Embodiments described herein relate generally to a semiconductor device and a method for manufacturing the same.
In a nonvolatile semiconductor memory device in which a plurality of NAND memory strings are arranged, miniaturization has been increasingly advanced. With this miniaturization, contacts and interconnections connected to each of the plurality of memory strings also come close to each other.
In this situation, if an insulating layer having a relatively high permittivity is provided around the contact plug or interconnection, delay of interconnection signal speed is more likely to occur due to the influence of parasitic capacitance.
According to one embodiment, a semiconductor device includes a semiconductor layer including a first region and a second region placed outside the first region, a first insulating layer provided above the semiconductor layer, a first contact electrode extending in a direction from the semiconductor layer toward the first insulating layer, having a sidewall surrounded with the first insulating layer, and electrically connected to a first element provided in the first region, a second contact electrode extending in the direction from the semiconductor layer toward the first insulating layer, having a sidewall surrounded with the first insulating layer, and electrically connected to a second element provided in the second region, a first interconnection layer connected to an upper end of the first contact electrode, extending in a direction crossing the extending direction of the first contact electrode, and having a sidewall surrounded with the first insulating layer, and a second interconnection layer connected to an upper end of the second contact electrode, extending in a direction crossing the extending direction of the second contact electrode, having a sidewall surrounded with the first insulating layer, and having a line width wider than a line width of the first interconnection layer.
Various embodiments will be described hereinafter with reference to the accompanying drawings. In the following description, like members are labeled with like reference numerals. The description of the members once described is omitted appropriately.
The nonvolatile semiconductor memory device 1 according to the first embodiment is what is called a NAND nonvolatile semiconductor memory device. The nonvolatile semiconductor memory device 1 includes a memory cell section (first region) and a peripheral section (second region) placed outside the memory cell section.
The memory cell section of the nonvolatile semiconductor memory device 1 is shown in
In the memory cell section 100, a plurality of semiconductor regions 11 (element regions) are arranged in the X-direction. Element isolation regions are each provided between the plurality of semiconductor regions 11. A line-shaped control gate electrode 60 and a line-shaped select gate electrode 61 are provided in the X-direction crossing the Y-direction in which the semiconductor regions 11 extend. The select gate electrodes 61 include a drain-side select gate electrode SGD and a source-side select gate electrode SGS. A plurality of control gate electrodes 60 (control gate electrodes WL0-WLn) are sandwiched between the select gate electrode SGD and the select gate electrode SGS.
The memory cell section 100 includes memory cells at the crossing positions of the plurality of semiconductor regions 11 and the plurality of control gate electrodes 60. The semiconductor region 11 sandwiched between the select gate electrode SGD and the select gate electrode SGS is provided with a plurality of memory cells. The memory cell section 100 includes a memory string in which the select gate electrode SGD, a plurality of memory cells, and the select gate electrode SGS are connected in series in the Y-direction.
The memory cell section 100 is surrounded with e.g. a circuit for driving and controlling the memory cell section 100. For instance, the peripheral section 200 described later is provided with transistors, resistors, capacitors, interconnections, contact plugs and the like constituting the circuit.
The portions shown in
The memory cell section 100 of the nonvolatile semiconductor memory device 1 shown in
The semiconductor layer 10 is e.g. a semiconductor substrate singulated from a semiconductor wafer. The semiconductor region 11 provided on the semiconductor layer 10 is an active region populated with transistors of the nonvolatile semiconductor memory device 1. Here, a diffusion region (source/drain region) is provided (not shown) in the semiconductor region 11 on both sides of the charge storage layer 30.
The gate insulating film 20 is provided between the charge storage layer 30 and the semiconductor region 11. The gate insulating film 20 functions as a tunnel insulating film for tunneling charge (e.g., electrons) between the semiconductor region 11 and the charge storage layer 30.
The charge storage layer 30 is provided at the crossing position of the semiconductor region 11 and the control gate electrode 60. The charge storage layer 30 covers the gate insulating film 20. The charge storage layer 30 can accumulate the charge tunneled from the semiconductor region 11 via the gate insulating film 20. The charge storage layer 30 may be referred to as floating gate layer.
