The present invention relates to a plasma treatment apparatus which performs plasma treatment at near atmospheric pressure, and a stage device which can be suitably used in a treatment apparatus, such as the plasma treatment apparatus, and allows a substrate to be treated to be set thereon.
Conventionally, surface treatment of a substrate made from, for example, glass, plastic, or other material by means of glow discharge plasma at a low pressure ranging from appropriately 0.1 Torr to 10 Torr is widely known and industrially applied. Surface treatment at such a vacuum-level low pressure prevents a shift from discharge to arc discharge, and therefore can be performed even on the substrate made from plastic or other material having a high heat resistance.
However, surface treatment by low-pressure glow discharge plasma requires an expensive vacuum chamber as a treatment container, and an evacuation unit. In addition, upsizing of substrates, typified by the so-called upsizing of a screen for a liquid crystal television or the like, has been developed in some fields. Surface treatment in such fields requires larger vacuum chamber and evacuation unit. This inevitably increases production cost of an apparatus and increases a footprint of the apparatus. Moreover, surface treatment on a substrate having a high water absorption requires a long time to form a vacuum inside the vacuum chamber, which increases treatment cost itself.
In order to overcome the above various kinds of problems, there has been proposed an apparatus which subjects a substrate to surface treatment at an atmospheric pressure while generating glow discharge plasma (for example, see Patent document 1).
Such a plasma treatment apparatus, as illustrated in
The adsorption groove 106 has a gap 108 between the substrate 104 and the electrode stage 102. In the gap 108 plasma easily occurs since a pressure inside the gap 108 is low. Therefore, a voltage drop in the adsorption groove 106 is relatively small.
As illustrated in
Patent document 2 discloses, which does not disclose a plasma treatment apparatus only, the technique of independently controlling the level of lift pins at their upward movement, which pins cause a wafer set on a setting table to be floated above the setting surface of the setting table.
[Patent document 1]
Japanese Unexamined Patent Publication No. 118857/1995 (Tokukaihei 7-118857; published on May 9, 1995)
[Patent document 2]
Japanese Unexamined Patent Publication No. 64132/2002 (Tokukai 2002-64132; published on Feb. 28, 2002)
Even though an upper end 120a of the pin (lift pin) at the downward movement of the lift pin mechanism 120 is set so as to be positioned at the same level as the adsorption surface 102a of the electrode stage 102, the upper end 120a cannot be positioned according to the setting. This is because mechanical precision of the lift pin mechanism 120 is limited. That is, the upper end 120a sinks below the adsorption surface 102a as illustrated in
When the upper end 120a of the pin is positioned below the adsorption surface 102a of the electrode stage 102, a gap 109 occurs due to difference in level between the upper end 120a of the pin and the substrate 104, as illustrated in
On the other hand, when the upper end 120a of the pin is positioned above the adsorption surface 102a of the electrode stage 102, a gap 111 occurs due to difference in level between the adsorption surface 102a and the substrate 104, as illustrated in
As different from the case of the adsorption groove 106, pressures in the gaps 109 and 111 caused by difference in level are atmospheric pressures, and no plasma therefore occurs even when a voltage is applied. As a result, a voltage drop in the gaps 109 and 111 increases.
More specifically, as illustrated in
The present invention has been attained in view of the above problems, and an object of the present invention is to provide a stage device which does not cause difference in level between the upper end of a pin in the lift pin mechanism and the setting surface in a state where a substrate is set on the setting surface of a stage, and a plasma treatment apparatus which includes such a stage device and thereby suppresses the occurrence of uneven treatment.
In order to achieve the object, a stage device of the present invention includes: a stage having a setting surface on which a substrate to be treated is set; and a lift pin mechanism having first pins, provided in the stage, each capable of emerging from the setting surface, the first pins being protruded so that the substrate is detached from the setting surface, wherein the lift pin mechanism includes contact adjusting means that brings an upper end of the first pin being withdrawn in the stage into contact with the substrate on the setting surface without lifting the substrate above the setting surface.
A plasma treatment apparatus of the present invention is a plasma treatment apparatus which generates plasma in between an electrode stage and a counter electrode at near atmospheric pressure so as to subject a substrate to be treated being set on the electrode stage to plasma treatment, the plasma treatment apparatus including the above stage device as the electrode stage.
