The use of semiconductor materials in electronics, photovoltaics, illumination and other applications has rapidly developed in recent decades, and continues to grow exponentially. Further growth of these industries is greatly dependent on the ability to develop cost-effective production of semiconductor materials. Epitaxy is one method of producing semiconductors, in which crystalline layers are deposited on a substrate. In homoepitaxy, the crystalline layer is grown on a substrate of the same material. In heteroepitaxy the crystalline film is grown on a different material, which allows for more readily-available materials to be used as substrates, and also allows for layers of different materials to be integrated together. Deposition of the layers typically occurs by vapor phase epitaxy, in which the crystal layers are deposited under chemical reaction, usually at relatively high temperatures. Although silicon has long been used as a semiconductor substrate, advancement of materials and technologies is requiring development of other choices for substrates. Selection of substrate materials depends on many factors, such as electrical properties, thermal properties, crystalline compatibility with the deposited layers, and cost.
One application of heteroepitaxy is in light emitting diodes (LEDs), such as LEDs formed from gallium nitride (GaN) grown over sapphire. Silicon carbide (SiC) and gallium arsenide (GaAs) are other substrates used in LEDs. GaN is capable of efficient light emission from deep ultraviolet to infrared wavelengths, and thus is a key material being developed for semiconductor-based white light sources. Choices for other materials in LED are based on factors such as cost, and compatibility with processing steps in the fabrication process.
Another application of heteroepitaxy is in transistor devices. Solid-state power devices—used in switching or amplifying large voltages and currents—are important components in communications, power delivery, and increasingly, transportation applications. One of the biggest innovations in this field in the last ten years has been the introduction of high electron mobility transistors (HEMTs) made on III-V semiconductors such as gallium nitride. HEMTs are devices that utilize a heterojunction between materials of differing bandgaps, where a two-dimensional electron gas (2DEG) is formed at the junction. The electrons have higher mobility at this heterojunction compared to moving through a doped region as in other semiconductor devices. HEMTs can be used at higher frequencies, control larger voltages in smaller areas, and dissipate (that is, waste) less power than similar transistors made with silicon. However, HEMTs face similar materials and processing challenges as LEDs.
Thus, there is an increasing need to produce heteroepitaxial materials with efficient cost and manufacturability.
A method of fabricating an electronic device includes providing a silicon carbide or diamond-like carbon donor body and implanting ions into a first surface of the donor body to define a cleave plane. After implanting, an epitaxial layer is formed on the first surface, and a temporary carrier is coupled to the epitaxial layer. A lamina is cleaved from the donor body at the cleave plane, and the temporary carrier is removed from the lamina. In some embodiments a light emitting diode or a high electron mobility transistor is fabricated from the lamina and epitaxial layer.
Each of the aspects and embodiments of the invention described herein can be used alone or in combination with one another. The aspects and embodiments will now be described with reference to the attached drawings.
Fabrication of electronic devices through heteroepitaxy typically involves depositing crystalline layers on a bulk wafer substrate, forming additional features such as electrical contacts and reflective coatings on the layers, and grinding down the back side of the wafer to the desired thickness. For example, gallium nitride LEDs are typically formed on thick silicon carbide wafers, such as on the order of 500 microns, and the SiC is ground down to a desired thinness. Thinning the wafer helps to reduce in-source inductance, and allows for low resistivity interconnects through the back side. Although SiC is less expensive than using bulk GaN, the loss of SiC material during grinding still results in a non-optimal use of the SiC. Sapphire is cheaper to use as an LED substrate than SiC, but sapphire still must be thinned due to its the poor thermal conductivity, and offers less lumens/area than SiC. Similarly, HEMT's usually have their substrate thinned before packaging, so that heat can be removed from the device more efficiently. This again results in wasted material and increased costs of the device. Thus, it is desirable to improve methods for heteroepitaxially-formed LEDs, HEMTs, and other electronic devices, such that the substrates are cost-effective and amenable to the manufacturing processes of these devices. The present invention utilizes silicon carbide and diamond-like carbon as substrates for heteroepitaxy, where the substrates are implanted with ions and exfoliated to produce lamina tailored to a desired thickness to be used in a final electronic device. Although the embodiments may be described in terms of silicon carbide substrates, it will be understood that diamond-like carbon may be interchanged with silicon carbide for the purposes of this disclosure.
