1. Field of the Invention
The present invention relates generally to photolithographic methods and mask devices that are utilized for multiple exposures of photoresist in the field of a feature, such as the placement of an identification number on a device such as a slider for a magnetic head.
2. Description of the Prior Art
When devices are created on a wafer substrate, such as a slider including a magnetic head or other microelectronic devices, an identification number is typically created on each such device. In the past, the identification number has been written on the back side of the slider using a laser etching technique. However, flash (ablated particulates) on the back side of the wafer due to the laser serialization of the sliders can result in the redeposition on the front side of the ablated material from the site of the characters formed on the back of the slider. This etching created flash can be deleterious to hard disk drive performance because it is a source of contamination that can lead to device failures, such as HDI's (head disk interactions), e.g. head crashes.
Moreover, as the dimensions of sliders move to the “femto” format, back side serialization of the slider necessitates the flipping of sliders over for inspection of slider identifiers in the serialization pattern. Since the small size of these sliders raises problems with regard to handling, it is desirable to serialize the front side of the wafer to avoid the handling that accompanies flipping these small format sliders over for inspection of slider identifiers.
More recent prior art slider serialization methods are based on photolithographic techniques that use mask sets to print row and column identifiers of sliders, as well as wafer identification numbers on individual sliders. However, these other methods, such as are described in U.S. Pat. No. 6,897,010 and 6,924,090, require significant processing time and are therefore costly. The methods and mask sets described in this invention provide a novel approach to front side serialization that brings substantial cost savings. Moreover, the invention may have many fundamental and novel applications outside of the particular embodiments recited with regard to wafer serialization when the invention is applied to the art of photolithography more generally.
The present invention includes a photolithographic mask set for creating a plurality of characters on a device, such as a series of identification characters formed on a magnetic head. The mask set includes a plurality of photolithographic masks, wherein each mask includes at least one mask character area and at least one mask character field area that surrounds each mask character area. Each mask character field area of each mask has a radiation energy density transmission factor Tf that is greater than zero, and each mask character area has a radiation energy density transmission factor Tc that is greater than zero, such that each mask character field area and each mask character area of each mask are not opaque.
A photolithographic method for forming a plurality of characters on a device utilizes the mask set. Initially a photoresist layer is fabricated upon the device in a location for forming the characters. The photoresist has a radiation energy density value Et wherein radiation energy density exposure below Et will not affect the photoresist during development, and a radiation energy density value Eo wherein radiation energy density exposure above Eo will affect the photoresist during development. The photoresist is exposed to radiation energy density through the set of masks using the masks sequentially such that the photoresist is exposed to radiation energy density through a mask character field area during each mask exposure, and the photoresist is also exposed to radiation through a mask character area during each mask exposure.
The exposure of the photoresist through a mask creates at least one character field area of the photoresist, and each character field area of the photoresist includes at least one character area of the photoresist in which a separate identification character is formed. Each character field area of the photoresist is exposed to radiation energy density through the mask set such that the total radiation energy density exposure in the character field area of the photoresist is less than Et. Significantly, each character area of the photoresist is exposed to greater radiation energy density than the character field areas of the photoresist, such that the total character area radiation energy density exposure in the character area of the photoresist is greater than Eo. Ultimately, because the character areas of the photoresist are exposed to some light energy density from the mask character field areas during each mask exposure, the total photoresist exposure time to create the series of characters is less than that of the prior art.
It is an advantage of the photolithographic method of the present invention that the photoresist exposure time required to create a series of characters upon a device is reduced.
It is another advantage of the photolithographic method of the present invention that the exposure time for each mask that is used to create a character in a string of characters is reduced.
It is a further advantage of the photolithographic method of the present invention that a mask set is utilized which is not opaque in mask character field areas of the masks.
It is an advantage of the mask set of the present invention that it includes non-opaque mask character field areas and non-opaque mask character areas, such that a reduction in time of usage of the mask set to create a string of characters is achieved.
These and other features and advantages of the present invention will no doubt become apparent to those skilled in the art upon reading the following detailed description which makes reference to the several figures of the drawing.
The following drawings are not made to scale as an actual device, and are provided for illustration of the invention described herein.
The present invention is a photolithographic process that is employed where a series of masks are sequentially utilized to expose a particular photoresist area, such as an area used in the creation of a series of characters that may comprise a device identification number. By way of example, the application of an identification number in a photoresist field, where the number involves N characters will typically utilize N masks, where a portion of each mask includes a particular character, and the masks are utilized sequentially to create a character string that comprises the identification number; thus N exposures utilizing the N masks are conducted to create the character string.