According to the arrangement of the stage device of the present invention, the contact adjusting means included in the lift pin mechanism brings the upper end of the first pin being withdrawn in the stage into contact with the substrate set on the setting surface without lifting the substrate above the setting surface (corresponding to adsorption surface). This makes it possible to make the upper end of the first pin positioned at the same level as the setting surface through the use of the substrate.
That is, through the use of the substrate, the stage device is realized in which there is no difference in level between the upper end of the first pin and the setting surface in a state where the substrate is set on the setting surface.
In the plasma treatment apparatus of the present invention, such a stage device of the present invention is used as the electrode stage. This allows the substrate to come into contact with both the setting surface and the first pin even in the vicinity of the first pin.
This arrangement is free from a gap caused by difference in level between the above-described lift pin (first pin) and the setting surface, i.e. a gap between the substrate and lift pin (first pin) or a gap between the substrate and the setting surface, where no plasma is generated and a great voltage drop occurs. This makes it possible to reduce the occurrence of uneven treatment and incomplete treatment on the substrate.
Therefore, it is possible to provide a stage device and a plasma treatment apparatus both of which are arranged such that no difference in level occurs between the upper end of the first pin and the setting surface in a state where the substrate is set on the setting surface.
A display panel substrate of the present invention is a display panel substrate for use in manufacturing a display panel, and the display panel substrate is subjected to surface treatment by means of the above plasma treatment apparatus of the present invention capable of effectively reducing the occurrence of uneven treatment. By manufacturing a display panel including such a display panel substrate, it is possible to provide a display device having an excellent display quality without display irregularity.
a) is a cross-sectional view schematically illustrating an essential part in the vicinity of the lift pin in the plasma treatment apparatus illustrated in
a) through 13(e) are cross-sectional views illustrating the structure of an electrode stage installed in a plasma treatment apparatus of another embodiment of the present invention, wherein an insulating section provided in the outer region of the electrode stage is movable.
a) through (d) are cross-sectional views illustrating the procedural steps for manufacturing a liquid crystal panel in which a color filter is formed on the substrate with the use of the plasma treatment apparatus illustrated in
a) and 22(b) are plan views illustrating examples of a pattern of black matrices for use in formation of a color filter.
The counter electrode 3 is realized by an electrically conductive member and is disposed so as to face the electrode stage 2. To the counter electrode 3, a power source section 10 is connected, and electrical discharge can occur between the counter electrode 3 and the electrode stage 2. The counter electrode 3 is located inside the chamber 1 at an upper position thereof, and the counter electrode 3 is connected to the gas injection pipe 9, through which a treatment gas is injected into the counter electrode 3. One end of the gas injection pipe 9 is connected to the surface of the counter electrode 3 opposite to the surface thereof facing the electrode stage 2. Further, the counter electrode 3 has a plurality of gas injection holes 8, through which the treatment gas supplied from the gas injection pipe 9 to the counter electrode 3 is supplied toward the substrate 4.
The structure of the counter electrode 3 is not limited to the above structure. The counter electrode 3 may be of any structure as long as gas is evenly injected in between the counter electrode 3 and the electrode stage 2.
The other end of the gas injection pipe 9 extends to the outside of the chamber 1 and is connected to a gas supply source. The bottom of the chamber 1 is connected to a discharge pipe 5, through which an exhaust gas in the chamber 1 is discharged.
The electrode stage device 35 has the electrode stage 2, and an adsorption mechanism 6 and a lift pin mechanism 7, both of which are provided in the electrode stage 2.
The electrode stage 2 is the one on which the substrate 4 is set. The electrode stage 2 has an electrode section 2a and an insulating section 2b. The electrode section 2a is realized by a electrically conductive member in the form of plate. The insulating section 2b is realized by insulators arranged around the electrode section 2a. The top surfaces of the electrode section 2a and the insulating section 2b are a setting surface 11, on which the substrate 4 is set. The electrode section 2a is grounded.
