The present application claims priority from Japanese patent application No. 2005-184295 filed on Jun. 24, 2005, the content of which is hereby incorporated by reference into this application.
The present invention relates to a semiconductor device which has SOI (Silicon-On-Insulator) structure, and its manufacturing method.
The SOI device using an SOI substrate which stacks a supporting substrate, an insulator layer, and a silicon layer (SOI layer) in layers attracts attention as a device which can improve the performance of a semiconductor device in recent years. For example, a MOS (Metal-Oxide Semiconductor) transistor formed in the SOI substrate has the small parasitic capacitance of the source and drain regions, and operation of a high speed and low power is possible for it.
Improvement in performance of a MOS transistor formed in a silicon substrate of a bulk also being achieved on the other hand, for example, implanting two kinds of impurity ion in formation of the source and drain regions of a MOS transistor is proposed in following Patent References 1-5.
[Patent Reference 1] Japanese Unexamined Patent Publication No. Hei 10-56171
[Patent Reference 2] Japanese Unexamined Patent Publication No. 2000-232221
[Patent Reference 3] Japanese Unexamined Patent Publication No. 2004-281693
[Patent Reference 4] Japanese Unexamined Patent Publication No. Hei 9-260649
[Patent Reference 5] Japanese Unexamined Patent Publication No. 2003-31798
As trench isolation which separates between each element, such as a transistor, in an SOI device, there are full trench isolation (FTI: Full Trench Isolation) which separates an SOI layer thoroughly, and partial trench isolation (PTI: Partial Trench Isolation) formed only in the upper part of an SOI layer.
Especially, in the device structure having PTI, the electric potential of the well (called a “body”) in which a transistor was formed can be controlled through the SOI layer which remains under PTI. Therefore, it is not necessary to form the terminal for controlling body electric potential in the same active region as the transistor, and increase of the parasitic capacitance of the transistor can be prevented. Body electric potential may be dynamically controlled depending on the application of a transistor, although usually fixed to a certain value for the operational stabilization of the transistor.
In order to reduce the parasitic capacitance of the transistor further, it is tended to make an SOI layer further thin, and it will be also needed to make PTI thin according to it. When PTI becomes thin, we will be anxious about the impurity ion concerned penetrating through PTI and reaching even the SOI layer under it in the case of implantation of the impurity ion for forming the source and drain regions of the transistor. When impurity ion penetrates through PTI and an impurity layer of the same conductivity type as the source and drain regions is formed in the SOI layer under PTI, the element isolation function of PTI will be spoiled and it will become a problem.
Therefore, when PTI is thin, it is necessary to perform impurity ion implantation for source and drain region formation with extremely low energy. Therefore, source and drain regions will be formed more shallowly than a conventional device, and the impurity concentration profile will become what has only a high surface portion.
In that case, when the region upper part concerned is made silicide for the purpose of the resistance reduction of the source and drain regions, the surface portion with high impurity concentration will be made silicide. That is, the impurity concentration in the boundary face of the formed silicide layer and the source and drain regions will become low. As a result, the connection resistance of the silicide layer and the source and drain regions becomes high, and the problem of it becoming impossible to aim at resistance reduction of the source and drain regions which is the original purpose of silicide formation occurs.
Since the source and drain regions are shallow, the distance of the pn junction surface in the bottom and the silicide layer becomes near. Thereby, the junction capacitance in the source and drain regions becomes large, and the problem that leakage current will increase occurs.
The present invention is made in order to solve the above problems, and aims at offering a semiconductor device in which the resistance reduction of the source drain of the transistor and reduction of leakage current are possible while aiming at thickness reduction of an SOI layer in the semiconductor device which has PTI structure as an isolation between elements formed in an SOI substrate.
A semiconductor device concerning the present invention comprises: a semiconductor layer formed over an insulator layer; an isolation insulating layer which is formed in the semiconductor layer and specifies an active region in the semiconductor layer concerned; a transistor which has source and drain regions formed in the active region; and a silicide layer formed in the source and drain region upper part of the transistor; wherein the isolation insulating layer has a portion which does not reach the insulator layer; and the source and drain regions include a first and a second impurity ions with which mass numbers differ mutually.
