This disclosure is generally related to optical spectrometers. More specifically, this disclosure is related to implementing raster scanning in optical spectrometers.
Optical spectrometers that rely on the detection of reflected and scattered light to perform spectral analysis typically detect very weak signals. For example, a Raman spectrometer can use a laser beam to excite inelastic scattering (also known as Raman scattering) of photons, and the returning Raman scattered signal can be one million times weaker than the excitation source. Because the signals of interest are so weak, the detection of low concentration elements in the sample often uses high power densities of excitation light as well as prolonged exposure times (e.g., typically 1-10 seconds). The most common way to achieve a higher power density for a given source is by focusing the excitation source to a very small spot size, typically under 100 microns in diameter.
This extremely small spot size of the excitation source can present two main challenges in applications of Raman spectrometers. First, the high power density and the prolonged exposure time of the excitation source may damage the sample, or even cause a fire or explosion for certain sample types. Second, measurement on non-homogeneous samples can be challenging as it involves performing many measurements in different physical locations to ensure that all contents of the sample are measured accurately and repeatably.
One embodiment provides an apparatus for facilitating raster scanning of an optical spectrometer. The apparatus can include an enclosure, a lens holder situated within the enclosure, and an actuation mechanism coupled to the lens holder. The lens holder is configured to hold a lens that focuses excitation light onto a sample surface, and the actuation mechanism is configured to cause the lens holder to perform a motion according to a predetermined pattern, thereby causing the focused excitation light to raster scan the sample surface.
In a variation on this embodiment, the lens holder is mechanically coupled to internal walls of the enclosure via one or more springs, and the actuation mechanism comprises at least one motor configured to compress or expand the springs.
In a further variation, the at least one motor is a vibration motor, and the springs are flat springs.
In a further variation, the at least one motor is a rotation motor configured to cause the lens holder to rotate off axis.
In a further variation, the at least one motor comprises a hollow core, and the lens holder and the one or more springs are situated inside the hollow core.
In a variation on this embodiment, the lens holder is coupled to a shaking plate, and the actuation mechanism comprises at least one motor configured to cause the shaking plate to move in a plane perpendicular to an optical axis of the lens.
In a variation on this embodiment, the lens holder is coupled to a linear rail system, and the actuation mechanism comprises a voice coil actuator.
In a variation on this embodiment, the apparatus further comprises a constraint mechanism configured to constrain motions of the lens holder to a plane that is substantially perpendicular to an optical axis of the lens.
In a variation on this embodiment, the apparatus further comprises a light-blocking mechanism surrounding the lens holder configured to prevent light from circumventing the lens holder to reach the detector.
In a variation on this embodiment, the apparatus further comprises an actuation control mechanism configured to control one or more parameters of the actuation mechanism in order to control a motion pattern of the lens holder.
One embodiment provides an optical spectrometer. The optical spectrometer can include a light source configured to provide excitation light, an excitation lens system configured to focus the excitation light onto a sample surface, and a detector configured to detect signals excited by the excitation light from the sample surface. The excitation lens system comprises a lens and an actuation mechanism coupled to the lens, and the actuation mechanism is configured to cause the lens to perform a motion according to a predetermined pattern, thereby causing the focused excitation light to raster scan the sample surface.
In the figures, like reference numerals refer to the same figure elements.
The following description is presented to enable any person skilled in the art to make and use the embodiments and is provided in the context of a particular application and its requirements. Various modifications to the disclosed embodiments will be readily apparent to those skilled in the art, and the general principles defined herein may be applied to other embodiments and applications without departing from the spirit and scope of the present disclosure. Thus, the present invention is not limited to the embodiments shown but is to be accorded the widest scope consistent with the principles and features disclosed herein.
Embodiments described herein solve the technical problem of enabling raster scanning in Raman spectrometers. Instead of moving the sample or using a mirror to steer the exciting laser beam, in some embodiments of the present application, the lens system (e.g., a lens barrel) that focuses the exciting laser beam onto the sample is configured to move in a plane perpendicular to the optical path to achieve raster scanning. In one embodiment, the lens barrel can be attached to a system of springs and one or more motors can disturb the springs, thus causing the lens barrel to move within the perpendicular plane according to a predetermined raster pattern. In addition to springs, other mechanisms, such as off-centered rotation, a shaking plate, or a stacked linear rail system, can also be used to achieve the raster of the laser beam. In addition, the lens system can also be enclosed in a multiwalled housing to prevent light leakage.
