a) to 1(d) are schematic views for illustrating a method of alignment between a mold and a substrate by means of a reference substrate in Embodiment 1 of the present invention, wherein
a) to 2(c) are schematic views for illustrating a constitution of the reference substrate in Embodiment 1.
a) to 5(c) are schematic views for illustrating a method of alignment between a mold and is a substrate by means of a reference substrate in Embodiment 2 of the present invention, wherein
a) to 6(d) are schematic views for illustrating a signal processing method in Embodiment 3 of the present invention, wherein
a) to 7(f) are schematic views for illustrating alignment marks in Embodiment 3, wherein
a) and 8(b) are schematic views for illustrating a measurement optical system in Embodiment 4 of the present invention, wherein
a) and 9(b) are schematic views for illustrating a measurement optical system in Embodiment 4, wherein
a) to 10(d) are schematic views for illustrating marks used in Embodiment 4, wherein
a) and 11(b) are flow charts for illustrating a signal processing method in Embodiment 4, wherein
By the above described constitutions, the objects of the present invention can be accomplished. This is based on findings of constitutes for obtaining information about a difference in observation image between the respective image pickup devices (or image pickup portions) as a result of study by the present inventors in order to realize novel pattern transfer. More specifically, by employing such a constitution that the mold and the substrate are positionally aligned with each other by utilizing the reference substrate during nanoimprint, alignment between the mold and the substrate can be effected more inexpensively. The use of the constitutions of the present invention is not limited to the case where the imprinting pattern is transferred onto the substrate itself but may also be applicable to the case where the pattern transfer is effected via the resin material interposed between the mold and the substrate.
In an embodiment of the present invention, in order to realize a processing apparatus through the above described pattern transfer, it is possible to employ the following constitutions.
More specifically, it is possible to employ a constitution in which an optical system for observing a first object position at a processing surface of the mold and a second object position at a portion closer, than the processing surface, to a member to be processed is used and alignment between the mold and the member to be processed is effected by using a means for recognizing a relative relationship of (or a difference in) observation position between a first image pickup device for observing the first object position and a second image pickup device for observing the second object position. In this case, it is possible to employ a constitution in which the reference substrate is used as the means for recognizing the difference in observation position. Further, it is possible to employ a constitution in which the alignment between the mold and the member to be processed is effected by comparing data obtained in advance by the first and second image pickup devices with data (currently) obtained by the first and second image pickup devices. Further, it is also possible to employ a constitution in which the alignment between the mold and the member to be processed is effected by making comparison in each of several areas in image pickup ranges of the first and second image pickup devices.
Further, in order to realize a processing method by the above described pattern transfer, it is possible to employ the following constitutions.
In the processing method, an optical system for observing a first object position at a processing surface of the mold and a second object position at a portion closer to the member to be processed with respect to the processing surface of the mold is used. The processing method can be constituted so that alignment between the mold and the member to be processed is effected by using a means for recognizing a relative relationship of (or a difference in) observation position between a first image pickup device for observing the first object position and a second image pickup device for observing the second object position. In this case, it is possible to employ a constitution in which the reference substrate is used as the means for recognizing the difference in observation position. Further, it is possible to employ a constitution in which the processing method includes a step of recognizing the difference in observation position by the reference substrate and a step of effecting the alignment between the member to be processed and the mold at the second object position. Further, it is possible to employ a constitution in which the alignment between the mold and the member to be processed is effected by comparing data obtained in advance by the first and second image pickup devices with data (currently) obtained by the first and second image pickup devices. Further, it is possible to employ a constitution in which the processing method includes a step of selecting a plurality of areas from an image obtained by the first image pickup device, a step of effecting first signal processing in each of the plurality of areas, and a step of effecting second signal processing on the basis of a result of the first signal processing. Further, it is possible to employ a constitution in which the data obtained by the first and second image pickup devices by using grating having different pitches as marks for the alignment described above are overlaid or superposed and subjected to signal processing to generate moire fringes and the generated moire fringes are utilized.
In the above described embodiments of the present invention, a relative positional relationship between the respective image pickup ranges at two (first and second) object positions is measured or determined with the reference substrate by using the optical system for observing coaxially the two object positions of the mold and the substrate. By utilizing a result of measurement, it is possible to effect the alignment between the mold and the substrate. As a result, the alignment can be effected in a separation state between the mold and the substrate, so that it is possible to effect the alignment between the mold and the substrate at high speed without damage to the mold and the substrate. Further, by disposing the marks for the mold and the substrate in different areas as seen in a normal direction, interference between the marks for the mold and the substrate does not occur. As a result, the signal processing becomes easy.
