parameter is the ratio (ΔP/P) of the microwave power P of the reflected waves μr when no light is radiated, to the increment ΔP of the microwave power of the reflected waves μr when light (any one of Lλ1 to Lλn) is radiated. The microwave power P is a constant, and the microwave power P_L is a value that increases by radiating light (any one of Lλ1 to Lλn). Hereinafter, ΔP/P is also called “parameter”.

The parameter ΔP/P is expressed by Equation 1 using the change in reflectance R of the microwaves and the change in electrical conductivity σ₀ of the sample S.

$\begin{array}{cc}\frac{\Delta P\left(\Delta {\sigma }_0\right)}{P}\cong \frac{\partial R\left({\sigma }_0\right)}{\partial {\sigma }_0}\Delta {\sigma }_0& \left[\mathrm{Equation}1\right]\end{array}$

Here, Δσ₀ is the amount of change of the electrical conductivity (conductance) of the sample S. δR(σ₀)/δσ₀ represents change in reflectance with respect to the conductance. In Equation 1, ΔP is expressed as a function P(Δσ₀) of the amount of change Δσ₀ of the conductance.

According to Equation 1, the parameter ΔP/P on the left side is a function of the change amount Δσ₀ of the electrical conductivity (conductance) of the sample S. Therefore, the parameter ΔP/P does not indicate the electrical conductivity itself of the sample S, but may be used as an index related to the electrical conductivity of the sample S. That is, although the calculation unit 50 may not calculate the electrical conductivity of the sample S from the output of the microwave measuring device 40, the parameter ΔP/P may be calculated, and therefore change in the electrical conductivity of the sample S can be recognized from change in the parameter ΔP/P. For example, when the parameter ΔP/P decreases, it indicates that the change of the electrical conductivity of the sample S is small. Conversely, when the parameter ΔP/P rises, it indicates that the change of the electrical conductivity of the sample S is large. Furthermore, when the parameter ΔP/P is constant, it indicates that there is no change in the electrical conductivity of the sample S. In this manner, the parameter ΔP/P may be used as an index related to the change amount of the electrical conductivity of the sample S. The calculation unit 50 may indirectly recognize a change in electrical conductivity of the sample S by using the parameter ΔP/P.

The control unit 60 controls the intensity of the light L of the light source 10 so that the parameter ΔP/P calculated in response to any one of the light beams Lλ1 to Lλn becomes approximately a predetermined value. For example, FIG. 2 is a graph showing the parameter ΔP/P. The vertical axis of this graph is the parameter ΔP/P, and the horizontal axis is time. Either one of the light beams Lλ1 to Lλn is intermittently radiated in a pulsed manner, and the microwaves μi are also emitted immediately after each pulse. The control unit 60 controls the intensity of the light L of the light source 10 so that a peak PK and/or a curve CV of the parameter ΔP/P shown in FIG. 2 substantially matches a predetermined value.

The parameter ΔP/P in FIG. 2 will be described. For example, at t0, when any one of the pulses of the light beams Lλ1 to Lλn is radiated, the microwave power P_L increases and an increased amount ΔP of the microwave power P_L with respect to the microwave power P also increases. The microwave power P varies depending on the material, the film thickness, and the like of the sample S, but is a constant when the sample S is the same. Therefore, the parameter ΔP/P abruptly increases in response to irradiation by any one of the light beams Lλ1 to Lλn at t0. This means that the electrical conductivity of the sample S has increased in response to irradiation by any one of the light beams Lλ1 to Lλn. The light beams Lλ1 to Lλn are emitted in a pulsed manner at t0 and thereafter are not emitted until the next pulse. Therefore, after t0, the parameter ΔP/P gradually decreases. This means that the electrical conductivity of the sample S gradually returns to a normal value. As described above, the change in the parameter ΔP/P relates to the change in the electrical conductivity of the sample S. Therefore, it is possible to grasp the change in the electrical conductivity of the sample S in response to irradiation by any one of the different wavelengths of light beams Lλ1 to Lλn by referring to the change in the parameter ΔP/P in response to irradiation by the same. As described later in detail, assuming that an intensity is constant, the calculated parameter ΔP/P may vary depending on the wavelength of the radiate light beam due to an optical characteristic (absorption ratio) of the sample S. Conversely, by controlling the intensity of the light L of the light source 10 for respective wavelengths so that the parameter ΔP/P becomes approximately the predetermined value, the electrical conductivity of the sample S can be also controlled to a certain value. The calculated parameter ΔP/P may have a peak PK at t0 and a subsequent curve CV as shown in FIG. 2. For example, when substantially the same height of the peak PK and substantially the same shape of the curve CV are obtained at different measurement environments, it may be possible to assume that the electrical conductivity of the sample S is substantially equal among these measurement environments.

