Embodiments of the present disclosure relate to semiconductor devices, and more particularly to nanoribbon and nanowire transistor devices with strained channel regions.
As integrated device manufacturers continue to shrink the feature sizes of transistor devices to achieve greater circuit density and higher performance, there is a need to manage transistor drive currents while reducing short-channel effects, parasitic capacitance, and off-state leakage in next-generation devices. Non-planar transistors, such as fin and nanowire-based devices, enable improved control of short channel effects. For example, in nanowire-based transistors the gate stack wraps around the full perimeter of the nanowire, enabling fuller depletion in the channel region, and reducing short-channel effects due to steeper sub-threshold current swing (SS) and smaller drain induced barrier lowering (DIBL).
In order to further improve performance of non-planar transistors, strain engineering is often implemented. Particularly, strain is induced in the source and the drain. This is done by growing semiconductor materials in the source and the drain that has a lattice mismatch with the semiconductor material of the channel between the source and the drain. Additional solutions to enhance the performance of non-planar transistors includes modifying the channel length or reducing the gate dielectric thickness to provide improved channel control.
Described herein are nanoribbon and nanowire transistor devices with strained channel regions, in accordance with various embodiments. In the following description, various aspects of the illustrative implementations will be described using terms commonly employed by those skilled in the art to convey the substance of their work to others skilled in the art. However, it will be apparent to those skilled in the art that the present invention may be practiced with only some of the described aspects. For purposes of explanation, specific numbers, materials and configurations are set forth in order to provide a thorough understanding of the illustrative implementations. However, it will be apparent to one skilled in the art that the present invention may be practiced without the specific details. In other instances, well-known features are omitted or simplified in order not to obscure the illustrative implementations.
Various operations will be described as multiple discrete operations, in turn, in a manner that is most helpful in understanding the present invention, however, the order of description should not be construed to imply that these operations are necessarily order dependent. In particular, these operations need not be performed in the order of presentation.
Nanoribbon devices are described in greater detail below. However, it is to be appreciated that substantially similar devices may be formed with nanowire channels. A nanowire device may include devices where the channel has a width dimension and a thickness dimension that are substantially similar, whereas a nanoribbon device may include a channel that has a width dimension that is substantially larger or substantially smaller than a thickness dimension. As used herein, “high-voltage” may refer to voltages of approximately 1.0V or higher.
As noted above, improvements in the performance of transistors may be achieved by inducing strain in the source and drain of the transistor. However, embodiments disclosed herein may also include nanoribbon or nanowire transistors that include strained channels. That is, the channel that is surrounded by the gate structure may be strained in order to provide improved performance. Particularly, the strain induced in embodiments disclosed herein may be referred to as radial strain. A radial strain is distinct from an axial strain. For example, an axial strain may refer to a strain that is oriented along an axis parallel to the length direction of the channel, whereas the radial strain is oriented substantially perpendicular to centerline along the length direction of the channel. Embodiments may be characterized by a maximum tensile strain in the channel that is approximately 0.5% or greater. As used herein “approximately” may refer to a value that is within 20% of the recited value. For example, approximately 0.5% may refer to a range between 0.4% and 0.6%.
In an embodiment, the radial strain in the channel is induced by the annealing of a sacrificial polymer that is disposed around the workfunction metal. The annealing process shrinks the polymer and induces an outward force on the perimeter of the channel. This induces a radial tensile strain on the channel. In some embodiments, the annealing process may be implemented in an oxygen ambient. As such, some embodiments may also include the presence of oxygen in the workfunction metal. That is, the workfunction metal may be referred to as being selectively oxidized.
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The nanoribbon transistor 100 may comprise a source 105 and drain 105. In some embodiments, the source or drain may be referred to as an S/D region 105 to represent that the region may either be a source 105 or a drain 105. In an embodiment, the S/D regions 105 may comprise an epitaxially grown semiconductor material. The S/D regions 105 may comprise a silicon alloy. In some implementations, the S/D regions 105 comprise a silicon alloy that may be in-situ doped silicon germanium, in-situ doped silicon carbide, or in-situ doped silicon. In alternate implementations, other silicon alloys may be used. For instance, alternate silicon alloy materials that may be used include, but are not limited to, nickel silicide, titanium silicide, cobalt silicide, and possibly may be doped with one or more of boron and/or aluminum. In other embodiments, the S/D regions 105 may comprise alternative semiconductor materials (e.g., semiconductors comprising group III-V elements and alloys thereof) or conductive materials.