The gate insulating film 40 is provided between the charge storage layer 30 and the control gate electrode 60. The gate insulating film 40 covers the charge storage layer 30. The side surface of the charge storage layer 30 is covered with an interlayer insulating film 70. That is, the upper surface and the side surface of the charge storage layer 30 are covered with insulator so that the charge accumulated in the charge storage layer 30 does not leak to the control gate electrode 60. The gate insulating film 40 may be referred to as charge block layer.
The control gate electrode 60 covers the charge storage layer 30 via the gate insulating film 40. The control gate electrode 60 includes a polysilicon-containing layer 60a and a metal-containing layer 60b provided above the polysilicon-containing layer 60a. The control gate electrode 60 functions as a gate electrode for controlling a transistor.
The select gate electrode 61 includes e.g. a polysilicon-containing layer 61a, a polysilicon-containing layer 61b, and a metal-containing layer 61c. The gate insulating film 20 is provided between the polysilicon-containing layer 61a and the semiconductor region 11. A diffusion region (source/drain region) is provided (not shown) in the semiconductor region 11 on both sides of the polysilicon-containing layer 61a. The select gate electrode 61, the gate insulating film 20, and the semiconductor region 11 described above constitute a select gate transistor (first element). One memory string is selected from among the plurality of memory strings by the select gate transistor.
Insulating layers 71, 72 are provided on the control gate electrode 60. Insulating layers 71, 72 are provided on the select gate electrode 61. A sidewall film 73 is provided on the sidewall of the select gate electrode 61. An insulating layer 74 is provided on the interlayer insulating film 70, on the insulating layer 72, on the sidewall film 73, and on the gate insulating film 20.
An insulating layer 80 is provided on the insulating layer 74. A contact electrode 50 (third contact electrode) is provided in the insulating layer 80. The contact electrode 50 includes e.g. a barrier layer 50a and a conductive layer 50b. The contact electrode 50 extends in the direction (Z-direction) from the semiconductor layer 10 toward the insulating layer 80. The lower end of the contact electrode 50 pierces the insulating layer 74 and is connected to the semiconductor region 11. The contact electrode 50 is electrically connected to the diffusion region of the select gate transistor.
An insulating layer 82 is provided on the insulating layer 80. A contact electrode 51 (first contact electrode) is provided in the insulating layer 82. The contact electrode 51 includes e.g. a barrier layer 51a and a conductive layer 51b. The contact electrode 51 extends in the direction (Z-direction) from the semiconductor layer 10 toward the insulating layer 82. The sidewall 51w of the contact electrode 51 is surrounded with the insulating layer 82. The contact electrode 51 is connected to the contact electrode 50. The contact electrode 51 is electrically connected to the select gate transistor of the memory cell section 100.
Furthermore, an interconnection layer 52 is provided in the insulating layer 82. The interconnection layer 52 is used as a bit line of the nonvolatile semiconductor memory device. The interconnection layer 52 includes e.g. a seed layer 52a and a conductive layer 52b. The interconnection layer 52 is connected to the upper end of the contact electrode 51. The interconnection layer 52 extends in a direction (e.g., X-direction) crossing the extending direction of the contact electrode 51. The sidewall 52w of the interconnection layer 52 is surrounded with the insulating layer 82. An insulating layer 90 is provided on the insulating layer 82.
The peripheral section 200 (peripheral circuit region) of the nonvolatile semiconductor memory device 1 shown in
The semiconductor region 11 is an active region populated with transistors of the nonvolatile semiconductor memory device 1. The gate electrode 62 includes e.g. a polysilicon-containing layer 62a, a polysilicon-containing layer 62b, and a metal-containing layer 62c. The gate insulating film 20 is provided between the polysilicon-containing layer 62a and the semiconductor region 11. A diffusion region (source/drain region) is provided (not shown) in the semiconductor region 11 on both sides of the polysilicon-containing layer 62a. The gate electrode 62, the gate insulating film 20, and the semiconductor region 11 described above provide a transistor (second element) in the peripheral section 200.
Here, the second element provided in the peripheral section is not limited to the transistor. For instance, the element may be a resistor or capacitor. In the embodiment, a transistor is illustrated in
Furthermore, insulating layers 71, 72 are provided on the gate electrode 62. A sidewall film 73 is provided on the sidewall of the gate electrode 62. An insulating layer 74 is provided on the insulating layer 72, on the sidewall film 73, and on the gate insulating film 20.
