1. Field of the Invention
Embodiments of the present invention generally relate to a gas distribution showerhead, a shadow frame, and an apparatus for processing a substrate.
2. Description of the Related Art
Plasma enhanced chemical vapor deposition (PECVD) is a deposition method whereby processing gas is introduced into a processing chamber through a gas distribution showerhead. The showerhead is electrically biased to ignite the processing gas into a plasma. The susceptor, sitting opposite to the showerhead, is electrically grounded and functions as an anode. The showerhead spreads out the processing gas as it flows into the processing space between the showerhead and the susceptor.
PECVD has recently become popular for depositing material onto large area substrates. Large area substrates may have a surface area of greater than about one square meter. Large area substrates may be used for flat panel displays (FPDs), solar panels, organic light emitting displays (OLEDs), and other applications.
In addition to the showerhead and susceptor, a shadow frame may be present within the apparatus. The shadow frame may be used to cover the edges of the substrate, if desired, and the edges of the susceptor that are not covered by the substrate. The shadow frame may reduce deposition of material on the susceptor. In the absence of a shadow frame, material may deposit on the susceptor edges and potentially bridge to the substrate.
When material bridges to the substrate, the substrate and material deposited thereon may be damaged when the bridge is broken. Additionally, when material is deposited onto the susceptor, flaking of the material may occur or potentially, the substrate may be misaligned due to an uneven susceptor surface. Misalignment of the substrate may cause uneven deposition.
Due to the increased use of PECVD, there is a need for gas distribution showerheads and shadow frames.
The present invention generally relates to a gas distribution showerhead and a shadow frame for an apparatus. By extending the corners of the gas distribution showerhead, the electrode area may be expanded relative to the anode and thus, uniform film properties may be obtained. Additionally, the expanded corners of the gas distribution showerhead may have gas passages extending therethrough. In one embodiment, hollow cathode cavities may be present on the bottom surface of the showerhead without permitting gas to pass therethrough. The shadow frame in the apparatus may also have its corner areas extended out to enlarge the anode in the corner areas of the substrate being processed and thus, may lead to deposition of a material on the substrate having substantially uniform properties.
In one embodiment, a gas distribution showerhead includes a showerhead body having a generally rectangular shape with a plurality of gas passages extending therethrough and one or more elements extending from one or more corners of the showerhead body.
In another embodiment, a gas distribution showerhead includes a showerhead body having a generally rectangular shape and a plurality of gas passages extending therethrough. One or more cutouts may be carved in one or more sides of the showerhead body such that at least a portion of the one or more sides having the one or more cutouts extends beyond the one or more cutouts at one or more corners of the showerhead body.
In another embodiment, a gas distribution showerhead includes a showerhead body having a generally rectangular shape with four sides each having a length and four corners. At least one corner of the four corners has one or more flanges extending from the corner along a length of a side for a length less than the side length.
In another embodiment, an apparatus includes a chamber body, a susceptor disposed within the chamber body, and a gas distribution showerhead. The susceptor has a first surface area. The showerhead is disposed in the chamber body opposite the susceptor facing the side of the susceptor having the first surface area. The gas distribution showerhead has a second surface area greater than the first surface area.
In another embodiment, an apparatus includes a chamber body, a susceptor disposed in the chamber body and having a generally rectangular shape and four sides, and a gas distribution showerhead having a plurality of gas passages extending therethrough. The gas distribution showerhead has a generally rectangular shaped body having four sides substantially aligned with each of the four sides of the susceptor. The corners of the gas distribution showerhead are not substantially aligned with the corners of the susceptor.
In another embodiment, an apparatus includes a chamber body having a generally rectangular shape, a susceptor disposed in the chamber body having a generally rectangular shape, and a gas distribution showerhead disposed in the chamber body opposite the susceptor. The gas distribution showerhead has a generally rectangular shape and at least one corner that extends closer to a corner of the chamber body than any corner of the susceptor extends to any corner of the chamber body.
In another embodiment, an apparatus includes a chamber body having a generally rectangular shape, a susceptor disposed in the chamber body having a generally rectangular shape, a gas distribution showerhead disposed in the chamber body opposite the susceptor, and a shadow frame disposed in the chamber body between the susceptor and the gas distribution showerhead. The shadow frame has at least one corner that extends closer to a corner of the chamber body than any corner of the susceptor or showerhead extends to any corner of the chamber body.
In another embodiment, a gas distribution showerhead includes a showerhead body having an upstream surface and a downstream surface with a plurality of gas passages extending between the upstream surface and the downstream surface. The showerhead body also has one or more cavities in the downstream surface separate from the gas passages.
