The present invention generally relates to plasma-based light sources, and, more particularly, to plasma formed by transverse laser pumping.
The need for improved illumination sources used for characterization of ever-shrinking integrated circuit device features continues to grow. One such illumination source includes a laser-sustained plasma (LSP) source. Laser-sustained plasma light sources are capable of producing high-power broadband light. Laser-sustained light sources operate by focusing laser radiation into a gas volume in order to excite the gas, such as argon or xenon, into a plasma state, which is capable of emitting light. This effect is typically referred to as plasma “pumping.” In typical LSP sources, pump light is focused to a single point. In the case where pumping light is focused to a single point, the laser intensity is the highest in a small region of space surrounding the focal point. The plasma shaping options are limited to the direction and numerical aperture (NA) of the laser focused to this point.
As shown in
A system for transverse pumping of light-sustained plasma is disclosed. In one illustrative embodiment, the system includes a pump source configured to generate pumping illumination. In another illustrative embodiment, the system includes one or more illumination optical elements. In another illustrative embodiment, the system includes a gas containment structure configured to contain a volume of gas. In another illustrative embodiment, the one or more illumination optical elements are configured to sustain a plasma within the volume of gas of the gas containment structure by directing pump illumination along a pump path to one or more focal spots within the volume of gas. In another illustrative embodiment, the system includes one or more collection optical elements configured to collect broadband radiation emitted by the plasma along a collection path. In another illustrative embodiment, the one or more illumination optical elements are configured to define the pump path such that pump illumination impinges the plasma along a direction transverse to a direction of propagation of the emitted broadband light of the collection path such that the pump illumination is substantially decoupled from the emitted broadband radiation.
A method for transverse pumping of light-sustained plasma is disclosed. In one illustrative embodiment, the method includes generating pump illumination. In another illustrative embodiment, the method includes containing a volume of gas within a gas containment structure. In another illustrative embodiment, the method includes focusing at least a portion of the pump illumination, along a pump path, to one or more focal spots within the volume of gas to sustain an elongated plasma within the volume of gas. In another illustrative embodiment, the method includes collecting broadband radiation emitted by the plasma along a collection path defined by the axial dimension of the elongated plasma. In another illustrative embodiment, the pump illumination impinges the elongated plasma along a direction transverse to the collection path defined by the axial dimension of the elongated plasma.
It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are not necessarily restrictive of the present disclosure. The accompanying drawings, which are incorporated in and constitute a part of the characteristic, illustrate subject matter of the disclosure. Together, the descriptions and the drawings serve to explain the principles of the disclosure.
The numerous advantages of the disclosure may be better understood by those skilled in the art by reference to the accompanying figures in which:
Reference will now be made in detail to the subject matter disclosed, which is illustrated in the accompanying drawings.
Referring generally to
It is recognized that, in order to achieve stable LSP operation, pump illumination must penetrate the volume of the plasma and form a high intensity region of pump illumination near the illumination focus. As laser light penetrates the plasma and travels to the focus, the laser light is partially absorbed by the plasma. It is noted herein that the degree of plasma absorption is dependent upon a number of characteristics, such as, but not limited to, the gas used, the laser wavelength, and the pump power and geometry. In addition, it is noted that the transparency of the plasma may be tuned (i.e., increased or decreased) by changing one or more characteristics of the plasma or gas, such as, but not limited to, the pressure of the gas. For proper LSP operation, the transparency of the plasma must be high enough to transmit adequate illumination through to the focus, while being absorptive enough to provide efficient laser absorption.
In the case of broadband light collection, it is beneficial to collect the light from the hottest regions of the plasma, which are near the laser focal spot. The collected light is partially absorbed by the plasma as the light propagates away from the focal point and out of the plasma. It is noted that the degree of plasma absorption of the light is dependent on the gas used, the spectral region of the broadband light, and the plasma shape and temperature. It is further noted that the level of plasma absorption of the broadband light may be adjusted by changing one or more characteristics, such as, but not limited to, operating gas pressure. It is recognized that for adequate broadband light collection the plasma must be transparent enough to allow the transmission of broadband light from the focus and yet dense enough to provide efficient plasma emission at the collection wavelengths.
In cases where the pump illumination NA and the collection light NA overlap, both the requirements for plasma absorptivity at the pump and collection angles must be simultaneously met. It is noted that this may not be possible in many settings, such as settings where plasma absorption of the laser light is much higher or lower than that for collected light.