Further, the pattern transfer apparatus according to the present invention can also be constituted as described below. Herein, the apparatus means a pattern transfer apparatus for transferring the imprinting pattern formed on the mold onto the substrate or the resin material interposed between the substrate and the mold. The pattern transfer apparatus includes a first image pickup portion for obtaining an image at a first depth of focus and a second image pickup portion for obtaining an image at a second depth of focus. A first alignment mark provided to the mold and a second alignment mold provided to the substrate are disposed within the first depth of focus and observed through the first image pickup portion to obtain a first image. Further, a third mark provided to the mold or the substrate is disposed within the second depth of focus and observed through the second image pickup portion to obtain a second image. The pattern transfer apparatus is constituted so as to obtain information about a difference in observation range between the first and second image pickup portions by using the first and second images. The third alignment mark may be identical to or different from the first alignment mark or the second alignment mark.
Further, it is also possible to effect the alignment between the mark and the substrate (onto which the imprinting pattern is to be transferred) in an in-plane direction in a state in which the alignment mark for the mold is disposed within the first depth of focus and the alignment mark for the substrate is disposed within the second depth of focus. It is further possible to effect the alignment between the mold and the substrate in the in-plane direction in a state in which the alignment mark for the mold is disposed within the second depth of focus and the alignment mark for the substrate is disposed within the first depth of focus.
Hereinbelow, the present invention will be described more specifically based on Embodiments with reference to the drawings.
In Embodiment 1, an alignment method of the mold and the substrate in the present invention will be described.
a) to 1(d) are schematic views for illustrating the alignment method, in this embodiment, of the mold and the substrate in which the reference substrate is used.
Referring to
In the alignment method of this embodiment, an optical system for observing the first object position 101 at a processing surface of the mold 103 and the second object position 102 located in the substrate 112 side with respect to the processing surface is used. By the optical system, the mold mark 104 and the substrate mark 113 are observable at the same time.
The first object position 101 and the second object position 102 are spaced, e.g., several nanometers or more apart, so that the mold and the substrate are in a noncontact positional relationship even when the substrate is moved at high speed in an in-plane direction parallel to the processing surface.
In each of
Generally, it is not easy to dispose coaxially the image pickup device for observing these two (first and second) object positions with an accuracy on the order of nanometers, so that a difference in center position between the first observation range 106 and the second observation range 107 is caused to occur. Further, a difference in center position between each observation range and an associated image pickup range is also caused to occur. In addition, there is a difference in center position between the first observation range and the mold mark. Objects to be finally aligned with each other are the mold and the substrate, so that the center of the substrate mark is aligned with the center of the mold mark in this embodiment. For simplicity of explanation, it is assumed that the first observation range and the first image pickup range coincide with each other and the second observation range and the second image pickup range coincide with each other. Even when this assumption is made, generality of explanation is not lost. Further, for simplicity of explanation, it is assumed that the center positions of the first observation range and the second observation range are deviated only in y-direction. A direction from the second object position toward the first object position is taken as a positive direction of z-direction.
The alignment method of this embodiment will be briefly described. In the alignment method, the reference substrate 110 is used for the alignment between the mold and the substrate.
A procedure of the alignment method is as follows.
(1) The mold and the reference substrate are aligned at the first object position by using an in-plane moving mechanism (
(2) The reference substrate is moved in a negative direction of z-direction and an image thereof is constituted and obtained at the second object position (
(3) At the second object position, the observed image and the substrate are aligned by using the in-plane moving mechanism (
(4) Only by moving the substrate in the positive direction of z-direction, the substrate is aligned with the mold at the first object position (
In such a step-and repeat method that a predetermined pattern is repetitively transferred at many points on the same substrate, alignment may be effected only at a first point on the substrate. Thereafter, it is possible to effect repetitive transfer with an accuracy of the in-plane moving mechanism (on the order of subnanometers).
Next, a detailed description will be made.
In order to align the substrate mark with a desired position at the first object position, it is necessary to determine a position, at which the substrate mark should be disposed at the second object position, corresponding to the desired position at the first object position. This operation is, e.g., performed only during replacement of the mold.