The calculation unit 50 obtains the respective intensities of the light beams Lλ1 to Lλn when the electrical conductivity of the sample S is made substantially constant by using the relationship between the parameter ΔP/P and the electrical conductivity of the sample S. The respective intensities of the light beams Lλ1 to Lλn are used as the optical characteristic of the sample S for analysis and understanding of physical characteristics, confirmation of the result of simulation, and the like.

The storage unit 70 stores wavelengths and intensities of the light beams Lλ1 to Lλn, the parameter ΔP/P calculated by the calculation unit 50, and the like. In addition, the storage unit stores the intensities (also referred to as adjusted intensity) of the light beams Lλ1 to Lλn when the electrical conductivity of the sample S is substantially constant in association with the wavelengths of the light beams Lλ1 to Lλn, respectively. The association is not particularly limited, but the same name may be included in a file name, a folder name, and the like in the data.

The display unit 80 displays respective adjusted intensities for the wavelengths of the light beams Lλ1 to Lλn in a graph. The adjusted intensities may be converted into absorption rates of the light beams Lλ1 to Lλn in the sample S. The absorption rate is the reciprocal of the depth from the irradiated surface where the light radiated on the sample is absorbed as the light proceeds to the interior of the material and of which intensity is 1/e (e is Napier's constant). The absorption rate of the light beams Lλ1 to Lλn when the electrical conductivity of the sample S is substantially constant is hereinafter also referred to as the adjusted absorption rate. Therefore, high adjusted intensity of light beams Lλ1 to Lλn means that the light absorption rate of the sample S is relatively low. This is because it is necessary to increase the adjusted intensities of the light beams Lλ1 to Lλn in order to obtain the sample S having a predetermined electrical conductivity. On the other hand, low adjusted intensity of the light beams Lλ1 to Lλn means that the light absorption rate of the sample S is relatively high. This is because if the light absorption rate of the sample S is high, even if the intensities of the light beams Lλ1 to Lλn are low, it is possible to obtain the sample S having a predetermined electrical conductivity. Therefore, the display unit 80 may display the adjusted absorption rate corresponding to the adjusted intensity as a graph instead of the adjusted intensity.

FIG. 3 is an example of a graph displayed on the display unit 80. In this graph, the vertical axis shows the adjusted absorption rate of the sample S. The horizontal axis indicates the energy of the light beams Lλ1 to Lλn. Energy of the light beams Lλ1 to Lλn may be expressed as h·c/λ. Here, h is Planck's constant, c is the speed of light, and λ is the wavelength of lights beams Lλ1 to Lλn. Since the energy of the light beams Lλ1 to Lλn is proportional to the reciprocal of these wavelengths, the energy decreases as the wavelengths of the light beams Lλ1 to Lλn become longer.