A method of manufacturing a semiconductor device concerning the present invention comprises the steps of: (a) forming an isolation insulating layer which specifies an active region in a semiconductor layer to the semiconductor layer concerned formed over an insulator layer; (b) forming a gate electrode of a transistor in the active region; (c) forming source and drain regions of the transistor in the active region by implanting a first impurity ion with a comparatively small mass number, and a second impurity ion with a comparatively large mass number in an order of a small mass number; (d) diffusing the first and the second impurity ions of the source and drain regions by heat treatment; and (e) forming a silicide layer in the source and drain region upper part; wherein in the step (a), the isolation insulating layer is formed so that at least a portion may not reach even the insulator layer; and implantation conditions of the first and the second impurity ions in the step (c) is set up so that a concentration of the first impurity ion may become more than a concentration of the second impurity ion in a boundary face of the silicide layer and the source and drain regions after the step (d) and (e).
According to the semiconductor device concerning the present invention, since source drain regions include the first and the second impurity ions with which mass numbers differ mutually, the source and drain regions come to have an impurity concentration profile gradual and at high concentration, and a deep profile. That is, impurity concentration in the depth of a boundary face with a silicide layer in the source and drain regions can be made high, and the distance of the pn junction surface of the source and drain region bottom and the silicide layer can be detached. Therefore, resistance reduction between silicide layer-source and drain regions can be aimed at, and it is possible to reduce the leakage current by the junction capacitance of the source and drain regions.
According to the manufacturing method of the semiconductor device concerning the present invention, since the concentration of the first impurity ion becomes more than the concentration of the second impurity ion in the boundary face of a silicide layer and source and drain regions after a heat treatment, the impurity concentration of the boundary face concerned becomes high and resistance reduction between silicide layer-source and drain regions can be aimed at. Since the first and the second impurity ions are implanted in an order of a small mass number, the first impurity ion can be more deeply implanted with low energy by channeling. Therefore, since the source and drain regions can be formed by a deep profile, the distance of the pn junction surface of the source and drain region bottom and the silicide layer can be detached, and the leakage current by the junction capacitance of the source and drain regions can be reduced.
The semiconductor device concerning this embodiment has MOS transistor 10, and cell 30 for body electric-potential fixation which is a terminal (body terminal) for setting up the body electric potential on SOI substrate 100 like
With reference to
MOS transistor 10 is formed in the active region specified by isolation insulating layer 5 in SOI layer 3. MOS transistor 10 has gate insulating film 11 formed on SOI layer 3, and gate electrode 12 formed on the gate insulating film 11 concerned. Silicide layer 12a is formed in the upper part of gate electrode 12, and spacer oxide film 13, sidewall oxide film 14, and sidewall nitride film 15 are formed on the both side surfaces of gate electrode 12, respectively. MOS transistor 10 has source and drain regions 17 and extension region 16 in SOI layer 3, and silicide layer 17a is formed in the upper part of source and drain regions 17.
When MOS transistor 10 is an nMOS transistor, the extension region 16 and source and drain regions 17 are n type regions, and body region 18 is a p type region. With reference to
On SOI layer 3, interlayer insulating film 21 is formed so that MOS transistor 10 and cell 30 for body electric-potential fixation may be covered. Contacts 22, 24, and 32 are formed in interlayer insulating film 21, and it has connected with wirings 23, 25, and 33 formed on interlayer insulating film 21, respectively. Like
In this embodiment, source and drain regions 17 of MOS transistor 10 include two sorts of n type impurity ion with which mass numbers differ mutually. More concretely, it includes a phosphorus (P) ion as the first impurity ion with a comparatively small mass number, and an arsenic (As) ion as the second impurity ion with a comparatively large mass number.
Since the mass number is comparatively small, P ion has long range, and it tends to cause channeling. Therefore, since it is deeply implanted even with low energy, it is difficult to form the high-concentration source and drain regions. Since As ion has short range since the mass number is comparatively large, and it is hard to cause channeling, source and drain regions can be formed with high concentration and shallowly easily. Therefore, since SOI layer thickness became thin (for example, about 100 nm or less), when PTI was made thin, P ion was not usually used for formation of source and drain regions, but As ion was used.
However, in the source and drain regions formed only with As ion, since As ion hardly diffuses in annealing for activation of an impurity, only the surface portion of source and drain regions will become high concentration as a result. Therefore, as stated previously, when the upper part of the source and drain regions is made silicide, a problem that the impurity concentration in the boundary face of the silicide layer and the source and drain regions becomes low, and the connection resistance of the silicide layer and the source and drain regions concerned will become high, and a problem that leakage current will increase when the distance of the pn junction surface of the source and drain region bottom and the silicide layer becomes near had occurred.