It is further noted that in certain pump configurations, the plasma shape can be approximately spherical, with no significant difference along any dimension. This case may be realized using a lower-power, higher pump NA laser. In other pump configurations, the plasma can have essentially elongated shape with a distinct long direction. This case may be realized using a low-NA, higher-powered laser. In yet other pump configurations, the plasma can be shaped in essentially a flat shape.
In settings where the plasma has an elongated shape, at least one dimension of the plasma has a size smaller than the other dimensions. Elongated shapes may include, but are not limited to, prolate shapes, oblate shapes, pencil-like shapes, disk-like shapes or the like.
Embodiments of the present disclosure utilize features of elongated plasmas to provide transverse pumping of the plasma. For the purposes of the present disclosure the term “transverse pumping” refers to the case where pump illumination is delivered to a plasma along the direction corresponding with the smallest dimension of the plasma. In addition, the collection of broadband radiation emitted by the plasma of the present disclosure may occur, but is not required to occur, along the direction corresponding with the largest dimension of the plasma.
In one embodiment, the LSP system 100 includes a pump source 102 configured to generate pumping illumination 103. The pump source 102 is configured to generate pumping illumination 103 of a selected wavelength, or wavelength range, such as, but not limited to, infrared, visible or UV radiation. For example, the pump source 102 may include, but is not limited to, any source capable of emitting illumination in the range of approximately 200 nm to 1.5 μm.
In another embodiment, the system 100 includes one or more optical elements 104. In one embodiment, the one or more optical elements 104 are arranged to direct pump illumination 103 into a volume of gas 109 so as to establish and/or sustain a plasma 106. In one embodiment, the one or more optical elements 104 may establish and/or sustain a plasma 106 by directing pump illumination along a pump path 101 to one or more focal spots 113 (e.g., one or more elongated focal spots).
In another embodiment, the one or more illumination optical elements 104 are arranged to define a pump path 101 such that pump illumination 103 impinges the plasma 106 transversely to the direction of propagation of the emitted broadband light 107 of the collection path 111. In one embodiment, the one or more illumination optical elements 104 are arranged such that the pump illumination 103 impinges on the plasma 106 along a direction corresponding with the smallest dimension of the plasma 106. For example, as shown in
In one embodiment, as described further herein, the one or more illumination optical elements 104 of the LSP system 100 may form an elongated plasma (or plasmas) 106 through the formation of one or more elongated focal spots 113 in the gas 109. For example, the elongated plasma 106 may take on any elongated structure known in the art defined by a first dimension and at least a second dimension, where the dimensions are not equal in size. For instance, in the case of an oblate or prolate plasma (idealized in
In another embodiment, the one or more optical elements 104 of the LSP system 100 may form a plasma 106 including multiple plasma features through the formation of a series of focal spots 113 aligned along a selected direction. It is noted herein that the one or more illumination optical elements 104 may include any optical device known in the art suitable for directing/focusing pump illumination into the gas 109.
The one or more illumination optical elements 104 may serve to defocus the pump illumination 103 such that a larger volume of space receives laser intensity sufficient to form plasma.
The one or more illumination optical elements 104 used to form the plasma 106 (or plasmas) may include any optical element or device known in the art. For example, the one or more illumination optical elements 104 may include, but are not limited to, one or more lenses, one or more mirrors and the like.
As shown in
In another embodiment, the LSP system 100 includes a gas containment structure 105. The gas containment structure 105 may include any containment structure known in the art capable of containing a gas suitable for the formation of plasma via laser pumping. For example, the gas containment structure 105 may include, but is not limited to, a chamber, a bulb, a tube or a cell. In one embodiment, the gas containment structure 105 includes one or more transparent portions suitable for transmitting the pump illumination 103 (e.g., IR, visible or UV light) from the pump source 102 to the gas 109 contained within the gas containment structure 105. In another embodiment, the gas containment structure 105 includes one or more transparent portions suitable for transmitting emitted broadband illumination 107 (e.g., EUV light, VUV light, DUV light or UV light) from within the gas containment structure 105 to one or more optical elements outside of the gas containment structure 105. For example, as shown in
In another embodiment, the LSP system 100 includes one or more collection optical elements 108. In one embodiment, the one or more collection optical elements 108 are configured to collect broadband radiation 107 emitted by the plasma 106 along the collection pathway 111. In this regard, the one or more collection optical elements 108 are arranged to collect broadband radiation 107 along the direction transverse to the direction of pumping illumination 103. In another embodiment, as noted previously herein, the one or more collection optical elements 108 are arranged to collect broadband radiation 107 along the largest dimension of the plasma 106.