As illustrated in
The insulating section 2b has the function of preventing the occurrence of abnormal electrical discharge. More specifically, if the electrode section 2a was exposed toward the side surface of the electrode stage 2 on the assumption that the substrate 4 is of the same size as the electrode stage 2, electrical discharge between the electrode stage 2 and the counter electrode 3 due to their electrodes exposed, i.e. abnormal electrical discharge would occur at the point A illustrated in
On the contrary, the electrode stage 2 is surrounded by the insulating section 2b in the present embodiment. With this arrangement, no abnormal electrical discharge occurs as illustrated in
As illustrated in
As illustrated in
As illustrated in
As illustrated in
Although there is a gap between the substrate 4 and the electrode stage 2, the problem of uneven treatment occurs less frequently. This is because internal pressures of the adsorption holes 6a are depressurized by vacuuming, which facilitates plasma generation and causes a relatively small voltage drop. However, if the diameter of the adsorption holes 6a is large, uneven treatment may occur even when the gap is at a negative pressure. Therefore, it is desirable that the diameter of the adsorption holes 6a is not greater than 0.5 mm.
If the pitch between the adsorption holes 6a is not greater than 100 mm, it complicates working on the electrode stage 2 and the insulating section 2b. This results in high production cost. On the other hand, if the pitch is too large, it affects the capability of the adsorption holes 6a in adsorbing the substrate 4 onto the setting surface 11. This requires negative pressure to be increased. In view of this, the pitch between the adsorption holes 6a is preferably in the range from 100 mm to 200 mm.
Apart from the above arrangement, the adsorption mechanism 6 may be made up of a plurality of adsorption grooves which are formed in the electrode stage 2 and concentrically aligned in a rectangular ring manner (square-shaped-frame manner) in planar view. In this case, the adsorption grooves may be connected to a vacuum pump or the like via exhaust passages formed at the bottoms of the respective adsorption grooves. Also in this case, it is desirable that a width of the adsorption groove is not greater than 0.5 mm.
The lift pin mechanism 7 sets the substrate 4 on the electrode stage 2 and detaches the substrate 4 from the electrode stage 2, by means of lift pins which are arranged capable of emerging from the setting surface 11 of the electrode stage 2. In the present embodiment, contact adjusting means is provided that brings the upper end of the lift pin being withdrawn in the electrode stage 2 into contact with the substrate 4 on the setting surface 11 without lifting the substrate 4 above the setting surface 11, although details thereof will be described later. With this arrangement, it is possible to reduce the occurrence of the previously described uneven treatment during the plasma treatment.
In the plasma treatment apparatus S having such an arrangement, plasma is generated in between the counter electrode 3 and the electrode stage 2 when the power source section 10a applies a voltage ranging, for example, from 1 kV through several tens of kV in between the counter electrode 3 and the electrode stage 2 while a treatment gas is supplied in between the counter electrode and the electrode stage 2. With this plasma, the substrate 4 is subjected to plasma treatment.
For example, in order to perform etching with respect to a thin film formed on the substrate 4 (thin film having chemical, mechanical, optical, or electrical properties), the treatment gas is preferably a mixed gas of CF4, and He or Ar. In order to perform treatment for making the substrate 4 water repellent (liquid repellent), the treatment gas can be a fluorine-containing gas such as CF4, C2F6, or SF6. In order to form a thin film of a metal oxide film made from SiO2, TiO2, SnO2, or the like on the surface of the substrate 4, thereby making the substrate 4 hydrophilic, the treatment gas can be a metal hydride gas (hydrogenated metal gas), a halogenated metal gas, a gas of an organic metal compound such as metallic alcoholate, or water vapor.
Next, the lift pin mechanism 7 installed in the electrode stage device 35 of the plasma treatment apparatus S will be described in detail with reference to
As described previously, the lift pin mechanism 7 is provided with lift pins that are arranged capable of emerging from the setting surface 11 of the electrode stage 2. In this case, the lift pin mechanism 7 is provided with two types lift pins, spring type lift pins (first pins) 20 and fixed type lift pins (second pins) 28. Each of the spring type lift pins 20 is provided with a coil spring (elastic body) 23 having elasticity in a direction where the pin moves. Each of the fixed type lift pins 28 is not provided with the spring 23. As illustrated in
As illustrated in
The storage position is such a position that upper ends 20a of the spring type lift pins 20 and upper ends 28a of the fixed type lift pins 28 are positioned near the setting surface 11. The protrusion position is such a position that the upper ends 20a of the spring type lift pins 20 and the upper ends 28a of the fixed type lift pins 28 are protruded above the setting surface 11, so that the substrate 4 set on the setting surface 11 can be detached from the setting surface 11. These spring type lift pins 20 and fixed type lift pins 28 are electrically grounded as in the electrode stage 2.
