These and other features of this invention will now be described with reference to the drawings of preferred embodiments which are intended to illustrate and not to limit the invention. The drawings are oversimplified for illustrative purposes and not to scale.
a) and 10(b) are schematic diagrams of a plasma CVD apparatus according to an embodiment of the present invention.
a)-11(c) are schematic diagrams of three types of susceptor usable in embodiments of the present invention.
The present invention will be explained below with reference to preferred embodiments. However the preferred embodiments are not intended to limit the present invention.
In an embodiment, the present invention provides a plasma CVD apparatus for processing (e.g., forming a thin film) a substrate, comprising: (i) a vacuum chamber having an inner wall; (ii) an upper electrode (e.g., a shower-plate) installed inside the vacuum chamber; (iii) a susceptor serving as a lower electrode provided with a heater and having a substrate-supporting area for placing the substrate thereon, said susceptor facing (e.g., conductively-coupled to) the upper electrode, enclosed by the inner wall with a gap between an outer periphery of the susceptor and the inner wall, and positioned at a processing position for processing the substrate; and (iv) at least one plasma blocking insulation plate disposed in the gap in the vicinity of or in contact with the susceptor and surrounding all around the susceptor when at the processing position, the insulation plate having an upper surface, a lower surface, and an outer periphery, wherein the lower surface of the insulation plate is not higher than a top surface of the susceptor in an axial direction of the susceptor, the upper surface of the insulation plate is not lower than a lower end of the susceptor, the outer periphery of the insulation plate is located closer to the inner wall of the chamber than to the periphery of the susceptor when at the processing position.
According to the above embodiment, despite the fact that the structure is simple, a plasma generated in the chamber can effectively be confined above the substrate, thereby inhibiting contact of a plasma with an exposed conductive part such as a side of the susceptor and an inner wall of the chamber. As a result, a floating potential of the substrate can effectively be minimized, and a change of floating potential can be suppressed when a plasma is generated. Thus, a problem of charging damage and/or a problem of adhesion of the substrate to the susceptor can effectively be alleviated.
In the above, in an embodiment, the gap between the inner wall and the susceptor may be about 4 cm or greater (e.g., 4-10 cm). The gap can vary depending on the type and size of apparatus. For example, a PECVD apparatus for treating a substrate having a diameter of 8 inches may have a gap of about 6 cm, whereas a PECVD apparatus for treating a substrate having a diameter of 12 inches may have a gap of about 5 cm.
An exposed conductive part which can effectively be covered by the insulation plate includes an inner wall of the chamber, a side of the susceptor, a ring duct, etc., which are typically made of aluminum.
A distance A from the outer periphery of the susceptor to the outer periphery of the insulation plate and a distance B from the outer periphery of the insulation plate to the inner wall of the chamber may satisfy the following equation: A/(A+B)=50-99% (including 60%, 70%, 80%, 90%, 95%, and ranges between any two numbers of the foregoing, preferably 70-98%, more preferably 90% or higher). The distance is measured in a direction perpendicular to the axial direction of the susceptor.
The insulation plate may have an inner periphery which has a diameter greater than a diameter of the substrate-supporting area to be placed on the susceptor. When the insulation plate is attached to a top surface of the susceptor, the inner diameter of the insulation plate is greater than the diameter of the substrate-supporting area (or the substrate).
The insulation plate may be ring-shaped and attached to the susceptor or fixed to the chamber. In the former, the susceptor may have an annular lip portion on its top surface outside the substrate-supporting area, and the insulation plate may be disposed on the top surface outside the lip portion. Alternatively, the top plate may have no annular lip portion on a top surface outside the substrate-supporting area, and the insulation plate may be disposed on the top surface outside the substrate-supporting area.
The susceptor can be a single piece in which a heater is embedded, or two pieces (a top plate and a heating block) attached together. The top surface of the top plate may be anode-treated to cover it with an anodic oxide film.
The above includes, but is not limited to, the following embodiments: The susceptor is comprised of a top plate and a heating block on which the top plate is placed, wherein the insulation plate is ring-shaped and attached to the top plate. The susceptor is comprised of a top plate and a heating block on which the top plate is placed, wherein the insulation plate is ring-shaped and interposed between the top plate and the heating block. The susceptor is comprised of a top plate and a heating block on which the top plate is placed, wherein the insulation plate is ring-shaped and attached to a side of the heating block. The susceptor is comprised of a top plate and a heating block on which the top plate is placed, wherein the insulation plate has a ring portion and an annular upright peripheral portion, said ring portion being attached to a side of the heating block. The susceptor is comprised of a top plate and a heating block on which the top plate is placed, wherein the insulation plate is ring-shaped, fixed to a bottom of the chamber with a support, and disposed at or near a boundary between the top plate and the heating block when at the processing position.
Further, the at least one insulation plate may be composed of two insulation plates installed in different positions. One of the insulation plates may be attached to a top surface of the susceptor, and the other insulation plate may be fixed to a bottom of the chamber with a support.