In an embodiment, a plurality of semiconductor channels 130 may extend between the pair of S/D regions 105. The semiconductor channels 130 may be arranged in a vertical stack. Four semiconductor channels 130 are illustrated in
In an embodiment, a gate structure 120 may be disposed over the nanoribbon channels 130. The gate structure 120 may comprise spacers 110, a gate dielectric 112, a gate metal 114 and a fill metal 115. The nanoribbon channels 130 may pass through the spacers 110 to contact the S/D regions 105.
In an embodiment, the gate dielectric 112 may surround the nanoribbon channels 130. The material (or materials) chosen for the gate dielectric 112 may be any suitable high dielectric constant materials. For example, the gate dielectric 112 may be, for example, any suitable oxide such as silicon dioxide or high-k gate dielectric materials. Examples of high-k gate dielectric materials include, for instance, hafnium oxide, hafnium silicon oxide, lanthanum oxide, lanthanum aluminum oxide, zirconium oxide, zirconium silicon oxide, tantalum oxide, titanium oxide, barium strontium titanium oxide, barium titanium oxide, strontium titanium oxide, yttrium oxide, aluminum oxide, lead scandium tantalum oxide, and lead zinc niobate. In an embodiment, the gate dielectric 112 may also be subject to an annealing process to improve performance.
In an embodiment, the gate metal 114 wraps around the gate dielectric 112 to provide gate all around (GAA) control of the nanoribbon channel 130. The gate metal 114 may sometimes be referred to as a workfunction metal. That is, the material chosen for the gate metal 114 may be dependent on the workfunction of the material in order to provide a desired voltage threshold (VT) tuning for the nanoribbon transistor 100. For example, when the gate metal 114 will serve as an N-type workfunction metal, the gate metal 114 preferably has a workfunction that is between about 3.9 eV and about 4.2 eV. N-type materials that may be used to form the gate metal 114 include, but are not limited to, hafnium, zirconium, titanium, tantalum, aluminum, and metal carbides that include these elements, e.g., titanium carbide, zirconium carbide, tantalum carbide, hafnium carbide and aluminum carbide. Alternatively, when the gate metal 114 will serve as a P-type workfunction metal, the gate metal 114 preferable has a workfunction that is between about 4.9 eV and about 5.2 eV. P-type materials that may be used to form the gate metal 114 include, but are not limited to, ruthenium, palladium, platinum, cobalt, nickel, and conductive metal oxides, e.g., ruthenium oxide. In an embodiment, a fill metal 115 (e.g., tungsten) may be disposed over the gate metal 114.
In an embodiment, portions of the nanoribbon channels 130 that are surrounded by the gate structure 120 may be strained. Straining the nanoribbon channels 130 increases the carrier mobility within the nanoribbon channels 130 and improves efficiency. In an embodiment, the strain in the nanoribbon channels 130 is a tensile strain. In a particular embodiment, the tensile strain is a radial strain on the nanoribbon channels 130. That is, the nanoribbon channels 130 are strained by expanding the cross-section of the nanoribbon channels 130 shown in
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In
As shown, the strain between points A and B along the line through the thickness of the nanoribbon channel 230 may have a decreasing slope. That is, larger strains may be exhibited closer to the surface of the nanoribbon channel 230. At point B, the strain may be approximately 0%. That is, portions of the nanoribbon channel 230 between points B and C may be an unstrained region 232. Between points C and D, the strain may have a positive slope. In an embodiment, the nanoribbon channel 230 may exhibit a maximum strain that is approximately 0.5% or greater.
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It is to be appreciated that strain measurements of the nanoribbon channels 230 may be obtained with a variety of different analytical techniques. One exemplary analytical technique to determine the strain distribution within a nanoribbon channel 230 may include the use of TEM imaging and analysis. Additionally, the strain distributions illustrated in
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The relatively high concentration of oxygen in the gate metal 314 may be an artifact of processing used to induce strain in the nanoribbon channel 330. As will be described in greater detail below, a sacrificial polymer may be disposed around the gate metal 314 and annealed in an oxygen ambient in order to induce the strain in the nanoribbon channel 330. Such a process may result in the selective oxidation of the gate metal 314, particularly, the outer surfaces of the gate metal 314. As such, the oxygen concentration proximate to the outer surface of the gate metal 314 may be higher than an oxygen concentration within an internal volume of the gate metal 314 and/or at the surface of the gate metal 314 that interfaces with the gate dielectric 312.
