The present invention relates to a semiconductor device including a group III nitride semiconductor layer and an ohmic electrode that creates an ohmic contact with such semiconductor layer.
a) is a cross-sectional view, showing a schematic configuration of a hetero-junction field effect transistor (hereinafter referred to as HJFET) according to a conventional technology, which is typically described in Patent Document 1. A gallium nitride (GaN) channel layer 102 and an aluminum gallium nitride (AlGaN) electron-supplying layer 103 are consecutively formed on a substrate 100. The electron-supplying layer 103 creates no lattice match with the GaN channel layer 102, and thus a growth thereof to a sufficient thickness for avoiding an influence of the surface cannot be achieved. Therefore, an n-type indium aluminum gallium nitride (InAlGaN) cap layer 104, which is capable of creating lattice match with the GaN channel layer 102, is employed to coat over an upper surface of the electron-supplying layer 103.
A gate electrode 105 is formed in a concave portion provided in the cap layer 104 so as to be in contact with the electron-supplying layer 103. A source electrode 106 and a drain electrode 107 are formed on the cap layer 104. In this structure, InAlN ratio in the n-type InAlGaN cap layer 104 is selected to be 1.5 times or more of the AlN ratio in the electron-supplying layer 103, so that polarized charge in the cap layer 104 is not lower than polarized charge in the electron-supplying layer 103. This results in reduced potential barrier between the cap layer 104 and the electron-supplying layer 103, achieving a reduction of the ohmic resistance.
b) is a diagram of energy band, showing a conduction band energy distribution corresponding to the ohmic contact of
In addition to above, prior art literatures related to the present invention also includes Non-Patent Document 1, in addition to Patent Document 1.
[Patent Document 1]
In the conventional semiconductor device described above, the InAlGaN layer is employed for the cap layer to provide further inhibited potential barrier between the cap layer and the electron-supplying layer, as compared with the configuration employing the GaN layer for the cap layer. On the other hand, however, this also results in an increased potential barrier between the ohmic electrode and the cap layer, and thus sufficiently reduced contact resistance cannot be achieved.
According to one exemplary aspect of the present invention, there is provided a semiconductor device, including: a channel layer; an electron-supplying layer provided on the channel layer; a cap layer, provided on the electron-supplying layer and creating lattice match with the channel layer; and an ohmic electrode provided on the cap layer, wherein the cap layer has a composition of: (InyAl1-y)zGa1-zN where (0≦y≦1, 0≦z≦1), and z for the cap layer monotonically decreases as being farther away from the electron-supplying layer.
In such semiconductor device, the cap layer creates lattice match with the channel layer. Further, a value of z in the composition of the cap layer decreases as being farther away from the electron-supplying layer, or in other words, decreases toward the side of the ohmic electrode from the side of the electron-supplying layer. Such configuration is employed for the cap layer that creates an ohmic contact so that potential barrier between the ohmic electrode and the cap layer can be reduced as discussed later, which allows sufficiently reducing the contact resistance.
In addition to above, z of the cap layer is not required to be decreased at a constant gradient. For example, such z may be decreased at varied gradient, or may be stepwise decreased.
According to one exemplary aspect of the present invention, a semiconductor device having sufficiently lower contact resistance is achieved.
The above-mentioned object, other objects, features, and advantages will become more apparent from exemplary embodiments explained below by reference to the attached drawings.
a) is a cross-sectional view, illustrating first exemplary embodiment of a semiconductor device according to the present invention.
b) is a diagram of energy band, showing a distribution of conduction band energy corresponding to ohmic contact shown in
b) is a diagram of energy band, showing a distribution of conduction band energy corresponding to ohmic contact shown in
a) is a cross-sectional view, illustrating fifth exemplary embodiment of a semiconductor device according to the present invention.
b) is a diagram of energy band, showing a distribution of conduction band energy corresponding to ohmic contact shown in
a) is a cross-sectional view, illustrating sixth exemplary embodiment of a semiconductor device according to the present invention.
b) is a diagram of energy band, showing a distribution of conduction band energy corresponding to ohmic contact shown in
a) is a cross-sectional view, illustrating a conventional semiconductor device.
b) is a diagram of energy band, showing a distribution of conduction band energy corresponding to ohmic contact shown in
Exemplary embodiments of the present invention will be described below, in reference to the annexed figures. In all figures, an identical numeral is assigned to an element commonly appeared in the figures, and the detailed description thereof will not be repeated.
a) is a cross-sectional view, illustrating first exemplary embodiment of a semiconductor device according to the present invention. A semiconductor device 1 includes a channel layer 12, an electron-supplying layer 13 provided on the channel layer 12, a cap layer 14 provided on the electron-supplying layer 13 and creating lattice match with the channel layer 12, and ohmic electrodes 22 and 24 provided on the cap layer 14.
The channel layer 12 is formed over the substrate 10 such as SiC and the like through a buffer layer, which is not shown here. The channel layer 12 has a composition of GaN or IntGa1-tN (0<t≦1). The electron-supplying layer 13 has a composition of AlxGa1-xN (0<x≦1).