Raman Spectrometer with Raster Scanning
During operation, a laser beam emitted from laser 102 is reflected by dichroic filter 104, which is configured to block/reflect the laser wavelength, and mirror 106. The reflected laser beam is then focused by first lens 108 onto the surface of sample 110. Excited Raman signals can be collected by first lens 108 and reflected by mirror 106 and then pass through dichroic filter 104 (which is configured to pass the Raman wavelength) and longpass filter 112 before being focused by second lens 114. Second lens 114 focuses the Raman signals onto slit 116, which is placed in front of dispersive-and-detection optical module 118 to block noise. Dispersive-and-detection optical module 118 can facilitate spectra analysis on the Raman signals. For example, dispersive-and-detection optical module can include dispersive optics for dispersing the Raman signals and a detector for detecting the dispersed signal.
To prevent the sample from being exposed to high-intensity light for a prolonged period and to increase the measurement area, raster scanning of the sample surface has been proposed. Raster scanning refers to the act of rapidly and continuously moving the focused excitation spot around the sample, such that the measured Raman signals are averaged over the scanned area. For example, if the focused excitation spot has a diameter of around 100 microns, the raster scanning area (i.e., the area within which the focused spot moves around) can have a diameter of a few millimeters (e.g., two millimeters). Raster scanning can lower the overall power density on a sample (for a given exposure time) as well as increase the sampling area without sacrificing the benefits of a small spot size. With raster scanning, the exposure time per unit area can be decreased, thus allowing the sample to dissipate the received excitation energy without being damaged. Also, the spectrum returned from the larger area can better represent the sample, because any non-uniformities are averaged out with the signal collected from the entire scanned area.
One way to accomplish raster scanning is to move the sample several times (or continuously) during exposure to form a composite return signal. However, moving the sample (or the whole spectrometer) is often undesirable and sometimes not feasible. Another approach for raster scanning can involve moving mirror 106 in order to steer the beam from the excitation source (e.g., laser 102). However, this approach can have several disadvantages. For example, in a confocal system as shown in
To achieve raster scanning without the above problems, in some embodiments of the instant application, the lens focusing the excitation light onto the sample can move within a plane perpendicular to the optical path of the light excitation, thus steering the focused beam spot on the sample to form a raster pattern. More specifically, the excitation beam spot and the lens move together with a 1:1 ratio. In other words, a one-millimeter displacement of the lens can result in a one-millimeter displacement of the excitation beam spot.
Laser 202 can be a diode laser capable of producing high-intensity light at Raman excitation wavelengths (e.g., 785 nm). During measurement, a laser beam emitted from laser 202 can be reflected by dichroic filter 204 and focused, along the Z-axis, by moving lens 206 onto the surface of sample 208. In this example, the Z-axis can be along the optical axis of moving lens 206 and fixed lens 212. Because the moving lens 206 focuses the excitation light, it can also be referred to as the excitation lens. When moving lens 206 moves in the X-Y plane (as indicated by the hollow double arrows) so will the focused beam spot of the excitation light. The focused excitation light excites Raman signals from the sample, and the scattered Raman signals can be collected by moving lens 206 and can pass through dichroic filter 204 and longpass filter 210 before being focused by fixed lens 212. Unlike moving lens 206, the location of fixed lens 212 remains unchanged. Fixed lens 212 focuses the Raman signals onto slit 214, which is placed in front of dispersive-and-detection optical module 216.
Compared with the spectrometer shown in
Different mechanisms can be used to provide planar movement of the excitation lens (i.e., moving lens 206 shown in
Frame 302 can be a physical enclosure that encloses all other components of lens-motion system 300. In some embodiments, frame 302 can be made of a rigid material and can remain stationary during the operation of the spectrometer. A flat spring can be made of a flat strip of material, typically metal. They have different shapes and sizes. In the example shown in
Lens tube 312 can enclose the excitation lens. In many applications, the excitation lens can be a compound lens that includes multiple (e.g., two) thin lenses. In one embodiment, lens tube 312 can enclose achromatic lenses (e.g., an achromatic doublet). Lens tube 312 can be supported and mechanically coupled to all flat springs such that deformation of any flat spring can cause displacement of lens tube 312. In the example shown in
Vibration motor 314 can be attached to one of the flat springs (e.g., flat spring 304). When vibration motor 314 vibrates (or wobbles), flat spring 304 is deformed (e.g., compressed and expanded), causing lens tube 312 to move along with flat spring 304. The continuous vibration of vibration motor 314 can lead to continuous motion of lens tube 312. In one embodiment, the vibration or wobbling of vibration motor 314 can result in a circular motion of lens tube 312, and the radius of the circle can depend on the amplitude of the vibration. The amplitude of the vibration can depend on the stiffness of the spring and/or the parameters (e.g., the drive strength) of vibration motor 314. In other words, a particular raster pattern can be obtained by carefully selecting and configuring parameters associated with the springs and vibration motor 314. In further embodiments, the drive strength of vibration motor 314 can vary in time to produce a time-varying raster pattern (e.g., a spiral pattern). If the drive strength varies with time periodically, the raster pattern can also vary with time periodically. For example, in most applications, for each measurement, the sample may be exposed to the excitation light for a duration between 1 and 10 seconds. In such a situation, the drive strength may vary with time at a frequency of about 10 Hz. Consequently, the raster pattern can also vary with time at a frequency of about 10 Hz.
