The present embodiments relate to substrate processing, and more particularly, to electrostatic clamps for holding substrates.
Substrate holders such as electrostatic clamps are used widely for many manufacturing processes including semiconductor manufacturing, solar cell manufacturing, and processing of other components. Many substrate holders provide for substrate heating as well as substrate cooling in order to process a substrate at a desired temperature. In order to maintain proper heating or cooling some substrate holder designs including those for electrostatic clamps provide a gas that may flow adjacent or proximate the backside of a substrate being processed, such as a wafer.
In particular substrate holder designs, such as in electrostatic clamps, gas may provided via a backside gas distribution system so that gas is present as a heat conductor between an electrostatic clamp surface and a back surface of a wafer that is held by the electrostatic clamp. In order to facilitate cooling or heating of a substrate the gas pressure may be maintained in a range to provide a needed heat transfer while not generating excessive pressure on the back surface of the substrate. Because a high electric field may be employed to clamping electrodes of the electrostatic clamp, the gas species may be affected when provided to the electrostatic clamp. In some circumstances this may lead to the generation of a plasma within a backside gas distribution system. The plasma species such as ions may etch surfaces that come into contact with the plasma, creating etched species that may be transported to other regions in a processing system, including to a substrate being held by the electrostatic clamp.
Although in some manufacturing processes the level of substrate contamination introduced by formation of plasmas within a backside gas distribution system may be acceptable, in other processes this may be unacceptably high. For example, when a substrate is processed at high substrate temperature, metal contaminants created in a backside plasma may be sufficiently mobile to reach the front of a wafer.
It is with respect to these and other considerations that the present improvements have been needed.
This Summary is provided to introduce a selection of concepts in a simplified form that are further described below in the Detailed Description. This Summary is not intended to identify key features or essential features of the claimed subject matter, nor is it intended as an aid in determining the scope of the claimed subject matter.
In one embodiment, an apparatus to support a substrate may include a base and an insulator portion adjacent to the base and configured to support a surface of the substrate. The apparatus may also include an electrode system to apply a clamping voltage to the substrate, wherein the insulator portion is configured to provide a gas to the substrate through at least one channel that has a channel width, wherein a product of the gas pressure and channel width is less than a Paschen minimum for the gas, where the Paschen minimum is a product of pressure and separation of surfaces of an enclosure at which a breakdown voltage of the gas is a minimum.
In another embodiment, a method of operating an electrostatic clamp may include arranging at least one channel of an insulator portion of the electrostatic clamp with a channel width, applying a clamping voltage to an electrode of the electrostatic clamp, an delivering a gas to the electrostatic clamp at a gas pressure through the at least one channel, wherein a product of the gas pressure and channel width is less than a Paschen minimum for the gas, where the Paschen minimum is a product of pressure and distance of an enclosure at which breakdown voltage of the gas is a minimum.
The present embodiments address a phenomenon that may adversely affect manufacturing of components that are sensitive to contamination. The embodiments described herein provide apparatus and methods for reducing inadvertent plasma formation in substrate holders such as electrostatic clamps. In particular, the present embodiments reduce likelihood of formation of backside plasmas that may be generated during operation of present day electrostatic clamps. These backside plasmas may cause etching of metal or other contaminants and recondensation of the contaminants on a back surface of a substrate, which may lead to detectable concentrations at the front surface of the substrate under certain process conditions. In the example of CMOS image sensor fabrication, levels of metal contamination as low as 1E8/cm-2 may impact device yield, which contamination levels may be produced when a plasmas forms in an electrostatic clamp adjacent the back surface of a substrate during processing of the substrate.
In some embodiments, a novel electrostatic clamp system is configured to reduce likelihood of plasma formation by alteration of the design of components such as a channel or channels in an insulator portion of the electrostatic clamp that supports a substrate. In some embodiments, a gas distribution system may alter the gas pressure provided in backside distribution channels in order to provide adequate gas pressure at the back of a substrate while at the same time generating gas conditions that avoid plasma formation within the backside distribution system. The gas distribution system may additionally alter the composition of gas provided to the electrostatic clamp to avoid plasma formation. In further embodiments, as detailed below, the frequency of an AC voltage applied to an electrode system in the electrostatic clamp may be adjusted to reduce plasma formation. In still other embodiments, in order to reduce probability of forming a plasma, an insulator portion of the electrostatic clamp may include a grounded conductor or low emissivity material within a channel that conducts gas to the substrate.