Each of the spring type lift pins 20 is arranged such that a piston section 21 formed in the form of a column along the inner walls of the cylinder 26 is coupled via the coil spring (elastic body) 23 to a pin upper section 22 formed in the form of a bolt so as to be flat on top. The coil spring 23 is the contact adjusting means that brings the upper end 20a into contact with the substrate 4 on the setting surface 11 without lifting the substrate 4 above the setting surface 11, and the coil spring 23 is also elasticity function imparting means that imparts to the spring type lift pin 20 the function having elasticity in the direction where the pin 20 moves. The spring type lift pin 20 is imparted the function having elasticity by the coil spring 23, thereby having elasticity in the length direction, i.e. in the direction where the pin moves.
That is, with the arrangement in which the spring type lift pin 20 has elasticity in the direction where the pin moves, the upper end 20a of the spring type lift pin being withdrawn in the electrode stage 2 can be brought into contact with the substrate 4 on the setting surface 11 by means of elasticity of the spring type lift pin 20, without lifting the substrate 4 above the setting surface 11, even if the upper end 20a of the spring type lift pin 20 cannot be stopped accurately at the position that is at the same level as the setting surface 11a.
In the present embodiment, as illustrated in
As illustrated in
With this arrangement, the plasma treatment apparatus S of the present embodiment is free from the previously-described gap that occurs during the plasma treatment due to the difference in level between the upper end 20a of the spring type lift pin 20 and the setting surface 11. This makes it possible to reduce the occurrence of uneven treatment.
Incidentally, in order to completely press down the spring type lift pin 20 into the cylinder 26 by the force (load) with which the substrate 4 adsorbed by the adsorption mechanism 6 applies to the pin upper section 22, the upper end 20a needs to be positioned below the setting surface 11 in a state where the force (load) with which the substrate 4 applies to the pin upper end 22 is proportional to the force with which the coil spring 23 returns to its original state. Such a design is easily made since a load applied by the substrate to be treated can be increased by means of the adsorption action of the adsorption mechanism 6.
However, as a matter of course, the present embodiment permits a design that can be made considering only a load applied by the self weight of the substrate 4, without considering the adsorption action of the adsorption mechanism 6. In this case, a load applied to one spring type lift pin 20 varies depending upon the weight of the substrate 4, the number of the spring type lift pins 20 disposed, warpage of the substrate, and other factors. Therefore, assuming that spring forces of the coil springs 23 are identical with each other, the position of the upper end 20a in a state where the load applied by the substrate 4 is proportional to the force with which the coil spring 23 returns to its original state is varied by the load applied by the substrate 4. This may cause the upper end 20a to be positioned above the setting surface 11 in the periphery of the setting surface 11 to which a light load is applied. If the upper end 20a in such a proportional state comes above the setting surface 11, the spring type lift pin 20 holds itself with the upper end 20a protruding above the setting surface 11 even when the substrate 4 is set on the setting surface 11.
On the contrary, the substrate 4 is adsorptively held on the setting surface 11 in the present embodiment. This ensures the substrate 4 to be brought into contact with the setting surface 11 even if the substrate 4 is lightweight. In addition, the spring force of the coil spring 23 can be set in accordance with a load applied to the pin upper section 22 in the state where the substrate 4 is adsorbed. This makes it possible to make the spring force stronger than a spring force set in accordance with only a load applied by the self weight of the substrate 4, thus allowing the coil spring 23 to be easily designed, and allowing the coil spring 23 to have a longer life span.
Further, the spring type lift pin 20 is arranged such that a cylindrical member 24 is provided between the piston section 21 and the pin upper section 22 so as to surround the coil spring 23. The lower end of the cylindrical member 24 is fixed to the piston section 21, and the upper end thereof is free. At the shaft of the pin upper section 22, a sword-guard-like stopper 25 is provided so as to come into contact with the cylindrical member 24.
The cylindrical member 24 and the stopper 25 are the ones that restrict the constriction of the coil spring 23. That is, the coil spring 23 constricts when the pin upper section 22 moves downward by being pressed, but the constriction is stopped when the stopper 25 comes into contact with the cylindrical member 24.