Next, as shown in
Next, with reference to
As shown in
Next, as shown in
In the case where the mold and the substrate are deviated from each other and located outside a tolerable range, it is also possible to effect further alignment between the mold and the substrate. This operation may be required, e.g., in the case where the positions of the mold and the substrate are deviated from each other due to a stress, exerted thereon, caused by the contact between the mold and the substrate via the resin material. In the case where the positional deviation between the mold and the substrate occurs, when an amount of the deviation is between the mold and the substrate is identical irrespective of the position of the substrate, the following processing is performed. More specifically, a difference (referred to as “E1-2”) between the designated position (F1-1) of the substrate holding portion at that time and a position of the substrate holding portion at the time of completion of the alignment (referred to as “S1-2”) is stored. In this case, the alignment has already been effected at the second object position as shown in
The above described alignment is effected on the entire surface of the substrate on the basis of information about the positional deviation between the mold and the substrate at a certain point of the substrate. However, it is also possible to effect the alignment between the mold and the substrate on the basis of information about positional deviation, at the entire surface of the substrate, obtained in advance of the alignment.
Next, a constitution of the reference substrate used in this embodiment will be described with reference to
As the reference substrate, it is also possible to use the substrate itself onto which the imprinting pattern is to be transferred. However, in this case, there is apprehension that distortion of the substrate during the process and a difference among individual substrates can occur. For this reason, it is desirable that a stable reference substrate is used.
A reference substrate 201 shown in
A reference substrate 204 shown in
A reference substrate 207 shown in
Next, an optical system for measurement used in this embodiment will be described with reference to
In the optical system in this embodiment, light emitted from a light source 301 passes through an illumination optical system 302, a first beam splitter 303, a first imaging optical system 304 to reach a mold 309 and a substrate 312. Light reflected by the mold 309 and the substrate 312 passes through the first imaging optical system 304, the first beam splitter 303, a second imaging optical system 306, and a second beam splitter 305 to form an image on a first image pickup device 307 and a second image pickup device 308. An image of the first object position 313 is formed on the first image pickup device 307 and an image of the second object position 314 is formed on the first image pickup device 308. In this embodiment, a mold mark 310 is formed as an image on the first image pickup device 307 and a second mark 311 is formed as an image on the second image pickup device 308.
Next, a processing apparatus, used in this embodiment, constituting a pattern transfer apparatus for transferring an imprinting pattern formed on a mold onto a substrate or a resin material interposed between the substrate and the mold will be described with reference to
Referring to
The mold holding portion 403 effects chucking of a mold 411 according to a vacuum chucking method or the like. A substrate 412 is movable to a desired position by the in-plane moving mechanism 406. Further, by the substrate hoisting and lowering mechanism 405, adjustment of a height of the substrate 412 and application of pressure can be effected. The in-plane moving mechanism 406 and the substrate hoisting and lowering mechanism 405 are subjected to measurement of distance by an interferometer or the like with a control accuracy on the order of subnanometers. Control of positional movement of the substrate, pressure application, exposure and the like is made by an imprint control mechanism 410.
In Embodiment 2, a method of alignment between the mold and the substrate different from the alignment method of Embodiment 1 will be described.
In this embodiment, explanation of the alignment method common to
a) to 5(c) include schematic views for illustrating a mold of alignment between a mold 502 and a substrate 513.
In this embodiment, at both surfaces of a reference substrate 505, a first reference substrate mark 506 and a second reference substrate mark 504 are disposed, respectively. Further, an optical thickness of the reference substrate 505 is made equal to a distance between a first object position 501 and a second object position 503. Based on these features, it is possible to determine a position, to which a substrate mark should be moved at a second object position in order to align the substrate mark with a desired position of a mold mark at a first object position, at one time as described below.
a) includes schematic views showing the case where the first reference substrate mark 506 of the reference substrate 505 is located at a first object position 501. Further, the second reference substrate mark 504 is located at a second object position 503. The first reference substrate mark 506 is disposed in a first image pickup range 510 provided in a first observation range 509. Further, the second reference substrate mark 504 is disposed in a second image pickup range 512 provided in a second observation range 511. A reference numeral 508 represents a difference between center positions in the first and second image pickup ranges 510 and 512.