While an oxygen concentration distribution such as the one described with respect to
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In an embodiment, first nanoribbon channels 430A may have volumes that are substantially unstrained regions 432, and second nanoribbon channels 430B may have volumes that comprise a strained region 431. In some embodiments, the second nanoribbon channels 430B may have both a strained region 431 and an unstrained region 432 (similar to the embodiment shown in
In an embodiment, the first nanoribbon channels 430A may be located above the second nanoribbon channels 430B (with respect to the substrate 401). While two first nanoribbon channels 430A and 430B are shown, it is to be appreciated that the number of first nanoribbon channels 430A may be different than the number of second nanoribbon channels 430B.
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In an embodiment, the first transistor 500A and the second transistor 500B may comprise S/D regions 505 over a substrate 501 and an insulator 503. Nanoribbon channels 530 may extend between pairs of S/D regions 505. Each transistor 500A and 500B may comprise a gate structure 520. The gate structure 520 may comprise a gate dielectric 512, a gate metal 514, a fill metal 515, and spacers 510.
In an embodiment, one or both of the first transistor 500A and the second transistor 500B may comprise strained nanoribbon channels 530. The nanoribbon channels 530 may be strained similar to those described above with respect to
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Nanoribbon transistor 500A may utilize S/D regions 5051 and 5052, and nanoribbon transistor 500B may utilize S/D regions 5053 and 5054. In an embodiment, S/D region 5051 may be electrically isolated from S/D region 5053 by an insulating layer 556, and S/D region 5052 may be electrically coupled to S/D region 5054 by a conducting layer 557.
The second inverter 555B may have a similar stacked transistor configuration with a shared gate structure 520. For example, transistor 500C is below transistor 500D. In some embodiments, the conductivity types of the transistors 500 in the second inverter 555B may be opposite of those in the first inverter 555A. For example, transistor 500C may be the opposite conductivity type of the bottom transistor 500A in the first inverter 555A, and transistor 500D may be the opposite conductivity type of the top transistor 500B in the first inverter 555A. In other embodiments, the conductivity types of the first inverter 555A may match the conductivity types of the second inverter 555B.
In an embodiment, one or more of the nanoribbon channels 530 of the first inverter 555A and/or the second inverter 555B may be strained. In some embodiments, the nanoribbon channels 530 may have both a strained region and an unstrained region (similar to the embodiment shown in
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In an embodiment, the channel layers 634 are the material chosen for use as the nanoribbon channels of the finished device. The channel layers 634 and sacrificial layers 637 may each be a material such as, but not limited to, silicon, germanium, SiGe, GaAs, InSb, GaP, GaSb, InAlAs, InGaAs, GaSbP, GaAsSb, and InP. In a specific embodiment, the channel layers 634 are silicon and the sacrificial layers 637 are SiGe. In another specific embodiment, the channel layers 634 are germanium, and the sacrificial layers 637 are SiGe. The channel layers 634 and the sacrificial layers 637 may be grown with an epitaxial growth processes.
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The curing of the sacrificial polymer 681 may result in shrinkage of the cured sacrificial polymer 682. That is, the volume of the cured sacrificial polymer 682 may decrease. The shrinkage radially pulls against the gate metal 614. The force against the gate metal 614 is transferred through the gate dielectric 612 and induces a radial tensile strain on the nanoribbon channels 630. For example, the nanoribbon channels 630 may include a strained region 631. In some embodiments, the nanoribbon channels 630 may also include a substantially unstrained region 632 at the core of the nanoribbon channels 630, similar to the embodiment illustrated in
In an embodiment where the curing process is implemented in an oxygen ambient, the gate metal 614 may have an excess oxygen concentration. The oxygen from the ambient may diffuse through the sacrificial polymer 682 and oxidize portions of the gate metal 614. Particularly, the outer surfaces of the gate metal 614 may have a relatively higher oxygen concentration than an interior surface of the gate metal 614 that is in contact with the gate dielectric 612. For example, the oxygen concentration through a thickness of the gate metal 614 may be similar to the oxygen concentration distribution depicted in
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In an embodiment, a sacrificial polymer 781 is disposed over one or more of the nanoribbon channels 730. Particularly, in the illustrated embodiment, the bottom two nanoribbon channels 730 are surrounded by the sacrificial polymer 781, and the top two nanoribbon channels 730 are not covered by a sacrificial polymer 781.