The insulation plate may be made of a material selected from the group consisting of oxides, nitrides, and fluorides of aluminum, magnesium, silicon, titanium, and zirconium.
In all of the aforesaid embodiments, any element used in an embodiment can interchangeably be used in another embodiment unless such a replacement is not feasible or causes adverse effect. Further, the present invention can equally be applied to apparatuses and methods.
In another embodiment, the present invention provides a plasma CVD apparatus for processing a substrate, comprising: (i) a vacuum chamber having an inner wall; (ii) an upper electrode (e.g. a shower-plate) installed inside the vacuum chamber; (iii) a susceptor serving as a lower electrode provided with a heater and having a substrate-supporting area for placing the substrate thereon, said susceptor facing (e.g., conductively-coupled to) the shower-plate, enclosed by the inner wall with a gap between an outer periphery of the susceptor and the inner wall, and positioned at a processing position for processing the substrate; and (iv) a means for minimizing a floating potential charged on the substrate when a plasma is generated.
In another aspect, the present invention provides a method for processing a substrate using any one of the plasma CVD apparatus described above, comprising: (I) placing the substrate on a top surface of the susceptor; (II) generating a plasma in the chamber; and (III) confining the plasma above the substrate using the insulation plate, thereby minimizing a floating potential charged on the substrate. Further, the present invention provides a method for processing a substrate, comprising: (I) a step of placing a substrate on a susceptor installed in a chamber of a plasma CVD apparatus; (II) a step of generating a plasma in the chamber; and (III) a step for minimizing a floating potential charged on the substrate, thereby forming a thin film on the substrate.
In the present disclosure where conditions and/or structures are not specified, the skilled artisan in the art can readily provide such conditions and/or structures, in view of the present disclosure, as a matter of routine experimentation.
The present invention will be explained with reference to the drawings. However, the drawings are not intended to limit the present invention.
[Apparatus Structure]
On manufacturing lines using semiconductor apparatuses, dry etching, plasma CVD and other plasma processes are widely used. The plasma CVD apparatus shown in
[Overall]
This plasma CVD apparatus for forming a film on a semiconductor substrate, as illustrated in
[Opening]
The opening 2 is provided in a side face of the reactor chamber 1. The reactor chamber 1 is connected via a gate valve 3 to a transfer chamber (not shown) used to transfer a semiconductor substrate into and out of the reactor chamber.
[Exhaust Port]
The exhaust port 4 is provided inside the reactor chamber 1, where the exhaust port 4 is connected to an evacuation pump (not shown) via a piping 5. Provided between the exhaust port 4 and vacuum pump is a mechanism (not shown) for detecting and adjusting the pressure inside the reactor chamber, and this mechanism can be used to control the interior of the reactor chamber to a specified pressure.
[Upper Electrode]
The showerhead 7 is set in a position facing the aforementioned susceptor inside the reactor chamber 1.
The showerhead 7 is connected to the reaction gas introduction pipe 6 for introducing reaction gas, and the gas is ejected into the reactor chamber through several thousand pores (not shown) provided in the bottom face of the showerhead 7 for injecting the reaction gas onto a substrate. The showerhead 7 also connects electrically to the high-frequency power supply 8 to constitute one of the electrodes for implementing plasma discharge.
[Lower Electrode]
The susceptor 15 located inside the reactor chamber 1 and used to place a semiconductor substrate on top comprises the placement block 9 (top plate) that constitutes a placement surface covered with an anodized film and on which a semiconductor substrate is placed, as well as the heating block 10 (heater) that heats the semiconductor substrate using a heating element embedded inside the block.
The heating block 10 is grounded, and the susceptor constitutes one of the electrodes for implementing plasma discharge.
The placement block 9 is detachably affixed to the heating block 10 using screws, etc. However, the placement block 9 can also be connected to the heating block 10 in a non-detachable manner.
The heating block 10 is connected via a support body to a drive mechanism (not shown) for moving the susceptor 15 up and down.
Embedded inside the heating block 10 are a resistance-type heating element that is connected to an external power supply (not shown) and a temperature controller. The heating element is controlled by the temperature controller in such a way that the susceptor 15 is heated to a desired temperature (such as any temperature between 300° C. and 650° C.).
The foregoing explained the structure of the conventional apparatus shown in
[Insulator]
In a representative example of the invention specified in the present application for patent, an insulation plate is set around the susceptor.
The insulation plate is affixed to the interior of the reactor in an embodiment, or placed on the susceptor so that it can move together with the susceptor.
