This application claims the priority benefit of Taiwan application serial no. 103100832, filed on Jan. 9, 2014. The entirety of the above-mentioned patent application is hereby incorporated by reference herein and made a part of this specification.
1. Field of the Invention
The invention is related to a semiconductor device and a method of fabricating the same, and more particularly, to a memory and a method of fabricating the same.
2. Description of Related Art
In general, with the decrease in size of the memory, a self-aligned contact (SAC) process is applied to overcome the increasingly shrinking wire width and to avoid misalignment of contacts.
However, how to effectively integrate the SAC process in the memory cell region and the metal silicide process in the peripheral circuit region has become an urgent topic that needs to be solved.
The invention provides a method of fabricating a semiconductor device. The method can integrate a SAC process and a self-aligned metal silicide process and fabricate a semiconductor device having a metal silicide layer in the peripheral circuit region.
The method of fabricating a semiconductor device of the invention includes the following steps. A substrate having a first region and a second region is provided, wherein a plurality of stacked gate structures are formed on the substrate of the first region, each stacked gate structure includes a tunneling dielectric layer, a charge storage layer, an inter-gate dielectric layer, and a control gate, a gap exists between two adjacent stacked gate structures, and at least one gate structure is formed on the substrate of the second region. A liner layer is conformally formed on the substrate. A dielectric layer covering the liner layer is formed in the second region. A metal silicide layer is formed on the top portion of the gate structure and on the substrate on both sides of the gate structure. A contact process is performed to form a plurality of contacts connected to the metal silicide layer.
In an embodiment of the invention, the liner layer includes a multilayer structure of a silicon oxide layer/a silicon nitride layer/a silicon oxide layer (ONO).
In an embodiment of the invention, the following steps are further included before the metal silicide layer is formed on the top portion of the gate structure and on the substrate on both sides of the gate structure. A portion of each of the dielectric layer and the liner layer is removed to form a spacer and a plurality of openings on the substrate.
The semiconductor device of the invention includes a substrate, a plurality of stacked gate structures, a liner layer, at least one gate structure, a metal silicide layer, and a plurality of contacts. The substrate has a first region and a second region. The stacked gate structures are disposed on the substrate of the first region, wherein each stacked gate structure includes a tunneling dielectric layer, a charge storage layer, a blocking dielectric layer, and a control gate, and a gap exists between two adjacent stacked gate structures. The liner layer is disposed on the sidewall of each stacked gate structure. The gate structure is disposed on the substrate of the second region. The metal silicide layer is disposed on the top portion of the gate structure and on the substrate on both sides of the gate structure. The contacts are connected to the metal silicide layer.
In an embodiment of the invention, the liner layer includes a multilayer structure of a silicon oxide layer/a silicon nitride layer/a silicon oxide layer (ONO).
In an embodiment of the invention, the semiconductor device further includes an interlayer dielectric layer disposed on the substrate of the second region and covering the gate structure, wherein the interlayer dielectric layer has a plurality of contact holes therein.
The semiconductor device of the invention includes a substrate, a plurality of first gate structures, a liner layer, at least one second gate structure, and a plurality of contacts. The substrate has a first region and a second region. The first gate structures are disposed on the substrate of the first region, wherein each first gate structure includes a tunneling dielectric layer, a charge storage layer, an inter-gate dielectric layer, and a control gate, and a gap exists between two adjacent stacked gate structures. The liner layer is disposed on the sidewall of each first gate structure. The second gate structure is disposed on the substrate of the second region. The contacts are connected to the top portion of the second gate structure and the substrate on both sides of the second gate structure.
In an embodiment of the invention, the semiconductor device further includes a metal silicide layer disposed on the top portion of the second gate structure and on the substrate on both sides of the second gate structure.
In an embodiment of the invention, the control gate of the first gate structure located at the junction of the first region and the second region has a stepped shape.
In an embodiment of the invention, the liner layer includes a multilayer structure of a silicon oxide layer/a silicon nitride layer/a silicon oxide layer (ONO).
Based on the above, the method of fabricating a semiconductor device provided by the invention can integrate a SAC process and a self-aligned metal silicide process to fabricate a semiconductor device having a SAC in the first region and a metal silicide layer in the second region.
In order to make the aforementioned features and advantages of the disclosure more comprehensible, embodiments accompanied with figures are described in detail below.
The accompanying drawings are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification. The drawings illustrate embodiments of the invention and, together with the description, serve to explain the principles of the invention.
Referring to
A plurality of stacked gate structures 110 are formed on the substrate 100 of the first region 101, wherein a gap 111 exists between two adjacent stacked gate structures 110. A plurality of doped regions 112 are formed in the substrate 100 of the first region 101, wherein each doped region 112 is located between two adjacent stacked gate structures 110. A gate dielectric material layer 107 and a conductive material layer 108 are formed on the substrate 100 of the second region 102. Moreover, a hard mask layer 113 is formed on the substrate 100, wherein a portion of the hard mask layer 113 is located on the stacked gate structures 110 and another portion of the hard mask layer 113 is located on the conductive material layer 108.