By way of a prior art example,
Thereafter a second exposure is conducted utilizing the second mask 200, as depicted in
A third exposure is next conducted, utilizing the third mask 300, as is depicted in
A fourth character exposure is next conducted utilizing the further mask 400 depicted in
The last character exposure is next conducted utilizing the fifth mask 500 of
With reference to
As can be understood from
As will be next described, a significant feature of the present invention is that the exposure time that is conducted utilizing each mask, and therefore the total exposure time when all of the masks are utilized, is significantly less than the total exposure time of the prior art. This reduced total exposure time occurs because each of the character areas of the photoresist is partially exposed with an exposure energy density Ef when utilizing each mask other than the character mask for that character. As a result, the exposure time for each character is significantly reduced owing to the additional exposure energy density that the character areas of the photoresist receive from each successive mask. A generalized analysis of the sequential mask exposure method of the present invention can now be presented.
For a generalized method of the present invention utilizing N identical masks having the characteristics of the masks depicted in
E
tc=(N−1)If(t)+Ic(t)=Ic(tp) (1)
where If is the character field area intensity, Ic is the character area intensity, t is the mask exposure time and tp is the prior art mask exposure time, and where the character area intensity Ic of the prior art is the same as the character area intensity Ic of the present method; which assumes that the character transmission factor Tc in this generalized description of the present method is the same as the prior art, that is unity, because the character area of the prior art mask is clear.
Now, a useful ratio R can be created where
R=T
f
/T
c (2)
which is the ratio of the mask transmission factors of the mask of the present invention. And this ratio R can also be expressed as
R=T
f
/T
c
=I
f
/I
c
=I
f(t)/Ic(t)=Ef/Ec (3)
which is the ratio of exposure energy densities that illuminate the character field area and character area of the photoresist.
Another useful ratio r can also be created where
r=t
p
/t (4)
which is the ratio of prior art mask exposure time to the present invention mask exposure time t.
Now dividing equation 1 by Ic and substituting R creates the relationship
[(N−1)R+1](t)=tp (5)
and dividing equation 5 by t and substituting r yields
(N−1)R+1=r (6)
Now regarding the total exposure energy densities it can be said that
E
tf
<E
tc (7)
where Etf is the total character field area exposure energy density and Etc is the total character exposure energy density, and this can be further expressed as
E
tf
+ΔE=E
tc (8)
and the total character field exposure energy density Etf can be expressed as
E
tf
=NI
f(t) (9)
Now substituting equations 9 and 1 into equation 8 yields
NI
f(t)+ΔE=(N−1)If(t)+Ic(t)=Ic(tp) (10)
and therefore
I
f(t)+ΔE=Ic(t) (11)
and dividing by Ic(t) and substituting R creates the relationship
R+ΔE/I
c(t)=1 (12)
and a safety factor S is now created where
S=ΔE/I
c(t) (13)
Therefore the following relationships can be created; from equations 12 and 13
R+S=1 (14)
and from equations 10 and 13
NR+S=r (15)
and
S=r−NR (16)
and from equations 10 and 3
r=(N−1)R+1 (17)
The significance of the mask transmission factor ratio R, and the mask exposure time ratio r, and the safety factor S can be understood from the following Table I.
Table I indicates that for a five mask system (N=5), where the ratio of mask transmission factors R is 1/20, that a time savings ratio r per mask of 1.2 is achieved with a safety factor S of 0.950. This shows a modest time savings (r=1.2) over the prior art where the character field transmission factor Tf of the masks is significantly greater (20 times greater (R= 1/20)) than the character transmission factor Tc.
Now examining the case where R=¾ (the mask transmission factors are much closer), it can be seen that a time exposure ratio r=4 is created; that is, that the present invention requires only ¼ of the exposure time of the prior art. This represents a significant process time savings of the present invention as compared to the prior art. Particularly, where a prior art mask exposure time of two minutes is required to expose a character area, for a five character identifier the total prior art process time is ten minutes. In comparison thereto, the present invention mask exposure time is 30 seconds (¼ of the prior art (r=4)), and the total five mask exposure time is only 2.5 minutes.
It can therefore be seen that the present invention can achieve significant process time savings through the partial exposure of the character areas of the photoresist during each of the N−1 mask exposures using masks other than the particular character mask.
It is therefore to be understood that the present invention uses non-zero transmittance masks as part of a multi-exposure photolithographic process to subcritically expose photoresist in regions that are usually unexposed in the conventional process as known in the photolithographic art. The invention is distinguished from the prior art conventional photolithographic processes in that unlike such conventional processes, masks having opaque portions of zero transmittance are not used to form blank unexposed regions where the latent images of additional features are subsequently formed. Rather, in the method of the present invention, masks having non-opaque portions of partial transmittance are used to form blank partially exposed regions in the photoresist where the latent images of additional features are subsequently formed.
Therefore, it is not necessary to completely cut off light from portions of the photoresist that will subsequently be exposed to form latent images of structures, and in particular, sequentially printed members of a character string as required by a wafer serialization process. Instead, multiple exposures can be performed in the photoresist that are subcritical with regard to the formation of a latent image in the blank regions of the photoresist reserved for the printing of successive latent images of additional features in one embodiment, or alternatively with regard to the formation of multiple latent images in another embodiment, in the same region of photoresist that can later be developed to bring out one or more of these latent images. A preferred embodiment of the present invention is for the printing of sequential members of character strings used to identify slider row and column positions on a wafer, and used to label sliders with the wafer number from which the sliders originated. Moreover, the invention may have many fundamental and novel applications outside of the particular embodiments recited with regard to wafer serialization when the invention is applied to the art of photolithography more generally.