For example, in the case of an elongated cylinder-shaped plasma, as depicted in
In another embodiment, the one or more collection elements 108 are suitable for collecting EUV radiation, DUV radiation, VUV radiation, UV radiation and/or visible radiation. In another embodiment, the broadband output 118 from the one or more collection elements 108 may be provided to any number of downstream optical elements 110. In this regard, the LSP system 100 may deliver EUV radiation, DUV radiation, VUV radiation, UV radiation and/or visible radiation to one or more downstream optical elements. For example, the one or more downstream optical elements may include, but are not limited to, a homogenizer, one or more focusing elements, a filter, a stirring mirror and the like. In another embodiment, the LSP system 100 may serve as an illumination sub-system, or illuminator, for an optical system, such as, but not limited to, an optical characterization system or fabrication tool. For example, the LSP system 100 may serve as an illumination sub-system, or illuminator, for a broadband inspection tool (e.g., wafer or reticle inspection tool), a metrology tool or a photolithography tool.
It is noted that the configurations depicted in
In another embodiment, the one or more illumination optical elements 104 may include a combination of one or more cylindrical optical elements (e.g., cylindrical mirror or cylindrical lens) and one or more spherical optical elements. For example, the combination of a cylindrical optical element and a spherical optical element may form an astigmatic pump beam 103 impinging on the gas 109 of the gas containment structure. In one embodiment, the astigmatic pump beam may be focused to two elongated focus spots 113 (not shown in
In another embodiment, the one or more illumination optical elements 104 may include a combination of a cylindrical lens and a cylindrical or spherical mirror. Such an arrangement may produce a back reflection of the pump illumination 103 transmitted through the plasma 106.
It is noted herein that the utilization of multiple reflections off two confocal cylindrical mirrors 104a, 104b may produce a long plasma and/or a series of axially spaced plasma features 106a-106d. It is further noted that such an arrangement is more readily implemented in context where the plasma has high transparency to the pump illumination, such as in a dilute plasma. In this setting, a dilute plasma does not much of the pump laser beam 103a, 103b, allowing the pump illumination within the volume defined by the confocal lenses 104a,104b to be collected and refocused to a different spot. As shown in
In one embodiment, the system 100 includes multiple pump illumination insertion points. For example, pump illumination 103a, 103b may enter the confocal mirror assembly at different positions along the mirror assembly. For instance, the pump illumination 103a, 103b may enter the confocal mirror assembly at opposite ends of the confocal mirrors 104a, 104b. In this regard, the mirrors 104c, 104d (e.g., cylindrical mirrors) may focus light from the opposite pump illumination beams 103a, 103b, respectively, to two oppositely-positioned focal spots 113a, 113d to form the corresponding plasma features 106a, 106d. In turn, pump illumination 103a, 103b is collected by the confocal mirrors 104a, 104b and directed to additional focal spots 113b, 113c to form plasma features 106b, 106c and so on. This process can be repeated any number of times down the length of the confocal mirror assembly 104a, 104b. In another embodiment, pump illumination 103a and pump illumination 103b may be delivered to the confocal mirror assembly 104a, 104b such that the beams of illumination 103a and 103b are counter-propagating.