First, the reference substrate 505 is disposed on a substrate holding portion (not shown) and on the basis of a mold mark 507, alignment (positional adjustment) of the first reference substrate mark 506 is effected at the first object position 501 by an in-plane moving mechanism. More specifically, e.g., the alignment is effected so that the center of the first reference substrate mark 507 and the center of the mold mark 506 coincide with each other. At this time, at the second object position 503, the second reference substrate mark 504 is located and an image thereof is stored.
Thereafter, the reference substrate 505 is removed from the substrate holding portion.
Next, a method of alignment of the substrate will be described. This method is basically identical to that in Embodiment 1.
More specifically, as shown in
c) shows a state in which the substrate holding portion holding the substrate is raised, so that the first and second substrate marks 514 and 515 are disposed at the first object position 501. In this state, alignment between the mold and the substrate is ordinarily completed. Thereafter, imprint is effected by setting a designated position on the presumption that there is the difference (deviation) (E2-1) with respect to subsequent transfer onto the same substrate.
In the case where the mold and the substrate is are deviated from each other and located outside a tolerable range, similarly as in Embodiment 1, the second substrate mark 515 is positionally aligned on the basis of the mold mark 507 at the first object position 501 shown in
In Embodiment 3, a method of alignment between the mold and the substrate different in image processing method from the alignment method of Embodiment 1 will be described.
In this embodiment, explanation of the alignment method common to
a) to 6(c) include schematic views for illustrating an image processing method in this embodiment.
First, the case where a reference substrate 613 is observed at a first object position 601 will be described.
Next, a method of alignment of the substrate will be described.
More specifically, as shown in
Next, the case where the substrate 618 is observed at the first object position 601 will be described.
d) shows a state in which the substrate 618 is raised in the positive direction of z-direction by the hoisting and lowering mechanism to dispose the substrate mark 619 at the first object position 601. In this state, the alignment between the mold 602 and the substrate 618 is ordinarily completed, so that a resultant positional deviation is expected to be a level within a tolerable range. A difference (referred to as “E3-1”) between the designated position (F3-1) of the substrate holding portion at this time and a designated position of the substrate holding portion after completion of the alignment (referred to as “S3-1”) is stored. Thereafter, imprint is effected by setting a designated position on the presumption that there is the difference (deviation) (E3-1) with respect to subsequent transfer onto the same substrate.
In the case where the mold and the substrate are deviated from each other and located outside a tolerable range, similarly as in Embodiment 1, the alignment between the mold 602 and the substrate 618 is finally effected at the first object position 601. In this case, the alignment at the second object position 603 shown in
As described above, an effect of using different areas in the image pickup range of the image pickup device is that reflectances of the mold and the substrate are different from each other and thus the images of the mold and the substrate can be independently subjected to signal processing to facilitate an increase in accuracy of alignment. Further, it is not necessary to consider an influence of mutual interference since the mold and the substrate are not vertically overlaid on each other, so that a degree of freedom of the mark can be increased.
Next, a method of effecting high-accuracy alignment by generating moire fringes in the mark through image processing will be described.
a) to 7(f) are schematic views for illustrating alignment marks used when alignment is effected by image-processing moire fringes in Embodiment 3.
a) shows a first mark including a bar pattern 701 with a pitch P1 and a bar pattern 702 with a pitch P2.
Incidentally, in a state in which the alignment between the mark and the substrate is not completed, the left-hand and right-hand moire images are out of phase with each other. The moire fringes have a period is equal to a pitch PM represented by the following equation:
As described above, a positional deviation between the mold and the substrate is enlarged without using optical magnification.
Then, the moire fringes are arranged to constitute a first mark 709 for XYθ measurement as shown in
The above described apparatuses and methods according to the present invention can be utilized in manufacturing technologies and the like of semiconductors, optical devices such as photonic crystal and the like, and biochips such as μ-TAS and the like.
In Embodiment 4, another embodiment of the optical system described in Embodiment 1 will be described. Particularly, this embodiment is suitable for the contrast adjustment described in Embodiment 3. This is because when images of marks of a mold and a substrate different in reflectance are picked up in the same field of view, a sufficient contrast cannot be ensured to disturb accurate measurement in some cases.
Accordingly, it is important that the marks are disposed at positions so that the marks do not optically adversely affect each other to be independently adjusted in contrast for each of the marks when the marks are viewed from a vertical direction.