The cap layer 14 has a composition of (InyAl1-y)zGa1-zN (0≦y≦1, 0≦z≦1). The “z” for such cap layer 14 monotonically decreases as being farther away from the electron-supplying layer 13. More specifically, in the cap layer 14, ratio of InAlN is decreased from the side of the electron-supplying layer 13 toward the side of the ohmic electrodes 22 and 24, while maintaining lattice match with the channel layer 12. In particular, in the present exemplary embodiment, the composition of the cap layer 14 is GaN (the above-described z=0) at the interface with the ohmic electrodes 22 and 24.
Portions of the cap layer 14 and the electron-supplying layer 13 are removed, and the gate electrode 26 creates a Schottky contact with the electron-supplying layer 13 through a concave portion formed by such removal. Such gate electrode 26 constitutes an HJFET with the channel layer 12, the electron-supplying layer 13 and the cap layer 14. The above-described ohmic electrode 22 and ohmic electrode 24 function as a source electrode and a drain electrode of the HJFET, respectively. The ohmic electrodes 22 and 24 create ohmic contacts with the cap layer 14.
b) is a diagram of energy band, showing a distribution of conduction band energy corresponding to ohmic contact shown in
Here, the band gap is represented by Eg, the potential barrier for nickel (Ni) is represented by ΦB, the spontaneous polarized charge of the cap layer 14 is represented by Psp, and the piezo polarized charge for GaN is represented by Ppz. According to the above-described Non-patent Document 1, composition dependencies of Eg, ΦB, Psp and Ppz are as follows:
Eg=3.42+2.71z−9.58yz+5.4y2z(eV) (1),
ΦB=0.84+1.30z−1.66yz(eV) (2),
Psp=−0.034−0.056z+0.118yz−0.070y2z(Cm−2) (3),
Ppz=[−0.0525(1−y)+0.148y+0.0938y(1−y)]z(Cm−2) (4).
According to formula (4), a condition for creating no piezo polarized charge due to the lattice match with GaN is presented as: y=0.19. The band gap and the potential barrier in such case are presented from formula (1) and formula (2), respectively, as:
Eg=3.42+1.08z(eV) (5),
ΦB=0.84+0.98z(eV) (6).
Here, the potential barriers of the cap layer and the ohmic metal are considered as parameters indicative for the contact resistances. While the potential barrier for Ni is represented in formula (6), other metallic materials having smaller work function may be generally employed for the ohmic electrode for the purpose of obtaining further reduced potential barrier. However, since the potential barrier is correlated with a work function of a metal, aluminum (Al), which is generally employed for the ohmic electrode, also exhibits similar tendency, when the potential barrier for Ni is considered.
While the range of x in the composition AlxGa1-xN of the electron-supplying layer is 0<x≦1, the range may be preferably 0.1≦x≦0.3. Here, an exemplary implementation of x=0.2 will be described. Since z of the cap layer is presented as 0.3 when a condition of x=0.2 is employed according to the conventional technology, the potential barrier is obtained as 1.13 eV by formula (6). On the other hand, since the top of the cap layer is GaN (in other words, z=0) according to the present exemplary embodiment, the potential barrier can be considerably reduced to 0.84 eV. This allows effectively reducing the ohmic resistance according to the present exemplary embodiment. While the exemplary implementation employing GaN for the top of the cap layer has been described here, a reduced ohmic resistance can also be achieved if z is within a range that provides smaller potential barrier than the AlGaN electron-supplying layer, even though z>0.
a) is a cross-sectional view, illustrating second exemplary embodiment of a semiconductor device according to the present invention. In a semiconductor device 2, a cap layer 15 is employed in place of the cap layer 14 in the semiconductor device 1 shown in
The cap layer 15 is doped with n-type dopant, which creates negative charge that is larger than a spontaneous polarized charge. Other configurations of the cap layer 15 are similar to that of the cap layer 14. More specifically, the cap layer 15 also has a composition of: (InyAl1-y)zGa1-zN (0≦y≦1, 0≦z≦1), and z monotonically decreases as being away from the electron-supplying layer 13. Further, the cap layer 15 creates lattice match with the channel layer 12.
The doping concentration in such case may be designed as follows. Spontaneous polarized charge in the cap layer 15 is presented by substituting y=0.19, which is a condition for lattice match with the GaN layer, into formula (3) to obtain:
Psp=−0.034−0.036z(Cm−2) (7).
Spontaneous polarized charge for z ranging from z1 to 0 is obtained by an integration of formula (7) as:
Psp=−0.034z1−0.018z12(Cm−2) (8).
In an example assuming z=0.5, it is obtained:
Psp=0.022 Cm−2(1.34×1013 cm−2).
When the thickness of the cap layer 15 is assumed to be 50 nm, this corresponds to 2.68×1018 cm−3. A potential distribution of a convex profile from above downward as shown in
Here, z in the composition (InyAl1-y)zGa1-zN of the cap layer 15 in such case may be designed as follows. The band gap of the electron-supplying layer 13 is obtained by assigning the values of: Y=0 and Z=x, into formula (1) as:
Eg=3.42+2.71x+x2(eV) (9).