The position at which the insulation plate is placed is explained. If the insulation plate is set above the surface of the top plate, it is sufficient that the bottom of the insulation plate is positioned at a height equal to or below the surface of the top plate. If the insulation plate is set below the surface of the top plate, it is sufficient that the top of the insulator is positioned at a height equal to or above the bottom face of the heating block. In other words, the insulation plate can be placed at any position as long as virtually no gaps form between the susceptor and insulation plate and the plasma generation area can be limited. Normally a ring-shaped piece having a constant thickness is used to constitute the insulation plate, but it can have a raised periphery or otherwise have multiple thicknesses.
The insulator is normally made of ceramics or quartz, but its material is not limited to these two. Specifically, it is sufficient that the insulator is made of at least one of the materials that include oxides, nitrides and fluorides of aluminum, magnesium, silicon, titanium and zirconium. Specific examples of the present invention are explained below. It should be noted, however, that the present invention is not limited to these examples.
By the way, the floating potential can be measured using the method illustrated in
The insulation plate 21 comprises a ceramic disc whose thickness is in a range of approx. 1 mm to approx. 10 mm (or preferably in a range of 1 mm to 5 mm, or more preferably in a range of 2 mm to 4 mm), and whose inner diameter is greater than the semiconductor substrate 11 while whose outer diameter is equal to or greater than 95% of the distance from a top plate 29 to an interior wall 16. In other words, the insulation plate must not contact the semiconductor substrate 11, and its inner diameter must be smaller than the semiconductor substrate 11 so that the insulation plate will not overlap with the semiconductor substrate 11.
A step 25 is provided around the top plate 29 for placing the insulation plate 21. The insulation plate 21 is placed on the step and moves together with the top plate 29.
Because of this insulation plate 21, areas located below the insulation plate 21 where a conductive member is exposed can be insulated from plasma.
Experiment using Variation Example 1
The applicable conditions are specified below.
Various Conditions
TEOS Film Forming Conditions
As evident from the graph in
Other Variations of Example 1
In Example 1, the outer diameter of the insulator 21 was equal to or above 95% of the distance from the top plate 29 to the interior wall 16. However, the intended effects can be achieved as long as the outer diameter is at least one half the distance from the top plate 29 to the interior wall 16.
Also, the thickness of the insulator 21 may not be in a range of 1 to 10 mm as specified in Example 1, as long as the thickness is enough to shield plasma.
In Example 1, the height of the insulator 21 was roughly the same as the height of the top face of the top plate 29. However, the two can be positioned at different heights.
In Example 1, the insulation plate 21 was simply placed on a step. However, it is desirable to affix it to the top plate 29 by means of screws, etc.
When placing the insulation plate 21 on the susceptor, it is not necessary to provide a step on the top plate 29. Instead, the insulation plate may be affixed to the susceptor in a manner movable together with the susceptor, as shown in
Also, the insulation plate may not be flat. As shown in
By affixing the insulation plate to the heating block in this manner, gaps will not form between the heating block and insulation plate. Also, by affixing the insulation plate to the heating block in a movable manner, the insulation plate can be placed in an area not possible under the method in which the insulation plate is affixed to aid in the transfer of semiconductor substrates.
In Example 2, the insulation plate is affixed. As shown in
Here, the insulator 71 may preferably be set above the bottom face of the heating block 10.
Desirably the gap between the susceptor and insulator may be minimized. Even when the insulator is affixed to the bottom of the reactor, the gap from the susceptor may preferably be kept to 2 mm or less.
The inner diameter of the insulation plate 71 is roughly the same as the outer diameter of the susceptor, while the outer diameter of the insulation plate corresponds to 95% of the distance from a top plate 79 to the interior wall, in the same manner as explained in Example 1.
Variations of Example 2
In Example 2, the height of the insulation plate 71 was the same as the height of the bottom edge of the top plate. However, the heights of the two may not be the same as long as gaps do not virtually form between the susceptor and insulation plate.
If the insulation plate is set above the bottom edge of the top plate 79, it is sufficient that the bottom of the insulation plate 71 is at a height equal to or below the surface of the top plate 79. If the insulation plate is set below the surface of the top plate 79, it is sufficient that the top of the insulator 71 is at a height equal to or above the bottom face of the heating block.
The thickness, outer diameter and material of the insulation plate 71 may conform to those explained in Example 1.
By affixing the insulation plate to the reactor in this manner, the insulator temperature will not rise as much as when the insulation plate is affixed to the susceptor, which is advantageous when a material of lower heat resistance is used.
In Example 3, multiple insulation plates are used.
In
When multiple insulation plates are used in this way, the positions and shapes of insulation plate can be set in a more flexible manner to achieve greater effects in situations where using one insulation plate is not sufficiently effective.
It will be understood by those of skill in the art that numerous and various modifications can be made without departing from the spirit of the present invention. Therefore, it should be clearly understood that the forms of the present invention are illustrative only and are not intended to limit the scope of the present invention.
This application claims the benefit of U.S. Provisional Application No. 60/800,670, filed May 16, 2006, the disclosure of which is herein incorporated by reference in its entirety.
Number | Date | Country | |
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60800670 | May 2006 | US |