The electrostatic clamp system 100 includes an electrostatic clamp 102, gas supply system 110, and voltage supply 112. The electrostatic clamp 102 includes a base 104 and insulator portion 106 adjacent the base 104. The insulator portion 106 is configured to support a substrate 108, as illustrated. In various embodiments the insulator portion 106 may be a ceramic plate or ceramic layer. The voltage supply 112 is configured to supply a voltage to an electrode system (not separately shown) that is contained within the electrostatic clamp, which may generate an electric field that applies a clamping force to attract and hold the substrate 108. In various embodiments, as detailed below, the voltage may be applied as an AC signal in which image charge is rapidly created, thereby facilitating rapid chucking and de-chucking of the substrate 108. The voltage supply 112 may be configured to supply a bias voltage such as 1000 V in order to generate an appropriate clamping force to the substrate 108. This may generate an electrostatic clamp pressure on the order of 50 Torr to 200 Torr in some instances.
The gas supply system 110 is configured to supply a gas (not shown) to the base 104 of electrostatic clamp 102, which may be distributed to the substrate 108 in order to provide a heat-conducting medium between the electrostatic clamp 102 and substrate 108. In different embodiments, the gas that is supplied to the electrostatic clamp may be helium, neon, argon, nitrogen or other gas species or combination of gas species. The embodiments are not limited in this context. In order to supply sufficient heat conduction between substrate 108 and electrostatic clamp 102, the electrostatic clamp system 100 may be configured to deliver a gas pressure within the electrostatic clamp 102 of 10 Torr to 100 Torr, and in some instances 50 Torr to 100 Torr.
Consistent with various embodiments, the electrostatic clamp system 100 may be configured in different ways to avoid plasma formation in backside region 116. The backside region 116 may include channels within the electrostatic clamp 102 and cavities that are defined between the substrate 108 and electrostatic clamp 102 when the substrate 108 is held adjacent the insulator portion 106. As detailed below, the electrostatic clamp system 100 may provide immunity from plasma formation by adjusting the voltage signal applied to electrodes, adjusting the gas composition or adjusting gas pressure to avoid the Paschen minimum, adjusting cavity construction in the electrostatic clamp 102, or a combination of the adjusting voltage signal, gas pressure, or cavity construction. In some embodiments, the adjusting of cavity construction may include reducing the width of a channel or channels that conduct gas in the electrostatic clamp 102, by providing an electrically conductive channel coating that is grounded to form a grounded conductive layer within a channel or other cavity region of the electrostatic clamp 102, or by providing a low electron emissivity material in the channel or other cavity region.
In order to facilitate heat conduction between the electrostatic clamp 200 substrate 108, a gas may be provided to the electrostatic clamp 200. As illustrated in
Consistent with various embodiments, the gas supply system 110 and channels 210 may be designed in particular to avoid plasma formation when clamping voltage is applied and gas is provided to the electrostatic clamp 200. Turning now to
As further shown in
It is to be noted that when a high voltage is applied to the electrode 308, the field strength may be sufficient to generate a plasma in the backside region 214 if gas pressure of a gas directed into the electrostatic clamp 200 and cavity dimensions fall within certain ranges. Accordingly, in various embodiments, the dimensions of certain features within the electrostatic clamp 200 and gas pressure directed to the electrostatic clamp 200 are designed to avoid plasma formation. As detailed below, in particular embodiments, the dimensions of channel 210 and pressure of gas are designed so that the product of dimension and pressure do meet the Paschen minimum. In further embodiments, the composition of gas provided to an electrostatic clamp may be adjusted to reduce the probability of plasma formation in the backside region 214.