While not depicted in
While
It is noted herein that the gas containment structure may take on any form described throughout the present disclosure and is not limited to the configuration of
In another embodiment, as shown in
In one embodiment, the reflector pipe 104c is sealed. For example, as shown in
It is further noted herein that for purposes of clarity only a single set of light rays of the pump illumination is depicted in
In one embodiment, the pump illumination 103a having a first NA is focused to a focal spot (not shown for purposes of clarity) to form at least a portion of the elongated plasma 106a. In turn, the pump illumination is reflected back through the resonator 124 along a second pass of pump illumination 103b having a second NA. Pump illumination from the second pass 103b also serves to form a portion of the elongated plasma 106a. This process is repeated again for a third pass 103c of pump illumination having a third NA (and so on), where the third pass of pump illumination 103c also serves to contribute to the formation of the elongated plasma 106a. It is noted that for purposes of clarity only three passes of pump illumination 103a-103c are depicted in
In another embodiment, the reflective walls of the reflector pipe 122 and/or the conical mirror 124 are configured to reflect broadband light 107, or a portion of the broadband light 107, emitted by the plasma 106a back to the plasma 106a. In this regard, the reflector pipe 122 may pump the plasma 106a using the broadband light 107, or a portion of the broadband light 107. In one embodiment, the conical mirror 124 and/or the internal walls of the reflector pipe 122 may be configured so as to be reflective to the broadband light 107 or a selected spectral portion of the broadband light. It is noted herein that the further pumping of the plasma 106a with broadband light may provide improved efficiency of the system 100.
As shown in
Referring again to
In one embodiment, as shown in
In another embodiment, as shown in
In another embodiment, the pump source 102 is adjustable. For example, the spectral profile of the output of the pump source 102 may be adjustable. In this regard, the pump source 102 may be adjusted in order to emit a pump illumination 102 of a selected wavelength or wavelength range. In another embodiment, the shape and/or size (e.g., length along collection direction) of the plasma structure 106 may be dynamically adjusted by using the adjustable pump source in combination with the dispersive element and/or the directional element of
The aspheric optical element 162 is configured to map specific portions (e.g., specific rays) of pump illumination 103 from the pump source 102 to different locations along the line focus 113. It is noted herein that by selecting the mapping function to match the input power distribution uniform power along the line focus may be achieved. The aspheric optical element 162 may include any aspheric element known in the art. For example, the aspheric optical element 162 may include, but is not limited to, one or more aspheric mirrors or one or more aspheric lenses.
In another embodiment, broadband radiation 107 emitted by the plasma 106 along the collection direction (x-direction in
Referring again to
In some embodiments, the transparent portion of the gas containment structure 105 may be formed from a low-OH content fused silica glass material. In other embodiments, the transparent portion of the gas containment structure 105 may be formed from high-OH content fused silica glass material. For example, the transparent portion of the gas containment structure 105 may include, but is not limited to, SUPRASIL 1, SUPRASIL 2, SUPRASIL 300, SUPRASIL 310, HERALUX PLUS, HERALUX-VUV, and the like. In other embodiments, the transparent portion of the gas containment structure 105 may include, but is not limited to, CaF2, MgF2, crystalline quartz and sapphire. It is noted herein that materials such as, but not limited to, CaF2, MgF2, crystalline quartz and sapphire provide transparency to short-wavelength radiation (e.g., λ<190 nm). Various glasses suitable for implementation in the transparent portion of the gas containment structure 105 (e.g., chamber window, glass bulb, glass tube or transmission element) of the present disclosure are discussed in detail in A. Schreiber et al., Radiation Resistance of Quartz Glass for VUV Discharge Lamps, J. Phys. D: Appl. Phys. 38 (2005), 3242-3250, which is incorporated herein by reference in the entirety.
In one embodiment, the gas containment structure 105 may contain any selected gas (e.g., argon, xenon, mercury or the like) known in the art suitable for generating a plasma upon absorption of pump illumination 104. In one embodiment, focusing illumination 103 from the pump source 102 into the volume of gas 109 causes energy to be absorbed by the gas or plasma (e.g., through one or more selected absorption lines) within the gas containment structure 105, thereby “pumping” the gas species in order to generate and/or sustain a plasma.
It is contemplated herein that the system 100 may be utilized to initiate and/or sustain a plasma 106 in a variety of gas environments. In one embodiment, the gas used to initiate and/or maintain plasma 106 may include a noble gas, an inert gas (e.g., noble gas or non-noble gas) or a non-inert gas (e.g., mercury). In another embodiment, the gas used to initiate and/or maintain a plasma 106 may include a mixture of two or more gases (e.g., mixture of inert gases, mixture of inert gas with non-inert gas or a mixture of non-inert gases). In another embodiment, the gas may include a mixture of a noble gas and one or more trace materials (e.g., metal halides, transition metals and the like).