In embodiments of the present invention, methods are described in which a silicon carbide or diamond-like carbon donor body is implanted with ions and epitaxial layers are deposited on the donor body. A carrier is contacted to the donor body, a free standing lamina is cleaved at the ion implantation plane, and the lamina with epitaxial layers is used to fabricate an electronic device. The methods advantageously utilize the property that silicon carbide exfoliates at temperatures higher than some epitaxial processes. The methods also utilize carriers that are compatible with the high temperatures required by exfoliation, and that may be easily removed without damaging the lamina. Thus, the present methods enable epitaxial layers to be produced on lamina with thicknesses tailored to a desired value, instead of requiring grinding to thin wafers to the necessary level. For the purposes of this disclosure, the term “carrier” shall be used interchangeably with “support element,” “receiver” and “susceptor.” The free standing lamina may be formed by, for example, the methods of Sivaram et al., U.S. patent application Ser. No. 12/026,530, “Method to Form a Photovoltaic Cell Comprising a Thin Lamina,” filed Feb. 5, 2008, owned by the assignee of the present invention and hereby incorporated by reference. The free standing lamina of the present disclosure has a thickness tailored to be thin enough to eliminate grinding for the finished device. In addition, the same donor wafer may beneficially be reused to form multiple laminae, further reducing cost, and may be resold after exfoliation of multiple laminae for some other use.
In Sivaram, the fabrication of a photovoltaic cell comprising a thin semiconductor lamina formed of non-deposited semiconductor material is described. Referring to
In step 430 of
Still referring to
Following the contacting of the donor body to the temporary carrier, heat is applied to the donor body to exfoliate and cleave a lamina from the donor body at the cleave plane in step 450 of
In step 460 of
In step 470, the carrier is removed from the epitaxial layer of the donor body. Step 470 may be optionally preceded or followed by contacting the lamina and epitaxial layer(s) to a second carrier using a de-bondable adhesive, electrostatic force, vacuum force, or other contacting method. Transferring the semiconductor device (that is, the lamina with epitaxial layers) to a carrier may enable processing of both sides of the device, such as on the back side of the lamina where there are no epitaxial layers. The carrier may be contacted on either the front or back surface of the lamina, through one or more transfers from the carrier of step 440. If using a de-bondable adhesive, the de-bondable adhesive may include mechanical or chemical bonding to bond or de-bond the lamina to the carrier. The de-bondable adhesives may require certain steps to initiate the de-bonding of the lamina and/or to clean the surface of the lamina and the temporary carrier after detachment. In other embodiments, the de-bondable adhesive may be a decomposable adhesive as described in Brainard et al., U.S. patent application Ser. No. 13/456,134, “Method of Forming a Permanently Supported Lamina,” filed Apr. 25, 2012, which is owned by the assignee of the present invention and is hereby incorporated by reference for all purposes. In Brainard, the adhesive is decomposed by, for example, application of heat or ultraviolet light.
In step 640 of
After the transistor components have been fabricated, in step 650 the semiconductor device, which includes the lamina and transistor components, may be coupled to a susceptor and is exfoliated at the cleave plane of the donor body. In various embodiments, as described in Kell, U.S. patent application Ser. No. 13/331,915, the temporary carrier is a plate of porous material, such as porous graphite, porous boron nitride, porous silicon, porous silicon carbide, laser-drilled silicon, laser-drilled silicon carbide, aluminum oxide, aluminum nitride, silicon nitride or any combination thereof. In such embodiments, a vacuum force applied to temporary carrier causes the lamina to be contacted to and held against the susceptor. Release of the vacuum force allows the lamina to be separably released from the susceptor.
Exfoliation of silicon carbide occurs at approximately 950° C. Because this temperature is higher than the epitaxial processes, premature exfoliation is beneficially avoided during heteroepitaxy. The resulting exfoliated lamina is coupled to a temporary carrier in step 660, to the face that was implanted with ions and on which the epitaxial layers are located. The temporary carrier in step 660 may be the susceptor that was used during step 650, or the susceptor may be replaced by a different component to be used as a temporary carrier during subsequent processing steps. In step 670, a seed layer deposition, for example by sputtering, is followed by applying a metal with a suitable coefficient of thermal expansion (CTE) to the opposite face of the lamina (for example, electroplating on the cleaved side of the lamina). For example, a nickel-iron alloy (NiFe, “Invar”) would be able to match the CTE of GaN or other epitaxial layers (between 5 and 6 ppm/C). Because the final HEMT will operate at elevated temperatures, such as up to 150° C. for some applications, compared to other types of electronic devices such as LEDs CTE matching between materials is important. At this point, high temperature processing is finished, and the temporary carrier may be removed in step 680.