An insulating layer 80 is provided on the insulating layer 74. A contact electrode 55 is provided in the insulating layer 80. The contact electrode 55 includes e.g. a barrier layer 55a and a conductive layer 55b. The contact electrode 55 extends in the direction (Z-direction) from the semiconductor layer 10 toward the insulating layer 80. The lower end of the contact electrode 55 pierces the insulating layer 74 and is connected to the semiconductor region 11. The contact electrode 55 is electrically connected to the diffusion region of the transistor.
An insulating layer 82 is provided on the insulating layer 80. A contact electrode 56 (second contact electrode) is provided in the insulating layer 82. The contact electrode 56 includes a barrier layer 56a and a conductive layer 56b. The contact electrode 56 extends in the direction (Z-direction) from the semiconductor layer 10 toward the insulating layer 82. The sidewall 56w of the contact electrode 56 is surrounded with the insulating layer 82. The contact electrode 56 is connected to the contact electrode 55. The contact electrode 56 is electrically connected to the transistor of the peripheral section 200.
Furthermore, an interconnection layer 57 is provided in the insulating layer 82. The interconnection layer 57 includes a seed layer 57a and a conductive layer 57b. The interconnection layer 57 is connected to the upper end of the contact electrode 56. The interconnection layer 57 extends in a direction (e.g., X-direction) crossing the extending direction of the contact electrode 56. The line width of the interconnection layer 57 is wider than the line width of the interconnection layer 52. Here, the line width of the interconnection layer refers to the width of the interconnection layer cut perpendicular to the extending direction of the interconnection layer. The sidewall 57w of the interconnection layer 57 is surrounded with the insulating layer 82. The insulating layer 90 is provided on the insulating layer 82.
Furthermore, in the nonvolatile semiconductor memory device 1, the distance from the lower surface 10d of the semiconductor layer 10 to the upper end 52u of the interconnection layer 52 is equal to the distance from the lower surface 10d of the semiconductor layer 10 to the upper end 57u of the interconnection layer 57.
The material of the semiconductor layer 10 (or the semiconductor region 11) is e.g. a p-type (first conductivity type) semiconductor crystal. This semiconductor can be e.g. silicon (Si).
The material of the gate insulating film 20 is e.g. silicon oxide (SiOx), silicon nitride (SixNy) or the like. The gate insulating film 20 may be e.g. a monolayer of silicon oxide film or silicon nitride film, or may be a stacked film of either silicon oxide film or silicon nitride film.
The material of the charge storage layer 30 may be e.g. a semiconductor material such as Si and Si-based compound, a material different therefrom (e.g., metal or insulating film), or a stacked film thereof. The material of the charge storage layer 30 is e.g. a semiconductor containing n-type (second conductivity type) impurity, a metal, a metal compound or the like. This material can be e.g. amorphous silicon (a-Si), polysilicon (poly-Si), silicon germanium (SiGe), silicon nitride (SixNy), hafnium oxide (HfOx) or the like.
The gate insulating film 40 may be e.g. a monolayer of silicon oxide film or silicon nitride film, or may be a stacked film of either silicon oxide film or silicon nitride film. For instance, the gate insulating film 40 may be what is called an ONO film (silicon oxide film/silicon nitride film/silicon oxide film). Alternatively, the gate insulating film 40 may be a metal oxide film or metal nitride film.
The material of the barrier layer 50a, 51a, 55a, 56a is e.g. titanium (Ti), titanium nitride (TiNx) or the like. The material of the conductive layer 50b, 51b, 55b, 56b is e.g. tungsten (W) or the like. The material of the conductive layer 52b, 57b is e.g. copper (Cu) or the like.
The material of the polysilicon-containing layer 60a, 61a, 61b, 62a, 62b is e.g. a semiconductor containing an impurity element. This semiconductor can be polysilicon. The material of the metal-containing layer 60b, 61c, 62c is e.g. a metal such as tungsten, or metal silicide.
In the embodiment, the material of the portion referred to as insulating film, insulating layer, or sidewall film is e.g. silicon oxide (SiOx) or silicon nitride (SixNy).