By way of example, the volume of gas used to generate a plasma 106 may include argon. For instance, the gas may include a substantially pure argon gas held at pressure in excess of 5 atm (e.g., 20-50 atm). In another instance, the gas may include a substantially pure krypton gas held at pressure in excess of 5 atm (e.g., 20-50 atm). In another instance, the gas may include a mixture of two gases
It is further noted that the present invention may be extended to a number of gases. For example, gases suitable for implementation in the present invention may include, but are not limited, to Xe, Ar, Ne, Kr, He, N2, H2O, O2, H2, D2, F2, CH4, one or more metal halides, a halogen, Hg, Cd, Zn, Sn, Ga, Fe, Li, Na, Ar:Xe, ArHg, KrHg, XeHg, and the like. In a general sense, the system 100 should be interpreted to extend to any light pumped plasma generating system and should further be interpreted to extend to any type of gas suitable for sustaining a plasma within a gas containment structure.
It is noted herein that LSP system 100 may include any number and type of additional optical elements. In one embodiment, the LSP system 100 may include one or more additional optical elements arranged to direct illumination from the collection element 108 to downstream optics. In another embodiment, the set of optics may include one or more lenses placed along either the illumination pathway or the collection pathway of the LSP system 100. The one or more lenses may be utilized to focus illumination from the pump source 102 into the volume of gas within the gas containment structure 105. Alternatively, the one or more additional lenses may be utilized to focus broadband light emanating from the plasma 106 to a selected optical device, target or a focal point.
In another embodiment, the set of optics may include one or more filters placed along either the illumination pathway or the collection pathway of the LSP system 100 in order to filter illumination prior to light entering the gas containment structure 105 or to filter illumination following emission of the light from the plasma 106. It is noted herein that the set of optics of the LSP system 100 as described herein are provided merely for illustration and should not be interpreted as limiting. It is anticipated that a number of equivalent or additional optical configurations may be utilized within the scope of the present disclosure.
In another embodiment, the pump source 102 of system 100 may include one or more lasers. In a general sense, pump source 102 may include any laser system known in the art. For instance, the pump source 102 may include any laser system known in the art capable of emitting radiation in the infrared, visible or ultraviolet portions of the electromagnetic spectrum. In one embodiment, the pump source 102 may include a laser system configured to emit continuous wave (CW) laser radiation. For example, the pump source 102 may include one or more CW infrared laser sources. For instance, in settings where the gas within the gas containment structure 105 is or includes argon, the pump source 102 may include a CW laser (e.g., fiber laser or disc Yb laser) configured to emit radiation at 1069 nm. It is noted that this wavelength fits to a 1068 nm absorption line in argon and as such is particularly useful for pumping argon gas. It is noted herein that the above description of a CW laser is not limiting and any laser known in the art may be implemented in the context of the present invention.
In another embodiment, the pump source 102 may include one or more diode lasers. For example, the pump source 102 may include one or more diode lasers emitting radiation at a wavelength corresponding with any one or more absorption lines of the species of the gas contained within the gas containment structure 105. In a general sense, a diode laser of pump source 102 may be selected for implementation such that the wavelength of the diode laser is tuned to any absorption line of any plasma (e.g., ionic transition line) or any absorption line of the plasma-producing gas (e.g., highly excited neutral transition line) known in the art. As such, the choice of a given diode laser (or set of diode lasers) will depend on the type of gas contained within the gas containment structure 105 of system 100.
In another embodiment, the pump source 102 may include an ion laser. For example, the pump source 102 may include any noble gas ion laser known in the art. For instance, in the case of an argon-based plasma, the pump source 102 used to pump argon ions may include an Ar+ laser.
In another embodiment, the pump source 102 may include one or more frequency converted laser systems. For example, the pump source 102 may include a Nd:YAG or Nd:YLF laser having a power level exceeding 100 watts. In another embodiment, the pump source 102 may include a broadband laser. In another embodiment, the pump source 102 may include a laser system configured to emit modulated laser radiation or pulsed laser radiation.
In another embodiment, the pump source 102 may include one or more lasers configured to provide laser light at substantially a constant power to the plasma 106. In another embodiment, the pump source 102 may include one or more modulated lasers configured to provide modulated laser light to the plasma 106. In another embodiment, the pump source 102 may include one or more pulsed lasers configured to provide pulsed laser light to the plasma 106.
In another embodiment, the pump source 102 may include one or more non-laser sources. In a general sense, the pump source 102 may include any non-laser light source known in the art. For instance, the pump source 102 may include any non-laser system known in the art capable of emitting radiation discretely or continuously in the infrared, visible or ultraviolet portions of the electromagnetic spectrum.