Since source and drain regions 17 include two, P ion and As ion with which mass numbers differ mutually, according to this embodiment, the high-concentration impurity concentration profile which was difficult only with P ion is realizable. Since it is easy to make thermal diffusion of the P ion by heat treatment, the gradual impurity concentration profile and the deep profile which were difficult only with conventional As ion are realizable. That is, according to this embodiment, impurity concentration in the depth (the depth of about 50 nm from the surface of SOI layer 3) of the boundary face with silicide layer 17a in source and drain regions 17 can be made high, and the distance of the pn junction surface of source and drain region 17 bottom and silicide layer 17a can be detached. Therefore, resistance reduction between silicide layer 17a-source and drain regions 17 can be aimed at, and it is possible to reduce the leakage current by the junction capacitance of source and drain regions 17.
That is, avoiding the two above-mentioned problems of the resistance increase between silicide layer 17a-source and drain regions 17, and increase of leakage current, the parasitic capacitance of MOS transistor 10 can be reduced further, and it can contribute to speeding up and lowering of power consumption of a semiconductor device greatly. In the conventional MOS transistor, when SOI layer thickness became thin to about 100 nm or less, the two above-mentioned problems had the tendency to become remarkable. Therefore, in this embodiment, it can be said that application in the thin SOI layer of 100 nm or less is especially effective.
Since pn junction will not be formed in the bottom concerned when diffusing source and drain regions 17 especially like
Next, with reference to process drawings shown in
First, an SOI substrate stacking supporting substrate 1, BOX layer 2, and SOI layer 3 in layers is prepared. The thickness of SOI layer 3 is about 30 nm-200 nm, for example. And on SOI layer 3, silicon oxide film 51 and silicon nitride film 52 are formed one by one, a resist layer is applied to the whole surface after that, and resist pattern 53 is formed with a photoengraving process technology (photo lithography technology) (
And trench 54 for forming isolation insulating layer 5 is formed by etching silicon nitride film 52, silicon oxide film 51, and SOI layer 3 by using resist pattern 53 as a mask. Since isolation insulating layer 5 is PTI, etched depth at this time is made into extent with which SOI layer 3 remains under trench 54 (
Even if it is the case that SOI layer 3 is thin, when making trench 54 deep, the thickness of isolation insulating layer 5 can be earned to some extent. However, since SOI layer 3 under isolation insulating layer 5 functions as a wiring for applying the electric potential of cell 30 for body electric-potential fixation to body region 18 as shown in
Then, the inner wall of trench 54 is oxidized and silicon oxide film 4 of about 5 nm-50 nm of thickness is formed (when silicon oxide film 4 is unnecessary on the surface of isolation insulating layer 5, it is not necessary to perform this process step). And silicon oxide film 55 is formed in the whole surface so that trench 54 may be buried (
Isolation insulating layer 5 is formed by removing silicon oxide film 55 by the CMP method to extent to which silicon nitride film 52 appears in the upper surface, and etching removes silicon nitride film 52 after that. And after performing the ion implantation for well formation, silicon oxide film 51 is removed (
And thin silicon oxide film 56 is formed in the SOI layer 3 upper surface, and polysilicon film 57 is deposited on it (
Then, sidewall oxide film 14 and sidewall nitride film 15 are formed on the side face of gate electrode 12 by forming a silicon oxide film and a silicon nitride film in the whole surface one by one, and etching back them. And by an ion implantation, source and drain regions 17 which are n+ regions are formed (
As mentioned above, source and drain regions 17 of this embodiment include P ion and As ion which are the impurity ion with which mass numbers differ mutually. Especially by this embodiment, P ion (first impurity ion) and As ion (second impurity ion) are implanted sequentially from the one where a mass number is smaller. That is, P ion is implanted first. At this time, the implantation energy of the grade that P ion does not degrade the isolation characteristics of isolation insulating layer 5 by penetrating through isolation insulating layer 5 is chosen. Subsequently, As ion is implanted. Also at this time, the implantation energy of the grade that the As ion concerned does not degrade the isolation characteristics of isolation insulating layer 5 by penetrating through isolation insulating layer 5 is chosen.