In the example shown in
It is important to note that the moving lens should be constrained such that the moving lens does not experience angular displacement with regard to the system's optical path (i.e., along the Z-axis). If the lens angle changes, then the returned Raman signals may not be properly focused onto the detector. Flat springs can be advantageous in this regard because they typically resist rotation along their width. In addition, frame 302 can also include opposite flat walls that can confine the movements of lens tube 312 to be within the X-Y plane.
In addition to flat springs, other types of spring, such as wire or coil springs, can also be used in the lens-motion system to move the excitation lens, as long as there is a restraining system that confines movements of the excitation lens in the X-Y plane. Moreover, in addition to having the flat springs attached to a rigid body, in some embodiments, the lens-motion system can be a unibody construction where the springs are a single piece together with the outer frame. In one embodiment, a mold material, such as plastic, silicon, or rubber, can be used to construct the unibody lens-motion system.
The operation principle of unibody lens-motion system 400 can be very similar to that of lens-motion system 300 shown in
Rotation motor 504 can be any direct current (DC) motor, stepper, or AC motor that rotates at a predetermined speed. Lens-and-spring housing 506 can have a circular outer body and can include an oblong cavity 508, which can enclose lens tube 510 and a spring 512. In one embodiment, spring 512 can be a wire spring. In alternative embodiments, spring 512 can be made of any elastic material that can compress and expand responsive to an external force. One end of spring 512 can be attached to or in contact with the inner wall of oblong cavity 508, and the other end of spring 512 can be attached to or merely in contact with lens tube 510. Lens tube 510 is not attached to the inner wall of oblong cavity 508. When lens-and-spring housing 506 remains stationary, spring 512 is expanded and pushes lens tube 510 against the corresponding end wall of oblong cavity 508. However, when spring 512 is compressed, lens tube 510 can slide within the inner wall of oblong cavity 508. Note that the shorter axis of oblong cavity 508 is slightly larger that the diameter of lens tube 510, providing the freedom for lens tube 510 to move along the longer axis of oblong cavity 508 but preventing movement along the shorter axis. In addition to the single-spring configuration shown in
The edge of rotation motor 504 can be in contact and engage with the edge of the circular body of lens-and-spring housing 506, such that the rotation of rotation motor 504 can drive or actuate the rotation of lens-and-spring housing 506. In
During operation, rotation motor 504 can rotate at a predetermined speed, causing lens-and-spring housing 506 to rotate. Because their edges are in contact, the linear speeds of rotation motor 504 and lens-and-spring housing 506 can be the same, meaning that their angular speed can be reversely proportional to their radius. As lens-and-spring housing 506 rotates, the centrifugal force can push lens tube 510 away from the center of rotation, compressing spring 512. The range of movement of lens tube 510 can be controlled by controlling the rotation speed of rotation motor 504. In other words, a desired raster pattern can be generated by controlling the rotation speed of rotation motor 504. If the rotation speed varies in time, so will the raster pattern. In one embodiment, a continuously varying (e.g., from low to high and then from high to low) rotation speed can result in the raster pattern being an expanding and then contacting spiral pattern.
In the example shown in
Rotational lens housing 522 can include a hollow core motor that rotates responsive to a drive current, and cavity 524 can be its hollow core. An opaque filling material can be placed between the inner wall of cavity 524 and lens tube 526 to fix the location of lens tube 526. Because lens tube 526 is off center of rotational lens housing 522, when rotational lens housing 522 rotates about its center, lens tube 526 will also move in a circle around the center of rotational lens housing 522. The radius of such circular motion can be the distance between the centers of rotational lens housing 522 and lens tube 526, as indicated by line segment 528 in
Compared with other lens-motion systems (e.g., the systems shown in
Note that when the filling material is rigid, the length of line segment 528 remains a constant. In other words, the raster scanning area remains a constant. In some embodiments, instead of a rigid material, a soft, flexible material (e.g., plastic, silicone, gel, rubber, etc.) can be used as the filling material. This way, similar to what is shown in
Raster Scanning with Bearings and Rails
Supporting frame 602 can be similar to the one shown in
Vibration motor 612 is coupled to (e.g., attached to) shaking plate 610 such that the vibration of vibration motor 612 dives motion of shaking plate 610. Because shaking plate 610 in confined between coil spring 604 and the ball bearings, motion of shaking plate 610 is confined in the X-Y plane. In one embodiment, vibration motor 612 can cause shaking plate 610 to move (e.g., shake in a random pattern) in the plane between coil spring 604 and the ball bearings.