In another embodiment, the pump source 102 may include two or more light sources. In one embodiment, the pump source 102 may include two or more lasers. For example, the pump source 102 (or “sources”) may include multiple diode lasers. By way of another example, the pump source 102 may include multiple CW lasers. In another embodiment, each of the two or more lasers may emit laser radiation tuned to a different absorption line of the gas or plasma within the gas containment structure 105 of system 100. In this regard, the multiple pulse sources may provide illumination of different wavelengths to the gas within the gas containment structure 105.
The herein described subject matter sometimes illustrates different components contained within, or connected with, other components. It is to be understood that such depicted architectures are merely exemplary, and that in fact many other architectures can be implemented which achieve the same functionality. In a conceptual sense, any arrangement of components to achieve the same functionality is effectively “associated” such that the desired functionality is achieved. Hence, any two components herein combined to achieve a particular functionality can be seen as “associated with” each other such that the desired functionality is achieved, irrespective of architectures or intermedial components. Likewise, any two components so associated can also be viewed as being “connected”, or “coupled”, to each other to achieve the desired functionality, and any two components capable of being so associated can also be viewed as being “couplable”, to each other to achieve the desired functionality. Specific examples of couplable include but are not limited to physically interactable and/or physically interacting components and/or wirelessly interactable and/or wirelessly interacting components and/or logically interactable and/or logically interacting components.
It is believed that the present disclosure and many of its attendant advantages will be understood by the foregoing description, and it will be apparent that various changes may be made in the form, construction and arrangement of the components without departing from the disclosed subject matter or without sacrificing all of its material advantages. The form described is merely explanatory, and it is the intention of the following claims to encompass and include such changes. Furthermore, it is to be understood that the invention is defined by the appended claims.
The present application claims the benefit under 35 U.S.C. §119(e) of U.S. Provisional Application Ser. No. 61/973,266, filed Apr. 1, 2014, entitled LASER-SUSTAINED PLASMA (LSP) TRANSVERSE PUMP GEOMETRIES, naming Ilya Bezel, Anatoly Shchemelinin, Richard Solarz and Sebaek Oh as inventors, which is incorporated herein by reference in the entirety.
Number | Name | Date | Kind |
---|---|---|---|
4118274 | Bakken | Oct 1978 | A |
4152625 | Conrad | May 1979 | A |
4166760 | Fowler | Sep 1979 | A |
4369514 | Silfvast | Jan 1983 | A |
5552675 | Lemelson | Sep 1996 | A |
7705331 | Kirk | Apr 2010 | B1 |
20070228300 | Smith | Oct 2007 | A1 |
20090032740 | Smith | Feb 2009 | A1 |
20100264820 | Sumitomo | Oct 2010 | A1 |
20110085337 | Yokota | Apr 2011 | A1 |
20110181191 | Smith | Jul 2011 | A1 |
20110254448 | Mysyrowicz | Oct 2011 | A1 |
20120161631 | Kuwabara | Jun 2012 | A1 |
20120205546 | Solarz | Aug 2012 | A1 |
20130001438 | Bezel | Jan 2013 | A1 |
20130003384 | Bezel | Jan 2013 | A1 |
20130114637 | Chivel | May 2013 | A1 |
20130126751 | Mizoguchi | May 2013 | A1 |
20130329204 | Pellemans | Dec 2013 | A1 |
20130342105 | Shchemelinin et al. | Dec 2013 | A1 |
20140042336 | Bezel et al. | Feb 2014 | A1 |
20150168847 | Solarz | Jun 2015 | A1 |
20150262808 | Wang | Sep 2015 | A1 |
20150268559 | Badie | Sep 2015 | A1 |
20150271905 | Oh | Sep 2015 | A1 |
20150311058 | Antsiferov | Oct 2015 | A1 |
20160044774 | Antsiferov | Feb 2016 | A1 |
Entry |
---|
PCT Search Report dated Jul. 24, 2015, International Application No. PCT/US2015/023939, 3 pages. |
Number | Date | Country | |
---|---|---|---|
20150282288 A1 | Oct 2015 | US |
Number | Date | Country | |
---|---|---|---|
61973266 | Apr 2014 | US |