In another embodiment, a gas distribution showerhead is disclosed. The gas distribution showerhead includes a showerhead body having a generally rectangular shape, a first surface, a second surface opposite to the first surface, and a plurality of gas passages extending between the first surface and the second surface. The gas distribution showerhead also includes one or more corner extension elements coupled to the showerhead body and extending from one or more corners of the showerhead body, the one or more corner extension elements having a third surface and a fourth surface opposite the third surface.
In another embodiment, a plasma enhanced chemical vapor deposition apparatus is disclosed. The apparatus includes a chamber body and a substrate support disposed within the chamber body having a substrate support surface for receiving a substrate. The substrate support surface has a generally rectangular shape. The apparatus also includes a gas distribution showerhead disposed in the chamber body opposite the substrate support. The gas distribution showerhead has a first surface facing the substrate support surface and a second surface opposite the first surface. The first surface generally mirrors the substrate support surface. The apparatus also includes one or more showerhead extension elements coupled to the gas distribution showerhead at one or more corners thereof.
In another embodiment, a plasma enhanced chemical vapor deposition apparatus is disclosed. The apparatus includes a chamber body having a generally rectangular shape and a substrate support disposed in the chamber body having a generally rectangular shape. The apparatus also includes a gas distribution showerhead disposed in the chamber body opposite the susceptor. The apparatus may also include a shadow frame disposed in the chamber body between the substrate support and the gas distribution showerhead. The shadow frame has a main body that has a generally rectangular shape and one or more corner extension elements that extend from one or more corners of the main body.
So that the manner in which the above recited features of the present invention can be understood in detail, a more particular description of the invention, briefly summarized above, may be had by reference to embodiments, some of which are illustrated in the appended drawings. It is to be noted, however, that the appended drawings illustrate only typical embodiments of this invention and are therefore not to be considered limiting of its scope, for the invention may admit to other equally effective embodiments.
To facilitate understanding, identical reference numerals have been used, where possible, to designate identical elements that are common to the figures. It is contemplated that elements and features of one embodiment may be beneficially incorporated in other embodiments without further recitation.
The present invention generally relates to a gas distribution showerhead and a shadow frame for an apparatus. By extending the corners of the gas distribution showerhead, the electrode area may be expanded relative to the anode and thus, uniform film properties may be obtained. Additionally, the expanded corners of the gas distribution showerhead may have gas passages extending therethrough. In one embodiment, hollow cathode cavities may be present on the bottom surface of the showerhead without permitting gas to pass therethrough. The shadow frame in the apparatus may also have its corner areas extended out to enlarge the anode in the corner areas of the substrate being processed and thus, may lead to deposition of a material on the substrate having substantially uniform properties.
The invention will be described below in relation to a PECVD apparatus available from AKT America, Inc., a subsidiary of Applied Materials, Inc., Santa Clara, Calif. It is to be understood that the invention has applicability in other chambers as well, including PECVD apparatus available from other manufacturers.
Grounding straps 126 may be coupled to the susceptor 118 to provide RF grounding at the periphery of the susceptor 118. The grounding straps 126 may be coupled to the bottom 104 of the chamber 100. In one embodiment, the grounding straps 126 may be coupled to the corners of the susceptor 118 and the bottom 104 of the chamber 100.
The showerhead 106 is coupled to a backing plate 112 by a coupling 144. In one embodiment, the coupling 144 may comprise a bolt threadedly engaged with the showerhead 106. The showerhead 106 may be coupled to the backing plate 112 by one or more couplings 144 to help prevent sag and/or control the straightness/curvature of the showerhead 106. In one embodiment, twelve couplings 144 may be used to couple the showerhead 106 to the backing plate 112. The showerhead 106 may additionally be coupled to the backing plate 112 by a bracket 134. The bracket 134 may have a ledge 136 upon which the showerhead 106 may rest. The backing plate 112 may rest on a ledge 114 coupled with the chamber walls 102 to seal the chamber 100.
The spacing between the top surface of the substrate 120 and the showerhead 106 may be between about 400 mil and about 1,200 mil. In one embodiment, the spacing may be between about 400 mil and about 800 mil.
A gas source 132 is coupled to the backing plate 112 to provide gas through gas passages in the showerhead 106 to the substrate 120. A vacuum pump 110 is coupled to the chamber 100 at a location below the susceptor 118 to maintain the process volume at a predetermined pressure. A RF power source 128 is coupled to the backing plate 112 and/or to the showerhead 106 to provide a RF power to the showerhead 106. The RF power creates an electric field between the showerhead 106 and the susceptor 118 so that a plasma may be generated from the gases between the showerhead 106 and the susceptor 118. Various frequencies may be used, such as a frequency between about 0.3 MHz and about 200 MHz. In one embodiment, the RF power is provided at a frequency of 13.56 MHz. In one embodiment, an AC power source may be coupled to the showerhead 106. In another embodiment, the chamber 100 is a parallel plate PECVD chamber.