The reason for the vertical direction is that the mark or the substrate is moved in z-direction and thus a change in position of the marks in the image pickup device due to the movement of the mark or the substrate is required to be prevented. For this reason, when the marks are obliquely observed, a signal processing method is required to correspond to the positional change of the marks.
The mold mark has a high transmittance, so that the mold mark is liable to have a contrast lower than the substrate mark.
Generally, measurement accuracy is improved with an increase in contrast, so that such an adjustment that contrasts on the mold and the substrate are maximum values, respectively, is required.
Next, a measurement optical system in this embodiment will be described with reference to
a) shows a constitution in which a first optical device 801 and a second optical device 802 are disposed in front of a first image pickup device 307 and a second image pickup device 308, respectively. Each of the optical devices is constituted by a color filter, an interference filter, an ND (neutral-density) filter, a polarizer, and a combination thereof. The first and second optical devices are suitably selected depending on the reflectances. It is also possible to use color filters of a color CCD (charge coupled device) as they are.
b) shows a constitution in which light reaching respective positions of the image pickup devices is adjusted by first and second optical devices 803 and 804. In this case, the first optical device 803 and the second optical system 804 which are different in characteristic depending on position are disposed in image pickup ranges of the first image pickup device 307 and the second image pickup device 308, respectively, so as to adjust a contrast depending on the position. In this constitution, alignment can be effected at a first object position and a second object position. Further, it is possible to easily effect alignment by directly using a mold mark and a substrate mark even in the case where reflectances of the mold and the substrate are different from each other when the substrate mark is located at the first object position.
a) shows a constitution of an optical system in which a light amount control mechanism 901 for adjusting an amount of light in correspondence with each of marks for the mark and the substrate is used in order to effect contrast adjustment.
In a constitution shown in
In the optical systems shown in
The image pickup operation may be effected by changing the light amount as described above or changing exposure times or gains of the image pickup devices depending on characteristics of the mold and the substrate.
a) and 10(b) show embodiments of marks used for alignment between a mold and a substrate in an alignment method of a box-in-box type. In these figures, the image pickup device has a first area A 610 in which a mold mark 104 is provided to the mold and a second area B 611 in which a substrate mark 113 is provided to the substrate. Since the optical system of this embodiment is used, reflectances at the positions of the mold mark 104 and the substrate mark 113 are optimized.
c) and 10(d) show a constitution of a grating-type mold mark 701 in a first area A 610 of the mold and a constitution of a grating-type substrate mark 702 in a second area B 611 of the substrate, respectively. These constitutions are particularly suitable for the case where alignment on the order of nanometers is effected. Since the optical system of this embodiment (Embodiment 4) is used, reflectances of the mold and the substrate are optimized.
Next, a signal processing method in this embodiment will be described with reference to
a) is a flow chart for illustrating the case where magnification correction is not effected.
Referring to
In the case where the area of the first area A is different from that of the second area B, it is necessary to effect such a processing that data at a peripheral portion are extended as they are so as to cause the first and second areas A and B to have the same area.
Next in Step S-2, signal processing A is effected in the first area A and signal processing B is effected in the second area B. Each of the signal processings A and B is ordinary filtering using a low-pass filter, a high-pass filter, a band-pass filter, an FFT-filter, a smoothing filter, a differential filter, etc. Further, gain adjustment is effected so as to optimize a contrast depending on the reflectances of the mold and the substrate and the like factor.
Next, in step S-3, computation is performed. The computation may be performed by effecting addition of images, multiplication of images, calculation of a difference between images, or calculation of images using other functions.
Next, in Step S-4, signal processing C is performed by using a filter similar to those used in step S-2.
Finally, in step S-5, detection of a position is made.
b) is a flow chart showing the case where the step S-2 in the case shown in
In this embodiment, the case of using the two (first and second) areas is described but it is also possible to use three or more areas.
Next, an example of signal processing in the case where the mold mark shown in
First, in the step S-1, images of the area A and the area B are obtained. In the step S-2, magnification correction and filtering using the smoothing filter in each of the area A and the area B are effected to reduce noise. Further, contrasts of the areas A and B are adjusted. In the step S-3, the images of the areas A and B after the signal processing are added. This state is similar to that in the case of optical overlaying (superposition). In the step S-4, further signal processing using the smoothing filter or the like is effected. In the step S-5, the position is detected.