In the embodiment, the first conductivity type is p-type, and the second conductivity type is n-type. However, the first conductivity type may be n-type, and the second conductivity type may be p-type. The p-type impurity element can be e.g. boron (B). The n-type impurity element can be e.g. phosphorus (P) or arsenic (As).
A process for manufacturing the contact electrode and the interconnection layer in the nonvolatile semiconductor memory device 1 is now described.
First, before the state shown in
Next, the memory cell section 100 is subjected to the processing described below.
For instance, as shown in
Then, an insulating layer 83 (third insulating layer) different in composition from the insulating layer 82 is formed on the insulating layer 82. For instance, in the case where the insulating layer 80 is a silicon oxide layer, the insulating layer 83 is a silicon nitride layer (SixNy layer). Alternatively, the insulating layer 83 may be a silicon carbonitride layer (SiCxNy layer). This insulating layer 83 functions as a stopper film (described later).
Then, an insulating layer 84 (fourth insulating layer) different in composition from the insulating layer 83 is formed on the insulating layer 83. For instance, the insulating layer 84 is a silicon oxide layer.
Then, a contact hole 51h is formed in the direction (Z-direction) from the insulating layer 84 toward the semiconductor layer 10 by photolithography and RIE (reactive ion etching). The contact hole 51h pierces the insulating layer 84, the insulating layer 83, and the insulating layer 82. The contact hole 51h opens the upper end of the contact electrode 50.
On the other hand, the peripheral section 200 is subjected to the processing described below.
For instance, as shown in
Then, a contact hole 56h is formed in the Z-direction by photolithography and RIE. The contact hole 56h pierces the insulating layer 84, the insulating layer 83, and the insulating layer 82. The contact hole 56h opens the upper end of the contact electrode 55.
Here, in the memory cell section 100 and the peripheral section 200, the formation of the insulating layer 82, the insulating layer 83, and the insulating layer 84 can be simultaneously advanced. Furthermore, the formation of the contact hole 51h and the contact hole 56h can be simultaneously advanced.
The insulating layer 82, 83, 84 is formed by e.g. plasma CVD. The film thickness of the insulating layer 82 is e.g. 95 nm. The film thickness of the insulating layer 83 is e.g. 10 nm. The film thickness of the insulating layer 84 is e.g. 60 nm.
After forming the contact hole 51h, 56h, choline treatment at 70° C. for 5 minutes may be performed to remove natural oxide film at each upper end of the contact electrode 50, 55.
Next, the memory cell section 100 is subjected to the processing described below.
For instance, as shown in
Thus, a contact electrode 51 (first contact electrode) extending in the Z-direction is formed. The sidewall 51w of the contact electrode 51 is surrounded with the insulating layer 82, the insulating layer 83, and the insulating layer 84. The contact electrode 51 is electrically connected to the aforementioned select transistor.
On the other hand, the peripheral section 200 is subjected to the processing described below.
For instance, as shown in
Thus, a contact electrode 56 (second contact electrode) extending in the Z-direction is formed. The sidewall 56w of the contact electrode 56 is surrounded with the insulating layer 82, the insulating layer 83, and the insulating layer 84. The contact electrode 56 is electrically connected to the aforementioned transistor.
Here, in the memory cell section 100 and the peripheral section 200, the formation of the barrier layers 51a, 56a can be simultaneously advanced by sputtering film formation. The film thickness of the barrier layer 51a, 56a is e.g. 6 nm. Furthermore, in the memory cell section 100 and the peripheral section 200, the formation of the conductive layers 51b, 56b can be simultaneously advanced by sputtering film formation.
From the next figure onward, illustration of the structure below the insulating layer 82 is omitted.
Next, the memory cell section 100 is subjected to the processing described below.
For instance, as shown in
On the other hand, the peripheral section 200 is subjected to the processing described below.
For instance, as shown in
Here, the insulating layer 83 functions as a stopper film in CMP processing. Furthermore, in the memory cell section 100 and the peripheral section 200, the CMP processing can be simultaneously advanced. The contact electrodes 51, 56 and the insulating layer 83 are made flush with each other by this CMP processing. That is, the heights of the contact electrodes 51, 56 and the insulating layer 83 are made equal to each other.