In such a manner, the constriction of the coil spring is restricted. This defines a minimum length measurement of the spring type lift pin 20, thus suppressing the deterioration of the coil spring 23 without a pressure more than necessary applied to the coil spring 23. At the step of detaching the substrate 4 from the electrode stage 2, the coil spring 23 is made function as a columnar member by the cylindrical member 24 and the stopper 25. This allows the coil spring 23 to function in the same manner as the fixed type lift pin 28, thus ensuring the substrate 4 to be stably detached.
In this case, the coil spring 23 needs to be constricted until the upper end 20a of the spring type lift pin 20 comes down to the position that is at the same level as the setting surface 11. In view of this, a distance between the cylindrical member 24 and the stopper 25, i.e. a distance traveled by the stopper 25 until the stopper 25 comes into contact with the cylindrical member 24 needs to be set longer than the amount by which the upper end 20a is protruded above the setting surface 11 at the storage position.
Meanwhile, the fixed type lift pin 28 is formed in the form of a column along the inner walls of the cylinder 26, and the diameter of the fixed type lift pin 28 on the rear surface side of the electrode stage 2 (underside in
When the upper end of the fixed type lift pin 28 is positioned below the setting surface 11, a gap 49 occurs between the upper end 28a of the fixed type lift pin 28 and the substrate 104. This causes a voltage drop. However, the voltage drop does not affect the quality of treatment on the substrate 4 since the fixed type lift pins 28 are disposed in the non-treatment region 18b.
Next, the following will describe how to subject the substrate 4 to plasma treatment by means of the above plasma treatment apparatus S.
First of all, in a substrate adsorbing step, the substrate 4 is set on the electrode stage 2 in a state where the spring type lift pin 20 and the fixed type lift pin 28 in the lift pin mechanism 7 are moved to the respective storage positions, as illustrated in
Then, the vacuum pump 50 is driven so that the adsorption holes 6a are depressurized, which makes the substrate 4 adsorptively held on the setting surface 11, as illustrated in
Then, in a plasma generating step, the treatment gas is injected into the counter electrode 3 and evenly supplied from the gas injection holes 8 to the area between the counter electrode 3 and the electrode stage 2. In this state, a predetermined magnitude of voltage is applied from the power source section 10 to the counter electrode 3, so that plasma is generated in the area between the counter electrode 3 and the substrate 4 on the electrode stage 2 at near atmospheric pressure. With the generated plasma, the substrate 4 is subjected to plasma treatment such as etching. The exhaust gas in the chamber 1 is discharged via the discharge pipe 5.
Next, in the substrate detaching step, after the plasma treatment performed, application of a voltage by the power source section 10 and gas supply from the gas injection pipe 9 are stopped. Thereafter, the operation of the vacuum pump 50 is stopped, which moves the spring type lift pin 20 and the fixed type lift pin 28 in the lift pin mechanism 7 from the respective storage positions to the protrusion position. This causes the substrate 4 to be detached from the setting surface 11 for carrying.
Through the above steps, the substrate 4 is subjected to plasma treatment in the plasma treatment apparatus S.
Thus, according to the present embodiment, the setting surface 11 of the electrode stage 2 can be made at the same level as the upper end 20a of the spring type lift pin 20 in the lift pin mechanism 7 during the plasma treatment, and the substrate 4 can be brought into contact with both the electrode stage 2 and the spring type lift pin 20. Therefore, plasma is generated without a gap between the substrate 4 and the electrode stage 2 or between the substrate 4 and the upper end 20a of the spring type lift pin 20, in the vicinity of the spring type lift pin 20. As a result of this, it is possible to subject the whole area of the substrate 4 to even plasma treatment while suppressing a voltage drop caused by the gap. This makes it possible to reduce the occurrence of uneven plasma treatment and incomplete plasma treatment at near atmospheric pressure.
a) is a cross-sectional view schematically illustrating an essential part of the plasma treatment apparatus S, and
As is apparent from comparison between the equivalent circuit in
In the present embodiment, the fixed type lift pins 28 are disposed in the outer region of the electrode stage 2, and the upper end 28a of the fixed type lift pin 28 at the storage position is positioned below the setting surface 11. However, as a matter of course, all of the lift pins, including the lift pins disposed in the outer region of the electrode stage 2, can be changed to the spring type lift pins 20.