In this way, using the microwaves μi, the optical characteristics measuring device 1 according to the present embodiment may calculate the parameter ΔP/P related to the electrical conductivity of the sample S, and measure optical characteristics (for example, adjusted intensity, adjusted absorption rate) of the sample S by using the parameter ΔP/P. The microwaves μi may be used to irradiate the sample S and this may be measured without providing an electrode on the sample S. Further, the microwaves μi may be used to irradiate the sample S and this may be measured regardless of the film thickness and shape of the sample S. Therefore, in the present embodiment, it is possible to measure the optical characteristics of the sample S in a non-contact manner without being limited by the size and shape of the sample S. Therefore, in the present embodiment, for example, the optical characteristics of a thin film formed on a semiconductor substrate having a large area may be mapped.

Micro photoconductivity decay (PCD) is a method of analyzing the electrical conductivity (conductance, free carrier concentration) itself of a sample by using reflected waves of microwaves. However, at present, it is difficult to directly obtain the electrical conductivity of a sample with micro PCD. In contrast, in the present embodiment, the fact that that the change in the electrical conductivity of the sample S may be grasped indirectly by the change of the parameter ΔP/P instead of obtaining the electrical conductivity itself of the sample S is utilized for PCM, and the intensities of the light beams Lλ1 to Lλn are controlled referring to the parameter ΔP/P so that the electrical conductivity of the sample S is substantially constant. Therefore, the present embodiment is a different technology from the micro PCD in which the electrical conductivity itself of the sample is to be analyzed.

Next, the optical characteristics measuring method according to the present embodiment will be described.

FIG. 4 is a flowchart showing an example of the optical characteristics measuring method according to the first embodiment.

First, the sample S is placed on the stage (S10). The microwave power P of the reflected waves μr when the sample S is not irradiated with light is measured beforehand.

Next, the sample S is irradiated with light having a certain wavelength and a certain intensity as reference light, and is irradiated with the microwaves μi. As a result, the calculation unit 50 calculates the parameter ΔP/P of the reference light (S20). The parameter ΔP/P of the reference light is stored in the storage unit 70. The parameter ΔP/P of the reference light may be displayed on the display unit 80 as a graph as shown in FIG. 2. Hereinafter, the parameter ΔP/P of the reference light is referred to as reference parameter ΔP/Pref.

Next, the sample S is irradiated with the light Lλ1 as a first wavelength (S30). Simultaneously with or immediately after the irradiation with the pulse of the light Lλ1, the sample S is irradiated with the microwaves μi (S40). The microwaves μi are emitted to the irradiation position of the light Lλ1, and a part thereof is measured by the microwave measuring device 40 as the reflected waves μr (S50).

Next, the calculation unit 50 calculates the parameter ΔP/P using the microwave power of the reflected waves μr measured by the microwave measuring device 40 (S60).

Next, the calculation unit 50 compares the parameter ΔP/P obtained in step S50 with the reference parameter ΔP/Pref (S70). When the parameter ΔP/P is different from the reference parameter ΔP/Pref (NO in S70), the control unit 60 changes the intensity of the light Lλ1 (S80) and again executes steps S30 to S60 (S80). For example, when the parameter ΔP/P is smaller than the reference parameter ΔP/Pref, the control unit 60 increases the intensity of the light Lλ1. When the parameter ΔP/P is larger than the reference parameter ΔP/Pref, the control unit 60 lowers the intensity of the light Lλ1.

On the other hand, when the parameter ΔP/P substantially matches the reference parameter ΔP/Pref (YES in S70), the calculation unit 50 stores the intensity (first adjusted intensity) of the light Lλ1 at that time in the storage unit 70 in association with the wavelength (first wavelength) of the light Lλ1 (S90). The fact that the parameter ΔP/P closely coincides with the reference parameter ΔP/Pref means that the peak PK and/or the curve CV in FIG. 2 are substantially the same, achieving not only perfect matching, but also allowing some degree of misalignment. The allowable values may be set by a manufacturer or a user.