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In an embodiment, a sacrificial polymer 881 may be disposed around the nanoribbon channels 830 between the spacers 810. As shown, the sacrificial polymer 881 in the first transistor 800A may cover a different number of nanoribbon channels 830 than the sacrificial polymer 881 in the second transistor 800B. For example, a patterning process may be used to form the sacrificial polymers 881 with non-uniform thicknesses. In the particular embodiment illustrated in
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Depending on its applications, computing device 900 may include other components that may or may not be physically and electrically coupled to the board 902. These other components include, but are not limited to, volatile memory (e.g., DRAM), non-volatile memory (e.g., ROM), flash memory, a graphics processor, a digital signal processor, a crypto processor, a chipset, an antenna, a display, a touchscreen display, a touchscreen controller, a battery, an audio codec, a video codec, a power amplifier, a global positioning system (GPS) device, a compass, an accelerometer, a gyroscope, a speaker, a camera, and a mass storage device (such as hard disk drive, compact disk (CD), digital versatile disk (DVD), and so forth).
The communication chip 906 enables wireless communications for the transfer of data to and from the computing device 900. The term “wireless” and its derivatives may be used to describe circuits, devices, systems, methods, techniques, communications channels, etc., that may communicate data through the use of modulated electromagnetic radiation through a non-solid medium. The term does not imply that the associated devices do not contain any wires, although in some embodiments they might not. The communication chip 906 may implement any of a number of wireless standards or protocols, including but not limited to Wi-Fi (IEEE 802.11 family), WiMAX (IEEE 802.16 family), IEEE 802.20, long term evolution (LTE), Ev-DO, HSPA+, HSDPA+, HSUPA+, EDGE, GSM, GPRS, CDMA, TDMA, DECT, Bluetooth, derivatives thereof, as well as any other wireless protocols that are designated as 3G, 4G, 5G, and beyond. The computing device 900 may include a plurality of communication chips 906. For instance, a first communication chip 906 may be dedicated to shorter range wireless communications such as Wi-Fi and Bluetooth and a second communication chip 906 may be dedicated to longer range wireless communications such as GPS, EDGE, GPRS, CDMA, WiMAX, LTE, Ev-DO, and others.
The processor 904 of the computing device 900 includes an integrated circuit die packaged within the processor 904. In an embodiment, the integrated circuit die of the processor 904 may comprise a semiconductor channel with radial tensile strain, as described herein. The term “processor” may refer to any device or portion of a device that processes electronic data from registers and/or memory to transform that electronic data into other electronic data that may be stored in registers and/or memory.
The communication chip 906 also includes an integrated circuit die packaged within the communication chip 906. In an embodiment, the integrated circuit die of the communication chip 906 may comprise a semiconductor channel with radial tensile strain, as described herein.
In further implementations, another component housed within the computing device 900 may comprise a semiconductor channel with radial tensile strain, as described herein.
In various implementations, the computing device 900 may be a laptop, a netbook, a notebook, an ultrabook, a smartphone, a tablet, a personal digital assistant (PDA), an ultra mobile PC, a mobile phone, a desktop computer, a server, a printer, a scanner, a monitor, a set-top box, an entertainment control unit, a digital camera, a portable music player, or a digital video recorder. In further implementations, the computing device 900 may be any other electronic device that processes data.
The interposer 1000 may be formed of an epoxy resin, a fiberglass-reinforced epoxy resin, a ceramic material, or a polymer material such as polyimide. In further implementations, the interposer 1000 may be formed of alternate rigid or flexible materials that may include the same materials described above for use in a semiconductor substrate, such as silicon, germanium, and other group III-V and group IV materials
The interposer 1000 may include metal interconnects 1008 and vias 1010, including but not limited to through-silicon vias (TSVs) 1012. The interposer 1000 may further include embedded devices 1014, including both passive and active devices. Such devices include, but are not limited to, capacitors, decoupling capacitors, resistors, inductors, fuses, diodes, transformers, sensors, and electrostatic discharge (ESD) devices. More complex devices such as radio-frequency (RF) devices, power amplifiers, power management devices, antennas, arrays, sensors, and MEMS devices may also be formed on the interposer 1000. In accordance with embodiments of the disclosure, apparatuses or processes disclosed herein may be used in the fabrication of interposer 1000.
Thus, embodiments of the present disclosure may comprise a semiconductor channel with radial tensile strain, and the resulting structures.
The above description of illustrated implementations of the invention, including what is described in the Abstract, is not intended to be exhaustive or to limit the invention to the precise forms disclosed. While specific implementations of, and examples for, the invention are described herein for illustrative purposes, various equivalent modifications are possible within the scope of the invention, as those skilled in the relevant art will recognize.