However, this case may give rise to the problem illustrated in
In the present embodiment, as illustrated in
Further, in the present embodiment, the fixed type lift pins 28 are disposed in the insulating section 2b of the electrode stage 2, and the cylinders 26 are formed in the insulating section 2b. However, in a case where it is difficult to form holes or the like as the cylinders 26 in the insulating section 2b, a mechanism for detaching an insulating section 39, which is employed instead of the insulating section 2b, from the electrode stage 2 may be provided separately as illustrated in
Still further, as illustrated in
In a case where unevenness caused by such a small gap 15 is detected after the plasma treatment, it is more preferable that films 34 of different dielectric constants are formed respectively on the upper end 20a of the spring type lift pin 20, as illustrated in
Yet further, in the present embodiment, the spring type lift pin 20 holds its position in the storage position, which is a state in which the spring type lift pin 20 is withdrawn underneath the setting surface 11, in such a manner that the upper end 20a is protruded above the setting surface 11 in a state where the substrate 4 is not set on the setting surface 11.
However, the spring type lift pin 20 does not necessarily holds its position in the storage position in such a manner that the upper end 20a is protruded above the setting surface 11. Alternatively, as illustrated in
Also in such an arrangement, variations of stop positions of the lift pins are compensated for by means of the elasticity given to the spring type lift pins 20 in the direction where the pins move, so that the whole area of the substrate 4 can be subjected to even plasma treatment. This makes it possible to reduce the occurrence of uneven plasma treatment and the so-called incomplete treatment at near atmospheric pressure.
Note that in the arrangement illustrated in
Further, in the present embodiment, the coil spring 23, which makes up part of the spring type lift pin 20, is taken as an example of the elasticity function imparting means. In short, the elasticity function imparting means only needs to impart to the lift pin the function having elasticity in a direction where the pin moves. For example, a lift pin having no elasticity in its movement direction, like the fixed type lift pin 28, may be supported by a coil spring, a blade spring, or a rubber material, which is provided separately from the lift pin, so that the lift pin is imparted the function having elasticity in the movement direction.
The apparatus in Second Embodiment is different from that in First Embodiment illustrated in
That is, the arrangement in which the adsorption holes 6a are arranged evenly beneath the setting surface 11 of the electrode stage 2, as illustrated in
In order to solve the above problem, the apparatus in Second Embodiment is arranged as illustrated in
With the electrode stage 2 arranged in this manner, it is possible to obtain the same effect as obtained in First Embodiment, and it is possible to reliably attract and adsorb the substrate 4 to the electrode stage 2, as illustrated in
In First and Second Embodiments, the spring type lift pins 20 having elasticity in a direction of their movement are disposed so that no gap occurs between the substrate 4 and the electrode stage 2 and between the substrate 4 and the upper end of the lift pin in the vicinity of the lift pin. However, First and Second Embodiments are not limited to this. Alternatively, other arrangement may be adopted as long as it enables the substrate 4 in the vicinity of the lift pin to contact with both the electrode stage 2 and the lift pin.
Next, with reference to
First of all, as illustrated in
As the substrate 40, a glass substrate or a plastic substrate is preferably used. However, type of the substrate 40 is not particularly limited as long as it has essential properties of a color filter, such as transparency and mechanical strength. Generally, examples of a pattern of the black matrices 41 include, but are not particularly limited to, a matrix pattern illustrated in
The black matrices 41 form the concavity 42 for receiving ink, and function as a barrier (wall) for preventing inks of different colors in the adjacent concavities 42 from being mixed. A method for forming the black matrices 41 is not particularly limited, and the black matrices 41 may be formed by a known method. For example, it is possible to form the black matrices 41 by performing patterning with a black resin by photolithography or the like method. The thickness of the black matrix is preferably in the range from 0.5 μm to 3.0 μm, particularly preferably 1.0 μm to 2.0 μm.
Then, the substrate 40 on which the black matrices 41 are formed is set on the electrode stage 2 of the plasma treatment apparatus S of First and Second Embodiments so that the black matrices 41 are subjected to water repellent treatment (water repellency step).
The treatment gas is preferably a fluorine-containing gas such as CF4, C2F6, or SF6. However, the treatment gas is not limited to a fluorine-containing gas and may be a gas that gives the black matrices 41 water repellency that can prevent mixture of inks.
In a case where it is necessary to improve water repellency of the concavities 42, UV treatment or plasma treatment using Ar, He, or O2 as a treatment gas may be performed before the above water repellency step (hydrophilicity step).