Next, the memory cell section 100 is subjected to the processing described below.
For instance, as shown in
On the other hand, the peripheral section 200 is subjected to the processing described below.
For instance, as shown in
Here, in the memory cell section 100 and the peripheral section 200, the formation of the mask layer 95 can be simultaneously advanced.
Next, the memory cell section 100 is subjected to the processing described below.
For instance, as shown in
On the other hand, the peripheral section 200 is subjected to the processing described below.
For instance, as shown in
Here, in the memory cell section 100 and the peripheral section 200, the formation of the trenches 51t, 56t can be simultaneously advanced. Furthermore, each of the trenches 51t, 56t can be extended in a direction crossing the Z-direction.
In etching the contact electrode 56 and the insulating layer 83 opened through the mask layer 95, the contact electrode 56 and the insulating layer 83 can be simultaneously etched using a halogen-containing gas (e.g., Cl, HBr). Furthermore, the trench 56t is formed under a condition selected so that the insulating layer 83 and the contact electrode 56 have the same processing selection ratio.
After forming the trench 51t, 56t, choline treatment at 70° C. for 5 minutes may be performed to remove natural oxide film at each upper end of the contact electrode 51, 56.
Next, the memory cell section 100 is subjected to the processing described below.
For instance, as shown in
On the other hand, the peripheral section 200 is subjected to the processing described below.
For instance, as shown in
Here, in the memory cell section 100 and the peripheral section 200, the formation of the seed layers 52a, 57a can be simultaneously advanced. Each of the seed layers 52a, 57a includes a titanium film (film thickness 8 nm) formed by sputtering film formation, and a copper film formed on the titanium film (film thickness 15 nm). Furthermore, in the memory cell section 100 and the peripheral section 200, the formation of the conductive layers 52b, 57b can be simultaneously advanced by plating technique. After forming the conductive layers 52b, 57b, the conductive layers 52b, 57b may be heated in a nitrogen-based atmosphere containing hydrogen at 150° C. for 30 minutes. This heating treatment decreases defects in the conductive layers 52b, 57b.
Next, the memory cell section 100 is subjected to the processing described below.
For instance, as shown in
On the other hand, the peripheral section 200 is subjected to the processing described below.
For instance, as shown in
Here, in the memory cell section 100 and the peripheral section 200, the removal of the seed layers 52a, 57a, the conductive layers 52b, 57b, and the insulating layer 83 can be simultaneously advanced. Subsequently, the interconnection layers 52, 57 are covered with an insulating layer 90. The insulating layer 90 is e.g. a silicon nitride layer. The film thickness of the insulating layer 90 is e.g. 60 nm.
Here, the removal of the seed layers 52a, 57a, the conductive layers 52b, 57b, and the insulating layer 83 is performed by methods described below.
For instance, as a first method, the seed layers 52a, 57a, the conductive layers 52b, 57b, and the insulating layer 83 are all removed by CMP.
Alternatively, as a second method, the layers above the insulating layer 83 are removed by CMP. Subsequently, the insulating layer 83 is removed by RIE. Then, the surface of the interconnection layer 52 and the surface of the interconnection layer 57 are polished by CMP until the interconnection layer 52 and the interconnection layer 57 reach a desired height.
Alternatively, as a third method, the layers above the insulating layer 83 are removed by CMP. Subsequently, the insulating layer 83 is removed by wet etching. Then, the surface of the interconnection layer 52 and the surface of the interconnection layer 57 are polished by CMP until the interconnection layer 52 and the interconnection layer 57 reach a desired height.
By such processes, the heights of the interconnection layers 52, 57 do not depend on the pattern width, but are made equal to each other.
In the memory cell section 100,
In the reference example, the insulating layers 83, 84 are not provided on the insulating layer 82, but a contact electrode is previously formed in the insulating layer 82.
For instance, in the memory cell section 100, as shown in
On the other hand, the peripheral section 200 is subjected to the processing described below.
For instance, as shown in
Next, the memory cell section 100 is subjected to the processing described below.
For instance, as shown in
On the other hand, the peripheral section 200 is subjected to the processing described below.