These modifications may be made to the invention in light of the above detailed description. The terms used in the following claims should not be construed to limit the invention to the specific implementations disclosed in the specification and the claims. Rather, the scope of the invention is to be determined entirely by the following claims, which are to be construed in accordance with established doctrines of claim interpretation.
Example 1: a semiconductor device, comprising: a source; a drain; a semiconductor channel between the source and the drain, wherein the semiconductor channel has a non-uniform strain through a thickness of the semiconductor channel; and a gate stack around the semiconductor channel.
Example 2: the semiconductor device of Example 1, wherein a first strain at a surface of the semiconductor channel is greater than a second strain within the semiconductor channel.
Example 3: the semiconductor device of Example 2, wherein the second strain is approximately 0%.
Example 4: the semiconductor device of Example 2, wherein the second strain is greater than approximately 0%.
Example 5: the semiconductor device of Examples 2-4, wherein the first strain is approximately 0.5% or greater.
Example 6: the semiconductor device of Examples 1-3, wherein the non-uniform strain is a tensile strain.
Example 7: the semiconductor device of Examples 1-6, wherein the gate stack comprises: a gate dielectric on the semiconductor channel; and a gate metal on the gate dielectric.
Example 8: the semiconductor device of Example 7, wherein the gate metal comprises oxygen.
Example 9: the semiconductor device of Example 8, wherein a first concentration of oxygen at a surface of the gate metal facing away from the gate dielectric is greater than a second concentration of oxygen at a surface of the gate metal facing the gate dielectric.
Example 10: the semiconductor device of Examples 1-9, wherein the semiconductor channel is a nanowire or a nanoribbon.
Example 11: a semiconductor device, comprising: a source; a drain; a plurality of semiconductor channels arranged in a vertical stack between the source and the drain, wherein individual ones of the semiconductor channels comprise a radial tensile strain; a gate dielectric surrounding individual semiconductor channels; and a gate metal surrounding the gate dielectric.
Example 12: the semiconductor device of Example 11, wherein a first semiconductor channel of the plurality of semiconductor channels has a first maximum tensile strain, and a second semiconductor channel of the plurality of semiconductor channels has a second maximum tensile strain, wherein the first maximum tensile strain is greater than the second maximum tensile strain.
Example 13: the semiconductor device of Example 12, wherein the first semiconductor channel is below the second semiconductor channel.
Example 14: the semiconductor device of Example 12 or Example 13, wherein the first maximum tensile strain is approximately 0.5% or greater.
Example 15: the semiconductor device of Examples 11-14, wherein the gate metal comprises oxygen.
Example 16: the semiconductor device of Example 15, wherein an oxygen concentration along a line from an outer surface of the gate dielectric to a center of an individual one of the semiconductor channels, comprises: a decreasing oxygen concentration form the outer surface of the gate dielectric to an inner surface of the gate dielectric; an increasing oxygen concentration through a thickness of the gate dielectric; and a decreasing oxygen concentration into the individual one of the semiconductor channels.
Example 17: the semiconductor device of Examples 11-16, wherein individual semiconductor channels are nanowires or nanoribbons.
Example 18: a method of forming a semiconductor device, comprising: forming a semiconductor channel; disposing a gate dielectric around the semiconductor channel; disposing a gate metal around the gate dielectric; disposing a sacrificial polymer around the gate metal; annealing the sacrificial polymer, wherein annealing the sacrificial polymer reduces a volume of the sacrificial polymer and induces a tensile strain into the semiconductor channel; and removing the sacrificial polymer.
Example 19: the method of Example 18, wherein the sacrificial polymer is annealed in an oxygen ambient.
Example 20: the method of Example 19, wherein the annealing results in oxygen incorporated into the gate metal.
Example 21: the method of Examples 18-20, wherein the sacrificial polymer is annealed in an inert ambient.
Example 22: the method of Examples 18-21, wherein the tensile strain is approximately 0.5% or greater.
Example 23: the method of Examples 18-22, wherein the semiconductor channel is a nanowire or a nanoribbon.
Example 24: an electronic device, comprising: a board; a semiconductor package coupled to the board; and a die coupled to the semiconductor package, wherein the die comprises: a source; a drain; a semiconductor channel between the source and the drain, wherein the semiconductor channel comprises a radial tensile strain; and a gate stack around the semiconductor channel.
Example 25: the electronic device of Example 24, wherein the semiconductor channel is a nanowire or a nanoribbon.