Incidentally, as the method of signal processing, other than the above described method, it is also possible to directly determine centers of gravity of the marks in the areas A and B in the step S-2. Further, in the step S-3, a difference between the centers of gravity is calculated. In the step S-4, the signal processing is not particularly effected. In the step S-5, the difference is converted into a distance between the mold and the substrate. A condition of completion of the alignment is such that the difference is zero. The method described above may also be applicable to this embodiment.
Next, an example of signal processing in the case where the mold mark having a periodic structure shown in
First, in the step S-1, images of the areas A and B are obtained. In the step S-2, magnification correction and conversion of two-dimensional data into one-dimensional data by effecting averaging processing are made. Further, by using the FFT filter, components of basic frequency of the periodic structures are obtained. In the step S-3, the resultant values are multiplied mathematically. This multiplication is represented by the following equation.
In the above equation, δ represents a positional deviation and the second term of the right side represents a component of moire fringes.
In the step S-4, by the FFT, it is possible to simply divide the right side into the first term representing a low-frequency component and the second term representing a high-frequency component. As a result, as the component of moire fringes, the following term can be extracted.
In the step S-5, the following phase component is extracted.
From the phase component, it is possible to detect δ associated with the position.
In the alignment (positional adjustment), a condition of completing the alignment is taken as a time at which the phase component is zero in many cases.
Incidentally, as the grating-type marks, it is possible to use the grating-type marks 703 and 704 shown in
Incidentally, an essential difference between the overlaying (superposition) of patterns such as a grating pattern or the like in the signal processing of this embodiment and optical overlaying (superposition) will be described below.
The former (signal processing) overlaying is an ideal state but the latter (optical) overlaying is adversely affected by multiple reflection or the like. Particularly, in the case where the mold and the substrate have different reflectances, the optical overlaying is adversely affected by the multiple reflection. Accordingly, depending on a detection algorithm, an error occurs in measurement in some cases. For this reason, as in this embodiment, the signal processing overlaying is important in order to obtain ideal signals to result in a less occurrence of error by using the marks with grating patterns which do not coincide with each other when the patterns are observed in the vertical direction.
Incidentally, in order to increase the contrast, it is preferable from the viewpoint of improvement in contrast that a transmission wavelength range of a filter provided to the light source or the image pickup device is changed depending on a gap between the mold and the substrate.
For example, in the case of an imprint method in which a pattern formed on a processing surface of the mold is transferred by curing a resin material disposed on the surface of the substrate, the change in wavelength range is made in the following manner.
When an alignment mark provided to the mold is observed through the image pickup device, a wavelength of light entering the image pickup device is controlled depending on the gap between the mold and the substrate or a thickness of a member constituting the alignment mark. More specifically, in the imprint method, the resin material onto which the pattern is to be transferred is interposed between the mold and the substrate. In the case where refractive indices of the resin material and the mold are close to each other, a phenomenon which is called index matching such that the alignment mark including projections and recesses formed on the mold disappears is caused to occur. In an actual observation, it is difficult to perform the observation of the alignment mark for the mold.
In order to obviate the index matching by which the mold mark disappears, it is effective to use a mark formed of a high-refractive index material.
However, in the imprint method, the gap between the mold and the substrate can be several tens of nanometers to several hundreds of nanometers. In such a case, the contrast of the mark can be lowered by an interference effect of light, thus being required to be further improved.
The reason why the use of the high-refractive index material for the mold for imprint (particularly at the alignment mark portion) is preferable will be described.
Assuming that the mold mark is constituted by SiO2 having refractive index of 1.45, a resin materials having a refractive index of 1.5, and SiN having a refractive index of 2.0, a reflectance R at an interface between materials having refractive indices n1 and n2 is represented by the following equation.
Accordingly, a reflectance R at an interface between SiO2 and the resin material is:
R−2.9×10−4.
This value is very small. When the mark is observed, the mark is less observable due to the above described index matching.
On the other hand, a reflectance R at an interface between SiN and the resin material is:
R=2.0×10−2.
This value is larger than that at the interface between SiO2 and the resin material by about two digits. Here, a reflectance R at an interface between SiO2 and air is:
R=3.4×10−2.
As described above, it is found that the reflectance is largely improved by using SiN as the material for the mold mark.