A remote plasma source 130, such as an inductively coupled remote plasma source, may also be coupled between the gas source 132 and the backing plate 112. Between processing substrates, a cleaning gas may be provided to the remote plasma source 130 so that a remote plasma is generated. Radicals from the remotely generated plasma may then be provided to the chamber 100 to clean components of the chamber 100. The cleaning gas may be further excited by power provided by the RF power source 128 to the showerhead 106. Suitable cleaning gases include but are not limited to NF3, F2, and SF6.
A shadow frame 162 may be present within the chamber 100. The shadow frame 162 prevents deposition from occurring on the edges of the substrate support 106 that are not covered by the substrate 120. Additionally, the shadow frame 162 may prevent deposition from occurring on the edges of the substrate 120. The shadow frame 162 may be spaced from the substrate 120 such that material that deposits on the substrate 120 may not bridge to the shadow frame 162. Additionally, the shadow frame 162 is coupled to the susceptor 118 by a coupling. The susceptor 118, as it raises to the processing position, may come into contact with the shadow frame 162 and raise it along with the susceptor 118 and substrate 120. The coupling may be an alignment pin that properly aligns the shadow frame 162 on the susceptor 118 without fixedly coupling the shadow frame 162 to the susceptor 118. The shadow frame 162, by being coupled to the susceptor 118, may be part of the RF return path, which is sometimes referred to as RF grounded. Additionally, the shadow frame 162 creates a pumping plenum between the shadow frame 162 and the chamber walls 102.
The chamber 100 is suitable for chemical vapor deposition (CVD) or PECVD processes for fabricating a solar panel, an OLED, or the circuitry of an FPD on a large area glass, polymer, or other suitable substrate. The structures produced may be thin film transistors (TFTs) which may comprise a plurality of sequential deposition and masking steps. Other structures may include p-n junctions to form diodes for photovoltaic cells.
The chamber 100 is configured to deposit a variety of materials on a large area substrate that includes conductive materials (e.g., ITO, ZnO2, W, Al, Cu, Ag, Au, Ru or alloys thereof), dielectric materials (e.g., Si, SiO2, SiOxNy, HfO2, HfSiO4, ZrO2, ZrSiO4, TiO2, Ta2O5, Al2O3, derivatives thereof or combinations thereof), semiconductive materials (e.g., Si, Ge, SiGe, dopants thereof or derivatives thereof), barrier materials (e.g., SiNx, SiOxNy, Ti, TiNx, TiSixNy, Ta, TaNx, TaSixNy or derivatives thereof) and adhesion/seed materials (e.g., Cu, Al, W, Ti, Ta, Ag, Au, Ru, alloys thereof and combinations thereof). In one embodiment, the chamber 100 is used to deposit a layer of microcrystalline silicon.
Metal-containing compounds that may be deposited in the chamber 100 include metals, metal oxides, metal nitrides, metal silicides, or combinations thereof. For example, metal-containing compounds include tungsten, copper, aluminum, silver, gold, chromium, cadmium, tellurium, molybdenum, indium, tin, zinc, tantalum, titanium, hafnium, ruthenium, alloys thereof, or combinations thereof. Specific examples of conductive metal-containing compounds that are formed or deposited in the chamber 100 onto the large area substrates, such as gate electrodes and other conductive layers, include indium tin oxide, zinc oxide, tungsten, copper, aluminum, silver, derivatives thereof or combinations thereof.
The chamber 100 is also configured to deposit dielectric materials and semiconductive materials in a polycrystalline, amorphous or epitaxial state. For example, dielectric materials and semiconductive materials may include silicon, germanium, carbon, oxides thereof, nitrides thereof, dopants thereof or combinations thereof. Specific examples of dielectric materials and semiconductive materials that are formed or deposited by the chamber 100 onto the large area substrates may include epitaxial silicon, polycrystalline silicon, amorphous silicon, silicon germanium, germanium, silicon dioxide, silicon oxynitride, silicon nitride, dopants thereof (e.g., B, P or As), derivatives thereof or combinations thereof.
The chamber 100 is also configured to receive gases such as argon, hydrogen, nitrogen, helium, or combinations thereof, for use as a purge gas or a carrier gas (e.g., Ar, H2, N2, He, derivatives thereof, or combinations thereof). One example of depositing amorphous silicon thin films on a large area substrate using the chamber 100 may be accomplished by using silane as the precursor gas in a hydrogen carrier gas.