For instance, as shown in
Next, the memory cell section 100 is subjected to the processing described below.
For instance, as shown in
On the other hand, the peripheral section 200 is subjected to the processing described below.
For instance, as shown in
Here, the mask layer 95 is formed by photolithography and RIE. At this time, the insulating layer 83 functions as a stopper film for suppressing the loading effect during etching. The depths of the opening of the mask layer 95 in the memory cell section 100 and the peripheral section 200 are made equal to each other by the presence of this stopper film.
Next, the memory cell section 100 is subjected to the processing described below.
For instance, as shown in
On the other hand, the peripheral section 200 is subjected to the processing described below.
For instance, as shown in
Next, the memory cell section 100 is subjected to the processing described below.
For instance, as shown in
On the other hand, the peripheral section 200 is subjected to the processing described below.
For instance, as shown in
Next, the memory cell section 100 is subjected to the processing described below.
For instance, as shown in
On the other hand, the peripheral section 200 is subjected to the processing described below.
For instance, as shown in
In the manufacturing process shown in the reference example, in the stage shown in
Thus, in the structure shown in
In contrast, in the first embodiment, the insulating layer 83 is not in contact with the interconnection layer 52, 57. In the first embodiment, the insulating layer 83 is not used as a layer for suppressing the loading effect during etching, but used as a stopper film in CMP processing shown in
Thus, in the first embodiment, parasitic capacitance near the interconnection layer 52, 57 is lower than that in the reference example. This suppresses delay of interconnection signal speed. Furthermore, in the first embodiment, because there is no insulating layer 83, there is no problem of the delay of interconnection signal speed even if the pitch between interconnection layers becomes smaller.
According to the second embodiment, even if the aforementioned misalignment occurs, the contact electrode 51 formed in the contact hole 51h can be reliably made continuous with the contact electrode 50.
First, as shown in
Next, as shown in
Next, as shown in
Thus, the inner wall of the contact hole 51h at the position of the insulating layer 81 has a curved surface. That is, after the selective etching, the width (width in the X-direction and the Y-direction) of the contact hole 51h at the position of the insulating layer 81 is selectively expanded.
Furthermore, the formation of such a contact hole 51h reliably exposes the upper end of the contact electrode 50 at the bottom of the contact hole 51h.
Next, as shown in
As shown in
Thus, according to the second embodiment, even if there is a misalignment between the contact hole 51h and the contact electrode 50, the contact electrode 51 formed in the contact hole 51h can be reliably made continuous with the contact electrode 50 by selectively expanding the width of the lower part of the contact hole 51h.
In the embodiments described above, “above” expressed in “A portion A is provided above a portion B” may be used as the case where the portion A does not contact the portion B and the portion A is provided upward the portion B other than the case where the portion A contacts the portion B and the portion is provided on the portion B. “The portion A is provided above the portion B” may be applied to the case where the portion A and the portion B are reversed and the portion A is placed below the portion B or the case where the portion A is placed beside the portion B. This is because the structure of the semiconductor device does not change before and after the rotation even if the semiconductor device according to the embodiment is rotated.
Although the embodiments are described above with reference to the specific examples, the embodiments are not limited to these specific examples. That is, design modification appropriately made by a person skilled in the art in regard to the embodiments is within the scope of the embodiments to the extent that the features of the embodiments are included. Components and the disposition, the material, the condition, the shape, and the size or the like included in the specific examples are not limited to illustrations and can be changed appropriately.
The components included in the embodiments can be combined to the extent of technical feasibility and the combinations are included in the scope of the embodiments to the extent that the feature of the embodiments is included. Various other variations and modifications can be conceived by those skilled in the art within the spirit of the invention, and it is understood that such variations and modifications are also encompassed within the scope of the invention.
While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the inventions. Indeed, the novel embodiments described herein may be embodied in a variety of other forms; furthermore, various omissions, substitutions and changes in the form of the embodiments described herein may be made without departing from the spirit of the inventions. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the invention.
This application is based upon and claims the benefit of priority from U.S. Provisional Patent Application 61/873,159, filed on Sep. 3, 2013; the entire contents of which are incorporated herein by reference.
Number | Date | Country | |
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61873159 | Sep 2013 | US |