Next, the control unit 60 controls the monochromator 20 to change the wavelength of the light (NO in S100; S110) and executes steps S30 to S90. For example, the monochromator 20 changes from the light Lλ1 to the light Lλ2. Thereafter, steps S30 to S90 are executed. As a result, the adjusted intensity is also obtained for the light Lλ2. The calculation unit 50 stores the adjusted intensity (second adjusted intensity) of the light Lλ2 in association with the wavelength (second wavelength) of the light Lλ2 in the storage unit 70.

Likewise, steps S30 to S90 are executed for the light beams Lλ3 to Lλn (NO in S100). As a result, the calculation unit 50 may obtain an adjusted intensity of each of the light beams Lλ3 to Lλn. The adjusted intensities (third to n-th adjusted intensities) of the light beams Lλ3 to Lλn are also stored in association with the wavelengths of the light beams Lλ3 to Lλn (third to n-th wavelengths) in the storage unit 70.

When an adjusted intensity is obtained for all the light beams Lλ1 to Lλn (YES in S100), the calculation unit 50 displays the first to n-th wavelengths of the light beams Lλ1 to Lλn and the first to n-th adjusted intensities corresponding to the first to n-th wavelengths on the display unit 80 (S120). At this time, as shown in FIG. 3, the wavelength may be converted into energy. The adjusted intensity may be converted to an adjusted absorption rate. In this case, the first to n-th adjusted intensities are respectively converted into the first to n-th adjusted absorption rates.

The order of radiation of the light beams Lλ1 to Lλn is random. Also, the number of times of radiation of a certain light Lλk (1≤k≤n) (the number of loops in steps S30 to S80) is also not particularly limited. There is no particular limitation as long as the value of n is also 2 or more.

As described above, according to the present embodiment, for each of the light beams Lλ1 to Lλn having the first to n-th wavelengths, the first to n-th adjusted intensities at which the parameter ΔP/P indicated by the microwave power of the reflected waves μr of the microwaves μi becomes substantially the predetermined value (i.e., assumes the predetermined value or a value approximate to the predetermined value) are identified. Then, the relationships between the first to n-th wavelengths and the first to n-th adjusted intensities or the first to n-th adjusted absorption rates corresponding to the first to n-th wavelengths are obtained. The sample S may be irradiated with microwaves (microwave energy) μi and measured without providing an electrode on the sample S and regardless of the film thickness and shape of the sample S. Therefore, in the present embodiment, it is possible to measure the optical characteristics of the sample S in a non-contact manner without being limited by the size and shape of the sample S. For example, in the optical characteristics measuring device 1 according to the present embodiment, it is possible to measure the wavelength dispersion of the optical absorption rate even if it is a very thin material film whose product of the light absorption rate and the film thickness is less than 1.

While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the inventions. Indeed, the novel embodiments described herein may be embodied in a variety of other forms; furthermore, various omissions, substitutions and changes in the form of the embodiments described herein may be made without departing from the spirit of the inventions. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the inventions.

Claims

1. An optical characteristics measuring device, comprising: a first light source that irradiates a sample with light;a second light source that irradiates the sample with microwave energy;a detector configured to measure a microwave power of the microwave energy reflected from the sample from the second light source;a calculator configured to calculate a parameter relating to electrical conductivity of the sample by using the microwave power of the reflected waves measured by the detector; anda controller configured to control an intensity of the light of the first light source so that the parameter becomes approximately a predetermined value,wherein the calculator is configured to specify first to n-th intensities of the light at which the parameter becomes approximately the predetermined value for each of the first to n-th wavelengths, where n is an integer of 2 or more, of the light and thereby obtain relationships between the first to n-th wavelengths and the first to n-th intensities corresponding to each of the first to n-th wavelengths.

2. The optical characteristics measuring device according to claim 1, wherein the calculator is configured to calculate, as the parameter, the ratio between the microwave power of the reflected waves when the light is not radiated and an increased amount of the microwave power of the reflected waves resulting from radiating the light.