Next, as illustrated in
The ink 44 is selectively delivered to only the concavities 42 provided between the black matrices 41 while the nozzle 43 goes over the black matrices 41. The delivered ink 44 is preferably thermosetting ink having pigment dispersed therein. The ink 44 can be delivered by a known method.
Thereafter, the ink 44 is dried so as to form a color layer 48. For example, the color layer 48 can be formed by evaporating a solvent in the ink 44 and then burning the ink 44 for thermal polymerization of the ink 44. A method for evaporating a solvent of ink and a burning method may be selected appropriately from known methods according to the states of the ink 44 and the substrate 40.
Through the improvement of the problem of unevenness occurring in the vicinity of a lift pin in the plasma treatment apparatus, a color filter manufactured by the above manufacturing method has an excellent display quality without unevenness. A liquid crystal display device having the thus manufactured color filter provides high-performance, high-quality display and offers a comfortable viewing environment to the user.
Now, taking an example, the following will more specifically describe the procedural steps for manufacturing a liquid crystal panel in which the surface of a substrate is subjected to plasma treatment so that a color filter is formed on the substrate, with the use of the plasma treatment apparatus described in First and Second Embodiments. The present example will be also described with reference to
First of all, as illustrated in
Next, the substrate 40 on which the black matrices were formed was subjected to UV treatment for hydrophilic treatment of the concavities. Then, in the present example, plasma treatment was performed with a fluorine-containing gas by means of the plasma treatment apparatus S of First and Second Embodiments, so that water-repellent treatment was performed on the black matrices 41. In the present example, a contact angle of the hydrophilic concavity 42 with respect to pure water was approximately 10°, and a contact angle of the black matrix 41 with respect to pure water was approximately 90° to 100°.
Next, the ink 44 was delivered from the nozzle 43 as illustrated in
Next, a solvent was evaporated at 100° C. for 10 minutes by means of a hot plate. Then, the ink 44 was burned in an oven at 220° C. for 30 minutes for thermal polymerization of the ink 44. As a result, the colored layer 48 was formed as illustrated in
As described above, a stage device of the present invention includes: a stage having a setting surface on which a substrate to be treated is set; and a lift pin mechanism having first pins, provided in the stage, each capable of emerging from the setting surface, the first pins being protruded so that the substrate is detached from the setting surface, wherein the lift pin mechanism includes contact adjusting means that brings an upper end of the first pin being withdrawn in the stage into contact with the substrate on the setting surface without lifting the substrate above the setting surface.
A plasma treatment apparatus of the present invention is a plasma treatment apparatus which generates plasma in between an electrode stage and a counter electrode at near atmospheric pressure so as to subject a substrate to be treated being set on the electrode stage to plasma treatment, the plasma treatment apparatus including the above stage device as the electrode stage.
According to the arrangement of the stage device of the present invention, the contact adjusting means included in the lift pin mechanism brings the upper end of the first pin being withdrawn in the stage into contact with the substrate set on the setting surface without lifting the substrate above the setting surface (corresponding to adsorption surface). This makes it possible to make the upper end of the first pin positioned at the same level as the setting surface through the use of the substrate.
That is, through the use of the substrate, the stage device is realized in which there is no difference in level between the upper end of the first pin and the setting surface in a state where the substrate is set on the setting surface.
In the plasma treatment apparatus of the present invention, such a stage device of the present invention is used as the electrode stage. This allows the substrate to come into contact with both the setting surface and the first pin even in the vicinity of the first pin.
This arrangement is free from a gap caused by difference in level between the above-described lift pin (first pin) and the setting surface, i.e. a gap between the substrate and lift pin (first pin) or a gap between the substrate and the setting surface, where no plasma is generated and a great voltage drop occurs. This makes it possible to reduce the occurrence of uneven treatment and incomplete treatment on the substrate.
In the stage device of the present invention and the plasma treatment apparatus of the present invention, the contact adjusting means includes elasticity function imparting means that imparts to the first pin a function having elasticity in a direction where the first pin moves, and the upper end of the first pin is brought into contact with the substrate by the elasticity imparted by the elasticity function imparting means.