An embodiment of the invention may be described as a method of photolithographic processing including: 1) a first exposing of a photoresist layer with a radiation transmitted through a first mask having first regions of partial transmittance; 2) a second exposing of the photoresist layer with a radiation transmitted through a second mask having features defined over the regions of photoresist exposed to the partially transmitted light of the first exposing, wherein a latent image of the features is formed in the regions of photoresist exposed to the partially transmitted light of the first exposing; and 3) developing the photoresist to selectively develop a latent image of features formed in the regions of photoresist exposed to the partially transmitted light.
An alternative embodiment of the invention may be described as a method of photolithographic processing of the first embodiment wherein the first mask has opaque regions, regions of partial transmittance, and regions of essentially full transmittance, wherein the opaque regions correspond to unexposed regions of the photoresist, the partial transmittance regions, to partially exposed regions of photoresist, and the essentially full transmittance regions to essentially fully exposed regions of photoresist.
Another embodiment of the invention may be described as a method of photolithographic processing of the second method wherein the second mask has opaque regions, regions of partial transmittance, and regions of essentially full transmittance, wherein the opaque regions correspond to unexposed regions of the photoresist, the partial transmittance regions, to partially exposed regions of photoresist, and the essentially full transmittance regions to essentially fully exposed regions of photoresist.
Another embodiment of the invention may be described as a method of photolithographic processing of the first method wherein 1) the first mask has opaque regions, regions of partial transmittance, and regions of essentially full transmittance, wherein the opaque regions correspond to unexposed regions of the photoresist or opaque patterns that serve to define a first character of a character string, the partial transmittance regions to partially exposed regions of photoresist, and the essentially full transmittance regions to essentially fully exposed regions of photoresist; and 2) wherein the second mask has opaque regions, regions of partial transmittance, and regions of essentially full transmittance, wherein the opaque regions correspond to unexposed regions of the photoresist or opaque patterns that serve to define a subsequent character of a character string, the partial transmittance regions, to partially exposed regions of photoresist, and the essentially full transmittance regions to essentially fully exposed regions of photoresist.
Another embodiment of the invention may be described as a method of photolithographic processing of the methods described above wherein the regions of partial transmittance of the first mask are selected from the group consisting of a partially transmitting metallic layer, a pattern of light transmitting pinholes in an opaque field, a pattern of opaque features in a essentially light transmitting field, or a partially transmitting glass layer, wherein said regions of partial transmittance produce a subcritically exposed region of photoresist in which a subsequent latent image of a feature is formed. A partially transmitting metallic layer can be fabricated from a thin film of metal sufficiently thin to allow light to pass through it. A suitably thin layer of metal can be deposited by evaporation or sputtering under conditions favoring the coalescence of the metallic film into a continuous layer as is known in the art. A pattern of light transmitting pinholes can be fabricated by depositing a thin metallic film so thin that the film fails to coalesce into a continuous layer. The film consists essentially of metallic grains that are interconnected in a percolating pattern punctuated by intermittently dispersed pinholes. Again, such a film can be fabricated by the usual thin film deposition techniques of evaporation or sputtering but under conditions known in the art to prevent coalescence into a continuous layer. Alternatively, with even lower amounts of deposited material, the metallic grains may fail to link up into a percolating pattern; but rather, areas devoid of the light blocking material form a percolating pattern punctuated by intermittently dispersed metallic grains, or metallic islands, as is known in the art. Finally, the partially transmitting regions of a glass sheet may be produced in a photochromic glass that changes its transmissivity as a function of exposure to light transmitted through a conventional mask, or by electron lithography through the interaction of electrons with photochromic centers dispersed throughout the glass. When photons or electrons of a given energy interact with these photochromic centers, such incident radiation can change the transmissivity of the glass where such centers are located as is known in the art. Alternatively, any combination of the above methods of creating a partially transmitting region may be used to create a partially transmitting region of a mask.
Another embodiment of the invention may be described as a method of photolithographic processing as described above wherein the regions of partial transmittance of the second mask are selected from the group consisting of a partially transmitting metallic layer, a pattern of light transmitting pinholes in an opaque field, a pattern of opaque features in a essentially light transmitting field, or a partially transmitting glass layer, wherein said regions of partial transmittance produce a subcritically exposed region of photoresist in which a subsequent latent image of a feature is formed.
While the present invention has been shown and described with regard to certain preferred embodiments, it is to be understood that modifications in form and detail will no doubt be developed by those skilled in the art upon reviewing this disclosure. It is therefore intended that the following claims cover all such alterations and modifications that nevertheless include the true spirit and scope of the inventive features of the present invention.