On the other hand, according to the above-described Non-Patent Document 1, the valence band discontinuity ΔEc is presented as:
ΔEc=0.63(Eg1−Eg2)(eV) (10).
Therefore, the valence band discontinuity of the cap layer 15 and the electron-supplying layer 13 is obtained as:
ΔEc=0.63(2.71x+x2−1.08z)(eV) (11),
where k, Tch and Q are assigned to the Boltzmann constant, the channel temperature and the elementary charge, respectively. A valence band discontinuity of not higher than (kTch/q) (eV) provides no influence over the nature of the electron transfer between the cap layer 15 and the electron-supplying layer 13. Therefore, the following relation is achieved:
−kTch/q≦0.63(2.71x+x2−1.08z)≦kTch/q (12).
When a condition of X=0.2 and a channel temperature of 200 degree C. are assumed, the range of z is obtained as 0.48≦z≦0.6. If z is within the above range, a potential barrier between the cap layer 15 and the electron-supplying layer 13 can be eliminated, so that the ohmic resistance can be reduced. Further, the valence band discontinuity is reduced to zero in the case of z=0.54, and the spontaneous polarized charge in such case is obtained through formula (8) as 0.024 Cm−2 (1.50×1013 cm−2), and this is equivalent to 3.00×1018 cm−3 when the thickness of the cap layer is assumed to be 50 nm. A potential distribution of a convex profile from above downward is obtained by doping with n-type dopant at a concentration higher than the above-described concentration, so that better ohmic-ability can be achieved.
a) is a cross-sectional view, illustrating fifth exemplary embodiment of a semiconductor device according to the present invention. A semiconductor device 1 includes a channel layer 12, an electron-supplying layer 16 provided on the channel layer 12, a cap layer 14 provided on the electron-supplying layer 16 and creating lattice match with both the channel layer 12 and the electron-supplying layer 16, and ohmic electrodes 22 and 24 provided on the cap layer 14.
The channel layer 12 is formed over the substrate 10 through a buffer layer 11. The electron-supplying layer 16 has a composition of (InuAl1-u)xGa1-xN (0≦u≦1, 0<x≦1). Portions of the cap layer 14 and the electron-supplying layer 16 are removed, and the gate electrode 26 creates a Schottky contact with the electron-supplying layer 16 through a concave portion formed by such removal. Such gate electrode 26 constitutes an HJFET with the channel layer 12, the electron-supplying layer 16 and the cap layer 14. The above-described ohmic electrode 22 and ohmic electrode 24 function as a source electrode and a drain electrode of the HJFET, respectively. The ohmic electrodes 22 and 24 create ohmic contacts with the cap layer 14.
In the present exemplary embodiment, the electron-supplying layer 16 creates lattice match with the channel layer 12. This prevents a creation of a piezo polarized charge, so that carrier is generated only with a spontaneous polarized charge. A sheet concentration of carrier is presented by subtracting spontaneous polarized charge of the channel layer 12 from sum of piezo polarized charge and spontaneous polarized charge in the electron-supplying layer 16, and thus is calculated by formula (3) and formula (4). In the electron-supplying layer 16, the carrier density is presented as: 1.31×10−13 cm−2. In order to achieve a carrier density of the equivalent level, x in the electron-supplying layer 16 may be assigned as x=0.58 in formula (7).
b) is a diagram of energy band, showing a distribution of conduction band energy corresponding to ohmic contact of
a) is a cross-sectional view, illustrating sixth exemplary embodiment of a semiconductor device according to the present invention.
In an example assuming z=0.54, it is obtained as: 0.024 Cm−2 (1.50×1013 cm−2), and when the thickness of the cap layer is assumed to be 50 nm, this corresponds to 3.00×1018 cm−3. A potential distribution of a convex profile from above downward is obtained by doping with n-type dopant at a concentration higher than the above-described concentration, so that better ohmic-ability can be achieved.
Here, z in the composition of the cap layer 15 in such case may be designed as follows. A valence band discontinuity in the electron-supplying layer 16 and the cap layer 15 is presented by utilizing a condition of u=y=0.19 and formula (1) and formula (10) as:
ΔEc=0.68(x−z)(eV) (13).
A valence band discontinuity of not higher than (kTch/q) (eV) provides no influence over the nature of the electron transfer between the cap layer 15 and the electron-supplying layer 16. Therefore, the following relation is achieved:
−kTch/q≦0.68(x−z)≦kTch/q (14).
Fifth exemplary embodiment is taken as an exemplary implementation and when conditions of x=0.58 and a channel temperature of 200 degree C. are assumed, the range of z is presented as: 0.52≦z≦0.64, and if z is within the above range, a potential barrier between the cap layer 15 and the electron-supplying layer 16 can be eliminated, so that the ohmic resistance can be reduced.
Number | Date | Country | Kind |
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2006-129322 | May 2006 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2007/000482 | 5/7/2007 | WO | 00 | 11/4/2008 |
Publishing Document | Publishing Date | Country | Kind |
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WO2007/129471 | 11/15/2007 | WO | A |
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