P ion with a small mass number is previously implanted as order of implantation in order to make channeling cause in the case of the implantation and to implant P ion into SOI layer 3 more deeply with low energy. That is, when As ion is implanted in large quantities previously, SOI layer 3 will become amorphous. Since it becomes difficult to generate channeling even if P ion is implanted after that, it is not desirable.
Although the forming step (
Therefore, it is necessary to perform implantation of P ion perpendicularly to the upper surface of SOI layer 3 so that the direction of implantation may go along the crystal orientation of SOI layer 3. P ion can be implanted into the active region of SOI layer 3 deeply, preventing penetrating through isolation insulating layer 5 by implanting P ion so that channeling may happen in SOI layer 3, since channeling is not generated within isolation insulating layer 5.
Here, in order to prevent the penetration through isolation insulating layer 5 of P ion and As ion, the one where isolation insulating layer 5 is thicker is desirable. However, in order that it is necessary to secure the moderate thickness (for example, about 30 nm or more) of SOI layer 3 under isolation insulating layer 5, there is a limitation in forming isolation insulating layer 5 deeply. Then, like
Annealing for activating P ion and As ion which were implanted is performed after formation of source and drain regions 17. This annealing is effective in diffusing P ion and As ion in source and drain regions 17. Since P ion which is easy to diffuse with heat is implanted into source and drain regions 17 of this embodiment, source and drain regions 17 diffuse until they reach BOX layer 2 (
Then, silicide layers 12a and 17a are formed in the upper part of gate electrode 12 and source and drain regions 17, respectively by making metal, such as cobalt and nickel, accumulate and react on MOS transistor 10 (
And after removing the unreacted metal, interlayer insulating film 21 is formed by a silicon oxide film, and CMP performs flattening of the upper surface. And a contact hole is formed in interlayer insulating film 21 using a photo lithography technology, and contacts 22, 24, and 32 are formed by embedding metal, such as tungsten, in it. Finally, by depositing wiring materials, such as copper, on interlayer insulating film 21 and forming wirings 23, 25, and 33 by patterning with a photo lithography technology, MOS transistor 10 shown in
The impurity concentration profile of source and drain regions 17 in a conventional semiconductor device is shown in
Since P ion and As ion are implanted into source and drain regions 17 in this embodiment to it, the impurity concentration (sum of P ion concentration and As ion concentration) in the boundary face of silicide layer 17a and source and drain regions 17 becomes high. Therefore, the connection resistance between silicide layer 17a-source and drain regions 17 can be suppressed low.
Since source and drain regions 17 include P ion which is easy to make thermal diffusion, source and drain regions 17 can be made into a profile deeper than before by annealing. As a result, the distance of the pn junction surface of source and drain region 17 bottom and silicide layer 17a separates, and it becomes possible to reduce the leakage current resulting from the junction capacitance of source and drain regions 17. Since pn junction will not be formed in the bottom of source and drain regions 17 especially when making diffusion of P ion reach even BOX layer 2 like
The present inventor etc. conducted the experiment which measures the impurity concentration profile in the source and drain regions of the actually formed MOS transistor, in order to define the conditions from which the effect of this invention is acquired better.
Although the present invention is turned to the semiconductor device which has PTI, the whole isolation insulating layer 5 which specifies the active region of MOS transistor 10 as shown in
In this modification, like
In the above explanation, although MOS transistor 10 was explained as an nMOS transistor, the present invention is applicable also to a pMOS transistor. What is necessary is just to adopt two sorts from which a mass number differs mutually as ion for forming source and drain regions 17 also in the case. It is desirable to implant sequentially from what has a small mass number in the case of formation of source and drain regions 17, in order to make channeling cause. It is possible to adopt B (boron) ion as first ion with a comparatively small mass number, and to adopt BF2 (boron fluoride) or In (indium) ion as second ion with a comparatively large mass number concretely.