While the specification has been described in detail with respect to specific embodiments of the invention, it will be appreciated that those skilled in the art, upon attaining an understanding of the foregoing, may readily conceive of alterations to, variations of, and equivalents to these embodiments. These and other modifications and variations to the present invention may be practiced by those of ordinary skill in the art, without departing from the spirit and scope of the present invention. Furthermore, those of ordinary skill in the art will appreciate that the foregoing description is by way of example only, and is not intended to limit the invention. Thus, it is intended that the present subject matter covers such modifications and variations.
Number | Name | Date | Kind |
---|---|---|---|
4451969 | Chaudhuri | Jun 1984 | A |
4968372 | Maass | Nov 1990 | A |
6091021 | Ruby et al. | Jul 2000 | A |
6127623 | Nakamura et al. | Oct 2000 | A |
6486008 | Lee | Nov 2002 | B1 |
6518596 | Basore | Feb 2003 | B1 |
6534382 | Sakaguchi et al. | Mar 2003 | B1 |
6809044 | Aspar et al. | Oct 2004 | B1 |
7531428 | Dupont | May 2009 | B2 |
7842585 | Sivaram et al. | Nov 2010 | B2 |
7985604 | Isaka et al. | Jul 2011 | B2 |
8101451 | Murali et al. | Jan 2012 | B1 |
8173452 | Petti et al. | May 2012 | B1 |
8501522 | Herner et al. | Aug 2013 | B2 |
20020174959 | Yanagita et al. | Nov 2002 | A1 |
20030087479 | He et al. | May 2003 | A1 |
20050093100 | Chen et al. | May 2005 | A1 |
20060255340 | Manivannan et al. | Nov 2006 | A1 |
20070277874 | Dawson-Elli et al. | Dec 2007 | A1 |
20080179547 | Henley | Jul 2008 | A1 |
20080265255 | Goyal | Oct 2008 | A1 |
20080296584 | Hachigo | Dec 2008 | A1 |
20090020592 | Lee et al. | Jan 2009 | A1 |
20090189126 | Prunchak | Jul 2009 | A1 |
20090194153 | Hilali et al. | Aug 2009 | A1 |
20090194162 | Sivaram et al. | Aug 2009 | A1 |
20090194164 | Sivaram et al. | Aug 2009 | A1 |
20090223562 | Niira et al. | Sep 2009 | A1 |
20090280597 | Wijekoon et al. | Nov 2009 | A1 |
20100129951 | Henley | May 2010 | A1 |
20100147448 | Agarwal et al. | Jun 2010 | A1 |
20100224911 | Okita et al. | Sep 2010 | A1 |
20100273329 | Prabhu et al. | Oct 2010 | A1 |
20100307572 | Bedell et al. | Dec 2010 | A1 |
20100307582 | Arai | Dec 2010 | A1 |
20100319765 | Choi | Dec 2010 | A1 |
20100326510 | Agarwal et al. | Dec 2010 | A1 |
20100330788 | Yu et al. | Dec 2010 | A1 |
20110171812 | Letertre et al. | Jul 2011 | A1 |
20110174376 | Lochtefeld et al. | Jul 2011 | A1 |
20110186910 | Forrest et al. | Aug 2011 | A1 |
20110221040 | Joshi et al. | Sep 2011 | A1 |
20110248265 | Forbes | Oct 2011 | A1 |
20110311789 | Loy et al. | Dec 2011 | A1 |
20120024377 | Takanashi et al. | Feb 2012 | A1 |
20120067423 | Lochtefeld et al. | Mar 2012 | A1 |
20120068345 | Schmidt et al. | Mar 2012 | A1 |
20120091474 | Or-Bach et al. | Apr 2012 | A1 |
20120094414 | Or-Bach et al. | Apr 2012 | A1 |
20120119224 | Tai et al. | May 2012 | A1 |
20120199845 | Werkhoven et al. | Aug 2012 | A1 |
Number | Date | Country |
---|---|---|
1547146 | Sep 2011 | EP |
2003017723 | Jan 2003 | JP |
20060024763 | Mar 2006 | KR |
20060115990 | Nov 2006 | KR |
20080109711 | Dec 2008 | KR |
20100097537 | Sep 2010 | KR |