It is to be noted that present day electrostatic clamps may apply voltages of 1000 V (indicated by the line 412) or more to generate a desired clamping force for holding a substrate. Accordingly, using the example of clamping voltage of 1000 V, it can be seen from
However, this compromise between providing high enough backside pressure for good heat conduction between substrate and electrostatic clamp and low enough backside pressure to ensure proper substrate clamping comes at a cost. Present day electrostatic clamps often include gas distribution channels whose dimensions are susceptible to plasma formation at operating pressures and operating voltages that are applied to the electrostatic clamp. In particular, the channel width (D) may result in a PD product close to the Paschen minimum when gas is delivered to the electrostatic clamp. For example, it is common for channels to have widths in the range of three mm or more. In one instance, if 10 Torr pressure is delivered to the electrostatic clamp and the channel width is three mm, the value of PD product is 3 Torr-cm, which falls close to the Paschen minimum for gases such as Ar, Ne, and He, and lies within the region 406. When clamping voltage of, for example 500-1500 V, is applied to an electrostatic clamp that is operated under such design conditions, cavities such as channels within the electrostatic clamp may be especially susceptible to plasma formation.
Various embodiments overcome this problem by designing a combination of voltage signal, gas pressure and channel dimensions to avoid plasma formation. In particular, the combination of such factors may be such that the PD product falls in regions 408 or 410 of
In
In
In
In
In additional embodiments, the gas supplied to an electrostatic clamp may be changed from nitrogen to other gases to reduce the likelihood of plasma formation. In one embodiment, He gas is supplied to the electrostatic clamp. Although He may exhibit a lower VB at its Paschen minimum, He exhibits a first ionization potential of around 25 eV as compared to 15 eV for nitrogen, thereby reducing the probability of forming a plasma in an electrostatic clamp at least under certain conditions. In further embodiments, a gas supplied to an electrostatic clamp may contain a mixture of gas species. For example, gas species such as NF3 of SF6, which each show a strong electron affinity, may be added to a gas such as N2 or an inert gas to generate a mixed species gas in which the NF3 of SF6 act as a quench of any plasma that may tend to form. The embodiments are not limited in this context.
In additional embodiments, multiple features of a conventional electrostatic clamp may be adjusted to reduce plasma formation. In these embodiments, two or more features of a conventional electrostatic clamp may be adjusted to prevent plasma formation, such as adjusting at least two of: channel dimension in the electrostatic clamp, gas pressure, gas species, or addition of a grounded conductor to a channel. For example, a helium gas may be provided to an electrostatic clamp, for which the Paschen minimum lies in the region of 2 Torr-cm. The channel dimensions in an insulator portion, such as channel height or channel width, may be reduced to 0.1 mm, while pressure is adjusted to 75 Torr. This combination results in a PD product of 0.75, which is well below the region of the Paschen minimum for helium, making it unlikely for breakdown and plasma formation to take place.
In still further embodiments, an electrostatic clamp may include cavities that include a coating having a low secondary electron emission material to prevent plasma formation. Suitable materials for such coating include carbon, carbon nitride, and titanium nitride. The embodiments are not limited in this context.
The present disclosure is not to be limited in scope by the specific embodiments described herein. Indeed, other various embodiments of and modifications to the present disclosure, in addition to those described herein, will be apparent to those of ordinary skill in the art from the foregoing description and accompanying drawings. Thus, such other embodiments and modifications are intended to fall within the scope of the present disclosure. Furthermore, although the present disclosure has been described herein in the context of a particular implementation in a particular environment for a particular purpose, those of ordinary skill in the art will recognize that its usefulness is not limited thereto and that the present disclosure may be beneficially implemented in any number of environments for any number of purposes. Accordingly, the claims set forth below should be construed in view of the full breadth and spirit of the present disclosure as described herein.
This application is a divisional of, and claims the benefit of priority to, U.S. patent application Ser. No. 14/179,030, filed Feb. 12, 2014, entitled “Plasma Resistant Electrostatic Clamp,” which application is incorporated herein by reference in its entirety.
Number | Date | Country | |
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Parent | 14179030 | Feb 2014 | US |
Child | 16397324 | US |