In order to prevent degradation of the isolation characteristics, it is necessary to make the impurity ion implanted in the case of source and drain region 17 formation not penetrate through isolation insulating layer 5, when PTI is adopted as isolation insulating layer 5, as stated previously. In order to suppress this penetration, it is possible to thicken isolation insulating layer 5, but since SOI layer 3 under the isolation insulating layer 5 concerned needs to secure moderate thickness, there is a limitation in forming isolation insulating layer 5 deeply. Then, it is possible to make high the height (height h shown in
Thus, when the thickness reduction of SOI layer 3 progresses, it will become difficult to form isolation insulating layer 5 thickly. As a result, it will be necessary to set up very small the energy in implantation of the impurity ion for source and drain region 17 formation, and the margin will become small. Therefore, it becomes difficult to form source and drain regions 17 with sufficient accuracy, preventing the penetration through isolation insulating layer 5 of impurity ion. The technology for solving this problem is proposed in this embodiment.
In Embodiment 1 shown previously, sidewall oxide film 14 and sidewall nitride film 15 of a side face of gate electrode 12 were formed by forming the silicon oxide film used as sidewall oxide film 14 and the silicon nitride film used as sidewall nitride film 15 on the entire substrate one by one, and etching back them. In Embodiment 1, like
To it, in the above-mentioned etch back process, as shown in
Therefore, the thickness of isolation insulating layer 5 in the ion-implantation step for source and drain region 17 formation becomes thick only the part of the thickness of silicon oxide film 114 substantially. Therefore, it becomes difficult to generate that the implanted impurity ion penetrates through isolation insulating layer 5, and the margin of the energy of the impurity ion implantation concerned becomes large. Therefore, even when isolation insulating layer 5 is thin, formation of the semiconductor device concerning the present invention can be made easy, and it can contribute also to the thickness reduction of an SOI layer in an SOI device.
As Embodiment 1 explained using
In this embodiment, it is good to perform annealing (it corresponds to the step of the
When there is no need of suppressing the out-diffusion of source and drain regions 17, annealing may be performed after removing silicon oxide film 114 of the source and drain region 17 upper surface.
When forming silicide layers 12a and 17a on the upper part of gate electrode 12 and source and drain regions 17, respectively, since it is necessary to deposit metal directly on gate electrode 12 and source and drain regions 17, in the case, it is needed to remove silicon oxide film 114 on gate electrode 12 and source and drain regions 17 by etching.
Except the step explained above, it is good to be the same as that of the manufacturing method in Embodiment 1.
In above-mentioned Embodiment 2, substantial thickness of isolation insulating layer 5 in the ion-implantation step for source and drain region 17 formation was thickened by using silicon oxide film 114 used as sidewall oxide film 14.
In Embodiment 3, spacer oxide film 13 and sidewall oxide film 14 are formed like Embodiment 1. That is, the forming portions of the source and drain regions 17 concerned in SOI layer 3 are exposed in the case of formation of spacer oxide film 13 and sidewall oxide film 14. And after that, silicon oxide film 60 is separately deposited on the whole surface like
That is, the thickness of isolation insulating layer 5 in the ion-implantation step for source and drain region 17 formation becomes thick only the part of the thickness of silicon oxide film 60 substantially. Therefore, it becomes difficult to generate that the implanted impurity ion penetrates through isolation insulating layer 5, and the margin of the energy of the impurity ion implantation concerned becomes large. Therefore, formation of the semiconductor device concerning the present invention can be made easy like Embodiment 2, and it can contribute also to the thickness reduction of the SOI layer in an SOI device.
This embodiment has also increased the substantial thickness of isolation insulating layer 5 using silicon oxide film 60 formed after patterning of gate electrode 12, without making high height h of the portion projected from SOI layer 3 of isolation insulating layer 5. Therefore, it is not accompanied by the problem that the residual substance of polysilicon will remain in the level difference portion of S01 layer 3 and isolation insulating layer 5 in the case of patterning of gate electrode 12.
In this embodiment, it is good to perform annealing (it corresponds to the step of the
When there is no need of suppressing the out-diffusion of source and drain regions 17, annealing may be performed after removing silicon oxide film 60 of the source and drain region 17 upper surface.
When forming silicide layers 12a and 17a on the upper part of gate electrode 12 and source and drain regions 17, respectively, since it is necessary to deposit metal directly on gate electrode 12 and source and drain regions 17, in the case, it is needed to remove silicon oxide film 60 on gate electrode 12 and source and drain regions 17 by etching.
Except the step explained above, it is good to be the same as that of the manufacturing method in Embodiment 1.
Number | Date | Country | Kind |
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2005-184295 | Jun 2005 | JP | national |
Number | Date | Country | |
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Parent | 11425072 | Jun 2006 | US |
Child | 12253510 | US |