Lens 614 is attached to shaking plate 610. In one embodiment, shaking plate 610 can include an aperture, and lens 614 can fit into the aperture snugly. This way, when shaking plate 610 moves in the X-Y plane, lens 614 also moves in the X-Y plane. In some embodiments, shaking plate 610 can rotate or perform circular movements, and the range of the movement can be determined by the speed of vibration motor 612. Hence, the raster pattern of lens 614 can be controlled by configuring the speed of vibration motor 612. In one embodiment, the speed of vibration motor 612 can vary with time, thus leading to a time-varying rater pattern.
One advantage provided by the linear-bearing configuration is that the divergence angle of lens 614 is well-controlled during vibration, because shaking plate 610 is constrained by the ball bearings and coil spring 604. The ball bearings can also reduce noise resulting from mechanical friction. Moreover, the opaque nature of shaking plate 610 can also prevent light from leaking around lens 614, thus satisfying the light-blocking requirement.
In some embodiments, voice coil actuators (VCAs) can be used to control the movement of the liner rail systems, which can provide great accuracy and speed in controlling the position of the excitation lens. Moreover, decoupling motions in the X and Y directions can also make it possible to generate arbitrary raster patterns. Theoretically speaking, any number of specific raster patterns can be generated.
The linear-rail configuration can also ensure that the angular displacement of the lens is minimized because the motion is constrained by the linear rails to a planar motion (e.g., in the X-Y plane). In addition, like shaking plate 610 shown in
As discussed previously, light passing around the excitation lens may reach the detector, thus causing noise. Although a number of configurations of the lens-motion system have built-in light-blocking mechanisms (e.g., systems shown in
To further ensure that no light can pass around the excitation lens (e.g., lens tube 312 shown in
The left drawing of
Laser source 1002 can be responsible for providing high-intensity excitation light to be shone on a sample. Excitation lens 1004 can be responsible for focusing the excitation light onto the sample surface. Actuation mechanism 1006 can be coupled to the excitation lens 1004 and, when activated, can cause excitation lens 1004 to move within a plane substantially perpendicular to the optical axis of excitation lens 1004. In one embodiment, actuation mechanism 1006 can include a supporting mechanism that supports excitation lens 1004 and a motor that actuates/disturbs the supporting mechanism, thereby causing excitation lens 1004 to move.
Constraint mechanism 1008 can be responsible for constraining the movements of excitation lens 1004 to the plane substantially perpendicular to its optical axis. Constraint mechanism 1008 is optional because, in some embodiments, actuation mechanism 1006 can include a built-in constraint mechanism. Light-blocking mechanism 1010 can be responsible for blocking the light from circumventing excitation lens 1004 to reach dispersive-and-detection optical module 1016. Detection lens 1012 can be responsible for focusing light from the sample excited by the excitation light onto dispersive-and-detection optical module 1016. Spatial filter 1014 can be a slit or a pinhole and can be responsible for blocking out-of-focus light from reaching dispersive-and-detection optical module 1016.
In general, the disclosed embodiments provide a system and method for realizing a low-cost, compact spectrometer with raster scanning. The spectrometer can include a laser source for generating excitation light, an excitation lens system for focusing the excitation light onto the sample surface, a dispersive-detection system for detecting the excited light signals, and a lens system for focusing the excited light onto the detector. More specifically, the excitation lens system can include an actuator that actuates the lens to move according to a predetermined or random movement pattern. Different types of actuators can be used, including but not limited to: one or more vibration motors, one or more rotation motors, one or more voice coil motors, etc. The moving lens system can result in the focused beam spot performing raster scanning. Raster scanning of the sample surface prevents damage to the sample surface and increases the accuracy of the measurement. In addition to one or more motors that drive the motion, the lens system also includes a constraining mechanism that can constrain the motion of the lens system to a plane perpendicular to the optical path to ensure that excited signals can reach the detector properly. Moreover, a light-blocking structure can be included in the excitation lens system to prevent light from circumventing the lens system to reach the detector. Although a Raman spectrometer is used in the various examples, similar raster scanning mechanisms can be used in other types of optical spectrometers.
The foregoing descriptions of embodiments of the present invention have been presented for purposes of illustration and description only. They are not intended to be exhaustive or to limit the present invention to the forms disclosed. Accordingly, many modifications and variations will be apparent to practitioners skilled in the art. Additionally, the above disclosure is not intended to limit the present invention. The scope of the present invention is defined by the appended claims.
This application claims the benefit of U.S. Provisional Application No. 63/159,285, Attorney Docket Number OKA21-1001PSP, titled “System and Method for Facilitating Optical Raster Scanning,” by inventors Ruibo Wang and James F. Gass, filed on 10 Mar. 2021, the disclosure of which is incorporated herein by reference in its entirety.
Number | Date | Country | |
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63159285 | Mar 2021 | US |