With this arrangement, the contact adjusting means is realized by elasticity function imparting means that imparts to the first pin the function having elasticity in a direction where the first pin moves, and the upper end of the first pin is brought into contact with the substrate by the elasticity imparted by the elasticity function imparting means. That is, even in the event when the first pin cannot be stopped at such a position that the upper end of the first pin is at the same level as the setting surface due to the limitation of the lift pin mechanism in terms of mechanical precision, the event can be compensated for by a simple arrangement using elasticity. This makes it possible to make the upper end of the first pin bring into contact with the substrate without floating the substrate above the setting surface.
The elasticity function imparting means is realized by, for example, an elastic body being provided to the first pin and having elasticity in the direction where the first pin moves.
The stage device and the plasma treatment apparatus of the present invention can be arranged such that when each of the first pins is at a storage position where the first pin is withdrawn in the stage, the upper end of the first pin is protruded above the setting surface in a state where the substrate is not set on the setting surface, and the upper end of the first pin is positioned at the same level as the setting surface by a load applied by the substrate in a state where the substrate is set on the setting surface.
The stage device and the plasma treatment apparatus of the present invention can be also arranged such that when each of the first pins is at a storage position where the first pin is withdrawn in the stage, the upper end of the first pin is positioned below the setting surface in a state where the substrate is not set on the setting surface, and after the substrate is set on the setting surface, the first pin moves upward so that the upper end thereof comes into contact with the substrate.
Further, the stage device and the plasma treatment apparatus of the present invention is preferably arranged such that the stage is provided with an adsorption mechanism that adsorptively holds the substrate on the setting surface.
Provision of the adsorption mechanism allows the substrate to be adsorptively held on the setting surface. This makes it possible to securely fix the substrate as compared with the arrangement in which the substrate is just set on the setting surface. In addition, a load exerted on the first pin becomes stronger than a load caused only by the self weight of the substrate. This makes it easy to impart elasticity in the direction where the first pin moves and make the upper end of the first pin brought into contact with the substrate without lifting the substrate above the setting surface.
That is, in order to make the upper end of the first pin brought into contact with the substrate without floating the substrate above the setting surface by means of the elasticity of the first pin, the upper end of the first pin needs to be positioned below the setting surface in a state where a load received from the substrate being set is proportional to a force with which the first pin deformed by the load is returned to its original state.
With this arrangement, it is possible to easily make such a design that the upper end of the first pin is positioned below the setting surface in a state where a load received from the substrate is proportional to the force with which the first pin is returned to its original state.
In this case, it is preferable that the adsorption mechanism has a stronger adsorption force in the vicinity of the first pin to which the function having elasticity is imparted than an adsorption force in other area. This makes it possible to more effectively obtain the above action caused by using adsorption force.
Further, the stage device and the plasma treatment apparatus of the present invention can be arranged such that the lift pin mechanism has second pins, provided in the outer region of the stage, each capable of emerging from the setting surface and having no elasticity in a direction where the second pin moves, and an upper end of the second pin is positioned below the setting surface in a state where the second pin is withdrawn in the stage.
As described previously, in order to make the upper end of the first pin brought into contact with the substrate without floating the substrate above the setting surface by means of the elasticity of the first pin, the upper end of the first pin needs to be positioned below the setting surface in a state where a load received from the substrate is proportional to a restoring force. However, since a load received from the substrate is low in the outer region of the stage, the upper end of the first pin may be positioned above the setting surface in a state where both of the forces are proportional to each other. As a result, the substrate may float in an area corresponding to the outer region of the stage.
On the contrary, in the above arrangement, the second pins each of which is capable of emerging from the setting surface and has no elasticity in the direction where the second pin moves are disposed in the outer region of the stage, and the upper end of the second pin is positioned below the setting surface in a state where the second pin is withdrawn in the stage. This prevents the substrate from being floated in an area corresponding to the outer region of the stage.
A display panel substrate of the present invention is a display panel substrate for use in manufacturing a display panel, and the display panel substrate is subjected to surface treatment by means of the above plasma treatment apparatus of the present invention capable of effectively reducing the occurrence of uneven treatment. By manufacturing a display panel including such a display panel substrate, it is possible to provide a display device having an excellent display quality without display irregularity.
The present invention can be applied to the manufacture of a display panel substrate and the like, for example.
Number | Date | Country | Kind |
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2005-379021 | Dec 2005 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2006/325627 | 12/22/2006 | WO | 00 | 8/19/2008 |