Incidentally, in the imprint method, the gap between the mold and the substrate and the thickness of the film of the high-refractive index material can be several tens of nanometers to several hundreds of nanometers. In such a case, the light interference effect is remarkably obtained.
Calculation of values is made by using a model for Fresnel reflection. As a reference, a three-layer structure including three layers (SiO2 layer/resin material layer/Si layer) prepared by omitting the SiN layer from the above described four-layer structure is employed.
A resultant contrast when the mark is observed is better with a larger difference between the four-layer structure including the SiN layer and the three-layer (reference) structure lacking the SiN s layer.
For example, at the wavelength of 600 nm, a reflected light intensity is 0.27 when the SiN layer has a thickness of 50 nm and is 0.11 when the SiN layer has a thickness of 150 nm. The reference structure provides a reflected light intensity of 0.11 at the wavelengths of 400-800 nm, so that a contrast at the wavelength of 600 nm is increased in the order of the SiN layer thicknesses of 150 nm, 20 nm, and 50 nm. At the wavelength of 800 nm, a contrast is increased in the order of 20 nm, 50 nm, and 150 nm (SiN layer thickness). Further, at the wavelength of 400 nm, a contrast is highest at the SIN layer thickness of 20 nm.
When the reflected light intensities at the wavelength of 600 nm are compared, the intensity values are 0.273 for the gap (resin material layer thickness) of 100 nm, 0.099 for the gap of 50 nm, and 0.033 for the gap of 200 nm. Since the intensity of the reference structure is 0.11 at the wavelengths of 400-800 nm (
As described above, the reflectance is changed depending on the wavelength in the case where the SiN is layer thickness or the gap (resin material layer thickness) is several tens of nanometers to several hundreds of nanometers (a fraction of the wavelength of light for observation to several times the wavelength of light for observation). For this reason, it is desirable that the wavelength of light entering the image pickup device is controlled depending on the SiN layer thickness or the gap.
Incidentally, when spectra of light entering the image pickup device are in a range of 400-800 nm, a contrast is determined by a difference between an average of the spectra in this range and the reference(intensity:0.11).
Next, an alignment method will be described.
In the alignment, accuracy of alignment is improved with an increase in contrast of the mold mark. An observation wavelength of the mark in the case where alignment is effected while bringing the mold and the substrate near to each other will be described. The SiN layer has a thickness of 50 nm in this case. When the gap is 200 nm, the mark is observed at the wavelength of 400-450 nm. When the gap is 100 nm in a further approximated state, the mark is observed at the wavelength of 500-550 nm. When the gap is 50 nm in a still further approximated state, the mark is observed at the wavelength of 400-450 nm. Even when the gap is another value, the mark is observed at an optimum wavelength.
A method of selecting the wavelength may be a method using a color filter or a method using a plurality of laser beams. The color filter may be disposed on the illumination optical system side or the image pickup device side.
For example, in the above described embodiments and Embodiments 1-4, in the case where optical information is inputted into the image pickup device through a wavelength filter, it is possible to always obtain information about an image having a high contrast by changing a transmission wavelength range of the wavelength filter depending on the gap. Further, in an imprint apparatus for transferring a pattern formed on a processing surface of a mold by curing a resin material in a substrate surface, it is preferable that the apparatus includes an image pickup device for observing the mold and a means for controlling a wavelength of light entering the image pickup device depending on a gap between the mold and the substrate. The means for controlling the wavelength is constituted by the color filter or a plurality of light sources (capable of outputting light fluxes at a plurality of wavelengths).
As described hereinabove, according to the present invention, the mold or the substrate is less liable to be broken during the imprint and it is possible to effect the alignment at high speed. Further, the illumination optical system can be simplified, so that it is possible to reduce an apparatus cost.
While the invention has been described with reference to the structures disclosed herein, it is not confined to the details set forth and this application is intended to cover such modifications or changes as may come within the purpose of the improvements or the scope of the following claims.
This application claims priority from Japanese Patent Applications Nos. 114093/2006 filed Apr. 18, 2006, 305310/2006 filed Nov. 10, 2006, and 036598/2007 filed Feb. 16, 2007, which are hereby incorporated by reference.
Number | Date | Country | Kind |
---|---|---|---|
2006-114093 | Apr 2006 | JP | national |
2006-305310 | Nov 2006 | JP | national |
2007-036598 | Feb 2007 | JP | national |