To ensure microcrystalline silicon formation rather than amorphous silicon formation, a greater amount of silicon precursor gas may be introduced into the processing chamber. Additionally, a high RF current may be applied to the gas distribution showerhead. The higher power and/or higher precursor flow may increase the formation of microcrystalline silicon. As shown in
When the showerhead has a rectangle shape, the corners of the rectangle are close to two walls of the chamber that meet to form the corner of the chamber. The walls of the chamber are part of the RF return path, which may be referred to as RF grounded by some in industry, and act as an anode in opposition to the electrically biased showerhead. Thus, the wall effect in the corners may be about double the wall effect at all other areas of the showerhead. Due to the increased wall effect near the corners, the plasma near the corners may not have the same properties as the plasma at other locations in the chamber. The non-uniform plasma may lead to different properties in the layer deposited. Thus, the corner areas of the substrate may have amorphous silicon while the remainder of the substrate may have microcrystalline silicon. The plasma may also have a standing wave effect that may be greater in the corner areas of the chamber which may also contribute to the non-uniform plasma.
One manner to ensure microcrystalline silicon formation while also depositing a layer having a uniform thickness is to adjust the shape of the gas distribution showerhead.
The processing chamber in which the showerhead 300 will be placed may still retain a rectangular shape. The areas between the corners 304 may be left open if desired or filled with a material to prevent plasma formation in those locations. In one embodiment, the filler material may comprise ceramic and be coupled to the chamber walls.
Gas passages 306 may be present in both the rectangular areas 302 as well as the corner areas 304. The gas passages in the corner areas increase the flow of processing gas (or cleaning radicals when in cleaning mode) to the corner areas of the chamber and hence, may increase the amount of material deposited on the substrate in the corner areas. Additionally, the increased processing gas flow to the corner areas of the chamber and/or the increased electrode area in the corner areas of the chamber may ensure that the material deposited on the substrate has consistent properties throughout the layer. The gas passages 306 may be arranged in a closed pack pattern.
By extending the corners 324 of the showerhead 320 without having gas passages 326 through the corners 324, the electrode is extended out, but the gas flow is not extended closer to the corners of the chamber. However, the plasma formed near in the rectangular area 322 is further away from the chamber walls than it would otherwise be in absence of the corners 324. Thus, the plasma in the rectangular area 322 may be more uniformly distributed because the corner of the chamber is further away from the rectangular area 322 than they would otherwise be in absence of the corners 324. Therefore, the plasma is further away from the chamber walls and may permit a more uniform layer, in terms of the layer properties, to be deposited. The gas passages 326 may be arranged in a closed pack pattern.
The hollow cathode cavities 558 provide an area within the showerhead 550 where a plasma may ignite. When there are no gas passages in the corner extensions, one would not normally expect any plasma to ignite within the corner extensions because no gas is flowing therethrough. However, by having hollow cathode cavities 558 in the corner extensions, the gas, as is disperses within the chamber, comes into contact with the hollow cathode cavities 558 that are in the corner extensions and thus, ignite into a plasma within the hollow cathode cavities 558. The hollow cathode cavities 558 may alter the shape of the plasma and the plasma density within the processing chamber during operation. In one embodiment, the corner extensions may have straight gas passages without any hollow cathode cavities while the rectangular area of the showerhead 550 may have hollow cathode cavity type gas passages.
The hollow cathode cavity 604 is shaped to permit plasma to ignite within the hollow cathode cavity 604. For the situation where the hollow cathode cavities 606 are present on the downstream side 610, but the top bore 608 has not been drilled from the upstream side 612, no gas will flow through the showerhead 600 at the location of the hollow cathode cavity 604 such as is shown in
One reason to not drill the top bore 608 is to ensure the structural integrity of the showerhead 600. When the showerhead 600 has corner extensions that extend beyond the generally rectangular section of the showerhead 600, the structural integrity of the showerhead 600 may be compromised such that the showerhead 600 is too flimsy to support its own weight. A gas distribution showerhead 600 may have many thousand gas passages therethrough. Thus, the addition of additional gas passages in a corner extension may compromise the structural integrity of the showerhead 600.
By increasing the showerhead area, the susceptor area, and/or the shadow frame area, the anode and the electrode in a PECVD chamber may be optimized to permit uniform deposition of material onto a substrate. Thus, when depositing microcrystalline silicon, the corners of the substrate may have microcrystalline silicon deposited having the same properties as the microcrystalline silicon in other areas of the substrate. Additionally, the microcrystalline silicon may have a uniform thickness.
While the foregoing is directed to embodiments of the present invention, other and further embodiments of the invention may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow.
This application claims benefit of U.S. provisional patent application Ser. No. 61/089,825, filed Aug. 18, 2008, which is herein incorporated by reference.
Number | Date | Country | |
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61089825 | Aug 2008 | US |