The stacked gate structures 110 can be gate structures of a non-volatile memory device, such as gate structures of a flash memory device. In the present embodiment, each stacked gate structure 110 includes a tunneling dielectric layer 103, a conductive layer 104, a blocking dielectric layer 105, and a conductive layer 106 stacked on the substrate 100 in order. The material of the tunneling dielectric layer 103 is, for instance, silicon oxide. The conductive layer 104 can be used as a charge storage layer, and the charge storage layer can be a floating gate or a charge trapping layer. In the case that the charge storage layer is a floating gate, the material thereof is, for instance, doped polysilicon; and in the case that the charge storage layer is a charge trapping layer, the material thereof is, for instance, silicon nitride. The blocking dielectric layer 105 is, for instance, a multilayer structure of a silicon oxide layer/a silicon nitride layer/a silicon oxide layer (ONO). In the case that the charge storage layer is a floating gate, the blocking dielectric layer 105 can be used as an inter-gate dielectric layer. The conductive layer 106 can be used as a control gate, and the material thereof is, for instance, doped polysilicon. The material of the gate dielectric material layer 107 is, for instance, silicon oxide. The material of the conductive material layer 108 is, for instance, doped polysilicon. The material of the hard mask layer 113 is, for instance, silicon oxide or silicon nitride.
The method of forming the stacked gate structures 110, the gate dielectric material layer 107, and the conductive material layer 108 includes, for instance, sequentially performing a deposition process and a patterning process on the substrate 100 of the first region 101 and the second region 102. The method of forming the doped regions 112 includes, for instance, performing an ion implantation process by using the hard mask layer 113 and the stacked gate structures 110 as a mask.
It should be mentioned that, the conductive layer 106 in the first region 101 and the conductive material layer 108 in the second region 102 are formed by the same material layer. Therefore, after the patterning process is performed, the conductive layer 106 (shown by border A) of the stacked gate structures 110 located at the junction of the first region 101 and the second region 102 has a stepped shape. In other words, the conductive layer 106 (shown by border A) is extended toward the second region 102 and is in contact with the substrate 100.
Referring to
Referring to
In
Then, after the gate structure 118 is formed, an ion implantation step is performed to form a plurality of shallow doped regions 117 in the substrate 100 on both sides of the gate structure 118.
Referring to
Then, the sacrificial layer 124 filling the gap 111 is formed in the first region 101. The material of the sacrificial layer 124 is, for instance, polysilicon. The method of forming the sacrificial layer 124 includes the following steps. First, a sacrificial material layer (not shown) is conformally formed on the substrate 100. Then, a patterned photoresist layer (not shown) is formed on the sacrificial material layer. Then, a dry etching process is performed by using the patterned photoresist layer as a mask to remove the sacrificial material layer not covered by the patterned photoresist layer. Then, the patterned photoresist layer is removed. Specifically, since the liner layer 119 has a high etch selection ratio toward the sacrificial layer 124, when the dry etching process is performed to remove the sacrificial material layer not covered by the patterned photoresist layer, the sacrificial material layer in the second region 102 can be effectively removed.
Referring to
Referring to
Then, using the spacer 126 as a mask again, an ion implantation step is performed to form a plurality of doped regions 128 in the exposed substrate 100 in the openings 127. Moreover, in the step of forming the doped regions 128, an ion implantation step can be performed on the gates (i.e., the conductive layer 116) of the exposed gate structure 118.
Referring to
Moreover, since the anti-etch characteristics of the nitride layer 131 in the wet etching process is higher than the anti-etch characteristics of the nitride layer 129 in the wet etching process, a wet etching process can be used to remove the oxide material layer not covered by the nitride layer 131. Moreover, in the present embodiment, the dielectric layer 130 can be used as a self-aligned salicide block layer (SAB) or used as a film layer of resistive protection oxide layer (RPO).
Referring to
Referring to
Then, an interlayer dielectric layer (ILD) 136 is formed on the substrate 100 to at least cover the etch stop layer 134 in the second region 102. The material of the interlayer dielectric layer 136 is, for instance, silicon oxide. The method of forming the interlayer dielectric layer 136 includes the following steps. First, a dielectric material layer (not shown) completely covering the first region 101 and the second region 102 is formed on the substrate 100. Then, using the etch stop layer 134 in the first region 101 as a stop layer, a planarization process is performed on the dielectric material layer to obtain the interlayer dielectric layer 136, wherein the top surface of the interlayer dielectric layer 136 and the top surface of the etch stop layer 134 are substantially located on the same plane. The planarization process is, for instance, a chemical mechanical polishing process.
Referring to
Moreover, in the present embodiment, when the patterned etch stop layer 134a, the patterned dielectric layer 130a, the patterned sacrificial layer 124a, and the openings 133 are formed, since the liner layer 119 has a high etch selection ratio toward the sacrificial layer 124, better etching conditions can be used to remove the portion of the sacrificial layer 124 to obtain openings 133 having good vertical profile.
Referring to
Moreover, since the patterned etch stop layer 134a, the patterned dielectric layer 130a, and the patterned sacrificial layer 124a correspond to the locations of contact holes to be formed in a subsequent process, the isolation layers 138 can be used to isolate each contact hole and can be used as a mask layer defining the contact holes in a subsequent process.