102011003788 | Jan 2011 | KR |
20120006844 | Jan 2012 | KR |
20120041165 | Apr 2012 | KR |
20120050484 | May 2012 | KR |
03003434 | Jan 2003 | WO |
Entry |
---|
“Fujitsu Develops Breakthrough Technology for Low-Cost Production of Gallium-Nitride HEMT”, Fujitsu Global, Dec. 21, 2004, p. 1-4, www.fujitsu.com. |
Eddy et al., “Growth of gallium nitride thin films by electron cyclotron resonance microwave plasmaassisted molecular beam epitaxy”, Journal of Applied Physics, Jan. 1993, vol. 73, No. 1, pp. 448-455. |
Losurdo et al., “Plasmas for the Low-Temperature Growth of High-Quality GaN Films by Molecular Beam Epitaxy and Remote Plasma MOCVD”, Phys. Stat. Sol. 2002, a, 190, No. 1, 43-51. |
Mishra et al, “AlGaN/GaN HEMTs—An Overview of Device Operation and Applications”, Proceedings of the IEEE, Jun. 6, 2002, vol. 90 No. 6, pp. 1022-1031. |
Nguyen et al., “The fabrication of GaN-based light emitting diodes (LEDs)”, Advances in Natural Sciences: Nanoscience and Nanotechnology, 2010, p. 1-5. |
Shealy et al., “Optimization of Gallium Nitride High Power Technology for Commercial and Military Applications”, IEEE BCTM 9.4, 2008, p. 146-153. |
Sun and Han, “Heteroepitaxy of Nonpolar and Semipolar GaN”, GaN and ZnO-based Materials and Devices, 2012, Springer-Verlag Berline Heidelberg, 1-25. |
Vaughan, “Silicon Carbide Light Emitting Diode Fabrication and Characterization”, NNIN REU Research Accomplishments, 2004, p. 144-145. |
Examination Report dated Feb. 5, 2014 for European Patent Application No. 09152007.2. |
International Search Report and Written Opinion dated Jan. 29, 2014 for PCT Application No. PCT/US2013/053316. |
Office Action dated Feb. 12, 2014 for U.S. Appl. No. 13/366,338. |
Office Action dated Jan. 15, 2014 for U.S. Appl. No. 13/558,836. |
Office Action dated Jan. 8, 2014 for Chinese Patent Application No. 200910000496.1. |
Notice of Allowance and Fees dated Jul. 30, 2013 for U.S. Appl. No. 12/750,635. |
Office Action dated Aug. 1, 2013 for U.S. Appl. No. 13/494,687. |
Office Action dated Aug. 13, 2013 for U.S. Appl. No. 13/366,338. |
Office action dated Jul. 22, 2013 for U.S. Appl. No. 13/558,826. |
Office action dated Jul. 22, 2013 for U.S. Appl. No. 13/558,836. |
International Search Report and Written Opinion dated May 1, 2013 for PCT Application No. PCT/US2013/024682. |
International Search Report and Written Opinion dated May 1, 2013 for PCT Application No. PCT/US2013/024683. |
International Search Report and Written Opinion dated May 16, 2013 for PCT Application No. PCT/US2013/024681. |
International Search Report and Written Opinion dated Nov. 27, 2013 for PCT Application No. PCT/US2013/051541. |
Office Action dated Dec. 10, 2013 for U.S. Appl. No. 13/558,826. |
International Search Report and Written Opinion dated Nov. 26, 2013 for PCT Patent Application No. PCT/US2013/054443. |
International Search Report and Written Opinion dated Sep. 16, 2013 for PCT Application No. PCT/US2013/044622. |
Office Action dated Nov. 18, 2013 for U.S. Appl. No. 13/494,687. |
Office Action dated Nov. 8, 2013 for U.S. Appl. No. 13/689,628. |
Official Letter and Search report dated Sep. 24, 2013 for Taiwanese application No. 98102109. |
Number | Date | Country | |
---|---|---|---|
20140030836 A1 | Jan 2014 | US |