3. The optical characteristics measuring device according to claim 2, wherein the calculator is configured to obtain first to n-th absorption rates of the light of the sample with respect to the first to n-th wavelengths from the relationships between the first to n-th wavelengths and the first to n-th intensities.

4. The optical characteristics measuring device according to claim 3, further comprising: a storage configured to store information relating to the first to n-th wavelengths and the first to n-th intensities in association with each other.

5. The optical characteristics measuring device according to claim 1, wherein the light has a wavelength in a range between 190 nm and 2500 nm.

6. The optical characteristics measuring device according to claim 5, further comprising a monochromator configured to allow light of a specific wavelength to pass to irradiate the sample with the light.

7. The optical characteristics measuring device according to claim 1, wherein the microwave energy has a frequency range between 0.3 GHz and 300 GHz.

8. An optical characteristics measuring method using an optical characteristics measuring device including a first light source that irradiates a sample with light, a second light source that irradiates the sample with microwave energy, a detector that measures microwave power of a microwave reflection from the sample, a computer that calculates using the microwave power of the reflected waves and controls the light of the first light source, the method comprising: irradiating the sample with light of a first wavelength;irradiating the sample with microwave energy;calculating a parameter relating to electrical conductivity of the sample using the microwave power of the reflected waves measured by the measuring device;adjusting, by the computer, an intensity of the light that causes the parameter to become approximately a predetermined value;identifying a first intensity of the light at which the parameter becomes approximately the predetermined value; andobtaining a relationship between the first wavelength and the first intensity corresponding to the first wavelength.

9. The optical characteristics measuring method according to claim 8, further comprising: changing the wavelength of the light to be radiated to the sample to second to n-th wavelengths, wherein being an integer of 2 or more, while identifying the second to n-th intensities of the light at which the parameter becomes approximately the predetermined value, and thereby obtaining relationships between the second to n-th wavelengths and the second to n-th intensities corresponding to the second to n-th wavelengths.

10. The optical characteristics measuring method according to claim 9, further comprising: calculating the parameter of the sample from a ratio between the microwave power of the reflected waves when the light is not radiated and an increased amount of microwave power of the reflected waves resulting from radiating the light.

11. The optical characteristics measuring method according to claim 10, further comprising: obtaining a first absorption rate of the light of the sample with respect to the first wavelength, from the relationship between the first wavelength and the first intensity.

12. The optical characteristics measuring method according to claim 11, further comprising: obtaining second to n-th absorption rates of the light of the sample with respect to the second to n-th wavelengths, from the relationships between the second to n-th wavelengths and the second to n-th intensities.

13. A system for measuring optical characteristics of a sample, the system comprising: a first light source emitting a first electromagnetic wave to a sample;a second light source emitting a second electromagnetic wave to the sample;a detector configured to receive reflection information relating to a reflection of the second electromagnetic wave;a computer configured to calculate a parameter based on the reflection information, andto vary an intensity of the first electromagnetic wave of the first light source to vary the parameter calculated by the computer such that the parameter assumes a predetermined value.

14. The system of claim 13, wherein the computer is further configured to specify first to n-th intensities of the first electromagnetic wave, wherein the first to n-th intensities cause the parameter for each corresponding intensity becoming approximately the predetermined value for each of the first to n-th wavelengths of the first electromagnetic wave.

15. The system of claim 13, wherein the first electromagnetic wave has a wavelength in a range between 190 nm and 2500 nm.

16. The system of claim 15, further comprising a monochromator configured to allow an electromagnetic wave having a specific wavelength to pass and irradiate the sample with electromagnetic wave.

17. The system of claim 13, wherein the second electromagnetic wave has a frequency range between 0.3 GHz and 300 GHz.

18. The system of claim 14, further comprising a storage configured to store wavelengths and intensities of the first electromagnetic wave and the corresponding parameter calculated by the computer.

19. The system of claim 14, further comprising a display configured to display respective adjusted intensities for the wavelengths of the first electromagnetic wave.