Referring to
Moreover, in the present embodiment, the portion of the liner layer 119 which is removed includes the liner layer 119 located on the doped regions 112 and the liner layer 119 located above the stacked gate structures 110 and not covered by the isolation layers 138. Therefore, in the first region 101, a portion of the liner layer 119 is located on the sidewall of each stacked gate structure 110, and another portion of the liner layer 119 is located above the stacked gate structures 110. However, the invention is not limited thereto. In other embodiments, the isolation layers 138 may completely cover the liner layer 119 located above the stacked gate structures 110, and therefore the liner layer 119 located above the stacked gate structures 110 is not removed.
Moreover, after the portion of the patterned etch stop layer 134a, the portion of the patterned dielectric layer 130a, the patterned sacrificial layer 124a, and the portion of the liner layer 119 are removed, a hole 135 is formed between two adjacent isolation layers 138, and the gap 111 and the hole 135 between two adjacent liner layers 119 form a contact hole 137.
Moreover, since the liner layer 119 has a high etch selection ratio toward the patterned sacrificial layer 124a, better etching conditions can be used to remove the patterned sacrificial layer 124a to obtain contact holes 137 having good vertical profile. Therefore, when the patterned sacrificial layer 124a is removed to form the contact holes 137, even in the case of an alignment error, the liner layer 119 located on the sidewall of each stacked gate structure 110 can prevent damage to the stacked gate structures 110.
Referring to
However, in the present embodiment, since the patterned etch stop layer 134a completely covers the substrate 100 of the second region 102, a dry etching process can first be performed on the interlayer dielectric layer 136 by using the patterned etch stop layer 134a as a stop layer, and then performing etching on the patterned etch stop layer 134a to form the contact holes 139.
Referring to
Moreover, in the present embodiment, the contacts 140 include a first portion 140a located in the gaps 111 and a second portion 140b located in the holes 135, and the width Wb of the second portion 140b is greater than the width Wa of the first portion 140a. However, the invention is not limited thereto. In other embodiments, the width Wb of the second portion 140b can be controlled by adjusting the size of the isolation layers 138.
Moreover, in the present embodiment, since the liner layer 119 has a high etch selection ratio toward the patterned sacrificial layer 124a, the liner layer 119 on the sidewall of each stacked gate structure 110 can maintain an intact structure. In this way, the liner layer 119 on the sidewall of each stacked gate structure 110 can prevent the issue of leakage current between the conductive layer 104 of each stacked gate structure 110 and the contacts 140, and provide good electric insulation to the stacked gate structures 110.
Based on the embodiments above, it can be known that the method of fabricating a semiconductor device provided by the invention can integrate a SAC process and a self-aligned metal silicide process such that when a contact is formed in the first region, a metal silicide layer can also be formed in the second region.
Moreover, the semiconductor device 10 provided by the invention can be completed through the embodiments above. Then, in the following, the structure of the semiconductor device 10 provided by an embodiment of the invention is described with reference to
First, referring further to
Moreover, in the semiconductor device 10, a metal silicide layer 132 is further included on the top portion of the gate structure 118 and on the substrate 100 on both sides of the gate structure 118. The liner layer 119 further includes a multilayer structure of a silicon oxide layer 120/a silicon nitride layer 121/a silicon oxide layer 122. Moreover, the semiconductor device 10 further includes an isolation layer 138 disposed on the stacked gate structures 110 and a hole 135 exists between two adjacent isolation layers 138. The semiconductor device 10 further includes a barrier layer 141 disposed on the surface of contact holes 137. The semiconductor device 10 further includes an interlayer dielectric layer 136 disposed on the substrate 100 of the second region 102 and covering the gate structure 118. The interlayer dielectric layer 136 has contact holes 139 therein. The semiconductor device 10 further includes a barrier layer 143 disposed on the surface of the contact holes 139. The semiconductor device 10 further includes a hard mask layer 114 disposed on the conductive layer 106 of each of the stacked gate structures 110. Moreover, the material, the forming method, and the efficacy of each member in the semiconductor device 10 are described in detail in the embodiments above and are not repeated herein.
Based on the above, the method of fabricating a semiconductor device provided by the embodiments above can integrate a SAC process and a self-aligned metal silicide process to fabricate a semiconductor device having a contact in the first region and having a metal silicide layer in the second region. Moreover, when the semiconductor device has a metal silicide layer, the metal silicide layer can reduce the resistance of the device and increase conductivity. Moreover, when the liner layer is a multilayer structure of a silicon oxide layer/a silicon nitride layer/a silicon oxide layer, the liner layer on the sidewall of each stacked gate structure can prevent the issue of leakage current between a floating gate and a contact, and can provide good electric insulation to the stacked gate structures to ensure the quality of the semiconductor device.
Although the invention has been described with reference to the above embodiments, it will be apparent to one of the ordinary skill in the art that modifications to the described embodiments may be made without departing from the spirit of the invention. Accordingly, the scope of the invention is defined by the attached claims not by the above detailed descriptions.
Number | Date | Country | Kind |
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103100832 | Jan 2014 | TW | national |